CN102302005B - Application of JS399-19 (2-cyano-3-amino-3-phenylacrylic acetate) in preventing and controlling wheat take-all diease - Google Patents
Application of JS399-19 (2-cyano-3-amino-3-phenylacrylic acetate) in preventing and controlling wheat take-all diease Download PDFInfo
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Abstract
The invention discloses an application of JS399-19 (2-cyano-3-amino-3-phenylacrylic acetate) in preventing and controlling wheat take-all. The JS399-19 can be prepared into agriculturally allowable suspending seed coating agents, seed treatment dispersible powder, and seed treatment dispersible granules. The JS399-19 has effects of controlling and protecting the wheat take-all, good sterilizing effect, low use cost, and good crop safety, and can slow down the production of resistance and meet the safety requirement of the pesticide preparation. The indoor toxicity EC50 (50% effective concentration) of the JS399-19 to the wheat take-all bacteria is 3.62 mg/L, and the JS399-19 has higher activity, the prevention and control effect to the wheat take-all is 82.20%-94.15%, the production of the wheat is increased by 75.2%-83.3%, and the JS399-19 is superior to the like product abroad.
Description
Technical field
The present invention relates to the application of 2-cyano-3-amino-3-phenylancryic acetate in preventing and treating take-all, belong to technical field of pesticide.
Background technology
2-cyano-3-amino-3-phenylancryic acetate, chemical name: 2-cyano group-3-phenyl-3-aminoacrylic acid ethyl ester, belong to cyanoacrylate, be the new type bactericide of the autonomous initiative in Jiangsu Pesticide Research Institute Co., Ltd.Efficient, the little poison of 2-cyano-3-amino-3-phenylancryic acetate, low-residual, environmentally friendly; to had protection and therapeutic action by the microbial all kinds of plant diseases of reaping hook, can be applicable to prevent and treat the microbial wheat scab of reaping hook, cotton wilt, banana Panama disease, bakanae disease of rice, watermelon blight etc.The product of listing has only 25% 2-cyano-3-amino-3-phenylancryic acetate suspending agent a kind of at present, and the registration controlling object is wheat scab, bakanae disease of rice in the Ministry of Agriculture.
Take-all is the important root disease that generally takes place in a kind of world wide that is caused by the gaeumannomyce wheat variety.This disease is a kind of typical soil-borne disease, germ from wheat seedling stage to becoming the strain phase all can endanger.In a single day take-all takes place, and rate of propagation is very fast, and plot only needs 3 time-of-weeks from sporadicly occurring to death in blocks, and harm seriously.Wheat yield 20%-30% generally can be caused in the morbidity field, and heavy person can reach more than 50%, even total crop failure.Take-all is a kind of dangerous disease, and the Ministry of Agriculture classifies it as plant quarantine object.China finds take-all early than nineteen forty-three in Yunnan, nineteen fifty-two finds in succession that in Hebei province all there is the generation of this disease present domestic wheat main producing region.
Take integrated control technique in the control of take-all, chemical control is very important means of prevention wherein more, when wheat cultivation, wheat seed is carried out chemicals treatment have safety, efficient, economy, labour-saving characteristics.But the medicament that the whole nation is registered in the take-all control has only 125 grams per liter silicon metsulfovax suspending agents a kind of, is U.S. Meng Shan product all.The silicon metsulfovax used 4 years in China, existed resistance risk, and the cost costliness, was badly in need of a kind of substitute products of invention.
2-cyano-3-amino-3-phenylancryic acetate is used for preventing and treating take-all and does not appear in the newspapers, and the inventor finds that through a large amount of lab screenings and field control effectiveness test 2-cyano-3-amino-3-phenylancryic acetate has good control efficiency to take-all.But but being suspension seed-coating agent, seed treatment dispersion powder, seed treatment dispersible granule formulation, the 2-cyano-3-amino-3-phenylancryic acetate preparation formulation do not see open report yet.Because 2-cyano-3-amino-3-phenylancryic acetate has unique mechanism of action to pathogen, drug cost is low, uses it for the control of take-all to alleviating the pathogen resistance, fills up the domestic take-all medicament blank of preventing and treating, and guarantees that Wheat Production safety is significant.
Summary of the invention
The object of the present invention is to provide the new purposes of 2-cyano-3-amino-3-phenylancryic acetate in preventing and treating take-all.
But but the preparation formulation that 2-cyano-3-amino-3-phenylancryic acetate can be prepared according to the known method of those skilled in the art of the present technique is suspension seed-coating agent, seed treatment dispersion powder, seed treatment dispersible granule.
In above-mentioned preparation, the weight percentage of 2-cyano-3-amino-3-phenylancryic acetate is 0.5%～80%, preferably 5%～70%, be more preferably 20%～60%.
To suspension seed-coating agent, spendable auxiliary agent has: film forming agent such as polysaccharose macromolecular compound (soluble starch, polypropylene graft copolymer, xanthans, microorganism mucilage), cellulose derivatives (hydroxypropyl methylcellulose, sodium carboxymethylcellulose, ethyl cellulose), seaweeds such as sodium alginate, agar, rosin, paraffin, gelatin, pectin, the water-soluble composite of polyvinyl alcohol, polyethylene glycol, polyvinyl acetate, polyacrylamide, polyvinylpyrrolidone and polyhydric alcohol polymer; In inorganic binder aluminium-magnesium silicate, clay, waterglass, the gypsum one or more; Dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2020(U.S. Huntsman Corporation produce the alkyl naphthalene sulfonic acid salt) in one or more; Phenethyl phenol polyoxyethylene poly-oxygen propylene aether), among the TERSPERSE 4894 one or more the sorbitan monostearate APEO), agricultural newborn 1601#(common name sorbitan monostearate), emulsifier T-60(common name alkyl phenol formaldehyde resin polyoxyethylene ether), farming breast 2201, this dish-60#(common name emulsifier such as Nongru-700 #(common name::::; Among wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, the TERSPERSE 2500 one or more; In thickener such as xanthans, polyvinyl alcohol, the bentonite one or more; In preservative such as formaldehyde, benzoic acid, the Sodium Benzoate one or more; Defoamer such as organic silicon defoamer; In antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, inorganic salts such as the sodium chloride one or more; Water is deionized water.
But to the seed treatment dispersion powder, spendable auxiliary agent has: in dispersant such as polycarboxylate, lignosulfonates, the alkylnaphthalene sulfonate one or more; Film forming agent such as polysaccharose macromolecular compound (soluble starch, polypropylene graft copolymer, xanthans, microorganism mucilage), cellulose derivatives (hydroxypropyl methylcellulose, sodium carboxymethylcellulose, ethyl cellulose), seaweeds such as sodium alginate, agar, rosin, paraffin, gelatin, pectin, the water-soluble composite of polyvinyl alcohol, polyethylene glycol, polyvinyl acetate, polyacrylamide, polyvinylpyrrolidone and polyhydric alcohol polymer, in the inorganic binder (aluminium-magnesium silicate, clay, gypsum) one or more; In wetting agent such as alkyl sulfate, alkylsulfonate, the naphthalene sulfonate one or more; Filler such as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
But for the seed treatment dispersible granule, those skilled in the art are familiar with the corresponding auxiliary agent of use and finish the present invention very much.In dispersant such as polycarboxylate, lignosulfonates, the alkylnaphthalene sulfonate one or more; In wetting agent such as alkyl sulfate, alkylsulfonate, the naphthalene sulfonate one or more; In disintegrant such as ammonium sulfate, urea, sucrose, the glucose one or more; Film forming agent such as polysaccharose macromolecular compound (soluble starch, polypropylene graft copolymer, xanthans, microorganism mucilage), cellulose derivatives (hydroxypropyl methylcellulose, sodium carboxymethylcellulose, ethyl cellulose), seaweeds such as sodium alginate, agar, rosin, paraffin, gelatin, pectin, the water-soluble composite of polyvinyl alcohol, polyethylene glycol, polyvinyl acetate, polyacrylamide, polyvinylpyrrolidone and polyhydric alcohol polymer; In binding agent such as diatomite, corn starch, PVA, carboxymethyl (ethyl) cellulose family one or more; Filler such as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
The invention provides the new purposes of 2-cyano-3-amino-3-phenylancryic acetate bactericide, take-all is had treatment add protective effect, bactericidal effect is good, and drug cost is low, can slow down the generation of resistance, and is good to crop safety, meets the security requirement of pesticidal preparations.2-cyano-3-amino-3-phenylancryic acetate is to gaeumannomyces graminis indoor virulence EC
50Being 3.62mg/L, showing higher activity, is 82.20%-94.15% to the take-all field control effect, and wheat increase yield 75.2%-83.3% is better than external like product.
Embodiment
Be described further below in conjunction with the content of the present invention of embodiment.
FORMULATION EXAMPLE 1
Take by weighing 0.5% 2-cyano-3-amino-3-phenylancryic acetate, 1% TERSPERSE 2700(polycarboxylate, U.S. Huntsman Corporation produces), 1% TERSPERSE 2500(U.S. Huntsman Corporation produces), 3% TERSPERSE 4894(U.S. Huntsman Corporation produces), 2.0% polyvinylpyrrolidone, 0.2% xanthans, 5% ethylene glycol, 0.3% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces) deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 0.5% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent behind the sand mill sand milling.
FORMULATION EXAMPLE 2
Taking by weighing 15% 2-cyano-3-amino-3-phenylancryic acetate 3%TERSPERSE 4894,2%TERSPERSE 2500,1%TERSPERSE 2020(U.S. Huntsman Corporation produces), 3.0% hydroxypropyl methylcellulose, 0.5% bentonite, 5% ethylene glycol, 0.3% Sodium Benzoate, 0.5% silicone defoaming agent deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 15% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent behind the sand mill sand milling.
FORMULATION EXAMPLE 3
Take by weighing 30% 2-cyano-3-amino-3-phenylancryic acetate, 3%TERSPERSE 4894,1% alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, 1% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2.0% polyvinyl acetate, 0.2% xanthans, 5% propane diols, 0.3% benzoic acid, 0.5% silicone defoaming agent deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent behind the sand mill sand milling.
FORMULATION EXAMPLE 4
Take by weighing 60% 2-cyano-3-amino-3-phenylancryic acetate, 4%TERSPERSE 2700,2% hydroxypropyl methylcellulose, 3% polyethylene glycol (molecular weight is 8000), 2% lauryl sodium sulfate, 5% white carbon, attapulgite and add to 100% weight portion.Above-mentioned raw materials is through mixing, but air-flow makes 60% 2-cyano-3-amino-3-phenylancryic acetate seed treatment dispersion powder after pulverizing.
FORMULATION EXAMPLE 5
Take by weighing 40% 2-cyano-3-amino-3-phenylancryic acetate, 4% sodium lignin sulfonate, 2% sodium carboxymethylcellulose, 3% polyethylene glycol (molecular weight is 5000), 2% nekal, 5% white carbon, fine particle calcium carbonate and add to 100% weight portion.Above-mentioned raw materials is through mixing, but air-flow makes 40% 2-cyano-3-amino-3-phenylancryic acetate seed treatment dispersion powder after pulverizing.
FORMULATION EXAMPLE 6
Take by weighing 25% 2-cyano-3-amino-3-phenylancryic acetate, 4% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% nekal, 1% hydroxypropyl methylcellulose, 2% polyvinyl alcohol (molecular weight is 8000), 2% lauryl sodium sulfate, kaolin and add to 100% weight portion.Above-mentioned raw materials is through mixing, but air-flow makes 25% 2-cyano-3-amino-3-phenylancryic acetate seed treatment dispersion powder after pulverizing.
FORMULATION EXAMPLE 7
Take by weighing 50% 2-cyano-3-amino-3-phenylancryic acetate, 3% TERSPERSE 2700,0.5% xanthans, 3% polyethylene glycol (molecular weight is 10000), 3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% nekal, 2% lauryl sodium sulfate, 3% diatomite, 5% glucose, kaolin and add to 100% weight portion.But above-mentioned raw materials is produced 50% 2-cyano-3-amino-3-phenylancryic acetate seed treatment dispersible granule through mixing, the pulverizing of ultra micro air-flow, mixing, granulation step.
FORMULATION EXAMPLE 8
Take by weighing 80% 2-cyano-3-amino-3-phenylancryic acetate, 3% TERSPERSE 2700,1% hydroxypropyl methylcellulose, 3% polyacrylamide, 2% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 1% urea, kaolin adds to 100% weight portion.But above-mentioned raw materials is produced 80% 2-cyano-3-amino-3-phenylancryic acetate seed treatment dispersible granule through mixing, the pulverizing of ultra micro air-flow, mixing, granulation step.
FORMULATION EXAMPLE 9
Take by weighing 65% 2-cyano-3-amino-3-phenylancryic acetate, 3% TERSPERSE 2700,2%K-12(lauryl sodium sulfate), 2% sodium alginate, 0.3% xanthans, 3% polyvinylpyrrolidone, 5% ammonium sulfate, diatomite add to 100% weight portion.But above-mentioned raw materials is produced 65% 2-cyano-3-amino-3-phenylancryic acetate seed treatment dispersible granule through mixing, the pulverizing of ultra micro air-flow, mixing, granulation step.
Biological Examples 1:
Test is gaeumannomyces graminis: Gaeumannomyces grami nis, the former medicine that the former medicine of test medicine 2-cyano-3-amino-3-phenylancryic acetate adopts Jiangsu Province limited company of research institute to produce, the former medicine that the former medicine of silicon metsulfovax adopts U.S. Monsanto Company to produce.By the inventor former medicine is mixed with the test medicine that needs, test method is with reference to " the agricultural industry criteria NY/T1156.2-2006 of the People's Republic of China (PRC) ".At first each medicament is arranged 5 variable concentrations gradients, bacteriostasis rate is set by geometric progression in 5%～90% scope, establishes the clear water contrast, repeats 4 times.Adopt the mycelial growth rate method, with cultured pathogen, under aseptic condition, be 5 mm card punch with diameter, cut the bacterium cake from colony edge, with transfer needle the bacterium cake is connected on the culture medium flat plate of different drug concentrations, put in 26 ℃ of incubators and cultivated 72 hours, check colony diameter, calculate the percentage that each chemicals treatment suppresses mycelial growth, the EC of each medicament is obtained in the linear regression analysis between the probit value by inhibiting rate and the logarithm value of series concentration
50Value is estimated reagent agent to the activity of germ with this.
By table 1, table 2 as can be known, 2-cyano-3-amino-3-phenylancryic acetate has good restraining effect, EC to gaeumannomyces graminis
50Be 3.62mg/l, be better than silicon metsulfovax (EC
50Be 4.38mg/l), show very high biologically active.
Biological Examples 2
Prevent and treat the take-all field trial
The inventor carried out FORMULATION EXAMPLE 3(30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent in the Xinyue City, Hebei province in 2011) prevent and treat the take-all field trial, verified that this medicament is to the control efficiency of take-all, effective dose and to the safety of wheat.Trial crops is wheat, and kind is that stone is new 828, and controlling object is take-all (Gaeumannomyces grami nis).Test is located at Kimura township, Xinyue City Zhong Tong village poplar and increases army's farmland covered by contract, and the plot is sandy loam ground, pH value 7.8, irrigated land.Sowing on October 13rd, 2010, the amount of broadcasting 16.5 kilograms/667 ㎡.。
Test medicine and dosage are: 30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent 50g/15kg seed, 75g/15kg seed, 100g/15kg seed, 12.5% silicon metsulfovax suspending agent 20/15kg seed, 30 g/15kg seeds.Other establishes clear water contrast, and every processing repeats for 4 times, every residential quarter area 30 ㎡, and totally 24 residential quarters, district's group is arranged at random.
Dressing and seed dressing method: each handles medicine, kind amount by 4 repetitions (120 ㎡), earlier with the medicament thin up that weighs up, amount of water is pressed the 1500mL/100kg seed and is calculated, then soup is slowly poured on the seed of getting ready, the limit bevelling stirs and makes soup be evenly distributed to every the surface of the seed, vexed kind 12 hours is dried fully in the cool then and is broadcast.The quantitative hand slide of artificial trench digging method is adopted in sowing.
Investigation and statistical method:
Investigate altogether 2 times, respectively at the wheat during jointing stage investigation root system incidence of disease and harvesting wheat investigation in preceding 10 days dead ears rate.
The root system investigation: every residential quarter is 5 samplings at random, get 20 strain root samples at every, will put in order strain with spade and carefully dig out, and rinse well in clear water, and investigation root system incidence is represented with the percentage level that each plant root is infected under white background.
0 grade: anosis;
1 grade: the root system onset area accounts for 1%～5%;
3 grades: the root system onset area accounts for 6%～20%;
5 grades: the root system onset area accounts for 21%～40%;
7 grades: the root system onset area accounts for 41%～60%;
9 grades: the root system onset area accounts for more than 61%;
Dead ears rate investigation: get the 1.5m duplicate rows at every and investigate total spike number and dead ears rate.
3. computational methods
Disease index=[∑ (diseased plant numbers at different levels * relative level numerical value)/(investigating total strain number * 9)] * 100
Control efficiency % (root system)=[(contrast disease index-processing disease index)/contrast disease index] * 100
Dead ears rate (%)=(withered dead ears number/investigate total spike number) * 100
Control efficiency % (fringe portion)=[(contrast dead ears rate-processing dead ears rate)/contrast dead ears rate] * 100
The single receipts in each residential quarter of maturing stage, singles survey thousand kernel weight and output.
Security survey: wheat is broadcast investigation in back 15 days and is had or not influence to emerging and have or not symptom of chemical damage.
Field test results shows: 30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent is pressed 50g/15kg, 75g/15kg, the seed dressing of 100g/15kg seed consumption, take-all is respectively 85.64%, 91.25%, 94.15% in the shooting stage to the preventive effect of root system, be respectively 82.20%, 86.02%, 90.17% in preceding 10 days preventive effects to fringe portion of results, the wheat increase yield rate is respectively 75.2%, 78.7%, 83.3%.It is low slightly that 30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent 50g/15kg handles preventive effect than 12.5% silicon metsulfovax suspending agent 20/15kg, 30/15kg, 30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent is pressed 75g/15kg, the seed dressing of 100g/15kg seed consumption, and preventive effect and rate of growth all are higher than 12.5% silicon metsulfovax suspending agent 20/15kg, 30/15kg.
30% 2-cyano-3-amino-3-phenylancryic acetate suspension seed-coating agent shows good control efficiency to take-all, increase yield significantly, and consumption is advisable with the 75g-100g/15kg seed.
Investigation in back 15 days is broadcast in security survey, wheat does not have influence to emergence rate, and seedling-growing time late 1 day than blank does not have influence to late growing stage.
In sum, the present invention has supplied the new purposes of 2-cyano-3-amino-3-phenylancryic acetate bactericide, take-all is had treatment add protective effect, shows very high activity, and bactericidal effect is good, and drug cost is low, and is good to crop safety, meets efficient, the safety requirements of pesticidal preparations.
Claims (5)
1. the application of 2-cyano-3-amino-3-phenylancryic acetate in preventing and treating take-all.
2. according to the described application of claim 1, it is characterized in that: but but described 2-cyano-3-amino-3-phenylancryic acetate is processed as suspension seed-coating agent, seed treatment dispersion powder or seed treatment dispersible granule.
3. according to the described application of claim 2, it is characterized in that: the weight percentage of 2-cyano-3-amino-3-phenylancryic acetate is 0.5%～80%.
4. according to the described application of claim 3, it is characterized in that: the weight percentage of 2-cyano-3-amino-3-phenylancryic acetate is 5%～70%.
5. according to the described application of claim 4, it is characterized in that: the weight percentage of 2-cyano-3-amino-3-phenylancryic acetate is 20%～60%.
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| CN102715156B (en) * | 2012-06-29 | 2015-02-18 | 陕西上格之路生物科学有限公司 | Sterilization composition containing js399-19 |
| CN103749522B (en) * | 2012-07-30 | 2015-09-09 | 陕西上格之路生物科学有限公司 | The bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and acid amide fungicides |
| CN105707061B (en) * | 2016-03-25 | 2018-09-18 | 江西正邦作物保护有限公司 | Application of the composition of polyacrylamide and hydroxypropyl methyl cellulose in preparing pesticide |
| CN107760108A (en) * | 2017-09-25 | 2018-03-06 | 浙江纳美新材料股份有限公司 | A kind of seed coat agent wear-resisting mixing mill base and preparation method thereof |
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| CN1559210A (en) * | 2004-02-18 | 2005-01-05 | 江苏省农药研究所有限公司 | 2-cyano-3-amino-3-ethyl phenylacrylate used for prevention and control of plant disease and elimination of pests |
| CN1623390A (en) * | 2004-10-27 | 2005-06-08 | 江苏省农药研究所有限公司 | Application of 2-cydno-3-amino-3-phenylethyl acrylate for preventing and treating patty rice bakanae disease |
| CN101416625A (en) * | 2008-11-28 | 2009-04-29 | 陕西韦尔奇作物保护有限公司 | Agricultural bactericide containing JS399-19 and use thereof |
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| DE3361451D1 (en) * | 1982-03-05 | 1986-01-23 | Fbc Ltd | Fungicidal cyanopropenoates and compositions containing them |
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| CN1559210A (en) * | 2004-02-18 | 2005-01-05 | 江苏省农药研究所有限公司 | 2-cyano-3-amino-3-ethyl phenylacrylate used for prevention and control of plant disease and elimination of pests |
| CN1623390A (en) * | 2004-10-27 | 2005-06-08 | 江苏省农药研究所有限公司 | Application of 2-cydno-3-amino-3-phenylethyl acrylate for preventing and treating patty rice bakanae disease |
| CN101416625A (en) * | 2008-11-28 | 2009-04-29 | 陕西韦尔奇作物保护有限公司 | Agricultural bactericide containing JS399-19 and use thereof |
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