CN102491492A - Multi-operation-mode ozonation reaction device - Google Patents
Multi-operation-mode ozonation reaction device Download PDFInfo
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- CN102491492A CN102491492A CN2011104180796A CN201110418079A CN102491492A CN 102491492 A CN102491492 A CN 102491492A CN 2011104180796 A CN2011104180796 A CN 2011104180796A CN 201110418079 A CN201110418079 A CN 201110418079A CN 102491492 A CN102491492 A CN 102491492A
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- ozone
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- ozonization
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- saturex
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Abstract
The invention relates to a multi-operation-mode ozonation reaction device, which relates to an ozonation reaction device. The invention aims to solve the problem that the conventional sequencing batch ozonation reaction system and the semi-continuous ozonation reaction system, which cannot carry out sequencing batch experiment and semi-continuous experiment at the same time, are inconvenient for researches. According to the multi-operation-mode ozonation reaction device, the output opening of an oxygen cylinder is communicated with an input opening of an ozone generator; the output opening of the ozone generator is communicated with the input opening of an ozone saturating device through a rubber tube; the input opening of each ozonation reactor is communicated with the output opening of the ozone generator through a rubber tube; the output opening of each ozonation reactor is communicated with the input opening of an ozone absorber through a rubber tube; the output opening of the ozone saturating device is communicated with the input opening of the ozone absorber through a rubber tube; and each ozonation reactor is communicated with the ozone saturating device through a rubber tube. The multi-operation-mode ozonation reaction device is used for performing ozonation reaction experiments.
Description
Technical field
The present invention relates to a kind of ozonization device, be specifically related to a kind of ozonization device of multi-operating condition.
Background technology
Generally there are sequencing batch type ozone reaction system and semi continuous ozone reaction system in the ozone reaction system.Sequencing batch type ozone reaction system is promptly according to required ozone concn; With saturated ozone water with contain the organism water sample and put in the ozone reactor in proportion; Utilize magnetic stirring apparatus to make thorough mixing such as ozone, organic pollutant, water in the system; Through to the sampling under different time, the differential responses condition, study under different condition residual ozone concentration, hydroxyl free content, R in the system
CtIndexs such as value, organic constituents situation, concentration of hydrogen peroxide, thus ozone studied to organic effect situation, the amount of its reactant is easy to control, and parameter is easy to confirm in the reaction process, generally is used for the research to reaction mechanism.Semi continuous ozone reaction system aerogenesis principle is all identical with sequencing batch type ozone reaction system with process, sampling mode, test sample index; Be that this system continues to feed a certain amount of ozone in the ozone reaction device that contains the organism water sample is housed; Therefore the ozone amount that consumes in the reaction system is difficult for confirming; Need carry out the balance of ozone through ozone reactor and tail gas collecting device in each test; But therefore ozone be more suitable for being applied to the checking of production experiment more near the practical situation in the water factory in this system.But the equipment of these two kinds traditional ozone reaction systems is different with flow process, makes troubles to the research of carrying out two kinds of reactive systems simultaneously.
Summary of the invention
The present invention can not carry out sequencing batch type simultaneously with semi continuous ozone reaction system and tests and semicontinuous experiment for solving existing sequencing batch type ozone reaction system, the problem of making troubles to research, and then a kind of ozonization device of multi-operating condition is proposed.
The present invention addresses the above problem the technical scheme of taking to be: the present invention includes oxygen cylinder, ozonizer, ozone saturex, ozone resorber, magnetic stirring apparatus, two ozonization devices, two magnetic force rotors, two balloons and Duo Gen sebific duct; The delivery port of said oxygen cylinder is communicated with the input aperture of ozonizer; The delivery port of said ozonizer is communicated with the input aperture of ozone saturex through sebific duct; The input aperture of each ozonization device respectively is communicated with the delivery port of ozonizer through a sebific duct respectively; Two ozonization devices are set in parallel on the magnetic stirring apparatus side by side; Respectively place a magnetic force rotor in each ozonization device respectively; The delivery port of each ozonization device is communicated with the input aperture of ozone resorber through a sebific duct respectively, and the delivery port of said ozone saturex is communicated with the input aperture of ozone resorber through sebific duct, and each ozonization device respectively is connected with a balloon through a sebific duct respectively; Each ozonization device respectively is communicated with the ozone saturex through a sebific duct respectively, and two ozonization devices are communicated with through sebific duct.
The invention has the beneficial effects as follows: the present invention can carry out sequencing batch type experiment and semi continuous experiment; Can also carry out bilateral formula air inlet, one-sided formula air inlet and the air inlet of recycling formula; The present invention can also only carry out ozonize or catalytic ozonation; Also can carry out two kinds of oxidations simultaneously, also can make former water carry out independent ozonize, carry out catalytic ozonation again.The present invention has realized integral moduleization, and the cycle in work-ing life is long, has reduced the consumptive material loss, has practiced thrift experimental cost, and has realized multiple novel operation scheme, for experiment provides convenience.
Description of drawings
Fig. 1 is an operational system synoptic diagram of the present invention.
Embodiment
Embodiment one: combine Fig. 1 that this embodiment is described; The ozonization device of the said a kind of multi-operating condition of this embodiment comprises oxygen cylinder 1, ozonizer 2, ozone saturex 3, ozone resorber 4, magnetic stirring apparatus 5, two ozonization devices 6, two magnetic force rotors 7, two balloons 8 and Duo Gen sebific ducts 9; The delivery port of said oxygen cylinder 1 is communicated with the input aperture of ozonizer 2; The delivery port of said ozonizer 2 is communicated with the input aperture of ozone saturex 3 through sebific duct 9; The input aperture of each ozonization device 6 respectively is communicated with the delivery port of ozonizer 2 through a sebific duct 9 respectively; Two ozonization devices 6 are set in parallel on the magnetic stirring apparatus 5 side by side; Respectively place a magnetic force rotor 7 in each ozonization device 6 respectively; The delivery port of each ozonization device 6 is communicated with the input aperture of ozone resorber 4 through a sebific duct 9 respectively, and the delivery port of said ozone saturex 3 is communicated with the input aperture of ozone resorber 4 through sebific duct 9, and each ozonization device 6 respectively is connected with a balloon 8 through a sebific duct 9 respectively; Each ozonization device 6 respectively is communicated with ozone saturex 3 through a sebific duct 9 respectively, and two ozonization devices 6 are communicated with through sebific duct 9.
Embodiment two: combine Fig. 1 that this embodiment is described, the every sebific duct 9 of the ozonization device of the said a kind of multi-operating condition of this embodiment all is sebific ducts 9 of being made by corrosion resistant material, and every sebific duct 9 is provided with clip.Other composition and annexation are identical with embodiment one.
Embodiment three: combine Fig. 1 that this embodiment is described, respectively be fitted with five water shoots 10 respectively on two sidewalls of the ozone saturex 3 of the ozonization device of the said a kind of multi-operating condition of this embodiment.Other composition and annexation are identical with embodiment one or two.
Principle of work
Utilize the present invention to carry out sequencing batch type experiment: before the experiment, in the ozonization device 6 of ozonization is carried out in selections, to add magnetic force rotor 7, clamp the flexible pipe 9 of two ozonization devices 6 of connection; In the ozone saturex 3 that the Milli-Q ultrapure water only is housed, feed a certain amount of ozone; Feed ozone after half a hour, ozone water reaches capacity, and in the ozonization device 6 of selective reaction, adds former water and catalyzer; Close two ozonization devices 6; Ventilate in balloon 8 through plastic injector, sealing balloon 8 in ventilation back injects saturated ozone water through ozone saturex 3 to the ozonization device 6 of selective reaction fast; After for some time, the ozonization device of selecting to be used to react 6 is taken a sample.
Utilize the present invention to carry out semi continuous experiment: in the semi continuous experiment, the ozone saturex 3 of producing saturated ozone water is inoperative, and the sebific duct 9 between ozone saturex 3 and two the ozonization devices 6 is clamped.Before the experiment; In the ozonization device 6 that selection is reacted, put into magnetic force rotor 7; And then in the ozonization device 6 that selection is reacted, add former water, and open magnetic stirring apparatus 5, in the ozonization device 6 of selective reaction, feed the ozone of regime flow then; The ozone that overflows flows into from ozonization device 6 in the ozone resorber 4, and KI solution is housed in the ozone resorber 4.
Utilize the present invention to carry out elder generation's ozonize separately, catalytic ozonation experiment again: the general mode that ozone is provided that adopts the semi continuous experiment of this experiment.The ozone saturex 3 of producing saturated ozone water is inoperative; Sebific duct between ozone saturex 3 and two the ozonization devices 69 is clamped, before the experiment, in two ozonization devices 6, put into magnetic force rotor 7 respectively; In one of them ozonization device 6, add former water; Open magnetic stirring apparatus 5, in the ozonization device 6 that adds former water, feed ozone then, feed ozone after for some time; Treated water flows in another ozonization devices 6 through sebific duct 9 in the ozonization device 6 of feeding ozone; Add catalyzer this moment in another ozonization device 6, the water in another ozonization device 6 begins to carry out catalytic oxidation process, and can take a sample respectively from two ozonization devices 6 and experimentize this moment.
Claims (3)
1. the ozonization device of a multi-operating condition; It is characterized in that: the ozonization device of said a kind of multi-operating condition comprises oxygen cylinder (1), ozonizer (2), ozone saturex (3), ozone resorber (4), magnetic stirring apparatus (5), two ozonization devices (6), two magnetic force rotors (7), two balloons (8) and many sebific ducts (9); The delivery port of said oxygen cylinder (1) is communicated with the input aperture of ozonizer (2); The delivery port of said ozonizer (2) is communicated with the input aperture of ozone saturex (3) through sebific duct (9); The input aperture of each ozonization device (6) respectively is communicated with the delivery port of ozonizer (2) through a sebific duct (9) respectively; Two ozonization devices (6) are set in parallel on the magnetic stirring apparatus (5) side by side; Respectively place a magnetic force rotor (7) respectively in each ozonization device (6); The delivery port of each ozonization device (6) is communicated with the input aperture of ozone resorber (4) through a sebific duct (9) respectively, and the delivery port of said ozone saturex (3) is communicated with the input aperture of ozone resorber (4) through sebific duct (9), and each ozonization device (6) respectively is connected with a balloon (8) through a sebific duct (9) respectively; Each ozonization device (6) respectively is communicated with ozone saturex (3) through a sebific duct (9) respectively, and two ozonization devices (6) are communicated with through sebific duct (9).
2. according to the ozonization device of the said a kind of multi-operating condition of claim 1, it is characterized in that: every sebific duct (9) all is sebific ducts (9) of being made by corrosion resistant material, and every sebific duct (9) is provided with clip.
3. according to the ozonization device of claim 1 or 2 said a kind of multi-operating conditions, it is characterized in that: respectively be fitted with five water shoots (10) respectively on two sidewalls of said ozone saturex (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110418079 CN102491492B (en) | 2011-12-14 | 2011-12-14 | Multi-operation-mode ozonation reaction device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110418079 CN102491492B (en) | 2011-12-14 | 2011-12-14 | Multi-operation-mode ozonation reaction device |
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| CN102491492A true CN102491492A (en) | 2012-06-13 |
| CN102491492B CN102491492B (en) | 2013-07-03 |
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| CN 201110418079 Expired - Fee Related CN102491492B (en) | 2011-12-14 | 2011-12-14 | Multi-operation-mode ozonation reaction device |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001129571A (en) * | 1999-11-08 | 2001-05-15 | Ishikawajima Harima Heavy Ind Co Ltd | Method and apparatus for making ozone water |
| US6344130B1 (en) * | 1998-05-22 | 2002-02-05 | Iwatani Sangyo Kabushiki Kaisha (Iwatani International Corporation) | Method for continuously generating highly concentrated ozone gas |
| CN2931460Y (en) * | 2005-11-30 | 2007-08-08 | 韩春来 | Ozone adding device for pollution water |
| CN101386441A (en) * | 2008-11-04 | 2009-03-18 | 江苏大学 | Water treatment device by ozone oxidation |
| CN101659474A (en) * | 2009-09-30 | 2010-03-03 | 哈尔滨工业大学 | Water treatment device of continuous flow ozone/ultraviolet/advanced oxidation |
-
2011
- 2011-12-14 CN CN 201110418079 patent/CN102491492B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6344130B1 (en) * | 1998-05-22 | 2002-02-05 | Iwatani Sangyo Kabushiki Kaisha (Iwatani International Corporation) | Method for continuously generating highly concentrated ozone gas |
| JP2001129571A (en) * | 1999-11-08 | 2001-05-15 | Ishikawajima Harima Heavy Ind Co Ltd | Method and apparatus for making ozone water |
| CN2931460Y (en) * | 2005-11-30 | 2007-08-08 | 韩春来 | Ozone adding device for pollution water |
| CN101386441A (en) * | 2008-11-04 | 2009-03-18 | 江苏大学 | Water treatment device by ozone oxidation |
| CN101659474A (en) * | 2009-09-30 | 2010-03-03 | 哈尔滨工业大学 | Water treatment device of continuous flow ozone/ultraviolet/advanced oxidation |
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| CN102491492B (en) | 2013-07-03 |
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Inventor after: Li Xiangkun Inventor after: Fang Xing Inventor after: Wang Shutao Inventor after: Zhang Jie Inventor after: Ma Jun Inventor before: Li Xiangkun Inventor before: Fang Xing Inventor before: Zhang Jie Inventor before: Ma Jun |
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Free format text: CORRECT: INVENTOR; FROM: LI XIANGKUN FANG XING ZHANG JIE MA JUN TO: LI XIANGKUN FANG XING WANG SHUTAO ZHANG JIE MA JUN |
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