CN102491492B - Multi-operation-mode ozonation reaction device - Google Patents
Multi-operation-mode ozonation reaction device Download PDFInfo
- Publication number
- CN102491492B CN102491492B CN 201110418079 CN201110418079A CN102491492B CN 102491492 B CN102491492 B CN 102491492B CN 201110418079 CN201110418079 CN 201110418079 CN 201110418079 A CN201110418079 A CN 201110418079A CN 102491492 B CN102491492 B CN 102491492B
- Authority
- CN
- China
- Prior art keywords
- ozone
- ozonization
- sebific duct
- communicated
- saturex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Abstract
The invention relates to a multi-operation-mode ozonation reaction device, which relates to an ozonation reaction device. The invention aims to solve the problem that the conventional sequencing batch ozonation reaction system and the semi-continuous ozonation reaction system, which cannot carry out sequencing batch experiment and semi-continuous experiment at the same time, are inconvenient for researches. According to the multi-operation-mode ozonation reaction device, the output opening of an oxygen cylinder is communicated with an input opening of an ozone generator; the output opening of the ozone generator is communicated with the input opening of an ozone saturating device through a rubber tube; the input opening of each ozonation reactor is communicated with the output opening of the ozone generator through a rubber tube; the output opening of each ozonation reactor is communicated with the input opening of an ozone absorber through a rubber tube; the output opening of the ozone saturating device is communicated with the input opening of the ozone absorber through a rubber tube; and each ozonation reactor is communicated with the ozone saturating device through a rubber tube. The multi-operation-mode ozonation reaction device is used for performing ozonation reaction experiments.
Description
Technical field
The present invention relates to a kind of ozonization device, be specifically related to a kind of ozonization device of multi-operating condition.
Background technology
Generally there are sequencing batch type ozone reaction system and semi continuous ozone reaction system in the ozone reaction system.Sequencing batch type ozone reaction system is namely according to required ozone concn, with saturated ozone water with contain the organism water sample and put in the ozone reactor in proportion, utilize magnetic stirring apparatus to make fully mixing such as ozone, organic pollutant, water in the system, by to the sampling under different time, the differential responses condition, research under different condition, residual ozone concentration, hydroxyl free content, R in the system
CtIndexs such as value, organic constituents situation, concentration of hydrogen peroxide, thus ozone studied to organic effect situation, the amount of its reactant is easy to control, and parameter is easy to determine in the reaction process, the general research that is used for reaction mechanism.Semi continuous ozone reaction system aerogenesis principle is all identical with sequencing batch type ozone reaction system with process, sampling mode, test sample index, be that this system continues to feed a certain amount of ozone to being equipped with in the ozone reaction device that contains the organism water sample, therefore the ozone amount that consumes in the reaction system is difficult for determining, need carry out the balance of ozone by ozone reactor and tail gas collecting device in each test, but therefore ozone be more suitable for being applied to the checking of production experiment more near the practical situation in the water factory in this system.But the equipment of these two kinds traditional ozone reaction systems is different with flow process, makes troubles to the research of carrying out two kinds of reactive systems simultaneously.
Summary of the invention
The present invention can not carry out sequencing batch type experiment and semicontinuous experiment simultaneously for solving existing sequencing batch type ozone reaction system and semi continuous ozone reaction system, the problem of making troubles to research, and then a kind of ozonization device of multi-operating condition is proposed.
The present invention addresses the above problem the technical scheme of taking to be: the present invention includes oxygen cylinder, ozonizer, the ozone saturex, the ozone resorber, magnetic stirring apparatus, two ozonization devices, two magnetic force rotors, two balloons and Duo Gen sebific duct, the delivery port of described oxygen cylinder is communicated with the input aperture of ozonizer, the delivery port of described ozonizer is communicated with by the input aperture of sebific duct with the ozone saturex, the input aperture of each ozonization device respectively is communicated with the delivery port of ozonizer by a sebific duct respectively, two ozonization devices are set in parallel on the magnetic stirring apparatus side by side, respectively place a magnetic force rotor in each ozonization device respectively, the delivery port of each ozonization device is communicated with the input aperture of ozone resorber by a sebific duct respectively, the delivery port of described ozone saturex is communicated with by the input aperture of sebific duct with the ozone resorber, each ozonization device respectively is connected with a balloon by a sebific duct respectively, each ozonization device respectively is communicated with the ozone saturex by a sebific duct respectively, and two ozonization devices are communicated with by sebific duct.
The invention has the beneficial effects as follows: the present invention can carry out sequencing batch type experiment and semi continuous experiment, can also carry out bilateral formula air inlet, one-sided formula air inlet and the air inlet of recycling formula, the present invention can also only carry out ozonize or catalytic ozonation, also can carry out two kinds of oxidations simultaneously, also can make former water carry out independent ozonize, carry out catalytic ozonation again.The present invention has realized the non-detachable mold blocking, and the cycle in work-ing life is long, has reduced the consumptive material loss, has saved experimental cost, and has realized multiple novel operation scheme, for experiment provides convenience.
Description of drawings
Fig. 1 is operational system synoptic diagram of the present invention.
Embodiment
Embodiment one: present embodiment is described in conjunction with Fig. 1, the ozonization device of the described a kind of multi-operating condition of present embodiment comprises oxygen cylinder 1, ozonizer 2, ozone saturex 3, ozone resorber 4, magnetic stirring apparatus 5, two ozonization devices 6, two magnetic force rotors 7, two balloons 8 and Duo Gen sebific duct 9, the delivery port of described oxygen cylinder 1 is communicated with the input aperture of ozonizer 2, the delivery port of described ozonizer 2 is communicated with the input aperture of ozone saturex 3 by sebific duct 9, the input aperture of each ozonization device 6 respectively is communicated with the delivery port of ozonizer 2 by a sebific duct 9 respectively, two ozonization devices 6 are set in parallel on the magnetic stirring apparatus 5 side by side, respectively place a magnetic force rotor 7 in each ozonization device 6 respectively, the delivery port of each ozonization device 6 is communicated with the input aperture of ozone resorber 4 by a sebific duct 9 respectively, the delivery port of described ozone saturex 3 is communicated with the input aperture of ozone resorber 4 by sebific duct 9, each ozonization device 6 respectively is connected with a balloon 8 by a sebific duct 9 respectively, each ozonization device 6 respectively is communicated with ozone saturex 3 by a sebific duct 9 respectively, and two ozonization devices 6 are communicated with by sebific duct 9.
Embodiment two: in conjunction with Fig. 1 present embodiment is described, the every sebific duct 9 of the ozonization device of the described a kind of multi-operating condition of present embodiment all is sebific ducts 9 of being made by corrosion resistant material, and every sebific duct 9 is provided with clip.Other composition and annexation are identical with embodiment one.
Embodiment three: in conjunction with Fig. 1 present embodiment is described, respectively is fitted with five water shoots 10 respectively on two sidewalls of the ozone saturex 3 of the ozonization device of the described a kind of multi-operating condition of present embodiment.Other composition and annexation are identical with embodiment one or two.
Principle of work
Utilize the present invention to carry out the sequencing batch type experiment: before the experiment, carry out adding in the ozonization device 6 of ozonization magnetic force rotor 7 to selection, clamp the flexible pipe 9 that is communicated with two ozonization devices 6, in the ozone saturex 3 that the Milli-Q ultrapure water only is housed, feed a certain amount of ozone, feed ozone after half an hour, ozone water reaches capacity, in the ozonization device 6 of selective reaction, add former water and catalyzer, close two ozonization devices 6, ventilate in balloon 8 by plastic injector, ventilation back sealing balloon 8, by the ozonization device 6 quick injections saturated ozone water of ozone saturex 3 to selective reaction, after for some time, the ozonization device of selecting to be used for reaction 6 is taken a sample.
Utilize the present invention to carry out semi continuous experiment: in the semi continuous experiment, the ozone saturex 3 of producing saturated ozone water is inoperative, and the sebific duct 9 between ozone saturex 3 and two the ozonization devices 6 is clamped.Before the experiment, put into magnetic force rotor 7 in the ozonization device 6 that reacts to selection, and then add former water in the ozonization device 6 that reacts to selection, and open magnetic stirring apparatus 5, feed the ozone of regime flow then in the ozonization device 6 of selective reaction, the ozone that overflows flows into from ozonization device 6 in the ozone resorber 4, and KI solution is housed in the ozone resorber 4.
Utilize the present invention to carry out elder generation's ozonize separately, catalytic ozonation experiment again: the general mode that ozone is provided that adopts the semi continuous experiment of this experiment.The ozone saturex 3 of producing saturated ozone water is inoperative, sebific duct 9 between ozone saturex 3 and two the ozonization devices 6 is clamped, before the experiment, in two ozonization devices 6, put into magnetic force rotor 7 respectively, in one of them ozonization device 6, add former water, open magnetic stirring apparatus 5, in the ozonization device 6 that adds former water, feed ozone then, feed ozone after for some time, treated water flows in another ozonization devices 6 by sebific duct 9 in the ozonization device 6 of feeding ozone, add catalyzer this moment in another ozonization device 6, water in another ozonization device 6 begins to carry out catalytic oxidation process, and can take a sample respectively from two ozonization devices 6 and experimentize this moment.
Claims (3)
1. the ozonization device of a multi-operating condition, it is characterized in that: the ozonization device of described a kind of multi-operating condition comprises oxygen cylinder (1), ozonizer (2), ozone saturex (3), ozone resorber (4), magnetic stirring apparatus (5), two ozonization devices (6), two magnetic force rotors (7), two balloons (8) and many sebific ducts (9), the delivery port of described oxygen cylinder (1) is communicated with the input aperture of ozonizer (2), the delivery port of described ozonizer (2) is communicated with the input aperture of ozone saturex (3) by sebific duct (9), the input aperture of each ozonization device (6) respectively is communicated with the delivery port of ozonizer (2) by a sebific duct (9) respectively, two ozonization devices (6) are set in parallel on the magnetic stirring apparatus (5) side by side, respectively place a magnetic force rotor (7) respectively in each ozonization device (6), the delivery port of each ozonization device (6) is communicated with the input aperture of ozone resorber (4) by a sebific duct (9) respectively, the delivery port of described ozone saturex (3) is communicated with the input aperture of ozone resorber (4) by sebific duct (9), each ozonization device (6) respectively is connected with a balloon (8) by a sebific duct (9) respectively, each ozonization device (6) respectively is communicated with ozone saturex (3) by a sebific duct (9) respectively, two ozonization devices (6) are communicated with by sebific duct (9), carry out the sequencing batch type experiment: before the experiment, carry out the middle magnetic force rotor (7) that adds of ozonization device (6) of ozonization to selection, clamp the sebific duct (9) that is communicated with two ozonization devices (6), in the ozone saturex (3) that the Milli-Q ultrapure water only is housed, feed a certain amount of ozone, feed ozone after half an hour, ozone water reaches capacity, in the ozonization device (6) of selective reaction, add former water and catalyzer, close two ozonization devices (6), ventilate in balloon (8) by plastic injector, ventilation back sealing balloon (8), inject saturated ozone water by ozone saturex (3) fast to the ozonization device (6) of selective reaction, after for some time, the ozonization device of selecting to be used for reaction (6) is taken a sample; Carry out the semi continuous experiment: in the semi continuous experiment, the ozone saturex (3) of producing saturated ozone water is inoperative, and the sebific duct (9) between ozone saturex (3) and two the ozonization devices (6) is clamped; Before the experiment, put into magnetic force rotor (7) in the ozonization device (6) that reacts to selection, and then add former water in the ozonization device (6) that reacts to selection, and open magnetic stirring apparatus (5), then to the middle ozone that feeds regime flow of the ozonization device (6) of selective reaction, the ozone that overflows flows in the ozone resorber (4) from ozonization device (6), and the ozone resorber is equipped with KI solution in (4); Carry out elder generation's ozonize separately, catalytic ozonation experiment again: the general mode that ozone is provided that adopts the semi continuous experiment of this experiment; The ozone saturex (3) of producing saturated ozone water is inoperative, sebific duct (9) between ozone saturex (3) and two the ozonization devices (6) is clamped, before the experiment, in two ozonization devices (6), put into magnetic force rotor (7) respectively, in one of them ozonization device (6), add former water, open magnetic stirring apparatus (5), in the ozonization device (6) that adds former water, feed ozone then, feed ozone after for some time, the middle treated water of ozonization device (6) that feeds ozone flows in another ozonization device (6) by sebific duct (9), in another ozonization device (6), add catalyzer this moment, water in another ozonization device (6) begins to carry out catalytic oxidation process, and take a sample respectively from two ozonization devices (6) and experimentize this moment.
2. according to the ozonization device of the described a kind of multi-operating condition of claim 1, it is characterized in that: every sebific duct (9) all is sebific ducts (9) of being made by corrosion resistant material, and every sebific duct (9) is provided with clip.
3. according to the ozonization device of claim 1 or 2 described a kind of multi-operating conditions, it is characterized in that: respectively be fitted with five water shoots (10) respectively on two sidewalls of described ozone saturex (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110418079 CN102491492B (en) | 2011-12-14 | 2011-12-14 | Multi-operation-mode ozonation reaction device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110418079 CN102491492B (en) | 2011-12-14 | 2011-12-14 | Multi-operation-mode ozonation reaction device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102491492A CN102491492A (en) | 2012-06-13 |
| CN102491492B true CN102491492B (en) | 2013-07-03 |
Family
ID=46183363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110418079 Expired - Fee Related CN102491492B (en) | 2011-12-14 | 2011-12-14 | Multi-operation-mode ozonation reaction device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102491492B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6344130B1 (en) * | 1998-05-22 | 2002-02-05 | Iwatani Sangyo Kabushiki Kaisha (Iwatani International Corporation) | Method for continuously generating highly concentrated ozone gas |
| CN2931460Y (en) * | 2005-11-30 | 2007-08-08 | 韩春来 | Ozone adding device for pollution water |
| CN101386441A (en) * | 2008-11-04 | 2009-03-18 | 江苏大学 | Water treatment device by ozone oxidation |
| CN101659474A (en) * | 2009-09-30 | 2010-03-03 | 哈尔滨工业大学 | Water treatment device of continuous flow ozone/ultraviolet/advanced oxidation |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001129571A (en) * | 1999-11-08 | 2001-05-15 | Ishikawajima Harima Heavy Ind Co Ltd | Method and apparatus for making ozone water |
-
2011
- 2011-12-14 CN CN 201110418079 patent/CN102491492B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6344130B1 (en) * | 1998-05-22 | 2002-02-05 | Iwatani Sangyo Kabushiki Kaisha (Iwatani International Corporation) | Method for continuously generating highly concentrated ozone gas |
| CN2931460Y (en) * | 2005-11-30 | 2007-08-08 | 韩春来 | Ozone adding device for pollution water |
| CN101386441A (en) * | 2008-11-04 | 2009-03-18 | 江苏大学 | Water treatment device by ozone oxidation |
| CN101659474A (en) * | 2009-09-30 | 2010-03-03 | 哈尔滨工业大学 | Water treatment device of continuous flow ozone/ultraviolet/advanced oxidation |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2001-129571A 2001.05.15 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102491492A (en) | 2012-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Labatut et al. | Monitoring of anaerobic digestion process to optimize performance and prevent system failure | |
| CN104538659B (en) | A kind of microbiological fuel cell using conductive membrane aeration biomembrane reactor as negative electrode | |
| CN102701543B (en) | Water treatment device combining microbial fuel cells with membrane technology | |
| CN106928670A (en) | Oxidation modification lignin-base lactic acid composite material and preparation method thereof and oxidation unit | |
| CN102491492B (en) | Multi-operation-mode ozonation reaction device | |
| CN104891469A (en) | Method and device for carboxylation modification of carbon nano-material by ozone and use thereof | |
| Bakonyi et al. | Investigating the effect of hydrogen sulfide impurities on the separation of fermentatively produced hydrogen by PDMS membrane | |
| Esquiroz-Molina et al. | Influence of pH on gas phase controlled mass transfer in a membrane contactor for hydrogen sulphide absorption | |
| EP3267524B1 (en) | Fuel cell system | |
| CN102974213A (en) | Fully-automatic biogas interior micro-oxygen desulfurization device | |
| CN208104028U (en) | A kind of device for rapidly starting of anaerobic ammonia oxidation process | |
| CN104628121A (en) | Ozonation reaction apparatus | |
| CN108217937A (en) | The device for rapidly starting and method of a kind of anaerobic ammonia oxidation process | |
| JP5657327B2 (en) | Waste water treatment method and waste water treatment system | |
| CN113941257B (en) | System and method for detecting oxygen utilization efficiency of MABR (MABR) process | |
| CN104891592B (en) | The processing equipment of nitrogen-containing wastewater | |
| CN215179944U (en) | Multifunctional sulfur recovery catalyst evaluation device | |
| CN102242064A (en) | Continuous air supplying method and system for chlamydomonas cultivation | |
| CN104535725A (en) | Monitoring system | |
| GB900575A (en) | Liquid receiving and transfer means | |
| US20170066649A1 (en) | Co shift conversion device and shift conversion method | |
| CN205965796U (en) | Be used for fumaric acid oxidation panel reaction system | |
| CN204429058U (en) | A kind of ozone contact reaction device for recovering tail gas | |
| CN204330725U (en) | A kind of monitoring system | |
| CN208454593U (en) | A kind of catalytic ozonation reaction unit |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Xiangkun Inventor after: Fang Xing Inventor after: Wang Shutao Inventor after: Zhang Jie Inventor after: Ma Jun Inventor before: Li Xiangkun Inventor before: Fang Xing Inventor before: Zhang Jie Inventor before: Ma Jun |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LI XIANGKUN FANG XING ZHANG JIE MA JUN TO: LI XIANGKUN FANG XING WANG SHUTAO ZHANG JIE MA JUN |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130703 Termination date: 20141214 |
|
| EXPY | Termination of patent right or utility model |