CN102329459A - 一种低气味耐刮擦聚丙烯材料及其制备方法 - Google Patents
一种低气味耐刮擦聚丙烯材料及其制备方法 Download PDFInfo
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- CN102329459A CN102329459A CN 201110165675 CN201110165675A CN102329459A CN 102329459 A CN102329459 A CN 102329459A CN 201110165675 CN201110165675 CN 201110165675 CN 201110165675 A CN201110165675 A CN 201110165675A CN 102329459 A CN102329459 A CN 102329459A
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- polypropylene material
- resistant polypropylene
- low smell
- scrape resistant
- inhibitor
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- 239000000463 material Substances 0.000 title claims abstract description 54
- -1 polypropylene Polymers 0.000 title claims abstract description 54
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 45
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims description 11
- 230000003678 scratch resistant effect Effects 0.000 title abstract 5
- 239000000314 lubricant Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000000945 filler Substances 0.000 claims abstract description 29
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- 239000003112 inhibitor Substances 0.000 claims description 33
- 239000000865 liniment Substances 0.000 claims description 29
- 229940040145 liniment Drugs 0.000 claims description 29
- 238000001179 sorption measurement Methods 0.000 claims description 28
- 239000004925 Acrylic resin Substances 0.000 claims description 26
- 229920000178 Acrylic resin Polymers 0.000 claims description 26
- 239000002994 raw material Substances 0.000 claims description 23
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 20
- 238000005469 granulation Methods 0.000 claims description 11
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- 230000004044 response Effects 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- 239000011787 zinc oxide Substances 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 235000006708 antioxidants Nutrition 0.000 claims 3
- 238000000034 method Methods 0.000 abstract description 11
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 150000008301 phosphite esters Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
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- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
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- 238000001746 injection moulding Methods 0.000 description 1
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- 229910052760 oxygen Inorganic materials 0.000 description 1
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- 238000005453 pelletization Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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Abstract
Description
物性参数 | 实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 实例6 |
拉伸强度(MPa) | 21 | 20 | 21 | 21 | 22 | 21 |
断裂伸长率(%) | 15 | 14 | 13 | 13 | 14 | 12 |
弯曲强度(MPa) | 28 | 29 | 28 | 27 | 28 | 29 |
弯曲模量(MPa) | 980 | 920 | 945 | 925 | 950 | 985 |
IZOD缺口冲击强度(J/M) | 72 | 70 | 71 | 73 | 71 | 70 |
耐刮擦(10N)ΔL | 1.72 | 1.68 | 1.66 | 1.61 | 1.58 | 1.55 |
气味(级) | 5 | 6 | 6 | 5 | 6 | 5 |
Claims (9)
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103044779A (zh) * | 2012-12-29 | 2013-04-17 | 安徽科聚新材料有限公司 | 一种玻纤增强聚丙烯材料及其制备方法 |
CN104086881A (zh) * | 2014-07-03 | 2014-10-08 | 合肥杰事杰新材料股份有限公司 | 一种耐刮擦聚丙烯材料及其制备方法 |
CN104497911A (zh) * | 2014-11-27 | 2015-04-08 | 上海邦中新材料有限公司 | 一种用于汽车内饰的低挥发物含量聚乙烯复合热熔胶及其制备方法 |
CN104558831A (zh) * | 2014-12-22 | 2015-04-29 | 重庆普利特新材料有限公司 | 一种低散发性聚丙烯回料及其制备方法 |
CN106317743A (zh) * | 2016-09-19 | 2017-01-11 | 南京德尔隆工程塑料有限公司 | 一种高流动、低气味、耐划伤的汽车内饰用聚丙烯材料及其制备方法 |
CN108976561A (zh) * | 2018-08-03 | 2018-12-11 | 阜南佳利工艺品有限公司 | 一种低气味仿藤条的制备方法 |
CN110845799A (zh) * | 2019-11-14 | 2020-02-28 | 中广核俊尔(上海)新材料有限公司 | 一种低气味耐刮擦的聚丙烯复合材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101787159A (zh) * | 2010-02-05 | 2010-07-28 | 苏州旭光聚合物有限公司 | 一种低voc的耐刮擦改性聚丙烯复合材料及其制备方法 |
CN102336954A (zh) * | 2010-07-19 | 2012-02-01 | 哈尔滨鑫达高分子材料工程中心有限责任公司 | 一种用于汽车内饰的哑光、耐刮擦改性聚丙烯复合材料 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101787159A (zh) * | 2010-02-05 | 2010-07-28 | 苏州旭光聚合物有限公司 | 一种低voc的耐刮擦改性聚丙烯复合材料及其制备方法 |
CN102336954A (zh) * | 2010-07-19 | 2012-02-01 | 哈尔滨鑫达高分子材料工程中心有限责任公司 | 一种用于汽车内饰的哑光、耐刮擦改性聚丙烯复合材料 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103044779A (zh) * | 2012-12-29 | 2013-04-17 | 安徽科聚新材料有限公司 | 一种玻纤增强聚丙烯材料及其制备方法 |
CN104086881A (zh) * | 2014-07-03 | 2014-10-08 | 合肥杰事杰新材料股份有限公司 | 一种耐刮擦聚丙烯材料及其制备方法 |
CN104086881B (zh) * | 2014-07-03 | 2018-07-17 | 合肥杰事杰新材料股份有限公司 | 一种耐刮擦聚丙烯材料及其制备方法 |
CN104497911A (zh) * | 2014-11-27 | 2015-04-08 | 上海邦中新材料有限公司 | 一种用于汽车内饰的低挥发物含量聚乙烯复合热熔胶及其制备方法 |
CN104497911B (zh) * | 2014-11-27 | 2017-02-22 | 上海邦中新材料有限公司 | 一种用于汽车内饰的低挥发物含量聚乙烯复合热熔胶及其制备方法 |
CN104558831A (zh) * | 2014-12-22 | 2015-04-29 | 重庆普利特新材料有限公司 | 一种低散发性聚丙烯回料及其制备方法 |
CN106317743A (zh) * | 2016-09-19 | 2017-01-11 | 南京德尔隆工程塑料有限公司 | 一种高流动、低气味、耐划伤的汽车内饰用聚丙烯材料及其制备方法 |
CN108976561A (zh) * | 2018-08-03 | 2018-12-11 | 阜南佳利工艺品有限公司 | 一种低气味仿藤条的制备方法 |
CN108976561B (zh) * | 2018-08-03 | 2021-04-02 | 阜南佳利工艺品有限公司 | 一种低气味仿藤条的制备方法 |
CN110845799A (zh) * | 2019-11-14 | 2020-02-28 | 中广核俊尔(上海)新材料有限公司 | 一种低气味耐刮擦的聚丙烯复合材料及其制备方法 |
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