JP2001220329A - Composition for formulating hair treatment preparation and hair treatment preparation - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide the subject composition capable of easily and inexpensively preparing hair treatment preparations including hair conditioners, waving preparations, finishers and thickening agent to be prepared in time of use, and to provide hair treatment preparations excellent in feeling when applied such as dampishness, slipperiness, light oily feeling, hair touch, glossiness, hair wiriness, softness and favorable combability, and also in characteristics such as resistance to damaging the hair (hair protectiveness), absorbability/ infiltrativeness/settability/spreading adherability (in) to the hair (in particular, for waving preparations), humectancy, smooth formability of uneven and firmly curling waves and antistaticity. SOLUTION: This composition for formulating hair treatment preparations is characterized by containing a cationic surfactant and a nonionic surfactant.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a composition for blending a hair treatment agent and a hair treatment agent. In particular, the present invention relates to a composition for blending a hair treatment agent for preparing a hair treatment agent, and a treatment obtained therefrom, a hair conditioner such as a rinse, a waving agent, a finishing agent, and a thickening agent prepared at the time of use. It relates to a hair treatment agent.

[0002]

2. Description of the Related Art In recent years, the aesthetic sense of hair has increased, and accordingly, the demand for hair treatment agents has also increased. Specifically, a feeling of sit, a feeling of slip, a light oily feeling,
Excellent feeling of use, such as touch, gloss, suppleness, softness, and good combability for hair, as well as difficulty in damaging hair (protective power of hair), absorption, penetration, and fixability of treatment agents to hair -A hair treatment agent having excellent hair treatment agent properties such as spreadability, wettability, smooth formation of a tightly coherent wave without spots, and antistatic properties has been more strongly demanded.

[0003] Conventionally, in order to satisfy such demands of consumers, hair conditioners containing various compounding components,
Hair treatment agents such as waving agents, finishing agents, and thickeners prepared at the time of use have been proposed.

[0004] However, in the conventional preparation of a hair treatment agent, since each compounding component is weighed, added and mixed one by one, there is a problem that the process is very complicated and time and cost are required. there were.

[0005] Further, in conventional hair treatment agents, specific components such as specific fatty acid esters, surfactants, silicones, etc. are added to the hair treatment agent in order to exhibit various hair treatment effects. .

[0006] However, these compounds are often uncommon because they have a special structure. Therefore, there is a problem that it is difficult to obtain or expensive. There is also a problem that the hair treatment effect is not sufficient.

[0007]

DISCLOSURE OF THE INVENTION The present invention relates to a composition for compounding a hair treatment agent, which can easily and inexpensively prepare a hair treatment agent such as a hair conditioner, a waving agent, a finishing agent, and a thickening agent prepared at the time of use. It has excellent usability such as feeling, slipperiness, light oiliness, feel to hair, gloss, suppleness, softness, good combability, etc., and is hard to damage the hair (protective power of hair), and a treating agent (especially wave The above-mentioned hair which is excellent in properties such as absorption, penetration, fixability, spreadability of the agent) to the hair, wettability, smooth formation of a tightly packed wave without spots, and antistatic properties. It is intended to provide a treatment agent.

[0008]

Means for Solving the Problems In order to solve the above problems, the present inventors have conducted intensive studies. As a result, if a composition containing both a cationic surfactant and a nonionic surfactant is used, excellent hair can be obtained. It has been found that a hair treatment agent having a treatment effect can be easily and inexpensively prepared, and the present invention has been completed.

That is, the present invention provides a composition for compounding a hair treatment agent, comprising a cationic surfactant and a nonionic surfactant.

According to the present invention, the cationic surfactant is di (polyoxyethylene) oleylmethylammonium chloride,
One or three compounds selected from the group consisting of lauryltrimethylammonium chloride, lauryltrimethylammonium bromide, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, cetyltrimethylammonium saccharin, and aminopropyl / ethyldimethylammonium fatty acid lanolin ethyl sulfate. Yes, nonionic surfactants are polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene castor oil, polyoxyethylene lanolin, polyoxyethylene polyoxypropylene Lanolin, lauric acid diethanolamide, polyethylene glycol monolaurate,
The composition for compounding a hair treatment agent, which is one to four compounds selected from the group consisting of polyoxyethylene glyceryl oleate, sorbitan monolaurate, and sorbitan trioleate.

According to the present invention, the cationic surfactant is di (polyoxyethylene) oleylmethylammonium chloride,
Any one of the above-mentioned compositions for compounding a hair treatment agent, which is one or two compounds selected from the group consisting of lauryltrimethylammonium chloride and cetyltrimethylammonium chloride.

In the present invention, the nonionic surfactant is one or three compounds selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene lanolin, and lauric acid diethanolamide. A composition for blending any hair treatment agent is provided.

[0013] The present invention provides a composition for blending a hair treatment agent, wherein the composition further comprises oils and fats, hydrocarbons, silicones, alkalis, acids, amphoteric surfactants, sequestering agents, polymers, esters, and antibacterial agents. And any one or more selected from the group consisting of water and water.

The fats and oils are lanolin, the hydrocarbons are liquid paraffin, the silicons are polyoxyethylene / methylpolysiloxane copolymer or methylphenyl polyethylenesiloxane, the alkali is sodium hydroxide, and the acid is One or two compounds selected from the group consisting of phosphoric acid, sodium monohydrogen phosphate, and sorbic acid; the amphoteric surfactant is lauryl dimethylamino acetate betaine; and the sequestering agent is disodium edetate. Or hydroxyethanediphosphonic acid,
The composition for blending a hair treatment agent, wherein the polymer is polyethylene glycol, the ester is polyethylene glycol distearate, and the antibacterial agent is phenoxyethanol.

According to the present invention, in the composition of the composition for compounding a hair treatment agent, the contents of the cationic surfactant and the nonionic surfactant are respectively A and B (% by weight), and A and B are represented by the following formulas: Any of the above hair treating agent compounding compositions satisfying 0.5 ≦ A ≦ 30, 0.1 ≦ B ≦ 95 and A + B ≦ 100.

In the present invention, the composition for blending a hair treatment agent is a composition for blending a hair conditioner, a composition for blending a waving agent, a composition for blending a finish, or a composition for blending a thickener prepared at the time of use. A composition for blending any hair treatment agent is provided.

The present invention provides a hair treatment composition containing any of the above compositions for compounding a hair treatment composition.

The present invention provides the above hair treatment composition, wherein the hair treatment composition is a hair conditioner, a waving agent, a finishing agent, or a thickener prepared at the time of use.

[0019]

BEST MODE FOR CARRYING OUT THE INVENTION The composition for compounding a hair treatment composition of the present invention contains a cationic surfactant. Examples of the cationic surfactant include di (polyoxyethylene) alkyl (or alkenyl) methylammonium salt, alkyl (or alkenyl) trimethylammonium salt, and fatty acid amidealkylethyldimethylammonium salt.

Specifically, as the cationic surfactant, di (polyoxyethylene) oleylmethylammonium chloride (for example, 2 to 10 moles of ethylene oxide (E
O) polymers, etc.), lauryltrimethylammonium chloride, lauryltrimethylammonium bromide, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, cetyltrimethylammonium saccharin, and lanolin ethyl sulfate
One or three compounds selected from the group consisting of ethyl dimethyl ammonium.

For example, the composition for blending the hair conditioner, the composition for blending the waving agent, and the composition for blending the finishing agent may contain di (polyoxyethylene) oleylmethylammonium chloride. The composition for compounding a waving agent may contain, for example, lauryltrimethylammonium chloride. The composition for formulating a hair conditioner and the composition for formulating a waving agent may contain, for example, cetyltrimethylammonium chloride.

The composition for compounding a hair treatment composition of the present invention contains a nonionic surfactant. Examples of the nonionic surfactant include polyoxyethylene alkyl (and / or alkenyl or aryl) ether, polyoxyethylene derivative of natural fats and oils, ethylene oxide / propylene oxide block copolymer, fatty acid alkylolamides, and polyhydric alcohol ( Glycols, sorbitans, etc.) and higher fatty acid esters (eg, mono-, di-, or triesters).

The degree of EO polymerization of polyoxyethylene is as follows:
For example, it may be 2 to 70. The degree of polymerization of PO (propylene oxide) of polyoxypropylene is, for example, 10 to 2
It may be 0.

Specifically, examples of the nonionic surfactant include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene castor oil, and polyoxyethylene lanolin. One to four compounds selected from the group consisting of polyoxyethylene polyoxypropylene lanolin, diethanolamide laurate, polyethylene glycol monolaurate, polyoxyethylene glyceryl oleate, sorbitan monolaurate, and sorbitan trioleate No.

For example, the composition for compounding a waving agent may contain polyoxyethylene lauryl ether. The composition for compounding a waving agent and the composition for mixing a thickener prepared at the time of use may contain, for example, polyoxyethylene nonylphenyl ether. The composition for formulating a hair conditioner and the composition for formulating a waving agent may contain, for example, polyoxyethylene lanolin and / or diethanolamide laurate.

Further, the hair treatment composition of the present invention may contain various additives according to the type and purpose of the hair treatment composition. For example, the composition for compounding a hair treatment agent of the present invention includes, as additives, fats and oils, hydrocarbons, silicons (compounds containing Si element), alkalis, acids, amphoteric surfactants, sequestering agents, and polymers. , Esters, antibacterial agents, and water.

Specifically, the composition for compounding a waving agent
It may contain one or three selected from the group consisting of oils and fats, hydrocarbons, alkalis, amphoteric surfactants, and polymers. The composition for blending the finish and the composition for blending the thickener prepared at the time of use may contain, for example, silicones.

The composition for formulating a hair conditioner and the composition for formulating a waving agent may contain, for example, an acid and / or a sequestering agent. For example, esters may be contained in the composition for thickener composition prepared at the time of use. For example, an antimicrobial agent may be added to the finish compounding composition. For example, water may be contained in the composition for formulating a hair conditioner, the composition for formulating a waving agent, and the composition for formulating a finish.

The fats and oils include lanolin and the like. Examples of the hydrocarbons include liquid paraffin. Examples of the silicones include a polyoxyethylene / methyl polysiloxane copolymer and methylphenyl polyethylene siloxane (for example, having a viscosity of 10 to 100 cs). Examples of the alkali include sodium hydroxide.

Examples of the acid include one or two kinds of compounds selected from the group consisting of phosphoric acid, sodium monohydrogen phosphate, and sorbic acid. Examples of the amphoteric surfactant include betaine lauryldimethylaminoacetate. Examples of the sequestering agent include disodium edetate and hydroxyethanediphosphonic acid.

Examples of the polymers include polyethylene glycol (average molecular weight is, for example, 300 to 500). As the esters, polyethylene glycol distearate (the degree of ethylene polymerization is, for example, 1
00 to 200 etc.). Examples of antibacterial agents include phenoxyethanol and the like.

In the composition of the composition for compounding a hair treatment composition of the present invention, the contents of a cationic surfactant and a nonionic surfactant are defined as A and B (% by weight), respectively, and A and B are used.
May satisfy the following expressions: 0.5 ≦ A ≦ 30, 0.1 ≦ B ≦ 95, and A + B ≦ 100.

For example, in the compositions of the hair conditioner compounding composition and the waving agent compounding composition, A and B are represented by the following formulas: 0.5 ≦ A ≦ 30, 1 ≦ B ≦ 95 and A + B ≦ 100. You may be satisfied.

In the finish compounding composition, A and B may satisfy the following formula: 5 ≦ A ≦ 30, 0.1 ≦ B ≦ 10

In the composition for thickener composition prepared at the time of use,
A and B are represented by the following formulas: 0.5 ≦ A ≦ 10, 65 ≦ B ≦ 95
And A + B ≦ 100.

In the method of preparing the composition for compounding a hair treatment agent of the present invention, for example, a compounding component such as a cationic surfactant, a nonionic surfactant, and various additives as necessary is mixed, and if necessary, Under heating, stirring is performed until complete dissolution. The heating temperature is lower than the temperature at which the mixture does not decompose, for example, lower than 95 ° C. The order of addition of the components is not particularly limited.

As another method of preparing the composition for blending a hair treatment agent of the present invention, for example, a nonionic surfactant and other various oily components (for example, oils and fats, hydrocarbons and the like) are mixed, and the mixture is heated and uniformly mixed. Dissolve. This homogeneous solution is added to heated water while stirring to form an emulsion, which is then cooled.

On the other hand, the cationic surfactant, water and the like are stirred and mixed with heating, uniformly dissolved, and then cooled. afterwards,
This homogeneous solution may be added to the cooled emulsion while stirring and uniformly mixed to prepare the emulsion. The heating temperature is preferably lower than the temperature at which the mixture does not decompose, for example, 95 ° C or lower.

The hair treatment composition of the present invention contains the above-mentioned composition for compounding a hair treatment composition of the present invention. Hereinafter, a hair conditioner, a wave agent, a finishing agent, a thickener prepared at the time of use, and the like will be described as examples of hair treatment agents.

As the hair conditioner of the present invention,
It contains the composition for blending a hair conditioner. As the composition for blending a hair conditioner, one type or two or more types may be used.

Further, the hair conditioner of the present invention may contain polymers, water and the like as additives. As the polymers, for example, a 1% aqueous solution viscosity of 500 to 500
0 cps hydroxyethyl cellulose and the like.

In the composition of the hair conditioner of the present invention, the composition for blending the hair conditioner is, for example, 5 to 5%.
30% by weight is contained.

The method for preparing the hair conditioner of the present invention is not particularly limited. For example, the composition for blending the hair conditioner is heated to obtain a homogeneous solution. On the other hand, water, polymers and the like are mixed and heated to form a uniform mixture.
The homogeneous mixture may be added to the homogeneous mixture with stirring to emulsify and then cooled to prepare.

Examples of the waving agent of the present invention include those comprising a first agent and a second agent. (In the present invention, the first waving agent alone and the second waving agent alone are also used. , Included in the hair treatment composition of the present invention).

The waving agent first agent of the present invention includes a reducing agent, an alkali agent,
It may contain water and the like. Examples of the reducing agent include thioglycolic acid and cysteine, and salts thereof (ammonium salt, MEA salt, hydrochloride, and the like). Examples of the alkaline agent include ammonia, amines (such as MEA and isopropanolamine), ammonium salts (such as ammonium bicarbonate), and basic amino acids.

In the composition of the first part of the waving agent of the present invention, the composition for blending the waving agent may contain, for example, 0.1 to 25% by weight.

The waving agent second agent of the present invention includes, in addition to the waving agent composition of the present invention, an oxidizing agent, a surfactant,
It may contain a sequestering agent, water and the like. As oxidizing agents, bromates (eg, sodium bromate), hydrogen peroxide, etc., as surfactants, lauryl trimethyl ammonium halides (lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, etc.), and as metal ion sequestering agents, , Disodium edetate, hydroxyethanediphosphonic acid and the like.

In the composition of the second agent for the waving agent of the present invention, the composition for compounding the waving agent may contain, for example, 1 to 15% by weight.

As the waving agent second agent, those usually used for the waving agent second agent can be used in place of the waving agent second agent of the present invention. Examples of such a wave agent second agent include an oxidizing agent (eg, sodium bromate) and a surfactant (lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, etc.).
Prepared by uniformly dissolving in water.

As a method for preparing the first agent of the waving agent of the present invention, for example, a composition for mixing a waving agent, which is heated and uniformly dissolved in heated water, is stirred and emulsified, and then cooled to prepare a viscous liquid. . Thereafter, a reducing agent, an alkali agent and the like may be added at room temperature, and the mixture may be uniformly stirred and mixed. In addition, the concentration of the composition for compounding a wave agent contained in the viscous liquid may be, for example, 1 to 20% by weight.

As another method for preparing the first agent for the waving agent of the present invention, for example, a composition for mixing a waving agent, a reducing agent, an alkali agent, water and the like are added, and if necessary, the mixture is stirred and mixed under heating. May be.

The second preparation of the waving agent of the present invention may be prepared by, for example, adding a composition for blending the waving agent, an oxidizing agent, water and the like, and stirring and mixing under heating if necessary.

The waving agent of the present invention uses at least one of the first waving agent of the present invention and the second waving agent of the present invention. For example, as the waving agent of the present invention, those comprising the above-mentioned waving agent first agent of the present invention and the above waving agent second agent, the above-mentioned waving agent first agent of the present invention and other waving agents other than the above And the second wave agent of the present invention other than the above.

Examples of the "first agent other than the above-mentioned wave agent" and the "second agent other than the above-mentioned wave agent" include, for example, a first agent and a second agent each usually used for a wave agent. Specifically, "the second wave agent other than the above"
Examples thereof include those prepared by uniformly dissolving an oxidizing agent and a surfactant in water.

The finish of the present invention contains a finish compounding composition and usually further contains water. In addition, alcohols, preservatives, fragrances, and the like may be appropriately added as additional components.

Examples of alcohols include ethanol and the like. Preservatives include parabens.

In the composition of the finish of the present invention, the composition for blending the finish may contain, for example, 1 to 35% by weight.

As a method for preparing the finish of the present invention, for example, a composition for blending a finish, alcohols, preservatives, fragrances, water, etc. are sequentially mixed and, if necessary, uniformly mixed by heating. May do it.

The thickener prepared at the time of use according to the present invention is added at the time of preparing a waving agent or the like, and increases the viscosity of the waving agent or the like. Such thickeners prepared at the time of use of the present invention include:
It contains a thickener composition for use at the time of use, and may further contain esters, glycols, preservatives, water and the like.

Examples of esters include fatty acid esters such as cetyl octanoate, examples of glycols include 1,3-butylene glycol, and examples of preservatives include parabens such as methylparaben.

In the composition of the thickener prepared before use according to the present invention,
The composition for thickener formulation prepared at the time of use may contain 40 to 80% by weight.

As a method for preparing the thickener prepared before use according to the present invention, for example, the composition for mixing the thickener prepared before use, esters, glycols, preservatives, etc. may be prepared by heating, if necessary, under heating. After dissolving, this may be added to water with stirring and mixed uniformly to prepare.

[0063]

EXAMPLES The present invention will be described more specifically with reference to the following examples. (Preparation of composition for compounding hair treatment agent) Examples 1, 4 to 14 The components (kg) shown in Tables 1 and 2 were mixed in a container, and the mixture was mixed in Tables 1 and 2. Heat to the indicated temperature (Examples 1, 4 to 12, and 14) or at room temperature (Example 13), stir and completely dissolve, and mix each hair treatment composition of the present invention (Example 1) , 4-14) were prepared. Tables 1 and 2 show the ingredients and the weight (k
g).

Example 2 Polyoxyethylene oleyl ether [4.43 kg
(7EO polymer) +1.1 kg (20EO polymer)],
Mix lanolin and liquid paraffin and mix
The mixture was heated to 95 ° C. to obtain a homogeneous solution. 25.59 L of water heated to 93-95 ° C.
The mixture was added with stirring and mixed. Thereafter, the mixture was cooled to 28 ° C. or lower to obtain a uniform mixture.

On the other hand, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride and water
69 kg was mixed, heated to 80 ° C., and mixed by stirring, and then cooled to 30 ° C. or lower to prepare a homogeneous solution (I).

Further, polyoxyethylene lanolin and 9.84 kg of water were mixed, heated to 80 ° C. or higher, mixed with stirring, and cooled to 30 ° C. or lower to prepare a homogeneous solution (II).

The homogeneously dissolved materials (I) and (II) were sequentially added to the homogeneous mixture with stirring. Then, sorbic acid, phosphoric acid, sodium hydroxide, and the like are added, and finally, water (refilling water) is added to adjust the total weight to 100 kg, and the mixture is uniformly mixed. Was prepared. Tables 1 and 2 show the components and the weight (kg).

Example 3 Polyoxyethylene oleyl ether [2.67 kg
(30 EO) + 1.33 kg (50 EO)] and water 1
3.33 kg was mixed and stirred at 80 ° C. to dissolve uniformly.
Then, 13.33 kg of ice was added to the homogeneous melt, and 3
Cooled to 0 ° C. Thereafter, the aqueous composition ¹⁾ 66.
67 kg, and water (rehydration) is added to make the total weight 10
The composition was adjusted to 0 kg and uniformly mixed to prepare a composition for blending a hair treatment agent of the present invention. Tables 1 and 2 show the components and the weight (kg).

1) Ingredients (kg); lauryltrimethylammonium chloride (1.48), cetyltrimethylammonium chloride (9.88), polyoxyethylene oleyl ether (7.11), lanolin (4), liquid paraffin ( 9), sodium hydroxide (0.06), phosphoric acid (0.01), sorbic acid (0.15), water (68.3)
1).

[0070]

[Table 1]

In Table 1, 1) to 14) represent the following. 1) 75% by weight, 2EO, 2) 30% by weight, 3) 70% by weight, 4) 50% by weight, 5) 4EO, 6) 23EO, 7) 2EO: 6EO =
About 1: 4, 8) 20EO, 9) 7EO: 20EO = about 4: 1, 10) 11EO, 11) 70EO, 12) 50
EO, 12PO, 13) 85% by weight, 14) 85% by weight.

[0072]

[Table 2]

In Table 2, 1) to 18) represent the following. 1) 75% by weight, 2EO, 2) 30% by weight, 3) 50% by weight, 4) 50% by weight, 5) 60% by weight, 6) 35% by weight, 7) Contains 50% by weight of dipropylene glycol, 8)
23EO, 9) 11EO, 10) 15EO, 11) 9E
O, 12) 70EO, 13) 20EO, 14) 20E
O, 15) 10EO, 16) 60% by weight, 1
7) Average molecular weight 300-500, 18) Content concentration 85% by weight.

(Preparation of Hair Conditioner) Example 15 80 kg of initial water and 2 kg of hydroxyethyl cellulose
And heated to 90 ° C. to form an aqueous solution. Then, after cooling the heated aqueous solution to 45 ° C., the composition for blending the hair conditioner (Example 10) 10 k
g was added to the cooled aqueous solution while stirring, and mixed uniformly to prepare the hair conditioner of the present invention.

(Preparation of Waving Agent) Example 16 Preparation of 10% Viscous Liquid A composition for mixing a waving agent (Example 1) was charged with 10 kg of 80 kg.
The mixture was heated to 85 ° C. and uniformly dissolved. On the other hand, the initial water 8
0 kg was heated to 83-85 ° C. The heated homogeneous solution was added to the heated initial water while stirring, followed by uniform mixing. 47-49 ° C. while stirring this homogeneous mixture
After cooling, water (supplemented water) was added to adjust the total weight to 100 kg, and the mixture was uniformly mixed to prepare a 10% viscous liquid.

Preparation of the first part of the waving agent To 25 kg of the 10% viscous liquid obtained above, 13 kg of 50% ammonium thioglycolate (ATG) and an appropriate amount of strong aqueous ammonia were added at room temperature, and water (rehydration) was further added. In addition, the total weight was adjusted to 100 kg, and the mixture was uniformly mixed to prepare a first waving agent.

Preparation of second agent for waving agent 1 kg of lauryltrimethylammonium chloride, 8 kg of sodium bromate and water were added to make a total weight of 100 kg.
As an aqueous solution of the above, a second agent for the wave agent was prepared.

Examples 17 to 27 Preparation of first agent for waving agent Composition for compounding waving agent (Examples 2 to 12), 50%
ATG, strong ammonia water, and water were stirred and mixed at room temperature to form a first waving agent (Examples 17 to 2).
7) was prepared. Tables 3 and 4 show the components and amounts (kg).

Preparation of second agent for waving agent Composition for blending waving agent (Examples 2 to 4 and 1
2), sodium bromate, and water were stirred at room temperature and uniformly mixed to form a second agent for a wave agent (Examples 17 to 2).
7) was prepared. Tables 3 and 4 show the components and amounts (kg).

[0080]

[Table 3]

[0081]

[Table 4]

(Preparation of Finishing Agent) Example 28 Composition for Finishing Agent Mixing (Example 13) 10 kg, ethanol 10 L, methyl paraben 0.1 kg, appropriate amount of fragrance, appropriate amount of fragrance dispersant, and 100 liters of total weight of finishing agent The amount of water to be added was sequentially added with stirring and uniformly mixed to prepare a finish of the present invention (Example 28).

(Preparation of Thickener Prepared Before Use) Example 29 62 kg of composition for mixing thickener prepared before use (Example 14)
Mix 4 kg of cetyl octanoate, 12 kg of 1,3-butylene glycol and 0.1 kg of methyl paraben,
Heating to 0 ° C. provided a homogeneous solution. This homogeneous solution was added to water heated to 80 ° C. while stirring, and the solution was homogeneously dissolved to prepare a thickening agent for use according to the present invention. The water is
The amount used was such that the total weight of the thickener prepared at the time of use was 100 kg.

The thickener prepared above at the time of use (Example 2)
9) 30 kg was added to 70 kg of the waving agent (Example 4) to prepare another waving agent. As a result, it was visually confirmed that the liquid waving agent became a gel. Furthermore, about this newly obtained wave agent,
The following sensory evaluation test was performed. Table 5 shows the evaluation results.

(Sensory Evaluation of Hair Treatment Effect of Hair Treatment Agent) Hair treatment was performed on 50 test subjects by the following method, and the hair treatment effect (use feeling and characteristics) of the hair treatment agent was used. I had a sensory evaluation. Table 5 shows the evaluation results.
Shown in

Hair treatment method of hair conditioner After normal shampooing, the hair conditioner (Example 1)
5) was applied to the hair, combed and allowed to spread.
Then, it was rinsed and dried in a dryer.

Hair treatment method of waving agent In case of permanent giving wave Waving agent (Examples 16 to 27) The first agent is applied to hair and combed to spread the hair.
Allowed to stand at room temperature for minutes. Next, the second agent was applied with an applicator and allowed to stand for 7 minutes, and then the second agent was applied again with an applicator and allowed to stand for 7 minutes. Thereafter, the rod was removed, rinsed and dried with a dryer.

In the case of straight perm The first waving agent (new waving agent prepared in Example 29) was applied to the hair, combed and allowed to spread, so that the hair was straightened. Then, it was left for 10 minutes. Next, the second agent was applied to the hair, combed, allowed to spread, and left for 10 minutes. Finally, it was rinsed and dryer dried.

A method for treating the hair with a finishing agent A finishing agent (Example 28) was applied to the hair and allowed to spread.

[0090]

[Table 5]

In Table 5, ◎ indicates very good, ○ indicates good, and Δ indicates normal. As is evident from the results in Table 5, the hair treatment composition of the present invention has a crisp feeling, a smooth feeling, a light oily feeling,
Excellent feeling of use, such as touch, gloss, suppleness, softness, and good combability for hair, as well as difficulty in damaging hair (protective power of hair) and absorption of treatment agents (especially waving agents) into hair. It can be seen that the hair treating agent is excellent in properties such as permeability, fixing property, spreadability, wettability, smooth formation of a wave with a firm and uniform appearance, and antistatic property.

[0092]

The composition for compounding a hair treating agent of the present invention is prepared by appropriately selecting and combining inexpensive and easily available compounding ingredients so as to exert an excellent hair treating effect. Therefore, the composition for compounding a hair treatment agent of the present invention can be easily produced at low cost. Since the hair treatment composition of the present invention is prepared from the above composition, it is inexpensive, and has a crisp feeling, a smooth feeling, a light oiliness, a feeling on hair, a gloss, a suppleness, a soft feeling, good combability, etc. Excellent feeling of use, hard to damage the hair (protective power of the hair), Absorbency, penetration, fixation, spreadability of the treatment agent (especially wave agent) to the hair, no wetness, firmness without spots It is excellent in characteristics such as smooth formation of gathered waves and prevention of static electricity generation. Also, in the manufacturing process of the hair treatment agent, a cationic surfactant, a nonionic surfactant and the like can be compounded at a time, so that the process can be greatly simplified.

Claims (10)

[Claims] 1. A composition for compounding a hair treatment agent, comprising a cationic surfactant and a nonionic surfactant. 2. The method of claim 1, wherein the cationic surfactant is di (polyoxyethylene) oleylmethylammonium chloride, lauryltrimethylammonium chloride, lauryltrimethylammonium bromide, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, cetyltrimethylammonium saccharin, and ethyl sulfate. Lanolin fatty acid is at least one compound selected from the group consisting of aminopropylethyldimethylammonium, wherein the nonionic surfactant is polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene nonylphenyl Ether, polyoxyethylene castor oil, polyoxyethylene lanolin, polyoxyethylene / polyoxypropylene lano 2. The compound according to claim 1, wherein the compound is at least one compound selected from the group consisting of lauric acid, diethanolamide laurate, polyethylene glycol monolaurate, polyoxyethylene glyceryl oleate, sorbitan monolaurate, and sorbitan trioleate. A composition for formulating a hair treatment agent. 3. The method according to claim 1, wherein the cationic surfactant is at least one compound selected from the group consisting of di (polyoxyethylene) oleylmethylammonium chloride, lauryltrimethylammonium chloride, and cetyltrimethylammonium chloride. The composition for blending a hair treatment agent according to claim 1 or 2. 4. The method according to claim 1, wherein the nonionic surfactant is at least one compound selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene lanolin, and lauric acid diethanolamide. The composition for blending a hair treatment agent according to any one of claims 1 to 3, characterized in that: 5. The composition for blending a hair treating agent, further comprising an oil or fat, a hydrocarbon, a silicon, an alkali, an acid, an amphoteric surfactant, a sequestering agent, a polymer, an ester, an antibacterial agent, and The composition according to any one of claims 1 to 4, further comprising at least one selected from the group consisting of water. 6. The oils and fats are lanolin, the hydrocarbons are liquid paraffin, the silicons are polyoxyethylene / methylpolysiloxane copolymer and / or methylphenyl polyethylenesiloxane, and the alkali is sodium hydroxide. Wherein the acid is at least one compound selected from the group consisting of phosphoric acid, sodium monohydrogen phosphate, and sorbic acid, the amphoteric surfactant is betaine lauryl dimethylaminoacetate, and the sequestering agent is edetate. The hair according to claim 5, wherein the hair is disodium and / or hydroxyethanediphosphonic acid, the polymer is polyethylene glycol, the ester is polyethylene glycol distearate, and the antibacterial agent is phenoxyethanol. A composition for blending a treatment agent. 7. In the composition of the composition for blending a hair treatment agent, A and B are represented by A and B (% by weight), respectively, where A and B are the contents of a cationic surfactant and a nonionic surfactant, respectively.
The following formula: 0.5 ≦ A ≦ 30, 0.1 ≦ B ≦ 95 and A
The composition according to any one of claims 1 to 6, wherein the composition satisfies + B 100. 8. The composition for blending a hair treatment agent is a composition for blending a hair conditioner, a composition for blending a waving agent, a composition for blending a finish, or a composition for blending a thickener prepared at the time of use. A composition for blending a hair treatment agent according to any one of claims 1 to 7. 9. A hair treatment agent comprising the composition for compounding a hair treatment agent according to claim 1. 10. A hair conditioner comprising: a hair conditioner;
The hair treatment agent according to claim 9, which is a waving agent, a finishing agent, or a thickener prepared at the time of use.