CN102277746A - Antimicrobial emulsion used for textile fibers and application method thereof - Google Patents
Antimicrobial emulsion used for textile fibers and application method thereof Download PDFInfo
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- CN102277746A CN102277746A CN 201110213046 CN201110213046A CN102277746A CN 102277746 A CN102277746 A CN 102277746A CN 201110213046 CN201110213046 CN 201110213046 CN 201110213046 A CN201110213046 A CN 201110213046A CN 102277746 A CN102277746 A CN 102277746A
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Abstract
The invention discloses an antimicrobial emulsion used for textile fibers, which is prepared by co-mixing Lurol AM-7 antimicrobial agent, Lurol PS-13362 silicone oil and tri-distilled water. The application method of the antimicrobial emulsion comprises the following steps of: firstly, immersing fiber bundles in the antimicrobial emulsion in a drawing bath under the conditions that the temperature of the drawing bath is 70 to 80 DEG C and the immersion rate is 2 to 3 m/s; then, spraying the antimicrobial emulsion onto the fiber bundles in multiple directions by use of an oil mist sprayer behind a curling machine; and finally, heating for drying. According to the invention, functional groups and polyester fibers are coupled and bonded or form a certain cross-linked structure, and polymer films which are not soluble in water or common organic solvents are formed on fiber surfaces, so that the fibers have better durability; the Lurol AM-7 antimicrobial agent can not be released to the surrounding environment or to the skin, and the fibers have washing resistance; and in the next spinning process, the antimicrobial emulsion is encapsulated in fiber surface layers as the fibers are drawn, cooled and shrunk, and the antimicrobial agent can be well coated by the silicone oil to improve the washing fastness.
Description
Technical field
The invention belongs to the technical field of textile fabric antibacterial treatment, especially relate to a kind of antibiotic emulsion and using method thereof that is used for textile fabric.
Background technology
In recent years, along with the raising of people's living standard, synthetic fiber are transformed to functional form by suitable type gradually, and people pay attention to attractive in appearance, healthy, comfortable, the health care of fiber more.Textile fabric is very easy to grow germ, be the important propagating source of disease, so the antibiotic finish of textile fabric has extremely important meaning.It is exactly to make fiber have the function that suppresses fungus grown that textile fabric is carried out antibiotic finish, keeps the clothing living environment of health, guarantees health.The chemical reagent kind that can give textile fabric antibacterial deodourizing (or antimicrobial) performance has a lot, substantially can be divided into following a few class: 1. organic heavy metal compound, as beta-hydroxy quinolinone, 3,5-dimethylphenyl tin acetic acid esters, phenyl two hot mercury, tributyl lead acetate and alkanoic acid zinc etc.; 2. some dye well auxiliary agents are as triphenylmethane dye etc.; 3. antibiotic such as some organic titaniums, organo-aluminium, organic zirconate and tetracycline share; 4. aromatic series halogen compounds class is as alpha-bromo-cinnamaldehyde etc.; 5. organosilicon quaternary ammonium salt compound.Wherein the organosilicon quaternary amine is that a class is as making the antiseptic that is used for the textile fabric antimicrobial finish to measure, having active interlinkage and active sterilization two parts in the middle of the molecule constitutes, this product is applicable to various fibrous materials, broad-spectrum antiseptic, and solved the not laundry-resistant problem of most of bactericide; This product can also be used for the antibiosis anti-acarien arrangement.This product belongs to non-stripping property antibiotic property, can not induce to produce the drug resistance bacterium.
Summary of the invention
The present invention solves the existing in prior technology technical problem, and a kind of antibiotic emulsion and using method thereof that is used for textile fabric is provided.
Above-mentioned technical problem of the present invention is mainly solved by following technical proposals: a kind of antibiotic emulsion that is used for textile fabric, and by being made after Lurol AM-7 antiseptic, Lurol PS-13362 silicone oil and the tri-distilled water blend.
As preferably, the proportioning of described antibiotic emulsion component is: in 1000 weight portions, and Lurol AM-7 antiseptic 10-20 part, Lurol PS-13362 silicone oil 40-60 part, tri-distilled water 920-950 part is made into antibiotic emulsion after the blend.
As preferably, the proportioning of described antimicrobial formulation component is: in 1000 weight portions, and Lurol AM-7 antiseptic 13-17 part, Lurol PS-13362 silicone oil 47-53 part, tri-distilled water 930-940 part is made into antibiotic emulsion after the blend.
A kind of antibiotic emulsion that is used for textile fabric, its using method is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, then in the crimping machine back by the oil spray machine with a plurality of directions of antibiotic emulsion be sprayed on the fibre bundle, last heating, drying gets final product.
Lurol AM-7 antiseptic adopts antimicrobial technology and the permission raw material thereof of Aegis, improvement technology by Galston is made aqueous emulsion, adopt and contact the antibiotic mechanism of promptly going out, the cell membrane that the physics and the ionization of microbial cell film is destroyed bacterium by its antibiotic chain, make bacterium dead at once after contact, the LurolAM-7 antiseptic has extremely strong and insect killing effect fast to multiple mould, yeast and bacterium, can also prevent the resistance to the action of a drug of bacterium to this antiseptic; The functional group of Lurol AM-7 antiseptic can combine or form certain cross-linked structure with the polyster fibre coupling on the other hand, forms water-fast molecular film at fiber surface, makes finishing agent have durability preferably.Especially when being used in combination with specially designed silicone oil, durability can further be promoted.It can not be seeped into Lurol AM-7 antiseptic surrounding environment or transfer to skin.Aegis antiseptic in the Lurol AM-7 is by nearly 20 kinds of safety and toxicity check.This product can also be used for anti-mite arrangement.Aegis product line and Lurol AM-7 antiseptic multiple textiles, nonwoven fabric, sports goods, medical treatment, and all kinds of consumer goods on the extensive use recent two decades.
Functional group of the present invention combines or forms certain cross-linked structure with the polyster fibre coupling, form the polymeric membrane of water insoluble and common organic solvents at fiber surface, make it have durability preferably, Lurol AM-7 antiseptic can not be seeped into surrounding environment or transfer to skin, and water-fast washing; The present invention is in the spinning process process of back, and antibiotic emulsion is shunk with the drawing of fiber cooling, and fiber wraps into antiseptic in the top layer, and silicone oil can coat antiseptic preferably, has improved washing fastness.
The specific embodiment
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment 1: a kind of antibiotic emulsion that is used for textile fabric, by being made after Lurol AM-7 antiseptic, Lurol PS-13362 silicone oil and the tri-distilled water blend, the ratio of each component is: in 1000 weight portions, 10 parts of Lurol AM-7 antiseptics, 60 parts of Lurol PS-13362 silicone oil, 930 parts of tri-distilled waters are made into antibiotic emulsion after the blend.Its using method is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, a plurality of directions of antibiotic emulsion ground is sprayed on the fibre bundle by the oil spray machine in the crimping machine back then, and heating, drying gets final product at last.
Embodiment 2: a kind of antibiotic emulsion that is used for textile fabric, by being made after Lurol AM-7 antiseptic, LurolPS-13362 silicone oil and the tri-distilled water blend, the ratio of each component is: in 1000 weight portions, 20 parts of Lurol AM-7 antiseptics, 40 parts of Lurol PS-13362 silicone oil, 940 parts of tri-distilled waters are made into antibiotic emulsion after the blend.Its using method is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, a plurality of directions of antibiotic emulsion ground is sprayed on the fibre bundle by the oil spray machine in the crimping machine back then, and heating, drying gets final product at last.
Embodiment 3: a kind of antibiotic emulsion that is used for textile fabric, by being made after Lurol AM-7 antiseptic, LurolPS-13362 silicone oil and the tri-distilled water blend, the ratio of each component is: in 1000 weight portions, 10 parts of Lurol AM-7 antiseptics, 40 parts of Lurol PS-13362 silicone oil, 950 parts of tri-distilled waters are made into antibiotic emulsion after the blend.Its using method is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, a plurality of directions of antibiotic emulsion ground is sprayed on the fibre bundle by the oil spray machine in the crimping machine back then, and heating, drying gets final product at last.
Embodiment 4: a kind of antibiotic emulsion that is used for textile fabric, by being made after Lurol AM-7 antiseptic, LurolPS-13362 silicone oil and the tri-distilled water blend, the ratio of each component is: in 1000 weight portions, 20 parts of Lurol AM-7 antiseptics, 60 parts of Lurol PS-13362 silicone oil, 920 parts of tri-distilled waters are made into antibiotic emulsion after the blend.Its using method is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, a plurality of directions of antibiotic emulsion ground is sprayed on the fibre bundle by the oil spray machine in the crimping machine back then, and heating, drying gets final product at last.
Embodiment 5: a kind of antibiotic emulsion that is used for textile fabric, by being made after Lurol AM-7 antiseptic, Lurol PS-13362 silicone oil and the tri-distilled water blend, the ratio of each component is: in 1000 weight portions, 15 parts of Lurol AM-7 antiseptics, 50 parts of Lurol PS-13362 silicone oil, 935 parts of tri-distilled waters are made into antibiotic emulsion after the blend.Its using method is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, a plurality of directions of antibiotic emulsion ground is sprayed on the fibre bundle by the oil spray machine in the crimping machine back then, and heating, drying gets final product at last.
The contrast of the experimental data of the present invention and anti-bacteium deodorization finishing agent SCJ-891 is as follows: (detection method is an AATCC 100-1993 U.S. AATCC standard, and test sample is the fabric put of two kinds of antiseptics and the antibiotic finish fabric through washing for 20 times, 50 times, 90 times, 140 times initially the time and respectively)
Table 1, bacteriostatic experiment data of the present invention
The bacteriostatic experiment data of table 2, anti-bacteium deodorization finishing agent SCJ-891
At last, should be pointed out that above embodiment only is the more representational example of the present invention.Obviously, technical scheme of the present invention is not limited to the foregoing description, and many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (4)
1. an antibiotic emulsion that is used for textile fabric is characterized in that being made after described antibiotic emulsion is by Lurol AM-7 antiseptic, Lurol PS-13362 silicone oil and tri-distilled water blend.
2. according to the described antibiotic emulsion that is used for textile fabric of claim 1, the proportioning that it is characterized in that described antibiotic emulsion component is: in 1000 weight portions, Lurol AM-7 antiseptic 10-20 part, Lurol PS-13362 silicone oil 40-60 part, tri-distilled water 920-950 part is made into antibiotic emulsion after the blend.
3. according to the described antibiotic emulsion that is used for textile fabric of claim 1, the proportioning that it is characterized in that described antimicrobial formulation component is: in 1000 weight portions, Lurol AM-7 antiseptic 13-17 part, Lurol PS-13362 silicone oil 47-53 part, tri-distilled water 930-940 part is made into antibiotic emulsion after the blend.
4. according to claim 1 or the 2 or 3 described antibiotic emulsions that are used for textile fabric, the using method that it is characterized in that described antibiotic emulsion is: earlier fibre bundle is flooded antibiotic emulsion in the drawing-off bath, 70～80 ℃ of the temperature of drawing-off bath, the speed of dipping is 2～3m/s, then in the crimping machine back by the oil spray machine with a plurality of directions of antibiotic emulsion be sprayed on the fibre bundle, last heating, drying gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201110213046 CN102277746B (en) | 2011-07-28 | 2011-07-28 | Antimicrobial emulsion used for textile fibers and application method thereof |
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| CN 201110213046 CN102277746B (en) | 2011-07-28 | 2011-07-28 | Antimicrobial emulsion used for textile fibers and application method thereof |
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| CN102277746A true CN102277746A (en) | 2011-12-14 |
| CN102277746B CN102277746B (en) | 2013-02-06 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102517676A (en) * | 2011-12-16 | 2012-06-27 | 杭州贝斯特化纤有限公司 | Flame-resistant and antibacterial polyester staple fiber and production technique thereof |
| CN102605457A (en) * | 2012-03-26 | 2012-07-25 | 杭州汉邦化纤有限公司 | Anti-flaming extra-white regenerated three-dimensional crimp dacron staple fiber and manufacturing method thereof |
| CN115323763A (en) * | 2022-08-30 | 2022-11-11 | 宁波三邦超细纤维有限公司 | Formula and preparation method of nano-zinc oxide antibacterial and anticorrosive polyester fiber |
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2011
- 2011-07-28 CN CN 201110213046 patent/CN102277746B/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102517676A (en) * | 2011-12-16 | 2012-06-27 | 杭州贝斯特化纤有限公司 | Flame-resistant and antibacterial polyester staple fiber and production technique thereof |
| CN102517676B (en) * | 2011-12-16 | 2013-10-23 | 杭州贝斯特化纤有限公司 | Production technique for flame-resistant and antibacterial polyester staple fiber |
| CN102605457A (en) * | 2012-03-26 | 2012-07-25 | 杭州汉邦化纤有限公司 | Anti-flaming extra-white regenerated three-dimensional crimp dacron staple fiber and manufacturing method thereof |
| CN115323763A (en) * | 2022-08-30 | 2022-11-11 | 宁波三邦超细纤维有限公司 | Formula and preparation method of nano-zinc oxide antibacterial and anticorrosive polyester fiber |
| CN115323763B (en) * | 2022-08-30 | 2023-08-11 | 宁波三邦超细纤维有限公司 | Formula and preparation method of nano zinc oxide antibacterial antiseptic polyester fiber |
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| CN102277746B (en) | 2013-02-06 |
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