CN102373617A - Preparation method of textile function finishing agent - Google Patents
Preparation method of textile function finishing agent Download PDFInfo
- Publication number
- CN102373617A CN102373617A CN2010102651140A CN201010265114A CN102373617A CN 102373617 A CN102373617 A CN 102373617A CN 2010102651140 A CN2010102651140 A CN 2010102651140A CN 201010265114 A CN201010265114 A CN 201010265114A CN 102373617 A CN102373617 A CN 102373617A
- Authority
- CN
- China
- Prior art keywords
- nano
- finishing agent
- functional finishing
- preparation
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a preparation method of a textile nano-function finishing agent which is used for producing antibacterial, anti-odor, health care and skin care functional textiles and mainly contains inorganic nano-material. The preparation method comprises the following steps: dispersing the inorganic nano-material in water solution of a surfactant under stirring condition, continuously stirring to form fluid type colloid, further adding auxiliary components, and continuously uniformly stirring to prepare the nano-function finishing agent, wherein the inorganic nano-material is nano-zinc oxide, nano-titanium dioxide or mixture of nano-zinc oxide and nano-titanium dioxide, the content of the inorganic nano-material is 0.02%-35% by weight of the finishing agent, the balance is the auxiliary components, and the total amount of a prepared product is 100% by weight. The prepared nano-function finishing agent can be used for processing textile raw material through the process steps of immersing, rolling, parching and baking or direct spray-coating, thereby enabling the textile raw material to have antibacterial, anti-odor, health care and skin care functions and being further used for preparing the textiles. The method is simple in production process, reasonable in raw materials and formula and good in product performances, thereby being an ideal textile processing technology for disease prevention and health care.
Description
Technical field:
The present invention relates to a kind of method that is used to produce antibiotic, antibacterial deodourizing, antibiotic health care or antibiotic skin-care function textile, especially contain the preparation method of the fabric nano functional finishing agent of inorganic nano material.
Technical background:
Along with the raising of progress of science and technology and living standards of the people, people have proposed more, higher requirement to textile product, thereby are promoting the deep development of antibacterial deodourizing process technology.At present, antibacterial textile deodorization finishing agent various in style constantly emerges, and process technology is gradually improved, and indicates that clothes are used and the antibacterial deodourizing process technology of decorative textile product has got into the stable development stage.Face of mankind the ecological environment that goes from bad to worse now, waits in expectation to recover the naturopathy that human body is cured ability; The appearance that waits in expectation and to get well, improve the functional textile of immunity.Function textile involved in the present invention is meant that extract through natural medicinal plant is as functional agent; Textiles is processed; Thereby reach antibacterial deodourizing, preserve moisture, moisture absorption, mothproof, improve skin sense of touch, antiallergy, control processing effects such as dermatitis, should this be a kind of health care, comfortable processing method.
Because nano zine oxide, nano titanium oxide itself are nontoxic, environmentally friendly, institute thinks that developing the green functional textiles opens up a new way.Though nano-ZnO preparation research is more, its application technical research relatively lags behind; Research in particular for after-finishing of textile products is more rare.The technical term that is used for after-finishing of textile products in view of nano material is ununified as yet, will be called nano functional finishing agent or fabric nanometer finishing agent by the finishing agent of nano material preparation among the present invention; The textiles that is obtained by arrangement thereafter is called nano-function textile or nano functional fabric.
In actual life, people will touch microorganisms such as various bacteriums, fungi inevitably.These microorganisms can ramp under suitable environmental condition breeding, and through the contact transmission disease, influence the healthy of people.
In the daily life, all kinds of textiless are the ground of the good existence of these microorganisms, are the important propagating sources of disease, so the antibacterial research of textiles has extremely important meaning.Yet; In the technology of existing textiles antibacterial finishing agent; Mostly adopt in market is artificial synthetic organic microbial inoculum, like organosilicon quaternary ammonium salt, halogenated diphenyl ethers, pyridine sulphur copper class, itrofurans, organic nitrogen, benzimidazole, sulfonamides etc.Wherein most have certain toxic and side effect to human body, and environment is also had certain pollution because of refractory organics.For example; One Chinese patent application CN1041018 discloses a kind of fabric of hydroxyl diphenyl ether and has used anti-bacteium deodorization finishing agent; Because of dihydroxy diphenyl ether compounds and the poisonous chlorinated derivatives of chlorine bleaches reaction generation; And this antiseptic can produce carcinogenic substance tetrachloro dioxanes after heating or ultraviolet ray irradiation, and the use that is under an embargo; One Chinese patent application CN1048846 discloses a kind of organic fabric of quaternary amines that contains and has used anti-bacteium deodorization finishing agent, gathers to subtract to use because of anionic detergent effects such as chance soap, washing powder to be restricted; The disclosed flesh class of one Chinese patent application CN1169488 antiseptic also belongs to the artificial synthetic organic materials antiseptic.Another kind of antiseptic BCA/747 is 2-(3,5-dimethyl-1-1 pyrazoles)-4-phenyl-6-hydroxy pyrimidine and a-bromocinnamaldehyde, is used for textiles because of finding that its genotoxic potential is under an embargo.Though one Chinese patent application CN1034090 discloses a kind of manufacturing approach of unartificial synthesis of organic substance antibacterial fabric; But recently because antibacterial fabric receives consumer's popular welcome; Green consumption has become the loudest slogan of public consumption; The reinforcement of environmental protection consciousness simultaneously, people urgently hope to develop a kind of body harmless, environment amenable antibacterial finishing agent can apply to the arrangement of antibacterial textile deodorization.The present invention adapts to this demand and a kind of new textile finishing agent of developing just.
The object of the invention aims to provide a kind of harmless, environmentally friendly, fabric nano functional finishing agent that can substitute the organic synthesis antiseptic; And the nano functional finishing agent implanted the method for textiles, to be that all kinds of textiless have antibiotic, antibacterial deodourizing, antibiotic skin-care function.
Summary of the invention:
One of theoretical foundation of the present invention is that nano zine oxide, nano titanium oxide have known excellent anti-bacterium capability, and its sterilization mechanism is that anion and the stripping metal sterilization mechanism that produces sterilization induced in optical excitation; Another theoretical foundation is the macromolecule resin that the nano functional finishing agent that contains zinc oxide, titanium dioxide contains film forming on textiles, and particle has favorable durability after the crosslinked film forming on textiles.The preparation method of used for textiles functional finishing agent involved in the present invention has 3 summary of the invention, and the one, the prescription of functional finishing agent, the 2nd, the preparation technology of functional finishing agent, the 3rd, functional finishing agent is used for antibiotic, deodorization, health care, the skin care effect of textiles.Earlier inorganic nano material under the stirring condition, is scattered in the surface-active aqueous solution in container, continuous stirring becomes the fluid colloid, adds auxiliary composition again, continues to stir and promptly processes the nano functional finishing agent; Inorganic nano material in the nano functional finishing agent is nano zine oxide, nano titanium oxide or both mixtures, and its auxiliary composition comprises dispersant, softener, adhesive, catalyst, crosslinking agent, solvent; With the nano functional finishing agent of processing in the ratio of the 1-30% of relative fabric weight through soaking, roll, dry by the fire, bake processing step or directly cotton, the fiber crops of spraying coating process processing, thread, mao, textile raw materials such as chemical fibre and composition thereof, make it have antibiotic, deodorization, health care, skin-protecting function and be used to prepare fabric.
Antiseptic in the prepared fabric nano functional finishing agent is an inorganic nano material; Be nano zine oxide, nano titanium oxide or both mixtures; The particle diameter of inorganic nano-particle is 1-300nm, and particle diameter is 4-180nm preferably, and best particle diameter is 15-50nm; The content of inorganic nano material is the 0.02%-35% of finishing agent percentage by weight, and all the other are auxiliary composition, and the percentage by weight total amount of manufactured goods is 100%; Inorganic nano material can be the single composition of nano zine oxide or nano titanium oxide, also can be the mixture of nano zine oxide and two kinds of compositions of nano titanium oxide; If be mixture, the weight proportion of its nano zine oxide, nano titanium oxide is 0.3-99.70: 0.3-99.70, and summation is 100.
The auxiliary composition of fabric nano functional finishing agent is a composition, comprises dispersant, softener, adhesive, crosslinking agent, catalyst, solvent.
Dispersant in the auxiliary composition comprise polyacrylic acid, Sodium Polyacrylate, ammonium polyacrylate, polyacrylic acid potassium, etc. surfactant, it is 0.3%-45% that consumption accounts for nano functional finishing agent percentage by weight;
Softener in the auxiliary composition comprises organosilicon, modified organic silicon class; For example nonionic softener and anionic softeners such as amido organosilicon, two amido organosilicon, ring chloro organosilicon, hydrophilic organic silicon, epoxy radicals organosilicon, carboxymethyl organosilicon, polyethers organosilicon, it is 0.8%-80% that consumption accounts for nano functional finishing agent percentage by weight;
The adhesive of auxiliary composition comprises the macromolecule resin and the emulsion of the crosslinked film forming of ability of anion or nonionic, and like polyacrylate, gather ammonium ester, silicone etc., it is 0.5-60% that consumption accounts for nano functional finishing agent percentage by weight;
The crosslinking agent of auxiliary composition is a polybasic carboxylic acid, comprises butane tetracid, citric acid, tartaric acid, citric acid, oxalic acid, poly acrylic acid etc., and it is 0.5-25% that consumption accounts for nano functional finishing agent percentage by weight.
The catalyst of auxiliary composition comprises magnesium chloride, magnesium nitrate, sodium hypophosphite, phosphate, and it is 0.5-30% that consumption accounts for nano functional finishing agent percentage by weight.
Auxiliary composition solvent water station nano functional finishing agent percentage by weight is 0.5-100%; The various composition summations of nano functional finishing agent are 100%.
Specific embodiments:
Through instance the present invention is done further elaboration below.
Embodiment 1:
Prescription: nano zine oxide, particle diameter are 25-45nm, consumption 5%; Oligomeric acrylic acid sodium, viscosity 5Pa.S, consumption 8%; Two amido silicon oils, ammonia value 0.5, consumption 30%; Water, consumption 70%.
Preparation technology: earlier oligomeric acrylic acid sodium is dissolved in 20 parts of water, under agitation adds the nano zine oxide powder, add two amido silicon oils then, continue to stir a kind of nano functional finishing agent of model.
Technique for applying: the test fabric is the stamp cotton towel: nano functional finishing agent consumption is 8% (owf) of relative fabric weight; Technological process, the stamp cotton towel soaks two through two and rolls, pick-up 100%, reusable heat wind oven dry, 95 ℃-110 ℃ of temperature, process through cutting, sewing, packing respectively then have antibiotic, deodorization, the stamp cotton towel of health care, skin-protecting function.
Embodiment 2:
Prescription: nano titanium oxide, particle diameter are 15-25nm, consumption 5%; Ammonium polyacrylate consumption 3%; Hydrophilic organic silicon oil consumption 20%; Palyacrylate binder consumption 25%; Water consumption 60%.
Preparation technology: earlier ammonium polyacrylate is dissolved in 20 parts of water; Under agitation add nano titanium dioxide powder; Thereafter add hydrophilic organic silicon oil and ammonium polyacrylate ester adhesive, the back that stirs adds surplus water, with twice of colloid mill grinding a kind of nano functional finishing agent of model.
Technique for applying: test fabric, 21 ' * 21 ' 60 * 58 36 " bleach textile plain cloth; Nano functional finishing agent consumption is 4.5% (owf) of relative fabric weight; To bleach textile plain cloth cotton and soak two through two and roll, 40 ℃, behind the pick-up 70%-95% again through oven dry, 90 ℃-115 ℃ with bake, 140 ℃-195 ℃, process product through check, packing common process step again.
Embodiment 3:
Prescription: nano titanium oxide, particle diameter are 10-20nm, consumption 2.5%, and nano zine oxide, particle diameter are 55-65nm, consumption 4%, this dish-85, consumption 4%, Tween-85, consumption 3%, peregal 0-18, consumption 1.8%; Polyurethane binder, consumption 25%; Water, consumption 75%.
Preparation technology: earlier Arlacel-85, Tween-85, peregal 0-18 are dissolved in 35 parts of water, under agitation add nano titanium oxide, nano zinc oxide powder, grind twice, filter with colloid mill, a kind of nano functional finishing agent of model.
Technique for applying: tested fabrics is a cotton knitwear, and nano functional finishing agent consumption is 10% (owf) of relative fabric weight.Earlier terylen cotton knitting cloth is passed through centrifuge dewatering (making the band liquid measure is the heavy 85%-100% of cloth) hot-air seasoning then again through soaking (25 ℃-65 ℃, 1-2.5 hour), 90 ℃-120 ℃ of temperature are processed product to cross common process such as check, packing again.
Embodiment 4:
Prescription: nano titanium oxide, particle diameter are 30-40nm, consumption 3%, and nano zine oxide, particle diameter are 30-50nm, consumption 4%; Arlacel-60, consumption 1%, Tween-60, consumption 1%, dispersing agent NNO, consumption 2.5%; Polyether modified silicone, consumption 20%, nonionic flexible sheet, 10%; Water, consumption 58.5%.
Preparation technology: earlier Arlacel-80, Tween-80, dispersing agent NNO, nonionic flexible sheet are dissolved in 28 parts of water; Under agitation add nano titanium oxide, nano zine oxide powder; Grind twice with colloid mill; Thereafter add the polyether modified silicone back that stirs and add surplus water, with colloid mill grind twice, filter, a kind of nano functional finishing agent of model.
Technique for applying: the test fabric is the slubbing hair, and nano functional finishing agent consumption is 6.5% (owf) of relative fabric weight.Earlier the slubbing hair is soaked one through one and roll, temperature is passed through hot-air seasoning for 30 ℃-40 ℃ again, 95 ℃-110 ℃ of temperature, and through check, common process such as packing are processed product then.
Embodiment 5:
Prescription: nano titanium oxide, particle diameter are 40-60nm, consumption 2.5%, nano zine oxide, particle diameter 60-80nm, consumption 4.5%; Sodium Polyacrylate, consumption 12%; Hydroxy silicone emulsion, consumption 30%; BTCA, consumption 8%; Sodium hypophosphite, consumption 6%; Water, consumption 37%.
Preparation technology: earlier that polyacrylic acid is soluble in water, under agitation add nano titanium oxide, nano zinc oxide powder, with colloid barreling twice, add the hydroxy silicone emulsion silicone thereafter, filter with colloid barreling twice back that stirs, and is the A group; BTCA, sodium hypophosphite are B group: with two groups of A, B pack respectively a kind of nano functional finishing agent of model.
Technique for applying: the test fabric is textile bunting: nano functional finishing agent consumption is 13% (owf) of relative fabric weight.(1) the A component is pressed fabric and weigh 13%, the B component weighs 5% working solution of making soluble in water by fabric; (2) textile bunting is through spraying or blade coating, after 55 ℃ of-60 ℃ of immersions of temperature again through oven dry, 95 ℃-120 ℃ of temperature with bake 160 ℃-190 ℃, and then process product through common process such as check, packings.
Claims (4)
1. the preparation method of a fabric nano functional finishing agent; It is characterized in that under stirring condition, being scattered in inorganic nano material in the aqueous solution of surfactant; Continuous stirring becomes the fluidity colloid, adds auxiliary composition again, continues to stir to process the nano functional finishing agent; Inorganic nano material is nano zine oxide, nano titanium oxide or both mixtures, and its content is the 0.02%-35% of finishing agent percentage by weight, and all the other are auxiliary composition, and the weight percent total amount of manufactured goods is 100%; The nano functional finishing agent processed is through soaking, roll, dry by the fire, bake processing step or direct spray process textile raw material, makes it have antibiotic, deodorization, health care, skin-protecting function and is used to prepare fabric.
2. the preparation method of fabric nano functional finishing agent according to claim 1; It is characterized in that the inorganic nano material as antiseptic can be the single composition of nano zine oxide or nano titanium oxide; It also can be the mixture of two kinds of compositions; The weight ratio of its nano zine oxide, nano titanium oxide is 0.3-99.70: 0.3-99.70, and summation is 100, and the particle diameter of nano particle is 1-200nm.
3. the preparation method of nano functional finishing agent according to claim 1, the auxiliary composition of the nano functional finishing agent that it is characterized in that weaving is a composition, comprises powder, softener, adhesive, crosslinking agent, catalyst, solvent; Its each component accounts for nano functional finishing agent percentage by weight and respectively is 0.3%-45%; 0.8%-80%, 0.5-60%, 0.5-25%; 0.5-30%, 0.5-100%.
4. the preparation method of weaving nano functional finishing agent according to claim 1 is characterized in that ratio processing cotton, fiber crops, silk, hair, chemical fibre and mixture textile raw material in the 1%-20% of relative fabric weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102651140A CN102373617A (en) | 2010-08-27 | 2010-08-27 | Preparation method of textile function finishing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102651140A CN102373617A (en) | 2010-08-27 | 2010-08-27 | Preparation method of textile function finishing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102373617A true CN102373617A (en) | 2012-03-14 |
Family
ID=45792798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102651140A Pending CN102373617A (en) | 2010-08-27 | 2010-08-27 | Preparation method of textile function finishing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102373617A (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102677453A (en) * | 2012-05-25 | 2012-09-19 | 浙江理工大学 | Method for preparing cotton fabric loaded with organosilicon quaternary ammonium and nano titanium dioxide composite antibacterial agent |
| CN104005226A (en) * | 2013-02-21 | 2014-08-27 | 江苏南纬悦达纺织研究院有限公司 | Composite antibacterial mould-proof coated fabric and manufacturing method thereof |
| CN104264450A (en) * | 2014-09-11 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Silk fabric anti-bacterial finishing agent and preparation method thereof |
| CN104790207A (en) * | 2015-05-14 | 2015-07-22 | 宣海成 | Durable fabric odor-resisting and antistatic finishing agent |
| CN104878589A (en) * | 2015-06-09 | 2015-09-02 | 浙江汇千高飞新材料有限公司 | Preparation method of finishing agent of textiles |
| CN104947411A (en) * | 2015-07-07 | 2015-09-30 | 安徽理工大学 | Multifunctional fabric slurry composite and preparation method thereof |
| CN105040406A (en) * | 2015-06-16 | 2015-11-11 | 长兴县大成轻纺有限公司 | Deodorization fabric |
| CN105506973A (en) * | 2016-01-06 | 2016-04-20 | 安徽博朗凯德织物有限公司 | Fabric for airplane interior trimming |
| CN106049070A (en) * | 2016-07-15 | 2016-10-26 | 义乌市麻尚生针织品有限公司 | Yarn made by blending fiber having anions and far-infrared function and hemp-cotton fiber |
| RU2615693C1 (en) * | 2015-11-02 | 2017-04-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ, НИ ТГУ) | Method of producing materials with anti-bacterial properties based on cotton fabric modified by nanoparticles of zinc oxide |
| CN106567171A (en) * | 2016-11-14 | 2017-04-19 | 安徽省天助纺织科技有限公司 | Regenerated cotton-yarn textile material used in anti-ultraviolet aging-resistant gloves and preparation thereof |
| CN107897204A (en) * | 2017-11-06 | 2018-04-13 | 紫罗兰家纺科技股份有限公司 | A kind of production method of nano-titanium dioxide and nano zinc oxide hybridization finishing agent |
| CN108411630A (en) * | 2018-04-02 | 2018-08-17 | 东莞市佳乾新材料科技有限公司 | It is a kind of based on plant polyose and the compound radiation-resistant fabric finishing agent and preparation method thereof of inorganic nano material |
| CN110616579A (en) * | 2019-10-16 | 2019-12-27 | 花法科技有限公司 | Digital printing after-finishing process |
| CN110656487A (en) * | 2019-10-31 | 2020-01-07 | 青岛大学 | Method for improving attachment capacity and ultraviolet resistance of titanium dioxide on cotton fabric |
| CN111304907A (en) * | 2018-12-12 | 2020-06-19 | 博富科技股份有限公司 | Special antibacterial finishing liquid for towels and preparation method thereof |
| CN112210987A (en) * | 2020-09-22 | 2021-01-12 | 中华人民共和国虹口海关 | Reactive ultraviolet-proof finishing agent for textiles |
-
2010
- 2010-08-27 CN CN2010102651140A patent/CN102373617A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102677453A (en) * | 2012-05-25 | 2012-09-19 | 浙江理工大学 | Method for preparing cotton fabric loaded with organosilicon quaternary ammonium and nano titanium dioxide composite antibacterial agent |
| CN104005226A (en) * | 2013-02-21 | 2014-08-27 | 江苏南纬悦达纺织研究院有限公司 | Composite antibacterial mould-proof coated fabric and manufacturing method thereof |
| CN104264450A (en) * | 2014-09-11 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Silk fabric anti-bacterial finishing agent and preparation method thereof |
| CN104790207A (en) * | 2015-05-14 | 2015-07-22 | 宣海成 | Durable fabric odor-resisting and antistatic finishing agent |
| CN104878589A (en) * | 2015-06-09 | 2015-09-02 | 浙江汇千高飞新材料有限公司 | Preparation method of finishing agent of textiles |
| CN105040406A (en) * | 2015-06-16 | 2015-11-11 | 长兴县大成轻纺有限公司 | Deodorization fabric |
| CN105040406B (en) * | 2015-06-16 | 2017-08-01 | 长兴县大成轻纺有限公司 | A kind of deodorant fabric |
| CN104947411A (en) * | 2015-07-07 | 2015-09-30 | 安徽理工大学 | Multifunctional fabric slurry composite and preparation method thereof |
| CN104947411B (en) * | 2015-07-07 | 2016-09-28 | 安徽理工大学 | Multifunctional fabric slip compositions and preparation method thereof |
| RU2615693C1 (en) * | 2015-11-02 | 2017-04-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ, НИ ТГУ) | Method of producing materials with anti-bacterial properties based on cotton fabric modified by nanoparticles of zinc oxide |
| CN105506973A (en) * | 2016-01-06 | 2016-04-20 | 安徽博朗凯德织物有限公司 | Fabric for airplane interior trimming |
| CN106049070A (en) * | 2016-07-15 | 2016-10-26 | 义乌市麻尚生针织品有限公司 | Yarn made by blending fiber having anions and far-infrared function and hemp-cotton fiber |
| CN106567171A (en) * | 2016-11-14 | 2017-04-19 | 安徽省天助纺织科技有限公司 | Regenerated cotton-yarn textile material used in anti-ultraviolet aging-resistant gloves and preparation thereof |
| CN107897204A (en) * | 2017-11-06 | 2018-04-13 | 紫罗兰家纺科技股份有限公司 | A kind of production method of nano-titanium dioxide and nano zinc oxide hybridization finishing agent |
| CN108411630A (en) * | 2018-04-02 | 2018-08-17 | 东莞市佳乾新材料科技有限公司 | It is a kind of based on plant polyose and the compound radiation-resistant fabric finishing agent and preparation method thereof of inorganic nano material |
| CN111304907A (en) * | 2018-12-12 | 2020-06-19 | 博富科技股份有限公司 | Special antibacterial finishing liquid for towels and preparation method thereof |
| CN111304907B (en) * | 2018-12-12 | 2022-09-30 | 博富科技股份有限公司 | Special antibacterial finishing liquid for towels and preparation method thereof |
| CN110616579A (en) * | 2019-10-16 | 2019-12-27 | 花法科技有限公司 | Digital printing after-finishing process |
| CN110656487A (en) * | 2019-10-31 | 2020-01-07 | 青岛大学 | Method for improving attachment capacity and ultraviolet resistance of titanium dioxide on cotton fabric |
| CN112210987A (en) * | 2020-09-22 | 2021-01-12 | 中华人民共和国虹口海关 | Reactive ultraviolet-proof finishing agent for textiles |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102373617A (en) | Preparation method of textile function finishing agent | |
| CN1632214A (en) | Process for preparing textile nano function finishing agent | |
| CN100588768C (en) | A kind of sterilizing shape-memory-fabric finishing agent and method for sorting thereof | |
| CN100521943C (en) | Inorganic/organic nano composite antibacterial agent and its fabric product application | |
| CN102733184B (en) | Finishing technology for aromatic anti-bacteria cotton textile | |
| CN105648646B (en) | Anti-mite antibacterial healthy knitted fabric of one kind and preparation method thereof | |
| CN100529246C (en) | Process for preparing poly modified chitosan anti-bacteria wet keeping finishing agent | |
| CN104532596B (en) | A kind of Oleum Cinnamomi microcapsule fabric finishing liquid and its preparation method and application | |
| CN108166157A (en) | Antibacterial spunlace non-woven cloth beauty mask base fabric of a kind of moisture absorption and preparation method thereof | |
| CN102392346B (en) | Method for finishing nano anti-ultraviolet and antibacterial hydrophobic fabrics | |
| CN103726295B (en) | There is polyester cotton method for sorting that is antibacterial, hydrophobic and anti-pollution function | |
| CN101886338B (en) | A kind of biological antibiotic cotton fiber or cotton and preparation method thereof | |
| CN108360255A (en) | Based on natural plants mite-proofing and antimicrobial material extraction, finishing agent preparation method and application | |
| CN104947418A (en) | Preparation method of chitosan quaternary ammonium salt-silver nanoparticle antibacterial cotton fibers | |
| CN102517890A (en) | Bedsheet with effect of beautifying and health care and preparation method thereof | |
| CN106758204A (en) | A kind of arrangement antibacterial process of the knitting fabric of cap | |
| CN101967753A (en) | Nanometer antibiosis cashmere knit fabric and production method thereof | |
| CN105839408A (en) | Preparation method of bamboo fiber-cotton and ramie blended fabric | |
| CN105133184A (en) | Functional chitosan fiber spunlace non-woven fabric and preparation method thereof | |
| CN103233357A (en) | Natural bamboo powder-containing hygienic material finishing agent, natural bamboo powder-containing hygienic material and applications thereof | |
| CN108842439B (en) | A kind of moisture absorbing and sweat releasing agent and preparation method thereof | |
| CN104988741A (en) | Fragrance easy-care treating method of cotton shirt | |
| KR20120041617A (en) | Functional leather and the method of preparing thereof | |
| Samanta et al. | Specialty chemical finishes for sustainable luxurious textiles | |
| EP3277880B1 (en) | Wool treatment process and products |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| DD01 | Delivery of document by public notice |
Addressee: Ma Fei Document name: Notification of Passing Preliminary Examination of the Application for Invention |
|
| C06 | Publication | ||
| PB01 | Publication | ||
| DD01 | Delivery of document by public notice |
Addressee: Ma Fei Document name: Notification of Publication of the Application for Invention |
|
| DD01 | Delivery of document by public notice |
Addressee: Ma Fei Document name: Notification of before Expiration of Request of Examination as to Substance |
|
| DD01 | Delivery of document by public notice |
Addressee: Ma Fei Document name: Notification that Application Deemed to be Withdrawn |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120314 |