CN102920020A - Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof - Google Patents
Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof Download PDFInfo
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- CN102920020A CN102920020A CN2012104623642A CN201210462364A CN102920020A CN 102920020 A CN102920020 A CN 102920020A CN 2012104623642 A CN2012104623642 A CN 2012104623642A CN 201210462364 A CN201210462364 A CN 201210462364A CN 102920020 A CN102920020 A CN 102920020A
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- cigarette filter
- filter stick
- gucosamine
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Abstract
The invention discloses a glucosamine loaded cigarette filter stick additive, as well as a preparation method and an application method of the additive. The preparation method comprises the following steps: taking glucosamine as an active ingredient; taking silica gel, activated carbon, aluminum oxide and sodium alginate as carriers; loading the active ingredients on surfaces of the carriers by a surface chemical reaction to obtain loaded type materials; adding the prepared loaded type materials into a cigarette filter stick to prepare a composite filter stick; and rolling up the cigarette. The analysis shows that the cigarette with the loaded type materials can effectively reduce content of HCN (hydrogen cyanide) in the smoke by 15-37%, and content of volatile carbonyl compound by 8-15%. The cigarette filter stick additive capable of reducing harm is safe, stable, simple in preparation method and convenient to industrially produce at large scale.
Description
Technical field
The invention belongs to cigarette producing field, be specifically related to have cigarette filter tip additive and the methods for making and using same thereof of reducing poison function.
Background technology
Hydrogen cyanide (HCN) and volatile carbonyl compound are to mainly contain one of harmful substances in the flue gas, also are one of important environomental pollution sources simultaneously, and it may make the people dead, very harmful in several minutes in severe case.Contain group compounds of aldehydes and ketones in the cigarette smoke, proved that now the aldoketones pollutant in the atmosphere has the strong impulse effect to people's eyes, skin and respiratory tract, wherein formaldehyde, methacrylaldehyde have carcinogenesis to animal, and some other aldoketones also has very large harm to human body health.So this two classes nuisance in the necessary reduction flue gas, data shows has a large amount of scientific and technical personnel and mechanism to do related work.
That Chinese patent CN101116540A discloses is a kind of " for reducing the tobacco additive agent of content of group compounds of aldehydes and ketones in the cigarette smoke and its preparation method and application ", and it declares to reduce aldoketones material in the flue gas.CN2803014Y discloses a kind of " cigarette copper palladium base remodeling activated carbon fiber composite filter-tip ", can reduce aldehyde material in the flue gas, HCN and other harmful components.But these patented technologies relate to the problem such as complexity or active component security of technique, are difficult to large-scale industrial production, thereby substantially do not possess application prospect.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of additive of cigarette filter stick and methods for making and using same thereof that hydrogen cyanide in the flue gas (HCN) and volatile carbonyl compound is had the removal effect is provided.
The present invention realizes by following manner:
A kind of additive of cigarette filter stick of load gucosamine, described additive of cigarette filter stick are the additives that gucosamine is carried on the solid granular that forms on the carrier.
The shared mass ratio of gucosamine is 3-15% in the described additive.
Described carrier comprises one or more in silica gel, active carbon, aluminium oxide and the Na-alginate.
Described carrier granular degree is the 40-60 order.
A kind of preparation method of additive of cigarette filter stick of load gucosamine is that gucosamine is mixed with the solution that mass concentration is 5%-20%, carrier is immersed in wherein oven dry in 20 minutes-3 hours obtains.
Described bake out temperature is 80 ° of C-100 ° of C.
Described drying time is 9-24 hour.
The additive of cigarette filter stick of described load gucosamine adds in the cigarette filter rod for reducing hydrogen cyanide in the flue gas and content of volatile carbonyl compound.Specifically described additive is sieved and get 40-60 order particle, then prop up with 20-40mg/ and add in the cigarette filter.
The present invention compared with prior art, its maximum characteristics are that additive preparation technology is simple, are fit to industrialized production; Selected active material safety non-toxic, can not introduce external harm simultaneously this additive have the effect that reduces preferably hydrogen cyanide in the flue gas (HCN) and volatile carbonyl compound.
The specific embodiment
Following examples are intended to illustrate the present invention rather than the present invention are further limited.
Embodiment 1
Prepare 10% gucosamine solution 100g with distilled water, claim silochrom 100g, solution is slowly added in the silica gel, stir simultaneously, infuse made it abundant infiltration in 0.5 hour; In wet particle thing immigration baking oven, under 80 ° of C conditions, cause thermal response and toast with this understanding 24h, material is fully reacted and drying, naturally cool to room temperature, it is stand-by that the removal fine powder that sieves is got 40-60 order particle.
The additive that makes propped up with 40mg/ add in the cigarette filter, the flue gas inspection result shows that this material can effectively reduce hydrogen cyanide in the flue gas (HCN) 32.4%, reduces crotonaldehyde 14.9%.
Embodiment 2
Prepare 20% gucosamine solution 100g with distilled water, claim active carbon 114g, solution is slowly added in the active carbon, stir simultaneously, infuse made it abundant infiltration in 2 hours; The wet particle thing is moved in the baking oven, and baking made material fully dry in 12 hours under 100 ° of C conditions, naturally cooled to room temperature, and it is stand-by that the removal fine powder that sieves is got 40-60 order particle.
The additive that makes propped up with 40mg/ add in the cigarette filter, the flue gas inspection result shows that this material can effectively reduce hydrogen cyanide in the flue gas (HCN) 35.6%, reduces crotonaldehyde 12.1%.
Embodiment 3
Prepare 5% gucosamine solution 100g with distilled water, claim aluminium oxide 50g, solution is slowly added in the aluminium oxide, stir simultaneously, infuse made it abundant infiltration in 1 hour; The wet particle thing moved in the baking oven baking made material fully dry in 10 hours under 90 ° of C conditions, naturally cool to room temperature, sieve and remove fine powder to get 40-60 order particle stand-by.
The additive that makes propped up with 40mg/ add in the cigarette filter, the flue gas inspection result shows that this material can effectively reduce hydrogen cyanide in the flue gas (HCN) 21.5%, reduces crotonaldehyde 10.4%.
Embodiment 4
Prepare 20% gucosamine solution 100g with distilled water, claim sodium alginate 114g, solution is slowly added in the active carbon, stir simultaneously, infuse made it abundant infiltration in 0.5 hour; The wet particle thing is moved in the baking oven, and baking made material fully dry in 12 hours under 90 ° of C conditions, naturally cooled to room temperature, and it is stand-by that the removal fine powder that sieves is got 40-60 order particle.
The additive that makes propped up with 40mg/ add in the cigarette filter, the flue gas inspection result shows that this material can effectively reduce hydrogen cyanide in the flue gas (HCN) 30.1%, reduces crotonaldehyde 13.7%.
Embodiment 5
Prepare 5% gucosamine solution 120g with distilled water, claim aluminium oxide 194g, solution is slowly added in the silica gel, stir simultaneously, infuse made it abundant infiltration in 1.0 hours; In wet particle thing immigration baking oven, under 80 ° of C conditions, cause thermal response and toast with this understanding 24h, material is fully reacted and drying, naturally cool to room temperature, it is stand-by that the removal fine powder that sieves is got 40-60 order particle.
The additive that makes propped up with 20mg/ add in the cigarette filter, the flue gas inspection result shows that this material can effectively reduce hydrogen cyanide in the flue gas (HCN) 14.9%, reduces crotonaldehyde 8.1%.
Embodiment 6
Prepare 20% gucosamine solution 100g with distilled water, claim sodium alginate 114g, solution is slowly added in the active carbon, stir simultaneously, infuse made it abundant infiltration in 0.5 hour; The wet particle thing is moved in the baking oven, and baking made material fully dry in 12 hours under 90 ° of C conditions, naturally cooled to room temperature, and it is stand-by that the removal fine powder that sieves is got 40-60 order particle.
The additive that makes propped up with 30mg/ add in the cigarette filter, the flue gas inspection result shows that this material can effectively reduce hydrogen cyanide in the flue gas (HCN) 24.6%, reduces crotonaldehyde 11.2%.
Claims (9)
1. the additive of cigarette filter stick of a load gucosamine is characterized in that, described additive of cigarette filter stick is the additive that gucosamine is carried on the solid granular that forms on the carrier.
2. the additive of cigarette filter stick of load gucosamine according to claim 1 is characterized in that, the shared mass ratio of gucosamine is 3-15% in the described additive.
3. the additive of cigarette filter stick of load gucosamine according to claim 1 is characterized in that, described carrier comprises one or more in silica gel, active carbon, aluminium oxide and the Na-alginate.
4. the additive of cigarette filter stick of load gucosamine according to claim 1 is characterized in that, described carrier granular degree is the 40-60 order.
5. the preparation method of the additive of cigarette filter stick of a load gucosamine is characterized in that, is gucosamine is mixed with the solution that mass concentration is 5%-20%, carrier is immersed in wherein oven dry in 20 minutes-3 hours obtains.
6. the preparation method of the additive of cigarette filter stick of load gucosamine according to claim 5 is characterized in that, described bake out temperature is 80 ° of C-100 ° of C.
7. the preparation method of the additive of cigarette filter stick of load gucosamine according to claim 5 is characterized in that, described drying time is 9-24 hour.
8. the application process of the additive of cigarette filter stick of each described load gucosamine of claim 1-4 is characterized in that, adds in the cigarette filter rod for reducing hydrogen cyanide in the flue gas and content of volatile carbonyl compound.
9. application process according to claim 8 is characterized in that, described additive is sieved get 40-60 order particle, then props up with 20-40mg/ and adds in the cigarette filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104623642A CN102920020A (en) | 2012-11-16 | 2012-11-16 | Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104623642A CN102920020A (en) | 2012-11-16 | 2012-11-16 | Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof |
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| CN102920020A true CN102920020A (en) | 2013-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012104623642A Pending CN102920020A (en) | 2012-11-16 | 2012-11-16 | Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106076250A (en) * | 2016-06-24 | 2016-11-09 | 广东中烟工业有限责任公司 | A kind of preparation method and application of adsorbing material |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4638816A (en) * | 1985-03-22 | 1987-01-27 | Philip Morris Incorporated | Smoking compositions containing a glycosylamine flavorant additive |
| JPS6363369A (en) * | 1986-09-03 | 1988-03-19 | サントリー株式会社 | Tobacco filter |
| JPH0731452A (en) * | 1993-07-17 | 1995-02-03 | Taisei Boseki Kk | Cigarrete filter |
| US6440223B1 (en) * | 2000-02-15 | 2002-08-27 | R. J. Reynolds Tobacco Co. | Smoking article containing heat activatable flavorant-generating material |
| JP2003137789A (en) * | 2001-11-02 | 2003-05-14 | Yaizu Suisankagaku Industry Co Ltd | Nitrogen monoxide eliminator |
| CN1561872A (en) * | 2004-03-25 | 2005-01-12 | 江南大学 | Method for producing diacetate fiber tows of chitosan modified cigarette |
| CN1709170A (en) * | 2004-06-18 | 2005-12-21 | 江晓路 | Method for improving tobacco (cut tobacco) quality and effect using oligosaccharide |
| CN101336752A (en) * | 2007-07-06 | 2009-01-07 | 湖南中烟工业有限责任公司 | Filter-tip capable of reducing hydrocyanic acid in cigarette flue gas |
| CN101433371B (en) * | 2008-12-19 | 2011-10-12 | 湖南中烟工业有限责任公司 | Papery filter tip for reducing aldehydes material in smoke of cigarette and preparation method thereof |
| CN102499476A (en) * | 2011-11-03 | 2012-06-20 | 湖南中烟工业有限责任公司 | Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip |
-
2012
- 2012-11-16 CN CN2012104623642A patent/CN102920020A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4638816A (en) * | 1985-03-22 | 1987-01-27 | Philip Morris Incorporated | Smoking compositions containing a glycosylamine flavorant additive |
| JPS6363369A (en) * | 1986-09-03 | 1988-03-19 | サントリー株式会社 | Tobacco filter |
| JPH0731452A (en) * | 1993-07-17 | 1995-02-03 | Taisei Boseki Kk | Cigarrete filter |
| US6440223B1 (en) * | 2000-02-15 | 2002-08-27 | R. J. Reynolds Tobacco Co. | Smoking article containing heat activatable flavorant-generating material |
| JP2003137789A (en) * | 2001-11-02 | 2003-05-14 | Yaizu Suisankagaku Industry Co Ltd | Nitrogen monoxide eliminator |
| CN1561872A (en) * | 2004-03-25 | 2005-01-12 | 江南大学 | Method for producing diacetate fiber tows of chitosan modified cigarette |
| CN1709170A (en) * | 2004-06-18 | 2005-12-21 | 江晓路 | Method for improving tobacco (cut tobacco) quality and effect using oligosaccharide |
| CN101336752A (en) * | 2007-07-06 | 2009-01-07 | 湖南中烟工业有限责任公司 | Filter-tip capable of reducing hydrocyanic acid in cigarette flue gas |
| CN101433371B (en) * | 2008-12-19 | 2011-10-12 | 湖南中烟工业有限责任公司 | Papery filter tip for reducing aldehydes material in smoke of cigarette and preparation method thereof |
| CN102499476A (en) * | 2011-11-03 | 2012-06-20 | 湖南中烟工业有限责任公司 | Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip |
Non-Patent Citations (1)
| Title |
|---|
| A.E.齐齐巴宾: "《有机化学基本原理》", 31 December 1961 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106076250A (en) * | 2016-06-24 | 2016-11-09 | 广东中烟工业有限责任公司 | A kind of preparation method and application of adsorbing material |
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Application publication date: 20130213 |