CN102434776A - High-pressure gas cylinder for gas carrier - Google Patents
High-pressure gas cylinder for gas carrier Download PDFInfo
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- CN102434776A CN102434776A CN2011104203694A CN201110420369A CN102434776A CN 102434776 A CN102434776 A CN 102434776A CN 2011104203694 A CN2011104203694 A CN 2011104203694A CN 201110420369 A CN201110420369 A CN 201110420369A CN 102434776 A CN102434776 A CN 102434776A
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- Prior art keywords
- gas cylinder
- inner bag
- fortune car
- car according
- warm area
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002131 composite material Substances 0.000 claims abstract description 32
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 12
- 239000010959 steel Substances 0.000 claims abstract description 12
- 230000001681 protective effect Effects 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims abstract description 8
- 229920002635 polyurethane Polymers 0.000 claims abstract description 8
- 239000004593 Epoxy Substances 0.000 claims abstract description 6
- 239000011521 glass Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 238000004804 winding Methods 0.000 claims description 10
- 239000003365 glass fiber Substances 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 238000007711 solidification Methods 0.000 claims description 4
- 230000008023 solidification Effects 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000009987 spinning Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 238000007789 sealing Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 51
- 230000001070 adhesive effect Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000007590 electrostatic spraying Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
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- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
The invention provides a high-pressure gas cylinder for a gas carrier, which comprises a cylinder body section positioned in the middle, two bottle openings respectively positioned at two ends and a sealing head for connecting the cylinder body section and the bottle openings, wherein the wall of the high-pressure gas cylinder sequentially comprises the following components from inside to outside: an inner container made of steel; a bond coat made of a polyurethane material; a composite layer made of a glass fiber-epoxy system composite; and an outer protective film. The invention has the following beneficial effects: the composite material layer of the steel inner container and the glass fiber-epoxy system is adopted, so that the fatigue performance and the impact resistance are good, and the special requirements of the high-pressure gas cylinder for the gas carrier are met; the outer protective film is wrapped outside the composite material layer, so that the phenomenon that the outer surface of the composite material layer is corroded by moisture in the air and substances with corrosion properties to influence the performance of the gas cylinder is avoided.
Description
Technical field
The present invention relates to gas cylinder and make the field, relate in particular to a kind of gas cylinder that is used on the fortune car.
Background technique
Along with popularizing and development of CNG automobile, high pressure transportation gas semitrailer is being brought into play more and more important effect in the transportation of CNG gas.Using at present more is the CNG long-tube trailer, and the long-tube trailer gas cylinder belongs to super-huge control steel cylinder, on each trailer surplus several or ten a fixed set be contained on the trailer, be used for storing transportation gas.Because long-tube trailer is big with control steel cylinder useful load, raw material are required height, make also relatively difficulty, need some main equipments.Simultaneously, receive the restriction of vehicle weight and volume design, the fortune amount of each trailer also is restricted.
So; People put into sight on the composite material gas cylinder; With common with compressed natural gas as the vehicle CNG storage tank of the energy different be; The fortune vehicle gas cylinder requires higher to its fatigue behaviour, charge and discharge gas every day more than 2 times, and the temperature variation of gas when filling and discharge also is a test to the performance of gas cylinder; In addition; Because what the fortune car adopted mostly is semi-trailer; So be placed in the space of boot or other sealings with gas cylinder unlike the CNG automobile, fortune car gas cylinder is directly exposed, so it is higher with the Capability Requirement of resisting chemical corrosion that the gas cylinder outer surface is born mechanical deterioration.
Summary of the invention
The object of the present invention is to provide a kind of fatigue capability, the gas cylinder that is used for the fortune car that anti-physical impacts and chemical corrosion resistance are good.
The object of the invention is realized through following technological scheme is provided:
A kind of gas cylinder that is used for the fortune car comprises the shell portion that is positioned at the middle part, lays respectively at two bottlenecks at two ends and the end socket of connecting cylinder figure and bottleneck, and the wall of said gas cylinder comprises from inside to outside successively: the inner bag that is formed from steel; The combination coating of processing by polyurethane material; By the composite layer that glass fibre-the epoxy systems composite material is processed; Outer protective film.
Preferably, said inner bag is shaped by the mode of chrome molybdenum steel pipe with spinning closing-in.
Preferably, said inner bag is heat-treated after shaping according to the following steps: inner bag is put into oven, be heated to 860 ℃ to 910 ℃ and be incubated 40 minutes to 60 minutes; In water-soluble quenching liquid, cool off, carry out temper then.
Preferably, said combination coating forms for adopting electrostatic spraying technology that polyurethane powder coating evenly is sprayed at the inner bag surface, and thickness is greater than 60 μ m.
Preferably, said composite layer is surperficial by outside the tank, and the glass fibre that resin matrix has been flooded in use carries out the hoop winding, multilayer covers and forms, and soaks on the glass fibre that resin matrix is arranged during winding to be applied with preset tension force.
Preferably, in the said composite layer, the centre has 2 to 6 layers for medial axis 60 ° to the 80 ° spirals of one-tenth with respect to said gas cylinder are entwined, and other each layers are entwined for hoop.
Preferably; Gas cylinder after the said winding is cured by following mode: gas cylinder is put into continuous curing oven; In first warm area, second warm area and triple temperature region, be cured successively, the temperature of said first warm area is lower than second warm area, and the temperature of triple temperature region is lower than first warm area; In solidification process, keep the horizontal rotation of gas cylinder.
Preferably, the first warm area temperature is 90 ℃ to 110 ℃, and the second warm area temperature is 130 ℃ to 140 ℃, and the triple temperature region temperature is 70 ℃ to 90 ℃, 4.5 hours to 6.5 hours total curing time.
Preferably, the gas cylinder after the said curing carries out the tight and inwall oven dry processing from setting-out.
Preferably; The outer protective film of said gas cylinder is a thermo-contract film, and the parcel step of said thermo-contract film is following: the thermo-contract film of tubular is enclosed within shell portion, moves in 135 ℃ to 140 ℃ the infrared heating case; After 1 minute to 2 minutes, said gas cylinder is shifted out the infrared heating case.
Preferably, the volume of said gas cylinder is 200L to 400L, and working pressure arrives 35MPa at 25MPa.
Beneficial effect of the present invention is mainly reflected in:
Adopt the inner bag of steel and the composite layer of glass fibre-epoxy systems, fatigue behaviour and shock-resistant ability are good, satisfy the specific (special) requirements of the automobile-used gas cylinder of fortune;
Adopt the special thermal treatment means to handle inner bag, make inner bag have excellent stable mechanical property;
Adopt polyurethane material as combining coating, thickness is big and guaranteed the combining closely property and the adhesive property of inner bag and composite layer to make the stressed coordination more of inner bag and composite layer, and adhesive shear strength is greater than 40MPa;
The composite material layer segment adopts spiral to twine, and makes glass fibre can carry a part of axial strength, improves the working life of gas cylinder;
Gas cylinder keeps horizontal rotation when in curing oven, solidifying; Guaranteed surface quality of products; The aathermoset resin system that makes solidification process takes place crosslinked, given combination properties such as composite layer anti-shearing, anticorrosive, chemical stability and transmission fiber stress to a certain degree; Warm area setting during curing comprises the 3rd temperature that temperature is lower, and the composite layer after guaranteeing to solidify is progressively lowered the temperature, and avoids direct air cooling to cause resin fragility to increase.
The composite layer outerwrap outer protective film, the material of avoiding airborne moisture and having a corrosion property corrodes the composite layer outer surface, influences gas cylinder performance and working life; Adopt infrared heating case heat shrink, the parcel gas cylinder has avoided using the moulding of the outer protective film of hot blast influence of a conventional oven, makes the surface that is wrapped in gas cylinder that it can be firm.
Description of drawings
Below in conjunction with accompanying drawing technological scheme of the present invention is described further:
Fig. 1 is the schematic representation of the gas cylinder of specific embodiment of the present invention.
Embodiment
As shown in Figure 1, this gas cylinder that is used for the fortune car is a kind of steel inner bag glass fibre hoop winding gas cylinder, and volume uses working pressure between 25MPa ~ 35MPa at 200 L ~ 400L.Gas cylinder comprises the shell portion that is positioned at the middle part, lays respectively at two bottlenecks at two ends and the end socket of connecting cylinder figure and bottleneck, and its wall comprises from inside to outside successively: the inner bag 1 that is formed from steel; The combination coating of processing by polyurethane material 2; By the composite layer 3 that glass fibre-the epoxy systems composite material is processed; Outer protective film.
Inner bag 1 is shaped by the mode of chrome molybdenum steel pipe with spinning closing-in, and it provides the space for storing compressed natural gas, directly contacts with filling medium, plays the sealing effect of holding one's breath, and bears the pressure of a part.Inner bag 1 need be heat-treated after shaping, and step is: inner bag is put into oven, be heated to 860 ℃ to 910 ℃ and holding time 40 minutes to 60 minutes; In water-soluble quenching liquid, cool off, carry out temper then.This heat treatment mode can improve the mechanical property of inner bag significantly, and the metallographic structure of inner bag is a tempered sorbite after the heat treatment, and the overall performance good uniformity is no more than 40MPa with intraindividual tensile strength deviation between the inner bag individuality, and specific elongation reaches more than 12%.
Go out to satisfy the screw thread of size and required precision on the inner bag 1 with lathe in machining.
Preservative treatment is carried out on the surface of inner bag 1, adopts the mode of electrostatic spraying to spray paint, and has effectively guaranteed uniformity, conformity and the good glossiness of inner bag 1 surperficial paint film.
Form for adopting electrostatic spraying technology that polyurethane powder coating evenly is sprayed at inner bag 1 surface in conjunction with coating 2, thickness is greater than 60 μ m.Adopt polyurethane material as combining coating 2, thickness is big and guaranteed the combining closely property and the adhesive property of inner bag and composite layer to make the stressed coordination more of inner bag and composite layer, and adhesive shear strength is greater than 40MPa.
Composite layer 3 is used the glass fibre that has flooded resin matrix to carry out hoop and is entwined by the outer surface at inner bag 1, soaks on the glass fibre that resin matrix is arranged during winding to be applied with preset tension force.In concrete the winding; At first load onto at the two ends of inner bag 1 and Stetch Wrapping Machine, the supporting frock of curing oven, behind high strength glass fiber insulating varnish matrix, preset certain force of strain is wrapped on the cylindrical shell of inner bag 1; Design shop layer thickness according to gas cylinder; Hoop twines, multilayer covers, and the centre can have 2 to 6 layers for medial axis 60 ° to the 80 ° spirals of one-tenth with respect to said gas cylinder are entwined, and other each layers are entwined for hoop.Fiber can carry the axial strength of a part, the working life of effectively improving gas cylinder like this.
Gas cylinder after the winding is cured by following mode: gas cylinder is put into continuous curing oven; In first warm area, second warm area and triple temperature region, be cured successively; The temperature of first warm area is lower than second warm area; The temperature of said triple temperature region is lower than first warm area and second warm area, and the composite layer after guaranteeing like this to solidify is progressively lowered the temperature, and avoids direct air cooling to cause resin fragility to increase; In solidification process, keep the horizontal rotation of gas cylinder, can access gas cylinder surface quality preferably like this.Concrete, the first warm area temperature is 90 ℃ to 110 ℃, and the second warm area temperature is 130 ℃ to 140 ℃, and the triple temperature region temperature is 70 ℃ to 90 ℃, and total curing time is between 4.5 hours to 6.5 hours.
Generally, solidify that aathermoset resin system is taken place is crosslinked, given composite layer 3 anti-shearing, anticorrosive, chemical stability and transmission fiber stress to a certain degree etc.
Gas cylinder after the curing need do the self-tightening hydrostatic test and the inwall oven dry is handled.
Owing to have part to be exposed in the air after gas cylinder is installed, so composite layer 3 needs effective and efficient manner is protected influences gas cylinder to prevent the composite layer surface from being corroded performance.For this reason, the gas cylinder surface is provided with aforesaid outer protective film, and it adopts thermo-contract film to be wrapped to form; Step is following: the thermo-contract film of tubular is enclosed within shell portion; Move into 135 ℃ to 140 ℃ baking oven, be preferably in the infrared heating case, after 1 minute to 2 minutes; Said gas cylinder is shifted out baking oven, be preferably the infrared heating case.
This thermo-contract film adopts macromolecule orientation principle that is heated, can be very docile under suitable temperature, and the firm surface that is wrapped in gas cylinder, the material that prevents airborne moisture and have a corrosion property corrodes the composite layer outer surface; And use the heating of infrared heating case, avoided the moulding of the outer protective film of hot blast influence of use a conventional oven.Thermo-contract film parcel step is positioned over after the oven dry of self-tightening hydraulic pressure, can also cover the inevitable circumferential crack that produces in self-tightening hydraulic pressure gas cylinder surface, the surface of protection gas cylinder.
The present invention is not limited to aforementioned embodiments, and those skilled in the art also possibly make other changes, but as long as function and the present invention of its realization are same or similar, all should belong to protection scope of the present invention under the enlightenment of technical spirit of the present invention.
Claims (10)
1. gas cylinder that is used for the fortune car comprises the shell portion that is positioned at the middle part, lays respectively at two bottlenecks at two ends and the end socket of connecting cylinder figure and bottleneck, and it is characterized in that: the wall of said gas cylinder comprises from inside to outside successively: the inner bag that is formed from steel; The combination coating of processing by polyurethane material; By the composite layer that glass fibre-the epoxy systems composite material is processed; Outer protective film.
2. the gas cylinder that is used for the fortune car according to claim 1 is characterized in that, said inner bag is shaped by the mode of chrome molybdenum steel pipe with spinning closing-in.
3. the gas cylinder that is used for the fortune car according to claim 2 is characterized in that, said inner bag is heat-treated after shaping according to the following steps:
Inner bag is put into oven, be heated to 860 ℃ to 910 ℃ and be incubated 40 minutes to 60 minutes;
In water-soluble quenching liquid, cool off, carry out temper then.
4. the gas cylinder that is used for the fortune car according to claim 3 is characterized in that, said combination coating forms for adopting electrostatic powder coating evenly to spray on the inner bag surface, and thickness is greater than 60 μ m.
5. the gas cylinder that is used for the fortune car according to claim 4; It is characterized in that; Said composite layer is surperficial by outside the tank; The glass fibre that resin matrix has been flooded in use carries out the hoop winding, multilayer covers and forms, and soaks on the glass fibre that resin matrix is arranged during winding to be applied with preset tension force.
6. the gas cylinder that is used for the fortune car according to claim 5 is characterized in that, in the said composite layer, the centre has 2 to 6 layers for medial axis 60 ° to the 80 ° spirals of one-tenth with respect to said gas cylinder are entwined, and other each layers are entwined for hoop.
7. the gas cylinder of air-powered car according to claim 5; It is characterized in that; Gas cylinder after the said winding is cured by following mode: gas cylinder is put into continuous curing oven; In first warm area, second warm area and triple temperature region, be cured successively, the temperature of said first warm area is lower than second warm area, and the temperature of triple temperature region is lower than first warm area; In solidification process, keep the horizontal rotation of gas cylinder.
8. the gas cylinder that is used for the fortune car according to claim 7 is characterized in that, the gas cylinder after the said curing carries out the tight and inwall oven dry processing from setting-out.
9. the gas cylinder that is used for the fortune car according to claim 8; It is characterized in that; The outer protective film of said gas cylinder is a thermo-contract film, and the parcel step of said thermo-contract film is following: the thermo-contract film of tubular is enclosed within shell portion, moves in 135 ℃ to 140 ℃ the infrared heating case; After 1 minute to 2 minutes, said gas cylinder is shifted out the infrared heating case.
10. according to the gas cylinder that is used for the fortune car described in the claim 1, it is characterized in that: the volume of said gas cylinder is 200L to 400L, and working pressure arrives 35MPa at 25MPa.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2011104203694A CN102434776A (en) | 2011-12-15 | 2011-12-15 | High-pressure gas cylinder for gas carrier |
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CN2011104203694A CN102434776A (en) | 2011-12-15 | 2011-12-15 | High-pressure gas cylinder for gas carrier |
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CN102434776A true CN102434776A (en) | 2012-05-02 |
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CN2011104203694A Pending CN102434776A (en) | 2011-12-15 | 2011-12-15 | High-pressure gas cylinder for gas carrier |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105690039A (en) * | 2016-04-05 | 2016-06-22 | 山东天海高压容器有限公司 | Preparation method of high-pressure seamless steel cylinder |
CN109476416A (en) * | 2016-03-30 | 2019-03-15 | 康斯坦丁·弗拉基米罗维奇·索罗金 | Transport and the method for storing the case of gas cylinder and placing gas cylinder in case |
CN112108840A (en) * | 2020-09-07 | 2020-12-22 | 东风汽车股份有限公司 | Manufacturing method of light truck 80L compressed natural gas normal-temperature high-pressure gas cylinder |
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CN1529083A (en) * | 2003-09-30 | 2004-09-15 | 中材科技股份有限公司 | Fiber-winding composite material pressure vessel and manufacturing method thereof |
CN101029707A (en) * | 2007-03-21 | 2007-09-05 | 重庆汽车研究所 | Circular winding layer reinforced CNG air bottle of steel lining fibre material for vehicle and its production |
CN101187441A (en) * | 2007-12-28 | 2008-05-28 | 石家庄安瑞科气体机械有限公司 | Method for manufacturing ultrahigh pressure hydrogen cylinder |
CN102011933A (en) * | 2010-09-29 | 2011-04-13 | 沈阳斯林达安科新技术有限公司 | Hydrogen aluminum alloy inner container carbon fiber fully-winding gas cylinder for vehicle and production process thereof |
-
2011
- 2011-12-15 CN CN2011104203694A patent/CN102434776A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1529083A (en) * | 2003-09-30 | 2004-09-15 | 中材科技股份有限公司 | Fiber-winding composite material pressure vessel and manufacturing method thereof |
CN101029707A (en) * | 2007-03-21 | 2007-09-05 | 重庆汽车研究所 | Circular winding layer reinforced CNG air bottle of steel lining fibre material for vehicle and its production |
CN101187441A (en) * | 2007-12-28 | 2008-05-28 | 石家庄安瑞科气体机械有限公司 | Method for manufacturing ultrahigh pressure hydrogen cylinder |
CN102011933A (en) * | 2010-09-29 | 2011-04-13 | 沈阳斯林达安科新技术有限公司 | Hydrogen aluminum alloy inner container carbon fiber fully-winding gas cylinder for vehicle and production process thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109476416A (en) * | 2016-03-30 | 2019-03-15 | 康斯坦丁·弗拉基米罗维奇·索罗金 | Transport and the method for storing the case of gas cylinder and placing gas cylinder in case |
CN105690039A (en) * | 2016-04-05 | 2016-06-22 | 山东天海高压容器有限公司 | Preparation method of high-pressure seamless steel cylinder |
CN105690039B (en) * | 2016-04-05 | 2018-01-19 | 山东天海高压容器有限公司 | The preparation method of high-pressure seamless steel cylinder |
CN112108840A (en) * | 2020-09-07 | 2020-12-22 | 东风汽车股份有限公司 | Manufacturing method of light truck 80L compressed natural gas normal-temperature high-pressure gas cylinder |
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Application publication date: 20120502 |