CN102389379A - Hand sanitizer capable of self-generating flexible grinding particles and preparation method thereof - Google Patents
Hand sanitizer capable of self-generating flexible grinding particles and preparation method thereof Download PDFInfo
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- CN102389379A CN102389379A CN2011103507705A CN201110350770A CN102389379A CN 102389379 A CN102389379 A CN 102389379A CN 2011103507705 A CN2011103507705 A CN 2011103507705A CN 201110350770 A CN201110350770 A CN 201110350770A CN 102389379 A CN102389379 A CN 102389379A
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- abrasive particle
- handwashing liquid
- flexible abrasive
- acrylate copolymer
- mixture
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Abstract
Most of formulas of existing hand sanitizers contain surfactants which are difficult to wash, and the existing hand sanitizers are uneven in cleaning degree of cleaned parts with a lack of a clearing function for aged skin on hands. The invention provides a hand sanitizer capable of self-generating flexible grinding particles, which contains components according to the following percentages by weight: 1.5-12.0% of betaine, 1.5-10.0% of alkyl polyglucoside, 1.0-8.0% of humectant, 0.2-5.0% of acrylic polymer, 0.5-15.0% of cationic surfactant, 0.1-1.5% of essence, 0-2.0% of pearl pulp, 0.05-0.1% of preservative, 0-0.05% of pigment, and the balance of deionized water, and a pH value of the hand sanitizer is 4.5-7.0. Through normal scrubbing, the hand sanitizer can self-generate the flexible grinding particles with uniform particle size, and the flexible grinding particles are uniformly distributed on washed parts, so as to achieve the purpose of deep cleaning through friction.
Description
Technical field
The present invention relates to the daily chemicals field, especially a kind of from producing handwashing liquid of flexible abrasive particle and preparation method thereof.
Background technology
At present, the prescription of handwashing liquid series of products is similar basically, for consumer provides general cleaning and sterilizing function.The surfactant that contains difficult flushing in a lot of prescriptions, and uneven to the clean-up performance at cleaning position, to the removing deficient function of hand aging skin.In handwashing liquid, add abrasive particle, cooperate the surfactant that is prone to flushing can play the effect of deep layer cleaning hand; But because nearly all handwashing liquid all uses the mode of press pump to spray, the abrasive particle of common type makes spout stop up easily.Existing abrasive particle commonly used on the market is the particle of the system that is insoluble to mostly, as, Semen Juglandis nuclear pulverized particles, shellfish pulverized particles, quartz sand or the like; These abrasive particles are hard unusually, except that poor stability in system (free settling), if when washing by rubbing with the hands undue force injured skin very easily.
Summary of the invention
Technical problem to be solved by this invention is to overcome the defective that above-mentioned prior art exists; A kind of handwashing liquid that is easy to spray and can produce certainly flexible abrasive particle is provided; It can be extruded through press pump smoothly, through washing the even-grained flexible abrasive particle of spontaneous generation normally by rubbing with the hands; And be evenly distributed on and be washed the position, reach the deep clean purpose through friction.
For this reason, the present invention adopts following technical scheme: a kind of from the handwashing liquid that produces flexible abrasive particle, the weight ratio of its each component is following:
Betanin 1.5-12.0%,
Alkyl polyglucoside 1.5-10.0%,
Wetting agent 1.0-8.0%,
Acrylate copolymer 0.2-5.0%,
Cationic surfactant 0.5-15.0%,
Essence 0.1-1.5%,
Pearl Concentrate 0-2.0%,
Antiseptic 0.05-0.1%,
Pigment 0-0.05%,
Surplus materials is a deionized water, and the pH value of above-mentioned handwashing liquid is 4.5-7.0.
In suitable concentration range, acrylate copolymer has the fine solubility ability in water, can be distributed to easily in the system, forms high-molecular gel.Acrylate copolymer family macromolecule gel has negative charge, reacts with positively charged cationic surfactant easily, when the cationic surfactant consumption is suitable, generates soluble gel particle.When salt on touching skin or the inorganic salt in the tap water, this gel particle will rapid precipitation be separated out, in conjunction with agglomerating; Form a kind of flexible particle; This particle has suitable size, hardness, is graininess under the state basically rubbing, and can well replace the abrasive particle of other kinds; When washing, play good rubbing action, can not produce damage again simultaneously skin.
Betanin of the present invention is a cocamido propyl betaine, lauramide hydroxyl azochlorosulfonate propyl lycine, or the above two mixture.
Alkyl polyglucoside of the present invention is any or the mixture more than two kinds in single glycosides, two glycosides, three glycosides, the many glycosides, and wherein the alkyl carbon atoms number is 8-16.
Wetting agent of the present invention is one or more the mixture in silicone oil, glycerol, propylene glycol, 1,3 butylene glycol, the sorbitol.
Cationic surfactant of the present invention is any or the mixture more than two kinds in tetradecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, cetyl trimethyl ammonium bromide, the OTAC.
Acrylate copolymer of the present invention is carbomer (high molecular polymer of acrylic acid bonding allyl sucrose or tetramethylolmethane allyl ether); Maleic acid and acrylic acid bipolymer, any in the terpolymer of maleic acid, acrylic acid and butylacrylate or the mixture more than two kinds; The acrylate copolymer molecular weight is 1800-3000000.
Antiseptic of the present invention is diazolidinyl urea commonly used, methylchloroisothiazandnone, Methylisothiazolinone, DMDM Hydantoin etc.
The present invention is following from the method for preparing of the handwashing liquid that produces flexible abrasive particle:
Acrylate copolymer is dissolved in the deionized water, stirs, treat that whole swellings finish after, betanin, alkyl polyglucoside, wetting agent, essence, Pearl Concentrate, pigment and antiseptic are under agitation joined in the aforesaid propylene acid polymer solution; Add cationic surfactant after stirring, stirring gets final product.
Beneficial effect of the present invention is: the present invention is for produce the handwashing liquid of abrasive particle certainly; Before not using is the agranular system of homogeneous; Can extrude through press pump smoothly, on skin,, understand the even-grained flexible abrasive particle of spontaneous generation through washing by rubbing with the hands normally; And be evenly distributed on and be washed the position, can reach the deep clean effect through friction; This flexibility abrasive particle has suitable hardness, when playing good rubbing action, can not produce damage to skin again during washing.
Below in conjunction with the specific embodiment the present invention is described further.
The specific embodiment
Embodiment 1
Prepare handwashing liquid of the present invention according to following each component and weight ratio:
Lauramide hydroxyl azochlorosulfonate propyl lycine 5.0%
Glycerol 4.0%
Acrylate copolymer
1.1.2%
Hexadecyltrimethylammonium chloride 2.0%
Pearl Concentrate 0.7%
Pigment is an amount of
Kazon
0.05%
Essence 0.15%
Deionized water adds to 100%
Embodiment 2
Prepare handwashing liquid of the present invention according to following each component and weight ratio:
Lauramide hydroxyl azochlorosulfonate propyl lycine 5.0%
1,3 butanediol 4.0%
Hexadecyltrimethylammonium chloride 2.4%
Pearl Concentrate 0.7%
Pigment is an amount of
Essence 0.15%
Deionized water adds to 100%
Embodiment 3
Prepare handwashing liquid of the present invention according to following each component and weight ratio:
Cocamido propyl betaine 3.0%
APG
1.5%
Sorbitol 4.0%
Acrylate copolymer
1.1.6%
Cetyl trimethyl ammonium bromide 2.4%
Pearl Concentrate 0.7%
Pigment is an amount of
Essence 0.15%
Deionized water adds to 100%
Embodiment 4
Prepare handwashing liquid of the present invention according to following each component and weight ratio:
Cocamido propyl betaine 5.0%
Glycerol 4.0%
Acrylate copolymer
1.6%
Cetyl trimethyl ammonium bromide 2.4%
Pearl Concentrate 0.7%
Pigment is an amount of
DMDMH
0.2%
Essence 0.15%
Deionized water adds to 100%
1. trade name: carbopol 940 (brand: the promise reputation)
2. trade name: card ripple 980 (brand: the promise reputation)
3. (APG, carbon atom quantity are 8-14 to trade name: Glucopon 650 EC, Cognis)
4. (APG, carbon atom quantity are 12-14 to trade name: Glucopon 600 CSUP, Cognis)
5. trade name: KATHON CG, Dow
6. trade name: the GLYDANT Gloriosa saperba L. is red, LONZA
The performance test results such as the following table of embodiment gained handwashing liquid:
The above only is preferred embodiment of the present invention, is not technical scheme of the present invention is done any pro forma restriction.Every foundation technical spirit of the present invention all falls in protection scope of the present invention any simple modification, equivalent variations and modification that above embodiment did.
Claims (8)
1. one kind from producing the handwashing liquid of flexible abrasive particle, and the weight ratio of its each component is following:
Betanin 1.5-12.0%,
Alkyl polyglucoside 1.5-10.0%,
Wetting agent 1.0-8.0%,
Acrylate copolymer 0.2-5.0%,
Cationic surfactant 0.5-15.0%,
Essence 0.1-1.5%,
Pearl Concentrate 0-2.0%,
Antiseptic 0.05-0.1%,
Pigment 0-0.05%,
Surplus materials is a deionized water, and the pH value of above-mentioned handwashing liquid is 4.5-7.0.
2. according to claim 1 from the handwashing liquid that produces flexible abrasive particle, it is characterized in that described betanin is a cocamido propyl betaine, lauramide hydroxyl azochlorosulfonate propyl lycine, or the former two's mixture.
3. according to claim 1ly it is characterized in that described wetting agent is one or more the mixture in silicone oil, glycerol, propylene glycol, 1,3 butylene glycol, the sorbitol from producing the handwashing liquid of flexible abrasive particle.
4. according to claim 1ly it is characterized in that from producing the handwashing liquid of flexible abrasive particle that described alkyl polyglucoside is any or the mixture more than two kinds in single glycosides, two glycosides, three glycosides, the many glycosides, wherein the alkyl carbon atoms number is 8-16.
5. according to claim 1 from the handwashing liquid that produces flexible abrasive particle; It is characterized in that described cationic surfactant is any or the mixture more than two kinds in tetradecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, cetyl trimethyl ammonium bromide, the OTAC.
6. according to claim 1 from the handwashing liquid that produces flexible abrasive particle; It is characterized in that; Described acrylate copolymer is a carbomer; Maleic acid and acrylic acid bipolymer, any in the terpolymer of maleic acid, acrylic acid and butylacrylate or the mixture more than two kinds; The acrylate copolymer molecular weight is 1800-3000000.
7. according to claim 6 from the handwashing liquid that produces flexible abrasive particle, it is characterized in that described acrylate copolymer molecular weight is 4000-60000.
8. claim 1 is said from the method for preparing that produces the handwashing liquid of flexible abrasive particle, and its step is following:
Acrylate copolymer is dissolved in the deionized water, stirs, treat that whole swellings finish after, betanin, alkyl polyglucoside, wetting agent, essence, Pearl Concentrate, pigment and antiseptic are under agitation joined in the aforesaid propylene acid polymer solution; Add cationic surfactant after stirring, stirring gets final product.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104027257A (en) * | 2013-03-08 | 2014-09-10 | 广东雅威生物科技有限公司 | Cleaning cosmetic |
CN111096923A (en) * | 2020-02-10 | 2020-05-05 | 阿尔斯(厦门)日化有限公司 | Frosted hand sanitizer and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101690701A (en) * | 2009-10-12 | 2010-04-07 | 北京古龙嘉兰生物技术有限公司 | Bath foam |
CN102091020A (en) * | 2010-12-07 | 2011-06-15 | 江晨 | Formula of frosted facial washing milk |
CN102106787A (en) * | 2011-01-31 | 2011-06-29 | 邵素英 | Healthcare hand sanitizer |
-
2011
- 2011-11-09 CN CN2011103507705A patent/CN102389379A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101690701A (en) * | 2009-10-12 | 2010-04-07 | 北京古龙嘉兰生物技术有限公司 | Bath foam |
CN102091020A (en) * | 2010-12-07 | 2011-06-15 | 江晨 | Formula of frosted facial washing milk |
CN102106787A (en) * | 2011-01-31 | 2011-06-29 | 邵素英 | Healthcare hand sanitizer |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104027257A (en) * | 2013-03-08 | 2014-09-10 | 广东雅威生物科技有限公司 | Cleaning cosmetic |
CN111096923A (en) * | 2020-02-10 | 2020-05-05 | 阿尔斯(厦门)日化有限公司 | Frosted hand sanitizer and preparation method thereof |
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Application publication date: 20120328 |