JP2001213738A - Composition for compounding hair treatment agent, and hair treatment agent - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a composition for compounding hair treatment agent which can easily and cheaply prepare a hair treatment agent such as a hair conditioner, a hair dyeing agent, a wave agent and a finishing agent, and also to provide a hair treatment agent having good performance for obtaining such as a feel of soft, a feel of damp, a feel of light oily touch, gloss, a feel of dry touch, a natural hair line (volume up), set up, smooth combing, low irritation, spread of cream, salt resistance and without stickiness. SOLUTION: This hair treatment agent is characterized by containing esters, alcohols and a nonionic surface-active agent.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a composition for blending a hair treatment agent and a hair treatment agent. In particular, the present invention relates to a composition for blending a hair treatment agent for preparing a hair treatment agent, and a treatment (including a so-called leave-on treatment) obtained therefrom, a hair conditioner such as a rinse, and a hair dye. Hair treatment agents such as hair, waving agents and finishing agents.

[0002]

2. Description of the Related Art In recent years, the aesthetic sense of hair and the demand for a hair treatment agent have been increasing, and a soft feeling, a crisp feeling, a light oily feeling, a gloss, a smooth feeling, a smooth feeling, a natural hairline (volume up or down), Set properties,
Good combability, low irritation, extension of cream, no stickiness, salt resistance of hair treatment agents, etc., are required even more strongly.

[0003] Conventionally, in order to satisfy such demands of consumers, hair conditioners containing various compounding components,
Hair treatment agents such as hair dyes, waving agents and finishing agents have been proposed.

[0004] However, in the conventional preparation of a hair treatment agent, since each compounding component is weighed, added and mixed one by one, there is a problem that the process is very complicated and time and cost are required. there were.

[0005] Further, in conventional hair treatment agents, specific components such as specific fatty acid esters, surfactants, silicones, and the like are added to the hair treatment agent in order to exert various hair treatment effects. .

[0006] However, these compounds are often uncommon because they have a special structure. Therefore, there is a problem that it is difficult to obtain or expensive. There is also a problem that the hair treatment effect is not sufficient.

[0007]

DISCLOSURE OF THE INVENTION The present invention relates to a composition for blending a hair treatment agent, which can easily and inexpensively prepare a hair treatment agent such as a hair conditioner, a hair dye, a waving agent, and a finishing agent, as well as a soft feeling and a soft feeling. Feeling, light oiliness, gloss, smoothness, smoothness, natural hairline (volume up or down), setability, good combability, low irritation, cream spread, no stickiness, no salt on hair treatment agent An object of the present invention is to provide the above hair treatment agent having excellent properties and the like.

[0008]

Means for Solving the Problems In order to solve the above-mentioned problems, the present inventors have conducted intensive studies. As a result, the use of a composition containing both an ester, an alcohol, and a nonionic surfactant is excellent. The present inventors have found that a hair treatment agent having an improved hair treatment effect can be easily and inexpensively prepared, and have completed the present invention.

That is, the present invention provides a composition for blending a hair treatment agent, which comprises an ester, an alcohol, and a nonionic surfactant.

[0010] The present invention relates to a method wherein the esters are glycerin mono-di-tristearate or oleic acid mono-stearate.
Diglyceride, lipophilic glyceryl monostearate, lipophilic glyceryl monooleate, pentaerythrit tetra-2-ethylhexanoate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl stearate, di-2-succinate One or three compounds selected from the group consisting of ethylhexyl and diisobutyl adipate, wherein the alcohols are myristyl alcohol, hexyldecanol, cetanol, oleyl alcohol, behenyl alcohol, lanolin alcohol, ethanol, benzyl alcohol, 1,
One or three compounds selected from the group consisting of 3-butylene glycol and dipropylene glycol, wherein the nonionic surfactant is polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene hydrogenated castor oil, lauric acid The composition for blending a hair treatment agent, which is one or three compounds selected from the group consisting of diethanolamide, coconut oil fatty acid diethanolamide, and dimethylstearylamine.

[0011] The present invention provides the composition for compounding a hair treatment agent according to any one of the above, wherein the ester is isopropyl myristate.

[0012] The present invention provides the composition for blending a hair treatment composition according to any of the above, wherein the alcohol is cetanol.

[0013] The present invention provides the composition for blending a hair treatment agent according to any of the above, wherein the nonionic surfactant is polyoxyethylene cetyl ether.

According to the present invention, the composition for blending a hair treating agent further comprises a hardened oil (hydrogenated palm oil fatty acid triglyceride, hydrogenated tallow fatty acid triglyceride, etc.), mink oil, olive oil, castor oil, shea butter, sodium cetyl sulfate. , Sodium palmitoylmethyltaurate, sodium tetradecenesulfonate, sodium polyoxyethylene oleyl ether phosphate, N-coconut fatty acid acyl-L-glutamate triethanolamine, α-olefin oligomer,
Squalane, microcrystalline wax, liquid paraffin, ceresin, candelilla wax, beeswax, N-
[3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine hydrochloride, polyglyceryl diisostearate, lactic acid, methylpolysiloxane, dimethylaminopropylamide stearate, and purified water The composition for compounding a hair treatment agent according to any one of the above, comprising one to five compounds.

According to the present invention, in the composition of the composition for compounding a hair treatment agent, the contents of the esters, alcohols, and nonionic surfactants are respectively A, B, and C (% by weight).
A to C are represented by the following formula: 3 ≦ A ≦ 35, 5 ≦ B ≦ 7
The composition for blending a hair treatment agent according to any one of the above, which satisfies 0, 1 ≦ C ≦ 40, and A + B + C ≦ 100.

The present invention relates to a composition for blending a hair treatment agent, a composition for blending a hair conditioner, a composition for blending a hair dye,
The composition for blending a hair treatment agent according to any one of the above, which is a composition for blending a waving agent or a composition for blending a finishing agent.

The present invention provides a hair treatment composition containing any one of the compositions for blending a hair treatment composition described above.

The present invention provides the above-mentioned hair treatment agent, wherein the hair treatment agent is a hair conditioner, a hair dye, a waving agent, or a finishing agent.

[0019]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The composition for mixing a hair treatment agent of the present invention contains esters. Examples of the esters include fatty acid esters, higher fatty acid esters, and polybasic acid esters of polyhydric alcohols (for example, glycerin and pentaerythritol).

Specifically, glycerin fatty acid esters (for example, glycerin mono-di-tristearate mixture, mono-diglyceride mixture of stearic acid / oleic acid mixed acid, etc.), lipophilic glyceryl monostearate,
From the group consisting of lipophilic glyceryl monooleate, pentaerythrit tetra-2-ethylhexanoate, isopropyl myristate, myristyl myristate, isopropyl palmitate, butyl stearate, di-2-ethylhexyl succinate, and diisobutyl adipate One to three kinds of selected compounds can be mentioned.

For example, the composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a waving agent may contain isopropyl myristate.

The composition for blending a hair treatment composition of the present invention contains alcohols. Examples of the alcohols include lower / higher alcohols, aromatic alcohols, polyhydric alcohols, and the like.

Specifically, myristyl alcohol, hexyldecanol, cetanol, oleyl alcohol, behenyl alcohol, lanolin alcohol, ethanol,
One to three compounds selected from the group consisting of benzyl alcohol, 1,3-butylene glycol, and dipropylene glycol.

For example, the composition for blending a hair dye and the composition for blending a waving agent may contain cetanol.

The composition for blending a hair treatment composition of the present invention contains a nonionic surfactant. Examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene derivatives of natural fats and oils, fatty acid alkylolamides, and higher aliphatic tertiary amines. The degree of EO (ethylene oxide) polymerization of polyoxyethylene may be, for example, 3 to 65.

Specifically, one kind selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene hydrogenated castor oil, lauric acid diethanolamide, coconut oil fatty acid diethanolamide, and dimethyl stearylamine Or three kinds of compounds.

For example, the composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, and the composition for blending a finish may contain polyoxyethylene cetyl ether.

Further, various additives may be appropriately added to the composition for compounding a hair treatment agent of the present invention according to the type and purpose of the hair treatment agent. For example, the composition for compounding a hair treatment agent of the present invention includes, as additives, fats and oils, anionic surfactants, hydrocarbons, waxes, amphoteric surfactants, polyglycerin derivatives, organic acids, silicones, and fatty acid amino acids. It may contain alkylamides, water and the like.

Specifically, hydrogenated oils (hydrogenated palm oil fatty acid triglyceride, hydrogenated tallow fatty acid triglyceride, etc.),
Mink oil, olive oil, castor oil, shea butter, sodium cetyl sulfate, sodium palmitoyl methyl taurate, sodium tetradecene sulfonate, sodium polyoxyethylene oleyl ether phosphate, N-coconut oil fatty acid acyl-L-glutamate triethanolamine, α-
Olefin oligomer, squalane, microcrystalline wax, liquid paraffin, ceresin, candelilla wax, beeswax, N- [3-alkyl (12,14)
Oxy-2-hydroxypropyl] -L-arginine hydrochloride (where “alkyl (12,14)” is C12-C
14 alkyl. ), Polyglyceryl diisostearate, lactic acid, methylpolysiloxane, dimethylaminopropylamide stearate, and purified water may be contained.

For example, the composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a waving agent may contain fats and oils and / or an anionic surfactant. The composition for formulating a hair conditioner and the composition for formulating a finish may contain, for example, hydrocarbons.

The composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a finish may contain, for example, waxes. The composition for formulating a hair conditioner may contain, for example, an amphoteric surfactant, a polyglycerin derivative, lactic acid, and a fatty acid aminoalkylamide. The composition for hair coloring composition and the composition for waving composition may contain, for example, silicones. The hair dye composition may contain, for example, water.

In the composition of the composition for compounding a hair treatment composition of the present invention, the contents of esters, alcohols and nonionic surfactants are defined as A, B and C (% by weight), respectively. Has the following formula: 3 ≦ A ≦ 35, 5 ≦ B ≦ 70,
It is preferable to satisfy 1 ≦ C ≦ 40 and A + B + C ≦ 100.

For example, in the composition of the hair conditioner compounding composition, 3 ≦ A ≦ 35, 5 ≦ B ≦ 45,5
≦ C ≦ 40 and A + B + C ≦ 100.

In the composition of the hair dye composition,
≦ A ≦ 15, 50 ≦ B ≦ 70, 3 ≦ C ≦ 25, and A
+ B + C ≦ 100.

In the composition of the composition for compounding a wave agent, 10 ≦ A ≦ 20, 50 ≦ B ≦ 65, 1 ≦ C ≦ 25,
And A + B + C ≦ 100.

In the composition of the composition for blending the finishing agent,
20 ≦ A ≦ 30, 5 ≦ B ≦ 15, 30 ≦ C ≦ 45, and A + B + C ≦ 100.

In the method of preparing the composition for compounding a hair treatment composition of the present invention, for example, ingredients such as esters, alcohols, nonionic surfactants, and various additives as necessary are mixed and heated. Stirring until complete dissolution. The heating temperature is lower than the temperature at which the mixture does not decompose, for example, lower than 95 ° C. The order of addition of the respective components is not particularly limited.

[0038] The hair treatment composition of the present invention contains the composition for compounding a hair treatment composition of the present invention. Hereinafter, a hair conditioner, a hair dye, a waving agent, a finishing agent, and the like will be described as examples of hair treatment agents.

The hair conditioner of the present invention contains the above-mentioned composition for blending a hair conditioner. As the composition for blending a hair conditioner, one type or two or more types may be used.

Further, the hair conditioner of the present invention may contain water as an additive, an additive composition, a preservative, a fragrance, a pigment, an anionic surfactant, an alcohol, an organic acid, an amino acid, a higher fatty acid, a wax, and a silicone. , Esters, alkaline agents, polymers, fats and oils and the like.

Examples of the additive composition include esters,
Mixtures of oils and fats, silicones and the like can be mentioned. Preservatives include parabens such as methylparaben and propylparaben. As the fragrance, those commonly used in hair conditioners may be used. As a dye,
And tar dyes. Examples of the anionic surfactant include amino acid surfactants.

Examples of the alcohols include aromatic alcohols (such as phenoxyethanol), higher alcohols (such as stearyl alcohol), and glycols (such as polyethylene glycol). Examples of the organic acid include glycolic acid, lactic acid, and citric acid; examples of the amino acid include glutamic acid; and examples of the higher fatty acid include stearic acid and hydroxystearic acid. Examples of waxes include candelilla wax.

Examples of the silicon include dimethylpolysiloxane. Esters include fatty acid esters, polybasic acid esters, oligoesters and the like. Specifically, examples of the esters include N-acylglutamic acid ester, isopropyl palmitate, dioctyl succinate, and polypropylene glycol oligoester succinate.

Examples of the alkali agent include an organic alkali agent (eg, triethanolamine (TEA)) and an inorganic alkali agent (eg, sodium hydroxide). Examples of the polymer include polyethylene glycol having a molecular weight of 1,000,000 to 4,000,000, and polyvinylpyrrolidone (PVP) -vinyl acetate (VA) copolymer having a molecular weight of 1,000,000 to 3,000,000. Examples of fats and oils include hardened oils and the like.

In the composition of the hair conditioner of the present invention, the composition for blending the hair conditioner is, for example, 3 to
65% by weight is contained.

The method for preparing the hair conditioner of the present invention is not particularly limited. For example, an organic acid, an alkali agent and the like are added to water as necessary and heated. On the other hand, if necessary, an additive composition, a preservative, an anionic surfactant, an alcohol, an organic acid, a wax, a silicon, an ester, and the like are added to the composition for blending a hair conditioner, and the composition is heated and uniformly dissolved.

The resulting solution may be added to the heated water (or aqueous solution) while stirring to emulsify the mixture, and then cooled, followed by adding a fragrance, a dye and the like, if necessary. The heating temperature of water and the composition for mixing hair conditioner is preferably a temperature at which the components are not decomposed, for example, 95 ° C or lower.

As another method for preparing the hair conditioner of the present invention, for example, silicones, fats and oils, esters and the like are added to the composition for blending the hair conditioner with heating, if necessary, and the mixture is stirred and mixed so as to be uniformly dissolved. Later, add water,
It may be emulsified.

The hair dye of the present invention includes an oxidative hair dye. The oxidative hair dye comprises a first agent and a second agent (in the present invention, the oxidative hair dye first agent alone and the oxidative hair dye second agent alone also include the hair dye of the present invention). include.). The oxidative hair dye first agent of the present invention contains, in addition to the hair dye composition of the present invention, a dye intermediate, an antioxidant, an alkali agent, a sequestering agent, alcohols, a solvent, and water. May be contained.

Examples of dye intermediates include phenylenediamines (such as ortho-meta-para-phenylenediamine), phenols (such as ortho-meta-para-aminophenol and nitrophenol), and aminocresols. Examples of the antioxidant include those commonly used in oxidative hair dyes, such as sodium sulfite, ammonium thioglycolate, ascorbic acid, and cysteine.

Examples of the alkaline agent include monoethanolamine (MEA), ammonia and the like. Examples of the sequestering agent include edetate, hydroxyethanediphosphonic acid and the like. Cetanol is mentioned as alcohols. Examples of the solvent include N-methylpyrrolidone (NMP).

In the composition of the first part of the oxidative hair dye, the composition for compounding the hair dye is, for example, 10 to 35% by weight, preferably 2 to 35% by weight.
You may contain 0-30 weight%.

As a method for preparing the first oxidative hair dye, for example, a dye intermediate, an antioxidant, a sequestering agent, and the like are added to heated water to form an aqueous solution, which is then heated and uniformly dissolved. The composition may be added and mixed, and after cooling, the mixture may be added with an additive such as an alkali agent with stirring. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

The oxidative hair dye second agent of the present invention may contain a sequestering agent, a pH adjuster, an oxidizing agent, water and the like in addition to the composition of the present invention. Examples of the sequestering agent include hydroxyethanediphosphonic acid. Examples of the pH adjuster include a phosphate (eg, sodium monohydrogen phosphate) and the like. Examples of the oxidizing agent include hydrogen peroxide.

In the composition of the oxidative hair dye second agent, the composition for compounding the hair dye is, for example, 1 to 15% by weight, preferably 2 to 15% by weight.
It may contain 10% by weight.

As a method for preparing the oxidative hair dye second agent, for example, a hair dye composition for heating and uniformly dissolved is added to heated water, stirred and emulsified, cooled with stirring, and then sequestered with metal ions. It may be carried out by adding additives such as an agent, a pH adjuster, and an oxidizing agent. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

The oxidative hair dye of the present invention uses at least one of the first oxidative hair dye of the present invention and the second oxidative hair dye of the present invention. For example, the oxidative hair dye of the present invention includes the oxidative hair dye first agent of the present invention and the oxidative hair dye second agent of the present invention, and the oxidative hair dye first agent of the present invention. And an oxidized hair dye second agent other than the above, and an oxidized hair dye second agent other than the above and an oxidized hair dye second agent of the present invention.

Examples of the “first agent for oxidative hair dyes other than those described above” and the “second agent for oxidative hair dyes other than those described above” include, for example, the first agent and the second agent each of which are generally used for hair dyes. No.

Another hair dye of the present invention includes an acidic hair dye. Acidic hair dyes, besides the hair dye composition of the present invention, waxes, preservatives, gums, pigments, organic solvents,
It may contain ethers, organic / inorganic acids and salts thereof (ammonium salts and the like), flavors, water and the like.

Examples of the waxes, preservatives, pigments, organic acids, fragrances and the like include those exemplified in the composition for blending a hair conditioner. Examples of the gum include xanthan gum and the like. Examples of the organic solvent include benzyl alcohol and the like. Examples of ethers include diethylene glycol monoethyl ether. Examples of the inorganic acid include phosphoric acid.

In the composition of the acidic hair dye, the composition for blending the hair dye is, for example, 10 to 30% by weight, preferably 10 to 2% by weight.
It may contain 0% by weight.

As a method for preparing an acidic hair dye, for example, a composition for mixing a hair dye, a wax, a preservative, and the like are mixed, and the mixture is heated and uniformly dissolved. Next, the homogeneous solution is added to heated water containing gum and tar pigment, and the mixture is stirred and emulsified. Then, after cooling, the organic solvent and organic
The reaction may be performed by adding an inorganic acid or a salt thereof. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

Another hair coloring agent of the present invention includes a hair bleaching agent. Hair bleaching agents usually consist of a first agent and a second agent. The hair bleaching agent first agent includes, for example, the oxidative hair dye first agent which does not contain a dye intermediate. The composition and preparation method of the composition for blending a hair dye in the first part of the hair bleaching agent may be the same as that of the first part of the oxidative hair dye. As the hair bleaching agent second agent, an oxidative hair dye second agent can be used.

Examples of the waving agent of the present invention include those comprising a first agent and a second agent (in the present invention, the first waving agent alone and the second waving agent alone are also used. , Included in the wave agent of the present invention).

The waving agent first agent of the present invention includes, in addition to the waving agent blending composition of the present invention, a reducing agent, an alkali agent,
It may contain water and the like. Examples of the reducing agent include thioglycolic acid and cysteine, and salts thereof (ammonium salt, MEA salt, hydrochloride, and the like). Examples of the alkaline agent include ammonia, amines (such as MEA and isopropanolamine), ammonium salts (such as ammonium bicarbonate), and basic amino acids.

In the composition of the first waving agent of the present invention, the composition for blending the waving agent is, for example, 5 to 25% by weight,
Preferably, it may be contained in an amount of 5 to 20% by weight.

As a method for preparing the first agent of the waving agent of the present invention, for example, a composition for mixing a waving agent, which is heated and uniformly dissolved in heated water, is emulsified with stirring, cooled, and then stirred with a reducing agent and an alkali. It may be performed by adding an agent or the like. The heating temperature of the composition for mixing water and the waving agent is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

The second agent for the waving agent of the present invention includes, in addition to the composition for compounding the waving agent of the present invention, an oxidizing agent, a surfactant,
It may contain an organic / inorganic acid, a sequestering agent, water and the like. As oxidizing agents, bromates, hydrogen peroxide, etc., as surfactants, lauryl trimethyl ammonium halides (lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, etc.), as organic acids, citric acid, tartaric acid, etc., as inorganic acids, Examples include phosphoric acid and sodium monohydrogen phosphate, and examples of sequestering agents include hydroxyethanediphosphonic acid.

In the composition of the second waving agent of the present invention, the waving agent blending composition may contain, for example, 5 to 25% by weight.

As a method for preparing the second agent for the waving agent of the present invention, for example, a composition for blending a waving agent, which is heated and uniformly dissolved in heated water, is stirred and emulsified. It may be performed by adding an activator or the like. The heating temperature of the composition for mixing water and the waving agent is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

The waving agent of the present invention uses at least one of the first waving agent of the present invention and the second waving agent of the present invention. For example, as the waving agent of the present invention, those comprising the above-mentioned waving agent first agent of the present invention and the above waving agent second agent, the above-mentioned waving agent first agent of the present invention and other waving agents other than the above And the second wave agent of the present invention other than the above.

Examples of the "first agent other than the above-mentioned wave agent" and the "second agent other than the above-mentioned wave agent" include, for example, the first agent and the second agent each usually used for a wave agent. Specifically, "the second wave agent other than the above"
Examples thereof include those prepared by uniformly dissolving an oxidizing agent and a surfactant in water.

The finish of the present invention contains a finish blending composition and usually further contains water. In addition, alcohols, silicones, esters, waxes, fatty acids, preservatives, polymers, alkalis, additive compositions, and other additives exemplified in hair conditioners and the like are appropriately added as additional components. You may.

The alcohols include stearyl alcohol and the like. For silicons, 50 to 15
And 0 cs dimethylpolysiloxane. Examples of the esters include pentaerythritol tetra-2-ethylhexanoate. Examples of waxes include candelilla wax. Fatty acids include stearic acid and the like.

The preservatives include parabens. Examples of the polymer include polyethylene glycol having a molecular weight of 1,000,000 to 4,000,000. Examples of the alkaline agent include triethanolamine. Examples of the additive composition include solvents, glycols, and mixtures of amphoteric surfactants.

In the composition of the finish of the present invention, the composition for blending the finish may contain, for example, 1 to 35% by weight.

As a method for preparing the finishing agent of the present invention, for example, a polymer, an alkali agent and the like are dissolved in water and heated. on the other hand,
Alcohols, silicones, esters, waxes, fatty acids, preservatives, and the like are added to the finish compounding composition, and the mixture is stirred and uniformly dissolved while heating.

Next, this homogeneous solution is added to the heated aqueous alkali solution with stirring to emulsify. Next, an additive composition or the like is added to the emulsion and dispersed. After cooling the obtained homogeneous dispersion, a perfume or the like may be added as necessary. The heating temperature of the composition for water and finish compounding is
A temperature at which the components are not decomposed, for example, 95 ° C. or lower is preferable.

[0079]

EXAMPLES The present invention will be described more specifically with reference to the following examples. (Preparation of Hair Treatment Agent Composition) Examples 1 to 12 The components (kg) in the amounts shown in Tables 1 and 2 were placed in a container and mixed, and the mixture was heated at the temperatures shown in Tables 1 and 2. , And completely dissolved by stirring to prepare compositions for blending each hair treatment agent of the present invention (Examples 1 to 11).

[0080]

[Table 1]

[0081]

[Table 2]

Tables 1 and 2 in Tables 1 and 2 show the following. 1) glyceryl mono-di-tristearate, 2) mono-diglyceride oleate, 3) 7E0,
4) 23EO, 5) 5.5EO + 10EO (weight ratio 1:
2 mixture, 6) 5.5 EO + 30 EO + 40 EO (1: 1: 1 mixture by weight), 7) 40 EO, 8) 5 EO + 4
0EO (5:15 weight ratio mixture) 9) 13EO, 10)
60EO, 11) 25EO, 12) 60% by weight of solid content +
20% by weight of ethanol + 20% by weight of water; 13) 70% by weight of water.

(Preparation of Hair Conditioner) Examples 13 and 14 Initially purified water was heated to 80 to 85 ° C. On the other hand, the composition for hair conditioner formulation (Example 1), the additive composition, and the amino acid-based anionic surfactant obtained above were mixed, and the mixture was heated to 80 to 85 ° C and uniformly dissolved.

This homogeneous solution is added to the heated initial purified water while stirring to emulsify the mixture. The emulsion is cooled to 50 ° C. while stirring, a fragrance is added, and the purified water (refilled water) is further added. In addition, the total weight was adjusted to 100 kg and uniformly mixed to prepare each hair conditioner of the present invention (Examples 13 and 14). Table 3 shows the components and amounts (kg).

Example 15 Initially purified water was heated to 80 to 85 ° C. On the other hand, the composition for blending a hair conditioner obtained above (Example 1), phenoxyethanol, and N-acylglutamic acid ester were mixed, and heated to 80 to 85 ° C to be uniformly dissolved. The homogeneous solution was added to the heated purified water with stirring to emulsify, and then the emulsion was cooled to 50 ° C. while stirring.

Thereafter, a fragrance was added, purified water (refilled water) was further added to adjust the total weight to 100 kg, and the mixture was uniformly mixed to prepare a hair conditioner of the present invention. Table 3 shows the components and amounts (kg).

Examples 16 and 17 Initially purified water, glycolic acid and glutamic acid were mixed and heated to 80 to 85 ° C. to form an aqueous solution. On the other hand, the composition for hair conditioner formulation (Example 2) obtained above was heated to 80 to 85 ° C. and uniformly dissolved.

This homogeneous solution was added to the heated aqueous solution with stirring to emulsify, and then the emulsion was cooled to 38 ° C. with stirring. Thereafter, a preservative and a fragrance were added, and purified water (supplemented water) was further added to adjust the total weight to 100 kg and uniformly mixed to prepare a hair conditioner of the present invention. Table 3 shows the components and amounts (k
g).

Example 18 Initially purified water was heated to 85 to 90 ° C. On the other hand, the composition for hair conditioner blending (Example 3) obtained above and lactic acid were mixed, and the mixture was heated to 85 to 90 ° C. and uniformly dissolved. The homogeneous solution was added to the heated aqueous solution with stirring to emulsify, and then the emulsion was cooled to 50 ° C. with stirring. After that, a fragrance was added, and purified water (refilled water) was further added, so that the total weight was 100 kg.
And the resulting mixture was uniformly mixed to prepare a hair conditioner of the present invention. Table 3 shows the components and amounts (k
g).

Examples 19 and 20 Initially purified water and TEA were mixed and heated to 85 to 90 ° C. to form an aqueous solution. On the other hand, the composition for blending the hair conditioner obtained above (Example 6), stearyl alcohol, candelilla wax, dimethylpolysiloxane, isopropyl palmitate, dioctyl succinate,
Mix stearic acid, preservative, etc., and mix
The mixture was heated to 0 ° C. and uniformly dissolved.

This homogeneous solution was added to the heated aqueous solution with stirring to emulsify, and then the emulsion was cooled to 70 ° C. with stirring, and a PVP-VA copolymer was added and uniformly stirred and mixed. Thereafter, the mixture was further cooled to 50 ° C. while stirring, and a fragrance and, if necessary, polyethylene glycol were added.
The mixture was adjusted to 0 kg and uniformly mixed to prepare a hair conditioner of the present invention (keeping treatment applied). Table 3 shows the components and amounts (kg).

Example 21 Initially purified water and sodium hydroxide were mixed and mixed with 80
Heated to ９０90 ° C. to form an aqueous solution. On the other hand, the composition for compounding the hair conditioner obtained above (Example 6),
Dioctyl succinate, polyethylene glycol, and hydroxystearic acid were mixed, and the mixture was heated to 85 to 90 ° C. to be uniformly dissolved. This homogeneous solution was added to the heated aqueous solution with stirring to emulsify, and then the emulsion was cooled to 50 to 60 ° C. with stirring.

Thereafter, PVP-VA, citric acid, a dye,
A fragrance and the like were added, and purified water (supplemented water) was further added to adjust the total weight to 100 kg, followed by uniform mixing to prepare a hair conditioner (keeping on treatment) of the present invention. Table 3 shows the components and amounts (kg).

Example 22 A composition for blending a hair conditioner (Example 6), dimethylpolysiloxane, hardened oil, and polypropylene glycol oligoester succinate were mixed, and this mixture was mixed with a mixture of 85 to 85%.
The mixture was heated to 90 ° C. and uniformly dissolved. Thereafter, 12.5 kg of purified water was added to this dissolved product with stirring to prepare a hair conditioner (keeping on treatment) of the present invention as an emulsion having a total weight of 100 kg. Table 3 shows the components and amounts (kg).

[0095]

[Table 3]

In Table 3, 1) to 10) represent the following. 1) 70% concentration. 2) 50% ethanol solution.

3) Ingredients (% by weight): dipentaerythritol fatty acid ester [full of dipentaerythritol and mixed fatty acid (12-hydroxystearic acid: stearic acid: rosin = 4: 1.5: 0.5)] ester]
(50), coconut oil fatty acid triglyceride (30), isopropyl palmitate (10), diisobutyl adipate (10).

4) Ingredient (% by weight): dimethylsiloxane / methylstearoxysiloxane copolymer (5
0), diisopropyl adipate (25), diisobutyl adipate (25).

5) Trade name CAE (manufactured by Ajinomoto Co.). 6) Parabens. 7) Molecular weight 2 million. 8) 100 cs. 9) 20cs. 10) 50cs.

(Preparation of Oxidative Hair Dye) Examples 23 and 24 Preparation of First Agent Dye intermediates (resorcin, p-phenylenediamine, m-aminophenol, And a mixture of p-aminophenol), an antioxidant, and, if necessary, an edetate salt and NMP, and stirred to obtain an aqueous solution.

On the other hand, the hair dye composition (Example 10 or 9) was uniformly dissolved at 80 to 85 ° C., and this was added to the heated aqueous solution, followed by stirring and emulsification. After cooling the emulsion to 45 to 55 ° C. while stirring, if necessary, MEA,
Add edetate, 60% hydroxyethanediphosphonic acid, etc., and further add purified water (supplemented water) to a total weight of 100 kg.
To prepare the first agent. Table 4 shows the components and the amount (kg) of each component.

Preparation of Second Agent The hair dye composition (Example 11 or 9) was mixed with 80-85.
At 80 ° C., and added to initial purified water heated to 80 to 85 ° C., followed by stirring and emulsification. The emulsion was then cooled to 45 ° C. with stirring and 60% hydroxyethanediphosphonic acid and sodium monohydrogen phosphate (12%).
Hydrate) and a 35% by weight aqueous hydrogen peroxide solution,
Finally, purified water (replacement water) was added to adjust the total weight to 100 kg to prepare a second agent. Table 4 shows the components and the amount (kg) of each component.

[0103]

[Table 4]

In Table 4, 1) represents 50% ammonium thioglycolate.

(Preparation of Acid Hair Dye) Example 25 15 kg of a hair dye composition (Example 12), 3 kg of candelilla wax and 0.1 kg of parabens were mixed,
This mixture was heated to 80 to 85 ° C. to be uniformly dissolved.
On the other hand, 50 kg of a 1% aqueous solution of xanthan gum and tar dye (0.3 kg of black # 401 + 0.3 kg of purple # 401)
+ Orange No. 205 (0.6 kg) was heated to 80 to 85 ° C to form an aqueous solution. The homogeneous solution was added to the heated aqueous solution with stirring to emulsify.

After cooling this emulsion to 40 ° C., 5 kg of benzyl alcohol, 2.5 kg of diethylene glycol monoethyl ether, 1 kg of phosphoric acid, 2 kg of 70% glycolic acid aqueous solution, and 5 kg of 40% ammonium glycolate
And purified water (supplemented water) is added to make the total weight 100
The weight of the hair was adjusted so that the weight of the hair was adjusted to kg.

(Preparation of a waving agent) Example 26 Preparation of a first agent A composition for mixing a waving agent (Example 26) was heated at 80 to 85 ° C.
The mixture was uniformly dissolved by heating in water, and this was added to the initial purified water heated to 80 to 85 ° C. and emulsified with stirring. 45 ° C
The mixture was cooled to 50%, 50% ammonium thioglycolate, strong aqueous ammonia and ammonium bicarbonate were added, and purified water (replacement water) was added to adjust the total weight to 100 kg, thereby preparing a first agent. Table 5 shows the components and amounts (kg).

Preparation of Second Agent A second agent was prepared by adding purified water to lauryltrimethylammonium methyl chloride and sodium bromate to obtain an aqueous solution having a total weight of 100 kg. Table 5 shows the components and amounts (kg).

Example 27 Preparation of First Agent Same as Example 26 except that Example 10 (15% by weight) was used instead of Example 7 (10% by weight) as a composition for mixing a waving agent. To prepare a first agent. Table 5
Table 2 shows the components and the amount (kg).

Preparation of Second Agent The composition for compounding the waving agent (Example 10) was heated at 80 to 85 ° C.
The mixture was heated until homogeneously dissolved, added to initial purified water heated to 80 to 85 ° C., and stirred and emulsified. 45 of this emulsion
After cooling to ℃, sodium bromate was added, and purified water (supplemented water) was further added to adjust the total weight to 100 kg, thereby preparing a second agent. Table 5 shows the components and amounts (kg).

[0111]

[Table 5]

(Preparation of Finishing Agent) Example 28 40 kg of initial purified water, 0.2 kg of highly polymerized polyethylene glycol (molecular weight: 2,000,000), and 1.1 kg of TEA
And heated to 85-90 ° C. to form an aqueous solution. On the other hand, the finish compounding composition (Example 5) 20 k
g, stearyl alcohol 5 kg, dimethyl polysiloxane (100 cs) 5 kg, tetra-2-ethylhexanoic acid pentaerythritol 8 kg, candelilla wax 5 k
g, 4 kg of stearic acid, and an appropriate amount of parabens were mixed, and the mixture was heated to 85 to 90 ° C. to be uniformly dissolved.

The homogeneous solution was added to the heated aqueous solution with stirring to emulsify the solution. Thereafter, the emulsion is cooled to 80 ° C. while stirring, and 3 kg of an additive composition ¹⁾ is added and uniformly stirred and mixed. After further cooling to 45 ° C. while stirring, a fragrance is added, and purified water (refilled water) Was added to adjust the total weight to 100 kg, followed by uniform mixing to prepare the finish compounding composition of the present invention.

1) Components (% by weight): polyvinylpyrrolidone (1.3), dipropylene glycol (12.
5), government-designated denatured alcohol (5), N-methacryloyloxyethyl N, N-dimethylammonium-α-
N-methylcarboxybetaine / alkyl methacrylate copolymer (50), purified water (31.2).

(Sensory Evaluation on Hair Treatment Effect of Hair Treatment Agent) Fifty test subjects were subjected to hair treatment according to the following method, and sensory evaluation was performed on the hair treatment effect (feeling of use) of the hair treatment agent. I was asked to. Table 6 shows the evaluation results.

Hair treatment method of hair conditioner After normal shampooing, a hair conditioner (Examples 13 to 18) was applied to the hair, combed, and allowed to spread. Then, it was rinsed and dried in a dryer.

In the case of leave-on treatment The leave-on treatment (Examples 19 to 22) was used to treat the hair in the same manner as the hair treatment method for the finishing agent described below.

Hair treatment method of hair dye The first and second agents of the hair dye (Examples 23 and 24) were mixed at a ratio of 1: 1 (weight ratio) and applied to the hair. . Then, after leaving at room temperature for 30 minutes, it was rinsed and dried with a dryer.

When Acid Hair Dye is Used The hair was coated with the amount of acid hair dye (Example 25), heated at 45 ° C. for 15 minutes, rinsed and dried with a dryer.

A method for treating hair with a waving agent

In the case of a permanent that gives a wave: A wave agent (Example 26) was applied to the hair, combed and allowed to spread, the hair was wound around a rod, and allowed to stand at room temperature for 7 minutes. Next, the second agent was applied with an applicator and allowed to stand for 7 minutes, and then the second agent was applied again with an applicator and allowed to stand for 7 minutes. Then remove the rod, rinse,
Dryer was dried.

In the case of straight perm: The wave agent (Example 27) was applied to the hair, combed and allowed to spread, so that the hair was straightened. Then, it was left for 10 minutes. Next, the second agent was applied to the hair, combed, allowed to spread, and left for 10 minutes. Finally, it was rinsed and dryer dried.

Hair treatment method of finishing agent A finishing agent (Example 28) was applied to hair and allowed to spread.

[0124]

[Table 6]

In Table 6, ◎ indicates very good, ○ indicates good, and Δ indicates normal. As is clear from the results in Table 6, the hair treatment composition of the present invention has a soft feeling, a firm feeling, a light oily feeling,
It can be seen that it has excellent gloss, smooth feeling, smooth feeling, natural hairline (volume up), setting properties, good combability, low irritation, cream spreading, no stickiness, salt resistance and the like.

[0126]

The composition for compounding a hair treating agent of the present invention is prepared by appropriately selecting and combining inexpensive and easily available compounding ingredients so as to exert an excellent hair treating effect. Therefore, the composition for compounding a hair treatment agent of the present invention can be easily produced at low cost. Since the hair treatment composition of the present invention is prepared from the above composition, it is inexpensive, and has a soft feeling, a crisp feeling, a light oily feeling, a gloss, a smooth feeling, a smooth feeling, a natural hairline (volume up), a set. It has a hair treatment effect with excellent properties, good combability, low irritation, cream spreading, no stickiness, salt resistance and the like. Also, in the manufacturing process of the hair treatment agent,
Esters, alcohols, nonionic surfactants, fatty acids, and the like can be compounded at once, and the process can be greatly simplified.

Claims (10)

[Claims] 1. A composition for blending a hair treatment agent, which comprises an ester, an alcohol, and a nonionic surfactant. 2. The ester is glyceryl mono-di-tristearate, mono-diglyceride stearate oleate, lipophilic glyceryl monostearate, lipophilic glyceryl monooleate, pentaerythrit tetra-2-ethylhexanoate. Isopropyl myristate, myristyl myristate, isopropyl palmitate, butyl stearate, di-2-ethylhexyl succinate, and diisobutyl adipate, wherein the alcohol is myristyl alcohol, hexyldecanol Cetanol, oleyl alcohol, behenyl alcohol, lanolin alcohol, ethanol, benzyl alcohol, 1,3-butylene glycol, and dipropylene glycol. A group of nonionic surfactants consisting of polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene hydrogenated castor oil, lauric acid diethanolamide, coconut oil fatty acid diethanolamide, and dimethyl stearylamine The composition according to claim 1, wherein the composition is at least one compound selected from the group consisting of: 3. The composition according to claim 1, wherein the ester is isopropyl myristate. 4. The composition according to claim 1, wherein the alcohol is cetanol. 5. The composition according to claim 1, wherein the nonionic surfactant is polyoxyethylene cetyl ether. 6. The composition for blending a hair treatment agent further comprises a hardened oil, mink oil, olive oil, castor oil, shea butter, sodium cetyl sulfate, sodium palmitoylmethyltaurine, sodium tetradecenesulfonate, polyoxyethylene oleyl ether. Sodium phosphate, N-coconut fatty acid acyl-L-glutamate triethanolamine, α-olefin oligomer, squalane, microcrystalline wax, liquid paraffin, ceresin, candelilla wax, beeswax, N- [3-alkyl (1
2,14) oxy-2-hydroxypropyl] -L-arginine hydrochloride, polyglyceryl diisostearate,
The hair treatment according to any one of claims 1 to 5, further comprising at least one compound selected from the group consisting of lactic acid, methylpolysiloxane, dimethylaminopropylamide stearate, and purified water. Composition for agent formulation. 7. In the composition of the composition for blending a hair treatment agent, when the contents of the esters, alcohols, and nonionic surfactants are A, B, and C (% by weight), A to C The following equation: 3 ≦ A ≦ 35, 5 ≦ B ≦ 70, 1
The composition for blending a hair treatment agent according to any one of claims 1 to 6, wherein the composition satisfies ≤C≤40 and A + B + C≤100. 8. The composition for blending a hair treatment agent, the composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, or the composition for blending a finishing agent. 8. The composition for blending a hair treatment agent according to any one of 7. 9. A hair treatment agent comprising the composition for compounding a hair treatment agent according to claim 1. 10. A hair conditioner comprising: a hair conditioner;
The hair treatment agent according to claim 9, which is a hair dye, a waving agent, or a finishing agent.