CN102421876A

CN102421876A - Extraction of hydrocarbons from hydrocarbon-containing materials and/or processing of hydrocarbon-containing materials

Info

Publication number: CN102421876A
Application number: CN2009801592776A
Authority: CN
Inventors: 范良正; 穆罕默德·里扎·莎菲; 朱立尔斯·麦可·陶拉斯; 威廉·亚瑟·菲兹胡格·李
Original assignee: GREEN ENERGY CO Ltd
Current assignee: GREEN ENERGY CO Ltd; Green Source Energy LLC
Priority date: 2009-03-13
Filing date: 2009-03-13
Publication date: 2012-04-18
Anticipated expiration: 2029-03-13
Also published as: TW201038772A; MA33192B1; SG174325A1; AU2009341831B2; ZA201107482B; WO2010104944A8; CA2755215C; UA104886C2; AU2010224244B2; TWI491765B; AU2009341831A1; EA201101295A1; AP2011005920A0; GEP20166471B; IL215124A; KR101629753B1; PE20140775A1; NZ595324A; WO2010104944A2; JP5792077B2

Abstract

A method of extracting hydrocarbon-containing organic matter from a hydrocarbon-containing material includes the steps of providing a first liquid comprising a turpentine liquid; contacting the hydrocarbon-containing material with the turpentine liquid to form an extraction mixture; extracting the hydrocarbon material into the turpentine liquid; and separating the extracted hydrocarbon material from a residual material not extracted.

Description

From hydrocarbon-containing feedstock, extract the processing of hydrocarbon and/or hydrocarbon-containing feedstock

Technical field

The present invention relates to extract the field of hydrocarbon from hydrocarbon-containing feedstock.

Background technology

The mineral fuel (individually and jointly being called mineral fuel later on) of solid, semisolid, high sticking or viscous form are also referred to as the hydrocarbonaceous organic substance, its liquefaction, dissolving and/or extract and verifiedly have challenge and be difficulty very.As used herein; These mineral fuel comprise; But be not limited to the hydrocarbonaceous organic substance in coal, resinous shale, Tar sands and oil-sand (being called Tar sands later on jointly) and crude oil, heavy crude or extra-heavy oil, Sweet natural gas and petroleum gas, crude asphalt, petrologen, rock asphalt and/or the bituminous matter.Reason of difficulty partly is that these mineral fuel comprise the complicated organic polymer that is connected with sulfide linkage by oxygen, and they usually are embedded in the matrix of mineral compound.Because the demand of alkyl material increases with consuming constantly, there is the demand that other being used to made liquids and gases fuel and be used to produce the liquid hydrocarbons feedstocks of various chemistry, medicine and engineering materials of producing.

Develop many kind technology or technology and liquefied, dissolved and/or extracted mineral fuel.Yet the scale operation that does not have a kind of liquefaction, dissolving and extractive technique to be proved to be for all types mineral fuel in the prior art is commericially feasible.This is because the realization of the prior art of liquefaction, dissolving or the extraction of the hydro carbons of up to the present developing that is useful on and technology and operation all are very expensive.In addition, the prior art processes and the technology that are used for liquefaction, dissolving and/or the extraction of hydro carbons are difficult to enlargement of scale, operation and/or control owing to one or more of underlying cause: operate under very high pressure (1); (2) under very high temperature, operate; (3) need expensive process vessel with need be under extreme condition the device of outside hydrogen supply; (4) to contact the mixture of two or more reagent, catalyzer and/or auxiliary agent, or compsn, these materials usually are highly toxic, and non-renewable or recycle; (5) need supply the energy of special shape, for example, microwave irradiation; (6) very long process period for partial liquefaction, dissolving or extraction; (7) needing size be the especially fine particle of about 200 orders (0.074mm), for manufacturing and disposal be the devil with expensive; And (8) can not gather and essential reagent, catalyzer and/or the auxiliary agent of recycle.The RF that therefore, need provide other technology and technology to be used to improve hydrocarbon materials.

Small-scale experiment of past has shown that the solvent that the d-PC 560 can be used as hydrocarbon-containing feedstock plays a role.Yet d-PC 560 only part successfully dissolves hydrocarbon-containing feedstock.And because the d-PC 560 extracts from citrus fruit peel, it is can the acquisition amount limited, and is higher than cost with other solvent phase.

Other solvent that uses in the past comprises basic soln and alcohol-water mixture.Because hydrocarbon solubleness is little in aqueous solution, these compsns are useful a little in the dissolving hydrocarbon material.

The material that other art methods utilizes toluene and/or YLENE that paraffinic hydrocarbons and viscous crude cannot be liquefied as stickingly again.The carcinogenic chemical of this one or more evaporable of method use, danger close is liquefaction train alkane again.These products are polluted underground water and must handling according to the secure data indumentum of each chemical substance extremely careful the potentially.Cause the settling leakage in flow line or hold tank in case these products volatilize again, paraffinic hydrocarbons and viscous crude are returned to their original states.

" acid " hydrocarbon-containing feedstock contains by weight the sulphur greater than about 0.5%." acid " gas contains the H above 4ppm ₂S and other sulfonation gaseous substance.This sulphur can include but not limited to that forms such as sulfide, disulphide, thio-alcohol, thiophene-based, benzothiophene kind exist with free elementary sulfur, hydrogen sulfide and various other sulphur compound.Each starting material or crude gas contain different amounts or dissimilar sulphur compounds, but typically in heavier crude oil level is divided the ratio of sulphur compound, complicacy and stability maximum.Hydrogen sulfide is because poisonous insalubrity.And hydrogen sulfide can produce sulfuric acid, sulfuric acid corrosion equipment, pipeline, hold tank etc. with the water reaction.Therefore, the hydrocarbonaceous material of those reactive sulfur-bearings should be important to reduce corrosive nature and to avoid the health risk relevant with the hydrocarbonaceous material of untreated sulfur-bearing by modification.

Bore operation for tentatively adopting; It will be useful adopting following technology; Promptly increase dissolving and promote the motion of hydrocarbonaceous organic substance other or trap (trapped), make existing pressure gradient force the hydrocarbonaceous organic substance then through boring this hydrocarbonaceous organic substance of gathering.Particularly, to bore the heavier hydrocarbon that the operation dissolving usually remains in the oil reservoir (reservoir) will be useful through tentatively adopting.

For secondary and TOR or improve the RF operation, it will be useful adopting following technology, promptly increase oily dissolving with the mode that reduces cost and the do not damage oil reservoir hydrocarbonaceous organic substance in the oil reservoir of gathering.Although have the effective ways and the compsn that are used for the TOR operation, because running cost is compared with the value of the hydrocarbonaceous organic substance of production, existing method is non-remunerative.

Summary of the invention

According to one embodiment of the invention; A kind of method of from hydrocarbon-containing feedstock, extracting the hydrocarbonaceous organic substance comprises the steps: to provide first liquid that comprises turps liquid and this hydrocarbon-containing feedstock is contacted feasible formation with this turps liquid and extracts mixture and residual raw materials.This extraction mixture comprises at least a portion hydrocarbonaceous organic substance and turps liquid.This residual raw materials comprises the insoluble substance from this hydrocarbon-containing feedstock.Do not have all to be dissolved by turps liquid and move under the situation about extracting in the mixture at this hydrocarbon-containing feedstock, this residual raw materials also can comprise the hydrocarbonaceous organic substance of less part.Then this residual raw materials and this are extracted mixture separation.This extraction mixture is further separated into first part and second section.The first part that extracts mixture comprises hydrocarbon product stream, and this hydrocarbon product stream comprises the hydrocarbonaceous organic substance that at least a portion is extracted from hydrocarbon-containing feedstock.The second section that extracts mixture comprises at least a portion turps liquid.In one embodiment, part turps liquid is recycled in the hydrocarbon extracting liq at least.

In another embodiment, all basically hydrocarbonaceous material are extracted in the extraction mixture.In this embodiment, residual raw materials is substantially free of oil, and can further be used or dispose and environment is not influenced.

In another embodiment, the invention provides the corroding method that is used to reduce the corrosion rate of corrodible surface or material or suppresses corrodible surface or material.During the processing through for example transportation, boring, borehole operation, exploration, manufacturing hydrocarbon, storage or the hydrocarbon-containing feedstock of pipeline, oil tanker, chest, fishing tool or drill bit, the metallic surface of the sulfocompound in the contact hydrocarbon-containing feedstock can be corroded.Through reducing the corrosion rate on corrodible surface, realize that significant cost reduces.

Description of drawings

Fig. 1 is used for from the gather synoptic diagram of an embodiment of device of hydro carbons of Tar sands.

Fig. 2 is used for from the gather synoptic diagram of an embodiment of device of hydro carbons of resinous shale.

Fig. 3 is used for from the gather synoptic diagram of an embodiment of device of hydro carbons of coal.

Fig. 4 is the synoptic diagram that improves subsurface deposit hydrocarbon RF.

Fig. 5 has shown that pitch percentage pair time that contacts with different liqs (admixture of d-PC 560, turps liquid and water) of gathering reaches 30 seconds time course.

Fig. 6 is presented at liquid and in 1: 1 to 6: 1, contacts the bituminous amount of 97 second time after gathering with the admixture of turps liquid and d-PC 560 with the proportional range of Tar sands.

Fig. 7 is presented at the liquid and the proportional range of Tar sands and in 1: 1 to 6: 1, contacts the bituminous amount of gathering after the clock time in 5 minutes.

Fig. 8 is presented at the bituminous amount of gathering after liquid and the proportional range of Tar sands contacted 15 minutes in 1: 1 to 3: 1 time.

Embodiment

In one aspect, the present invention relates to a kind of being used for of being easy to utilize from coal, resinous shale, Tar sands etc. and from the compsn of oil reservoir extraction, liquefaction and/or dissolution of minerals fuel.

According to an embodiment; Method provides from hydrocarbon-containing feedstock, such as for example coal, resinous shale, Tar sands or contain the step of liquefaction in oil reservoir or its combination of heavy crude, crude oil, Sweet natural gas (often with the described mineral fuel coexistence of crude oil and other), dissolving and/or extraction hydrocarbonaceous organic substance.The hydrocarbonaceous organic substance includes, but are not limited to heavy crude, crude oil, Sweet natural gas, petroleum gas etc.The hydrocarbonaceous organic substance can be solid, semisolid, liquid, mud, viscous liquid, liquid or gas form.Other raw materials as the hydrocarbon-containing feedstock that is suitable for using method of the present invention to handle comprise liquid and the solid that comprises hydrocarbon-containing feedstock and residual raw materials.The hydrocarbon-containing feedstock of example also can comprise oil (oil tank bottom) at the bottom of the oil tank, oil hole (oil pit) or Pond Silt (pond sludge) and mortar mixture, garbage, fertilizer, mud or municipal wastes.Liquefaction, dissolving and/or extraction hydrocarbonaceous organic substance comprise the steps: to provide the hydrocarbon extracting liq; Hydrocarbon-containing feedstock is contacted with the hydrocarbon extracting liq so that the said hydrocarbonaceous organic substance of at least a portion is extracted into from said hydrocarbon-containing feedstock in the said hydrocarbon extracting liq to generate the extraction mixture; This extraction mixture comprises removed hydrocarbonaceous organic substance from hydrocarbon-containing feedstock and hydrocarbon extracting liq, and in the hydrocarbon extracting liq, the organic substance that extracts is separated with any residual raw materials that is not extracted.The hydrocarbon extracting liq can comprise a certain amount of turps liquid, such as, Terpineol 350 for example.Turps derived from natural origin generally includes a certain amount of terpenes.In one embodiment, turps liquid comprises lindenol.

Another embodiment of the invention comprises hydrocarbon-containing feedstock is contacted with turps liquid mixture (hereinafter refers to turps liquid admixture).Turps liquid admixture comprises lindenol, β-Terpineol 350, beta-pinene and Paracymene.In one embodiment, polycomponent turps liquid comprises at least about 30% lindenol with at least about 15% β-Terpineol 350.In another embodiment, turps liquid admixture comprises about 40-60% lindenol, about 30-40% β-Terpineol 350, about 5-20% beta-pinene and about 0-10% Paracymene.In another embodiment, turps liquid admixture comprises about 50% lindenol, about 35% β-Terpineol 350, about 10% beta-pinene and about 5% Paracymene.In optional embodiment, turps liquid admixture comprises about 40-60% lindenol, about 30-40% α-Pai Xi, about 5-20% beta-pinene and about 0-10% Paracymene.In another embodiment, turps liquid admixture comprises about 50% lindenol, about 35% α-Pai Xi, about 10% beta-pinene and about 5% Paracymene.

In certain embodiments, the ratio of turps liquid and hydrocarbon-containing feedstock is in the scope of about 1: 2 and 6: 1 by weight or in the scope of about 1: 2 and 4: 1 by weight.In another embodiment, the ratio of turps liquid and hydrocarbon-containing feedstock is in the scope of about 1: 1 and 3: 1 by weight.In relating to the embodiment that oil reservoir gathers, this ratio can be more than or equal to about 3: 1, and in relating to other embodiments that oil reservoir gathers, this ratio can be more than or equal to about 4: 1.In order from oil reservoir, to extract, pore volume is used for confirming the estimation observed value of hydrocarbon-containing feedstock.In other aspects of the present invention, such as, when using Tar sands, coal and resinous shale, the volume of hydrocarbon-containing feedstock can more directly be estimated.

In certain embodiments, the minimum organic content that contains in the hydrocarbon-containing feedstock is about 1% more than or equal to hydrocarbon-containing feedstock weight, in other embodiments, and more than or equal to about 10%, and in further embodiment, more than or equal to about 14%.

Tar sands used herein, coal, resinous shale, Sweet natural gas, petrologen, pitch (bitumen), pitch (asphalt) can contain few extremely natural hydrocarbonaceous organic substance of about 1%.Described method and liquid very lowly extract the hydrocarbonaceous organic substance up to about 100% to the hydrocarbon-containing feedstock of the hydrocarbon of a large amount very (promptly contain few hydrocarbon feed to about 1% weight former expect the raw material that contains up to the hydrocarbon feed of about 100% weight) from containing effectively.

In one embodiment of the invention, liquifier, solvating agent or extraction agent that selection is used for hydrocarbonaceous material are natural, synthetic or mineral turpentine, and it can comprise lindenol or lindenol itself.

In certain embodiments, the liquefaction of mineral fuel or hydrocarbonaceous organic substance, dissolving and/or extract and under the temperature in the about 2 ℃～about 300 ℃ scope, to carry out.In certain embodiments, organic substance or raw material and turps liquid is less than about 300 ℃, or less than contacting under about 60 ℃ temperature.In other embodiments, liquefaction, dissolving and/or extract temperature can be in about 20 ℃～about 200 ℃ scope.Carry out the liquefaction, dissolving of mineral fuel and/or the pressure when extracting generally can be about 1.0 * 10 ⁴Pascal (0.1atm)～about 5.0 * 10 ⁶In pascal's (50.0atm) the scope.In certain embodiments, this technology can be about 5.0 * 10 ⁴Pascal (0.5atm)～about 8.0 * 10 ⁵Carry out under pascal's (8.0atm) the pressure.At some in other the embodiment; Through being immersed in one or more turps liquid or contacting the mineral fuel that are liquefied, dissolve and/or extract with one or more turps liquid or the form of particle, sheet, piece or agglomerate that the hydrocarbonaceous organic substance can be mineral fuel; Entering contains its size of internal portion of liquefaction, dissolving or extraction vessel (hereinafter is also referred to as reactor drum or contacting container, and both exchange use) of one or more said liquifiers, solvating agent and/or extraction agent in the scope of about 0.74mm～about 10mm.In certain embodiments, the size of the particle of mineral fuel, sheet, piece or agglomerate is in the scope of about 0.149mm (100 order)～about 20mm.In certain embodiments, through liquifier, solvating agent and/or (multiple) extraction agent are boiled these (multiple) reagent are come stirring particles, lamella, piece layer or agglomerate layer with the form of liquid particle, sheet, piece or the agglomerate through mineral fuel.In certain embodiments, liquefaction, dissolving and/or the time length of extracting are about 1 minute～about 90 minutes.Mineral fuel can partly or wholly be liquefied, dissolve and/or extract; Can influence the degree of liquefaction, dissolving and/or extraction such as type, relative consumption and the concentration of (multiple) liquifier, (multiple) solvating agent and/or (multiple) extraction agent in temperature, pressure, stirring intensity and the time length of operating and/or the adjustment reactor drum through the red-tape operati condition.

The basis of one aspect of the present invention is to be surprised to find that; When about 500 gram reagent lindenols being added to about 250 grams in the plate from the particle diameter in the coal seam, Pittsburgh in Pennsylvania Washington county during less than the coal sample of about 25mm; It is almost pitch-dark that the color of reagent becomes immediately, and still like this after several hours.This shows that colour-change is not because the suspension of coal particle has been extracted the hydrocarbonaceous organic substance but indicate from coal.Subsequently, 2: 1 mixtures of this lindenol and coal sample from plate be transferred to capping and tight seal the jar, and about 20 ℃ be slightly smaller than about 1.01 * 10 ⁵Kept about 25 days under pascal's (1atm) the envrionment conditions.The transformation efficiency of coal sample (that is liquefaction degree) is filtering, is being determined as about 71wt.% with washing with alcohol, drying with after weighing.This 71wt.% transformation efficiency is corresponding to the nearly all soluble pitch (organic substance) that exists in the coal sample, and its proximate analysis is 2.00wt.% as received basis moisture (as-received moisture), 9.25wt.% dry ash, 38.63wt.% drying and volatilizing thing and 50.12wt.% exsiccant fixed carbon.Use coal and resinous shale and a series of subsequently the tests of Tar sands under multiple operational condition to show and comprise the alcohols that contains firpene and firpene; Promptly; Natural and/or the synthetic terebinthine reagent family of Terpineol 350 liquefies, dissolves and/or extract mineral fuel especially effectively and comprises petrologen (organic substance) and/or bituminous matter (organic substance) in coal, resinous shale, Tar sands, heavy crude and/or the crude oil, and does not need any catalyzer or alkali-metal auxiliary.These reagent; Except the mineral turpentine that derives from oil; Be renewable and " green "; Promptly comparing with the multiple solution or the mixture of other compounds with every other known liquefaction, dissolving and/or extraction agent such as tetraline, YLENE, anthracene and these reagent that is used for mineral fuel, is hypotoxic, capable of circulation with relatively inexpensive.Even derive from the mineral turpentine of oil, although non-renewable, be that relative hypotoxicity is with cheap.Have been found that even in the required condition more under the demulcent condition than the invention of nearest liquefaction, dissolving and/or extraction far away about mineral fuel such as coal, resinous shale, Tar sands, crude oil and heavy crude; For example; Under envrionment temperature and the pressure; Said arbitrarily liquefaction, dissolving and/or extraction agent permeate through the mineral fuel hole with considerable speed or diffuse in particle, sheet, agglomerate or the piece of mineral fuel, cause these particles, sheet, piece or agglomerate often almost almost in liquefaction, dissolving and/or extraction agent, to discharge liquefiable, solubilized or extractible cut subsequently fully thus.

One aspect of the present invention provides the method for liquefaction from hydrocarbon-containing feedstock such as coal, resinous shale and Tar sands, dissolving and/or extraction mineral fuel or hydrocarbonaceous organic substance; Wherein a part of solid or semi-solid mineral fuel contact with turps liquid in extracting mixture, and this extraction mixture can lack basic metal, catalyzer, hydrogen (H ₂) and/or carbon monoxide (CO).Although hydrogen and CO can be used as mixture, one embodiment of the invention provide technology and the compsn that lacks hydrogen and CO.

In certain embodiments, turps liquid is selected from natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, its polymkeric substance and composition thereof.In some other embodiment; Turps liquid is selected from Geraniol, 3-carene, limonene (to the Meng-1; The 8-diene) (p-mentha-1,8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol (p-methan-8-ol), α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice and composition thereof.In other embodiments, turps liquid is selected from methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone and composition thereof.

The shortcoming that the present invention has avoided existing extraction system inherent environment, economy and implemented.Current, comprise that the solvent of various tensio-active agents, basic soln or acidic solution, salt, volatile compound and alcohol is used, successful degree is different.Yet these known solvent prescriptions possibly have some defective for every kind, and they are overcome by one or more embodiment of the present invention.In one embodiment, reproducible and " green " extracting liq of the present invention are natural deutero-or basic surfactant-free.In another embodiment, extracting liq is a surfactant-free.And, of the present invention be used for from the use that natural geological formations is extracted the extracting liq of hydrocarbonaceous organic substance avoided with other known liquefaction that is used for mineral fuel, dissolving and/extract relevant economy of reagent and the cost on the environment.

In certain embodiments, aspect of the present invention provides to use and has comprised that the on-aqueous liquid that has basically no tensio-active agent of turps liquid extracts the method for hydrocarbonaceous material.Non-aqueous solvent has when hydrocarbon that less environment reveals, increases extracts, avoided contact with other reactive sulphur compounds of embedding in the hydrocarbonaceous material with hydrogen sulfide and forms sulfuric acid, suppresses the advantage that burn into reduces viscosity and capillary effect elimination.

According to an aspect; Solid or semi-solid mineral fuel or other hydrocarbon-containing feedstocks; Such as coal, resinous shale, Tar sands and heavy crude, or for example at the bottom of the oil tank oil, oily hole or Pond Silt, garbage, fertilizer, mud or municipal wastes can promote the arbitrary dimension that contacts with turps liquid to provide.Mineral fuel or hydrocarbon-containing feedstock can be used as particle, sheet, piece or agglomerate and provide, for example the big fragment or the sheet of coal or resinous shale.According to certain aspect of the present invention, mineral fuel or hydrocarbon-containing feedstock provide as particle.According to certain aspect of the present invention, the particulate mean particle size of mineral fuel or hydrocarbon-containing feedstock is about 0.01mm～about 100mm.In other the embodiment, the particulate mean particle size of mineral fuel is about 4mm～about 25mm at some.

According to an aspect of the present invention, can second liquid be added in the turps liquid.According to certain aspect of the present invention, second liquid is selected from lower aliphatic alcohols, paraffinic hydrocarbons, aromatic hydrocarbon, aliphatic amide, aromatic amine, dithiocarbonic anhydride and composition thereof.The mixture of example is included in the solvent of making in refining of petroleum such as decanted oil (decant oil), light cycle oil and the petroleum naphtha, or the solvent of in destructive distillation coal and fractionation liquefaction coal, making.

As employed at this, lower aliphatic alcohols refer to 2～12 carbon atoms primary, the second month in a season and uncle's monohydroxy-alcohol and polyvalent alcohol.As employed at this, paraffinic hydrocarbons refers to the straight chain and the side chain paraffinic hydrocarbons of 5～22 carbon atoms.As in this use, aromatics refers to monocycle, heterocycle and polynuclear compound.As using at this, aliphatic amide refer to have 1～15 carbon atom alkyl substituent primary, the second month in a season and tertiary amine.In certain embodiments, use benzene, naphthalene, toluene or its combination.In another embodiment, can use above-mentioned lower aliphatic alcohols.In one embodiment; Operationally solvent is being remained under the liquid temperature and pressure, solvent is selected from ethanol, propyl alcohol, Virahol, butanols, pentane, hexane, benzene,toluene,xylene, naphthalene, anthracene, tetraline, triethylamine, aniline, dithiocarbonic anhydride and composition thereof.

In certain embodiments, the ratio of any other turps miscible solvents that contain in turps liquid and the said fluid is more than or equal to about 1: 1, in certain embodiments more than or equal to about 9: 4.In certain embodiments, this ratio was more than or equal to about 3: 1.In other embodiments, this ratio was more than or equal to about 4: 1.

According to an aspect of the present invention, mineral fuel and turps liquid contact under about 2 ℃～about 300 ℃ temperature.In certain embodiments, mineral fuel contact under less than about 200 ℃ temperature with turps liquid.

The further aspect according to the present invention, mineral fuel and turps liquid are about 1.0 * 10 ⁴Pascal (0.1atm)～about 5.0 * 10 ⁶Pascal's (50atm) pressure is contact down.According to an aspect, this method is carried out under the pressure of about 0.5atm～about 8atm.

According to an aspect of the present invention, this method further comprises provides extraction vessel, and solid or semi-solid mineral fuel contact in extraction vessel with turps liquid.According to an aspect, whipping appts can be provided, the turps liquid mixing and the stirring that contain of mineral fuel and reactor drum or extractor whereby.

According to an aspect of the present invention, mineral fuel and turps liquid can be in storage tank, in the pipeline or in other suitable vessels incubation so that prolong its duration of contact.According to further aspect, the degree that the time span that contacts with turps liquid through solid or semi-solid mineral fuel and/or the temperature of mineral fuel and turps mixtures of liquids are controlled liquefaction, dissolving and/or extracted.

According to an aspect of the present invention, mineral fuel with as contacting comprising of whipping up agent (agitant) as the turps liquid of whipping up agent and the heterogeneous body liquid of boiling water.The foaming of boiling water causes that stirring increases the contact surface between mineral fuel and the turps liquid thus.Therefore, the result has observed the extraction of higher degree.After the extraction, utilize in not coexisting of fluid density slurry tank for example known in the art, decanter or other tripping devices and can the turps liquid of hydrocarbonaceous be separated with water.

In certain embodiments, the ratio of turps liquid and water forms to avoid slurry by volume more than or equal to about 1: 1, forms slurry and can make the organic substance of separation and Extraction in the fluid that contains turps liquid become difficult.

According to an aspect of the present invention, mineral fuel and turps liquid be selected from following energy input in the presence of contact: surpass about 300 ℃, surpass the pressure of 50atm, micro-wave energy, ultrasonic energy, ionizing rays can, mechanical shearing and mixing thereof.

According to an aspect of the present invention, liquefaction or catalyst-solvent are provided in mineral fuel and turps mixtures of liquids.

According to an aspect of the present invention, be selected from compound and the postreaction or the dissolving mixt of hydrogen, carbon monoxide, water, MOX, metal and composition thereof through adding.

According to an aspect of the present invention, mikrobe is included in reaction or the dissolving mixt.Destroy the selection chemical bond in the hydrocarbon of mineral fuel and other hydrocarbon-containing feedstocks through biological treatment effect with bacillus-type thermophilus microorganism that is selected from the natural strain isolated that derives from solfatara and chemolithotrophy mikrobe, for example, sulfur-crosslinked key and oxygen cross-link bond.These select the destruction of chemical bond to promote the dissolving of the hydrocarbon in mineral fuel and other hydrocarbon-containing feedstocks.

According to one embodiment of the invention, provide with a kind of method from hydrocarbon-containing feedstock extraction hydrocarbonaceous organic substance, this hydrocarbon-containing feedstock comprises the mineral fuel raw material of viscous liquid, liquid or gas.This method provides first liquid that comprises turps liquid.Turps liquid contacts with hydrocarbon-containing feedstock original position in the subterranean strata that contains said mineral fuel raw material, extracts mixture so that the hydrocarbonaceous organic substance is extracted in the said turps liquid thereby form, and forms extracting liq.Extracting liq is removed from said rock stratum, and wherein this extracting liq comprises the turps liquid that contains the hydrocarbonaceous organic substance that has extracted.The hydrocarbonaceous organic substance that has extracted is separated with the residual raw materials that is not extracted.This method can further comprise the hydrocarbonaceous organic substance of said extraction and turps liquid separation.Viscous liquid, liquid or gas mineral fuel raw material can be heavy crude, crude oil, Sweet natural gas or its combination.For example, subterranean strata can be crude oil oil reservoir or natural gas pool.

The present invention can be used to the mineral fuel in direct in-situ liquefaction and/or the dissolving subterranean strata at an easy rate, and the gained product liquid is extracted from these rock stratum.

Exemplary extraction agent of the present invention is a liquid, for example comprises that with the bituminous organic substance pitch, petrologen and/or tar in coal, resinous shale and the Tar sands have very strong physical chemistry avidity.When extraction agent of the present invention and the bituminous organic substance that mainly comprises hydro carbons were in contact with one another, organic substance was extracted in the extraction agent of the present invention, thereby with this organic substance liquefaction.When contact, hydro carbons and extraction agent of the present invention promptly form homogeneous solution, that is, and and a phase liquid.

Might utilize physical chemistry avidity between extraction agent of the present invention and the bituminous material to be used to improve the oil recovery of oil reservoir under the original position condition.The most of so-called frontal displacement method (frontal displacement method) that relies on of the original position harvesting technique of the prior art of in oil reservoir, using so far.This technology strictly receives heterogeneous fluid mobile Characteristics Control in the porous medium.This technology often makes major part, even for " good " LV oil reservoir, often can't gather from geological stratification above about 40% original oil-generating (original oil).Extraction agent of the present invention has improved oil recovery through the complex behavior that overcomes dominant heterogeneous fluid under the condition in position.

The invention provides through hydrocarbon-containing feedstock is contacted with the turps liquid that reduces hydrocarbonaceous material viscosity and increase mobile and extraction viscosity or the fixed hydrocarbon-containing feedstock.Also increased mobile because turps liquid has been eliminated the non-aqueous matter of capillary effect relevant with aqueous solution so turps liquid.The contact original position or the generation of offing normal.

The present invention has utilized the very strong physical chemistry avidity of turps liquid.

A kind of method of the present invention is injected into oil reservoir or natural gas pool with extraction agent of the present invention through injecting well.

When oil contacted in oil reservoir with extraction agent of the present invention, oil was extracted in the extraction agent, thereby produced homogeneous solution, that is, and and a phase liquid.The extraction agent of the present invention remarkable ground displacement of reservoir oil is communicated with the subsurface geology layer fluid because it moves to recovery well from the injection well; On the contrary, the front is extracted in the extraction agent of the present invention by (trapped) oil of trap and is exhausted fully by oil until extraction agent in the formation homogeneous phase solution.Afterwards, the homogeneous phase solution of hydrocarbon that comprises extraction finally arrives recovery well simply as the flow of pore of a phase liquid through oil reservoir.

Following instance is explained three specific embodiments of original position oil production method of the present invention.

In first original position embodiment, the extraction agent of the present invention of about 3 (3.0)～7 (7.0) pore volumes is injected into and is filled to ROS in advance and has produced simultaneously in the oil reservoir of about 51% original oil-generating in this oil reservoir.Other about 41% original oil-generating of this oil reservoir can be unexpectedly produced in the injection subsequently of extraction agent.This embodiment of this method is identified in test, described in following embodiment 22.

In second original position embodiment, the extraction agent of the present invention of about two (2.0)～five (5.0) pore volumes is injected in the oil reservoir.When beginning, injection only makes oil produce before the extraction agent of the present invention that injects about 1/3rd 3/(0.3)～four (0.75) pore volumes; Afterwards, produce the wherein oily extraction agent of the present invention that has been extracted.Injecting about one not only during the extraction agent of 1/2nd (1.5)～three but also 1/2nd (3.5) total pore volumes, the most trapped fuel of can gathering.Unexpectedly gathered in the oil reservoir about 90% original oil-generating of this method.This embodiment of this method also is identified in test, described in following embodiment 22.

In the 3rd original position embodiment, inject extraction agent of the present invention to improve from containing the very oil reservoir of heavy-gravity oil, for example, the oil recovery in the oil reservoir of " Reno section's oil band difficult to understand (Orinoco Oil Belt) " of Venezuela.The RF of the extra heavy oil of employing prior art oil production method is very low, in this oil reservoir, is generally about 10%～about 15% original oil-generating.Inject turps liquid extraction agent of the present invention to the beat all increase of the RF of these oil reservoirs can through to recovery well with inject well and all adopt horizontal well, and the regular steam stimulation of these wells is further improved.

Extraction agent of the present invention is injected into the ultimate recovery factor that can increase Sweet natural gas in the gas reservoir in the large-scale gas reservoir.Aerogenesis produces dangerous sedimentation on a large scale through the face of land in the gas field of being everlasting from these gas reservoirs, for example, and " Groeningen " gas field of Holland.Therefore, usually need keep reservoir pressure (reservoir pressure) through injecting water.Since water and gas pass through under the caused high pressure of two-phase flow of the low gas reservoir of permeability, be injected into water in the gas reservoir can trap up to about 30% gas.Through injecting extraction agent of the present invention, yet the gas of trap is extracted in the extraction agent in the gas reservoir, and flows to recovery well.Through separation and Extraction agent and gas on the face of land, the gas and extraction agent recycling is used for utilizing again of gathering.

Process for extracting of the present invention can one or more be used to promote the currently known methods of produce oil in enforcement, for example, inject CO ₂Or implement behind Sweet natural gas and the interpolation tensio-active agent.

To become obviously to those skilled in the art from this specification sheets others of the present invention and advantage, embodiments wherein of the present invention only confirm through the illustration that carries out the best mode that relates to of the present invention and describe.Should be appreciated that the present invention can implement other different embodiments, and can revise the different obvious aspect of its some details, can not depart from the present invention.Therefore, it is illustrative that specification sheets is considered in essence, rather than restrictive.

Embodiment

Coal

In certain embodiments, hard coal or bituminous coal can be ground into the size of about 0.841mm (20 order)～about 0.149mm (100 order), and pass through about 1.0 * 10 subsequently ⁵Pascal (1atm)～about 2.0 * 10 ⁵Be immersed under the pressure in pascal's (2.0atm) the scope in the turps liquid and dissolved and/or extract, that is, and liquefaction.In other the embodiment, turps liquid can be natural, synthetic or mineral turpentine at some, and this turps comprises other components until β-Terpineol 350 and about 10% volume of the lindenol of about 50-70% volume, about 20-40% volume.Like this paper definition, term " other component " comprises natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes or its mixture.In other embodiment; Turps liquid comprises at least a following compound that is selected from: Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice or its mixture.Also in other embodiment, turps liquid comprises at least a following compound that is selected from: methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture.In certain embodiments, flaxseed coal or bituminous coal layer can be under 80 ℃～about 130 ℃ temperature, or possibly under the temperature of the boiling point of said turps liquid, stir through said turps liquid.In certain embodiments, dissolving and/or extraction, that is, the time length of liquefaction can be about 10 minutes～about 40 minutes.The duration of contact of in certain embodiments, from coal, extracting the hydrocarbonaceous organic substance was less than about 5 minutes.

In some embodiments, dark-coloured brown coal, earthy browncoal or arbitrarily other low grade coal can be crushed to the size of about 0.419mm (40 order)～about 0.074mm (200 order), and subsequently through about 1.0 * 10 ⁵Pascal (1atm)～about 2.0 * 10 ⁵Be immersed under the pressure in pascal's (2.0atm) the scope in the turps liquid and dissolved and/or extract, that is, and liquefaction.In other the embodiment, turps liquid can be natural, synthetic or mineral turpentine at some, and this turps comprises other components of β-Terpineol 350 and about 5% volume of the lindenol of about 70-90% volume, about 5-25% volume.In other embodiments, broken dark-coloured brown coal, earthy browncoal layer or other low grade coal can be under about 80 ℃～about 130 ℃ temperature arbitrarily, or possibly under the temperature of the boiling point of said turps liquid, stir through said turps liquid.In certain embodiments, dissolving and/or extract, that is, liquefaction can continue about 20 minutes～and about 60 minutes.The duration of contact of in certain embodiments, from coal, extracting the hydrocarbonaceous organic substance was less than about 5 minutes.

Resinous shale

In certain embodiments, resinous shale can be crushed to the size of about 0.419mm (40 order)～about 0.074mm (200 order), and passes through about 1.0 * 10 subsequently ⁵Pascal (1atm)～about 2.0 * 10 ⁵Be immersed under the pressure in pascal's (2.0atm) the scope in the turps liquid and dissolved and/or extract, that is, and liquefaction.In other embodiment, turps liquid can be natural, synthetic or mineral turpentine, and this turps comprises other components of β-Terpineol 350 and about 5% volume of the lindenol of about 70-90% volume, about 5-25% volume.At some in other the embodiment, broken oil shale layer can be under about 80 ℃～about 130 ℃ temperature, or possibly under the temperature of the boiling point of said turps liquid, stir through said turps liquid.In other embodiment, dissolving and/or extract, that is, liquefaction can continue about 30 minutes～and about 60 minutes.The duration of contact of in certain embodiments, from resinous shale, extracting the hydrocarbonaceous organic substance was less than 5 minutes.

Tar sands

In certain embodiments, Tar sands can be crushed to the size of about 25.4mm (1 order)～about 4.76mm (4 order), and pass through about 1.0 * 10 subsequently ⁵Pascal (1atm)～about 2.0 * 10 ⁵Be immersed under the pressure in pascal's (2.0atm) the scope in the turps liquid and dissolved and/or extract, that is, and liquefaction.In other embodiment; Turps liquid can be natural, synthetic or mineral turpentine, and this turps comprises other components of α-Pai Xi and/or beta-pinene and about 5% volume of the β-Terpineol 350 of the lindenol that contains the 40-60% volume of having an appointment, about 30-50% volume, about 5% volume.In another embodiment, broken oil shale layer can be under about 60 ℃～about 90 ℃ temperature, or possibly under the temperature of the boiling point of said turps liquid, stir through said turps liquid.In other embodiment, dissolving and/or extract, that is, liquefaction can continue about 10 minutes～and about 30 minutes.The duration of contact of in certain embodiments, from Tar sands, extracting the hydrocarbonaceous organic substance was less than 5 minutes.

Crude oil

In certain embodiments, lightweight and middle matter crude oil can produce in position, and turps liquid that can be through injecting about one (1.0)～about five (5.0) pore volumes takes out from subsurface deposit and is used for preliminary, secondary or gathers for three times.In other embodiment, can inject the turps liquid of about two (2.0)～about four (4.0) pore volumes.In certain embodiments; Turps liquid can be natural, synthetic or mineral turpentine, and this turps comprises other components of α and/or beta-pinene and about 10% volume of the β-Terpineol 350 of the lindenol of about 40-70% volume, about 30-40% volume, about 10% volume.In certain embodiments, the water of available about one (1.0)～about three (3.0) pore volumes carries out water filling behind the injection turps liquid.

In certain embodiments, heavy crude and extra-heavy oil can produce through the turps liquid that injects about one (1.0)～about five (5.0) pore volumes in position, promptly take out from subsurface deposit to be used for preliminary, secondary or to gather for three times.In other embodiment, can inject the turps liquid of about two (2.0)～about four (4.0) pore volumes.In certain embodiments; Turps liquid can be natural, synthetic or mineral turpentine, and this turps comprises other components of α and/or beta-pinene and about 5% volume of the β-Terpineol 350 of the lindenol of about 50-70% volume, about 20-35% volume, about 10% volume.In other embodiment, said method can be used in combination with the steam injection after injecting hydrocarbonaceous extract liquid, neutralization.

With reference to Fig. 1, provide a kind of and be used for from the gather equipment of hydrocarbonaceous organic substance of Tar sands.Equipment 100 comprises turps liquid source of supply 102, and source of supply 102 can randomly be connected with pump 104 to supply the turps liquid to contacting container or extraction vessel 110.In certain embodiments, turps liquid source of supply can comprise the device that is used to heat turps liquid.In certain embodiments, contacting container can be sloped rotary type filter or trommel.Tar sands sample 106 provide to transfer roller 108 or similarly feeding device be used for Tar sands are supplied to the inlet of contacting container 110.Randomly, transfer roller 108 can comprise that filter screen or similar size separation equipment are fed in the technology to prevent macrobead.Contacting container 110 comprise importing that at least one inlet is used for turps liquid with the contacting of Tar sands.Contacting container 110 can comprise a plurality of column plates or fin 114, and said column plate or fin are designed to Tar sands are kept certain period of time in contacting container, and the contact between increase or control Tar sands particle and the turps liquid.In certain embodiments, contacting container can be the sloped rotary type filter.The extraction mixture of the hydrocarbonaceous organic substance that comprises extracting liq and from Tar sands, extract is moved out of from contacting container 110 through exporting 116, and outlet 116 can comprise that filter 118 is removed with the extraction mixture of the hydrocarbonaceous organic substance that comprises extraction to prevent solid.Pump 120 can be connected to outlet 116 and be supplied to storage tank 122 to assist extracting mixture.Pipeline 124 can be connected to storage tank 112 and be used for supply extraction mixture with further processing.After extracting the hydrocarbonaceous organic substance, the inoganic solids that is insoluble in the turps liquid can be removed from contacting container through second transfer roller 126 with other materials.Be effective to use equipment 100 includes, but not limited to comprise lindenol and β-Terpineol 350 from the turps liquid of Tar sands recovery of hydrocarbons liquid.

Referring now to Fig. 2, but provide equipment 200 to be used for from the resinous shale that comprises the recovery of hydrocarbons material and other sedimentary type formations hydrocarbonaceous organic substance of gathering.Resinous shale appearance 202 is supplied to shredder or crusher 204 to reduce the size of resinous shale.In one embodiment, resinous shale is decreased to about diameter is 0.074～0.42mm for shredder or crusher 204.Broken resinous shale can randomly be supplied to filter with guarantee homogeneous and/or consistent particle size.First transfer roller 206 provides particle to contacting container 208 from shredder or crusher 204.Contacting container 208 is connected with turps liquid source of supply 210, and turps liquid source of supply 210 can randomly be connected with pump, and turps liquid is supplied at least one inlet 212 that is connected with contacting container 208.In certain embodiments, turps liquid source of supply can comprise the device that is used to heat turps liquid.Contacting container 208 can comprise a plurality of column plates or fin 214, and said column plate or fin are designed to Tar sands are kept certain period of time in contacting container, and the contact between increase or control Tar sands particle and the turps liquid.In certain embodiments, contacting container can be sloped rotary type filter or trommel.Storage tank 220 is collected and be supplied to the extraction mixture flow of the hydrocarbonaceous organic substance that comprises turps liquid and gather from resinous shale through exporting 216.Pump 218 can randomly be connected to outlet 216 and be supplied to storage tank 220 to assist extracting mixture flow.The extraction mixture flow can be connected with pipeline 222 and be used for supply extraction mixture flow further to process.Second transfer roller 224 assists to remove inorganic or insoluble substance from contacting container 208.Be effective to use equipment 200 and can include, but are not limited to lindenol and β-Terpineol 350 from the turps liquid of resinous shale recovery of hydrocarbons.

Referring now to Fig. 3, provide equipment 300 to be used for from the coal hydrocarbonaceous organic substance of gathering.Coal sample 302 is supplied to shredder or crusher 304 to reduce the size of coal.In one embodiment, it is 0.01～1mm that shredder or crusher 304 are decreased to about diameter with coal, depends on the quality of coal sample.In certain embodiments, shredder or crusher 304 can be wet wheeling machines.Broken coal can randomly be supplied to filter with guarantee homogeneous and/or consistent particle size.Broken coal is supplied to first contacting container 306.First contacting container 306 also is connected with turps liquid source of supply 308, and turps liquid source of supply 308 can randomly be connected with pump 310, and pump 310 is supplied to first contacting container 306 with turps liquid.In certain embodiments, turps liquid source of supply can comprise the device that is used to heat turps liquid.First contacting container 306 comprises mixing device, and this mixing device is designed to stir and improves or control contacting between solid coal particle and the turps liquid.Second contacting container 316 is collected and be supplied to the extraction mixture flow of the hydrocarbonaceous organic substance that comprises turps liquid and gather from resinous shale through first contacting container outlet 313.Pump 314 randomly is connected to outlet 313 and is supplied to second contacting container 316 to assist extracting mixture flow.Second contacting container 316 can comprise a series of column plates or fin 318, and said column plate or fin are designed to increase or control separating of solid and turps liquid.Randomly, second contacting container 316 can be sloped rotary type filter or trommel.Can collect from second contacting container outlet 320 and extract mixture flow, outlet 320 can randomly be connected with pump 322, is supplied to storage tank 324 to assist extracting mixture flow.The liquid coal that exists in the storage tank 324 and arbitrarily turps liquid can be provided to liquid coal refinery or other procedure of processings through pipeline 326.Transfer roller 328 can be connected with second contacting container 316 and be used to remove and reclaim the solid as the by product of technology.Be effective to use equipment 300 and can include, but not limited to lindenol and β-Terpineol 350 from the turps liquid of coal recovery of hydrocarbons.Equipment 300 also can be used for processing high grade and inferior shale.

Referring now to Fig. 4, provide technology 400 to be used for improving the RF of hydrocarbonaceous organic substance from the hydrocarbonaceous subterranean strata.404 demonstrations of hydrocarbonaceous reservoir are positioned at the face of land below 402.Recovery well 406 has been in service.Provide injection well 408 to be used for injecting the turps liquid through pipeline 410.Liquefaction, dissolving and/or the extraction of the hydrocarbonaceous organic substance that exists in the turps liquid promotion reservoir, and provide motivating force so that the hydrocarbonaceous organic substance in the rock stratum is promoted towards recovery well.The hydrocarbon product stream that comprises the turps liquid of injection is collected through pipeline 412.Be effective to use equipment 400 and can include, but not limited to lindenol and β-Terpineol 350 from the turps liquid of the subterranean strata recovery of hydrocarbons of hydrocarbonaceous.

In certain embodiments, be provided for comprising the natural turps at least about 30% volume, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes or its mixture from the turps liquid of oil well increase output.In other embodiment; Turps liquid comprise at least about the Geraniol of 30% volume, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice or its mixture.Also in other embodiment, turps liquid comprises at least about the methyl allylphenol of 30% volume, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture.

In certain embodiments, turps liquid comprises the lindenol at least about 40% volume.In other embodiments, turps liquid comprises the β-Terpineol 350 at least about 25% volume.Also in other embodiment, turps liquid comprises at least about the lindenol of 40% volume with at least about the β-Terpineol 350 of 25% volume.In other embodiments, turps liquid comprises the lindenol at least about 50% volume, and also comprises β-Terpineol 350 in certain embodiments.In certain embodiments, turps liquid comprises the β-Terpineol 350 at least about 20% volume.In certain embodiments, turps liquid comprises the lindenol of about 50～70% volumes and the β-Terpineol 350 of about 10～40% volumes.

In yet another aspect, a kind of technology that is used to increase through the output of the underground hydrocarbonaceous reservoir that improves the RF operation is provided, this technology comprises turps liquid is injected into reservoir to promote the generation of hydrocarbonaceous material through injecting well.Turps liquid can comprise at least a compound that is selected from natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes or its mixture.In other embodiment; Turps liquid can comprise be selected from Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-at least a compound of 8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice or its mixture.Also in other embodiment, turps liquid can comprise and is selected from methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7, at least a compound of 8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture.The hydrocarbonaceous organic substance product stream that comprises turps liquid and the hydrocarbon of gathering reclaims from the recovery well that is connected with this hydrocarbonaceous reservoir.Hydrocarbonaceous organic substance product stream can be separated into gather hydrocarbon stream and the turps liquid that is used for recycling.In certain embodiments, further method can further comprise the step that the turps liquid recycle stream is injected into the injection well.

In yet another aspect, providing a kind of is used for from the gather method of hydrocarbonaceous organic substance of the subterranean strata that is rich in the hydrocarbon coal.The method comprising the steps of: through extracting the hydrocarbonaceous organic substance by the coal sample that obtains to comprise the hydrocarbonaceous organic substance that can gather with the method for the step of the broken generation broken coal of coal dust basically.Broken coal is filtered and is supplied to contacting container, this contacting container comprise be used to supply hydrocarbon extracting liq to contacting container at least one inlet.The non-aqueous hydrocarbon extracting liq of broken coal with basic surfactant-free contacted; This hydrocarbon extracting liq is formed by being selected from the turps liquid of being made up of following material basically: natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture make to form and extract mixture and form residual raw materials.Extract mixture and be included in the turps liquid part hydrocarbonaceous organic substance at least, and residual raw materials comprises the insoluble insolubles from coal in turps liquid of part at least.Residual raw materials from extracting mixture separation, is produced hydrocarbon product stream and turps liquid flow with hydrocarbonaceous organic substance and turps liquid separation, and wherein hydrocarbon product stream comprises at least partly the hydrocarbonaceous organic substance from coal.At least the turps liquid flow of part is recirculated to contacting step.

In yet another aspect, a kind of method that is used to increase the output of passing through the hydrocarbonaceous subterranean hydrocarbon rock stratum of improving the RF operation is provided.This method comprises turps liquid through injecting the step that well is injected into the rock stratum.In certain embodiments, turps liquid comprises at least about the lindenol of 40% volume with at least about the β-Terpineol 350 of 10% volume.The dissolving of turps liquid, extraction and/or displacement rock stratum hydrocarbonaceous material, subsequently through recovery well with the turps liquid hydrocarbonaceous material of gathering from the rock stratum.In certain embodiments, this method further comprises hydro carbons and turps liquid separation.Also in other embodiment, this method further comprises turps liquid is recycled to recovery well.In certain embodiments, lindenol exists with the amount of about 40-70% volume.In some other embodiment, lindenol exists with the amount at least about 70% volume.Also in other embodiments, β-Terpineol 350 exists with the amount of about 10-40% volume.In other embodiment, turps liquid further comprises the γ-Terpineol 350 of about at the most 10% volume.In other embodiment, turps liquid can comprise the organic solvent that is selected from methyl alcohol, ethanol, propyl alcohol, toluene and YLENE of about at the most 25% volume.This method comprises that at preliminary, secondary with gather operating period for three times the gathering of hydrocarbonaceous organic substance after the secondary recovery operation (comprising water filling) is useful.

In yet another aspect, provide and be used for from the gather turps liquid of hydrocarbonaceous organic substance of Tar sands.In one embodiment, turps liquid comprises at least about the lindenol of 30% volume with at least about the β-Terpineol 350 of 25% volume.In another embodiment, turps liquid comprises the lindenol of about 30～70% volumes, the β-Terpineol 350 of about 25～55% volumes, the β-terpenes of the α-terpenes of about at the most 10% volume and about at the most 10% volume.

In yet another aspect, provide a kind of and be used for from the fat coal resource such as for example the turps liquid of the hydrocarbonaceous organic substance of gathering in hard coal or the bituminous coal.In one embodiment, turps liquid comprises at least about the lindenol of 45% volume with at least about the β-Terpineol 350 of 15% volume.In another embodiment, turps liquid comprises the lindenol of about 45～80% volumes, the β-Terpineol 350 of about 15～45% volumes, the β-terpenes of the α-terpenes of about at the most 10% volume and about at the most 10% volume.

In yet another aspect, providing a kind of is used for from the gather turps liquid of hydrocarbonaceous organic substance of low-quality coal resources.In one embodiment, turps liquid comprises the β-Terpineol 350 at least about the lindenol of 60% volume and about at the most 30% volume.In another embodiment, turps liquid comprises the lindenol of about 60～95% volumes, the β-Terpineol 350 of about at the most 30% volume, the β-terpenes of the α-terpenes of about at the most 5% volume and about at the most 5% volume.

In yet another aspect, providing a kind of is used for from the gather turps liquid of hydrocarbonaceous organic substance of resinous shale.Such as this use, resinous shale is often referred to any sedimentation rock that contains asphaltic substances.In one embodiment, turps liquid comprises the β-Terpineol 350 at least about the lindenol of 60% volume and about at the most 30% volume.In another embodiment, turps liquid comprises the lindenol of about 60～95% volumes, the β-Terpineol 350 of about at the most 30% volume, the β-terpenes of the α-terpenes of about at the most 5% volume and about at the most 5% volume.

A kind of turps liquid of the hydrocarbonaceous organic substance that is used for from lightweight and matter crude oil, gathering is provided in yet another aspect.In one embodiment, turps liquid comprises at least about the lindenol of 40～70% volumes with at least about the β-Terpineol 350 of 30～40% volumes.In another embodiment, turps liquid comprises the lindenol of about 40～70% volumes, the β-Terpineol 350 of about 30～40% volumes, the β-terpenes of the α-terpenes of about at the most 10% volume and about at the most 10% volume.

In yet another aspect, providing a kind of is used for from the gather turps liquid of hydrocarbonaceous organic substance of heavy and extra-heavy oil.In one embodiment, turps liquid comprises at least about the lindenol of 50～70% volumes with at least about the β-Terpineol 350 of 30～40% volumes.In another embodiment, turps liquid comprises the lindenol of about 50～70% volumes, the β-Terpineol 350 of about 30～40% volumes, the β-terpenes of the α-terpenes of about at the most 10% volume and about at the most 10% volume.

In yet another aspect, providing a kind of is used for from the gather method of hydrocarbonaceous organic substance of Tar sands.This method comprises and obtains the tar sand sample, such as through the rich Tar sands of digging rock stratum so that the tar sand sample to be provided, wherein said tar sand sample comprises the hydrocarbonaceous organic substance and remaining inorganic or insoluble substance that can gather.The tar sand sample is supplied the abutment container, and wherein this contacting container comprises that at least one inlet that is used to supply basically the hydrocarbon extracting liq of being made up of turps liquid is used for from the Tar sands recovery of hydrocarbons.Thereby the tar sand sample contacts and stirs with the hydrocarbonaceous extracting liq and from Tar sands, extracts the hydrocarbonaceous organic substance to produce residual raw materials and to extract mixture.Extract mixture and comprise hydrocarbon extracting liq and the hydrocarbonaceous organic substance of gathering, and will comprise the residual raw materials of the insoluble substance of part at least.To extract mixture and separate with residual raw materials and further separate into hydrocarbon product stream and hydrocarbon extracting liq stream, wherein the hydrocarbon extracting liq stream hydrocarbonaceous organic substance that extracts from Tar sands that comprises part at least and turps liquid separation are with generation hydrocarbon product stream and turps liquid recycle stream.In certain embodiments, this method further comprises the step that the turps liquid flow is recycled to contacting container.In other embodiment, extracting mixture can be through fractionation by distillation to produce hydrocarbon product stream and turps liquid recycle stream.

In certain embodiments, turps liquid can comprise lindenol.In other embodiments, turps liquid can comprise at least about the lindenol of 40% volume and the β-Terpineol 350 of about 10～40% weight.In certain embodiments, about 0.5～4 normal turps liquid hydro carbons that is used for contacting and gathering with Tar sands.In certain embodiments, about 0.5～2.0 normal turps liquid hydro carbons that is used for contacting and gathering with Tar sands.

In yet another aspect, providing a kind of is used for from the gather method of hydrocarbonaceous organic substance of rich hydrocarbon ils shale.This method comprises digging and comprises that but the rock stratum of hydrocarbonaceous organic substance comprises the hydrocarbonaceous resinous shale of recovery of hydrocarbons material and inorganic or insoluble substance with generation.Resinous shale is pulverized to produce broken hydrocarbonaceous resinous shale.Broken then hydrocarbonaceous resinous shale is provided in the extraction process to prevent or to control oversized particles with strainer filtering.Broken hydrocarbonaceous resinous shale is dosed to contacting container; Wherein contacting container comprises that at least one inlet that is used for supplying basically the hydrocarbon extracting liq of being made up of turps liquid is used for from the broken hydrocarbonaceous resinous shale hydro carbons of gathering; And thereby broken hydrocarbonaceous resinous shale contacts with the hydrocarbon extracting liq from forming the extraction mixture and forming residual raw materials; Wherein extract mixture and comprise the hydrocarbonaceous organic substance that is partially soluble at least in the hydrocarbon extracting liq, residual raw materials comprises at least the insoluble substance of part from resinous shale.Hydrocarbon is extracted mixture to be separated with residual raw materials.Extract in the mixture from the hydrocarbonaceous organic substance of hydrocarbon extracting liq and turps liquid separation and comprise the hydrocarbon product stream of part hydrocarbonaceous organic substance and hydrocarbon extracting solution liquid flow at least with generation.In certain embodiments, the hydrocarbon liquid flow is recycled to contacting container.Also in other embodiment, broken hydrocarbonaceous resinous shale has mean particle size less than about 0.4mm.Other embodiments of the method for the hydrocarbonaceous organic substance that is used for gathering from resinous shale, turps liquid comprises at least a compound that is selected from natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes or its mixture.In other embodiment; Turps liquid can comprise be selected from Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-at least a compound of 8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice or its mixture.In other embodiment, turps liquid can comprise and is selected from methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7, at least a compound of 8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture.In certain embodiments, turps liquid comprises the lindenol of at least 60% volume.In certain embodiments, turps liquid comprises the lindenol of at least 45% volume and at least about the β-Terpineol 350 of 15% volume.In other the embodiment, turps liquid can comprise lindenol at some.In other embodiments, turps liquid can comprise at least about the lindenol of 40% volume and the β-Terpineol 350 of about 10～40% volumes.In certain embodiments, about 0.5～4 normal turps liquid hydrocarbonaceous organic substance that is used for contacting and gathering with resinous shale.In certain embodiments, about 0.5～2.0 normal turps liquid hydro carbons that is used for contacting and gathering with resinous shale.

In yet another aspect, providing a kind of is used for from the gather method of hydrocarbonaceous organic substance of rich coal subterranean strata.This method comprise such as through the digging subterranean strata to produce coal, wherein coal comprises can gather hydrocarbonaceous organic substance and inorganic or insoluble substance.Coal is pulverized to produce broken coal and to filter so that the sample of homogeneous or required size to be provided.Broken coal is dosed to contacting container; Wherein contacting container comprises that at least one inlet that is used for supplying basically by the hydrocarbon extracting liq of turps liquid is used for from the broken coal hydro carbons of gathering; And thereby broken coal contacts formation hydrocarbon extraction mixture and residual raw materials with turps liquid;, wherein extract mixture and comprise the hydrocarbonaceous organic substance in the hydrocarbon extracting liq at least partly.Residual raw materials comprises the insoluble substance from coal of part at least.With residual raw materials from extracting mixture separation.Hydrocarbonaceous organic substance and hydrocarbonaceous liquid separation flow with the hydrocarbon extracting liq with the hydrocarbon product stream from the hydrocarbonaceous organic substance of coal that generation comprises at least part.In certain embodiments, this method further comprises hydrocarbon extracting liq stream is recycled to contacting container.Also in other embodiment, liquid coal product stream is supplied to liquid coal refinery.In certain embodiments, coal sample comprises the low grade coal of mean particle size less than about 0.4mm.In certain embodiments, coal sample comprises the fat coal of mean particle size less than about 1mm.

Also other embodiments of the method for the hydrocarbonaceous organic substance that is used for gathering from coal, turps liquid comprises at least a compound that is selected from natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes or its mixture.In other embodiment; Turps liquid can comprise be selected from Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-at least a compound of 8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice or its mixture.In other embodiment, turps liquid can comprise and is selected from methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7, at least a compound of 8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture.In certain embodiments, turps liquid comprises the lindenol of at least 60% volume.In certain embodiments, turps liquid comprises the lindenol of at least 45% volume and at least about the β-Terpineol 350 of 15% volume.In other the embodiment, turps liquid comprises the β-Terpineol 350 at least about the lindenol of 60% volume and about at the most 30% volume at some.In certain embodiments, 0.5～4 normal turps liquid hydrocarbonaceous organic substance that is used for contacting and gathering with coal.In certain embodiments, 0.5～2.0 normal turps liquid hydrocarbonaceous organic substance that is used for contacting and gathering with resinous shale.

In yet another aspect, provide to be used to increase from the gather method of hydrocarbonaceous organic substance of recovery well, wherein recovery well is connected to the hydrocarbonaceous subterranean strata that comprises hydrocarbon-containing feedstock.Method comprises the step of extracting the hydrocarbonaceous organic substance through the method that comprises the step that the injection well that is communicated with the subterranean strata fluid is provided.First liquid that has basically no tensio-active agent is provided, and it comprises the non-water hydrocarbon extracting liq of being made up of the turps liquid that comprises Terpineol 350 basically.The hydrocarbon extracting liq is injected into the rock stratum through injecting well, hydrocarbon extracting liq and form from the hydrocarbonaceous organic substance of hydrocarbonaceous subterranean strata and to extract mixture wherein, and it comprises the hydrocarbonaceous organic substance in part turps liquid at least of part at least.Gather the extraction mixture from the rock stratum to produce hydrocarbon product stream and turps liquid flow through recovery well.

In yet another aspect, providing a kind of is used for from the gather system of hydrocarbonaceous organic substance of Tar sands.The Tar sands recovery system comprises storage tank and the contacting container that is used to supply turps liquid, and wherein contacting container comprises and is used to import at least one inlet of turps liquid and is used for gathering from contacting container and extracts at least one outlet of mixture.This system also comprises first transfer roller that is used for Tar sands are supplied to contacting container.The storage tank that comprises the pipeline that connects storage tank and contacting container is provided, and the pipeline that wherein connects contacting container and storage tank comprises that filter enters in the storage tank to prevent solid.This system comprises that also second transfer roller is used to gather and conveying solid substance.

In one embodiment, contacting container is rotating inclined filter, and it comprises that a series of fins or column plate are used for separating and/or the control Tar sands.In another embodiment, fin or column plate are provided for the duration of contact between increase or control Tar sands and the turps liquid.In certain embodiments, turps liquid can comprise lindenol.In other embodiment, turps liquid can comprise the lindenol of about 30～70% volumes and the β-Terpineol 350 of about 25～55% volumes.

In yet another aspect, providing a kind of is used for from the gather system of hydrocarbonaceous organic substance of resinous shale.This system comprises and is used to supply the storage tank of turps liquid and be used for resinous shale is ground into the shredder than small grain size.Contacting container is provided, and this contacting container comprises at least one inlet, at least one inlet that is used to receive broken resinous shale of being used to import turps liquid, be used for from gather at least one outlet of solid and be used for gathering from contacting container and extract at least one outlet of mixture of contacting container.Provide first transfer roller to be used for broken resinous shale is supplied to contacting container.This system further comprises storage tank, and wherein storage tank comprises the pipeline that connects storage tank and contacting container, and wherein this pipeline comprises that filter enters in the storage tank to prevent solid; Solid second transfer roller is used to gather.In certain embodiments, this system comprises that further being used for that the reaction mixture that comprises the hydro carbons of gathering and turps liquid is supplied to refinery is used for the pipeline that further separates and/or process.In certain embodiments, turps liquid can comprise lindenol.In certain embodiments, turps liquid can comprise the β-Terpineol 350 at least about the lindenol of 60～95% volumes and about at the most 30% volume.In other embodiment, turps liquid can comprise the lindenol of about 70～90% volumes and the β-Terpineol 350 of about 5～25% volumes.

In yet another aspect, providing a kind of is used for from the gather system of hydrocarbonaceous organic substance of coal.This system comprises the storage tank that is used to supply turps liquid and is used for the broken shredder with the particulate material that produces reduced size of coal dust.Randomly, system comprises that filter is to limit oarse-grained introducing.Contacting container is provided, and this contacting container comprises and is used to import at least one inlet of turps liquid and is used for from gather at least one outlet of solid and liquid of contacting container.Contacting container also comprises the whipping appts that is used for mixing fully turps liquid and broken coal.Provide separator to be used for separate solid and liquid, wherein separator comprises inlet, outlet and is connected the entering the mouth to the pipeline of the outlet of contacting container of separator.This system also comprises storage tank, and wherein storage tank comprises the pipeline that connects storage tank to separator, and wherein this pipeline can comprise that filter enters in the storage tank to prevent solid.

In certain embodiments, this system comprises that further filter is used for optionally preventing that mean diameter is fed to contacting container greater than the particle of about 1mm.In other the embodiment, this system comprises that further being used for that the liquid coal product is supplied to refinery is used for the further pipeline of processing at some.In certain embodiments, this system comprises that further first transfer roller is used for broken coal is supplied to contacting container.In other embodiment, this system comprises that further second transfer roller is used for removing solid from separator.In certain embodiments, turps liquid can comprise lindenol.In the embodiment to the hydro carbons of from fat coal, gathering, turps liquid can comprise the lindenol of about 45～80% volumes and the β-Terpineol 350 of about 15～45% volumes.In the embodiment to the hydro carbons of from low grade coal, gathering, turps liquid can comprise the lindenol of about 60～95% volumes and the β-Terpineol 350 of about 0～30% volume.

In certain embodiments; The hydrocarbon extracting liq can with the hydrocarbonaceous organic substance, near or separate very much near the extraction site of hydrocarbon material, it is coal, resinous shale, Tar sands, crude oil, heavy crude, Sweet natural gas and petroleum gas, crude asphalt, oil bearing rock, rock asphalt and/or bituminous matter that hydrocarbonaceous extracts material.

Further, the hydrocarbon extracting liq can part from the hydrocarbonaceous organic substance matter, near or separate very much near extracting the site.In such embodiment, part hydrocarbon extracting liq is allowed to be retained in the hydrocarbonaceous organic substance, reduces viscosity thus and stops the corrosion between storage and delivery period.

In other embodiments, occurring in from hydrocarbon extracting liq and separating of hydrocarbonaceous organic substance can be away from the upstream device that extracts the site, for example refinery.

In yet another aspect, partially or completely the separate hydrocarbons extracting liq go for recovery of hydrocarbons other method to obtain advantage of the present invention.

In yet another aspect, a kind of turps liquid extracts the hydrocarbonaceous organic substance from hydrocarbonaceous material method that is used for optimizing is provided.In general, this method comprises the sample that hydrocarbon-containing feedstock is provided, and analyzes the type of this hydrocarbon-containing feedstock with the hydrocarbon confirming to be extracted.The scheme of extracting the hydrocarbonaceous organic substance from hydrocarbon-containing feedstock is provided, and wherein this scheme is the function of size of type, general operational requirement(GOR) and the particulate state hydrocarbon feed of rock stratum.In general, this prescription comprises at least about the lindenol of 40% volume with at least about the β-Terpineol 350 of 10% volume.The amount of lindenol and β-Terpineol 350 in filling a prescription based on above-mentioned parameter adjustment then.Usually; Although aforesaid method provides good starting point for confirming the required prescription that extracts various hydrocarbon-containing feedstocks; But, can carry out the test of a series of statistics designs or carry out a series of tests to confirm the terebinthine best composition of liquid according to optimization method for other hydrocarbon-containing feedstock and concrete operational condition.

As shown in table 1, be used for changing according to granularity from the concrete prescription of Tar sands extraction, liquefaction and/or dissolving hydrocarbonaceous organic substance.In certain embodiments, be used for preparing the method for extracting the turps liquid of hydrocarbonaceous organic substance from Tar sands and comprise that adjustment is as the prescription lindenol of the function of the size of the rich hydrocarbon solid particulate matter that is extracted and the amount of β-Terpineol 350.In other embodiment, if hydrocarbonaceous organic granular shape material comprises low grade coal or resinous shale, the amount of β-Terpineol 350 in the amount of lindenol and the minimizing turps liquid in the increase turps liquid.In other embodiments, if hydrocarbonaceous organic granular shape material comprises Tar sands, the amount of β-Terpineol 350 in the amount of lindenol and the increase turps liquid in the minimizing turps liquid.In other embodiments, if the mean diameter that hydrocarbonaceous organic granular shape material comprises Tar sands and particulate material, then reduces the amount of lindenol in the turps liquid less than about 4.76mm and increases the amount of β-Terpineol 350 in the turps liquid.In other embodiments, if hydrocarbonaceous organic granular shape material comprises the mean diameter of Tar sands and particulate material greater than about 25mm (1 order), then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.

Table 1. is used to extract the prescription of Tar sands based on granularity

Granularity (mm diameter)	Lindenol	β-Terpineol 350	α-/β-terpenes	Other
					＜5mm)	30-50％vol	35-55％vol	10％vol	5％vol
5mm-25mm	40-60％vol	30-50％vol	10％vol	5％vol
					＞25mm	50-70％vol	25-45％vol	10％vol	5％vol

Above being similar to about the prescription that extraction showed of Tar sands, the quality and the general operational requirement(GOR) of the coal that shown in table 2 and 3, extraction, liquefaction and/or the dissolved prescription that is used for coal depend on granularity, be extracted.An embodiment in the method that is used for preparing the turps liquid that extracts the hydrocarbonaceous organic substance; If hydrocarbonaceous material comprises the mean diameter of hard coal, bituminous coal or other fat coals and particulate material less than about 0.1mm, then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.In other embodiments; If rich hydrocarbon particulate material comprises the mean diameter of hard coal, bituminous coal or other fat coals and particulate material greater than about 0.84mm, then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.In another embodiment, if rich hydrocarbon particulate material comprises the mean diameter of low grade coal and particulate material less than about 0.07mm, then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.In another embodiment, if rich hydrocarbon particulate material comprises the mean diameter of low grade coal and particulate material greater than about 0.4mm, then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.

Table 2. is used to extract the prescription of fat coal based on granularity

Table 3. is used to extract the prescription of low grade coal based on granularity

Granularity (mm diameter)	Lindenol	β-Terpineol 350	α-/β-terpenes	Other
					＜0.07mm	60-80％vol	10-30％vol	5％vol	0％vol
0.07mm-0.4mm	70-90％vol	5-25％vol	5％vol	0％vol
					＞0.4mm	75-95％vol	0-20％vol	5％vol	0％vol

About the prescription that extraction showed of Tar sands and coal, as shown in table 4, the extraction, liquefaction and/or the dissolved prescription that are used for resinous shale depend on granularity above being similar to.An embodiment that is used for extracting the method for compositions of hydrocarbonaceous organic substance in preparation; If rich hydrocarbon particulate material comprises the mean diameter of resinous shale and particulate material less than about 0.074mm, then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.In another embodiment, if rich hydrocarbon particulate material comprises the mean diameter of resinous shale and particulate material greater than about 0.42mm, then reduce the amount of lindenol in the turps liquid and increase the amount of β-Terpineol 350 in the turps liquid.

Table 4. is used for the prescription of stripping oil shale based on granularity

The extraction of crude oil prescription depend on similarly be extracted, the type of liquefaction and/or dissolved crude oil.As shown in table 5, be used to extract, the prescription of liquefaction and/or dissolving crude oil is granularity and the function of the quality of the density of the crude oil that is extracted.This method comprises provides turps liquid formulations, this prescription to comprise the lindenol of at least 50% volume and the β-Terpineol 350 of at least 20% volume; Amount based on lindenol and β-Terpineol 350 in the density adjustment turps liquid formulations of the liquid hydrocarbon that is extracted.In one embodiment, if the api gravity of the liquid hydrocarbon that is extracted, then reduces the amount of lindenol in the turps liquid greater than about 22 ° and increases the amount of β-Terpineol 350 in the turps liquid.In another embodiment, if the api gravity of the liquid hydrocarbon that is extracted, then increases the amount of lindenol in the turps liquid less than about 22 and reduces the amount of β-Terpineol 350 in the turps liquid.As employed at this, the API of lightweight oil is at least about 31 °, and the API of middle matter crude oil is about 22 °～about 31 °, and the API of BO is about 10 °～about 22 °, and the API of extra heavy oil is less than about 10 °.

Table 5. is used to extract the prescription of crude oil based on API density

In yet another aspect, provide a kind of preparation to be used for improving from the method for the turps liquid of the RF of the liquid hydrocarbonaceous organic substance of subterranean strata.This method comprises providing and comprises at least about the lindenol of 50% volume with at least about the prescription of the β-Terpineol 350 of 20% volume; And based on the amount of lindenol and β-Terpineol 350 in this prescription of the geologic feature of this subterranean strata adjustment.

In yet another aspect; Provide a kind of and be used for from the container cleaning of hydrocarbon containing liquid and/or the compsn of the hydro carbons of gathering, wherein said compsn comprises at least a compound that is selected from natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes or its mixture.In other embodiment; Be used to clean and/or the compsn of the hydro carbons of gathering can comprise be selected from Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-at least a compound of 8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice or its mixture.Also in other embodiment, be used to clean and/or the compsn of the hydro carbons of gathering can comprise and is selected from methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7, at least a compound of 8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture.In one embodiment, said composition comprises and is selected from following at least a compound: α-Pai Xi, beta-pinene, lindenol and β-Terpineol 350.In another embodiment, said composition comprises lindenol or the β-Terpineol 350 at least about 25% volume.

In yet another aspect, providing a kind of is used for from the container cleaning of hydrocarbon containing liquid and/or the method for the hydro carbons of gathering.This method comprises with the hydrocarbon cleaning combination and contacting with the inside of container to generate mixture; Said compsn comprises at least a compound that is selected from α-Pai Xi, beta-pinene, lindenol and β-Terpineol 350, and wherein this mixture comprises liquid hydrocarbon residue and hydrocarbon cleaning combination.Gather from container and remove this mixture.In certain embodiments, cleaning combination comprises lindenol or the β-Terpineol 350 at least about 25% volume.At some in other the embodiment, cleaning combination comprises at least about the lindenol of 25% volume with at least about the β-Terpineol 350 of 25% volume.

According to one embodiment of the invention; The method of extracting the hydrocarbonaceous organic substance from hydrocarbon-containing feedstock with a kind of is provided; Comprise through may further comprise the steps, extracting the hydrocarbonaceous organic substance by following steps or by the method that following steps are formed basically: non-aqueous hydrocarbon extracting liq first liquid of being made up of turps liquid basically that comprises that has basically no tensio-active agent is provided; Hydrocarbon-containing feedstock is contacted feasible formation extract mixture with non-water hydrocarbon extracting liq; Said extraction mixture comprises at least the hydrocarbonaceous organic substance in the non-aqueous hydrocarbon extracting liq that is extracted into of part, and will extract mixture and separate with the insoluble substance that contains from the non-aqueous hydrocarbon extracting liq of being insoluble to of hydrocarbon-containing feedstock.

Further, the hydrocarbonaceous organic substance contacts in the subterranean strata original position that contains the hydrocarbonaceous organic substance with the hydrocarbon extracting liq, and is provided for extracting from subterranean strata the device of hydrocarbonaceous organic substance.

In further embodiment; Extract mixture and can separate into first part and second section; The first part that extracts mixture comprises hydrocarbon product, and hydrocarbon product comprises the hydrocarbonaceous organic substance of part at least, and the second section that extracts mixture comprises the hydrocarbon extracting liq of part at least.

The amount of the organic substance that extracts from hydrocarbon-containing feedstock in one embodiment, is at least about 50%.In another embodiment, extract organic substance from hydrocarbon-containing feedstock at least about 50%.In further embodiment, extract the organic substance of about 75-100% from hydrocarbon-containing feedstock.

In another embodiment, for example when raw material be extra-heavy oil for example during Venezuela's extra-heavy oil, method of the present invention is extracted the organic substance at least about the 30-35% amount from hydrocarbon-containing feedstock effectively.

In further embodiment, at least about 80% be present in hydrocarbon-containing feedstock and in non-aqueous hydrocarbon extracting liq extractible hydrocarbon can in about 5 minutes extraction time, extract in the non-aqueous hydrocarbon extracting liq.In other embodiments, at least about 80% be present in hydrocarbon-containing feedstock and in non-aqueous hydrocarbon extracting liq extractible hydrocarbon can in about 3 minutes extraction time, extract in the non-aqueous hydrocarbon extracting liq.

In one embodiment, hydrocarbon-containing feedstock and hydrocarbon extracting liq contact with the ratio of 2: 1 turps flowing fluid ratio hydrocarbon-containing feedstock at least.

For example extracting from some embodiment that coal extracts, hydrocarbon is mainly from the volatility extracting section of coal, and the fixed carbon in this and the coal is opposite.

In further embodiment, hydrocarbon-containing feedstock can be the natural hydrocarbon-containing feedstock from natural geological formations.Some instances of natural hydrocarbon-containing feedstock are coal, crude oil, tar, Tar sands, resinous shale, oil-containing sand, Sweet natural gas, petroleum gas, crude asphalt, natural oil parent rock, rock asphalt and rock asphalt matter.

In an embodiment of method, the hydrocarbonaceous organic substance is extracted in the hydrocarbon extracting liq with the amount that is contained in the hydrocarbonaceous organic substance in the natural hydrocarbon-containing feedstock corresponding to about 1% to about 100% original packet.The hydrocarbonaceous organic substance that is contained in the natural hydrocarbon-containing feedstock at least about 90% original packet at least about 80%, in another embodiment at least about 70%, in another embodiment at least about 60%, in another embodiment at least about 40% or 50%, in one embodiment in some embodiments is extracted in the hydrocarbon extracting liq.Will from the natural hydrocarbon-containing feedstock some or all the hydrocarbonaceous organic substance extract the hydrocarbon extracting liq and can be sent to about 3 seconds to 180 minutes, about 97 seconds to 30 minutes or about 15 to 30 minutes of contact; In one embodiment in about 10 minutes; Contact temperature in about 10 to 400 ℃ scope at about 3 intramolecularly in another embodiment; In one embodiment less than 100 ℃; About 20-30 ℃ scope, the hydrocarbon extracting liq is about 10% to about 600% than the weight ratio of natural hydrocarbon-containing feedstock in another embodiment.In another embodiment, the hydrocarbon extracting liq is about 1: 1 to 2: 1 than the weight ratio of natural hydrocarbon-containing feedstock.

In one embodiment, be contained in contacting about 3 second with about 1: 1 to 2: 1 hydrocarbon extracting liq than the ratio of coal at least about the contact temperature of amount in about 80 to 100 ℃ of scopes of the total carbon of 30% to 90% hydrocarbonaceous organic substance and be extracted in the hydrocarbon extracting liq in the coal sample from the hydrocarbonaceous organic substance of coal with the amount that is contained in the hydrocarbonaceous organic substance in the coal sample corresponding to about 60% to about 100% original packet and/or original packet by 3 minutes.

In another embodiment, contacting about 3 second with about 1: 1 to 2: 1 hydrocarbon extracting liq than the ratio of Tar sands with the contact temperature of amount in about 30 to 60 ℃ of scopes that be contained in the hydrocarbonaceous organic substance in the tar sand sample corresponding to about 85% to about 100% original packet from the hydrocarbonaceous organic substance of Tar sands was extracted in the hydrocarbon extracting liq by 3 minutes.

In another embodiment, contacting about 3 second with about 1: 1 to 2: 1 hydrocarbon extracting liq than the ratio of resinous shale with the contact temperature of amount in about 100 to 1300 ℃ of scopes that be contained in the hydrocarbonaceous organic substance in the resinous shale appearance corresponding to about 50% to about 100% original packet from the hydrocarbonaceous organic substance of resinous shale was extracted in the hydrocarbon extracting liq by 3 minutes.

In another embodiment, the crude oil in subterranean strata contacts with hydrocarbon extracting liq original position in subterranean strata.At period of contact, contact about 3 second with about 1: 1 to 2: 1 hydrocarbon extracting liq than the ratio of the total pore volume of subterranean strata with the amount that is contained in the hydrocarbonaceous organic substance in the former oil sample corresponding to about 80% to about 100% original packet from the hydrocarbonaceous organic substance of crude oil and be extracted in the hydrocarbon extracting liq by 3 minutes.In another embodiment, contacting about 3 second with about 0.1 to 600% hydrocarbon extracting liq than the weight ratio of said hydrocarbon-containing feedstock with the contact temperature of amount in about 10 to 300 ℃ of scopes of the original hydrocarbonaceous organic substance that contains in the Sweet natural gas appearance that is equivalent to about 50%-100% from the hydrocarbonaceous organic substance of Sweet natural gas was extracted in the hydrocarbon extracting liq by 60 minutes.

In another embodiment; The invention provides and be used for modification from the method for the sulphur compound of the sulfur-and hydrocarbon-containing raw material of homogenous rock stratum natively; It makes the interaction modification hydrocarbon-containing feedstock effectively of the sulphur in hydrocarbon hydrocarbon extracting liq and the hydrocarbon-containing feedstock through hydrocarbon-containing feedstock being contacted with the hydrocarbon extracting liq or mixing, for example the corrosion through inhibited reaction property sulphur kind and toxic action is arranged.And this embodiment of the present invention can be applicable to gas sweetening.Through the desulfurization module of using gas processing factory, it can comprise that dish, packing etc. realize desulfurization.

The sulfur-and hydrocarbon-containing raw material can include but not limited to Sweet natural gas, petroleum gas, crude oil, Tar sands, resinous shale and coal.Existence such as sulphur can element sulphur, hydrogen sulfide, sulfide, disulphide, mercaptan, thiophene, thionaphthene.

In further embodiment, the sulfur-and hydrocarbon-containing raw material of gas form, such as Sweet natural gas or petroleum gas can be diffused through the hydrocarbon extracting liq by bubbling and make gas sweetening.

In one embodiment, the invention provides the corroding method that reduces corrodible surface.Passing through the for example processing or the production period of transportation, boring, borehole operation, exploration, manufacturing hydrocarbon, storage or the hydrocarbon-containing feedstock of pipeline, oil tanker, chest, fishing tool or drill bit, the metallic surface of the sulfocompound in the contact hydrocarbon-containing feedstock can be corroded.The invention provides through adding and reduce the significantly corrosive method of reduction of corrosive liquid to hydrocarbon-containing feedstock.Method of the present invention can suppress uniform corrosion and tubercular corrosion.When with hydrocarbon-containing feedstock when reducing corrosive liquid mixing and form mixture, and compare when not existing the hydrocarbon-containing feedstock that reduces corrosive liquid to contact when these surfaces, the corrosion rate on the corrodible surface that contacts with mixture significantly reduces.In one embodiment, reduce corrosive liquid and do not produce stable sulfonation component.In another embodiment, there is not the accumulation of sulphur in the hydrocarbon extracting liq.

In some embodiments, mixture comprises at least about the corrosive liquid of the reduction of 0.0001%-0.002% volume.In another embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.0005% volume.In another embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.001% volume.In another embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.0015% volume.In another embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.001%-0.002% volume.In another embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.01%-10% volume.In further embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.1%-5% volume.In another embodiment, mixture comprises at least about the corrosive liquid of the reduction of 0.5%-2% volume.In further embodiment, mixture comprises at least about the corrosive liquid of the reduction of 1% volume.

In further embodiment, and to compare when the surperficial surface corrosion that contacts when not having the hydrocarbon-containing feedstock that reduces corrosive liquid, corrosion rate reduces at least about 2 times.

In another embodiment, compare with the surface corrosion that contacts when not having the hydrocarbon-containing feedstock that reduces corrosive liquid when the surface, corrosion rate reduces at least about 3 times.In another embodiment, corrosion rate reduces at least about 4 times.

In one embodiment, reduce corrosive liquid and comprise lindenol, β-Terpineol 350, beta-pinene and Paracymene.In another embodiment, reduce lindenol, β-Terpineol 350 of about 30%-about 40%, the beta-pinene of about 5%-about 20% and the Paracymene of about 0-about 10% that corrosive liquid comprises about 40%-about 60%.In further embodiment, reduce the admixture that corrosive liquid comprises turps liquid.

In some embodiments, be crude oil, heavy crude, Tar sands, oil-containing sand, resinous shale, Sweet natural gas, petroleum gas or their combination with the hydrocarbon-containing feedstock that reduces corrosive liquid treatment.

In another embodiment; The invention provides the method for preparing gas containing hydrocarbon; It carries out through following: hydrocarbon-containing feedstock is contacted with first liquid of the basic surfactant-free that comprises non-aqueous hydrocarbon extracting liq; Wherein non-aqueous hydrocarbon extracting liq comprises turps liquid, forms mixture, and wherein mixture comprises the hydrocarbonaceous organic substance of part at least; The hydrocarbonaceous organic substance is extracted in the hydrocarbon extracting liq and heated mixt forms gas that contains hydrocarbon extraction raw material and the hydrocarbon that extracts from hydrocarbon-containing feedstock.

In some embodiments, hydrocarbon-containing feedstock is crude oil, heavy crude, Tar sands, oil-containing sand, resinous shale, Sweet natural gas, petroleum gas or their combination.

The invention provides from the gather method of hydrocarbonaceous organic substance of the recovery well increase that links to each other with the hydrocarbonaceous subterranean strata that contains hydrocarbon-containing feedstock.Said method comprises: the injection well that is communicated with the subterranean strata trickling is provided; Injection comprise basically by turps liquid for example first liquid of the basic surfactant-free of the non-aqueous hydrocarbon extracting liq formed of Terpineol 350 form the mixture that is included in the hydrocarbonaceous of the part at least organic substance in the part turps liquid at least in the rock stratum; Reclaim extraction mixture and separation and Extraction mixture generation hydrocarbon product stream and turps liquid flow from the rock stratum through recovery well.The hydrocarbon extracting liq can be recycled and be used to reinject.

The invention provides from the gather method of hydrocarbonaceous organic substance of Tar sands.Method comprises: the Tar sands that obtain to comprise the hydrocarbonaceous organic substance that can gather; First liquid flow that contains lindenol or β-Terpineol 350 hydrocarbon extracting liq one of at least comprising of basic surfactant-free is provided; Supply Tar sands sample is to contacting container; The Tar sands sample is contacted and stir Tar sands sample and hydrocarbon extracting liq in contacting container with the hydrocarbon extracting liq make formation extract mixture and residual raw materials; Separation and Extraction mixture and residual raw materials will be extracted mixture separation and become hydrocarbon product stream and hydrocarbon extracting liq stream and general hydrocarbon extracting liq stream at least partly to be recycled to contacting step.Extract mixture and be included in the hydrocarbonaceous organic substance of part at least and residual raw materials in the hydrocarbon extracting liq and comprise that part is from the insoluble substance in the hydrocarbon extracting liq that is insoluble to of Tar sands at least, hydrocarbon product stream comprises the hydrocarbonaceous organic substance from Tar sands of part at least.

The invention provides from the method for hydrocarbonaceous resinous shale (broken hydrocarbonaceous resinous shale) the hydrocarbonaceous organic substance of pulverizing of gathering.Method comprises: contacted comprising basically by being selected from the non-aqueous hydrocarbon extracting liq that following turps liquid forms of the hydrocarbonaceous resinous shale of pulverizing and basic surfactant-free: natural turps, synthesize turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2,6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture; Filter broken hydrocarbonaceous resinous shale; Broken hydrocarbonaceous resinous shale is dosed to contacting container, contacts broken hydrocarbonaceous resinous shale and hydrocarbon extracting liq and make formation extract mixture and residual raw materials, the hydrocarbonaceous organic substance from the hydrocarbon extracting liq in the separation and Extraction mixture produces hydrocarbon product stream and hydrocarbon extracting liq stream; Hydrocarbon product stream comprise from the hydrocarbonaceous organic substance of part at least of the hydrocarbonaceous resinous shale of pulverizing and at least the hydrocarbon extracting liq stream of part be recycled to contacting step.Extract mixture and be included in the hydrocarbonaceous of the part at least organic substance in the hydrocarbon extracting liq, residual raw materials comprises at least part from the insoluble substance in the hydrocarbon extracting liq that is insoluble to of resinous shale.

The invention provides from the gather method of hydrocarbonaceous organic substance of rich coal subterranean strata.Method comprises: the acquisition coal grinding comprises the coal of the hydrocarbonaceous organic substance that can gather to produce broken coal; Filter said broken coal; Said broken coal is dosed to contacting container, and said contacting container comprises that at least one inlet is used for the hydrocarbon extracting liq is supplied to said contacting container; Contacted comprising basically by being selected from the non-aqueous hydrocarbon extracting liq that following turps liquid forms of said broken coal and basic surfactant-free: natural turps, synthesize turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone or its mixture make to form and extract mixture and form residual raw materials; Said extraction mixture comprises the hydrocarbonaceous organic substance of at least a portion in the hydrocarbon extracting liq, and said residual raw materials comprises at least be insoluble to the insoluble substance in hydrocarbon extracting liq of part from coal; Separate the hydrocarbonaceous organic substance from the hydrocarbon extracting liq and produce hydrocarbon product stream and hydrocarbon extracting liq stream; Hydrocarbon product stream comprises the hydrocarbonaceous of the part at least organic substance from coal; The hydrocarbon extracting liq stream of part is recycled to contacting step with inciting somebody to action at least, and wherein said first liquid does not contain water or substantially anhydrous.

Embodiment

Embodiment 1. liquefies with the reagent lindenol from the coal in the coal seam, Pittsburgh in Pennsylvania Washington county in the present embodiment.Coal sample is available from the coal-hole (Coal Bank) of Pennsylvania State University, and this university is following to the proximate analysis that it provides: 2.00wt.% as received basis moisture, 9.25wt.% dry ash, 38.63wt.% drying and volatilizing thing and 50.12wt.% exsiccant fixed carbon.The granularity of coal sample is about 60 orders.About 60 gram lindenols are added to the about 30 gram coal samples that place extraction vessel lightly, and consequent reagent sample ratio is 2: 1.Contain gained lindenol and coal mixture capping but not the extraction vessel of tight seal be maintained at about 96 ℃ constant temperature down and continue to stir.Pressure in the extraction vessel maintains and is lower than about 1.01 * 10 slightly ⁵Under pascal's (1atm) the environmental stress, and do not make the lindenol boiling.After about 30 minutes, filtering mixt, and the coal particle that is retained on the filter uses washing with alcohol, and be dried to constant weight.Based on weight loss, the transformation efficiency of coal sample, that is, the liquefaction degree is measured as about 68wt.%.

Embodiment 2. present embodiments are almost identical with embodiment 1, and difference has two aspects.With the same among the embodiment 1, after about 30 minutes, the extraction vessel that contains coal sample and lindenol keeps about 30 minutes time under about 135 ℃ temperature in addition under temperature being maintained at about 96 ℃.Pressure in the extraction vessel remains on and is lower than about 1.01 * 10 slightly ⁵Under pascal's (1atm) the environmental stress.The transformation efficiency of coal sample, that is, the liquefaction degree is measured as about 70wt.%.

The coal sample of using among the coal sample that embodiment 3. uses and preceding two embodiment is originated identical and is had identical proximate analysis.About 31 gram lindenols are added in the about 31 gram coal samples in the extraction vessel.Mixture is under about 96 ℃ and be lower than about 1.01 * 10 slightly ⁵Pascal's (1atm) environmental stress kept about 30 minutes down.Through as preceding two embodiment after filtration, washing and drying with samples weighing, the transformation efficiency of the coal sample that measure to obtain, that is, the liquefaction degree is about 71wt.%.

Embodiment 4. present embodiments are identical with embodiment 3, and difference is to replace with hexane the lindenol of about 30wt.%, obtain comprising the reagent of hexane of lindenol and the 30wt.% of 70wt.%.With transformation efficiency, that is, the liquefaction degree is decreased to about 1.3wt.% like this.

Embodiment 5. is for present embodiment, the source of coal sample and proximate analysis, and temperature, pressure are identical with embodiment 3 with the test conditions of reagent sample ratio.Yet the time length of extraction was reduced to about 20 minutes from about 30 minutes.In addition, replace the lindenol of about 30wt.%, obtain comprising the reagent of 1-butanols of lindenol and the 30wt.% of 70wt.% with the 1-butanols.The coal amount of liquefaction is merely about 0.30 gram, and corresponding transformation efficiency is about 1.0wt.%.

Embodiment 6. is with regard to the source and the proximate analysis of coal sample, and temperature, pressure and the time length of extracting, and present embodiment is identical with embodiment 3.Yet the amount of the coal sample of use is about 25 grams, and reagent comprises about 24 gram (80wt.%) lindenols and about 6 gram (20wt.%) YLENE.Obtain comprising the reagent of YLENE of lindenol and the 30wt.% of 70wt.%.The coal of liquefaction is about 10.0 grams, and corresponding transformation efficiency is about 40wt.%.

Embodiment 7. liquefies with the reagent lindenol from the coal in the coal seam, Wyoming (Wyodak seam) in Wyoming State Campbell county in the present embodiment.Coal sample is available from the coal-hole (Coal Bank) of Pennsylvania State University, and this university is following to the proximate analysis that it provides: 26.30wt.% as received basis moisture, 7.57wt.% dry ash, 44.86wt.% drying and volatilizing thing and 47.57wt.% exsiccant fixed carbon.The granularity of coal sample is about 20 orders.About 60 gram lindenols are added to the about 30 gram coal samples that place extraction vessel lightly, and the reagent sample ratio is about 2: 1.Contain gained lindenol and coal mixture capping but not the extraction vessel of tight seal be maintained at about 96 ℃ constant temperature down and continue to stir.Pressure in the extraction vessel maintains and is lower than about 1.01 * 10 slightly ⁵Under pascal's (1atm) the environmental stress, and do not make the lindenol boiling.After about 30 minutes, filter the mixture in the extraction vessel, and the coal particle that is retained on the filter uses washing with alcohol, and be dried to constant weight.Based on weight loss, the transformation efficiency of coal sample, that is, the liquefaction degree is measured as 75wt.%.

Test in embodiment 8. present embodiments is carried out under the condition identical with the embodiment of front, and difference is an aspect.About 60 grams among about 15 gram lindenols rather than the front embodiment are added in about 30 gram coal samples, and thus obtained reagent coal ratio is 0.5: 1.The transformation efficiency of the coal sample that obtains, that is, about 75wt.% that the liquefaction degree obtains from the embodiment of front drops to about 69wt.%.

Embodiment 9. in the present embodiment; About 3 grams dissolve from the resinous shale of the green river reach (Green-river region) of the state of Colorado lindenol with about 9 grams; Consequent reagent sample ratio is 3: 1, with therefrom stripping oil matrix (organic substance) and/or pitch (organic substance).Organic carbon content comprises volatile matter and fixed carbon, is determined as about 22.66wt.% by the analysis company of authentication.Using granularity is that 60 purpose resinous shale samples are respectively in about 25 ℃ envrionment temperature be lower than about 1.01 * 10 slightly ⁵Carry out two tests under pascal's (1atm) the pressure.Through filter, the weight loss of the working sample of weighing after with washing with alcohol and drying.Weight loss is about 9wt.% after about 30 minutes, after about 45 minutes, is about 17wt.%.From these weight loss, organic substance is petrologen and/or bituminous transformation efficiency, that is, the extraction degree estimates that the former is about 40wt.%, and the latter is about 75wt.%.

Embodiment 10. present embodiments repeat the embodiment of front, and difference is carrying out single test under about 96 ℃ temperature rather than under about 25 ℃ temperature, continue about 15 minutes.The weight loss of resinous shale is about 12wt.%, the transformation efficiency of corresponding petrologen (organic substance), i.e. and extraction degree is about 53wt.%.

Embodiment 11. in the present embodiment, with the synthetic turps dissolving of commercial grade with extract from the pitch in the Tar sands of Canadian Alberta (organic substance).The Tar sands sample is studied board of management (Alberta Research Council) available from Alberta, and is following to the proximate analysis that this sample provides: 84.4wt.% drying solid, the as received basis moisture of dry pitch of 11.6wt.% and 4.0wt.%.The synthetic turps of about 30 grams is added to capping lightly but not in the about 15 gram Tar sands samples in the extraction vessel of tight seal, the reagent sample of employing is about 2: 1 than by weight.This extraction vessel of mixture that contains synthetic turps and the Tar sands of gained be maintained at about 96 ℃ constant temperature down and continue to stir.Pressure in the extraction vessel maintains and is lower than about 1.01 * 10 slightly ⁵Under pascal's (1atm) the environmental stress, and do not make synthetic turps boiling.After about 20 minutes, filter the mixture in the extraction vessel, and the solid (Tar sands) that is retained on the filter uses washing with alcohol, and be dried to constant weight.Based on weight loss, from the transformation efficiency of Tar sands sample medium pitch, that is, the extraction degree is measured as about 100wt.%.

Embodiment 12. in the present embodiment, about 60 grams from the source identical and Tar sands sample with identical proximate analysis with previous embodiment through about 60 grams lindenol rather than comprise that the synthetic turps of commercial grade of lindenol extracts.The reagent sample ratio of gained is 2: 1 in 1: 1 rather than the previous embodiment.Test is under about 96 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Pascal's (1atm) environmental stress continues about 30 minutes down.The transformation efficiency of the pitch in the Tar sands sample (organic substance), that is, the extraction degree is measured as about 100wt.%.

Embodiment 13. in the present embodiment, about 60 grams from the source identical and Tar sands sample with identical proximate analysis with two embodiment in front through the synthetic turps extraction of the commercial grade of about 60 grams.Therefore, the reagent sample of gained ratio is about 1: 1.Test is under about 96 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Carried out under pascal's (1atm) the environmental stress about 30 minutes.The transformation efficiency of the pitch in the Tar sands sample (organic substance), that is, the extraction degree is measured as about 70wt.%.

Step among the test repetition embodiment 8 in embodiment 14. present embodiments, difference is reagent sample than being decreased to about 0.5: 1 from about 2: 1.About 60 gram Tar sands samples extract with the synthetic turps of about 30 gram commercial grades.The transformation efficiency of pitch (organic substance), that is, about 100wt.% that the extraction degree obtains from embodiment 9 is reduced to about 70wt.%.

Test in embodiment 15. present embodiments repeats the step among the last embodiment, uses lindenol to replace the synthetic turps of commercial grade.The transformation efficiency of the pitch in the Tar sands sample (organic substance), that is, the extraction degree is about 70wt.%, and is the same with last embodiment.

Test in embodiment 16. present embodiments is used from the Tar sands sample that adopts the identical source of the embodiment of Tar sands with the front and have an identical proximate analysis and is being lower than about 1.01 * 10 slightly ⁵Carry out under pascal's (1atm) the environmental stress.The synthetic turps of about 60 gram commercial grades is added in about 60 gram Tar sands samples, and consequent reagent sample ratio is about 1: 1.The synthetic terebinthine temperature of sample and commercial grade kept about 30 minutes down at about 65 ℃, then at about 5 minutes internal cooling to about 15 ℃.Subsequently, with Tar sands sample filtering, washing, drying with weigh.Based on weight loss, the transformation efficiency of the pitch in the Tar sands sample (organic substance), that is, the extraction degree is measured as about 70wt.%.

Test in embodiment 17. present embodiments repeats the step of last embodiment, uses lindenol to replace the synthetic turps of commercial grade.The transformation efficiency of pitch (organic substance), that is, the extraction degree increases to about 90wt.% from about 70wt.%.

Embodiment 18. in the present embodiment, about 30 grams of weighing from the source identical and Tar sands sample with identical proximate analysis with embodiment 11-17 with the liquid of the toluene of the lindenol that comprises about 20 grams (80wt.%) and about 5 grams (20wt.%) under about 96 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Pascal's (1atm) environmental stress extracts down.The time length of test (reaction or extraction time) is about 30 minutes.The weight loss of sample is about 10.2 grams.From then on weight loss, the transformation efficiency of pitch (organic substance), that is, the extraction degree is estimated as about 33wt.%.

Embodiment 19. from three Tar sands samples that adopt the identical source of the Tar sands that use among all embodiment of Tar sands with the front and have an identical proximate analysis with the lindenol that comprises different amounts and alcoholic acid reagent under about 15 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Pascal's (1atm) environmental stress extracts down.For each Tar sands sample, the time length of each test (reaction or extraction time) is about 15 minutes.First sample is with comprising about 0 gram (0wt.%) lindenol and about 15 gram (100wt.%) alcoholic acid mixtures, that is, straight alcohol extracts.Second sample is with comprising that about 7.5 gram (50wt.%) lindenols and about 7.5 gram (50wt.%) alcoholic acid mixtures extract.The 3rd sample is with comprising that about 12 gram (80wt.%) lindenols and about 3 gram (20wt.%) alcoholic acid mixtures extract.For first, second and the 3rd sample, the transformation efficiency of the weight loss in three samples and the pitch (organic substance) of estimation, that is, the extraction degree is respectively about 0.2 gram (1.0wt.%), and 0.6 gram (3.0wt.%) and 0.9 restrains (4.5wt.%).

Embodiment 20. mean sizes for the irregular shape bead of commercial grade bituminous of about 15mm under about 22 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Dissolve and extraction with lindenol under pascal's (1atm) the environmental stress.First sample that is weighed as about 20 grams is with the lindenol dissolving of about 40 grams and extract, and weighs also and to dissolve and extraction for second sample of about 20 grams lindenol with about 20 grams.Hydrocarbon in 30 minutes latter two samples is extracted fully.Carry out dissolving and the extraction of these tests with simulation heavy crude, heavy crude often is rich in and is similar to the bituminous bituminous matter.

Embodiment 21. in the present embodiment; From adopting the identical source of the Tar sands that use among all embodiment of Tar sands with the front and having pitch (organic substance) in the Tar sands of identical proximate analysis with two kinds of different vegetables oil, VT 18 and Semen Maydis oil extraction.Vegetables oil and turps liquid are complete miscibilities.In first test, be weighed as VT 18 that the Tar sands sample and about 30 of about 15 grams restrains under about 96 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Mixing and lasting stir about are 20 minutes under pascal's (1atm) the environmental stress.Weight loss is about 0.5 gram, weight loss thus, and the transformation efficiency of sample estimates medium pitch, that is, the extraction degree is about 3.3wt.%.In second test, be weighed as Semen Maydis oil that the Tar sands sample and about 60 of about 30 grams restrains under about 175 ℃ temperature and be lower than about 1.01 * 10 slightly ⁵Mixing and lasting stir about are 30 minutes under pascal's (1atm) the environmental stress.Weight loss is about 4.8 grams, weight loss thus, and the transformation efficiency of sample estimates medium pitch, that is, the extraction degree is about 12wt.%.

22. pairs of Berea sandstones of embodiment block up the heart (Berea sandstone plug core) sample and carry out two experiments to measure the effect of reagent injection to the rock core oil recovery.First experiment is designed to be determined at injects the oil recovery increase that is produced by lindenol after the oil field has been filled to the limit.The rock core of selecting contains the experimental oil of the similar crude oil of 9.01mL.Produce 4.6mL oil with the aqueous solution water filling that contains 3.0% Repone K.The lindenol that injects five (5) pore volumes produces other 3.61mL oil, thereby makes the remaining oil of rock core less than 8.0% of original volume.Second experiment be designed to represent from inject with lindenol the desired acquisition of undeveloped reserves than high recovery rate.The rock core of selecting contains the experimental oil of the similar crude oil of 8.85mL.Behind the lindenol that injects about 0.5 pore volume, begin produce oil, continue to the lindenol that injects 3.5 pore volumes always; Yet, the most oil of behind the lindenol that only injects 2.5 pore volumes, just gathering.The total of having gathered 7.94mL experimental oil, thus make the remaining oil of rock core less than 7.5% of original volume.

In a test, the multiple ratio of test turps liquid and Tar sands sample.For following each test that provides, turps liquid has identical prescription, and wherein said composition comprises the β-Terpineol 350 of the lindenol of about 60% volume, about 20% volume and the γ-Terpineol 350 of about 20% volume.Tar sands are the different ore batch mixings from Canadian Alberta, and asphalt content is about 12wt%, and water-content is about 4-5wt%.Test is all carried out under the listed all temps of table 6.

Shown in following table 6, the hydrocarbon RF from Tar sands under all ratios that provide below (that is, the ratio of turps liquid and Tar sands is about 1: 2～2: 1) has all obtained good hydrocarbon RF and can distinguish that difference is very little.About the temperature of extracting, believe that the optimum temps for extraction from Tar sands, dissolving and/or liquefaction hydro carbons is about 65 ℃.Shown in table, in the time of about 130 ℃, the hydrocarbon amount of gathering from Tar sands reduces.Yet, note, for some solid of the hydro carbons that is difficult to especially to gather, increase the amount that the temperature of extracting solvent can increase the hydro carbons of being gathered.At last, show that duration of contact is very little to the influence of the amount of substance that is extracted.This possibly be because the shortest extraction time is about 20 minutes, believes that this extraction time is enough to from Tar sands, extracting hydro carbons.

Table 6

Use optional solvent, promptly ethanol and Semen Maydis oil carry out additional test, compare with the compsn of the γ-Terpineol 350 of the β-Terpineol 350 of the lindenol that comprises about 60% volume, about 20% volume and about 20% volume.The performance that is noted that ethanol and Semen Maydis oil in the table 7 that provides below unexpectedly is significantly less than the compsn of γ-Terpineol 350 of β-Terpineol 350 and about 20% volume of the lindenol that comprises about 60% volume, about 20% volume.For example, the Terpineol 350 compsn has extracted extractible hydro carbons fully or almost entirely, and ethanol has only obtained about gathered hydro carbons of 10%, and the Semen Maydis oil of heating has only obtained about gathered hydro carbons of 33%.

Table 7

Shown in following table 8, the performance of multiple turps liquid formulations is provided, comprise the turps liquid formulations of the combination that only comprises lindenol and lindenol and multiple known organic solvent.Three kinds of compsns that in table, at first provide comprise lindenol, β-Terpineol 350 and γ-Terpineol 350.For example, first compsn comprises the β-Terpineol 350 of the lindenol of about 60% volume, about 30% volume and the γ-Terpineol 350 of about 10% volume.The result shows that unexpectedly the concentration along with lindenol increases, and the performance of turps liquid increases to the moment when turps liquid comprises about 70% lindenol, can realize from the Tar sands sample, extracting whole hydrocarbon materials this moment.

Provided second group of data for extracting the hydrocarbonaceous Tar sands with pure lindenol.It is as shown in the table, maybe be because the hydrocarbon content of sample to be inconsistent, and extraction has surpassed 100%.Yet the result has proved beat all result substantially, that is, but lindenol can extract all recovery of hydrocarbons basically from the Tar sands sample.

The effectiveness of last group data declaration lindenol that provides in the table 8 at last, and the mixing system of known organic solvent.It is as shown in the table, adopts to comprise that ratio is 1: the recovery of hydrocarbons but 1 lindenol and alcoholic acid compsn have been gathered basically fully.This result is beat all, but because straight alcohol has only removed about 10% of total recovery of hydrocarbons.In addition, comprise that ratio is 1: 1 or 3: 77% and 92% of total recovery of hydrocarbons but the mixing system of 1 lindenol and toluene has still been gathered.This result is beat all.

Table 8

Various spray liquid below embodiment 23. about 30g Tar sands samples are used: the water of the admixture of d-PC 560, turps liquid and conduct contrast.Temperature maintenance is at about 18 ℃.After about 5,10,15,20,25 and 30 seconds of duration of contact, measured the bituminous percentage of gathering.The admixture of turps liquid is than the more effective extraction agent of d-PC 560, yet water is invalid (see figure 5).

Embodiment 24. about 15g Tar sands samples contact 97 seconds with the admixture sprinkling of d-PC 560 or turps liquid and with said liquid.The ratio of flowing fluid ratio Tar sands be about 1: 1 to about 6: 1 scope.RF is that in the scope of this blending ratio, the admixture of turps liquid extracts more pitch (see figure 6) than PC 560 from 84% of 1: 1 o'clock 54% to 6: 1 o'clock.

The turps liquid that embodiment 25. has measured some kinds and combination with respect to each liquid from the gather effect of extraction hydrocarbon of bituminous ability of Tar sands sample.In each test, descend with the following about 15g Tar sands of a kind of turps liquid treatment sample at about 18 ℃: the admixture of lindenol, β-Terpineol 350, beta-pinene, α-Pai Xi Paracymene, d-PC 560 and turps liquid.After the duration of contact of about 5 (Fig. 7) and about 15 (Fig. 8) minutes, measure the bituminous percentage of gathering.The all turps liquid of data presentation has extracted the pitch of a great deal of from Tar sands.The admixture of turps liquid is the most effective extraction agent in the ratio of all flowing fluid ratio raw materials, is extracting the asphalt content (see figure 7) of having gathered nearly all in about 5 minutes time.

Embodiment 26. has compared can be by the amount of the SAE 40 (moderate severe crude oil) of the admixture of turps liquid extraction and the amount of propyl carbinol, hexalin and 1-enanthol.Under about 35 ℃, the amount of finding to be extracted the SAE 40 in the admixture of the turps liquid of being made up of about 50% lindenol, about 35% β-Terpineol 350, about 10% beta-pinene and about 5% Paracymene is howed about 8.14-, 6.67-and 7.46 times than the amount of the SAE 40 that extracts 100ml propyl carbinol, 100ml hexalin and 100ml 1-enanthol respectively.Each basic soln contains 97% Starso of 150ml.

Embodiment 27. about 15g and 30g paraffin sample are being extracted about 15 minutes with about 100g bituminous matter sample under about 60 ℃ in the admixture of 100% lindenol and 100% turps liquid.Table 9 demonstration is extracted the hydrocarbon solid percentage in the turps liquid.

Comparative example. in a comparative example, compared with the method described in the embodiment 27 and used liquid and use lindenol and polycomponent turps system liquid fossil waxes and bituminous matter by about 1/3 terpene (PC 560, firpene), about 1/3 heavier petroleum fraction and about 1/3 low-density oil fractions consisting.The paraffin and the bitum percentile contrast of extracting are presented in the table 9.

Table 9

Embodiment 28. tables 10 show that the oil viscosity that contacts the back Different Weight with turps liquid reduces.In 20 seconds, read measured value at about 21 ℃.Oil that will be heavier contacts with turps liquid admixture and obtains maximum percentile viscosity reduction.

Table 10

(Alabama USA) is exposed to and contains 500ppm Na embodiment 29. corrosion measurements for METAL SAMPLES COMPANY, Munford with the test piece of API X-65 carbon steel ₂The ASTM of S substitutes seawater, regulates pH to about 4.8 with acetate, 2 weeks of continuous flow.The base soln that control sample only contains seawater does not have corrosion inhibitor.Sample I, II and III contain the turps liquid admixture of 0.0005%, 0.001% and 0.0015% volume of having an appointment.The corrosion rate of record with observed in each test piece the crack corrode directly identical.Sample III is made up of the turps liquid admixture of about 0.0015% volume, has produced minimum average corrosion rate (seeing table 11) and has not had tubercular corrosion.

Table 11

Embodiment 30. has compared the turps liquid admixture and the extractability that contains the d-PC 560 of 0,3,9 and 12% tensio-active agent (from the sulfonic acid N-95 of Huntsman) of surfactant-free.(the turps liquid admixture of surfactant-free gathers materials weight: 92.9% with containing the d-PC 560 of tensio-active agent and the high-quality road oil of 30g.Pitch emphasis: 6.6%, polymkeric substance is heavy: 0.5%) with 1: 1 flowing fluid ratio bituminous ratio 45 ℃ of contacts 2 minutes.The amount that the pitch of the turps liquid admixture of surfactant-free is gathered is 8.3%, and contains only gather respectively 4%, 6.3%, 5.3% and 5.7% pitch of 4%, 6.3%, 5.3% and 5.7% bituminous d-PC 560.The turps liquid admixture of surfactant-free than the d-PC 560 that contains or do not contain tensio-active agent from the more hydrocarbonaceous organic substance of bitumen extraction.

In specification sheets, and the result who from hydrocarbon-containing feedstock, extracts the hydrocarbonaceous organic substance described in the embodiment is beat all especially.

Such as this paper survey, in some samples, RF is that productive rate surpasses 100%, this be because some hydrocarbon-containing feedstock for example Tar sands comprise the mixture of the especially sticking liquid relatively coarse solid particulate different with the out-of-shape size.Therefore, because these variable factors are measured sometimes above 100% based on the gathering of value of the average hydrocarbon materials in the hydrocarbon-containing feedstock.And some experimental error is any experiment inherent.

As this employed term approximately with probably should be understood to include said numerical value 5% within arbitrary value.And, should be interpreted as the top and bottom that comprise said scope about numerical range term pact and general narration.As being interpreted as unique identifying feature, be not any particular order that refers to or be limited to each key element or step in this employed term first, second, third grade.

Although only show in some embodiments of the present invention or the present invention has been described, it will be apparent to one skilled in the art that to the invention is not restricted to this, but under the prerequisite that does not deviate from scope of the present invention, be easy to make many variations.

Claims (according to the modification of the 19th of treaty)

1. method of from hydrocarbon-containing feedstock, extracting the hydrocarbonaceous organic substance comprises through extracted the step of hydrocarbonaceous organic substance basically by the following method of forming:

First liquid of basic surfactant-free is provided; This first liquid comprises basic by being selected from the non-aqueous hydrocarbon extracting liq that following turps liquid is formed: natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene are (to the Meng-1; The 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene, Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone and composition thereof;

Said hydrocarbon-containing feedstock is contacted feasible formation extract mixture with said hydrocarbon extracting liq, said extraction mixture comprises the said hydrocarbonaceous organic substance in the hydrocarbon extracting liq that extracts at least partly; With

Separation and Extraction mixture and any residual raw materials, this residual raw materials contains the insoluble substance from the said hydrocarbon extracting liq of being insoluble to of said hydrocarbon-containing feedstock.

2. the method for claim 1 further comprises step:

Be provided for said hydrocarbonaceous organic substance and the said turps liquid device that original position contacts in the subterranean strata that contains said hydrocarbonaceous organic substance, and the device that is used for extracting from said subterranean strata said hydrocarbonaceous organic substance.

3. the method for claim 1; Further comprise step: will extract mixture separation and become first part and second section; The first part of said extraction mixture comprises hydrocarbon product; This hydrocarbon product comprises the hydrocarbonaceous organic substance of part at least, and the second section of said extraction mixture comprises the turps liquid of part at least.

4. method as claimed in claim 3 further comprises step:

At least partly said turps liquid is recycled in the said hydrocarbon extracting liq to be used for said contacting step.

5. method as claimed in claim 3 wherein is extracted in a site and carries out, and is separated in this extraction site and maybe carries out near this extraction site.

6. method as claimed in claim 3 wherein is extracted in a site and carries out, and the upstream device that is separated in away from this extraction site carries out.

7. method as claimed in claim 3 wherein is extracted in a site and carries out, and in this extraction site maybe near this extraction site the hydrocarbon extracting liq partly separate with the hydrocarbonaceous organic substance.

8. method as claimed in claim 2, wherein said hydrocarbon-containing feedstock is in subterranean strata, and said hydrocarbon-containing feedstock takes place with contacting in said subterranean strata original position of said turps liquid; And further comprise the steps:

Through the recovery well that is communicated with the said subterranean strata fluid said extraction mixture of gathering, wherein said residual raw materials original position is retained in the said subterranean strata.

9. method as claimed in claim 8 further comprises the step that hydrocarbon extracting liq stream is injected into the further extraction that is used for hydrocarbon materials in the subterranean strata.

10. the method for claim 1, wherein said turps liquid comprise at least about the lindenol of 30% volume with at least about the β-Terpineol 350 of 15% volume.

11. the method for claim 1, wherein said turps liquid comprise at least about the lindenol of 50% volume with at least about the β-Terpineol 350 of 20% volume.

12. the method for claim 1, wherein said turps further comprise at least a in α-terpenes, β-terpenes or the γ-terpenes.

13. the method for claim 1, wherein said turps liquid comprises lindenol and β-Terpineol 350, and wherein lindenol is at least about 1.3: 1 with the ratio of β-Terpineol 350.

14. the method for claim 1, wherein said turps liquid comprises lindenol and β-Terpineol 350, and wherein lindenol is at least about 2: 1 with the ratio of β-Terpineol 350.

15. the method for claim 1, wherein said turps liquid is made up of lindenol, β-Terpineol 350, α-terpenes and β-terpenic mixture basically.

16. the method for claim 1, wherein said turps liquid is made up of the mixture of lindenol and β-Terpineol 350 basically.

17. the method for claim 1, wherein said first liquid is made up of lindenol, β-Terpineol 350, α-terpenes and β-terpenic mixture basically.

18. the method for claim 1, the amount of the organic substance that wherein extracts from hydrocarbon-containing feedstock is about at least 50%.

19. method as claimed in claim 18, the amount of the organic substance that wherein extracts from hydrocarbon-containing feedstock is about at least 70%.

20. method as claimed in claim 19, the amount of the organic substance that wherein extracts from hydrocarbon-containing feedstock is about at least 75%.

21. method as claimed in claim 20, the amount of the organic substance that wherein extracts from hydrocarbon-containing feedstock is about at least 90%.

22. method as claimed in claim 21, the amount of the organic substance that wherein extracts from hydrocarbon-containing feedstock is about 100%.

23. the method for claim 1 wherein is present in being extracted in the said turps liquid in that said hydrocarbon-containing feedstock is contacted in about 5 minutes with said first liquid at least about 80% hydrocarbon in the said turps liquid of extracting in the said hydrocarbon-containing feedstock.

24. the ratio of the amount of any other turps miscible solvent that contains in the method for claim 1, the amount of wherein said turps liquid and said first liquid is at least about 1: 1.

25. the ratio of the amount of any other turps miscible solvent that contains in the method as claimed in claim 24, the amount of wherein said turps liquid and said first liquid is at least about 9: 4.

26. the ratio of the amount of any other turps miscible solvent that contains in the method as claimed in claim 25, the amount of wherein said turps liquid and said first liquid is at least about 3: 1.

27. the ratio of the amount of any other turps miscible solvent that contains in the method as claimed in claim 26, the amount of wherein said turps liquid and said first liquid is at least about 4: 1.

28. the method for claim 1, wherein said first liquid is made up of said turps liquid basically.

29. the method for claim 1, wherein said hydrocarbon-containing feedstock contacts with the ratio that the ratio of said hydrocarbon-containing feedstock is at least about 2: 1 with said turps liquid with said turps liquid.

30. the method for claim 1; Wherein said hydrocarbon-containing feedstock is the natural hydrocarbon-containing feedstock from natural geological formations, and wherein said natural geological formations contains at least a of coal, crude oil, extra-heavy oil, tar, Tar sands, resinous shale, oil-sand, Sweet natural gas, crude asphalt, natural oil parent rock, rock asphalt or rock asphalt matter.

31. method as claimed in claim 30; The amount that wherein is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq at said period of contact is equivalent to the amount of about 30%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance is in about 3 seconds to 180 minutes of said contact; Under the contact temperature of about 10 to 400 ℃ of scopes, be extracted in the said hydrocarbon extracting liq with the about 10%-600% of the weight ratio of hydrocarbon extracting liq and natural hydrocarbon-containing feedstock.

32. method as claimed in claim 30; The amount that wherein is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq at said period of contact is equivalent to the amount of about 75%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance is in about 3 seconds to 3 minutes of said contact; Under the contact temperature of about 20 to 30 ℃ of scopes, be extracted in the said hydrocarbon extracting liq in about 1: 1 to 2: 1 with the weight ratio of hydrocarbon extracting liq and natural hydrocarbon-containing feedstock.

33. method as claimed in claim 30; The amount that wherein is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq at said period of contact is equivalent to the amount of about 85%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance is in about 3 seconds to 3 minutes of said contact; Under the contact temperature of about 20 to 30 ℃ of scopes, be extracted in the said hydrocarbon extracting liq in about 1: 1 to 2: 1 with the weight ratio of hydrocarbon extracting liq and natural hydrocarbon-containing feedstock.

34. method as claimed in claim 31; Wherein said hydrocarbon-containing feedstock is a coal; And wherein at said period of contact; The amount that is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq is equivalent to the amount of about 60%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance under the contact temperature of about 80 to 100 ℃ of scopes, was extracted in the said hydrocarbon extracting liq with the weight ratio of hydrocarbon extracting liq and said hydrocarbon-containing feedstock in about 3 seconds to 3 minutes of said contact in about 1: 1 to 2: 1.

35. method as claimed in claim 31; Wherein said hydrocarbon-containing feedstock is Tar sands; And wherein at said period of contact; The amount that is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq is equivalent to the amount of about 85%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance under the contact temperature of about 30 to 60 ℃ of scopes, was extracted in the said hydrocarbon extracting liq with the weight ratio of hydrocarbon extracting liq and said hydrocarbon-containing feedstock in about 3 seconds to 3 minutes of said contact in about 1: 1 to 2: 1.

36. method as claimed in claim 31; Wherein said hydrocarbon-containing feedstock is a resinous shale; And wherein at said period of contact; The amount that is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq is equivalent to the amount of about 50%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance under the contact temperature of about 100 to 130 ℃ of scopes, was extracted in the said hydrocarbon extracting liq with the weight ratio of hydrocarbon extracting liq and said hydrocarbon-containing feedstock in about 3 seconds to 3 minutes of said contact in about 1: 1 to 2: 1.

37. method as claimed in claim 30; Wherein said hydrocarbon-containing feedstock is the crude oil in the subterranean strata; And said crude oil occurs in the subterranean strata with the original position that contacts of said hydrocarbon extracting liq; And wherein at said period of contact, the amount that is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq is equivalent to the amount of about 80%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock, and said hydrocarbonaceous organic substance is in about 3 seconds to 3 minutes of said contact;, be extracted in the said hydrocarbon extracting liq than about 1: 1 to 1: 2 with hydrocarbon extracting liq and said subterranean strata total pore volume.

38. method as claimed in claim 30; Wherein said hydrocarbon-containing feedstock is the extra-heavy oil in the subterranean strata; And said crude oil occurs in subterranean strata with the original position that contacts of said hydrocarbon extracting liq; And wherein at said period of contact; The amount that is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq is equivalent to the amount of about 25%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock, and said hydrocarbonaceous organic substance is extracted in the said hydrocarbon extracting liq than about 1: 1 to 1: 2 with hydrocarbon extracting liq and said subterranean strata total pore volume in about 3 seconds to 60 minutes of said contact.

39. method as claimed in claim 31; Wherein said hydrocarbon-containing feedstock is Sweet natural gas or petroleum gas; And wherein at said period of contact; The amount that is extracted the hydrocarbonaceous organic substance in the hydrocarbon extracting liq is equivalent to the amount of about 50%-100% of the original hydrocarbonaceous organic substance that contains in the said natural hydrocarbon-containing feedstock; Said hydrocarbonaceous organic substance under the contact temperature of about 10 to 300 ℃ of scopes, is extracted in the hydrocarbon extracting liq to 600% with the weight ratio of hydrocarbon extracting liq and said natural hydrocarbon-containing feedstock about 0.1 in about 3 seconds to 60 minutes of said contact.

40. the method that is used for extracting from hydrocarbon-containing feedstock the hydrocarbonaceous organic substance as claimed in claim 1, said hydrocarbon-containing feedstock comprises Tar sands,

Wherein said hydrocarbon-containing feedstock and contacting of said hydrocarbon extracting liq comprise the steps: with said Tar sands be supplied to extraction vessel internal portion and with the said internal portion that said hydrocarbon extracting liq is supplied to said extraction vessel continue with for some time can operate the said hydrocarbonaceous organic substance that is used for extracting major portion from said hydrocarbon-containing feedstock.

41. the method that is used for extracting from hydrocarbon-containing feedstock the hydrocarbonaceous organic substance as claimed in claim 1, said hydrocarbon-containing feedstock comprises resinous shale, and said method further may further comprise the steps:

Grind said hydrocarbonaceous organic substance to form a plurality of particles, said particle is limited to the average diameter size in 4mm～25mm scope, makes said a plurality of particle contact with said hydrocarbon extracting liq.

42. the method that is used for extracting from hydrocarbon-containing feedstock the hydrocarbonaceous organic substance as claimed in claim 1, said hydrocarbon-containing feedstock comprises coal, and said method further may further comprise the steps:

Grind said hydrocarbonaceous organic substance to form a plurality of particles, the average diameter size that said particle is limited to 0.01mm～1mm makes said a plurality of particle contact with said hydrocarbon extracting liq.

43. one kind from the gather method of hydrocarbonaceous organic substance of Tar sands, said method comprises through extracted the step of hydrocarbonaceous organic substance basically by the following method of forming:

Acquisition comprises the Tar sands of the hydrocarbonaceous organic substance that can gather;

First liquid that comprises the hydrocarbon extracting liq of basic surfactant-free is provided, and the hydrocarbon extracting liq comprises and contains lindenol or β-Terpineol 350 turps liquid one of at least;

Said Tar sands sample is supplied to contacting container, and said contacting container comprises that at least one inlet is used to supply said hydrocarbon extracting liq;

Said Tar sands sample is contacted in contacting container with said hydrocarbon extracting liq; And stir said Tar sands sample and said hydrocarbon extracting liq; Make to form and extract mixture and form residual raw materials; Said extraction mixture comprises the said hydrocarbonaceous organic substance of at least a portion in the hydrocarbon extracting liq, and said residual raw materials comprises the insoluble substance of at least a portion from the said hydrocarbon extracting liq of being insoluble to of said Tar sands;

Said extraction mixture is separated with said residual raw materials;

With said extraction mixture separation is hydrocarbon product stream and hydrocarbon extracting liq stream, and said hydrocarbon product stream comprises the said hydrocarbonaceous organic substance of at least a portion from said Tar sands; And

The said hydrocarbon extracting liq stream of at least a portion is recycled to said contacting step.

The method of hydrocarbonaceous organic substance 44. the hydrocarbonaceous resinous shale from pulverizing is gathered, this method comprise through extracted the step of hydrocarbonaceous organic substance basically by the following method of forming:

The hydrocarbonaceous resinous shale of said pulverizing is provided;

First liquid of basic surfactant-free is provided; It comprises basic by being selected from the non-aqueous hydrocarbon extracting liq that following turps liquid is formed: natural turps, synthesize turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone and its mixture;

The hydrocarbonaceous resinous shale of said pulverizing is filtered;

The hydrocarbonaceous resinous shale of said pulverizing is dosed to contacting container, and said contacting container comprises that at least one inlet is used for said hydrocarbon extracting liq is supplied to said contacting container;

The hydrocarbonaceous resinous shale of said pulverizing is contacted with the hydrocarbon extracting liq; Make to form and extract mixture and form residual raw materials; Said extraction mixture comprises the said hydrocarbonaceous organic substance of at least a portion in said hydrocarbon extracting liq, and said residual raw materials comprises the insoluble substance of at least a portion from the said hydrocarbon extracting liq of being insoluble to of said resinous shale;

Said extraction mixture is separated with said residual raw materials;

Said hydrocarbonaceous organic substance in the said extraction mixture is separated with said hydrocarbon extracting liq to produce hydrocarbon product stream and hydrocarbon extracting liq stream, and said hydrocarbon product stream comprises the said hydrocarbonaceous organic substance of at least a portion from the hydrocarbonaceous resinous shale of said pulverizing; And

The method of hydrocarbonaceous organic substance 45. the rich coal subterranean strata from hydrocarbonaceous is gathered, this method comprise through extracted the step of hydrocarbonaceous organic substance basically by the following method of forming:

Obtain coal, said coal comprises the hydrocarbonaceous organic substance that can gather;

With said coal grinding to produce broken coal;

Filter said broken coal;

Said broken coal is dosed to contacting container, and said contacting container comprises that at least one inlet is used for the hydrocarbon extracting liq is supplied to said contacting container;

The non-aqueous hydrocarbon extracting liq of said broken coal with basic surfactant-free contacted; Said hydrocarbon extracting liq is formed by being selected from following turps liquid basically: natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2,6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone; With its mixture; Make to form and extract mixture and form residual raw materials that said extraction mixture comprises the said hydrocarbonaceous organic substance of at least a portion in the hydrocarbon extracting liq, said residual raw materials comprises the insoluble substance of at least a portion from the said hydrocarbon extracting liq of being insoluble to of said coal;

With said residual raw materials and said extraction mixture separation;

Said hydrocarbonaceous organic substance is separated with said hydrocarbon extracting liq to produce hydrocarbon product stream and hydrocarbon extracting liq stream, and said hydrocarbon product stream comprises the said hydrocarbonaceous organic substance of at least a portion from said coal; And

The said hydrocarbon extracting liq stream of at least a portion is recycled to said contacting step, and wherein said first liquid does not contain water or does not have water basically.

46. one kind from recovery well that the subterranean strata of hydrocarbonaceous is connected improve the method for the RF of hydrocarbonaceous organic substance, said subterranean strata comprises hydrocarbon-containing feedstock, this method comprises through extracted the step of hydrocarbonaceous organic substance basically by the following method of forming:

The injection well is provided, and said injection well is communicated with said subterranean strata fluid;

First liquid of basic surfactant-free is provided, and said first liquid comprises non-aqueous hydrocarbon extracting liq, and said non-aqueous hydrocarbon extracting liq is made up of the turps liquid that comprises Terpineol 350 basically;

Said hydrocarbon extracting liq is injected through said injection well and is injected into said rock stratum; Wherein said hydrocarbon extracting liq and form from the hydrocarbonaceous organic substance of the subterranean strata of said hydrocarbonaceous and to extract mixture; Said extraction mixture comprises the said hydrocarbonaceous organic substance of at least a portion, and said at least a portion hydrocarbonaceous organic substance is in part hydrocarbon extracting liq at least;

Through the said recovery well said extraction mixture of gathering from said rock stratum; And

Separate said extraction mixture to produce hydrocarbon product stream and hydrocarbon extracting liq stream.

47. a modification comprises step in the method from the sulphur compound in the sulfur-and hydrocarbon-containing raw material of homogenous rock stratum natively:

First liquid of comprising of basic surfactant-free of non-aqueous hydrocarbon extracting liq is provided; Said non-aqueous hydrocarbon extracting liq is formed by being selected from following turps liquid basically: natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2,6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone; With its mixture and

Contact hydrocarbon-containing feedstock and said hydrocarbon extracting liq, make with said hydrocarbon-containing feedstock in sulphur interact and the said hydrocarbon-containing feedstock of modification thus;

Wherein said sulfur-and hydrocarbon-containing raw material is selected from Sweet natural gas, petroleum gas, crude oil, Tar sands, resinous shale and coal.

48. method as claimed in claim 46, wherein said contact comprises mixing.

49. method as claimed in claim 46, wherein said hydrocarbon-containing feedstock contains Sweet natural gas or petroleum gas, and wherein said Sweet natural gas or petroleum gas bubbling are through said turps liquid.

50. a reduction is used for the corroding method on transportation, storage or the corrodible surface of treatment facility of hydrocarbon-containing feedstock, comprises step:

Make hydrocarbon-containing feedstock and the corrosive liquid of the non-aqueous reduction that reduces corrosive amount form mixture; The corrosive liquid of said non-aqueous reduction is formed by being selected from following turps liquid basically: natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone and its mixture;

Said corrodible surface is contacted with said mixture, wherein compare with the corrosion on said surface when said surface contacts the said hydrocarbon-containing feedstock that does not have the corrosive liquid of said reduction, the corrosion rate on said surface significantly reduces.

51. method as claimed in claim 49, wherein said mixture comprise the corrosive liquid of said reduction greater than about 0.0005%.

52. method as claimed in claim 50, wherein said mixture comprise the corrosive liquid of said reduction greater than about 0.001%.

53. method as claimed in claim 51, wherein said mixture comprise the corrosive liquid of said reduction greater than about 0.0015%.

54. method as claimed in claim 49, the amount of the corrosive liquid of wherein said reduction are equivalent to the amount at least about 0.001% to 0.002% said hydrocarbon-containing feedstock.

55. method as claimed in claim 49 is wherein compared with the corrosion on said surface when said surface contacts the said hydrocarbon-containing feedstock that does not have the corrosive liquid of said reduction, said corrosion rate is lowered about at least 2 times.

56. method as claimed in claim 49 is wherein compared with the corrosion on said surface when said surface contacts the said hydrocarbon-containing feedstock that does not have the corrosive liquid of said reduction, said corrosion rate is lowered about at least 3 times.

57. method as claimed in claim 49 is wherein compared with the corrosion on said surface when said surface contacts the said hydrocarbon-containing feedstock that does not have the corrosive liquid of said reduction, said corrosion rate is lowered about at least 4 times.

58. method as claimed in claim 49, the corrosive liquid of wherein said reduction comprises lindenol, β-Terpineol 350, beta-pinene and Paracymene.

59. method as claimed in claim 49, the corrosive liquid of wherein said reduction comprises:

About 40%-60% lindenol,

About 30%-40% β-Terpineol 350,

About 5%-20% beta-pinene and

About 0-10% Paracymene.

60. method as claimed in claim 49, wherein said hydrocarbon-containing feedstock are selected from crude oil, heavy crude, Tar sands, oil-sand, resinous shale, Sweet natural gas, petroleum gas and their combination.

61. prepare the method for gas containing hydrocarbon, comprise step:

Hydrocarbon-containing feedstock is contacted to form mixture with first liquid of basic surfactant-free; Said first liquid comprises non-aqueous hydrocarbon extracting liq; This non-aqueous hydrocarbon extracting liq is formed by being selected from following turps liquid starting material basically: natural turps, synthetic turps, mineral turpentine, pine tar, α-Pai Xi, beta-pinene, lindenol, β-Terpineol 350, γ-Terpineol 350, terpine resin, α-terpenes, β-terpenes, γ-terpenes, Geraniol, 3-carene, limonene (to the Meng-1, the 8-diene), nopol, pinane, 2-pinane hydroperoxide, Terpine hydrate, 2-pinanol, dihydromyrcenol, isocamphol, to the Meng-8-alcohol, α-tirpinyl acetate, geraniol, to the Meng-8-alcohol acetic ester, 7-hydroxyl dihydro geranial, Therapeutic Mineral Ice, methyl allylphenol, amphene; Paracymene, aubepine, 3; 7-dimethyl--1; 6-octadiene, isobornyl acetate, ocimene, alloocimene, muguol, 2-methoxyl group-2; 6-dimethyl--7,8-octylene oxide, camphor, itral, 7-melonia-geranial, 10-camphorsulfonic acid, geranial, piperitone and its mixture;

Form mixture, wherein said mixture comprises the said hydrocarbonaceous organic substance in the said hydrocarbon extracting liq of extracting of at least a portion; With

Heat said mixture forming gas, said gas contains the turps raw material and from the hydrocarbon of said hydrocarbon-containing feedstock.

62. method as claimed in claim 60, wherein said hydrocarbon-containing feedstock are selected from crude oil, heavy crude, Tar sands, oil-sand, resinous shale, Sweet natural gas, petroleum gas and their combination.

Claims

2. the method for claim 1 further comprises step:

4. method as claimed in claim 3 further comprises step:

Said extraction mixture is separated with said residual raw materials;

The hydrocarbonaceous resinous shale of said pulverizing is provided;

The hydrocarbonaceous resinous shale of said pulverizing is filtered;

Said extraction mixture is separated with said residual raw materials;

With said coal grinding to produce broken coal;

Filter said broken coal;

With said residual raw materials and said extraction mixture separation;

48. method as claimed in claim 46, wherein said contact comprises mixing.

49. method as claimed in claim 46, wherein said Sweet natural gas or petroleum gas bubbling are through said turps liquid.

About 40%-60% lindenol,

About 30%-40% β-Terpineol 350,

About 5%-20% beta-pinene and

About 0-10% Paracymene.

61. prepare the method for gas containing hydrocarbon, comprise step: