CN102454226B - High-polymer self-adhesion waterproof coiled material of a kind of pre-spread/wet paving and preparation method thereof - Google Patents

High-polymer self-adhesion waterproof coiled material of a kind of pre-spread/wet paving and preparation method thereof Download PDF

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Publication number
CN102454226B
CN102454226B CN201010529390.3A CN201010529390A CN102454226B CN 102454226 B CN102454226 B CN 102454226B CN 201010529390 A CN201010529390 A CN 201010529390A CN 102454226 B CN102454226 B CN 102454226B
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Prior art keywords
self
spread
coiled material
adhesive layer
waterproof coiled
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Expired - Fee Related
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CN201010529390.3A
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CN102454226A (en
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张春森
李芳兰
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SHENYANG LANGUANG TECHNOLOGY DEVELOPMENT CO LTD
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SHENYANG LANGUANG TECHNOLOGY DEVELOPMENT CO LTD
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Abstract

The invention provides the high-polymer self-adhesion waterproof coiled material of a kind of pre-spread/wet paving, the high-polymer self-adhesion waterproof coiled material of described pre-spread/wet paving comprises modified bitumen self-adhesive layer, containing petroleum bitumen, modifier, softening agent, tackifier and filler in described modified bitumen self-adhesive layer.The present invention take polymer resin layer as tire base, by the high-polymer self-adhesion waterproof coiled material of the pre-spread/wet paving of the modified bitumen self-adhesive layer composition of single or double attachment preparation, and long service life, stable chemical performance, and waterproof effect is splendid.

Description

High-polymer self-adhesion waterproof coiled material of a kind of pre-spread/wet paving and preparation method thereof
Technical field
The present invention relates to high-polymer self-adhesion waterproof coiled material of a kind of pre-spread/wet paving and preparation method thereof.
Background technology
Waterproof roll is mainly used for construction wall, roofing, and tunnel, highway, subway, the places such as refuse landfill, play and resist extraneous rainwater, the flexible building material product of a kind of rollable one-tenth web-like of ground water seepage, be connected as leakproof between engineering foundation with building, it is the first barrier of whole engineering waterproofing, vital effect is played to whole engineering, asphalt waterproofing material can be divided into according to its main waterproof composition material, modified-high polymer waterproof roll material and synthetic polymeric waterproofing material three major types asphalt water-proof coiled material asphalt water-proof coiled material are (as body paper at base tire, fabric) on invade pitching after, again at the isolated material of surperficial spreading powdery or sheet and the rollable sheet waterproofing materials made, therefore, traditional asphalt waterproofing materials is short for application life, poor chemical stability, and waterproof effect is undesirable.
Summary of the invention
The present invention aims to provide a kind of long service life, stable chemical performance, and the high-polymer self-adhesion waterproof coiled material of the pre-spread of good water-proof effect/wet paving, for realizing the object of foregoing invention, the present invention solves by the following technical solutions:
A high-polymer self-adhesion waterproof coiled material for pre-spread/wet paving, the high-polymer self-adhesion waterproof coiled material of described pre-spread/wet paving comprises modified bitumen self-adhesive layer, containing petroleum bitumen, modifier, softening agent, tackifier and filler in described modified bitumen self-adhesive layer.
Preferably, described modifier be s-B-S (SBS), polypropylene (PP) one or more.
Preferably, described softening agent is second line of distillation oil, subtracts one or more of third fractional oil.
Preferably, stating tackifier is cycloparaffin resin.
Preferably, described filler is French chalk.
Preferably, described modified bitumen self-adhesive layer formula is (by mass fraction):
Petroleum bitumen 50-60;
Modifier 10-20;
Softening agent 5-15;
Tackifier 1-10;
Filler 10-20.
Preferably, described modified bitumen self-adhesive layer formula is (by mass fraction):
Petroleum bitumen 54;
Modifier 15;
Softening agent 10;
Tackifier 5;
Filler 16.
Preferably, described modified bitumen self-adhesive layer is at least equipped with polymer resin layer in side, and described polymer resin layer is one or more in the blend ECB of ethylene-vinyl acetate copolymer EVA, ethylene vinyl acetate and pitch, polyvinylchloride and high density polyethylene.
Preferably, also barrier film is covered with outside described polymer resin layer.
And the high-polymer self-adhesion waterproof coiled material preparation method of a kind of pre-spread/wet paving, comprise the following steps:
In part petroleum bitumen, add modifier, softening agent be warming up to 180 DEG C-200 DEG C, stir 180 minutes, obtained modified materials;
Modified materials squeezes into another sky agitator tank through colloid mill;
Add another kind of modifier (PP), filler in modified materials in batches, 150 minutes, every batch of interval, and continue to stir;
Add tackifier and remain asphalt temperature and keep 180 DEG C, continue to stir;
Modified bitumen is coated in polymer resin layer one or both sides from sizing from sizing by immersion trough by modified bitumen.
From such scheme, the present invention take polymer resin layer as tire base, by the high-polymer self-adhesion waterproof coiled material of the modified bitumen self-adhesive layer composition pre-spread/wet paving of single or double attachment preparation.Macromolecule resin tool has the following advantages: 1, have long service life, weather-proof, ageing-resistant, waterproof, antiseptic property are superior, tasteless, pollution-free, construction safety is easy, and the duration is short.2, protection against the tide, mildew-resistant, smooth abrasion-proof, induration are nontoxic.3, the chemical attack performance of coating acid and alkali resistance, salt and oils and anti-various solvent is strong, has excellent anti-flammability, insulating properties.Further, the construction body that the pitch self-adhesive layer of the high-polymer self-adhesion waterproof coiled material of pre-spread/wet paving can be master with concrete produces ion exchange, makes the two firmly be bonded together, forms gapless waterproof sealing system.
Detailed description of the invention
Below in conjunction with by embodiment, the present invention is set forth, but protection scope of the present invention is not only confined to following examples.Person of an ordinary skill in the technical field, according to content disclosed by the invention, all can realize object of the present invention.
The high-polymer self-adhesion waterproof coiled material of pre-spread/wet paving, the high-polymer self-adhesion waterproof coiled material of described pre-spread/wet paving comprises modified bitumen self-adhesive layer, containing petroleum bitumen, modifier, softening agent, tackifier and filler in described modified bitumen self-adhesive layer.
Preferably, described modified bitumen self-adhesive layer formula is (by mass fraction):
Petroleum bitumen 50-60;
Modifier 10-20;
Softening agent 5-15;
Tackifier 1-10;
Filler 10-20.
Described modified bitumen self-adhesive layer is at least equipped with polymer resin layer in side, and described polymer resin layer is one or more in the blend ECB of ethylene-vinyl acetate copolymer EVA, ethylene vinyl acetate and pitch, polyvinylchloride and high density polyethylene.
Further, also barrier film is covered with outside polymer resin layer.
Embodiment 1:
Get petroleum bitumen 25g, in petroleum bitumen, add 5g s-B-S (SBS) be warming up to 180 DEG C as modifier, second line of distillation oil 5g as softening agent, to stir 180 minutes, obtain modified materials;
Modified materials squeezes into another sky agitator tank through colloid mill;
Add another kind of modifier polypropylene (PP) 2.5g and 300 object French chalk 5g in modified materials as filler, stir after 150 minutes, again add modifier polypropylene (PP) 2.5g and 300 object French chalk 5g as filler;
Add 1g cycloparaffin resin and keep 180 DEG C as tackifier and 25g asphalt temperature, continue to stir;
Modified bitumen is coated in ethylene-vinyl acetate copolymer (EVA resin) side from sizing from sizing by immersion trough by modified bitumen, makes the high-polymer self-adhesion waterproof coiled material of pre-spread/wet paving.
As the improvement of above-described embodiment scheme, ethylene-vinyl acetate copolymer (EVA resin) outside is also covered with barrier film.
Embodiment 2:
Get petroleum bitumen 30g, in petroleum bitumen, add 10g s-B-S (SBS) be warming up to 200 DEG C as modifier, second line of distillation oil 10g as softening agent, to stir 180 minutes, obtain modified materials;
Modified materials squeezes into another sky agitator tank through colloid mill;
Add another kind of modifier polypropylene (PP) 5g and 300 object French chalk 10g in modified materials as filler, stir after 150 minutes, again add modifier polypropylene (PP) 5g and 300 object French chalk 10g as filler;
Add 10g cycloparaffin resin and keep 180 DEG C as tackifier and 30g asphalt temperature, continue to stir;
Modified bitumen is coated in blend (ECB) side of ethylene vinyl acetate and pitch by modified bitumen from sizing by immersion trough from sizing, make the high-polymer self-adhesion waterproof coiled material of pre-spread/wet paving.
As the improvement of above-described embodiment scheme, blend (ECB) outside of ethylene vinyl acetate and pitch is also covered with barrier film.
Embodiment 3:
Get petroleum bitumen 27g, add in petroleum bitumen 7g s-B-S (SBS) as modifier, subtract third fractional oil 10g as softening agent and be warming up to 200 DEG C, to stir 180 minutes, obtained modified materials;
Modified materials squeezes into another sky agitator tank through colloid mill;
Add another kind of modifier polypropylene (PP) 4g and 300 object French chalk 8g in modified materials as filler, stir after 150 minutes, again add modifier polypropylene (PP) 4g and 300 object French chalk 8g as filler;
Add 10g cycloparaffin resin and keep 180 DEG C as tackifier and 27g asphalt temperature, continue to stir;
Modified bitumen is coated in the both sides of polyvinyl chloride (PVC) or high density polyethylene (HDPE) (HDPE) or both mixtures by modified bitumen from sizing by immersion trough from sizing, make the high-polymer self-adhesion waterproof coiled material of pre-spread/wet paving.
As the improvement of above-described embodiment scheme, the outside of polyvinyl chloride (PVC) or high density polyethylene (HDPE) (HDPE) or both mixtures is also covered with barrier film.
Above the high-polymer self-adhesion waterproof coiled material of pre-spread provided by the present invention/wet paving is described in detail, apply specific case herein to set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping; Meanwhile, for one of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.

Claims (1)

1. a high-polymer self-adhesion waterproof coiled material for pre-spread/wet paving, is characterized in that:
The high-polymer self-adhesion waterproof coiled material of described pre-spread/wet paving comprises modified bitumen self-adhesive layer, containing petroleum bitumen, modifier, softening agent, tackifier and filler in described modified bitumen self-adhesive layer;
Described modifier is made up of s-B-S, polypropylene;
Described modified bitumen self-adhesive layer formula is (by mass fraction):
Described modified bitumen self-adhesive layer is at least equipped with polymer resin layer in side; Described polymer resin layer is one or more in the blend of ethylene-vinyl acetate copolymer, ethylene vinyl acetate and pitch, polyvinyl chloride and high density polyethylene (HDPE);
Described softening agent is second line of distillation oil, subtracts one or more of third fractional oil;
Also barrier film is covered with outside described polymer resin layer;
Described tackifier are cycloalkanes tree; Described filler is French chalk.
CN201010529390.3A 2010-10-29 2010-10-29 High-polymer self-adhesion waterproof coiled material of a kind of pre-spread/wet paving and preparation method thereof Expired - Fee Related CN102454226B (en)

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CN103361980B (en) * 2013-08-02 2015-08-12 南京道润交通科技有限公司 The preparation method of self-adhering type Fibergrass polyester mat and self-adhering type Fibergrass polyester mat
CN103802380B (en) * 2014-02-28 2016-08-17 北京东方雨虹防水技术股份有限公司 Modified asphalt waterproof coiled material
CN104194719A (en) * 2014-09-11 2014-12-10 惠州东方雨虹建筑材料有限责任公司 Creeping self-adhesive asphalt water-proof coiled material and preparation method thereof
CN104830207B (en) * 2015-05-28 2017-04-12 天津市禹红建筑防水材料有限公司 Organic adhesive cover paint and application thereof in modified asphalt waterproof coils
CN104960267B (en) * 2015-06-18 2017-02-01 四川蜀羊防水材料有限公司 Modified asphalt waterproof coiled material
CN110128840B (en) * 2016-04-20 2021-07-30 锦州东方雨虹建筑材料有限责任公司 Modified asphalt for waterproof coiled material and preparation method thereof
CN107663380A (en) * 2016-07-30 2018-02-06 甘肃西盟公路新材料科技有限公司 A kind of bituminous composition and preparation method thereof
CN108116004A (en) * 2016-11-29 2018-06-05 河北四正北方新型材料科技有限公司 Band takes off the modified pitch base waterproof roll of membrane process
CN106675409A (en) * 2016-12-30 2017-05-17 上海东方雨虹防水技术有限责任公司 Modified asphalt coating with saline-alkaline tolerance and root resistance and production method as well as waterproof roll and production method
CN109695158B (en) * 2017-10-23 2021-09-28 南京道之尊复合材料有限公司 Self-adhesive stress cloth
CN110016298A (en) * 2019-04-16 2019-07-16 新疆北新路桥集团股份有限公司 A kind of concrete road conserving material and its application
CN113059895A (en) * 2021-05-08 2021-07-02 四川环图材料科技有限公司 Preparation method of plant root puncture-resistant waterproof coiled material for planted roof
CN114672264A (en) * 2022-04-06 2022-06-28 安徽省奥佳建材有限公司 Elastic self-adhesive waterproof roll and preparation method thereof

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