CN102385083B - Apparatus and method for manufacturing color filter substrate by using ink-jet print method - Google Patents

Apparatus and method for manufacturing color filter substrate by using ink-jet print method Download PDF

Info

Publication number
CN102385083B
CN102385083B CN201110258391.3A CN201110258391A CN102385083B CN 102385083 B CN102385083 B CN 102385083B CN 201110258391 A CN201110258391 A CN 201110258391A CN 102385083 B CN102385083 B CN 102385083B
Authority
CN
China
Prior art keywords
blanket
pattern
substrate
manufacture
color filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201110258391.3A
Other languages
Chinese (zh)
Other versions
CN102385083A (en
Inventor
金大铉
李承宪
朴美姬
U·R·李
金星炫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Corp
Original Assignee
LG Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020110069837A external-priority patent/KR101219098B1/en
Application filed by LG Chemical Co Ltd filed Critical LG Chemical Co Ltd
Publication of CN102385083A publication Critical patent/CN102385083A/en
Application granted granted Critical
Publication of CN102385083B publication Critical patent/CN102385083B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Optical Filters (AREA)
  • Printing Methods (AREA)

Abstract

The present invention provides an apparatus and a method for manufacturing a color filter substrate by using an ink-jet print method, wherein a pattern is formed on the substrate by using a blanket containing a printing layer, a groove portion with a pattern is limited in the printing layer. Compared with a conventional manufacture method, the method for manufacturing the color filter can simplify the color filter manufacture process and reduce the manufacture time and cost. Further, the material consumption can be reduced and it is unnecessary to manufacture a mask or a printing plate, such that the pattern can stably keep the shape thereof to provide a color filter substrate with high quality.

Description

Blanket and manufacture method thereof and color filter substrate and manufacturing installation thereof and method
Technical field
The present invention relates to use ink jet printing method to manufacture the apparatus and method of color filter substrate (color filter substrate).
Background technology
Conventionally, such as the electronic equipment such as liquid crystal display device and semiconductor devices by form pattern manufacture on multiple layer.Photoetching process is widely used in forming pattern up to now.
The following principle of photoetching process utilization: specific photoresist (photo resist) (hereinafter referred to as " PR ") is receiving light time chemically reactive to change its proper characteristics (prosperity).At the negativity for color filter (negative) photoresist, only have the part that is not exposed to light be just melted and remove, occur crosslinked because be exposed to the part of light.At positivity (positive) photoresist of the metal electrode pattern for semiconductor devices and TFT, be decomposed to produce acid owing to being exposed to the part of light, there is the significant difference of expose portion and the unexposed portion solubleness to developer, made only to melt and remove expose portion.Thereby, in photoetching process, can use optionally radiant light of mask for desired pattern, there is the pattern with the pattern of this mask with same shape or anti-shadow shape to form.Photoetching process comprises: PR coating procedure, for PR is located to substrate; Exposure process, for using optionally radiant light of mask; And developing process, for using developer to remove to be exposed to the PR of part of light or the PR of part that is not exposed to light to form desired pattern.But, in photoetching process, should manufacture predetermined mask.And, the in the situation that of positive photoresist, should repeat chemical etching and stripping process as the subsequent process that is used to form metal electrode pattern.Thereby there is limitation: manufacturing process may be complicated, and may produce a large amount of poisonous chemical wastes.Therefore, thus manufacturing cost may increase weaken product competitiveness.
In order to solve photolithographic limitation, the roller printing method (roll printing process) of a kind of use print roller (printing roll) is proposed as the new method that is used to form pattern.In addition, actively carrying out with for using ink-jet printing technology to manufacture the relevant research of the technology of color filter substrate.
Have various roller printing methods, but roller printing method can roughly be divided into two class methods, i.e. gravure process (gravure printing method) and anti-shadow lithographic process (reverse offset printing method).
According to gravure process, China ink is coated on the reeded printed panel of tool to the unnecessary China ink of then raking off.Afterwards, use transferring roller that the China ink of staying in groove is transferred on substrate to carry out printing process.Because China ink is to use transferring roller to transfer on substrate, so used the area transferring roller corresponding with the area of desired display equipment.And, have in large-area situation at display device, can carry out transfer process and once form pattern.The printing process that gravure process is known as one and is suitable for being applied to every field---such as publication, packaging, viscose paper (cellophane), vinyl (vinyl), tygon (polyethylene) etc.---.And, studying gravure process is being used to form to having redness, green or blue multicolour pattern and being formed for preventing the metal pattern of the EMI screen layer that occurs static in PDP display of color filter.
For example, but in the typical gravure process that is used to form fine pattern, in large-scale substrate,---glass substrate---above carries out etching process to form groove, thereby manufactures printed panel.Because be filled into China ink in groove, only some is transferred roller and transfers on substrate, so may need extraly a compressing process to guarantee to be formed into by transfer the homogeneity of the thickness of the pattern on substrate.As a result, gravure process can be useful on and forms extensive pattern and have the pattern of shape of stripes, but is not suitable for forming fine pattern---the black matix (black matrix) of for example color filter or the pattern of TFT substrate.Accordingly, anti-shadow lithographic process can be mainly used in forming accurate fine pattern.
According to anti-shadow lithographic process, different from gravure process, China ink is coated in to blanket (blanket) upper, then the jut of the reeded printed panel of tool (protrusion) contact is coated to the China ink on blanket.Afterwards, less desirable pattern part is removed, the pattern part of staying on blanket is transferred on substrate to form desired pattern.And except the multicolour pattern of color filter, anti-shadow lithographic process can also form the fine pattern with various shapes---for example BM and TFT.In addition, manufacturing cost can reduce, and throughput rate can improve.But the blanket need to high-quality obtains fine pattern.And, be difficult to keep having the pattern of constant shape.
The in the situation that of ink jet printing method, compared with roller printing method, due to black diffusion, can reduce material consumption.In addition, needn't manufacture printed panel.Thereby ink jet printing method can be very effective to manufacturing color filter substrate.But, in ink jet printing method, spacer (barrier) must be set on object to be printed, stably to keep the shape of pattern when the ink-jet.
Thereby the color filter that continues to need research to manufacture more simply and have superior quality has again the method for the advantage of ink jet printing method simultaneously.
Summary of the invention
The invention provides the apparatus and method that use ink jet printing method to manufacture color filter substrate, the blanket wherein using in roll marks method and print roller are used to directly form the groove with pattern form in blanket.
The present invention also provides the apparatus and method of manufacturing color filter substrate, wherein in blanket, directly form the groove with pattern form, and China ink is ejected in this groove, stably to keep pattern form in the case of not providing discrete (separate) spacer, and form fine pattern simply.
Embodiment of the present invention provide the printed layers that comprises the roughness (roughness) with pattern form.In some embodiments, this pattern can be to be selected from least one pattern of following group: black matix pattern (black matrix pattern); Redness, green and blue honeycomb pattern (cell patterns); And column spacer patterns (column spacer pattern).
In other embodiments, printed layers can be by siliceous organic polymer, and---for example dimethyl silicone polymer (PDMS)---forms, or formed by the organic polymer being formed by polyurethane (polyurethane) material.Preferably, printed layers can be to be formed by siliceous organic polymer.When the printed layers of blanket be by siliceous organic polymer material---for example PDMS---form time, China ink or solvent can be not easy to be absorbed in printed layers, and provide the permanance of blanket, can remain on intended shape with the China ink that makes to be filled in groove part, thereby easily China ink be transferred on substrate.
In some embodiments again, printed layers may further include multiple juts and multiple groove part, wherein on the top surface of each jut, can be furnished with the coat (coating layer) with respect to China ink with low adhesion.
In other embodiment, coat can be to use the solution that contains fluorinated surfactant (fluorinated surfactant) to form, or uses the polymer solution prepared by the monomer with high fluorine content to form.
In other embodiments of the present invention, the method for manufacturing printed layers comprises: manufacture the substrate for module (module), be formed with the roughness with pattern form on this substrate; Organic polymer is applied and is solidificated on this substrate; And, after this organic polymer solidifies, by organic polymer layers and this substrate separation.
In some embodiments more of the present invention, blanket comprises printed layers.
In other embodiment of the present invention, the method for manufacturing blanket comprises: manufacture carrier layer (support layer); Cushion is formed to material (cushion layer formation material) and apply and be solidificated in a surperficial part for this carrier layer, to form cushion (cushion layer); And, by the reversion of this carrier layer, with the surface of the surface opposition of the carrier layer of reversion on form the printed layers that the method by manufacturing printed layers is manufactured.
In more some embodiments of the present invention, the device that uses ink jet printing method to manufacture color filter substrate comprises: blanket; Print roller, it can reel this blanket to make this blanket to rotate on this substrate; And exhaust unit, it is for being discharged into China ink the blanket of rotation.
In also some embodiments of the present invention, the method that uses ink jet printing method to manufacture color filter substrate comprises: prepare blanket by the method for manufacturing blanket; Preparation print roller, this print roller can reel this blanket to make this blanket to rotate on this substrate; This blanket is wound in this print roller; To be filled into the groove part of this blanket from the China ink of exhaust unit discharge; And, this blanket is rotated on this substrate with the speed of being scheduled to, with by design transfer to this substrate.
In other embodiments, blanket can rotate to the speed of about 200mm/s with about 10mm/s on substrate.
In the time that blanket rotates with the little speed of the speed than in above-mentioned scope, more than China ink may be discharged into the height of jut.Thereby China ink may be attached on jut, thereby produce defective pattern.In addition, may spend the long time China ink is filled in groove part, thereby increase the processing time.On the other hand, in the time that blanket rotates with the large speed of the speed than in above-mentioned scope, China ink may be filled in groove part deficiently.Thereby pattern may transfer to be shifted by halves because of the fast rotary of blanket.In addition, the shape of pattern to be transferred may be out of shape.
In other embodiments of the present invention, color filter substrate is that the method by using ink jet printing method to manufacture color filter substrate is manufactured.
Brief description of the drawings
Accompanying drawing is included to provide a further understanding of the present invention, and is included in this instructions and forms the part of this instructions.These accompanying drawings are exemplified with exemplary of the present invention, and are used from and explain principle of the present invention with explanation one.In the accompanying drawings:
Fig. 1 is according to the schematic cross sectional view of the blanket of one embodiment of the invention;
Fig. 2 is according to the schematic cross sectional view of the blanket that further comprises coat of one embodiment of the invention;
Fig. 3 is according to the schematic diagram of the process of the printed layers of the manufacture blanket of one embodiment of the invention.
Fig. 4 is the schematic diagram of manufacturing the process of color filter substrate according to the use ink jet printing method of one embodiment of the invention; And
Fig. 5 is according to the schematic diagram of the process of manufacturing column spacer on color filter substrate of one embodiment of the invention.
Embodiment
The invention provides the apparatus and method that use ink jet printing method to manufacture color filter substrate.According to the apparatus and method of described manufacture color filter substrate, use and comprised thering is roughness the blanket of printed layers of---it has pattern form---stably forms pattern, even if discrete spacer is not provided on substrate.
Hereinafter, in connection with brief description of the drawings exemplary of the present invention.
The device that uses ink jet printing method to manufacture color filter substrate comprises blanket 1, print roller 2 and exhaust unit 3.Blanket 1 comprises printed layers 11, carrier layer 12 and cushion 13.
Fig. 1 is according to the schematic cross sectional view of the blanket of one embodiment of the invention.Describe printed layers 11 in detail with reference to Fig. 1.
The China ink 31 discharging from exhaust unit 3 can directly be attached to printed layers 11, and then printed layers 11 contacts substrate 4 so that China ink 31 is attached on this substrate.
Can be the printed layers 11 with multiple coarse article (roughs) according to the printed layers 11 of one embodiment of the invention, this be different from the typical printed layers without roughness.Described roughness can have groove and projection.Hereinafter, the projection of roughness will be called as jut 112, and the recess of roughness will be called as groove part 111.Printed layers 11 is necessary parts of the present invention.Printed layers 11 can comprise that multiple groove parts 111 are to realize below by the following target of explanation.
According in the printed layers 11 of one embodiment of the invention, China ink is only filled in groove part 111, and is not filled in jut 112.Thereby China ink is not adhered to jut 112.Accordingly, even if discrete spacer is not provided on substrate 4, also the China ink being filled in groove part 111 stably can be transferred on substrate 4.
The present invention is not subject to the restriction of the size and dimension of groove part 111.Can set according to the size and dimension that is transferred into the pattern 5 on substrate 4 size and dimension of groove part 111.
And the present invention is subject to the restriction of the kind of described pattern.For example, described pattern can be to be selected from a pattern of following group: black matix (BM) pattern; Red (R), green (G), blue (B) honeycomb pattern; And column spacer patterns.
As mentioned above, the device of the manufacture color filter substrate providing is a kind of color filter manufacturing installation that uses following printed layers, this printed layers has comprised the groove part with pattern form, and it is except the color filter substrate for the manufacture of having superior quality is also for saving time and cost.
Printed layers 11 can have the thickness being restricted to from the border between carrier layer 12 and printed layers 11 to groove part 111.Printed layers 11 can have the thickness of about 0.1mm to about 1.0mm, but is not limited to this.
Printed layers 11 can be formed by organic polymer, and this organic polymer has and black cohesive, for blanket provides permanance, is not easy China ink or solvent absorption in printed layers, and easily the China ink being filled in groove part 111 is transferred on substrate 4.
This organic polymer can comprise siliceous organic polymer---for example dimethyl silicone polymer (PDMS), or comprise the organic polymer being formed by polyurethane material.Preferably, this organic polymer can be siliceous organic polymer.
In addition, the invention provides the printed layers 11 that further comprises coat 114.
Particularly, in the time that China ink is attached to the jut 112 of printed layers 11, except being filled into the China ink in the groove part 111 with pattern form, the China ink being positioned on jut 112 also can be transferred on substrate 4.Thereby, can produce less desirable defective pattern.In order to prevent defective pattern, as shown in Figure 2, can on the top surface of jut 112 113, arrange the coat 114 with China ink with low adhesion.Although show the coat 114 thicker than actual (real) thickness in order to represent the position of coat 114 in Fig. 2, coat 114 can have thin thickness.And, because coat 114 is included in the outer wall of groove part 111, the China ink of being not difficult fully to fill.
Coat 114 is by forming with China ink 31 materials with low adhesion.Thereby although China ink 31 discharges from exhaust unit 3, China ink 31 can not be attached to jut 112 yet.Therefore, China ink 31 is only attached to the groove part 111 with pattern form, to prevent from being formed with the pattern of defect.
Coat 114 can be to use solution---it significantly reduces the surface tension of the jut 112---formation that contains fluorinated surfactant, or uses the polymer solution prepared by the monomer with high fluorine content to form.But the present invention is not subject to the restriction of the material of coat 114.
Fluorinated surfactant can use and well known to a person skilled in the art material.The example of described fluorinated surfactant can comprise: perfluoro alkyl sulfonic acid ammonium (ammonium perfluoroalkylsulfonate), perfluoroalkyl ethoxylate (perfluoroalkyl ethoxylate), neopelex (sodium dodecylbenzenesulfonate), calcium dodecyl benzene sulfonate (calcium dodecylbenzenesulfonate), dioctyl sodium sulphosuccinate (sodium dioctylsulfosuccinate), polyxyethylated aromatic sulfuric acid sodium (sodium polyoxyethylene alkylarylsulfate), polyxyethylated ammonium sulfate (ammounium polyoxyethylene alkylsulfate), polyxyethylated aromatic sulfuric acid ammonium (ammounium polyoxyethylene alkylarylsulfate), perfluoro alkyl sulfonic acid ammonium (ammonium perfluoroalkylsulfonate) and polyoxyethylene alkyl ether sulfate salt (polyoxyethylene alkyl ether sulfate).
The polymkeric substance of being prepared by the monomer with high fluorine content can use and well known to a person skilled in the art material.The example of described polymkeric substance can comprise: polytetrafluoroethylene (PTFE), fluorinated ethylene propylene copolymer (FEP), tetrafluoroethene perfluor (alkyl vinyl ether) multipolymer (PFA), ethylene tetrafluoroethylene copolymer (ETFE) and ethene chlorotrifluoroethylene (ECTFE).
Have the process of groove part 111 of pattern form except forming, can manufacture by conventional manufacture method according to printed layers of the present invention.For example, comprised the manufacture process of the printed layers 11 of the groove part 111 with pattern form with reference to Fig. 3 explanation.Manufactured the substrate 6 for module with roughness, described roughness has pattern form.Organic polymer is coated in to the substrate 6 for module, then solidifies.After organic polymer solidifies, in the time that organic polymer layers separates with the substrate 6 for module, can manufacture the printed layers 11 that has comprised the groove part 111 with pattern form.
Referring to Fig. 1, in carrier layer 12, form the printed layers 11 that has comprised the groove part 111 with pattern form.
Carrier layer 12 can be carried printed layers 11 and cushion 13.Carrier layer 12 can be formed by following film (film), and this film has low elasticity to suppress the contraction of printed layers and cushion, to improve printing precision.Particularly, carrier layer 12 can be by having approximately 1,000MPa or larger---preferably approximately 2,000MPa is to approximately 5,000MPa---stretch modulus (tensile modulus) film formed.The known resin molding that meets above-mentioned condition can be used as described film before this.The example of described film can comprise: for example polyethylene terephthalate of polyester film (PET), polycarbonate membrane (polycarbonate film), high density polyethylene (HDPD) film and polypropylene (PP) film.
The present invention is not subject to the restriction of the thickness of carrier layer 12.For example, the thickness that carrier layer 12 can have about 0.1mm to about 0.5mm---preferably about 0.2mm is to about 0.45mm---.In the time that the basic material (base material) of carrier layer 12 has than the little thickness of the thickness in above-mentioned scope, may be not enough to strengthening and carrying cushion or printed layers.On the other hand, in the time that the basic material of carrier layer 12 has than the large thickness of the thickness in above-mentioned scope, blanket can have thick thickness so that described blanket is not rolled around print roller.
Referring to Fig. 1, on cushion 13, form carrier layer 12.
When printed layers 11 has inhomogeneously when surperficial, cushion 13 can compensate the thickness difference of printed layers 11.Similar with printed layers 11, cushion 13 can have the foam texture being formed by PDMS material or the foam texture being formed by polyurethane material, but is not limited to this.
The present invention is not subject to the restriction of the thickness of cushion 13.For example, the thickness that cushion 13 can have about 0.05mm to about 2mm---preferably about 0.3mm is to about 1mm---.In the time that cushion 13 has than the little thickness of the thickness in above-mentioned scope, corresponding cushion 13 may be difficult to obtain enough impression pressure and adjust effect.On the other hand, in the time that the basic material of cushion 13 has than the large thickness of the thickness in above-mentioned scope, described basic material has relatively little thickness.Thereby the supporting effect between basic material layer may be impaired.
The printed layers 11 that has comprised the groove part 111 with pattern form is formed in carrier layer 12.Cushion 13 is formed on the surface opposing with the surface that is furnished with printed layers 11 of carrier layer 12, to form blanket 1.Blanket 1 can be rotatable on substrate by print roller 2.
Particularly, referring to Fig. 4, print roller 2 is around there being blanket 1, to make blanket 1 rotatable on substrate 4.That is to say, the cushion 13 of blanket 1 is around the surface of print roller 2.
As known before this, print roller 2 is to be formed by the metal of stainless steel (SUS) material.The present invention is not subject to the length of print roller 2 and the restriction of diameter.For example, print roller can have following length, approximately 1.1 times to approximately 1.3 times of the width that this length is used substrate.And print roller 2 can have following diameter, this diameter makes approximately 1.1 times to approximately 1.5 times of length that the girth of print roller 2 is used substrate.In the time that print roller has than the length in above-mentioned scope and the little length of diameter and diameter, the undergage that is wound on the printed layers in print roller with by design transfer to the whole surface of substrate.On the other hand, in the time that print roller has than the length in above-mentioned scope and the large length of diameter and diameter, printed layers has the wide size than needs, thereby has reduced efficiency.
In the time that the print roller 2 that blanket 1 is reeled is rotated on substrate 4, substrate 4 is advanced with the direction of the sense of rotation corresponding to print roller 2.At this, because the printed layers 11 of blanket 1 contacts with substrate 4, the China ink 31 being filled in the groove part with pattern form 111 of printed layers 11 can be transferred on substrate 4.
In process in the groove part 111 of China ink being transferred to blanket 1, blanket 1 can the speed rotation to about 200mm/s with about 10mm/s.In the time that blanket rotates with the little speed of the speed than in above-mentioned scope, more than China ink 31 may be discharged into the height of jut 112.Thereby China ink may be attached to jut 112, thereby produce defective pattern.In addition, may spend the long time China ink is filled in groove part 111, thereby increase the processing time.On the other hand, in the time that blanket rotates with the large speed of the speed than in above-mentioned scope, China ink 31 may be filled in groove part 111 fully.Thereby the pattern 5 of expectation may not be transferred on substrate 4.And pattern being transferred to from blanket in the process substrate, blanket can the speed rotation to about 200mm/s with about 10mm/s.And, when blanket is during with the rotation of the little speed of the speed than in above-mentioned scope, may spend the long time by design transfer to substrate.Thereby the processing time may increase.On the other hand, in the time that blanket rotates with the large speed of the speed than in above-mentioned scope, pattern may transfer to be shifted by halves due to the fast rotary of blanket.In addition, the shape of pattern to be transferred may be out of shape.
China ink 31 discharges from exhaust unit 3.China ink 31 is only discharged in groove part 111, and is not discharged on the jut 112 of printed layers.
The thickness of considering China ink 31, exhaust unit 3 can be arranged to the distance predetermined with blanket 1 interval.Can will can discharge black unit as exhaust unit 3.For example, can be by the exhaust unit that pattern of fever or piezo-electric type nozzle are housed as exhaust unit 3.
As mentioned above, the invention provides a kind of color filter substrate manufacturing installation that can manufacture the color filter substrate with superior quality.This device comprises: blanket 1, and it comprises printed layers, defines the groove part with pattern form in described printed layers; Print roller 2, it rotates blanket 1 on substrate; And exhaust unit, it is for being filled into China ink the groove part 111 with pattern form.
Thereby, use this color filter substrate manufacturing installation, can manufacture the color filter substrate with superior quality.Referring to Fig. 4, the China ink discharging from exhaust unit 3 is filled into the groove part with pattern form 111 of blanket 1.At this, the print roller rotation of coiling blanket 1, to be filled into China ink in the groove part with pattern form 111 of blanket 1.
In the time filling China ink, China ink 31 is filled along a direction of blanket 1, and China ink shifts along another direction of blanket 1 simultaneously.That is to say, the filling of China ink and transfer can be carried out simultaneously.Or, after China ink 31 is filled in the groove part 11 of blanket 1 completely, prepare substrate 4.Then, China ink 31 is transferred on substrate 4.That is to say, the filling of China ink and transfer can separately be carried out.
The print roller 2 that is wound with the blanket 1 that is filled with China ink 31 is rotated to the speed of about 200mm/s with about 10mm/s on substrate 4, and substrate 4 is along advancing with the corresponding direction of sense of rotation of print roller simultaneously.
In the time that the print roller of coiling blanket 1 is rotated on substrate 4, the printed layers 11 of blanket 1 contacts with substrate 4.In the time of printed layers contact substrate 4, the China ink 31 being filled in the groove part with pattern form 111 of printed layers 11 is transferred on substrate 4.Thereby, in the case of not using discrete spacer, can on substrate 4, form the pattern 5 having with the 111 corresponding shapes of the groove part with pattern form of printed layers 11.
As mentioned above, have by having comprised the groove part with BM pattern printed layers, have redly, the printed layers of the groove part of green, blue honeycomb pattern and there is the color filter manufacturing installation of the printed layers of the groove part with column spacer patterns, can manufacture with excellent quality the color filter that is formed with black matix (BM), redness, green, blueness, external application (over coat) and column spacer patterns on it simply.
Hereinafter, illustrate in greater detail the present invention with reference to specific embodiments.But, the invention is not restricted to following embodiment.
The manufacture of 1.1 printed layers
In order to manufacture the printed substrates that is formed with the roughness with column spacer patterns shape on it, use for the photoresist of column spacer and in glass substrate, carry out photoetching treatment, to form the column spacer patterns of the thickness with approximately 4 microns to approximately 8 microns, thereby manufacture main mould (master mold).
Next, using Sylgard184(Dow Corning, USA) as PDMS(dimethyl silicone polymer) with 10:1(base-material: hardening agent) ratio mix to remove bubble.After this, use applicator (applicator), this potpourri can be coated in equably on the main mould of the area with about 20cm × about 40cm, to cast coated potpourri.Then, by this potpourri the temperature-curable of approximately 90 DEG C approximately a hour to manufacture printed layers, to define in this printed layers the groove part of the thickness with column spacer patterns shape and approximately 600 microns.Then, use tackifier that polyethylene terephthalate (PET) film of the thickness with approximately 350 microns is attached to carrier layer, to manufacture PDMS print pad (printing pad).Then, adhere to the isocyanurate foam film of the thickness with approximately 350 microns with tackifier, to manufacture the blanket that there is the thickness of approximately 1,300 micron and comprised printed layers, carrier layer and cushion.
The manufacture of 2.2 color filter substrate manufacturing installations
Blanket is installed on the metal printing brush roll being formed by SUS material.Servomotor can be installed to control rotational speed in this print roller.
Exhaust unit comprises: piezo-electric type nozzle, discharges China ink by it; And storage compartment, it is for storing China ink.And, approximately 100 microns to approximately 1,000 micron, exhaust unit and blanket interval.Reel when blanket print roller rotation time, be filled into the groove part with pattern form and be limited in the printed layers of blanket from the China ink of black exhaust unit discharge.
The manufacture of 3.3 color filter substrates
Use the color filter substrate manufacturing installation of manufacturing to manufacture color filter substrate.Use exhaust unit that China ink is filled in the groove part with column spacer patterns shape.At this, by the print roller rotation that is wound with blanket, so that a direction filling along blanket is black continuously, meanwhile, pattern is transferred on substrate along another direction of blanket.
Described substrate can be the substrate that is wherein one after the other formed with BM pattern, red pattern, green pattern, blue pattern and outer coating pattern.And described substrate is transmitted device and moves, with along advancing with the corresponding direction of sense of rotation of the print roller that is wound with blanket.Described substrate can be to move according to the speed of print roller rotational speed.In this embodiment, print roller speed rotation to about 200mm/s with about 10mm/s.
The print roller that is wound with blanket can be rotated on substrate, to allow printed layers and the described substrate contact of blanket.Therefore, column spacer patterns can be transferred on substrate to manufacture color filter substrate.
As mentioned above, compared with conventional manufacture method, according to using ink jet printing method to manufacture the device of color filter substrate and using this device to manufacture the method for color filter substrate, can simplified manufacturing technique and reduce manufacturing time and cost.And, owing to can reducing material consumption and needn't manufacturing mask or printed panel, can stably keep pattern form, so that the color filter substrate with high-quality to be provided.
Disclosed theme should be considered as illustrative rather than restrictively above, and claims are intended to cover and fall into all such amendment, strengthening and other embodiments in true spirit of the present invention and scope.
Thereby in allowed by law maximum magnitude, scope of the present invention allows explanation to determine by the widest of following claim and equivalent thereof, and should not be subject to limitation detailed above or restriction.

Claims (10)

1. a blanket, it comprises printed layers, carrier layer and cushion according to priority;
Wherein said printed layers comprises the roughness with pattern form;
Wherein said printed layers further comprises multiple juts and multiple groove part, and on the top surface of each jut, is furnished with the coat with respect to China ink with low adhesion;
Wherein said printed layers is formed by dimethyl silicone polymer;
Wherein said carrier layer is formed by polyethylene terephthalate, polycarbonate, high density polyethylene or polypropylene; And
Wherein said cushion has the foam texture being formed by dimethyl silicone polymer or the foam texture being formed by polyurethane.
2. blanket according to claim 1, wherein this pattern is to be selected from least one pattern of following group: black matix pattern; Redness, green and blue honeycomb pattern; And column spacer patterns.
3. blanket according to claim 1, wherein this coat is to use the solution that contains fluorinated surfactant to form, or uses the polymer solution prepared by the monomer with high fluorine content to form.
4. a method of manufacturing blanket, the method comprises:
(1) manufacture carrier layer;
(2) cushion is formed in the surperficial part that material applied and be solidificated in this carrier layer, to form cushion;
(3) by the reversion of this carrier layer, with the surface of the surface opposition of the carrier layer of reversion on form printed layers;
Wherein manufacture described printed layers by following method, the method comprises: manufacture the substrate for module, be formed with the roughness with pattern form on this substrate; Organic polymer is applied and is solidificated on this substrate; And after this organic polymer solidifies, by organic polymer layers and this substrate separation;
Wherein this printed layers comprises multiple juts and multiple groove part, and forms the coat with respect to China ink with low adhesion on the top surface of each jut;
Wherein this organic polymer is formed by dimethyl silicone polymer (PDMS);
Wherein said carrier layer is formed by polyethylene terephthalate, polycarbonate, high density polyethylene or polypropylene; And
Wherein said cushion has the foam texture being formed by dimethyl silicone polymer or the foam texture being formed by polyurethane.
5. the method for manufacture blanket according to claim 4, wherein this pattern is to be selected from least one pattern of following group: black matix pattern; Redness, green and blue honeycomb pattern; And column spacer patterns.
6. the method for manufacture blanket according to claim 4, wherein this coat is to use the solution that contains fluorinated surfactant to form, or uses the polymer solution prepared by the monomer with high fluorine content to form.
7. use ink jet printing method to manufacture a device for color filter substrate, this device comprises:
Blanket according to claim 1;
Print roller, it can reel this blanket to make this blanket to rotate on this substrate; And
Exhaust unit, it is for being discharged into China ink the blanket of rotation.
8. use ink jet printing method to manufacture a method for color filter substrate, the method comprises:
Method by manufacture blanket according to claim 4 is prepared blanket;
Preparation print roller, this print roller can reel this blanket to make this blanket to rotate on this substrate;
This blanket is wound in this print roller;
To be filled into the groove part of this blanket from the China ink of exhaust unit discharge; And
This blanket is rotated on this substrate with the speed of being scheduled to, with by design transfer to this substrate.
9. the method for manufacture color filter substrate according to claim 8, wherein this blanket is with the speed rotation of 10mm/s to 200mm/s.
10. a color filter substrate, it is to manufacture by the method for manufacture color filter substrate according to claim 8 or claim 9.
CN201110258391.3A 2010-09-03 2011-09-02 Apparatus and method for manufacturing color filter substrate by using ink-jet print method Active CN102385083B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2010-0086718 2010-09-03
KR20100086718 2010-09-03
KR1020110069837A KR101219098B1 (en) 2010-09-03 2011-07-14 Color filter substrate fabricating apparatus and method using ink-jet printing method
KR10-2011-0069837 2011-07-14

Publications (2)

Publication Number Publication Date
CN102385083A CN102385083A (en) 2012-03-21
CN102385083B true CN102385083B (en) 2014-09-03

Family

ID=45824685

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110258391.3A Active CN102385083B (en) 2010-09-03 2011-09-02 Apparatus and method for manufacturing color filter substrate by using ink-jet print method

Country Status (1)

Country Link
CN (1) CN102385083B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107111226B (en) * 2014-12-22 2021-04-13 皇家飞利浦有限公司 Method for manufacturing patterned stamp, patterned stamp and imprint method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101019474A (en) * 2004-09-17 2007-08-15 伊斯曼柯达公司 Structured surface using ablatable radiation sensitive material
CN101235236A (en) * 2007-01-11 2008-08-06 住友橡胶工业株式会社 Ink for reversal printing, reversal printing method, liquid crystal color filter and preparation method thereof
CN101533116A (en) * 2008-03-12 2009-09-16 住友橡胶工业株式会社 Color filter manufacturing method and ink for color filter

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5991493A (en) * 1996-12-13 1999-11-23 Corning Incorporated Optically transmissive bonding material
JPH11295519A (en) * 1998-04-09 1999-10-29 Seiko Epson Corp Color filter and its production
JP2003107236A (en) * 2001-09-28 2003-04-09 Koji Onuma Manufacturing method for color filter
KR101171190B1 (en) * 2005-11-02 2012-08-06 삼성전자주식회사 Manufacturing method of dsplay device and mold therefor
JP2009090663A (en) * 2007-09-20 2009-04-30 Think Laboratory Co Ltd Gravure simultaneously perfecting printer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101019474A (en) * 2004-09-17 2007-08-15 伊斯曼柯达公司 Structured surface using ablatable radiation sensitive material
CN101235236A (en) * 2007-01-11 2008-08-06 住友橡胶工业株式会社 Ink for reversal printing, reversal printing method, liquid crystal color filter and preparation method thereof
CN101533116A (en) * 2008-03-12 2009-09-16 住友橡胶工业株式会社 Color filter manufacturing method and ink for color filter

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JP特开2003-107236A 2003.04.09
JP特开2009-90663A 2009.04.30
JP特开平11-295519A 1999.10.29

Also Published As

Publication number Publication date
CN102385083A (en) 2012-03-21

Similar Documents

Publication Publication Date Title
JP5147201B2 (en) Pattern forming method and liquid crystal display device manufacturing method using the same
Jeans et al. Advances in roll-to-roll imprint lithography for display applications
CN101952093A (en) Manufacturing method for seamless mold
CN104303104A (en) Large area imprint lithography
US20050126410A1 (en) System and method for printing an alignment film
CN103197501A (en) Array substrate and preparation method thereof, and display device
CN108649052A (en) A kind of array substrate and preparation method thereof, display device
US20130269554A1 (en) Member with concave portion and method for manufacturing same
WO2013119083A1 (en) Free-standing polymer membrane having through-holes and method for manufacturing same
CN102385083B (en) Apparatus and method for manufacturing color filter substrate by using ink-jet print method
CN100508121C (en) Method for patterning coatings
KR100652062B1 (en) Method for manufacturing of printing plate
US20070120931A1 (en) Method for manufacturing substrate having thin film pattern layer
WO2014209428A1 (en) Method of manufacturing a high-resolution flexographic printing plate
KR101219098B1 (en) Color filter substrate fabricating apparatus and method using ink-jet printing method
KR101652590B1 (en) Blanket for printing and manufacturing the same
JP2008207374A (en) Resin mold and manufacturing method of printing plate utilizing the same
KR101430998B1 (en) Roll printing apparatus comprising a softness porosity sheet and method of printing reverse offset using the same
KR101308447B1 (en) Printing device and method for pattrning thin layer using the same
CN101271267B (en) Production method of exposure light shield and thin film graphic pattern layer
KR20070027784A (en) Method for manufacturing of printing plate
JP2001030644A (en) Printing plate and method for printing
JP2013208826A (en) Thin film printing method and thin film printer
US20160271992A1 (en) Blanket for offset printing and fine pattern manufactured by using the same
KR101298103B1 (en) Apparatus and method for manufacturing fine circuit pattern and fine circuit pattern manufactured thereby

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant