CN102307830B - 使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制 - Google Patents

使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制 Download PDF

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Publication number
CN102307830B
CN102307830B CN201080006847.0A CN201080006847A CN102307830B CN 102307830 B CN102307830 B CN 102307830B CN 201080006847 A CN201080006847 A CN 201080006847A CN 102307830 B CN102307830 B CN 102307830B
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China
Prior art keywords
inhibitor
monomer
delayed
action activator
quinone methides
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CN201080006847.0A
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Chinese (zh)
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CN102307830A (zh
Inventor
文森特·E·莱维斯
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ChampionX LLC
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Nalco Co LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201080006847.0A 2009-02-05 2010-02-03 使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制 Active CN102307830B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/366,154 2009-02-05
US12/366,154 US7651635B1 (en) 2009-02-05 2009-02-05 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
PCT/US2010/022977 WO2010091040A1 (en) 2009-02-05 2010-02-03 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxomine combination

Publications (2)

Publication Number Publication Date
CN102307830A CN102307830A (zh) 2012-01-04
CN102307830B true CN102307830B (zh) 2014-10-22

Family

ID=41559765

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080006847.0A Active CN102307830B (zh) 2009-02-05 2010-02-03 使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制

Country Status (11)

Country Link
US (1) US7651635B1 (enExample)
EP (1) EP2393765B1 (enExample)
JP (1) JP5536106B2 (enExample)
KR (1) KR101613760B1 (enExample)
CN (1) CN102307830B (enExample)
BR (1) BRPI1005420B1 (enExample)
CA (1) CA2750187C (enExample)
ES (1) ES2398053T3 (enExample)
SG (1) SG173564A1 (enExample)
TW (1) TWI461406B (enExample)
WO (1) WO2010091040A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8691994B2 (en) 2011-02-03 2014-04-08 Nalco Company Multi-component polymerization inhibitors for ethylenically unsaturated monomers
US9090526B2 (en) 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
US8884038B2 (en) * 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
MX2014002218A (es) 2011-08-26 2014-05-28 Dorf Ketal Chemicals India Private Ltd Composicion aditiva para el control y la inhibicion de la polimerizacion del estireno y metodo de preparacion y uso de la misma.
KR102033096B1 (ko) * 2011-12-09 2019-10-16 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 방향족 비닐 단량체의 중합화의 제어 및 억제를 위한 개선된 첨가제 조성물, 및 그의 사용 방법
CN103998404B (zh) * 2011-12-26 2017-12-15 多尔夫凯塔尔化学制品（I）私人有限公司 用于控制及抑制芳香族乙烯基单体聚合的改良的基于胺的添加剂组合物，及其使用方法
WO2014030131A1 (en) * 2012-08-24 2014-02-27 Dorf Ketal Chemicals (India) Private Limited Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof
US9944577B2 (en) 2012-10-25 2018-04-17 Baker Hughes, A Ge Company, Llc Hydroquinone compounds for inhibiting monomer polymerization
US9611336B2 (en) 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
IN2013MU01165A (enExample) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
US9399622B2 (en) 2013-12-03 2016-07-26 Ecolab Usa Inc. Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes
BR112018016444B1 (pt) * 2016-02-13 2022-08-16 Dorf Ketal Chemicals (India) Private Limited Composição de aditivo à base de amina aprimorada, seu método de uso e método para controle e inibição de monômeros de vinila aromáticos
KR102763208B1 (ko) * 2018-07-13 2025-02-04 에코랍 유에스에이 인코퍼레이티드 비닐계 단량체에 대한 항파울런트로서의 산소화 아민 및 퀴논 메티드의 조성물
WO2020014596A1 (en) 2018-07-13 2020-01-16 Ecolab Usa Inc. Composition for inhibiting monomer polymerization comprising a nitroxide inhibitor, a quinone methide retarder and an amine stabilizer
TWI880966B (zh) * 2019-10-11 2025-04-21 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
WO2025217595A1 (en) * 2024-04-12 2025-10-16 Bl Technologies, Inc. Boosted styrene polymerization retarder and method of use

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061020A (zh) * 1990-09-17 1992-05-13 Ecp·恩尼化学聚合有限公司 乙烯基芳族单体的纯化方法
US5670692A (en) * 1995-04-14 1997-09-23 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
WO1999048996A1 (en) * 1998-03-25 1999-09-30 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US20040097619A1 (en) * 2001-03-20 2004-05-20 Troutman Malisa V. Flame retardant compositions
CN1761638A (zh) * 2003-03-17 2006-04-19 伯东株式会社 芳香族乙烯基化合物的聚合抑制剂以及聚合抑制方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3390198A (en) * 1965-12-16 1968-06-25 Koppers Co Inc Tertiary-butyl-5-methyl catechol as polymerization inhibitor for hot styrene
US4003800A (en) 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4409408A (en) * 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US5446220A (en) 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US7045647B2 (en) 2000-10-16 2006-05-16 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061020A (zh) * 1990-09-17 1992-05-13 Ecp·恩尼化学聚合有限公司 乙烯基芳族单体的纯化方法
US5670692A (en) * 1995-04-14 1997-09-23 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
WO1999048996A1 (en) * 1998-03-25 1999-09-30 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US20040097619A1 (en) * 2001-03-20 2004-05-20 Troutman Malisa V. Flame retardant compositions
CN1761638A (zh) * 2003-03-17 2006-04-19 伯东株式会社 芳香族乙烯基化合物的聚合抑制剂以及聚合抑制方法

Also Published As

Publication number Publication date
SG173564A1 (en) 2011-09-29
JP2012516933A (ja) 2012-07-26
KR101613760B1 (ko) 2016-04-19
KR20110122111A (ko) 2011-11-09
JP5536106B2 (ja) 2014-07-02
US7651635B1 (en) 2010-01-26
ES2398053T3 (es) 2013-03-13
CN102307830A (zh) 2012-01-04
BRPI1005420A2 (pt) 2020-08-18
CA2750187A1 (en) 2010-08-12
TW201035046A (en) 2010-10-01
BRPI1005420B1 (pt) 2021-05-11
EP2393765B1 (en) 2012-12-26
WO2010091040A1 (en) 2010-08-12
TWI461406B (zh) 2014-11-21
CA2750187C (en) 2016-05-10
EP2393765A1 (en) 2011-12-14

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