CN102492277A - 一种聚碳酸酯复合材料及其制备方法 - Google Patents
一种聚碳酸酯复合材料及其制备方法 Download PDFInfo
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- CN102492277A CN102492277A CN2011103895895A CN201110389589A CN102492277A CN 102492277 A CN102492277 A CN 102492277A CN 2011103895895 A CN2011103895895 A CN 2011103895895A CN 201110389589 A CN201110389589 A CN 201110389589A CN 102492277 A CN102492277 A CN 102492277A
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- 239000004417 polycarbonate Substances 0.000 title claims abstract description 50
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 23
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 230000007062 hydrolysis Effects 0.000 claims abstract description 26
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 238000012545 processing Methods 0.000 claims abstract description 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 3
- 239000003112 inhibitor Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 13
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 12
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 8
- 238000005453 pelletization Methods 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 125000003700 epoxy group Chemical group 0.000 claims description 5
- -1 ethylamino- Chemical group 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical group CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 4
- 229930185605 Bisphenol Natural products 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 150000002118 epoxides Chemical class 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Chemical group 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000012467 final product Substances 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 125000004185 ester group Chemical group 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B29C47/92—
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 对比例1 | |
PC树脂 | 98.8 | 99.1 | 99.22 | 98.8 |
白矿油 | 0.2 | 0.1 | 0.1 | 0.2 |
AH210 | 0.1 | 0.05 | 0.08 | 0 |
1076 | 0.3 | 0.1 | 0.2 | 0.3 |
168 | 0.2 | 0.1 | 0.2 | 0.2 |
EBS | 0.4 | 0.5 | 0.2 | 0.5 |
拉伸强度/Mpa | ||||
正常、不处理 | 59.8 | 60.4 | 62.1 | 61.2 |
70℃/95%/120H | 56.4 | 51.3 | 54.3 | 41.1 |
水煮/72H | 55.1 | 52.7 | 55.1 | 40.5 |
断裂伸长率/% | ||||
正常、不处理 | 103.5 | 100.8 | 122.4 | 110.6 |
70℃/95%/120H | 98.4 | 87.1 | 108.5 | 75.2 |
水煮/72H | 86.5 | 89.4 | 110.8 | 76.8 |
弯曲强度/Mpa | ||||
正常、不处理 | 93.7 | 96 | 94.7 | 95.4 |
70℃/95%/120H | 94.2 | 81.6 | 82.1 | 56.9 |
水煮/72H | 89.6 | 83.2 | 80.8 | 60.7 |
弯曲模量/Mpa | ||||
正常、不处理 | 2491 | 2456 | 2513.5 | 2471.3 |
70℃/95%/120H | 2601.3 | 2088 | 2264 | 1650.2 |
水煮/72H | 2511.1 | 2140 | 2304.2 | 1512.6 |
冲击强度J/m | ||||
正常、不处理 | 681.6 | 659 | 726.3 | 751.8 |
70℃/95%/120H | 630.5 | 560 | 653.4 | 398 |
水煮/72H | 621.4 | 553.2 | 642.5 | 216 |
透光度/% | 87.1 | 87.4 | 87.5 | 88.2 |
热变形温度/℃ | 126.5 | 126.3 | 127.6 | 127 |
Claims (8)
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CN2011103895895A CN102492277B (zh) | 2011-11-30 | 2011-11-30 | 一种聚碳酸酯复合材料及其制备方法 |
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CN102492277A true CN102492277A (zh) | 2012-06-13 |
CN102492277B CN102492277B (zh) | 2013-10-23 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106317835A (zh) * | 2016-09-30 | 2017-01-11 | 福建华塑新材料有限公司 | 一种耐水解聚碳酸酯复合材料及其制备方法 |
CN108017894A (zh) * | 2017-11-29 | 2018-05-11 | 合肥圆融新材料有限公司 | 一种耐高低温耐水解的pc合金及其制备方法 |
CN108431131A (zh) * | 2015-12-22 | 2018-08-21 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
CN108713044A (zh) * | 2016-03-09 | 2018-10-26 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
CN108884306A (zh) * | 2016-03-09 | 2018-11-23 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
US10538620B2 (en) | 2016-08-31 | 2020-01-21 | Lg Chem, Ltd. | Method for preparing polycarbonate |
CN112980171A (zh) * | 2021-02-24 | 2021-06-18 | 广东锦湖日丽高分子材料有限公司 | 一种耐食用油高抗冲耐热聚碳酸酯材料及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101885907A (zh) * | 2010-07-09 | 2010-11-17 | 深圳市科聚新材料有限公司 | 一种led灯遮光板用聚碳酸酯改性材料及其制备方法 |
-
2011
- 2011-11-30 CN CN2011103895895A patent/CN102492277B/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101885907A (zh) * | 2010-07-09 | 2010-11-17 | 深圳市科聚新材料有限公司 | 一种led灯遮光板用聚碳酸酯改性材料及其制备方法 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108431131A (zh) * | 2015-12-22 | 2018-08-21 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
CN108431131B (zh) * | 2015-12-22 | 2021-06-01 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
CN108713044A (zh) * | 2016-03-09 | 2018-10-26 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
CN108884306A (zh) * | 2016-03-09 | 2018-11-23 | 出光兴产株式会社 | 聚碳酸酯系树脂组合物及其成形品 |
US11161977B2 (en) | 2016-03-09 | 2021-11-02 | Idemitsu Kosan Co., Ltd. | Polycarbonate-based resin composition and molded product thereof |
US10538620B2 (en) | 2016-08-31 | 2020-01-21 | Lg Chem, Ltd. | Method for preparing polycarbonate |
CN106317835A (zh) * | 2016-09-30 | 2017-01-11 | 福建华塑新材料有限公司 | 一种耐水解聚碳酸酯复合材料及其制备方法 |
CN108017894A (zh) * | 2017-11-29 | 2018-05-11 | 合肥圆融新材料有限公司 | 一种耐高低温耐水解的pc合金及其制备方法 |
CN112980171A (zh) * | 2021-02-24 | 2021-06-18 | 广东锦湖日丽高分子材料有限公司 | 一种耐食用油高抗冲耐热聚碳酸酯材料及其制备方法 |
CN112980171B (zh) * | 2021-02-24 | 2022-05-06 | 广东锦湖日丽高分子材料有限公司 | 一种耐食用油高抗冲耐热聚碳酸酯材料及其制备方法 |
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Effective date of registration: 20150908 Address after: Baoan District Fuyong street Shenzhen city Guangdong province 518000 two office building four floor B room left Radford (Office) Patentee after: Shenzhen city Uniross long Technology Co. Ltd. Address before: 518000 Guangdong, Baoan District, Fuyong Town, Fu Qiao Industrial Zone, the three phase of the two phase A19 building Patentee before: Shenzhen Keju New Material Co., Ltd. |
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