CN105584135B - Wet-laying waterproof roll is overlay with cross-linking reaction layer - Google Patents
Wet-laying waterproof roll is overlay with cross-linking reaction layer Download PDFInfo
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- CN105584135B CN105584135B CN201410570698.0A CN201410570698A CN105584135B CN 105584135 B CN105584135 B CN 105584135B CN 201410570698 A CN201410570698 A CN 201410570698A CN 105584135 B CN105584135 B CN 105584135B
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- Prior art keywords
- layer
- cross
- linking reaction
- wet
- waterproof roll
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Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 48
- 238000004132 cross linking Methods 0.000 title claims abstract description 47
- 239000010410 layer Substances 0.000 claims abstract description 317
- 239000000463 material Substances 0.000 claims abstract description 47
- 239000010426 asphalt Substances 0.000 claims abstract description 32
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 6
- -1 allyl oxygen Chemical compound 0.000 claims description 71
- 239000007822 coupling agent Substances 0.000 claims description 37
- 239000004698 Polyethylene Substances 0.000 claims description 30
- 229920000573 polyethylene Polymers 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 25
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 23
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 19
- 229920000728 polyester Polymers 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 14
- 239000004744 fabric Substances 0.000 claims description 13
- 229920002521 macromolecule Polymers 0.000 claims description 13
- 239000001301 oxygen Substances 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 11
- 239000010452 phosphate Substances 0.000 claims description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims description 11
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052726 zirconium Inorganic materials 0.000 claims description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 7
- 125000004423 acyloxy group Chemical group 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 5
- 229920005610 lignin Polymers 0.000 claims description 5
- VYICTQFDOGOFQH-UHFFFAOYSA-N C(CCCCC)[Zr] Chemical compound C(CCCCC)[Zr] VYICTQFDOGOFQH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 claims description 4
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 claims description 3
- 235000014121 butter Nutrition 0.000 claims description 3
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 3
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 3
- UARGAUQGVANXCB-UHFFFAOYSA-N ethanol;zirconium Chemical compound [Zr].CCO.CCO.CCO.CCO UARGAUQGVANXCB-UHFFFAOYSA-N 0.000 claims description 3
- 238000007731 hot pressing Methods 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011152 fibreglass Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 claims description 2
- 229920006267 polyester film Polymers 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 2
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims 1
- 239000006087 Silane Coupling Agent Substances 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims 1
- GVVNVWMBOHQMEV-UHFFFAOYSA-N n'-(1-trimethoxysilylpropyl)ethane-1,2-diamine Chemical class CO[Si](OC)(OC)C(CC)NCCN GVVNVWMBOHQMEV-UHFFFAOYSA-N 0.000 claims 1
- WDHYRUBXLGOLKR-UHFFFAOYSA-N phosphoric acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OP(O)(O)=O WDHYRUBXLGOLKR-UHFFFAOYSA-N 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000011295 pitch Substances 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 18
- 239000004567 concrete Substances 0.000 abstract description 17
- 238000010276 construction Methods 0.000 abstract description 14
- 230000032683 aging Effects 0.000 abstract description 3
- 239000012790 adhesive layer Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000003431 cross linking reagent Substances 0.000 description 8
- 238000007789 sealing Methods 0.000 description 8
- 239000004568 cement Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010382 chemical cross-linking Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011280 coal tar Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 239000005001 laminate film Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 2
- 125000004334 oxygen containing inorganic group Chemical group 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 description 1
- UMHKOAYRTRADAT-UHFFFAOYSA-N [hydroxy(octoxy)phosphoryl] octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OP(O)(=O)OCCCCCCCC UMHKOAYRTRADAT-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical group 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000011382 roller-compacted concrete Substances 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
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Landscapes
- Road Paving Structures (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention is intended to provide a kind of overlay wet-laying waterproof roll with cross-linking reaction layer, including material of main part layer, be bonded and sealed glue-line and cross-linking reaction layer, and the glue-line that is bonded and sealed is asphalt layer, modified asphalt layer or polymeric pressure sensitive adhesive layer.It is of the present invention overlay wet-laying waterproof roll increased cross-linking reaction layer after, can realize and the more preferable bond effect of concrete surface, suitable for various pitches or polymeric pressure sensitive adhesive wet-laying waterproof roll is overlay for adhesive layer primary raw material, range of application is wide, technique effect is protruded, solve because the influence of the factor such as environment moisture and hot ageing, steam expansion, base layer motion, and so that with overlay wet-laying waterproof coiled material construction into waterproof layer loss of seal waterproof effect problem.
Description
Technical field
The present invention relates to seal waterproof field, more particularly to a kind of overlay wet-laying waterproof roll with cross-linking reaction layer.
Background technology
It is presently used for tunnel in communications and transportation, subway basement and contains for shed deckhead, civil air defense constructions and installations, dykes and dams
Lock, the water proof anti-seepage in all kinds of ponds construction work it is more and more, the material for waterproof is mainly coating and various
Sheet material or coiled material, with the appearance of asphalt water-proof coiled material or the macromolecular sheet material of fabric layer because its can with industrialized production,
It is easy to use, applied in construction and increasingly favored by people, particularly building top layer terrace, subway terrace and dike
The construction of dam culverts and water gates top surface, is adhered directly onto one side of the modified bituminous pitch coiled material with adhesive concrete surface and just reaches waterproof
Purpose.Open source literature also discloses that the technology of some this respects, such as Chinese patent：It is compounded with tyre water-proof coiled material and viscose glue
Agent, application number：CN94110918.6, the applying date：1994.04.04, publication number：CN1110301, publication date：1995.10.18,
Applicant：Zhang Guoming, address：Zhuzhou, hunan province city balcony road balcony mountain villa 18, inventor：Zhang Guoming, summary：It is compounded with tire
Waterproof roll and adhesive are architectural waterproof materials, the waterproof roll and adhesive with thermoplastic rubber and haloflex,
Mixed resin after polychloroethylene blended, adds appropriate coal tar and inserts, auxiliary material are made.In the proportioning of the coiled material
Mixed resin accounts for 25~35%, and coal tar accounts for 35~40%, and inserts accounts for 25~30%, and auxiliary material accounts for 5%, mixes in the viscose glue
Base-material accounts for 10~15%, and coal tar accounts for 50~55%, and inserts accounts for 25~30%, and auxiliary material accounts for 5~10%.Polyvinyl chloride used is new
Old not limit, inserts used is talcum powder, red mud, charcoal acid calcium or flyash；It is described to be compounded with tyre water-proof coiled material, be with glass,
The fabrics such as jute, non-woven fabrics are carcass, are made through extruding compound technology.
Such as the patent of Hebei province Qinhuangdao Zhang Shoubin applications：Multi-layer high-molecular water-proof rolled, application number：00245890,
The applying date：2000.08.15, notification number：CN2442835, summary：A kind of Multi-layer high-molecular water-proof rolled, its cross section is at least
Four layers of construction, are from top to bottom followed successively by：1. 2. EVA resin modified polyethylene waterproof increases filament polypropylene fibre non-woven fabric upper surface protective layer
Strong layer 3. polypropylene waterproof membrane lamella 4. filament polypropylene fibre non-woven fabric lower surface protective layer；Thereon, the long filament polypropylene fibre nonwoven of lower surface
There are the groove and projection of stereo grid shaped rectangle and/or rhombus in cloth material outer surface.
Such as Chinese patent：Waterproof construction and its manufacture method, application number：CN200810112011.3, the applying date：
2008.05.20, publication number：CN101586381, publication date：2009.11.25, make a summary：The invention is on a kind of waterproof construction
And its manufacture method.The waterproof construction is used for the waterproof of detail treatment on roofing, including waterproof roll layer, and waterproof coating
Layer, is arranged on detail treatment position, and mutually overlap joint is bonded with above-mentioned waterproof roll layer.Can be wrapped in described waterproof coating layer
It is polyester or nylon nonwoven fabrics or weaving cloth enhancement layer to include material.The material of waterproof coating layer is exposed type polyurea waterproof coating material
Or its modified water-proof coating, exposed type polyurethane water-proof paint or its modified water-proof coating, exposed type polymethyl methacrylate
Class water-repellent paint and its modified water-proof coating or exposed type polystyrene-ethylene-butadiene-styrene or its modified waterproof painting
Material.Waterproof construction of the invention is big due to the bonding force of waterproof coating layer, and tensile resistance is strong, and elasticity higher, is meeting
When causing roofing detail treatment position distortions to strong wind weather or other reasonses, waterproof coating layer will not be destroyed, and still have
There is excellent waterproof effect.
The inventors discovered that, the patent of the above and present waterproof roll seen on the market are mainly modified asphalt waterproof volume
Material, macromolecular sheet material, its construction method is more to be constructed with hot pressing or applies oiliness pool cream, oiliness base oil, macromolecule glue bonding, is existed
Highly energy-consuming, danger, environmental pollution are big, moisture substrate construction bonding is insecure；With polyvinyl alcohol latex cement adhesive and other
The waterproof roll of polymer latex cement bonding, be easy to by environment moisture and hot ageing, steam expansion, base layer motion etc. because
Element influence, makes coiled material have invertibity with the bonding of basal plane, disengaging, obscission occurs, loses permanent seal waterproof effect.
Although prior art occurs pitch and crosslinking agent mixing produces chemical crosslinking and physics mortise and tenon to act on anti-to strengthen
Water coiled material and the cementation power of concrete surface, lift the effect of waterproof.But after crosslinking agent mixes with pitch, major part is handed over
Connection agent is inside waterproof roll, and what can be contacted with concrete interface is less, and its addition consumption is not reaching to most preferably with adhesiving effect
State.
The content of the invention
The present invention is intended to provide a kind of overlay wet-laying waterproof roll with cross-linking reaction layer, the waterproof roll is by coiled material
Cross-linking reaction layer with concrete by chemical crosslinking and the effect of physics mortise and tenon, coiled material and concrete surface is reached with reference to tightly
Close, firm bond effect.
It is described to overlay wet-laying waterproof roll with cross-linking reaction layer, including material of main part layer, be bonded and sealed glue-line and friendship
Connection conversion zone；The glue-line that is bonded and sealed is asphalt layer, modified asphalt layer or polymeric pressure sensitive adhesive layer, and the crosslinking is anti-
Layer is answered for silane coupler, bimetallic coupling agent, lignin coupling agent, tin coupling agent, zirconium coupling agent, phosphate coupling agent, dilute
The mixture layer of the one or more than one in native coupling agent；The upper one side of material of main part layer is be bonded and sealed glue-line or upper and lower two
Face is the glue-line that is bonded and sealed, and is cross-linking reaction layer on the glue-line that is bonded and sealed.
The asphalt that described asphalt floor is used is 70~No. 120 asphalt.
The modified pitch that described modified asphalt layer is used is in SBS modified pitch, APP modified pitch, SBR modified pitch
One or several blend.
The polymeric pressure sensitive adhesive that polymeric pressure sensitive adhesive layer is used is pressure sensitive adhesive of the rubber by formation after mixed refining process.
Described silane coupler includes VTES, aminopropyltriethoxywerene werene, vinyl three
Methoxy silane, VTES, vinyl three ('beta '-methoxy ethyoxyl) silane, N-(β-aminoethyl)-α ammonia
Propyl trimethoxy silicane, N-(β-aminoethyl)-γ-aminopropyl triethoxysilane, 3-glycidyl ether oxygen propyl three
Methoxy silane, 2-(3,4-7-oxa-bicyclo[4.1.0 base) ethyl trimethoxy silanes, γ-methacryloxypropyl front three
TMOS；
Described lignin coupling agent includes sodium lignin sulfonate and calcium lignosulfonate；
Described tin coupling agent includes butter of tin；
Described zirconium coupling agent includes DBSA zirconium complex, neodecanoic acid zirconium complex, isooctanol hydrogen phosphoric acid
Zirconium complex, 2- [(2- amino-ethyls) amino] ethanol zirconium complex, the new caprate of hexyl zirconium three of two allyl oxygen；
Described phosphate coupling agent includes methylacryoyloxyethyl phosphate, glycolmethacrylate phosphoric acid
Ester, alkyl acrylate phosphate, polyfunctionality acid acrylate；
Described rare-earth coupling agent includes rare earth aluminic acid ester coupling agent, rare earth titanate coupling agent.
Described rare earth aluminic acid ester coupling agent includes distearyl acyl-oxygen aluminum isopropoxide acid esters；
Described rare earth titanate coupling agent includes isopropyl two oleic acid acyloxy (dioctylphyrophosphoric acid acyloxy) metatitanic acid
Ester, isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, monoalkoxy unrighted acid titanate esters, double (two octyloxies Jiao
It is phosphate-based) ethylene titanate esters and triethanolamine chelate, Di(dioctylpyrophosphato) ethylene titanate, plant acid type
Monoalkoxy class titanate esters, isopropyl three (dodecyl benzenesulfonyl) titanate esters, isopropyl three (dioctylphosphoric acid ester) titanate esters,
Tetra isopropyl diphosphorous acid dioctyl ester titanate esters, the dioctyl pyrophosphate titanate esters of isopropyl three, isopropyl three (capryl) metatitanic acid
Ester, isopropyl three (N- β-aminoethyl-β-aminoethyl) titanate esters, isopropyl three [N- β-(aminoethyl) first-aminoethyl] metatitanic acid
Ester, the oleoyl epoxide titanate esters of isopropyl three.
The material of main part layer is macromolecule membranous layer, macromolecule membranous layer, thermoplastic elastomer, the macromolecule of the coat of metal
Laminate film layer, polyester fiber cloth, fiberglass cloth or scrim layer.
Described overlays wet-laying waterproof roll with cross-linking reaction layer, and its preparation method is comprised the following steps：First by main body
Material layer and the glue-line that is bonded and sealed are bonded to one by way of hot pressing；Then the mode for the cross-linking reaction layer being sprayed
It is covered in and is bonded and sealed on glue-line.
Described overlays wet-laying waterproof roll with cross-linking reaction layer, and the wet-laying waterproof roll that overlays with cross-linking reaction layer is
The one side of material of main part layer is the structure of glue-line and cross-linking reaction layer of being bonded and sealed, or for the upper and lower surface of main body material layer is equal
Be be bonded and sealed glue-line and cross-linking reaction layer structure.
Described overlays wet-laying waterproof roll with cross-linking reaction layer, also including the isolation on described cross-linking reaction layer
Film layer.
Described separating film layer is polyethylene film, polyvinyl chloride film, polyester film or barrier paper.
Of the invention overlaying coated on wet-laying waterproof roll one layer of crosslinking agent, including the coupling of silane coupler, titanate esters
The mixture of one or more than one in agent or aluminate coupling agent, this composition is for lifting construction system waterproof layer to mixed
The bonding force for coagulating soil serves vital effect, is one of core technology in the present invention, and inventor have passed through substantial amounts of sieve
Select experiment that this crosslinker component is determined.Its principle is as follows：Because concrete is that have building stones to be formed with cement blending solidification, water
Generate hydrated calcium silicate (C-S-H gels) and calcium hydroxide after muddy water, substantial amounts of active Si-OH groups this and band is contained on surface
The oxygen-containing inorganic compound of negative electricity.Silane coupler, titanate coupling agent or aluminate coupling agent can be rolled up with wet-laying waterproof is overlay
Sealing cement layer in material is chemically reacted, and the contact surface to overlaying the sealing cement layer in wet-laying waterproof roll is carried out
Particular functionalization is modified, and allows the active hydroxy group and oxygen-containing inorganic compound of binding material and concrete surface
Learn cross-linking reaction and irreversible chemical covalent bonds are stablized in formation, while forming ion by the electrostatic interaction between zwitterion
Key, i.e. chemisorbed, so that producing, intensity is big, stablize irreversible chemical bonding.It is numerous with reaction just because of these
Property bioactive molecule " bridge " effect and " drawing " effect so that overlay sealing cement layer in wet-laying waterproof roll and mix
The adhesion on solidifying soil surface is far longer than the adhesion of water and concrete surface, then reaches mixed by " bridge " in sealing system
Solidifying soil surface and the moment of aggregate contact, will produce a larger extruding force, this extruding force that concrete surface is adsorbed
Moisture extrusion goes, and makes way for the compositions such as modified pitch, and the moisture content being extruded mutually is assembled, and is coalesced as continuous aqueous phase.Then it is pre-
Mutually adsorbed between sealing cement layer and concrete grout in paving wet-laying waterproof roll, permeated, be finally fused together, interface
Disappear.Concrete surface is wrapped completely by sealing system, and forms chemical action between, ultimately forms floor height bonding
The film of intensity so that waterproof roll sealing system layer form skin with concrete surface as combination, resist with very high
Tensile strength.
It is of the present invention overlay wet-laying waterproof roll increased cross-linking reaction layer after, the cross-linking reaction layer being capable of conduct
Bridge between modified pitch or polymeric pressure sensitive adhesive and concrete interface so that modified pitch or polymeric pressure sensitive adhesive layer with it is mixed
Very firm chemical crosslinking effect is formed between solidifying Soil Interface, relative to the technical scheme for mixing crosslinking agent with pitch, this
One scheme considerably increases the reactivity active area of crosslinking agent so that modified pitch or polymeric pressure sensitive adhesive and concrete
Contact surface can be merged by the crosslinking agent bridge linking effect, significantly increased and overlay wet-laying waterproof roll and concrete ground
The adhesive attraction in face, acquisition is used in mixed way bigger cementation power than pitch and crosslinking agent, reaches more preferably sealing waterproof effect
Really.
The present invention can be realized and the more preferable bond effect of concrete surface, it is adaptable to various pitches or polymeric pressure sensitive adhesive
Overlay wet-laying waterproof roll for adhesive layer primary raw material, range of application is wide, technique effect protrude, greatly avoid because
Be the influence of the factors such as environment moisture and hot ageing, steam expansion, base layer motion, and cause with overlay wet-laying waterproof coiled material construction into it is anti-
Water layer loss of seal waterproof effect.
Brief description of the drawings
Fig. 1 is the structural profile for overlaying wet-laying waterproof roll with cross-linking reaction layer that the embodiment of the present invention 1,4,6 is provided
Figure
Fig. 2 is the structural profile for overlaying wet-laying waterproof roll with cross-linking reaction layer that the embodiment of the present invention 2,3,5 is provided
Figure
Each several part title and sequence number are as follows in figure：
1 is main body material layer, and 2 is the glue-line that is bonded and sealed, and 3 is cross-linking reaction layer, and 4 is separating film layer.
Specific embodiment
As shown in figure 1, ground floor is material of main part layer 1, the second layer is the glue-line 2 that is bonded and sealed, and third layer is cross-linking reaction
Layer 3, bottom is separating film layer 4.
As shown in Fig. 2 ground floor is separating film layer 4, the second layer is cross-linking reaction layer 3, and third layer is the glue-line that is bonded and sealed
2, the 4th layer is material of main part layer 1, and layer 5 is the glue-line 2 that is bonded and sealed, and layer 6 is cross-linking reaction layer 3, and bottom is barrier film
Layer 4.
Embodiment 1
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene film layer, and the second layer is SBS modified asphalt layers,
Third layer is VTES layer, and bottom is polyethylene isolated film layer.
Embodiment 2
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyvinyl chloride isolated film layer, and the second layer is four isopropyls
Base two (dioctyl phosphito acyloxy) metatitanic acid ester layer, third layer is SBR modified asphalt layers, and the 4th layer is polyester fiber cloth, the
Five layers is SBR modified asphalt layers, and layer 6 is aminopropyltriethoxywerene werene layer, and bottom is polyvinyl chloride isolated film layer.
Embodiment 3
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyester isolated film layer, and the second layer is the second of vinyl three
TMOS layer, third layer is SBS modified asphalt layers, and the 4th layer is thermoplastic elastomer, and layer 5 is SBS modified pitch
Layer, layer 6 is VTES layer, and bottom is polyester isolated film layer.
Embodiment 4
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is the macromolecule layer of aluminum metal plating, the second layer be SBS with
SBR blend modified asphalts layer, third layer is two (triethanolamine) metatitanic acid diisopropyl esters and distearyl acyl-oxygen aluminum isopropoxide acid esters
Mixture layer, bottom is polyester isolated film layer.
Embodiment 5
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene isolated film layer, and the second layer is aminopropyl
Triethoxysilane and N- β (aminoethyl)-γ-aminopropyltrimethoxysilane mixture layer, third layer is polymeric pressure sensitive adhesive
Layer, the 4th layer is polyethylene film and polyethylene film mutually laminates film layer, and layer 5 is polymeric pressure sensitive adhesive layer, layer 6
It is VTES layer, bottom is polyethylene isolated film layer.
Embodiment 6
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene film layer, and the second layer is APP modified asphalt layers,
Third layer is vinyltrimethoxy silane layer, and bottom is polyethylene isolated film layer.
Embodiment 7
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyvinyl chloride isolated film layer, and the second layer is four isopropyls
Base two (dioctyl phosphito acyloxy) metatitanic acid ester layer, third layer is SBR modified asphalt layers, and the 4th layer is polyester fiber cloth, the
Five layers is SBR modified asphalt layers, and layer 6 is vinyl three ('beta '-methoxy ethyoxyl) silylation layer, and bottom is polyvinyl chloride isolation
Film layer.
Embodiment 8
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyester isolated film layer, and the second layer is the second of vinyl three
TMOS layer, third layer is SBS modified asphalt layers, and the 4th layer is thermoplastic elastomer, and layer 5 is SBS modified pitch
Layer, layer 6 is, 3-glycidyl ether oxygen propyl trimethoxy silicane and γ-methacryloxypropyl trimethoxy silicon
Alkane mixture layer, bottom is polyester isolated film layer.
Embodiment 9
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is the macromolecule layer of aluminum metal plating, the second layer be APP with
SBR blend modified asphalts layer, third layer is butter of tin and the new caprate mixture layer of hexyl zirconium three of two allyl oxygen, and bottom is poly-
Ester isolated film layer.
Embodiment 10
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene isolated film layer, and the second layer is 2- [(2- ammonia
Base ethyl) amino] ethanol zirconium complex and monoalkoxy unrighted acid titanate esters mixture layer, third layer is macromolecule pressure
Quick glue-line, the 4th layer is polyethylene film and polyethylene film mutually laminates film layer, and layer 5 is polymeric pressure sensitive adhesive layer, the
Six layers is VTES layer, and bottom is polyethylene isolated film layer.
Embodiment 11
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene film layer, and the second layer is SBS modified asphalt layers,
Third layer is distearyl acyl-oxygen aluminum isopropoxide acid esters layer, and bottom is polyethylene isolated film layer.
Embodiment 12
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyvinyl chloride isolated film layer, and the second layer is four isopropyls
Base two (dioctyl phosphito acyloxy) metatitanic acid ester layer, third layer is SBR modified asphalt layers, and the 4th layer is polyester fiber cloth, the
Five layers is SBR modified asphalt layers, and layer 6 is glycolmethacrylate phosphate layer, and bottom is polyvinyl chloride isolated film
Layer.
Embodiment 13
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyester isolated film layer, and the second layer is the second of vinyl three
TMOS layer, third layer is APP modified asphalt layers, and the 4th layer is thermoplastic elastomer, and layer 5 is APP modified pitch
Layer, layer 6 is isooctanol hydrogen basic zirconium phosphate complex layer, and bottom is polyester isolated film layer.
Embodiment 14
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is the macromolecule layer of aluminum metal plating, the second layer be SBS with
APP blend modified asphalts layer, third layer is calcium lignosulfonate and the new caprate mixture layer of hexyl zirconium three of two allyl oxygen, bottom
It is polyester isolated film layer.
Embodiment 15
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene isolated film layer, and the second layer is double (two pungent oxygen
Base pyrophosphoric acid ester group) ethylene titanate esters and N- β (aminoethyl)-γ-aminopropyltrimethoxysilane mixture layer, third layer is high
Molecule pressure-sensitive adhesive layer, the 4th layer is polyethylene film and polyethylene film mutually laminates film layer, and layer 5 is pressure-sensitive macromolecule
Glue-line, layer 6 is VTES layer, and bottom is polyethylene isolated film layer.
Embodiment 16
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene isolated film layer, and the second layer is distearyl
Oxygen isopropoxy Aluminate and isopropyl three (N- β-aminoethyl-β-aminoethyl) titanate esters mixture layer, third layer is macromolecule
Pressure-sensitive adhesive layer, the 4th layer is polyethylene film and polyethylene film mutually laminates film layer, and layer 5 is polymeric pressure sensitive adhesive layer,
Layer 6 is VTES layer, and bottom is polyethylene isolated film layer.
Embodiment 17
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene film layer, and the second layer is No. 70 asphalt floor,
Third layer is DBSA zirconium complex layer, and bottom is polyethylene isolated film layer.
Embodiment 18
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyvinyl chloride isolated film layer, and the second layer is alkyl third
Olefin(e) acid ester phosphate layer, third layer is SBR modified asphalt layers, and the 4th layer is polyester fiber cloth, and layer 5 is SBR modified pitch
Layer, layer 6 is aminopropyltriethoxywerene werene layer, and bottom is polyvinyl chloride isolated film layer.
Embodiment 19
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyester isolated film layer, and the second layer is the second of vinyl three
TMOS layer, third layer is SBS modified asphalt layers, and the 4th layer is thermoplastic elastomer, and layer 5 is SBS modified pitch
Layer, layer 6 is the dioctyl pyrophosphate metatitanic acid ester layer of isopropyl three, and bottom is polyester isolated film layer.
Embodiment 20
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is the macromolecule layer of aluminum metal plating, and the second layer is SBS, APP
With SBR blend modified asphalts layer, third layer is rare earth aluminic acid ester coupling agent and tin coupling agent mixture layer, and bottom is polyester isolation
Film layer.
Embodiment 21
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is polyethylene isolated film layer, and the second layer is zirconium coupling agent
With lignin coupling agent mixture layer, third layer is polymeric pressure sensitive adhesive layer, and the 4th layer is polyethylene film and polyethylene film
Mutually laminate film layer, layer 5 is polymeric pressure sensitive adhesive layer, and layer 6 is VTES layer, and bottom is poly- second
Alkene isolated film layer.
Embodiment 22
Technical performance index is contrasted
By surface spraying, direct mixed cross-linker aminopropyltriethoxywerene werene and anti-without overlaying for crosslinking agent
Water coiled material is using comparing, and its comparing result is as shown in table 1.
The technical performance index of table 1 is contrasted
The structure for overlaying wet-laying waterproof roll is as follows：Ground floor is azide polymer press mold layer, and the second layer is that SBS and APP is total to
Mixed modification bitumen layer, third layer is VTES, tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters
With distearyl acyl-oxygen aluminum isopropoxide acid ester mixtures layer, bottom is polyester isolated film layer.
Technical performance：
Its peel strength is more than 2 times of national standard to product of the invention on inspection, other performances meet GB/23457-
2009 require.
Mechanics of the invention, physics, chemical property Testing index (see table 2 below, table 3)：
Table 2 overlays waterproof roll index
The wet-laying waterproof roll physical and mechanical property of table 3
Claims (11)
1. it is a kind of to overlay wet-laying waterproof roll, including material of main part layer with cross-linking reaction layer（1）, be bonded and sealed glue-line（2）With
Cross-linking reaction layer（3）, it is characterised in that：The glue-line that is bonded and sealed（2）It is asphalt layer, modified asphalt layer or high score
Sub- pressure-sensitive adhesive layer, the cross-linking reaction layer（3）For silane coupler, bimetallic coupling agent, lignin coupling agent, tin coupling agent,
The mixture layer of one or more of zirconium coupling agent, phosphate coupling agent, rare-earth coupling agent；Material of main part layer（1）Upper one side is
Be bonded and sealed glue-line（2）Or upper and lower surface is the glue-line that is bonded and sealed（2）, be bonded and sealed glue-line（2）On for cross-linking reaction layer
（3）.
2. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1, it is characterised in that：Described oil
The asphalt that bitumen layer is used is 70~No. 120 asphalt.
3. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1, it is characterised in that：Described is modified
The modified pitch that bitumen layer is used is one or several in SBS modified pitch, APP modified pitch, SBR modified pitch
Blend.
4. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1, it is characterised in that：The macromolecule
Pressure-sensitive adhesive layer with polymeric pressure sensitive adhesive be rubber by the pressure sensitive adhesive that is formed after mixed refining process.
5. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1, it is characterised in that：Described silane
Coupling agent includes VTES, aminopropyltriethoxywerene werene, vinyltrimethoxy silane, vinyl three
Ethoxysilane, vinyl three（'beta '-methoxy ethyoxyl）Silane, N-（β-aminoethyl）- α aminopropyl trimethoxysilanes,
N—（β-aminoethyl）- γ-aminopropyl triethoxysilane, 3-glycidyl ether oxygen propyl trimethoxy silicane, 2-（3,
4-7-oxa-bicyclo[4.1.0 base）Ethyl trimethoxy silane, γ-methacryloxypropyl trimethoxy silane；
Described lignin coupling agent includes sodium lignin sulfonate and calcium lignosulfonate；
Described tin coupling agent includes butter of tin；
Described zirconium coupling agent includes DBSA zirconium complex, neodecanoic acid zirconium complex, isooctanol hydrogen basic zirconium phosphate network
Compound, 2- [(2- amino-ethyls) amino] ethanol zirconium complex, the new caprate of hexyl zirconium three of two allyl oxygen；
Described phosphate coupling agent includes methylacryoyloxyethyl phosphate, glycolmethacrylate phosphate, alkane
Base acrylate phosphate, polyfunctionality acid acrylate；
Described rare-earth coupling agent includes rare earth aluminic acid ester coupling agent, rare earth titanate coupling agent.
6. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 5, it is characterised in that：
Described rare earth aluminic acid ester coupling agent includes distearyl acyl-oxygen aluminum isopropoxide acid esters；
Described rare earth titanate coupling agent includes the oleic acid acyloxy of isopropyl two（Dioctylphyrophosphoric acid acyloxy）It is titanate esters, different
Propyl group three（Dioctyl phosphoric acid acyloxy）It is titanate esters, monoalkoxy unrighted acid titanate esters, double（Two octyloxy pyrophosphates
Base）It is ethylene titanate esters and triethanolamine chelate, double（Two octyloxy pyrophosphoric acid ester groups）Ethylene titanate esters, plant acid type list alcoxyl
Base class titanate esters, isopropyl three (dodecyl benzenesulfonyl) titanate esters, isopropyl three（Dioctylphosphoric acid ester）Acid esters, tetra isopropyl
Diphosphorous acid dioctyl ester titanate esters, the dioctyl pyrophosphate titanate esters of isopropyl three, isopropyl three（Capryl）Titanate esters, isopropyl
Three (N- β-aminoethyl-β-aminoethyl) titanate esters, isopropyl three [N- β-（Aminoethyl）First-aminoethyl] titanate esters, isopropyl
Three oleoyl epoxide titanate esters.
7. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1, it is characterised in that：The main body material
The bed of material（1）It is the macromolecule membranous layer of the coat of metal, thermoplastic elastomer, polyester fiber cloth, fiberglass cloth or grid
Layer of cloth.
8. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1, it is characterised in that its preparation method
Comprise the following steps：First by material of main part layer（1）With the glue-line that is bonded and sealed（2）It is bonded to one by way of hot pressing；Then
By cross-linking reaction layer（3）The glue-line that is bonded and sealed is covered in the mode of spraying（2）On.
9. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1~8 any one, its feature exists
In：Wet-laying waterproof roll is overlay for main body material layer with cross-linking reaction layer（1）One side be the glue-line that is bonded and sealed（2）And crosslinking
Conversion zone（3）Structure, or be main body material layer（1）Upper and lower surface be the glue-line that is bonded and sealed（2）With cross-linking reaction layer
（3）Structure.
10. wet-laying waterproof roll is overlay with cross-linking reaction layer as described in claim 1~8 any one, its feature exists
In：Also include described cross-linking reaction layer（3）On separating film layer（4）.
11. overlay wet-laying waterproof roll as described in claim 10 with cross-linking reaction layer, it is characterised in that：It is described every
From film layer（4）It is polyethylene film, polyvinyl chloride film, polyester film or barrier paper.
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| CN108374566B (en) * | 2018-02-06 | 2020-10-02 | 厦门防水博士建筑工程有限公司 | Repairing process for leakage water on back water surface |
| CN111608208B (en) * | 2020-05-19 | 2022-01-11 | 浙江鲁班建材科技股份有限公司 | Time-controllable water-absorbing expansion leakage-stopping pre-paved coiled material |
| CN111744553B (en) * | 2020-07-23 | 2021-12-03 | 江南大学 | Zirconium dodecylbenzene sulfonate catalyst and application thereof in furfuryl alcohol alcoholysis reaction |
| CN116444907B (en) * | 2023-06-15 | 2023-08-18 | 山东恒旺新材料科技有限公司 | Chlorinated polyethylene waterproof coiled material |
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| CN101871248A (en) * | 2010-05-31 | 2010-10-27 | 广东科顺化工实业有限公司 | Reactive polymer waterproofing coiled material |
| CN204605052U (en) * | 2013-11-05 | 2015-09-02 | 广西金雨伞防水装饰有限公司 | Wet paving waterproof roll is overlay with cross-linking reaction layer |
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| US7037864B2 (en) * | 2001-08-22 | 2006-05-02 | Denis Faucher | Integral waterproofing membrane |
| WO2011139692A1 (en) * | 2010-04-28 | 2011-11-10 | W.R. Grace & Co.-Conn. | Waterproofing membrane |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101871248A (en) * | 2010-05-31 | 2010-10-27 | 广东科顺化工实业有限公司 | Reactive polymer waterproofing coiled material |
| CN204605052U (en) * | 2013-11-05 | 2015-09-02 | 广西金雨伞防水装饰有限公司 | Wet paving waterproof roll is overlay with cross-linking reaction layer |
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Denomination of invention: A pre-paving wet-paving waterproof coiled material with a crosslinking reaction layer Effective date of registration: 20171206 Granted publication date: 20170616 Pledgee: Guangxi Beibu Bay bank Limited by Share Ltd. Nanhu branch of Nanning City Pledgor: Lu Guicai|Guangxi Golden Umbrella Waterproofing Co.,Ltd. Registration number: 2017450000014 |
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Address after: 530001 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region, Lin18 Sunshine Green City, 1 Building, 1 Unit 4 Patentee after: Xiniupi Waterproof Technology Co.,Ltd. Address before: 530001 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region, Lin18 Sunshine Green City, 1 Building, 1 Unit 4 Patentee before: Guangxi Golden Umbrella Waterproofing Co.,Ltd. |
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Change date: 20190409 Registration number: 2017450000014 Pledgor after: West Cattle Leather Waterproof Decoration Co.,Ltd. Pledgor after: Lu Guicai Pledgor before: GUANGXI GOLDEN UMBRELLA WATERPROOFING Co.,Ltd. Pledgor before: Lu Guicai |
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Date of cancellation: 20190415 Granted publication date: 20170616 Pledgee: Guangxi Beibu Bay bank Limited by Share Ltd. Nanhu branch of Nanning City Pledgor: West Cattle Leather Waterproof Decoration Co.,Ltd.|Lu Guicai Registration number: 2017450000014 |
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Application publication date: 20160518 Assignee: Xiniu leather waterproof technology (Qinzhou) Co.,Ltd. Assignor: Xiniupi Waterproof Technology Co.,Ltd. Contract record no.: X2021980006621 Denomination of invention: Pre laid wet laid waterproof coiled material with crosslinking reaction layer Granted publication date: 20170616 License type: Common License Record date: 20210722 |
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Application publication date: 20160518 Assignee: Xiniu leather waterproof technology (Qinzhou) Co.,Ltd. Assignor: Xiniupi Waterproof Technology Co.,Ltd. Contract record no.: X2024980008205 Denomination of invention: Pre laid wet laid waterproof membrane with cross-linked reaction layer Granted publication date: 20170616 License type: Common License Record date: 20240627 |
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