CN104116133A - Application of polymers rich in amino groups in paper filter stick - Google Patents
Application of polymers rich in amino groups in paper filter stick Download PDFInfo
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- CN104116133A CN104116133A CN201410372301.7A CN201410372301A CN104116133A CN 104116133 A CN104116133 A CN 104116133A CN 201410372301 A CN201410372301 A CN 201410372301A CN 104116133 A CN104116133 A CN 104116133A
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Abstract
The invention discloses an application of polymers rich in amino groups in a paper filter stick. The polymers rich in amino groups are prepared into aqueous solutions with the mass fraction ranging from 0.01 percent to 1 percent, the aqueous solutions are directly added to paper for the paper filter stick, and the mass fraction of the polymers rich in amino groups in the paper for the paper filter stick ranges from 0.01 percent to 1 percent; or activated carbon or silicon oxide or alumina carrier materials are added into the polymer aqueous solutions with the mass fraction ranging from 0.01 percent to 1 percent, carrier materials loaded with the polymers rich in amino groups are obtained after centrifugation and drying are carried out, and 0.1-3 mg of the carrier materials is applied to each millimeter of the paper filter stick. The polymers rich in amino groups are added to the paper filter stick, so that suction quality is improved, the purpose of harm reduction is achieved, the process is simple, cost is low, and industrial feasibility is achieved.
Description
technical field:
The invention belongs to additive of cigarette filter stick technical field, be specifically related to the application of a kind of polymer that is rich in amino group in paper filter stick.
background technology:
Cigarette filter is the main cigarette supplementary of tobacco business, along with the growing interest of society to smoking and health problem, Jiao falls in Harm reduction techniques becomes the focus of cigarette area research, and the design of cigarette filter rod and the selection of material suction quality and the lowering harm and decreasing coking on cigarette has significant impact.Compared with the cellulose acetate filter rod generally using at present, Jiao is falling in paper filter stick, in cost and environmental protection, there is obvious advantage, but paper filter stick cigarette burn and suck in process in cigarette exist heat to subside, flue gas is dry, excitant is large, have the shortcomings such as obvious paper taste, makes it be difficult in cigarette generally application.How, in keeping cigarette style characteristic, reduce the harm of paper filter stick cigarette to human body, improve the suction quality of cigarette, become one of tobacco business problem in the urgent need to address.
In the disclosed method of Chinese patent application CN101731757A, the spray solution that contains humectant by handle has obviously reduced paper taste, excitant and the peculiar smell of paper filter stick cigarette on papery filter material, but the method can not optionally reduce the part harmful components in flue gas.In the disclosed method of Chinese patent application CN101967770A, by add the functionalized diacetate fiber of aminated compounds in paper filter stick fiber, not only overcome the flue gas that paper filter stick causes dry, the shortcoming that aesthetic quality declines, can also effectively remove the phenol type substances in flue gas, but it is relatively loaded down with trivial details to prepare the functionalized diacetate fiber technique of aminated compounds.
summary of the invention:
The object of the present invention is to provide the application of a kind of polymer that is rich in amino group in paper filter stick, this additive can effectively reduce the hydrogen cyanide in cigarette smoke, crotonaldehyde and phenol harmful components are improved the dry defect with inhaling taste variation of flue gas that common paper filter stick causes simultaneously.
The present invention is achieved through the following technical solutions:
The application of a kind of polymer that is rich in amino group in paper filter stick, it is that the aqueous solution of 0.01%-1% adds in paper filter stick paper using that the polymer formulation that is rich in amino group is become to mass fraction, the mass fraction of the polymer that is rich in amino group in paper filter stick paper using is 0.01%-1%, is added with paper filter stick paper using drying, the embossing of described polymer and cuts the mouth rod forming machine processing and forming that rear employing generally uses at present to become paper filter stick.
The application of a kind of polymer that is rich in amino group in paper filter stick, it is the aqueous solution of 0.01%-1% that the polymer formulation that is rich in amino group is become to mass fraction, in the aqueous solution, add active carbon or silica or alumina supporting material according to the 0.1%-1% of aqueous solution mass fraction, stir after 5 hours through centrifugal, dry and obtain load and have the carrier material of described polymer, this carrier material adopts conventional adding method to add in paper filter stick in paper filter stick processing and forming, and addition is 0.1mg-3mg in every millimeter of filter stick.
Preferably, the polymer that is rich in amino group described in is one or more of PEOz, polypropylene amine, polymethylacrylic acid diformazan ammonia ethyl ester, polyacrylamide, PMAm and polymine.
Preferably, by the method spraying or flood, the aqueous solution of described polymer is added in paper filter stick paper using.
Preferably, described active carbon or silica or alumina supporting material are 30-100 order.
Compared with prior art, tool has the following advantages in the present invention:
1, the application of the polymer that is rich in amino group of the present invention in paper filter stick, has improved suction quality, has reached the object of harm reduction, and technique is simple simultaneously, and cost is low, has commercial viability.
2, the amino of high reaction activity not only has moisture-keeping function, has improved flue gas by the water balance of paper filter stick, reduces excitant, improves oral cavity comfort level, obviously reduces the dry sensation of flue gas; Can also hold back the part harmful components in flue gas, as hydrogen cyanide, crotonaldehyde and phenol type substances, thus play harm reduction and the effect that regulates flue gas acid-base value, improve the suction quality of paper filter stick.
The amino that contains abundant high reaction activity in PEOz, polypropylene amine, polymethylacrylic acid diformazan ammonia ethyl ester, polyacrylamide, PMAm and polymine strand; there is high tack and hygroscopicity; can generate hydrogen bond and ionic bond with organic acid reaction, react with carbonic acyl radical and generate covalent bond.The present invention applies the polymer that is rich in amino group in paper filter stick, by literature search, has no the open source literature report identical with the present invention.The polymer that is rich in amino group adds in paper filter stick, has improved suction quality, has reached the object of harm reduction, and technique is simple simultaneously, and cost is low, has commercial viability.
detailed description of the invention:
The polymer that is rich in amino group that the present invention proposes comprises one or more of PEOz, polypropylene amine, polymethylacrylic acid diformazan ammonia ethyl ester, polyacrylamide, PMAm and polymine.
This base polymer water obtains the aqueous solution that mass fraction is 0.01%-1% after dissolving, and is applied in paper filter stick paper using by the mode of spray, dipping, and the mass fraction of polymer in paper filter stick paper using is 0.01%-1%.
This base polymer adds in paper filter stick by carrier loaded form, and carrier material is any of active carbon, silica and aluminium oxide, and its size distribution is 30 order-120 orders.
Adopt when carrier loaded, first after this base polymer water being dissolved, obtain the aqueous solution that mass fraction is 0.01%-1%, in the aqueous solution, add carrier material according to the 0.1%-1% of aqueous solution mass fraction, stir after 5 hours through centrifugal, dry and obtain load and have the carrier material of this base polymer, the applied amount of carrier material in paper filter stick is 0.1mg-3mg in every millimeter of filter stick.
Application process of the present invention is after water-soluble the polymer that is rich in amino group, to add on papery filter material by the mode of spray, dipping, and then papery filter material adopts conventional method for processing forming to prepare paper filter stick or composite filter through embossing with after cutting.Or in paper filter stick processing and forming, adopt conventional adding method to have the carrier material of the polymer that is rich in amino group to prepare paper filter stick or composite filter in adding filter stick to load.
Below in conjunction with the technical scheme in embodiment, the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiment.Those skilled in the art, not paying the every other embodiment obtaining under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1:
4g PEOz, 3g polypropylene amine and 3g polymethylacrylic acid diformazan ammonia ethyl ester are dissolved in and in deionized water, obtain mass fraction is 1% the aqueous solutions of polymers that is rich in amino group, by the method spraying or flood, this polymer is added in paper filter stick paper using, the mass fraction of polymer in paper filter stick paper using is 1%.Paper filter stick paper using drying, embossing and cut the conventional method for processing forming of rear employing and make paper filter stick, long this paper filter stick for 15cm is made to composite filter after compound with long for 15cm cellulose acetate filter rod, taking long 30cm cellulose acetate filter rod as contrast, after rolling into cigarette, test, can reach respectively 35.4%, 30.2% and 20.3% to the clearance of HCN, phenol and crotonaldehyde, sensory quality assessment improves 1.5 points.
embodiment 2:
0.1g polymine is dissolved in and in deionized water, obtains mass fraction is 0.01% the aqueous solution, is that this polymer is added in paper filter stick paper using by the method spraying or flood, and the mass fraction of this polymer in paper filter stick paper using is 0.01%.Add paper filter stick paper using drying, the embossing of this polymer and cut the conventional method for processing forming of rear employing and made paper filter stick, after compound to this paper filter stick of long 10cm and long 20cm cellulose acetate filter rod, make composite filter, taking long 30cm cellulose acetate filter rod as contrast, after rolling into cigarette, can reach respectively 10.7%, 8.3% and 5.2% to the clearance of HCN, phenol and crotonaldehyde, sensory quality assessment improves 0.5 point.
embodiment 3:
1g PEOz, 1g polypropylene amine, 1g polyacrylamide and 2g polymine are dissolved in and in deionized water, obtain mass fraction is 0.5% aqueous solutions of polymers, be that this polymer is added in paper filter stick paper using by the method spraying or flood, the mass fraction of polymer in paper filter stick paper using is 0.5%.Drying, embossing and cut the conventional method for processing forming of rear employing and make paper filter stick, after compound to this paper filter stick of long 10cm and long 15cm cellulose acetate filter rod, make composite filter, taking long 25cm cellulose acetate filter rod as contrast, after rolling into cigarette, can reach respectively 20.3%, 16.4% and 18.7% to the clearance of HCN, phenol and crotonaldehyde, sensory quality assessment improves 2 points.
embodiment 4:
2g PEOz, 3g polypropylene amine, 2g PMAm and 3g polymine are dissolved in and in deionized water, obtain mass fraction is 1% the aqueous solution, in the above-mentioned aqueous solution, adding 30 object active carbons to make its mass fraction is 1%, stir, centrifugal drying after stirring 5h, load has the active carbon of polymer to add and make paper filter stick in paper filter stick molding process, and addition is 0.1mg-0.8mg in every millimeter of filter stick.After compound to long 15cm paper filter stick and long 15cm acetic acid filter stick, make composite filter, taking long 30cm cellulose acetate filter rod as contrast, after rolling into cigarette, can reach respectively 28.9%, 24.7% and 22.4% to the clearance of HCN, phenol and crotonaldehyde, sensory quality assessment improves 3 points.
embodiment 5:
0.1g PEOz is dissolved in and in deionized water, obtains mass fraction is 0.01% the aqueous solution, in the above-mentioned aqueous solution, adding 100 object porous silicas to make its mass fraction is 0.1%, stir, centrifugal drying after stirring 5h, load has the silica of polymer to add and make paper filter stick in paper filter stick molding process, and addition is 0.8mg-1.6mg in every millimeter of filter stick.10cm paper filter stick and 20cm acetic acid filter stick are made to composite filter after compound, taking 30cm cellulose acetate filter rod as contrast, can reach respectively 12.4% and 9.5% to the clearance of HCN and phenol after rolling into cigarette, sensory quality assessment improves 1.5 points.
embodiment 6:
1g PEOz, 1.5g polypropylene amine, 1g PMAm, 1g polymethylacrylic acid diformazan ammonia ethyl ester and 1.5g polymine are dissolved in and in deionized water, obtain mass fraction is 0.4% the aqueous solution, in the above-mentioned aqueous solution, adding 80 object aluminium oxide to make its mass fraction is 0.4%, after stirring 5h, centrifugal drying obtains load the alumina supporting material of above-mentioned polymer, the paper filter stick that load has the aluminium oxide of polymer to make add paper filter stick in conventional paper filter stick molding process in, addition is 1.6mg-3mg in every millimeter of filter stick.After compound to long 10cm paper filter stick and long 15cm acetic acid filter stick, make composite filter, taking long 25cm cellulose acetate filter rod as contrast, after rolling into cigarette, can reach respectively 28.9%, 24.7% and 20.4% to the clearance of HCN, phenol and crotonaldehyde, sensory quality assessment improves 2.5 points.
Claims (5)
1. a polymer that the is rich in amino group application in paper filter stick, it is characterized in that, it is that the aqueous solution of 0.01%-1% adds in paper filter stick paper using that the polymer formulation that is rich in amino group is become to mass fraction, the mass fraction of the polymer that is rich in amino group in paper filter stick paper using is 0.01%-1%, is added with paper filter stick paper using drying, the embossing of described polymer and cuts the mouth rod forming machine processing and forming that rear employing generally uses at present to become paper filter stick.
2. a polymer that the is rich in amino group application in paper filter stick, it is characterized in that, it is the aqueous solution of 0.01%-1% that the polymer formulation that is rich in amino group is become to mass fraction, in the aqueous solution, add active carbon or silica or alumina supporting material according to the 0.1%-1% of aqueous solution mass fraction, stir after 5 hours through centrifugal, dry and obtain load and have the carrier material of described polymer, this carrier material adopts conventional adding method to add in paper filter stick in paper filter stick processing and forming, and addition is 0.1mg-3mg in every millimeter of filter stick.
3. the application of a kind of polymer that is rich in amino group according to claim 1 and 2 in paper filter stick, it is characterized in that, described in be rich in amino group polymer be one or more of PEOz, polypropylene amine, polymethylacrylic acid diformazan ammonia ethyl ester, polyacrylamide, PMAm and polymine.
4. the application of a kind of polymer that is rich in amino group according to claim 1 in paper filter stick, is characterized in that, by the method spraying or flood, the aqueous solution of described polymer is added in paper filter stick paper using.
5. the application of a kind of polymer that is rich in amino group according to claim 2 in paper filter stick, is characterized in that, described active carbon or silica or alumina supporting material are 30-100 order.
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| CN201410372301.7A CN104116133A (en) | 2014-07-31 | 2014-07-31 | Application of polymers rich in amino groups in paper filter stick |
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| CN201410372301.7A CN104116133A (en) | 2014-07-31 | 2014-07-31 | Application of polymers rich in amino groups in paper filter stick |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705783A (en) * | 2015-01-21 | 2015-06-17 | 中国烟草总公司郑州烟草研究院 | Filter tip additive material capable of improving sensory characteristics of smoke and application thereof |
| CN104720103A (en) * | 2015-02-11 | 2015-06-24 | 浙江中烟工业有限责任公司 | Cigarette filter additive and preparation method and application thereof |
| CN105342006A (en) * | 2015-12-09 | 2016-02-24 | 中国烟草总公司郑州烟草研究院 | Liquid function material for selectively reducing HCN in cigarette main stream smoke and application thereof |
| CN106174693A (en) * | 2016-08-25 | 2016-12-07 | 福建中烟工业有限责任公司 | A kind of cigarette filter rod containing Amino End Group polyamideamine polymers |
| CN107594616A (en) * | 2017-09-15 | 2018-01-19 | 福建中烟工业有限责任公司 | Adsorbing composition, its preparation method and application |
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| US3716063A (en) * | 1970-09-25 | 1973-02-13 | Brown & Williamson Tobacco | Selective gas phase filter material |
| CN101194755A (en) * | 2007-12-21 | 2008-06-11 | 湖南中烟工业有限责任公司 | Additive agent selectively reducing aldehydes matter in cigarette flue gas, production method and application thereof |
| CN101408012A (en) * | 2008-10-31 | 2009-04-15 | 湖南中烟工业有限责任公司 | Paper and filter stick of paper filter stick for reducing phenols material in cigarette smoke and preparing method thereof |
| CN101433371A (en) * | 2008-12-19 | 2009-05-20 | 湖南中烟工业有限责任公司 | Papery filter tip for reducing aldehydes material in smoke of cigarette and preparation method thereof |
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2014
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3716063A (en) * | 1970-09-25 | 1973-02-13 | Brown & Williamson Tobacco | Selective gas phase filter material |
| CN101194755A (en) * | 2007-12-21 | 2008-06-11 | 湖南中烟工业有限责任公司 | Additive agent selectively reducing aldehydes matter in cigarette flue gas, production method and application thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705783A (en) * | 2015-01-21 | 2015-06-17 | 中国烟草总公司郑州烟草研究院 | Filter tip additive material capable of improving sensory characteristics of smoke and application thereof |
| CN104720103A (en) * | 2015-02-11 | 2015-06-24 | 浙江中烟工业有限责任公司 | Cigarette filter additive and preparation method and application thereof |
| CN104720103B (en) * | 2015-02-11 | 2018-01-30 | 浙江中烟工业有限责任公司 | A kind of cigarette filter-tip additive agent and its preparation method and application |
| CN105342006A (en) * | 2015-12-09 | 2016-02-24 | 中国烟草总公司郑州烟草研究院 | Liquid function material for selectively reducing HCN in cigarette main stream smoke and application thereof |
| CN105342006B (en) * | 2015-12-09 | 2021-03-12 | 中国烟草总公司郑州烟草研究院 | Liquid functional material for selectively reducing HCN in mainstream smoke of cigarettes and application thereof |
| CN106174693A (en) * | 2016-08-25 | 2016-12-07 | 福建中烟工业有限责任公司 | A kind of cigarette filter rod containing Amino End Group polyamideamine polymers |
| CN107594616A (en) * | 2017-09-15 | 2018-01-19 | 福建中烟工业有限责任公司 | Adsorbing composition, its preparation method and application |
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Application publication date: 20141029 |
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