CN102365968A - Pesticide with acarol and hexythiazox - Google Patents
Pesticide with acarol and hexythiazox Download PDFInfo
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- CN102365968A CN102365968A CN2011103341733A CN201110334173A CN102365968A CN 102365968 A CN102365968 A CN 102365968A CN 2011103341733 A CN2011103341733 A CN 2011103341733A CN 201110334173 A CN201110334173 A CN 201110334173A CN 102365968 A CN102365968 A CN 102365968A
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- hexythiazox
- fenisobromolate
- emulsion
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- former medicine
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- SULNVVXEHJJJSF-UHFFFAOYSA-N CC(C)OC(C(c(cc1)ccc1Br)(c(cc1)ccc1Br)O)O Chemical compound CC(C)OC(C(c(cc1)ccc1Br)(c(cc1)ccc1Br)O)O SULNVVXEHJJJSF-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention relates to a composition of acarol and hexythiazox, which can be prepared into preparations such as pesticide emulsifiable solution, emulsion in water, micro-emulsion, suspension, wettable powder, water dispersible granules and the like according to a conventional production technology in the field. The applying form of the composition is determined according to specific application; and under various types of situations, the preparations must be dispersed as finely and evenly as possible. The invention has the advantages that: firstly, the composition as a compound pesticide has a good synergistic effect; and secondly, the composition has a good killing effect to mites and eggs.
Description
Technical field
The present invention relates to the combination of a kind of fenisobromolate and Hexythiazox, have a kind of fenisobromolate, the Hexythiazox agricultural chemicals of good synergistic effect, be applicable to crops such as cotton, fruit tree, vegetables and tea, can prevent and treat multiple harmful mites such as tetranychid, goitre mite, line mite, belong to agricultural chemicals and make the field.
Background technology
CN1486136A, title " the reactive compound combination with desinsection and acaricidal properties ", the combination of the reactive compound of listed reactive compound (1)-(29) has fine desinsection and acaricidal activity in some new cyclic keto-enols and the specification.
CN635834A, title " active compound combinations with desinsection and acaricidal activity " the present invention relates to the composition with very high desinsection and the active component of acaricidal activity (1)-(29) that new containing given an example in specific cyclic ketoenols and the specification.
CN101018482A, title " based on the insecticide of selective insecticide and safener "; The invention discloses and be used to prevent and treat arthropodan insecticide; It is characterized in that being comprised by the active part that active agent combinations constitutes: (A) one or more are selected from acetylcholinesteraseinhibitors inhibitors, sodium channel modulators, chitin biosynthesis inhibitor, juvenile hormone analogies, chloride channel activator, ecdysone agonist, GABA-control chloride channel antagonist or acaricidal compound, and (B) at least a compound that is selected from the raising crop plants compatibility of this compounds described in the specification.Also disclose the application of the invention chemicals treatment plant and prevented and treated arthropodan method with its seed.
Summary of the invention
Purpose of design: design the combination of a kind of fenisobromolate and Hexythiazox, have fenisobromolate, the Hexythiazox agricultural chemicals of good synergistic effect.
Design: in order to realize above-mentioned purpose of design.The application is on agricultural chemicals composite:
1, select fenisobromolate:
Chemical name: 4; 4'-dibromo diphenylglycollic acid isopropyl ester; Molecular formula: C17H16Br2O3; Molecular weight: 428.1151; CA No:18181-80-1, structural formula:
Characteristics: fenisobromolate kills the mite spectrum extensively, and the longevity of residure is long, and toxicity is low, to the safer miticide of natural enemy, honeybee and crop.Tagging property is stronger, absorption in not having, and to one-tenth, if mite and ovum all have certain lethal effect, variations in temperature is little to the drug effect influence.
The scope of application: this medicine is applicable to crops such as cotton, fruit tree, vegetables and tea, can prevent and treat multiple harmful mites such as tetranychid, goitre mite, line mite.
Colourless crystallization, fusing point: 77 ℃, saturated vapour pressure (kPa): 1.13 * 10-3 (20 ℃)), relative density (water=1): 1.59, be soluble in multiple organic solvent.
2, Hexythiazox:
Chemical name 5-(4-chlorphenyl)-3-(N-the cyclohexyl carboxyamide)-bright basic thiazolidine-2-ketone of 4-first; Molecular formula C17H21ClN2O2S; Molecular weight 352.9; Structural formula:
Physicochemical property: former medicine is light yellow or white crystals; 108～108.5 ℃ of fusing points; Vapour pressure is 338.6 * 10-8Pa in the time of 20 ℃; Solvability is 0.5 mg/litre in the water, and the solvability in per 100 milligrams methyl alcohol, hexane, acetone and other organic solvent is respectively 2.06 grams, 0.39 gram, 16.0 grams, preserves down for 50 ℃ and does not decompose in 3 months.
Toxicity: rat acute per os LD50>5000mg/kg, rat acute is through skin LD50>and 5000mg/kg, low toxicity.
Purposes: the harmful mite of various plants is had strong ovum extremely, kills the children if the characteristic of mite is invalid to the one-tenth mite, but the ovum that female adult worm produced that touches soup is had the effect of inhibition hatching.Can use with Multiple Pesticides such as bordeaux mixture, lime sulfurs.With action of contace poison is main, and plant tissue is had good penetration property, absorption effect in not having.
Characteristics: these article are thiazolidine ketone miticide, and active ingredient is Hexythiazox.The missible oil outward appearance is faint yellow or light brown liquid, and the wetting powder outward appearance is a pale powder, under shady and cool drying condition, preserves and never degenerates in 2 years.To the people, animal low toxicity, eye there is the minimal irritation effect, to the honeybee non-toxic reaction, very little under constant to the birds low toxicity to the natural enemy influence, poisonous to fish.The evil mite is had the ovum of killing, kills if mite acts on, but to becoming mite not have lethal effect.The environmental temperature height does not influence result of use, just can demonstrate in 10 days after the general dispenser
Preventive effect preferably, the lasting period can keep about 50 days.
The application's composition pesticide can be mixed with preparations such as emulsifiable concentrates for agricultural chemicals, aqueous emulsion, microemulsion, suspending agent, wetting powder, water dispersible granules according to the conventional production process of this area.Administration form depends on certain applications, under various situation, must guarantee that their dispersion is trickle as much as possible and even.
These preparations can prepare in a known manner; For example through reactive compound is mixed with liquid flux and/or solid carrier; If desired; Surfactant such as emulsifier, dispersant, wetting agent etc. can be added simultaneously, other auxiliary agent such as thickener, antifoaming agent, antifreeze, pH regulator agent, warning agent, preservative etc. can also be added.If use water as thinner, also available other organic solvent is made cosolvent.
The organic solvent that is fit to comprises: aromatic compound (for example xylol); Chlorinated aromatic hydrocarbons compound (for example chlorobenzene); Hydrocarbon compounds such as atoleine; Alcohols (for example methyl alcohol, ethanol); Ketone (for example cyclohexanone); Amine (for example monoethanolamine, dimethyl formamide); Ethers (for example benzinum); Vegetable oil (corn oil, cottonseed oil) etc., and other synthetics.
The synthetic mineral matter (for example white carbon, silicate etc.) that solid carrier commonly used has natural mineral matter (for example kaolin, talcum, bentonite, attapulgite) and grinds.
Surfactant can be: AEO (AEO-5), APES (NP-10), multi-styrene phenol APEO (601,33#), talan phenol poly-formaldehyde condensate APEO (404), NPE formaldehyde condensation products (700#), castor oil polyoxyethylene ether (BY-125), polyoxyethylene polyoxypropylene block polyether (L61), aliphatic acid polyethenoxy ether (SG-40), sorbitol ester APEO (Tween 80), APG APG (APG (C12-14)), organosilicon APEO (SILWET-L77), tallow amine APEO, calcium dodecyl benzene sulfonate (500#), sulfuric acid (K12), Sulfonates (sodium lignin sulfonate), sulphosuccinates class (fast T), polycarboxylate (2700, T36), phosphates (601P), modification terminal olefine sulfonate, modification NPE, with and compound surfactant (0203,0204,2201).
Thickener; Can be for example carboxymethyl alcohol, polyvinyl alcohol or the polyvinyl acetate that synthesizes; Or natural water-soluble polymer; For example xanthans, aluminium-magnesium silicate, gelatin, gum Arabic, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc. add in the preparation with powder, particle or latex form.
Antifoaming agent: silicone, C
8-10Fatty alcohol, phosphoric acid ester, C
10-20Saturated fat acids (like capric acid) and amide-type etc.
Antifreeze: ethylene glycol, glycerine etc.
The pH regulator agent: oxalic acid, citric acid, sodium carbonate, sodium hydroxide, etc.
Warning agent; Acid red, rhodamine toner, light blue, emerald etc.
Preservative: Sodium Benzoate, 2,6 BHTs (BHT) etc.
Technical scheme 1: a kind of fenisobromolate, Hexythiazox missible oil, it is characterized in that containing in fenisobromolate and the Hexythiazox missible oil mass percent is fenisobromolate 24%～40.0%, Hexythiazox 2%～5.0%.
Technical scheme 2: a kind of fenisobromolate, Hexythiazox aqueous emulsion is characterized in that containing in fenisobromolate and the Hexythiazox aqueous emulsion mass percent and are the former medicine of fenisobromolate 10%～16%, the former medicine 2%～5% of Hexythiazox.
Technical scheme 3: a kind of fenisobromolate, hexythiazox micro-emulsion is characterized in that containing in fenisobromolate, the hexythiazox micro-emulsion mass percent and are the former medicine of fenisobromolate 5%～9%, the former medicine 3%～5% of Hexythiazox.
Technical scheme 4: a kind of fenisobromolate, hexythiazox suspension agent, it is characterized in that containing in fenisobromolate, the hexythiazox suspension agent mass percent is fenisobromolate 10%～16%, Hexythiazox 2%～5%.
Technical scheme 5: a kind of fenisobromolate, Hexythiazox wetting powder, it is characterized in that containing in fenisobromolate, the Hexythiazox wetting powder mass percent is fenisobromolate 3%～8%, Hexythiazox 2%～6%.
Technical scheme 6: a kind of fenisobromolate, Hexythiazox water dispersible granules, it is characterized in that containing in fenisobromolate, the Hexythiazox water dispersible granules mass percent is fenisobromolate 32.0%～45.0%, Hexythiazox 4.0%～5.0%.
Technical scheme 7: a kind of fenisobromolate, Hexythiazox water dispersible granules, it is characterized in that containing in fenisobromolate, the Hexythiazox water dispersible granules mass percent is fenisobromolate 32.0%～45.0%, Hexythiazox 4.0%～5.0%.
The present invention compares with background technology, and the one, composite agricultural chemicals has good synergistic effect; The 2nd, mite and ovum all there are good lethal effect.
Embodiment
Embodiment 1:45% fenisobromolate Hexythiazox missible oil:
Fenisobromolate 40.0%
Hexythiazox 5.0%
Calcium dodecyl benzene sulfonate 6.5%
Styryl phenyl APEO 5.0%
Solvent naphtha supplies 100%
At first join partial solvent oil in the agitated reactor during production, add each raw material more successively,, fully after the dissolving, promptly get 45% fenisobromolate, Hexythiazox missible oil with 2000 rev/mins of stirrings 30 minutes.
Embodiment 2:26% fenisobromolate, Hexythiazox missible oil:
Fenisobromolate 24%
Hexythiazox 2%
Calcium dodecyl benzene sulfonate 6.0%
Styryl phenyl APEO 5%
Solvent naphtha supplies 100%
At first join partial solvent oil in the agitated reactor during production, add each raw material more successively,, fully after the dissolving, promptly get 26% fenisobromolate, Hexythiazox missible oil with 2000 rev/mins of stirrings 30 minutes.
Embodiment 3:15% fenisobromolate, Hexythiazox aqueous emulsion:
The former medicine of fenisobromolate 10%,
The former medicine 5% of Hexythiazox
Calcium dodecyl benzene sulfonate 5.2%
Styryl phenyl APEO 3%
Solvent naphtha 30%
Aluminium-magnesium silicate 1%
Ethylene glycol 5%,
Sodium Benzoate 0.5%
Water supplies 100%
Earlier solvent naphtha is added during production and shear still; In shearing still, add the former medicine of fenisobromolate, the former medicine of Hexythiazox and emulsifier then; Stir 20min treat qualified after; This oil phase is pressed certain speed shear in the homogeneous mixture that adds thickener, antifreezing agent, preservative, water, add the back and promptly get 15% fenisobromolate, Hexythiazox aqueous emulsion with shear-mixed mulser shearing 20min.
Embodiment 4:18% fenisobromolate, Hexythiazox aqueous emulsion:
Fenisobromolate 16%
Hexythiazox 2%
Calcium dodecyl benzene sulfonate 6.8%
Styryl phenyl APEO 5%
Solvent naphtha 35%
Aluminium-magnesium silicate 1%
Ethylene glycol 5%
Sodium Benzoate 0.5
Water supplies 100%
Earlier solvent naphtha is added during production and shear still; In shearing still, add the former medicine of fenisobromolate, the former medicine of Hexythiazox and emulsifier then; Stir 20min treat qualified after; This oil phase is pressed certain speed shear in the homogeneous mixture that adds thickener, antifreezing agent, preservative, water, add the back and promptly get 18% fenisobromolate, Hexythiazox aqueous emulsion with shear-mixed mulser shearing 20min.
Embodiment 5:10% fenisobromolate, hexythiazox micro-emulsion:
Fenisobromolate 5%
Hexythiazox 5%
Calcium dodecyl benzene sulfonate 4%
Phenethyl phenyl polyoxyethylene polyoxypropylene ether 8%
Cyclohexanone 15%
Dimethyl formamide 5%
Water supplies 100%
At first join cyclohexanone and dimethyl formamide in the agitated reactor during production; Add former medicine again, dissolving back adding emulsifier fully mixes again, stirs to add in the deionized water down and stirs 30 minutes with 2000 rev/mins; Fully after the dissolving, promptly get 10% fenisobromolate, hexythiazox micro-emulsion.
Embodiment 6:12% fenisobromolate, hexythiazox micro-emulsion:
Fenisobromolate 9%
Hexythiazox 3%
Calcium dodecyl benzene sulfonate 4%
Phenethyl phenyl polyoxyethylene polyoxypropylene ether 8.5%
Cyclohexanone 20%
Dimethyl formamide 10%
Water supplies 100%
At first join cyclohexanone and dimethyl formamide in the agitated reactor during production; Add former medicine again, dissolving back adding emulsifier fully mixes again, stirs to add in the deionized water down and stirs 30 minutes with 2000 rev/mins; Fully after the dissolving, promptly get 12% fenisobromolate, hexythiazox micro-emulsion.
Embodiment 7:18% fenisobromolate, hexythiazox suspension agent:
Fenisobromolate 16.0%
Hexythiazox 2.0%
Calcium dodecyl benzene sulfonate 7.0%
APES phosphate 5.0%
Alkyl naphthalene sulfonic acid condensation polymer sodium salt 5.0%
Aluminium-magnesium silicate 1.0%
Ethylene glycol 5.0%
Silicone defoaming agent 0.1%
Sodium Benzoate 0.5%
Water supplies 100%
During production each raw material added in modulation kettle and stir 30min, the water amount of supplying, about 2 hours of sand milling, froth breaking is also regulated the pH value and is promptly got 18% fenisobromolate, hexythiazox suspension agent.
Embodiment 8:15% fenisobromolate, hexythiazox suspension agent:
Fenisobromolate 10.0%
Hexythiazox 5.0%
Calcium dodecyl benzene sulfonate 6.5%
APES phosphate 4.0%
Alkyl naphthalene sulfonic acid condensation polymer sodium salt 4.0%
Aluminium-magnesium silicate 1.0%
Ethylene glycol 5.0%
Silicone defoaming agent 0.1%
Sodium Benzoate 0.5%
Water supplies 100%
During production each raw material added in modulation kettle and stir 30min, the water amount of supplying, about 2 hours of sand milling, froth breaking is also regulated the pH value and is promptly got 10% fenisobromolate, hexythiazox suspension agent.
Embodiment 9:12% fenisobromolate, Hexythiazox wetting powder:
Fenisobromolate 8.0%
Hexythiazox 2.0%
Lauryl sodium sulfate 4.5%
Sodium lignin sulfonate 4.4%
White carbon 8.0%
Kaolin supplies 100%
During production each raw material is mixed after the fluidized bed airflow breaking plant is pulverized, behind the mixing, promptly get 10% fenisobromolate, Hexythiazox wetting powder.
Embodiment 10:9% fenisobromolate, Hexythiazox wetting powder:
Fenisobromolate 3.0%
Hexythiazox 6.0%
Lauryl sodium sulfate 4.0%
Sodium lignin sulfonate 4.4%,
White carbon 8.0%
Kaolin supplies 100%
During production each raw material mixed after the fluidized bed airflow breaking plant is pulverized, behind the mixing, i.e. 9% fenisobromolate, Hexythiazox wetting powder.
Embodiment 11:50% fenisobromolate, Hexythiazox water dispersible granules:
Fenisobromolate 45.0%
Hexythiazox 5.0%
Modification terminal olefine sulfonate 6.5%
Polycarboxylate 4.5%
Sodium lignin sulfonate 2.0%
Starch 10.0%,
Kaolin supplies 100%
During production each raw material is mixed after the fluidized bed airflow breaking plant is pulverized, the intermediate after pulverizing is put into the fluidized bed granulation drying equipment, by equipment operation requirement, slowly process particle, the screening of dry back promptly gets 50% fenisobromolate, Hexythiazox water dispersible granules.
Embodiment 12:36% fenisobromolate, Hexythiazox water dispersible granules:
Fenisobromolate 32.0%
Hexythiazox 4.0%
Modification terminal olefine sulfonate 6.0%
Polycarboxylate 4.0%
Sodium lignin sulfonate 2.0%
Starch 10.0%
Kaolin supplies 100%
During production each raw material is mixed after the fluidized bed airflow breaking plant is pulverized, the intermediate after pulverizing is put into the fluidized bed granulation drying equipment, by equipment operation requirement, slowly process particle, the screening of dry back promptly gets 20% fenisobromolate, Hexythiazox water dispersible granules.
What need understand is: though the foregoing description is to the mentality of designing of the present invention detailed text description of contrasting; But these text descriptions; It is simple description to mentality of designing of the present invention; Rather than to the restriction of mentality of designing of the present invention, any combination, increase or modification that does not exceed mentality of designing of the present invention all falls in protection scope of the present invention.
Claims (12)
1. a fenisobromolate, Hexythiazox missible oil, it is characterized in that containing in fenisobromolate and the Hexythiazox missible oil mass percent is fenisobromolate 24%～40.0%, Hexythiazox 2%～5.0%.
2. fenisobromolate according to claim 1, Hexythiazox missible oil is characterized in that: contain fenisobromolate 40.0%, Hexythiazox 5.0% in said fenisobromolate and the Hexythiazox missible oil, or contain fenisobromolate 24%, Hexythiazox 2% in fenisobromolate and the Hexythiazox missible oil.
3. a fenisobromolate, Hexythiazox aqueous emulsion is characterized in that containing in fenisobromolate and the Hexythiazox aqueous emulsion mass percent and are the former medicine of fenisobromolate 10%～16%, the former medicine 2%～5% of Hexythiazox.
4. fenisobromolate according to claim 3, Hexythiazox aqueous emulsion; It is characterized in that: contain the former medicine of fenisobromolate 10%, the former medicine 5% of Hexythiazox in said fenisobromolate and the Hexythiazox aqueous emulsion, or contain the former medicine of fenisobromolate 16%, the former medicine 2% of Hexythiazox in fenisobromolate and the Hexythiazox aqueous emulsion.
5. a fenisobromolate, hexythiazox micro-emulsion is characterized in that containing in fenisobromolate, the hexythiazox micro-emulsion mass percent and are the former medicine of fenisobromolate 5%～9%, the former medicine 3%～5% of Hexythiazox.
6. fenisobromolate according to claim 5, hexythiazox micro-emulsion is characterized in that: contain fenisobromolate 5%, Hexythiazox 5% in said fenisobromolate, the hexythiazox micro-emulsion, or contain fenisobromolate 9%, Hexythiazox 3% in the fenisobromolate, hexythiazox micro-emulsion.
7. a fenisobromolate, hexythiazox suspension agent, it is characterized in that containing in fenisobromolate, the hexythiazox suspension agent mass percent is fenisobromolate 10%～16%, Hexythiazox 2%～5%.
8. fenisobromolate according to claim 7, hexythiazox micro-emulsion is characterized in that: contain fenisobromolate 16%, Hexythiazox 2% in said fenisobromolate, the hexythiazox suspension agent, or contain fenisobromolate 10%, Hexythiazox 5% in the fenisobromolate, hexythiazox suspension agent.
9. a fenisobromolate, Hexythiazox wetting powder, it is characterized in that containing in fenisobromolate, the Hexythiazox wetting powder mass percent is fenisobromolate 3%～8%, Hexythiazox 2%～6%.
10. fenisobromolate according to claim 9, Hexythiazox wetting powder is characterized in that: contain fenisobromolate 8%, Hexythiazox 2% in said fenisobromolate, the Hexythiazox wetting powder, or contain fenisobromolate 3%, Hexythiazox 6% in the fenisobromolate, Hexythiazox wetting powder.
11. a fenisobromolate, Hexythiazox water dispersible granules, it is characterized in that containing in fenisobromolate, the Hexythiazox water dispersible granules mass percent is fenisobromolate 32.0%～45.0%, Hexythiazox 4.0%～5.0%.
12. fenisobromolate according to claim 11, Hexythiazox water dispersible granules; It is characterized in that: contain fenisobromolate 45.0%, Hexythiazox 5.0% in said fenisobromolate, the Hexythiazox water dispersible granules, or contain fenisobromolate 32.0%, Hexythiazox 4.0% in the fenisobromolate, Hexythiazox water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103341733A CN102365968A (en) | 2011-10-29 | 2011-10-29 | Pesticide with acarol and hexythiazox |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103341733A CN102365968A (en) | 2011-10-29 | 2011-10-29 | Pesticide with acarol and hexythiazox |
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| CN102365968A true CN102365968A (en) | 2012-03-07 |
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| CN2011103341733A Pending CN102365968A (en) | 2011-10-29 | 2011-10-29 | Pesticide with acarol and hexythiazox |
Country Status (1)
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63130507A (en) * | 1986-11-19 | 1988-06-02 | Chugai Pharmaceut Co Ltd | House dust mite controlling agent |
| CN101044854A (en) * | 2007-04-24 | 2007-10-03 | 海南博士威农用化学有限公司 | Compound acaricide composition |
| CN101379980A (en) * | 2008-07-04 | 2009-03-11 | 张少武 | Caricidal composition containing bromopropylate and diafenthiuron |
-
2011
- 2011-10-29 CN CN2011103341733A patent/CN102365968A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63130507A (en) * | 1986-11-19 | 1988-06-02 | Chugai Pharmaceut Co Ltd | House dust mite controlling agent |
| CN101044854A (en) * | 2007-04-24 | 2007-10-03 | 海南博士威农用化学有限公司 | Compound acaricide composition |
| CN101379980A (en) * | 2008-07-04 | 2009-03-11 | 张少武 | Caricidal composition containing bromopropylate and diafenthiuron |
Non-Patent Citations (1)
| Title |
|---|
| 王振林: "噻螨酮和溴螨酯防治棉花红蜘蛛", 《农药》, no. 2, 30 April 1987 (1987-04-30), pages 46 - 25 * |
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Application publication date: 20120307 |