CN101416625A - Agricultural bactericide containing JS399-19 and use thereof - Google Patents
Agricultural bactericide containing JS399-19 and use thereof Download PDFInfo
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- CN101416625A CN101416625A CNA2008102324654A CN200810232465A CN101416625A CN 101416625 A CN101416625 A CN 101416625A CN A2008102324654 A CNA2008102324654 A CN A2008102324654A CN 200810232465 A CN200810232465 A CN 200810232465A CN 101416625 A CN101416625 A CN 101416625A
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- cyano
- amino
- phenylancryic acetate
- bactericide
- phenylancryic
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Abstract
The invention belongs to the technical field of pesticide, particularly relates to an agriculture germicide containing JS399-19 with 1-80% of active constituents. The JS399-19 belongs to 2-cyanoacrylate, which is a novel germicide developed by Jiangsu Pesticide Research Institution Co., Ltd. The invention has comparatively high sterilizing activity to various pathogenic bacteria. The invention is mainly applied to the prevention and treatment to leaf spot, scab, rust, powdery mildew, wheat scab, and alternaria leaf spot.
Description
Technical field:
The invention belongs to technical field of pesticide, announced a kind of disinfectant use in agriculture that contains 2-cyano-3-amino-3-phenylancryic acetate, belong to 2-cyanoacrylate bactericide.
Background technology:
2-cyano-3-amino-3-phenylancryic acetate, outward appearance are white powder, molecular formula C
12H
12N
2O
2, chemical name is: 2-cyano group-3-amino-3-aminoacrylic acid ethyl ester.
2-cyano-3-amino-3-phenylancryic acetate is a kind of new type bactericide of mode of action uniqueness, also is first commercial bactericide in such chemical constitution.This medicine is synthetic in 1998 by Jiangsu Prov. Inst. of Agricultural Chemicals, and calendar year 2001 is carried out field trial, is carrying out interim registration of agricultural chemicals and further investigation exploitation at present, will play a significant role in chemical control such as wheat scab, bakanae disease of rice.
This medicine has higher bactericidal activity to multiple pathogen, and especially the head blight that the Fusarium graminearum of Fusarium is caused, the bakanae disease of rice that fusarium moniliforme causes, the watermelon blight that Fusarium oxysporum causes have good control.2-cyano-3-amino-3-phenylancryic acetate is effective to the disease that the reaping hook mushroom causes, has protection and therapeutic action.Be absorbed by root, upwards transporting is arranged on blade.To crop safety, do not see that poisoning takes place.
At present, the formulation of 2-cyano-3-amino-3-phenylancryic acetate preparation is mainly suspending agent, and registration card number is LS20072657, and the registration crop is a wheat scab.The bin stability of suspending agent is important performance indications, it concerns the performance and the effect of product, and the factor of influence stability is more, require all higher to former concentration, auxiliary agent, pH value, and suspending agent placed and occurred layering or deposited phenomenon for a long time easily, and then influenced the performance of drug effect.Wetting powder, water dispersible granules, aqueous emulsion, microemulsion can effectively be avoided the weak point of suspending agent formulation.
Summary of the invention
The objective of the invention is to propose a kind of disinfectant use in agriculture that contains 2-cyano-3-amino-3-phenylancryic acetate, this bactericide is mainly used in the control of leaf spot, scab, rust, powdery mildew, head blight, spot defoliation.
The present invention is achieved by the following technical solutions:
A kind of disinfectant use in agriculture that contains 2-cyano-3-amino-3-phenylancryic acetate, its effective active composition percentage composition is 1%～80%.
A kind of disinfectant use in agriculture that contains 2-cyano-3-amino-3-phenylancryic acetate, this bactericide adds auxiliary agent and excipients is made wetting powder, water dispersible granules, aqueous emulsion, microemulsion.
Described wetting powder comprises the component of following weight portion:
2-cyano-3-amino-3-phenylancryic acetate 10%～80%, dispersant 1%～10%, wetting agent 1%～5%, filler surplus.
Described dispersant is selected from one or more in lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO, uses that total consumption is no more than 10% when multiple.
Described wetting agent is natural products wetting agent and cationic wetting agent, available tea is withered, spaonin powder, silkworm excrement, soapberry powder, bay alcohol radical sodium sulphate, neopelex, washing powder, draw back in the powder one or more, uses that total consumption is no more than 5% when multiple.
Described filler is mineral carrier or synthetic vectors, one or more in available kaolin, diatomite, white carbon, the fine particle calcium carbonate;
Above-mentioned formulation material is mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
Described water dispersible granules comprises the component of following weight portion:
2-cyano-3-amino-3-phenylancryic acetate 20%～80%, dispersant 1%～15%, wetting agent 1%～5%, disintegrant 1%～5%, adhesive 0.1%～5%, filler surplus.
Wherein, described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO, uses that total consumption is no more than 15% when multiple.
Described wetting agent is selected from lauryl sodium sulfate, draws back powder, among the wetting and penetrating agent T, spaonin powder one or more, uses that total consumption is no more than 5% when multiple.
Described disintegrant is selected from one or more in bentonite, ammonium sulfate, calcium chloride, urea, magnesium chloride, aluminium chloride, citric acid, succinic acid, the carbonic hydroammonium, uses that total consumption is no more than 5% when multiple.
Described adhesive is selected from one or more in polyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, the white dextrin, uses that total consumption is no more than 5% when multiple.
Described carrier is selected from one or more in kaolin, diatomite, white carbon, starch, bentonite, the fine particle calcium carbonate.
Described 2-cyano-3-amino-3-phenylancryic acetate water dispersible granules is produced by following steps:
The former medicine of 2-cyano-3-amino-3-phenylancryic acetate is obtained the particle diameter that needs with dispersant, wetting agent, disintegrant, thinner etc. through comminution by gas stream, add other auxiliary agents such as adhesive again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, gets its product.
Described aqueous emulsion comprises the component of following weight portion:
2-cyano-3-amino-3-phenylancryic acetate 1%～60%, solvent and cosolvent 1%～20%, emulsifier 3%～10%, co-emulsifier 0%～5%, antifreeze 1%～5%, defoamer 0.1%～1%, water surplus.
Described solvent and cosolvent are selected from toluene, dimethylbenzene, methyl alcohol, ethanol, cyclohexanone, vegetable oil, dimethyl formamide, acetonitrile, polyethylene glycol, pyrrolidones, use that total consumption is no more than 20% when multiple.
Described emulsifier is selected from alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, phenethyl phenol polyoxy third rare ether, homemade farming breast 300
#, farming breast 506
#, OP-10 phosphate, farming breast 600
#, 601 phosphates, Nongru-700
#, in agricultural newborn A, agricultural newborn B, sorbester p17, the Tween 80 one or more, use that total consumption is no more than 10% when multiple.
Described co-emulsifier is one or more in butanols, isobutanol, dodecanol-1, tetradecanol-1, the octadecanol-1, uses that total consumption is no more than 5% when multiple.
Described frost resistance is selected from one or more in ethylene glycol, glycerine, propane diols, glycerine, polyethylene glycol, sorbierite, isopropyl alcohol or the urea, uses that total consumption is no more than 5% when multiple.
Described defoamer is selected from one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound, uses that total consumption is no more than 1% when multiple.
Described 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion is produced by following steps:
(1) above-mentioned formulation material is mixed, the former medicine of 2-cyano-3-amino-3-phenylancryic acetate, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase;
(2) water, antifreeze, defoamer are mixed, become the homogeneous water;
(3) under high-speed stirred, water is added oil phase, can make 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion product of the present invention.
Described microemulsion comprises the composition of following weight portion:
2-cyano-3-amino-3-phenylancryic acetate 1%～50%, emulsifier 1%～20%, solvent and cosolvent 1%～20%, antifreezing agent 3%～10%, stabilizing agent 0.3%～5%, water surplus.
Described emulsifier is selected from alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, phenethyl phenol polyoxy third rare ether, homemade farming breast 300
#, farming breast 506
#, farming breast 600
#, Nongru-700
#, among agricultural newborn A, the agricultural newborn B one or more, use that total consumption is no more than 20% when multiple.
Described solvent and cosolvent are selected from one or more in methyl alcohol, acetonitrile, dimethyl formamide, ethylene glycol, propane diols, toluene, dimethylbenzene, ethanol, cyclohexanone, vegetable oil, N-methyl pyrrolidone, the N-octylpyrrolidone, use that total consumption is no more than 20% when multiple.
Described antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, glycerine, polyethylene glycol, sorbierite, isopropyl alcohol or urea, uses that total consumption is no more than 10% when multiple.
Described stabilizing agent is selected from one or more in butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether or the sodium sorbate, uses that total consumption is no more than 5% when multiple.
Described 2-cyano-3-amino-3-phenylancryic acetate microemulsion is produced by following steps:
(1) the former medicine of 2-cyano-3-amino-3-phenylancryic acetate is dissolved in the reactor that solvent and cosolvent are housed;
(2) emulsifier is joined mixed in the reactor of above-mentioned solution after, antifreezing agent, stabilizing agent and water constantly slowly adding under the condition of stirring, are stirred and obtain the as clear as crystal 2-cyano-3-amino-3-phenylancryic acetate microemulsion of outward appearance after 30 minutes.
The invention has the advantages that: it is simple to have production technology, cost is low, easy to use, operator ' s health there are not the injury and the characteristics of environmentally safe, reduced cost, improved safety to the producer, transporter, user, have the advantage of suspending agent simultaneously concurrently, overcome its shortcoming, and can give full play to the drug effect of 2-cyano-3-amino-3-phenylancryic acetate, strengthened penetrating ability, improved the availability of effective active composition plant disease.
Specific embodiment
The present invention describes with following embodiment, but not as limitation of the present invention.
Embodiment 1 40% 2-cyano-3-amino-3-phenylancryic acetate wetting powder
The former medicine 40g of 2-cyano-3-amino-3-phenylancryic acetate, wetting and penetrating agent T4g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 5g, white carbon 8g, kaolin adds to 100g, and mixture carries out comminution by gas stream, makes 40% 2-cyano-3-amino-3-phenylancryic acetate wetting powder.
Embodiment 2 65% 2-cyano-3-amino-3-phenylancryic acetate wetting powders
The former medicine 65g of 2-cyano-3-amino-3-phenylancryic acetate, lauryl sodium sulfate 2g, Nekal BX 6g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 5g, white carbon 8g, kaolin adds to 100g, and mixture carries out comminution by gas stream, makes 65% 2-cyano-3-amino-3-phenylancryic acetate wetting powder.
Embodiment 3 50% 2-cyano-3-amino-3-phenylancryic acetate water dispersible granules
The former medicine 50g of 2-cyano-3-amino-3-phenylancryic acetate, sodium lignin sulfonate 8g, ammonium sulfate 4g, tributyl phosphate 1.5g, wetting agent T 3g, polyethylene glycol 0.5g, kaolin 10g, diatomite add to 100g.Make 50% 2-cyano-3-amino-3-phenylancryic acetate water dispersible granules.
Embodiment 4 70% 2-cyano-3-amino-3-phenylancryic acetate water dispersible granules
The former medicine 70g of 2-cyano-3-amino-3-phenylancryic acetate, two sodium naphthasulfonate 8g, spaonin powder 5g, urea 5g, polyethylene glycol 0.5g, diatomite add to 100g, the mixed 70% 2-cyano-3-amino-3-phenylancryic acetate water dispersible granules that gets.
Embodiment 5 30% 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsions
The former medicine 30g of 2-cyano-3-amino-3-phenylancryic acetate, N, dinethylformamide 5g, OP-10 phosphate 8g, farming breast 600
#8g, glycerine 5g, polyacrylate 0.1g, deionized water add to 100g, the mixed 30% 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion that gets.
Embodiment 6 20% 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsions
The former medicine 20g of 2-cyano-3-amino-3-phenylancryic acetate, N, dinethylformamide 15g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyoxy third rare ether 8g, isopropyl alcohol 1.5g, ethylene glycol 2g, glycerine 1g, deionized water add to 100g, the mixed 20% 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion that gets.
Embodiment 7 25% 2-cyano-3-amino-3-phenylancryic acetate microemulsions
The former medicine 25g of 2-cyano-3-amino-3-phenylancryic acetate, farming breast 506
#8g, farming breast 602
#10g, N, dinethylformamide 18g, glycerin ether 1g, acetonitrile 1g, sldium lauryl sulfate 2g, ethylene glycol 5g, sodium sorbate 1g, water add to 100g.Above-mentioned formulation material is mixed stirring by aforementioned requirement in reactor, obtained 25% as clear as crystal 2-cyano-3-amino-3-phenylancryic acetate microemulsion of outward appearance at last.
Embodiment 8 45% 2-cyano-3-amino-3-phenylancryic acetate microemulsions
The former medicine 45g of 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyoxy third rare ether 8g, N, dinethylformamide 20g, cresyl glycidyl ether 1g, acetonitrile 2g, isopropyl alcohol 2g, glycerine 5g, water add to 100g.Above-mentioned formulation material is mixed stirring by aforementioned requirement in reactor, obtained 45% as clear as crystal 2-cyano-3-amino-3-phenylancryic acetate microemulsion of outward appearance at last.
Wetting powder the key technical indexes of the present invention:
Table 1
2-cyano-3-amino-3-phenylancryic acetate wetting powder of the present invention is better to the sigatoka control efficiency in the field, and result of the test is as shown in table 2:
Table 2
Water dispersible granules the key technical indexes of the present invention:
Table 3
2-cyano-3-amino-3-phenylancryic acetate water dispersible granules of the present invention is better to the banana freckle control efficiency in the field, and result of the test is as shown in table 4:
Table 4
Aqueous emulsion the key technical indexes of the present invention:
Table 5
It is as shown in table 6 that 2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion of the present invention is prevented and treated result of the test in the field to wheat scab:
Table 6
Microemulsion the key technical indexes of the present invention:
Table 7
It is as shown in table 8 that 2-cyano-3-amino-3-phenylancryic acetate microemulsion of the present invention is prevented and treated result of the test in the field to alternaria leaf spot of apple:
Table 8
In process of the test, find that in the control efficiency after control efficiency behind 3 days to wheat powdery mildew is 53.78%～65.48%, 10 days is 82.44%～92.15% to the wheat scab control.
In this scope of experiment, bactericide of the present invention is not seen harmful effect to target crop and beneficial organism, and drug effect is better than or is suitable with the contrast medicament.And it is little to have consumption, the advantage that the lasting period is long.
In sum, the bactericide of 2-cyano-3-amino-3-phenylancryic acetate-containing of the present invention, when formulation is wetting powder, water dispersible granules, aqueous emulsion, microemulsion, the control that is used for leaf spot, scab, rust, powdery mildew, head blight, spot defoliation has very high biologically active, good quick-acting, and wetting powder, water dispersible granules have added the auxiliary agent of heterogeneity, make the present invention have the active component content height, dispersive property is good in the water, the suspensibility height, environmental pollution is little, and disintegration rate is fast, stable storage, drug effect is brought into play advantages such as abundant.It is few to compare other 2-cyano-3-amino-3-phenylancryic acetate preparation dosage, and crop is not had poisoning, and influence has no adverse effects to natural enemy.Therefore, development of the present invention and promotion potential are huge, and development prospect is very wide, have the necessity and the feasibility of exploitation.
Claims (6)
1, the present invention relates to a kind of disinfectant use in agriculture of 2-cyano-3-amino-3-phenylancryic acetate-containing, its effective active component content is 1%～80%.
2, according to the described bactericide that contains 2-cyano-3-amino-3-phenylancryic acetate of claim 1, it is characterized in that: this bactericide comprises 2-cyano-3-amino-3-phenylancryic acetate 10%～80%, dispersant 1%～10%, and wetting agent 1%～5%, the filler surplus can be made into wetting powder.
3, according to the described bactericide that contains 2-cyano-3-amino-3-phenylancryic acetate of claim 1, it is characterized in that: this bactericide comprises 2-cyano-3-amino-3-phenylancryic acetate 20%～80%, dispersant 1%～15%, wetting agent 1%～5%, disintegrant 1%～5%, adhesive 0.1%～5%, the filler surplus can be made into water dispersible granules.
4, according to the described bactericide that contains 2-cyano-3-amino-3-phenylancryic acetate of claim 1, it is characterized in that: this bactericide comprises 2-cyano-3-amino-3-phenylancryic acetate 1%～60%, solvent and cosolvent 1%～20%, emulsifier 3%～10%, co-emulsifier 0%～5%, antifreeze 1%～5%, defoamer 0.1%～1%, water surplus can be made into aqueous emulsion.
5, according to the described bactericide that contains 2-cyano-3-amino-3-phenylancryic acetate of claim 1, it is characterized in that: this bactericide comprises 2-cyano-3-amino-3-phenylancryic acetate 1%～50%, emulsifier 1%～20%, solvent and cosolvent 1%～20%, antifreezing agent 3%～10%, stabilizing agent 0.3%～5%, water surplus can be made into microemulsion.
6, be mainly used in the control of leaf spot, scab, rust, powdery mildew, head blight, spot defoliation according to the described disinfectant use in agriculture that contains 2-cyano-3-amino-3-phenylancryic acetate of claim 1 to 5.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102324654A CN101416625A (en) | 2008-11-28 | 2008-11-28 | Agricultural bactericide containing JS399-19 and use thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102324654A CN101416625A (en) | 2008-11-28 | 2008-11-28 | Agricultural bactericide containing JS399-19 and use thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101919392A (en) * | 2010-08-31 | 2010-12-22 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing famoxadone and JS399-19 |
| CN102302004A (en) * | 2011-07-05 | 2012-01-04 | 青岛奥迪斯生物科技有限公司 | Suspension seed coating agent containing JS399-19 (2-cyano-3-amino-3-ethyl phenylacrylate) |
| CN102302005A (en) * | 2011-10-11 | 2012-01-04 | 陕西上格之路生物科学有限公司 | Application of JS399-19 (2-cyano-3-amino-3-phenylacrylic acetate) in preventing and controlling wheat take-all |
| CN104137833A (en) * | 2014-07-18 | 2014-11-12 | 江苏省绿盾植保农药实验有限公司 | Complex biological fungicide for preventing and treating wheat scab and application thereof |
| CN105076212A (en) * | 2015-09-09 | 2015-11-25 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing bacillus subtilis and phenamacril and application thereof |
| CN105660507A (en) * | 2016-03-02 | 2016-06-15 | 怀远县渔业科技发展有限责任公司 | Method for treating fish pond through pond cleaning |
| CN106818803A (en) * | 2017-03-02 | 2017-06-13 | 贵州道元生物技术有限公司 | The bactericide for preventing and treating wheat scab that rosickyite azoles is compounded with 2-cyano-3-amino-3-phenylancryic acetate |
-
2008
- 2008-11-28 CN CNA2008102324654A patent/CN101416625A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101919392A (en) * | 2010-08-31 | 2010-12-22 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing famoxadone and JS399-19 |
| CN101919392B (en) * | 2010-08-31 | 2013-04-10 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing famoxadone and JS399-19 |
| CN102302004A (en) * | 2011-07-05 | 2012-01-04 | 青岛奥迪斯生物科技有限公司 | Suspension seed coating agent containing JS399-19 (2-cyano-3-amino-3-ethyl phenylacrylate) |
| CN102302005A (en) * | 2011-10-11 | 2012-01-04 | 陕西上格之路生物科学有限公司 | Application of JS399-19 (2-cyano-3-amino-3-phenylacrylic acetate) in preventing and controlling wheat take-all |
| CN102302005B (en) * | 2011-10-11 | 2013-08-07 | 陕西上格之路生物科学有限公司 | Application of JS399-19 (2-cyano-3-amino-3-phenylacrylic acetate) in preventing and controlling wheat take-all diease |
| CN104137833A (en) * | 2014-07-18 | 2014-11-12 | 江苏省绿盾植保农药实验有限公司 | Complex biological fungicide for preventing and treating wheat scab and application thereof |
| CN104137833B (en) * | 2014-07-18 | 2016-05-18 | 江苏丘陵地区镇江农业科学研究所 | One is prevented and treated the biological composite bactericide of wheat scab and application thereof |
| CN105076212A (en) * | 2015-09-09 | 2015-11-25 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing bacillus subtilis and phenamacril and application thereof |
| CN105076212B (en) * | 2015-09-09 | 2018-03-20 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition containing bacillus subtilis and 2-cyano-3-amino-3-phenylancryic acetate |
| CN105660507A (en) * | 2016-03-02 | 2016-06-15 | 怀远县渔业科技发展有限责任公司 | Method for treating fish pond through pond cleaning |
| CN106818803A (en) * | 2017-03-02 | 2017-06-13 | 贵州道元生物技术有限公司 | The bactericide for preventing and treating wheat scab that rosickyite azoles is compounded with 2-cyano-3-amino-3-phenylancryic acetate |
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Application publication date: 20090429 |