CN102493126A - 一种含纳米银的复合纤维材料及其制备方法 - Google Patents
一种含纳米银的复合纤维材料及其制备方法 Download PDFInfo
- Publication number
- CN102493126A CN102493126A CN2011103449127A CN201110344912A CN102493126A CN 102493126 A CN102493126 A CN 102493126A CN 2011103449127 A CN2011103449127 A CN 2011103449127A CN 201110344912 A CN201110344912 A CN 201110344912A CN 102493126 A CN102493126 A CN 102493126A
- Authority
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- China
- Prior art keywords
- electrostatic spinning
- dissolved
- acetone
- carrene
- nano silver
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- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000002657 fibrous material Substances 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title claims abstract description 9
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 18
- SQGYOTSLMSWVJD-UHFFFAOYSA-N Silver nitrate Chemical compound 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[Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000243 solution Substances 0.000 claims abstract description 12
- 229920000620 organic polymer Polymers 0.000 claims abstract description 10
- 239000012528 membrane Substances 0.000 claims abstract description 9
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- FOIXSVOLVBLSDH-UHFFFAOYSA-N silver ion Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 4
- 239000011259 mixed solution Substances 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
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- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound 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CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 22
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound 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[Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 22
- 229910052709 silver Inorganic materials 0.000 claims description 22
- 239000004332 silver Substances 0.000 claims description 22
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethylsulphoxide Chemical compound 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CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound 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- 231100000331 toxic Toxicity 0.000 description 1
Abstract
本发明公开了一种含纳米银的复合纤维材料及其制备方法，先将硝酸银分散在有机溶剂或有机溶剂与水的混合溶液中配制静电纺丝溶液，在将配制静电纺丝溶液在现有静电丝纺设备上收集纤维膜；然后，将收集纤维膜置于紫外灯下照射5-10小时；最后，在真空状态下室温干燥1-3天，去除残留溶剂，并以4度保存，形成包含纳米银的复合纤维膜；本发明利用静电纺丝技术生产复合纤维膜材料，将具有广谱抗菌的银离子与具有良好生物相容性的有机高分子混合后进行静电纺丝，纤维膜制备后利用紫外光照射，银离子原位生产纳米银，所制得复合纤维材料，制备工艺简单，成本低；并且使纤维膜具有广谱、强效抗菌性能。
Description
一种含纳米银的复合纤维材料及其制备方法技术领域：[0001] 本发明涉及复合纤维材料及其制备方法，尤其涉及一种有广谱抗菌功效的含纳米银的复合纤维材料及其制备方法。背景技术：[0002] 静电纺丝是一种利用高压静电来制备直径几纳米到几微米纤维的技术。通过静电纺丝技术制备纳米纤维材料是近十几年来世界材料科学技术领域的研究热点之一。静电纺丝以其制造装置简单、纺丝成本低廉、可纺物质种类繁多、工艺可控等优点，已成为有效制备纳米纤维材料的主要途径。静电纺丝纤维具有很多独特性能，如小直径，高孔隙率，优良的孔互连和高表面体积比。这些特性可以改善材料性能。同时通过添加小的不溶性微粒或水溶性药物到聚合物溶液和封装在纳米纤维可以制备出功能化纤维膜。[0003] 众所周知，银是一种有效的抗菌剂。纳米银，是利用前沿纳米技术将银纳米化，银在纳米状态下的杀菌能力产生了质的飞跃，极少的纳米银可产生强大的杀菌作用，纳米银颗粒直接进入菌体与氧代谢酶（-SH)结合，使菌体窒息而死的独特作用机制，可杀死与其接触的大多数细菌、真菌、霉菌、孢子等微生物。据研究统计，少量纳米银可在数分钟内杀死 650多种细菌，广谱杀菌且无任何的耐药性，能够促进伤口的愈合、细胞的生长及受损细胞的修复，无任何毒性反应，对皮肤也未发现任何刺激反应，所以纳米银被誉为是最新一代的天然抗菌剂。[0004] 所以，通过静电纺丝技术，制备一类含有纳米银的抗菌纤维膜，使其在具有良好的生物相容性，机械性能，加工性能的同时，同时具有强效抗菌作用，可以用作敷料或应用于组织工程。这类抗菌纤维膜一定具有广阔的应用前景。发明内容：[0005] 本发明针对现有技术的不足，提供了一种有广谱抗菌功效的含纳米银的复合纤维材料及其制备方法。[0006] 一种含纳米银的复合纤维材料，其特征在于：将具有广谱抗菌的银离子与具有良好生物相容性的有机高分子混合后进行静电纺丝织成纤维膜，纤维膜制备后利用紫外光照射，银离子原位生产纳米银。所制得复合纤维材料，制备工艺简单，成本低。[0007] 所述的有机高分子为：重均分子量为5〜30万，选自聚乳酸-羟基乙酸共聚物 (PLGA)、聚环氧乙烷（PEO)、聚乙烯醇（PVA)、聚乳酸（PLA)以及聚己内酯（PCL)。[0008] 一种含纳米银的复合纤维材料制备方法，步骤如下：[0009] (1)配制静电纺丝溶液：将硝酸银分散在有机溶剂或有机溶剂与水的混合溶液中，超声2小时；有机高分子室温溶解于上述溶液中，浓度为30-50% W/V，搅拌过夜后备用。[0010] (2)制备包含纳米银的复合纤维膜：有机高分子与硝酸银混合液装于5毫升注射器，使用5号不锈钢枕头，直径l_3mm，针头距离纤维收集板15-30厘米，溶液流速 0. 8-1. 2mL/h，外加电压20-30千伏，在现有静电丝纺设备上静电纺丝收集纤维膜；然后，将收集纤维膜置于紫外灯下照射5-10小时；最后，在真空状态下室温干燥1-3天，去除残留溶剂，并以4度保存。[0011] 所述的有机溶剂为：聚乳酸-羟基乙酸共聚物（PLGA)溶于丙酮或二氯甲烷或丙酮与二甲基甲酰胺（DMF)的混合液，聚环氧乙烷（PEO)溶于二甲基亚砜（DMSO)或二氯甲烷与丙酮的混合液，聚乙烯醇（PVA)溶于二氯甲烷或二甲基亚砜（DMSO)，聚乳酸（PLA)溶于二氯甲烷，以及聚己内酯（PCL)溶于丙酮或二甲基亚砜（DMSO)或二氯甲烷与丙酮的混合液。[0012] 本发明利用静电纺丝技术生产复合纤维膜材料，将具有广谱抗菌的银离子与具有良好生物相容性的有机高分子混合后进行静电纺丝，纤维膜制备后利用紫外光照射，银离子原位生产纳米银，所制得复合纤维材料，制备工艺简单，成本低；并且使纤维膜具有广谱、 强效抗菌性能，可用作敷料或应用于组织工程，具有广阔的应用前景。具体实施方式：[0013] 为了加深对本发明的理解，下面结合实施例对本发明作进一步详述。[0014] 按照如下方法制备一种含纳米银的复合纤维材料制备方法，步骤如下：[0015] (1)配制静电纺丝溶液：将硝酸银分散在丙酮与二甲基甲酰胺（DMF)I ： 1的混合溶液中，超声2小时，聚乳酸-羟基乙酸共聚物（PLGA)室温溶解于上述溶液中，浓度为50% (W/V)，搅拌过夜后备用。[0016] (2)制备包含纳米银的复合纤维膜：聚乳酸-羟基乙酸共聚物（PLGA)与硝酸银混合液装于5毫升注射器，使用5号不锈钢枕头，直径3mm，针头距离纤维收集板20厘米，溶液流速1. OmL/h，外加电压20千伏，在现有静电丝纺设备上收集纤维膜；然后，将收集纤维膜置于紫外灯下照射6小时；最后，在真空状态下室温干燥2天，去除残留溶剂，并以4度保存。
Claims (4)
1. 一种含纳米银的复合纤维材料，其特征在于：将银离子与有机高分子混合后进行静电纺丝织成纤维膜。
2.根据权利要求1所述的一种含纳米银的复合纤维材料，其特征在于：所述的有机高分子为：重均分子量为5〜30万，选自聚乳酸-羟基乙酸共聚物、聚环氧乙烷、聚乙烯醇、聚乳酸以及聚己内酯。
3. 一种含纳米银的复合纤维材料制备方法，其特征在于：步骤如下：(1)配制静电纺丝溶液：将硝酸银分散在有机溶剂或有机溶剂与水的混合溶液中，超声2小时；有机高分子溶解于上述溶液中，浓度为30-50% W/V，搅拌过夜后备用。(2)制备包含纳米银的复合纤维膜：有机高分子与硝酸银混合液装于5毫升注射器，使用5号不锈钢枕头，直径l_3mm，针头距离纤维收集板15-30厘米，溶液流速0. 8-1. 2mL/h, 外加电压20-30千伏，在现有静电丝纺设备上静电纺丝收集纤维膜；然后，将收集纤维膜置于紫外灯下照射5-10小时；最后，在真空状态下室温干燥1-3天，去除残留溶剂，并以4度保存。
4.根据权利要求1所述的一种含纳米银的复合纤维材料制备方法，其特征在于：所述的有机溶剂为：聚乳酸-羟基乙酸共聚物溶于丙酮或二氯甲烷或丙酮与二甲基甲酰胺的混合液，聚环氧乙烷溶于二甲基亚砜或二氯甲烷与丙酮的混合液，聚乙烯醇溶于二氯甲烷或二甲基亚砜，聚乳酸溶于二氯甲烷，以及聚己内酯溶于丙酮或二甲基亚砜或二氯甲烷与丙酮的混合液。
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