CN102304399A - Emulsifier special for alcohol-based fuel and alcohol-based fuel prepared from same as well as preparation methods - Google Patents
Emulsifier special for alcohol-based fuel and alcohol-based fuel prepared from same as well as preparation methods Download PDFInfo
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- CN102304399A CN102304399A CN201110221650A CN201110221650A CN102304399A CN 102304399 A CN102304399 A CN 102304399A CN 201110221650 A CN201110221650 A CN 201110221650A CN 201110221650 A CN201110221650 A CN 201110221650A CN 102304399 A CN102304399 A CN 102304399A
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Abstract
The invention relates to an emulsifier special for alcohol-based fuel and the alcohol-based fuel prepared from the same as well as preparation methods. The preparation method of the emulsifier comprises the following steps: pouring baking soda, industrial salt and acetone in warm water for dissolution; mixing potassium permanganate with p-dihydroxybenzene and adding water for dissolution; and mixing two solutions from the former two steps with ethanol, and standing for later use. The preparation method of the alcohol-based fuel comprises the following steps: blending a crude alcohol solution; injecting the emulsifier in the crude alcohol; injecting a combustion-supporting agent; and injecting a potassium nitrate solution, and standing. According to the invention, processes are simple, cost is lower, and the prepared alcohol-based fuel has the characteristics of high heat value, low energy consumption and higher safety and is more beneficial to environment protection.
Description
Technical field
The present invention relates to a kind of biofuel field, particularly relate to a kind of alcohol-group fuel of emulsifier special, preparation method and preparation thereof of alcohol-group fuel.
Background technology
Alcohol-group fuel is to be the fuel of main body preparation with alcohols (like methyl alcohol, ethanol, butanols etc.) material; Be a kind of environment friendly biological fuel, store at normal temperatures and pressures, transport, use, need not the high-pressure cylinder storage; Only with plain metal or plastic containers storage; The same with nuclear energy, sun power, wind power energy, hydraulic energy, be the environment protection clean energy that national governments widely popularize at present, in the face of the exhaustion of fossil energy; Alcohol-group fuel is the most potential novel substitute energy, receives the favor of every industry or trade and tissue deeply.
The preparation technology of alcohol-group fuel is generally the agent of the preparation gain of heat earlier: with 70kg concentration is the thick alcohol adding plastic tank stirring of 88%-95%, and attention will guarantee not have flocculence or granular substance to get into, in case in use stop up oil pipe; Add 3.6kg 35% Liquor Hydrogen Peroxide (H
2O
2) note trying not directly to contact with hand, in order to avoid injury skin; 3.5kg turps reagent is warmed to about 50 degree, pours in the mixed solution of preceding two kinds of raw materials, treat to dissolve fully; Add 350g propyl carbinol reagent (CH again
3CH
2CH
2CH
2OH, the 1-butanols); Get potassium permanganate particles 7g at last, dissolve fully with 80 degree warm water, the acquisition saturated solution is poured institute into and is joined fully foaming in the raw material, and reaction was sealed up for safekeeping 15 minutes.
Prepare alcohol-group fuel afterwards: thick pure 1000kg is squeezed in the plastic tank, and the big I of bucket is suitably selected according to own needs, has half ton, and 1 ton, 3 tons are waited different size; Add alcohol-group fuel emulsifier special 3.5kg, add the gain of heat agent 25～30kg that has prepared after the stirring again, can suitably regulate according to the concentration of thick alcohol; Add saltpetre 2kg at last,, stir and treat that post precipitation uses with water dissolution, dilution.
The emulsifying agent of above-mentioned employing makes through technology:
Get lightweight oil stoste 200g and add sodium bicarbonate particle 60g, after get potassium permanganate particles 60g and process saturated solution with warm water, solution is poured in the mixed solution of preceding two kinds of raw materials and is fully stirred;
Get dihydroxy-benzene 85g and put into the acetone that concentration is 90%, weight is 10kg and dilute, stir, color is faint yellow.
Sodium chloride solution 130g with concentration 3.5% adds in the mixed solution of preceding two kinds of preparation liquid at last, evenly stirs, and waits for that color becomes light yellow can the use.
Alcohol-group fuel according to above-mentioned technology preparation has following characteristics:
1, be prone to storage, easy transportation, safe and reliable, store at normal temperatures and pressures, transport and use; Need not the high-pressure cylinder storage, only get final product with plain metal or plastic container sealing storage, easy to use; Just in case catch fire, water can put out, danger that can be not explosion caused; Can not a kind of ideal environment-friendly fuel also because of leakage causes poisoning;
2, sanitation and hygiene, environmental protection, the fuel oxygen level is high, sufficient combustion, at the bottom of no black smoke, no carbon distribution, the no blacking pan, no raffinate residue, the waste steam exhausting after the burning is lower more than 80% than oil liquefied gas, is genuine clean fuel;
3, applied widely; Can substitute diesel oil, liquefied gas, natural gas; Be applicable to large-lot producer and groups of unit such as hotel, hotel, school, office, except that the kitchen range core was different with common kitchen range core, other was the same basically; Diesel range that use in kitchen, dining room or gas-cooker only need be changed the kitchen range core and can use, and install and use very convenient.
But, when reality is used, find, according to the alcohol-group fuel of above-mentioned traditional technology preparation exist also that cost is higher, poor stability, defective such as volatile; And calorific value is lower; Only about 5300 kilocalories/kg, the requirement that not reaching makes a fire cooks, and consumption is big; Waste is many, does not have remarkable economic efficiency.Therefore, how to found a kind of high heating value, less energy-consumption, security is higher and is more conducive to the alcohol-group fuel of new alcohol-group fuel emulsifier special, preparation method and the preparation thereof of environmental protection, belong to the current industry utmost point and need improved target in fact.
Summary of the invention
The technical problem that the present invention will solve provides a kind of alcohol-group fuel of emulsifier special, preparation method and preparation thereof of alcohol-group fuel; Make its technology simple; Cost is lower; And the alcohol-group fuel of preparation has the characteristics of high heating value, less energy-consumption, and security is higher and be more conducive to environmental protection, thereby overcomes the deficiency of existing alcohol-group fuel and preparation method thereof.
For solving the problems of the technologies described above, the present invention at first provides a kind of emulsifier special preparation method of alcohol-group fuel, may further comprise the steps: sodium bicarbonate, Industrial Salt, acetone are poured in the warm water dissolved; Potassium permanganate and Resorcinol are mixed and be dissolved in water; Above-mentioned two kinds of solution are mixed stand for standby use with ethanol.
As a kind of improvement of the present invention, described: sodium bicarbonate is the solid of 210 weight parts, and Industrial Salt is the solid of 32 weight parts, and acetone is the liquid of 26 weight parts, and the three joins in 200 weight parts, 70 ℃ the water dissolves; Potassium permanganate is the solid of 31 weight parts, and Resorcinol is the solid of 16 weight parts, and the two adds in the water of 200 weight parts dissolves; The alcoholic acid mass concentration is 99.9%, gets 400 weight parts and mixes with two solution of above-mentioned weight part.
Secondly, the invention provides alcohol-group fuel emulsifier special according to method for preparing.
In addition, the present invention also provides a kind of alcohol-group fuel, and it contains the above-mentioned alcohol-group fuel emulsifier special of mass percent 0.515%.
As further improvement, described alcohol-group fuel also contains mass percent and is respectively 0.545%, 0.025% and 84% ignition dope, saltpetre and methyl alcohol, and surplus is a water.
At last, the invention provides a kind of preparation method of above-mentioned alcohol-group fuel, may further comprise the steps: blend thick alcoholic solution; Above-mentioned emulsifying agent is injected thick alcohol; Inject ignition dope; The injection potassium nitrate solution also leaves standstill.
As further improvement, described thick alcohol is that mass percent is 90% methanol aqueous solution.
Described ignition dope is to be mixed by 5: 4: 100 liquid tween 80 of mass ratio, class 80 of department and ethyl acetate.
Described potassium nitrate solution is 70 ℃ of aqueous solution of saltpetre of mass percent 85%.
Also comprise the concentration adjustment step at last, promptly regulate the concentration to 85% of methyl alcohol in the product through adding methyl alcohol or cleaning water.
After adopting such design, the present invention has the following advantages at least:
1, the present invention is to be basis a kind of environment friendly biological fuel newly developed with methyl alcohol, and its raw material is extensive, and is with low cost, and technology is simple, and chemical plant, material benzenemethanol various places, fertilizer plant and Chemical market all have sale.Can purchase processing nearby, market goods locally adds the emulsifying agent according to new formulated, and the calorific value of alcohol-group fuel of the present invention and oil liquefied gas is suitable, and cost is merely about 1/2 of oil liquefied gas or diesel oil, utilizes the space very big.Invest the pure oily factory of a daily output 3-5 ton, plant area 100m2 gets final product, the sale of can turning round of ten thousand yuan of funds of 1-2; Need not mechanical means, have power for illumination to get final product, common plastics bucket, oil drum can transport storage; Scale is changeable, does not need production unit, and the no three wastes are produced in artificial preparation; 2 people can produce 10 tons daily, and investment cycle is short, takes effect in the week;
2, calorific value is high, energy consumption is low; Add 5.15 ‰ emulsifying agent and can improve the calorific value of alcohol-group fuel about 1/3, use through pilot conversion, its technical feature and safety index meet the requirement of domestic fuel; Calorific value is up to 8600 kilocalorie/kilograms; Obviously be superior to existing alcohol-group fuel, under combustion time, temperature, consumption and situation that diesel oil, liquefied gas equate, its production cost price only is 1/3 of a diesel-fuel price.
3, be difficult for performance, calorific value is sufficient, well solved the defective that calorific value is not enough, consumption is big of alcohol-group fuel, and it is unstable to have solved traditional alcohol-group fuel, volatile, uneasy congruent problem.
Embodiment
The emulsifier special of alcohol-group fuel of the present invention is to adopt following method preparation: the aqueous acetone of the solid Industrial Salt of the solid sodium bicarbonate of 210 weight parts, 32 weight parts and 26 weight parts is poured in 70 ℃, the warm water of 200 weight parts dissolved earlier; Again the solid potassium permanganate of 31 weight parts and the solid Resorcinol of 16 weight parts are mixed, add the water dissolution of 200 weight parts; Be that 99.9% ethanol mixes stand for standby use with above-mentioned two kinds of solution and 400 weight parts, mass concentration at last.
Alcohol-group fuel of the present invention is through the alcohol-group fuel emulsifier special of the present invention preparation and ignition dope, potassium nitrate solution are injected thick alcoholic solution and make.
Wherein, thick alcoholic solution is that mass percent is 90% methanol aqueous solution.Ignition dope is to be mixed and left standstill by 5: 4: 100 tween 80 of mass ratio, class 80 of department and ETHYLE ACETATE liquid to process.Potassium nitrate solution is 70 ℃ the aqueous solution of mass percent 85%.
The mass percent that emulsifying agent, ignition dope, potassium nitrate solution and methyl alcohol account for alcohol-group fuel is respectively 0.515%, 0.545%, 0.025% and 84%, and surplus is a water.
Leave standstill more than 15 minutes after above-mentioned solution mixes and be finished product, batch process should be left standstill more than 4 hours to good.Put into finished product with the alcohol detection meter and carry out the concentration detection, add methyl alcohol or cleaning water and carry out concentration adjustment, the mass concentration to 85% of in general regulating methyl alcohol is for suitable.
With Measuring Instrument of Flame Temperature traditional alcohol-group fuel and alcohol-group fuel of the present invention are tested, the result shows: existing alcohol-group fuel calorific value is 5300 kilocalories, and calorific value of the present invention is 8700 kilocalories, and effect of the present invention is obviously better.
The above; It only is preferred embodiment of the present invention; Be not that the present invention is done any pro forma restriction, those skilled in the art utilize the technology contents of above-mentioned announcement to make a little simple modification, equivalent variations or modification, all drop in protection scope of the present invention.
Claims (10)
1. the emulsifier special preparation method of an alcohol-group fuel is characterized in that may further comprise the steps:
Sodium bicarbonate, Industrial Salt, acetone poured in the warm water dissolve;
Potassium permanganate and Resorcinol are mixed and be dissolved in water;
Above-mentioned two kinds of solution are mixed stand for standby use with ethanol.
2. the emulsifier special preparation method of alcohol-group fuel according to claim 1 is characterized in that described:
Sodium bicarbonate is the solid of 210 weight parts, and Industrial Salt is the solid of 32 weight parts, and acetone is the liquid of 26 weight parts, and the three joins in 200 weight parts, 70 ℃ the water dissolves;
Potassium permanganate is the solid of 31 weight parts, and Resorcinol is the solid of 16 weight parts, and the two adds in the water of 200 weight parts dissolves;
The alcoholic acid mass concentration is 99.9%, gets 400 weight parts and mixes with two solution of above-mentioned weight part.
3. according to the alcohol-group fuel emulsifier special of claim 1 or the preparation of 2 said methods.
4. alcohol-group fuel is characterized in that containing the described alcohol-group fuel emulsifier special of claim 3 of mass percent 0.515%.
5. alcohol-group fuel according to claim 4 is characterized in that also containing mass percent and is respectively 0.545%, 0.025% and 84% ignition dope, saltpetre and methyl alcohol, and surplus is a water.
6. the preparation method of claim 4 or 5 described alcohol-group fuels is characterized in that may further comprise the steps:
Blend thick alcoholic solution;
The described emulsifying agent of claim 3 is injected thick alcohol;
Inject ignition dope;
The injection potassium nitrate solution also leaves standstill.
7. the preparation method of alcohol-group fuel according to claim 6 is characterized in that described thick alcohol is that mass percent is 90% methanol aqueous solution.
8. the preparation method of alcohol-group fuel according to claim 6 is characterized in that described ignition dope is to be mixed by 5: 4: 100 liquid tween 80 of mass ratio, class 80 of department and ethyl acetate.
9. the preparation method of alcohol-group fuel according to claim 6 is characterized in that described potassium nitrate solution is 70 ℃ of aqueous solution of saltpetre of mass percent 85%.
10. the preparation method of alcohol-group fuel according to claim 6 is characterized in that also comprising at last the concentration adjustment step, promptly regulates the concentration to 85% of methyl alcohol in the product through adding methyl alcohol or cleaning water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110221650A CN102304399A (en) | 2011-08-04 | 2011-08-04 | Emulsifier special for alcohol-based fuel and alcohol-based fuel prepared from same as well as preparation methods |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110221650A CN102304399A (en) | 2011-08-04 | 2011-08-04 | Emulsifier special for alcohol-based fuel and alcohol-based fuel prepared from same as well as preparation methods |
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| CN102304399A true CN102304399A (en) | 2012-01-04 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618337A (en) * | 2012-04-11 | 2012-08-01 | 韦唯 | Method for manufacturing civil fuel of biological alcohol oil |
| CN103666586A (en) * | 2012-08-31 | 2014-03-26 | 天津滨海新区金火焰科技有限公司 | High-energy synthetic fuel |
| CN103666602A (en) * | 2012-08-31 | 2014-03-26 | 天津滨海新区金火焰科技有限公司 | Emulsifier capable of promoting fuel combustion |
| CN108504401A (en) * | 2018-04-28 | 2018-09-07 | 潍坊长润新能源有限公司 | A kind of new energy fuel formula and preparation method thereof |
| CN111484879A (en) * | 2020-04-29 | 2020-08-04 | 白城师范学院 | Preparation method of biological alcohol fuel |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1213694A (en) * | 1998-08-18 | 1999-04-14 | 张云 | Formulation and prodn. method of gas light oil |
| CN101880554A (en) * | 2010-07-30 | 2010-11-10 | 郑德明 | Alcohol liquid fuel and preparation method thereof |
-
2011
- 2011-08-04 CN CN201110221650A patent/CN102304399A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1213694A (en) * | 1998-08-18 | 1999-04-14 | 张云 | Formulation and prodn. method of gas light oil |
| CN101880554A (en) * | 2010-07-30 | 2010-11-10 | 郑德明 | Alcohol liquid fuel and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618337A (en) * | 2012-04-11 | 2012-08-01 | 韦唯 | Method for manufacturing civil fuel of biological alcohol oil |
| CN103666586A (en) * | 2012-08-31 | 2014-03-26 | 天津滨海新区金火焰科技有限公司 | High-energy synthetic fuel |
| CN103666602A (en) * | 2012-08-31 | 2014-03-26 | 天津滨海新区金火焰科技有限公司 | Emulsifier capable of promoting fuel combustion |
| CN108504401A (en) * | 2018-04-28 | 2018-09-07 | 潍坊长润新能源有限公司 | A kind of new energy fuel formula and preparation method thereof |
| CN111484879A (en) * | 2020-04-29 | 2020-08-04 | 白城师范学院 | Preparation method of biological alcohol fuel |
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Application publication date: 20120104 |