CN102283785B - Self-heating hair care composition - Google Patents
Self-heating hair care composition Download PDFInfo
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- CN102283785B CN102283785B CN 201110235718 CN201110235718A CN102283785B CN 102283785 B CN102283785 B CN 102283785B CN 201110235718 CN201110235718 CN 201110235718 CN 201110235718 A CN201110235718 A CN 201110235718A CN 102283785 B CN102283785 B CN 102283785B
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Abstract
The invention discloses a self-heating hair care composition. The composition comprises the following components in percentage by weight: 0.05 to 10 percent of cationic surfactant, 0.05 to 15 percent of high-melting-point aliphatic compounds, 0.5 to 40 percent of inorganic salt and 30 to 95 percent of carrier. The invention also discloses a preparation method for the hair care composition. When the composition is applied to wet hair, the composition can ensure that the temperature on the surface of the hair is raised, promote active ingredients to be permeated more effectively, improve a conditioning effect, and improve the quality of the hair; and compared with general hair care compositions, the composition provides quicker and deeper conditioning.
Description
Technical field
The present invention relates to filed of daily-use chemical industry, be specifically related to a kind of self-heating hair care composition.
Background technology
At present, developed the hair care composition of a lot of kinds on market, the method that those skilled in the art commonly use is to use conditioner, as quaternary ammonium salt, cationic polymer, hard fat compounds of group, silicone compounds and some grease compounds, and their mixture.These care compositions can provide various conditioning effects, send out and dried softness and the smooth feeling of sending out as wet.During use, these conditioners can provide the beneficial effect of conditioning hair.
As everyone knows, when bestowing same hair products on hair, if adopt the mode that heat is steamed or other machinery heats, its final conditioning effect that obtains is much better than the effect of using under normal temperature condition, reason is, under temperature higher strip part, conditioning component can be carried to more efficiently hair surface or infiltrate into hair inside, more soft and smooth feel is provided, and hair is more glossy.Adopt the mode of heating usually can see in professional hairdressing place.
But, still there is more consumer to be chosen in family and uses hair products, usually do not possess the condition of heating, can not obtain better nursing efficacy, if can develop a kind of hair care product of spontaneous heating, even if family's routine use also can obtain to steam identical conditioning effect with professional hairdressing place heat.
Summary of the invention
The object of the invention is to the deficiency that exists in existing Haircare composition, provide a kind of can spontaneous heating, can improve the Haircare composition of hair hair quality and hair conditioning.
A kind of self-heating hair care composition comprises following component by mass percentage:
Cationic surfactant 0.05 ~ 10.0%,
Hard fat compounds of group 0.05 ~ 15%,
Inorganic salt 0.5 ~ 40%,
Carrier 35～95%.
In above-mentioned self-heating hair care composition, the structural formula of described cationic surfactant is as follows:
Wherein, R1, R2, R3, R4 are selected from the fat base that contains 1～40 carbon atom, fragrant fat, alkoxyl or alkylamidoalkyl, X
-Be alkyl sulfate ion or the chloride ion that contains 1～4 carbon atom.
Described cationic surfactant is single long alkyl quaternary ammonium salts, and one in its structural formula in R1, R2, R3, R4 is to be selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide; Remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom.
Described single long alkyl quaternary ammonium salts is one or more the mixture in cetyl trimethyl sulfate methyl ammonium, hexadecyltrimethylammonium chloride, stearyl trimethyl sulfate methyl ammonium, stearyl trimethyl ammonium chloride, docosanol trimethyl sulfate methyl ammonium, INCROQUAT TMC-80 ECONOL TM22, palmitamide oxypropyl trimethyl sulfate methyl ammonium, palmitamide oxypropyl trimethyl ammonium chloride, preferably hexadecyltrimethylammonium chloride.
Described cationic surfactant is two long alkyl quaternary ammonium saltss, two in its structural formula in R1, R2, R3, R4 is to be selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide, and remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom.
described two long alkyl quaternary ammonium salts is two cetyl dimethyl sulfate ammonium methyls, two cetyl alkyl dimethyl ammonium chlorides, two stearyl dimethyl sulfate ammonium methyls, two stearyl alkyl dimethyl ammonium chlorides, two docosyl dimethyl sulfate ammonium methyls, two docosyl alkyl dimethyl ammonium chlorides, two palmitamide propyl-dimethyl sulfate methyl ammoniums, two palmitamide propyl-dimethyl ammonium chloride, the mixture of one or more in two h-tallow fat base dimethyl sulfate ammonium methyls and two h-tallow fat base alkyl dimethyl ammonium chloride.
The preferred two cetyl dimethyl sulfate ammonium methyls of described two long alkyl quaternary ammonium salts.
In above-mentioned self-heating hair care composition, described hard fat compounds of group is one or more the mixture in aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid; Wherein, described aliphatic alcohol has 12～40 carbon atoms, and described fatty acid has 12～40 carbon atoms.
Described hard fat compounds of group is preferably spermol, stearyl alcohol and composition thereof.
In above-mentioned self-heating hair care composition, described inorganic salt is soluble in water, can produce exothermic reaction after this inorganic salt is dissolved in, and temperature rises 5～30 ℃.
Described inorganic salt comprises: sodium sulfate, calcium sulfate, aluminum sulfate, magnesium sulfate, calcium chloride, magnesium chloride and composition thereof.
Described inorganic salt preferably sulfuric acid magnesium, magnesium sulfate exists with particle form in compositions, and particle diameter is 1 ~ 50 micron.
In above-mentioned self-heating hair care composition, described carrier comprises: propylene glycol, ethylene glycol, glycerol, tetramethylolmethane, sorbitol, and composition thereof.The preferred propylene glycol of described carrier.
In above-mentioned self-heating hair care composition, also can add silicone compounds or grease, described silicon oxide compound is 0.1～6.0% by mass percentage, described grease is 0.1～5.0% by mass percentage.
Described silicone compounds is selected from: polydimethylsiloxane, dimethiconol, and composition thereof.
Described grease is selected from: mineral oil, glyceride oil, trihydroxy methyl ester oil, fatty acid ester oil, and composition thereof.
When this spontaneous heating hair care combination was executed on wet hair, temperature can rise 5～20 ℃.
The preparation method of above-mentioned self-heating hair care composition comprises the steps:
(1) cationic surfactant, hard fat compounds of group and carrier are mixed;
(2) under 65～80 ℃, the said mixture mix and blend is carried out homogenize.
(3) under 65～80 ℃, inorganic salt particle added in (2) and get final product.
The second preparation method of above-mentioned self-heating hair care composition comprises the steps:
(1) carrier is heated to 70～80 ℃;
(2) cationic surfactant and hard fat compounds of group are added in (1), be heated to 70～80 ℃, middling speed stirs homogenize;
(3) inorganic salt particle is added the mixture of step (2) be mixed into system, the rapid stirring homogenize;
(4) be cooled to 50～60 ℃ and add silicone compounds and grease, the mixture that obtains with step (3) mixes, and is cooled to room temperature, and get final product.
Compared with prior art, the present invention has following beneficial effect:
When self-heating hair care composition of the present invention uses, when it is bestowed wet hair, can make the temperature of hair increase 5～35 ℃, and can continue 2～3 minutes, have all advantages that heat is steamed, more superior nursing efficacy can be provided.Haircare composition of the present invention can improve hair quality, makes wet sending out have good spreadability and smooth feeling, improves and does pliability, the smooth feeling of sending out and moisten degree.
The specific embodiment
Below just embodiment further explain the present invention, but embodiment does not do any restriction to the present invention.
Preparation method:
(1) carrier is heated to 75 ℃;
(2) cationic surfactant and hard fat compounds of group are added in (1), be heated to 80 ℃, stir homogenize;
(3) inorganic salt particle is added the mixture of step (2) be mixed into system, the rapid stirring homogenize;
(4) be cooled to 50 ℃ and add silicone compounds and grease, the mixture that obtains with step (3) mixes, and is cooled to room temperature, and get final product.
Table 1
| Embodiment | 1 | 2 | 3 | 4 | 5 |
| Magnesium sulfate | 40.0 | 20.0 | 15.0 | 25.0 | ? |
| Magnesium chloride | ? | ? | 15.0 | ? | 20.0 |
| Cetyl trimethyl sulfate methyl ammonium | 2.0 | ? | 2.0 | 1.5 | ? |
| The stearyl trimethyl ammonium chloride | ? | 2.0 | ? | ? | 2.0 |
| Two cetyl trimethyl oronains | 1.0 | 0.5 | 0.5 | 1.0 | 0.5 |
| Spermol | 0.9 | 1.5 | 1.2 | 1.5 | 1.2 |
| Stearyl alcohol | 2.1 | 2.5 | 2.8 | 3.0 | 2.8 |
| Propylene glycol | 54 | 69.5 | ? | 63 | 64.5 |
| Glycerol | ? | ? | 58.0 | ? | ? |
| Polydimethylsiloxane | ? | 1.0 | 2.0 | 0.5 | 2.0 |
| Encircle five polydimethylsiloxane | ? | 1.0 | 1.5 | 1.5 | 1.0 |
| Isopropyl palmitate | ? | 2.0 | ? | 1.5 | ? |
| Isopropyl myristate | ? | ? | 2.0 | ? | 3.0 |
| Mineral oil | ? | ? | ? | 1.5 | 3.0 |
Using method: during use, when it is bestowed wet hair, can make the temperature of hair increase 5～35 ℃, and can continue 2～3 minutes, have all advantages that heat is steamed, obtain more superior nursing efficacy.
Claims (6)
1. self-heating hair care composition is characterized in that said composition comprises following component by mass percentage:
Cationic surfactant 0.05～10%,
Hard fat compounds of group 0.05～15%,
Inorganic salt 0.5～40%,
Carrier 35～95%;
The structural formula of described cationic surfactant is as follows:
Wherein, R1, R2, R3, R4 are selected from the fat base that contains 1～40 carbon atom, fragrant fat, alkoxyl or alkylamidoalkyl, X
-Be alkyl sulfate ion or the chloride ion that contains 1～4 carbon atom;
Described hard fat compounds of group is one or both the mixture in aliphatic alcohol, fatty acid; Wherein, described aliphatic alcohol has 12～40 carbon atoms, and described fatty acid has 12～40 carbon atoms;
Described inorganic salt is sodium sulfate, calcium sulfate, aluminum sulfate, magnesium sulfate, calcium chloride, magnesium chloride and composition thereof;
Described carrier is propylene glycol, ethylene glycol, glycerol, tetramethylolmethane, sorbitol or its mixture.
2. self-heating hair care composition as claimed in claim 1, it is characterized in that, described cationic surfactant is single long alkyl quaternary ammonium salts, and one in its structural formula in R1, R2, R3, R4 is to be selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide; Remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom;
Described cationic surfactant is two long alkyl quaternary ammonium saltss, and two in its structural formula in R1, R2, R3, R4 is to be selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide; Remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom.
3. self-heating hair care composition as claimed in claim 2, it is characterized in that, described single long alkyl quaternary ammonium salts is one or more the mixture in cetyl trimethyl sulfate methyl ammonium, hexadecyltrimethylammonium chloride, stearyl trimethyl sulfate methyl ammonium, stearyl trimethyl ammonium chloride, docosanol trimethyl sulfate methyl ammonium, INCROQUAT TMC-80 ECONOL TM22, palmitamide oxypropyl trimethyl sulfate methyl ammonium, palmitamide oxypropyl trimethyl ammonium chloride;
described two long alkyl quaternary ammonium salts is two cetyl dimethyl sulfate ammonium methyls, two cetyl alkyl dimethyl ammonium chlorides, two stearyl dimethyl sulfate ammonium methyls, two stearyl alkyl dimethyl ammonium chlorides, two docosyl dimethyl sulfate ammonium methyls, two docosyl alkyl dimethyl ammonium chlorides, two palmitamide propyl-dimethyl sulfate methyl ammoniums and two palmitamide propyl-dimethyl ammonium chloride, two h-tallow fat base dimethyl sulfate ammonium methyls, the mixture of one or more in two h-tallow fat base alkyl dimethyl ammonium chlorides.
4. self-heating hair care composition as claimed in claim 1, is characterized in that, described hard fat compounds of group is spermol, stearyl alcohol and composition thereof.
5. self-heating hair care composition as claimed in claim 1, it is characterized in that, also add silicone compounds or grease, described silicone compounds accounts for compositions by mass percentage 0.1～6.0%, and described grease accounts for compositions by mass percentage 0.1～5.0%.
6. self-heating hair care composition as claimed in claim 5, is characterized in that, described silicone compounds is polydimethylsiloxane, dimethiconol or its mixture; Described grease is mineral oil, glyceride oil, trihydroxy methyl ester oil, fatty acid ester oil or its mixture.
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| CN 201110235718 CN102283785B (en) | 2011-08-17 | 2011-08-17 | Self-heating hair care composition |
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| CN 201110235718 CN102283785B (en) | 2011-08-17 | 2011-08-17 | Self-heating hair care composition |
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| CN102283785A CN102283785A (en) | 2011-12-21 |
| CN102283785B true CN102283785B (en) | 2013-06-19 |
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| CN104059585A (en) * | 2014-07-17 | 2014-09-24 | 李倩楠 | Ultralow-temperature-resistant resistivity-variable conductive adhesive as well as preparation and using methods thereof |
| CN104059586A (en) * | 2014-07-17 | 2014-09-24 | 李倩楠 | Resistivity-variable conductive adhesive |
| CN112190493A (en) * | 2020-10-19 | 2021-01-08 | 广州荃智美肤生物科技研究院有限公司 | Anhydrous transparent liquid head conditioning composition and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1200031A (en) * | 1995-08-29 | 1998-11-25 | 普罗克特和甘保尔公司 | High lather styling shampoos |
| WO2010089228A1 (en) * | 2009-02-05 | 2010-08-12 | Rhodia Operations | Aqueous composition suitable as shampoo |
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2011
- 2011-08-17 CN CN 201110235718 patent/CN102283785B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1200031A (en) * | 1995-08-29 | 1998-11-25 | 普罗克特和甘保尔公司 | High lather styling shampoos |
| WO2010089228A1 (en) * | 2009-02-05 | 2010-08-12 | Rhodia Operations | Aqueous composition suitable as shampoo |
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Application publication date: 20111221 Assignee: Zhaoqing Dicai Daily Chemical Science and Technology Co., Ltd. Assignor: Guangzhou Decolor Cosmetic Co., Ltd. Contract record no.: 2014440000134 Denomination of invention: Self-heating hair care composition Granted publication date: 20130619 License type: Exclusive License Record date: 20140331 |
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