CN103005712A - Grapheme type fiber cigarette filter and preparation method thereof - Google Patents

Grapheme type fiber cigarette filter and preparation method thereof Download PDF

Info

Publication number
CN103005712A
CN103005712A CN2013100015888A CN201310001588A CN103005712A CN 103005712 A CN103005712 A CN 103005712A CN 2013100015888 A CN2013100015888 A CN 2013100015888A CN 201310001588 A CN201310001588 A CN 201310001588A CN 103005712 A CN103005712 A CN 103005712A
Authority
CN
China
Prior art keywords
graphene
fiber
filter
carrier
class
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013100015888A
Other languages
Chinese (zh)
Inventor
朱怀远
盛金
庄亚东
尤晓娟
刘献军
沈晓晨
张媛
曹毅
张映
熊晓敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Tobacco Jiangsu Industrial Co Ltd
Original Assignee
China Tobacco Jiangsu Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Tobacco Jiangsu Industrial Co Ltd filed Critical China Tobacco Jiangsu Industrial Co Ltd
Priority to CN2013100015888A priority Critical patent/CN103005712A/en
Publication of CN103005712A publication Critical patent/CN103005712A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses a grapheme type fiber cigarette filter and a preparation method thereof. The filter comprises a fiber carrier, wherein the fiber carrier is provided with a grapheme type material for absorbing harmful components in smoke. The filter loads the grapheme type material on a carbon fiber or acetate fiber carrier; and the carrier is added in the filter by adopting the binary filter production mode in the existing industries to produce a compound filter for absorbing harmful substances in the smoke which is generated when cigarettes are smoked. The filter applies unique phi absorption characteristics and higher surface active atom ratio of novel two-dimensional nanometer materials to efficiently absorb benzo [a] pyrene, volatile aldehyde ketone type cancer promoting molecules, phenol and HCN (Hydrogen Cyanide) under the condition of smaller adding quantity, so that the filter is environment-friendly and has no additional poison; as the amount is small and the effect is high, the harm of the cigarettes to human bodies is reduced under the condition of not influencing the inherent sensory quality of the cigarettes. And at the same time, the method has the advantages of simple technique, large-scale production and low cost, and has wide application foreground in the cigarette field of harm reduction and tar reduction.

Description

A kind of Graphene fiber cigarette filter and preparation method thereof
Technical field
The present invention relates to technical field of cigarettes, be specifically related to a kind of Graphene fiber cigarette filter and preparation method thereof.
Background technology
Produce NH in the cigarette burning process 3, the harmful substances such as CO, phenol, benzo [a] pyrene, HCN, crotonaldehyde, methyl nitrosamine pyridine radicals butanone (NNK), when suction, enter human body with flue gas and work the mischief.Cigarette filter can stop these materials to enter human body to a certain extent.
At first, cigarette filter is take single fibrous material as main, and is low to the adsorption efficiency of harmful substance; Afterwards, along with the development of material technology, the fibrous material of body phase composite fibre, ion-exchange fibre, metal or doped metallic oxide, nano carbon sol etc. were used to make by different way cigarette filter.As in CN101019692A, disclose a kind of in cellulose acetate equably blending account for the filter tip of the NACF of its certain weight proportion, improved filter stick or filter tip to the adsorption efficiency of volatilization and half volatile harmful substance in the main flume; In CN1652703A, a kind of filter tip is disclosed, this filter tip contains the fiber of a branch of energy loaded particle thing, bead or powder, helps reduce flue gas composition.These methods have all reduced the harmful components in the cigarette mainstream flue gas to a certain extent, but because traditional macromolecular material or metallochemistry material itself have the characteristics such as poor selectivity, low, the active conjugation of polarity site are few, take physical absorption as main, lower to the adsorption efficiency of harmful substances in flue gas to the suction type of harmful substance.
Along with the development of nanometer technology, nano material is applied to the every field of productive life gradually.Nano composite material is applied to the research of harmful components in the selective absorption cigarette mainstream flue gas shows up prominently, although very limited, all obtained good effect.(Feng Shouai etc., the nanometer SiO such as Feng Shouai 2The research of harmful components in the selective absorption cigarette mainstream flue gas, the material Leader, 2011,25,44-46) reported nanometer SiO the end of the year 2011 2Make dispersion liquid and be injected in the mouth rod, the result show benzo in the flue gas [a] pyrene, phenol and crotonaldehyde content more than 8%; Xu Yihua makes efficient tobacco filters (patent No.200810063747. 6) with nano carbon sol, thinks that effect is fine.Although nano carbon sol has more adsorption activity site, also have simultaneously complicated components, the surface atom number does not reach best with the ratio of total atom number, and to the shortcomings such as poor selectivity of absorbed component.
Graphene (Graphene) be a kind of by carbon atom with sp 2Hybridized orbit forms the brand-new two-dimensional nano material of cellular regular hexagon lattice, except the characteristic with common nano material, also has unique p key conjugation suction-operated and chemical catalysis activity.It was found the rear global research boom that evoked rapidly, and the finder also obtained Nobel Prize in physics in 2010.It is prize-winning, and the Graphene that has its source in has extremely good character in absorption, catalysis etc. aspect numerous.Graphene oxide (Graphene oxide) is the direct derivative of Graphene, and Graphene has the character of improvement relatively, such as surface rich abundant hydroxyl and carboxyl functional group, has better water-soluble than Graphene.In addition, (comprise the H-p effect, p-p effect, p except the good p suction-operated that has kept non-oxide Graphene Cation-p effect, cation-p effect, anion-p effect, and non-polar gas-p effect) and catalytic property outside, also easily with hydroxyl, amino, carboxyl isopolarity group formation hydrogen bond, polar molecule is had better characterization of adsorption.Therefore Graphene and graphene oxide have good selective absorption effect to conjugated molecule, base, porphyrin, aldehyde ketone molecule etc.In addition, (B. Huang, Z. Li, Z. Liu, G. Zhou, S. Hao, J.Wu, B. Gu, W. Duan, the J. Phys. Chem. C 2008,112,13443 such as B. Huang.) report Graphene regular hexagon lattice and NH 3The molecular size coupling, the gas molecules such as adsorbable nitrogen oxide.
At present, Graphene and graphene oxide are applied to every field in a plurality of fields, but so far, Graphene and graphene oxide fall burnt field at Harm reduction techniques and there is not yet Patents and bibliographical information, also do not obtain introducing and using.The of new generation two-dimensional nano material of the present invention take Graphene as representative is applied to Harm reduction techniques and falls Jiao and will bring new breakthrough as the cigarette technology.
Summary of the invention
Goal of the invention: for the deficiencies in the prior art, the purpose of this invention is to provide a kind of Graphene fiber cigarette filter and preparation method thereof, the harmful substance that produces in the flue gas during efficient selective absorption cigarette smoking, do not affecting in the cigarette in the aesthetic quality, reducing smoking to the harm of human body.
Technical scheme: in order to realize the foregoing invention purpose, the technical solution used in the present invention is as follows:
A kind of Graphene fiber cigarette filter, described filter tip comprises fiber carrier, is provided with for the Graphene class material that adsorbs the flue gas harmful constituent at described fiber carrier; Described Graphene class dispersion of materials is on described fiber carrier.
Described fiber carrier comprises charcoal fiber, acetate fiber, sepiolite fibre, various organic and inorganic, the macromolecular materials such as animal and plant fiber and molecular sieve, and the preparation feedback condition is not necessarily simply mixed, and also can be other synthetic methods such as hydro-thermal method, solid-phase synthesis, active function groups coupling method.
Described Graphene class material is a kind of or its mixing in Graphene and the graphene oxide.
Described filter tip is binary combined filter tip, and contact pipe tobacco end is close to the fiber carrier section that Graphene class material in load, and the thickness of carrier is 1 ~ 4 mm, then connects common acetate fiber section.
In described every cigarette, the fiber carrier weight of load Graphene class material is 5 ~ 20 mg.
A kind of method for preparing Graphene fiber cigarette filter may further comprise the steps:
1) Graphene class material is evenly spread in the solvent, be made into the Graphene class solution of 0.1 ~ 10 mg/mL;
2) fiber carrier is carried out pre-activation process, remove impurity, assorted gas that carrier itself contains, oven dry;
3) will activate good fiber carrier and be immersed into 10 ~ 60 min in the Graphene class solution, oven dry; The quality of Graphene class material is 0.5 ~ 15% of fiber carrier quality;
4) adopt conventional dual filter preparation method, with load the fiber carrier of above-mentioned Graphene class material add in the filter tip, make composite filter tip;
In the step (1), the solvent of described Graphene class solution is ethanol, water or the mixed liquor of the two.
In the step (1), the mode of described dispersion is ultrasonic dispersion.
In the step (2), described activation process mode is that boiling water boils 25 min.
In the step (3), the submergence mode is first ultrasonic, and rear concussion is left standstill again.
Beneficial effect: compared with prior art, the present invention has following characteristics:
(1) compares with three-dimensional nanometer material with the conventional bulk phase material, Graphene and graphene oxide have p absorption property and the chemical catalysis activity of larger surface atom ratio, uniqueness, carry out modification by interpolation Graphene and graphene oxide in cigarette filter, can greatly improve the adsorption efficiency to harmful substances from flue gases, Graphene class material has good dispersiveness in water or ethanol simultaneously, and be easy to charcoal fiber and acetate fiber carrier compound, difficult drop-off, therefore no matter to environment still to human body, do not produce additional murder by poisoning, environmental protection.
(2) in consumption situation seldom, can reach very high selective absorption efficient, not affect the inherent aesthetic quality of cigarette.Detect by analysis, the present invention has improved the strainability of cigarette filter by add Graphene class material modification in cigarette filter, can significantly reduce the burst size of harmful constituents in cigarette flue gas, benzo in the flue gas [a] pyrene, phenol, HCN, crotonaldehyde and NH 3Content all obviously descend, very little on the fragrant atmosphere material impact in the flue gas simultaneously.After smokeing panel test, the personnel that have a qualification of smokeing panel test through industry confirm that using mineral carbon alkene class material modification cigarette inherent quality does not later have the significant change additive effect obviously to be better than using the cigarette of the method modification filter tips such as metal or oxide.
(3) manufacture craft of filter tip is the existing mature technology of industry, so technique of the present invention is simple, and it is very convenient to operate, with low cost during large-scale production.
The specific embodiment
The present invention is described further below in conjunction with specific embodiment.
Embodiment 1
1) the graphite oxide aqueous solution of preparation 0.2 mg/mL;
2) acetate fiber is placed water boil 25 min and carries out activation process, after be immersed in the graphite oxide aqueous solution that contains acetate fiber quality 1.0% ultrasonic 10 min(80 W), leave standstill 10 min, in 110 ℃ of oven dry;
3) adopt the existing binary mouth rod of industry production method with load the acetate fiber carrier of above-mentioned graphene oxide add in the mouth rod, make composite filter tip, the acetate fiber carrier thickness is 2 mm, and the acetate fiber weight of load graphene oxide is 10 mg in every cigarette.
4) composite filter tip is made cigarette, adopt national standard that the harmful components in the main flume are detected.Analysis result sees Table 1.
Embodiment 2
1) the graphite oxide aqueous solution of preparation 0.5 mg/mL;
2) acetate fiber is placed water boil 25 min and carries out activation process, after be immersed in the graphite oxide aqueous solution that contains acetate fiber quality 2.5% ultrasonic 10 min(80 W), shake 20 min(160 W), leave standstill 10 min, in 110 ℃ of oven dry;
3) adopt the existing binary mouth rod of industry production method with load the acetate fiber carrier of above-mentioned graphene oxide add in the mouth rod, make composite filter tip, the acetate fiber carrier thickness is 1.5 mm, and the acetate fiber weight of load graphene oxide is 8 mg in every cigarette.
4) composite filter tip is made cigarette, adopt national standard that the harmful components in the main flume are detected.Analysis result sees Table 1.
Embodiment 3
1) the Graphene ethanolic solution of preparation 0.2 mg/mL;
2) acetate fiber is placed water boil 25 min and carries out activation process, after be immersed in the Graphene ethanolic solution that contains acetate fiber quality 1.0% ultrasonic 20 min(80 W), shake 20 min(160 W), leave standstill 10 min, in 110 ℃ of oven dry;
3) adopt the existing binary mouth rod of industry production method with load the acetate fiber carrier of above-mentioned Graphene add in the mouth rod, make composite filter tip, the acetate fiber carrier thickness is 2 mm, the acetate fiber weight of load Graphene is 10 mg in every cigarette.
4) composite filter tip is made cigarette, adopt national standard that the harmful components in the main flume are detected.Analysis result sees Table 1.
Embodiment 4
1) the graphite oxide aqueous solution of preparation 0.2 mg/mL;
2) the charcoal fiber is placed water boil 25 min and carries out activation process, after be immersed in the graphite oxide aqueous solution that contains charcoal fiber quality 1.0% ultrasonic 10 min(80 W), shake 20 min(160 W), leave standstill 10 min, in 110 ℃ of oven dry;
3) adopt the existing binary mouth rod of industry production method with load the charcoal fiber carrier of above-mentioned graphene oxide add in the mouth rod, make composite filter tip, charcoal fiber carrier thickness is 2 mm, the charcoal fibre weight of load graphene oxide is 10 mg in every cigarette.
4) composite filter tip is made cigarette, adopt national standard that the harmful components in the main flume are detected.Analysis result sees Table 1.
Embodiment 5
1) the graphite oxide aqueous solution of preparation 0.4 mg/mL and the Graphene ethanolic solution of 0.4 mg/mL, equal-volume mixes the mixed solution that makes graphene oxide and Graphene;
2) the charcoal fiber is placed water boil 25 min and carries out activation process, after be immersed in the admixed graphite alkene solution that contains charcoal fiber quality 2.0% ultrasonic 20 min(80 W), shake 20 min(160 W), leave standstill 10 min, in 110 ℃ of oven dry;
3) adopt the existing binary mouth rod of industry production method with load the NACF carrier of above-mentioned Graphene and graphene oxide add in the mouth rod, make composite filter tip, charcoal fiber carrier thickness is 1.5 mm, and the charcoal fibre weight of load Graphene and graphene oxide is 8 mg in every cigarette.
4) composite filter tip is made cigarette, adopt national standard that the harmful components in the main flume are detected.Analysis result sees Table 1.
Embodiment 6
Adopt national standard, respectively the main flume of being made by the composite filter tip of embodiment 1 ~ 5 in the cigarette is carried out the harmful components detection, the results are shown in Table 1.
Table 1 cigarette smoke harmful components burst size reduces the result
Data can be found out from table, after Graphene and graphene oxide are composite modified, especially the adsorption efficiency of conjugate class, polar micromolecules are obviously improved mainly containing harmful substances.And these conjugate class polar micromolecules are the harmful substances of generally acknowledging, such as " carcinogenic promoting agent " role who plays the part of Carciuogenesis, the viewpoint that has thinks that also they are direct carcinogens.
Above-mentioned example shows that all the cigarette filter based on Graphene and graphene oxide modification can well reduce the harmful substance in the cigarette smoke.The above embodiment of the present invention only is for example of the present invention clearly is described, is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here can't give all embodiments exhaustive.Everyly belong to the row that apparent variation that technical scheme of the present invention extends out or change still are in protection scope of the present invention.

Claims (10)

1. Graphene fiber cigarette filter, it is characterized in that: described filter tip comprises fiber carrier, is provided with Graphene class material for absorption flue gas harmful constituent at described fiber carrier; Described Graphene class dispersion of materials is on described fiber carrier.
2. Graphene fiber cigarette filter according to claim 1, it is characterized in that: described fiber carrier comprises charcoal fiber, acetate fiber, sepiolite fibre, animal and plant fiber and molecular sieve.
3. Graphene fiber cigarette filter according to claim 1, it is characterized in that: described Graphene class material is a kind of or its mixing in Graphene and the graphene oxide.
4. Graphene fiber cigarette filter according to claim 1, it is characterized in that: described filter tip is binary combined filter tip, contact pipe tobacco end is close to the fiber carrier section that Graphene class material in load, and the thickness of carrier is 1 ~ 4 mm, then connects common acetate fiber section.
5. Graphene fiber cigarette filter according to claim 1, it is characterized in that: in described every cigarette, the fiber carrier weight of load Graphene class material is 5 ~ 20 mg.
6. a method for preparing Graphene fiber cigarette filter claimed in claim 1 is characterized in that, may further comprise the steps:
1) Graphene class material is evenly spread in the solvent, be made into the Graphene class solution of 0.1 ~ 10 mg/mL;
2) fiber carrier is carried out pre-activation process, remove impurity, assorted gas that carrier itself contains, oven dry;
3) will activate good fiber carrier and be immersed into 10 ~ 60 min in the Graphene class solution, oven dry; The quality of Graphene class material is 0.5 ~ 15% of fiber carrier quality;
4) adopt conventional dual filter preparation method, with load the fiber carrier of above-mentioned Graphene class material add in the filter tip, make composite filter tip.
7. the method for preparing Graphene fiber cigarette filter according to claim 6 is characterized in that, in the step (1), the solvent of described Graphene class solution is ethanol, water or the mixed liquor of the two.
8. the method for preparing Graphene fiber cigarette filter according to claim 6 is characterized in that, in the step (1), the mode of described dispersion is ultrasonic dispersion.
9. the method for preparing Graphene fiber cigarette filter according to claim 6 is characterized in that, in the step (2), described activation process mode is that boiling water boils 25 min.
10. the method for preparing Graphene fiber cigarette filter according to claim 6 is characterized in that, in the step (3), the submergence mode is first ultrasonic, and rear concussion is left standstill again.
CN2013100015888A 2013-01-04 2013-01-04 Grapheme type fiber cigarette filter and preparation method thereof Pending CN103005712A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013100015888A CN103005712A (en) 2013-01-04 2013-01-04 Grapheme type fiber cigarette filter and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013100015888A CN103005712A (en) 2013-01-04 2013-01-04 Grapheme type fiber cigarette filter and preparation method thereof

Publications (1)

Publication Number Publication Date
CN103005712A true CN103005712A (en) 2013-04-03

Family

ID=47955232

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2013100015888A Pending CN103005712A (en) 2013-01-04 2013-01-04 Grapheme type fiber cigarette filter and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103005712A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104055219A (en) * 2014-06-19 2014-09-24 川渝中烟工业有限责任公司 Tobacco shred additive as well as preparation method and application thereof in cigarette production
CN104389234A (en) * 2014-09-12 2015-03-04 河南中烟工业有限责任公司 Cigarette filter tip added with chitosan-graphene oxide composite material
CN104432505A (en) * 2014-12-15 2015-03-25 湖南中烟工业有限责任公司 Cigarette filter tip reducing carbonyl compounds in cigarette mainstream smoke and manufacture method thereof
CN104489922A (en) * 2014-12-11 2015-04-08 上海烟草集团有限责任公司 Preparation and application of graphene oxide-bonded silica gel composite
CN104522885A (en) * 2014-12-18 2015-04-22 湖北中烟工业有限责任公司 Adsorbing agent capable of reducing phenol release amount in mainstream cigarette smoke and preparation method and application thereof
CN104525126A (en) * 2014-12-18 2015-04-22 湖北中烟工业有限责任公司 Bio-polyamines-modified graphene adsorption material as well as preparation method and application thereof
CN104549163A (en) * 2014-12-18 2015-04-29 湖北中烟工业有限责任公司 Spermine modified graphene adsorbing material, and preparation method and application thereof
CN105029694A (en) * 2015-08-11 2015-11-11 广西中烟工业有限责任公司 Harm-reducing type ternary composite filter rod containing graphene oxide particles
CN105054291A (en) * 2015-08-09 2015-11-18 王干 Graphene composite cigarette filter tip and cigarette with same
CN105054293A (en) * 2015-08-09 2015-11-18 王干 Novel graphene composite cigarette filter tip
CN105233794A (en) * 2015-10-26 2016-01-13 合肥工业大学 Preparation method for prussian blue/graphene/carbon fiber composite material
CN105361241A (en) * 2015-11-20 2016-03-02 东南大学 Cigarette binary composite filter tip filled with graphene oxide and preparation method of cigarette binary composite filter tip
CN106000316A (en) * 2015-12-31 2016-10-12 济南圣泉集团股份有限公司 Graphene adsorption material, preparation method and application thereof and cigarette filter
WO2017024933A1 (en) * 2015-08-09 2017-02-16 济南圣泉集团股份有限公司 Graphene adsorbing material, preparation method therefor and application thereof, and cigarette filter tip and cigarette
WO2017124992A1 (en) * 2016-01-18 2017-07-27 张麟德 Cigarette smoke filter device and tobacco product
CN107537439A (en) * 2016-07-25 2018-01-05 济南圣泉集团股份有限公司 A kind of graphene sorbing material, its preparation method and its application and cigarette filter
CN107895653A (en) * 2017-10-27 2018-04-10 西安理工大学 Method that microwave prepares cigarette filter/graphene composite material and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060151382A1 (en) * 2005-01-12 2006-07-13 Petrik Viktor I Contact devices with nanostructured materials
CN101711603A (en) * 2009-11-13 2010-05-26 湖南中烟工业有限责任公司 Composite filter tip of cigarette and preparation process thereof
WO2012047346A1 (en) * 2010-10-06 2012-04-12 Celanese Acetate Llc Smoke filters for smoking devices with porous masses having active nanoparticles and binder particles
WO2012051548A2 (en) * 2010-10-15 2012-04-19 Celanese Acetate Llc Apparatuses, systems, and associated methods for forming porous masses for smoke filter
WO2012054111A1 (en) * 2010-10-06 2012-04-26 Celanese Acetate Llc Smoke filters for smoking devices with porous masses having a carbon particle loading and an encapsulated pressure drop
CN102499479A (en) * 2011-11-03 2012-06-20 湖南中烟工业有限责任公司 Complex adsorbent capable of reducing release amount of heavy metals in mainstream smoke of cigarettes, preparation method for complex adsorbent and application of complex adsorbent
CN102732027A (en) * 2012-05-29 2012-10-17 东南大学 Preparation method for graphene oxide-polyethyleneimine composite

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060151382A1 (en) * 2005-01-12 2006-07-13 Petrik Viktor I Contact devices with nanostructured materials
CN101711603A (en) * 2009-11-13 2010-05-26 湖南中烟工业有限责任公司 Composite filter tip of cigarette and preparation process thereof
WO2012047346A1 (en) * 2010-10-06 2012-04-12 Celanese Acetate Llc Smoke filters for smoking devices with porous masses having active nanoparticles and binder particles
WO2012054111A1 (en) * 2010-10-06 2012-04-26 Celanese Acetate Llc Smoke filters for smoking devices with porous masses having a carbon particle loading and an encapsulated pressure drop
WO2012051548A2 (en) * 2010-10-15 2012-04-19 Celanese Acetate Llc Apparatuses, systems, and associated methods for forming porous masses for smoke filter
CN102499479A (en) * 2011-11-03 2012-06-20 湖南中烟工业有限责任公司 Complex adsorbent capable of reducing release amount of heavy metals in mainstream smoke of cigarettes, preparation method for complex adsorbent and application of complex adsorbent
CN102732027A (en) * 2012-05-29 2012-10-17 东南大学 Preparation method for graphene oxide-polyethyleneimine composite

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104055219B (en) * 2014-06-19 2016-02-03 川渝中烟工业有限责任公司 The preparation method of tobacco shred additive and the application for the production of cigarette
CN104055219A (en) * 2014-06-19 2014-09-24 川渝中烟工业有限责任公司 Tobacco shred additive as well as preparation method and application thereof in cigarette production
CN104389234B (en) * 2014-09-12 2017-02-15 河南中烟工业有限责任公司 Cigarette filter tip added with chitosan-graphene oxide composite material
CN104389234A (en) * 2014-09-12 2015-03-04 河南中烟工业有限责任公司 Cigarette filter tip added with chitosan-graphene oxide composite material
CN104489922B (en) * 2014-12-11 2017-09-26 上海烟草集团有限责任公司 A kind of preparation and application of graphene oxide bonded silica gel composite
CN104489922A (en) * 2014-12-11 2015-04-08 上海烟草集团有限责任公司 Preparation and application of graphene oxide-bonded silica gel composite
CN104432505A (en) * 2014-12-15 2015-03-25 湖南中烟工业有限责任公司 Cigarette filter tip reducing carbonyl compounds in cigarette mainstream smoke and manufacture method thereof
CN104522885A (en) * 2014-12-18 2015-04-22 湖北中烟工业有限责任公司 Adsorbing agent capable of reducing phenol release amount in mainstream cigarette smoke and preparation method and application thereof
CN104525126A (en) * 2014-12-18 2015-04-22 湖北中烟工业有限责任公司 Bio-polyamines-modified graphene adsorption material as well as preparation method and application thereof
CN104549163A (en) * 2014-12-18 2015-04-29 湖北中烟工业有限责任公司 Spermine modified graphene adsorbing material, and preparation method and application thereof
CN104525126B (en) * 2014-12-18 2017-12-05 湖北中烟工业有限责任公司 Biopolyamines modified graphite alkenes sorbing material and its preparation method and application
EP3332868A4 (en) * 2015-08-09 2019-01-02 Jinan Shengquan Group Share Holding Co., Ltd Graphene adsorbing material, preparation method therefor and application thereof, and cigarette filter tip and cigarette
US20180228209A1 (en) * 2015-08-09 2018-08-16 Jinan Shengquan Group Share Holding Co., Ltd. Graphene adsorbing material, preparation method therefor and application thereof, and cigarette filter tip and cigarette
KR20180044311A (en) * 2015-08-09 2018-05-02 지난 셩취엔 그룹 쉐어 홀딩 코., 엘티디. Graphene sorbent, its preparation methods and uses, and cigarette filter tips and cigarettes
CN105054293A (en) * 2015-08-09 2015-11-18 王干 Novel graphene composite cigarette filter tip
KR102177137B1 (en) * 2015-08-09 2020-11-11 지난 셩취엔 그룹 쉐어 홀딩 코., 엘티디. Graphene adsorbent, its manufacturing method and use, and cigarette filter tips and tobacco
CN105054291A (en) * 2015-08-09 2015-11-18 王干 Graphene composite cigarette filter tip and cigarette with same
WO2017024933A1 (en) * 2015-08-09 2017-02-16 济南圣泉集团股份有限公司 Graphene adsorbing material, preparation method therefor and application thereof, and cigarette filter tip and cigarette
US11006664B2 (en) * 2015-08-09 2021-05-18 Jinan Shengquan Group Share Holding Co., Ltd. Graphene adsorbing material, preparation method therefor and application thereof, and cigarette filter tip and cigarette
CN105029694A (en) * 2015-08-11 2015-11-11 广西中烟工业有限责任公司 Harm-reducing type ternary composite filter rod containing graphene oxide particles
CN105233794B (en) * 2015-10-26 2017-11-07 合肥工业大学 A kind of preparation method of Prussian blue/graphene/carbon fiber composite
CN105233794A (en) * 2015-10-26 2016-01-13 合肥工业大学 Preparation method for prussian blue/graphene/carbon fiber composite material
CN105361241B (en) * 2015-11-20 2019-07-12 东南大学 A kind of cigarette binary combined filter tip and preparation method thereof filled with graphene oxide
CN105361241A (en) * 2015-11-20 2016-03-02 东南大学 Cigarette binary composite filter tip filled with graphene oxide and preparation method of cigarette binary composite filter tip
CN106000316B (en) * 2015-12-31 2019-09-10 济南圣泉集团股份有限公司 A kind of graphene adsorbent material, preparation method and its application and cigarette filter
CN106000316A (en) * 2015-12-31 2016-10-12 济南圣泉集团股份有限公司 Graphene adsorption material, preparation method and application thereof and cigarette filter
WO2017124992A1 (en) * 2016-01-18 2017-07-27 张麟德 Cigarette smoke filter device and tobacco product
CN107537439B (en) * 2016-07-25 2019-11-22 济南圣泉集团股份有限公司 A kind of graphene adsorbent material, preparation method and its application and cigarette filter
CN107537439A (en) * 2016-07-25 2018-01-05 济南圣泉集团股份有限公司 A kind of graphene sorbing material, its preparation method and its application and cigarette filter
CN107895653A (en) * 2017-10-27 2018-04-10 西安理工大学 Method that microwave prepares cigarette filter/graphene composite material and application thereof

Similar Documents

Publication Publication Date Title
CN103005712A (en) Grapheme type fiber cigarette filter and preparation method thereof
CN104815630A (en) Preparation method of filter tip fibers for selectively adsorbing benzopyrene and phenol
CN104389234A (en) Cigarette filter tip added with chitosan-graphene oxide composite material
KR102177137B1 (en) Graphene adsorbent, its manufacturing method and use, and cigarette filter tips and tobacco
CN102100405B (en) Alkaloid composite filter tip addition material capable of reducing hydrocyanic acid in cigarette mainstream smoke
CN105597675A (en) Graphene adsorbing material, preparation method and application thereof and cigarette filter tip
CN102697182B (en) Preparation method of filter nozzle additive for lowering ammonia in smoke of cigarette and application thereof
CN1265744C (en) Method for producing diacetate fiber tows of chitosan modified cigarette
CN103141940B (en) Entrapment agent for selectively lowering crotonaldehyde content in cigarette smoke and filter stick
CN102920022A (en) Preparation method of additive for reducing content of ammonia in mainstream smoke of cigarette and application of preparation method
CN101385574B (en) Composite environment protection cigarettes tar absorbent
CN104525126A (en) Bio-polyamines-modified graphene adsorption material as well as preparation method and application thereof
CN101992058B (en) Mesoporous copper oxide-aluminum oxide adsorbing agent for reducing hydrogen cyanide content in main stream smoke of cigarette, and preparation and application
CN102813279B (en) Method for efficiently reducing specific nitrosamines in cigarette smoke
CN102002888B (en) Cellulose paper capable of reducing benzo(a)pyrene content of smoke of cigarettes, preparation method thereof and use thereof
CN103611505A (en) Preparation method, product and application of copper ion functionalized porous cellulose composite microsphere
CN107628619A (en) A kind of preparation method of the rich nitrogen active sludge carbon of adulterated food leftover bits and pieces
CN106820261A (en) A kind of filter tip for selecting to adsorb BaP and phenol in cigarette smoke
CN102771894A (en) Thread added cigarette holder capable of reducing harmfulness of cigarettes
CN101949106B (en) Cellulose paper for reducing formonitrile content of cigarette smoke, preparation method and application thereof
CN107594616A (en) Adsorbing composition, its preparation method and application
CN102499481A (en) Adsorbent capable of reducing content of hydrocyanic acid in mainstream smoke of cigarette as well as preparation and application of absorbent
CN103070477B (en) Application of aminopropanol compound
CN102551206A (en) Cigarette filter containing layered double hydroxide and capable of reducing harmful ingredient emission in cigarette mainstream smoke
CN203597391U (en) Composite filter tip with copper ion functionalization porous cellulose composite microsphere

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20130403