JPH04108185A - Washing-resistant anti-bacterial treatment of textile structure - Google Patents
Washing-resistant anti-bacterial treatment of textile structureInfo
- Publication number
- JPH04108185A JPH04108185A JP22174790A JP22174790A JPH04108185A JP H04108185 A JPH04108185 A JP H04108185A JP 22174790 A JP22174790 A JP 22174790A JP 22174790 A JP22174790 A JP 22174790A JP H04108185 A JPH04108185 A JP H04108185A
- Authority
- JP
- Japan
- Prior art keywords
- textile structure
- washing
- antibacterial
- bacterial
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 27
- 239000004753 textile Substances 0.000 title claims abstract description 7
- 238000005406 washing Methods 0.000 title claims description 10
- -1 polysiloxane Polymers 0.000 claims abstract description 24
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 238000003672 processing method Methods 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract description 5
- 239000003242 anti bacterial agent Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 229920002994 synthetic fiber Polymers 0.000 abstract description 2
- 239000012209 synthetic fiber Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002759 woven fabric Substances 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
- RNKMOGIPOMVCHO-SJMVAQJGSA-N 1,3,6-trigalloyl glucose Chemical compound C([C@@H]1[C@H]([C@@H]([C@@H](O)[C@H](OC(=O)C=2C=C(O)C(O)=C(O)C=2)O1)OC(=O)C=1C=C(O)C(O)=C(O)C=1)O)OC(=O)C1=CC(O)=C(O)C(O)=C1 RNKMOGIPOMVCHO-SJMVAQJGSA-N 0.000 description 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- YUUVAZCKXDQEIS-UHFFFAOYSA-N azanium;chlorite Chemical compound [NH4+].[O-]Cl=O YUUVAZCKXDQEIS-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatment Of Fiber Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は耐洗濯性抗菌効果を有する繊維構造物の加工方
法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for processing a fibrous structure having wash-resistant antibacterial effects.
（従来の技術）
従来より繊維構造物用抗菌剤としては四級アンモニウム
塩素両性活性剤、オルガノシリコン第四級アンモニウム
塩、ジフェニルエーテル系化合物等が知られているが、
この様な処理剤で処理された繊維構造物の抗菌性は、加
工直後は優れた効果を発揮するが、繰返し洗濯やドライ
クリーニングにより抗菌効果が失なわれるという問題が
ある。(Prior Art) Conventionally, quaternary ammonium chloride amphoteric activators, organosilicon quaternary ammonium salts, diphenyl ether compounds, etc. have been known as antibacterial agents for textile structures.
Although the antibacterial properties of fiber structures treated with such processing agents are excellent immediately after processing, there is a problem in that the antibacterial effects are lost by repeated washing or dry cleaning.
この問題を解決するためにＮ−メ千ロールメラミン及び
Ｎ−メチロール尿素等Ｎ−メチロール誘導体を同時に用
いる方法や、布帛に抗菌加工剤を付与すると同時もしく
は付与した後にアニオン系フェノール化合物（例えばタ
ンニン、フェノールスルホン酸ホルムアルデヒド樹脂）
を付与する方法（特開昭５９−１１２０７０号公報）や
、オルガノシリコン第４級アンモニウム塩の耐洗濯性を
向上させるために、硫酸塩界面活性剤（例えばアルキル
硫酸塩、ポリオキシアルキレンアルキルエチルｇ酸塩若
しくはポリオキソアルキレンアルキルアＩＪ−ルエーテ
ル硫酸塩）を同時に用いる方法（特開昭６２−１７７２
８４号公報）、有機および／または無機塩（例えば塩化
ナトリウム、ｇ酸ナトリウム）を同時に用いる方法（特
開昭５９８６６３２号公報）、電解質塩類（例えば硫安
）を同時に用いる方法（特開昭６０−１６２８７０号公
ｌ）等多数提案されている。To solve this problem, there is a method of simultaneously using N-methylol derivatives such as N-methylol melamine and N-methylol urea, or anionic phenol compounds (e.g. tannin, phenolsulfonic acid formaldehyde resin)
(Japanese Unexamined Patent Publication No. 112070/1982), and in order to improve the washing resistance of organosilicon quaternary ammonium salts, sulfate surfactants (e.g. alkyl sulfates, polyoxyalkylene alkylethyl g A method of simultaneously using an acid salt or a polyoxoalkylene alkyl ether sulfate (Japanese Patent Application Laid-Open No. 62-1772
84), a method using organic and/or inorganic salts (e.g. sodium chloride, sodium chloride) at the same time (Japanese Patent Application Laid-open No. 5986632), a method using electrolyte salts (e.g. ammonium sulfate) at the same time (Japanese Patent Application Laid-open No. 162870-1982). A number of proposals have been made, including No. 1).
（発明が解決しようとする課題）
しかしながら、Ｎ−メチロール誘導体を同時に用いる方
法は多かれ少なかれ残留ホルマリンの問題を生し、用途
によっては使用出来な０こと力（ある。また他の加工方
法はオルガノソリコン第４級アンモニウム塩に限定され
たものや合成繊維に限定されたものであり、多くの抗菌
剤また多くの繊維に通用できる耐洗濯性抗菌加工法は未
だ完成していないのが現状である。(Problems to be Solved by the Invention) However, the method of using N-methylol derivatives at the same time causes the problem of residual formalin to a greater or lesser extent, making it impossible to use depending on the application. The current situation is that many antibacterial agents and washing-resistant antibacterial processing methods that can be applied to many fibers have not yet been completed. .
本発明の目的は多くの抗菌剤また多くの繊維に適用しう
る、ｆｃ濯耐久性抗菌効果を有する繊維構造物の加工方
法を提供することにある。An object of the present invention is to provide a method for processing a fiber structure having antibacterial effects that are resistant to FC washing and can be applied to many antibacterial agents and many fibers.
（課題を解決するための手段）
上述の目的は、繊維構造物に、抗菌物質、末端基変性ポ
リシロキサン及びメチルハイドロジエンポリシロキサン
を付与し、しかる後熱処理することを特徴とする繊維構
造物の耐洗濯性抗菌加工方法により達成される。(Means for Solving the Problems) The above object is to provide a fibrous structure characterized in that an antibacterial substance, a terminal group-modified polysiloxane, and a methylhydrogen polysiloxane are added to the fibrous structure, followed by heat treatment. Wash resistance is achieved through antibacterial processing methods.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明に云う繊維構造物とは、糸、織物１編物不織布等
を言い、綿、麻、羊毛等の天然繊維、レーヨン、キュプ
ラ等の再生繊維、ナイロン、ポリエステル等の合成繊維
単独または該繊維と他の繊維との混用品が挙げられる。The fiber structure referred to in the present invention refers to yarns, woven fabrics, nonwoven fabrics, etc., and includes natural fibers such as cotton, linen, and wool, recycled fibers such as rayon and cupro, and synthetic fibers such as nylon and polyester alone or in combination with such fibers. Examples include mixed products with other fibers.
本発明において用いられる抗菌物質は公知のものを使用
できる。好ましい例として、オルガノシリコン第４級ア
ンモニウム塩が挙げられる。たとえばポロンＭＦ５０（
商標：信越化学工業株式会社）として市販されている３
−（トリメトキンンリル）プロビルジメチルオクタデソ
ルアンモニウムクロライトを用いることができる。ある
いはジフェニルエーテル系化合物を用いることもできる
。Known antibacterial substances can be used in the present invention. A preferred example is an organosilicon quaternary ammonium salt. For example, Poron MF50 (
Trademark: Shin-Etsu Chemical Co., Ltd.)
-(Trimethquinnryl)probyldimethyloctadesol ammonium chlorite can be used. Alternatively, diphenyl ether compounds can also be used.
さらに、四級アンモニウム塩系両性活性剤を用いること
もできる。たとえばニノカノンＲＢ（商標。Furthermore, quaternary ammonium salt-based amphoteric surfactants can also be used. For example, Ninokanon RB (trademark).
日華化学株式会社、固形分１５％）として市販されてい
る下記の構造式のものを用いることができる。A product having the following structural formula and commercially available from NICCA Chemical Co., Ltd. (solid content: 15%) can be used.
（上式中、Ｒ１は炭素数８〜２２のアルキルまたはアル
ケニル基を表し、Ｒ２及びＲ１は炭素数１〜５のアルキ
ル基を表し、Ｒ′は炭素数２〜４のアルキレン基を表し
、ｍは１または２を表し、ｎは１〜５の整数を表し、Ｘ
はアルキルリン酸エステルイオンを表す。）
変性ポリノロキサンを除く）重量に対してＯ，Ｏ’１〜
１重量％、好ましくは０．１〜０．５重量％用いる。(In the above formula, R1 represents an alkyl or alkenyl group having 8 to 22 carbon atoms, R2 and R1 represent an alkyl group having 1 to 5 carbon atoms, R' represents an alkylene group having 2 to 4 carbon atoms, and m represents 1 or 2, n represents an integer from 1 to 5,
represents an alkyl phosphate ion. ) O, O'1~ based on weight (excluding modified polynoloxane)
1% by weight, preferably 0.1-0.5% by weight is used.
０．０１重量％未満であると抗菌効果は得られず、ヅル
ソフトＷＥ（商標：へキストジャノぐン株式会社）等を
用いることができる。If the amount is less than 0.01% by weight, no antibacterial effect will be obtained, and Zurusoft WE (trademark: Hoechst Janogun Co., Ltd.) or the like can be used.
この末端基変性ポリシロキサンは固形分として繊維重量
自体（抗菌物質及びメチルハイドロジエンポリシロキサ
ンをμ ）重量に対して０．１〜５重量％、好ましくは
０．２〜３重量％用いる。０゜重量％未満であると充分
な耐久性が得られず５重量％以上ではヌメリ怒が大とな
る。The terminal group-modified polysiloxane is used as a solid content of 0.1 to 5% by weight, preferably 0.2 to 3% by weight, based on the weight of the fiber itself (μ of the antibacterial substance and methylhydrodiene polysiloxane). If it is less than 0% by weight, sufficient durability will not be obtained, and if it is more than 5% by weight, it will become slimy.
本発明において用いられるメチルハイドロジエンポリシ
ロキサンは下記の構造式
サンは下記の構造式
（但しＸ ニー０Ｈ２−ＣＨ＝ＣＨ２，又はＣＨ３）
を持つものであり、市販されているライトチ、クス９０
０（商標：共栄社油脂化学工業株式会社）、を持つもの
であり、市販されているライトテックスＳ−０１１（商
標：共栄社油脂化学工業株式会社）、ドライポン６００
（商標二日華化学工業株式会社）及びＤＩＣ５ＩＬＩＣ
ＯＮＥ ｃｏｎｃ−３Ａ （商標：大日本インキ化学工
業株式会社）等を用いることができる。The methylhydrodiene polysiloxane used in the present invention has the following structural formula (wherein
0 (trademark: Kyoeisha Yushi Kagaku Kogyo Co., Ltd.), and commercially available Lighttex S-011 (trademark: Kyoeisha Yushi Kagaku Kogyo Co., Ltd.), Drypon 600
(Trademark Nikka Kagaku Kogyo Co., Ltd.) and DIC5ILIC
ONE conc-3A (trademark: Dainippon Ink & Chemicals Co., Ltd.) or the like can be used.
このメチルハイドロジエンポリシロキサンは固ポリシロ
キサンを除く）重量に対して０．０５〜５重量％、好ま
しくは０．１〜４重量％用いる。The methylhydrodiene polysiloxane is used in an amount of 0.05 to 5% by weight, preferably 0.1 to 4% by weight, based on the weight (excluding solid polysiloxane).
０．０５重量％未満であると充分な耐久性が得られず、
一方５重量％以上ではヌメリ感が大となる。If it is less than 0.05% by weight, sufficient durability cannot be obtained,
On the other hand, if it exceeds 5% by weight, the slimy feeling will become large.
浸漬槽には各種助剤を投入してもよいことは勿論である
が、特に潜在酸性触媒即ち、加工浴では中性で加熱（キ
ユアリング）時に酸性となる塩化アンモニウム、硫酸ア
ンモニウム、りん酸水素２アンモニウム等のアンモニウ
ム塩、２−アミノ２−メチルプロパツール、ハイドロク
ロリド等のアミン塩、塩化マグネシウム、硝酸亜鉛、塩
化亜鉛、はうふつ化亜鉛、はうふつ化マグネシウムのよ
うな金属塩を投入することが好ましく、投入量としては
、メチルハイドロジエンポリシロキサンの総量に対して
１０〜５０重量％、更には２０〜４０重量％が好ましい
。Of course, various auxiliary agents may be added to the dipping tank, but in particular latent acidic catalysts, such as ammonium chloride, ammonium sulfate, and diammonium hydrogen phosphate, which are neutral in the processing bath but become acidic when heated (curing). Adding ammonium salts such as 2-amino 2-methyl propatool, amine salts such as hydrochloride, metal salts such as magnesium chloride, zinc nitrate, zinc chloride, zinc sulfide, and magnesium sulfide. is preferable, and the amount to be added is preferably 10 to 50% by weight, more preferably 20 to 40% by weight, based on the total amount of methylhydrodiene polysiloxane.
次に耐洗濯性抗菌繊維構造物の加工方法の一実施態様を
述べると、所定量の抗菌物質、末端基変性ポリシロキサ
ン及びメチルハイドロジエンポリノロキサンに水を加え
て処理液を作り、これをパディング法によって繊維構造
物に付与する。次に１００〜１２０°Ｃで２〜３分間乾
燥し、１４０〜１６０℃で３〜５分間の熱処理を行なう
。Next, we will describe one embodiment of the method for processing a wash-resistant antibacterial fiber structure.Water is added to a predetermined amount of an antibacterial substance, end group-modified polysiloxane, and methylhydrodiene polyoloxane to create a treatment solution. It is applied to the fiber structure by a padding method. Next, it is dried at 100-120°C for 2-3 minutes, and heat-treated at 140-160°C for 3-5 minutes.
尚、処理液の付与方法としてはパディング法に限定され
るものではなく、スプレー法、コーティング法、浸漬−
脱水法等で付与しても良いことは云うまでもない。Note that the method of applying the treatment liquid is not limited to the padding method, and may include spraying, coating, and dipping.
Needless to say, it may be applied by a dehydration method or the like.
（作用）
本発明は上記の様に構成したので、メチルハイドロジエ
ンポリシロキサンが末端基変性ポリシロキサンの架橋剤
として働き、熱処理することにより繊維表面に三次元的
網目構造を構成するようになる。そして抗菌物質はこの
三次元的網目構造の中に保持されるようになるので繰り
返し洗濯に対しても抗菌効果が失なわれないようになる
のである。(Function) Since the present invention is configured as described above, the methylhydrodiene polysiloxane acts as a crosslinking agent for the end group-modified polysiloxane, and by heat treatment, a three-dimensional network structure is formed on the fiber surface. Since the antibacterial substance is retained within this three-dimensional network structure, the antibacterial effect will not be lost even after repeated washing.
（実施例） 以下実施例で本発明の詳細な説明する。(Example) The present invention will be explained in detail below with reference to Examples.
尚、抗菌効果は菌数測定法で黄色ぶどう状球菌（ｓｔａ
ｐｈｙｌｏｃｏｃｃｕｓ ａｕｒｅｕｓ） ＜ ＩＦＯ
１２７３２＞を用いて測定した。In addition, the antibacterial effect was determined by measuring the number of Staphylococcus aureus (staphylococcus aureus).
phylococcus aureus) < IFO
12732>.
又耐洗濯性はＪＩＳ Ｌ０２１７ １０３法で洗濯を
１０回行なった後、上記法による抗菌効果を調べた。Washing resistance was determined by washing the product 10 times using the JIS L0217 103 method, and then examining the antibacterial effect using the above method.
実施例１
綿平織物で経、！４０番手、密度が経１１９本／吋、緯
１０８本／吋のものを常法により毛焼糊抜、精練、晒、
シルケットを行なった。Example 1 Warp cotton plain fabric! 40, with a density of 119 warps/inches and wefts of 108 threads/inches.
Performed mercerization.
該平織物を、抗菌物質としてニノカノンＲＢ（商標１日
華化学株式会社、固形分１５％含有）１５ ｇ／ｌ、末
端基変性ポリシロキサンとしてライトテックス９００（
商標、共栄社油脂化学工業株式会社、固形分３０％含有
）３０ｇ／ｌ メチルハイドロジエンポリシロキサンと
してライトテックスＳ−０１１（商標、共栄社油脂化学
工業株式会社、固形分５８．５％含有）１０ｇ／１．触
媒としてライトチ７クスＦ−１２（商標、共栄社油脂化
学工業株式会社、有効成分１７％、有機金属塩系）１０
ｇ／ｆからなる処理液中を通過せしめ、ビフクアノプ率
７０％に搾液後、１００℃で２分間乾燥し、引き続き１
５０℃で３分間熱処理し、実施例１の製品を得た。The plain woven fabric was treated with 15 g/l of Ninokanone RB (Trademark 1, Nicca Chemical Co., Ltd., solid content 15%) as an antibacterial substance and Litetex 900 (as an end group-modified polysiloxane).
Trademark, Kyoeisha Yushi Kagaku Kogyo Co., Ltd., solid content 30%) 30 g/l Methylhydrodiene polysiloxane as Litetex S-011 (trademark, Kyoeisha Yushi Kagaku Kogyo Co., Ltd., solid content 58.5%) 10 g/1 ．． As a catalyst, Light Chi7x F-12 (trademark, Kyoeisha Yushi Kagaku Kogyo Co., Ltd., active ingredient 17%, organometallic salt type) 10
After squeezing to a bifuquaanop ratio of 70%, it was dried at 100°C for 2 minutes, and then
The product of Example 1 was obtained by heat treatment at 50° C. for 3 minutes.
比較例１
実施例と同様の処理において、末端基変性ポリシロキサ
ンを添加しなかった他は実施例１と同様の加工を行ない
、比較例１の製品を得た。Comparative Example 1 A product of Comparative Example 1 was obtained by carrying out the same processing as in Example 1 except that the end group-modified polysiloxane was not added.
比較例２
実施例と同様の処理において、メチルハイドロジエンポ
リシロキサンを添加しなかった他は実施例１と同様の加
工を行ない比較例２の製品を得た。Comparative Example 2 A product of Comparative Example 2 was obtained by carrying out the same processing as in Example 1 except that methylhydrodiene polysiloxane was not added.
実施例１．比較例１〜２で得られた製品及び洗濯１０回
後の抗菌効果を第１表に示した。Example 1. Table 1 shows the antibacterial effects of the products obtained in Comparative Examples 1 and 2 and after 10 washes.
（以下余白）
第
■
表
また特殊な装置を必要としないので、安価に捉伊できる
という効果も奏する。(Left below) Table ① Also, since no special equipment is required, it can be captured at low cost.
第１表かられかるとおり、本発明は洗濯１０回後にも抗
菌効果が高いことがわかる。As can be seen from Table 1, the present invention has a high antibacterial effect even after 10 washes.
尚、ポリエステル平織物、ナイロン平織物についても同
様に試験を行なった所、はぼ同等の耐洗濯性抗菌効果が
得られた。Similar tests were conducted on polyester plain woven fabrics and nylon plain woven fabrics, and the same washing resistance and antibacterial effects were obtained.
（発明の効果）
以上、詳述したように本発明方法により得られた製品は
、優れた抗菌性能を長期に亘り維持するものであり、し
かもホルマリンを含有しないので、衣料素材、シーツ、
枕カバー等の用途に頗る有用である。(Effects of the Invention) As detailed above, the products obtained by the method of the present invention maintain excellent antibacterial performance over a long period of time, and since they do not contain formalin, they can be used as clothing materials, sheets,
It is extremely useful for uses such as pillow covers.
Claims (1)
ン及びメチルハイドロジエンポリシロキサンを付与し、
しかる後熱処理することを特徴とする繊維構造物の耐洗
濯性抗菌加工方法。1) Adding an antibacterial substance, end group-modified polysiloxane, and methylhydrogen polysiloxane to the fiber structure,
A washing-resistant antibacterial processing method for a textile structure, which is characterized by subjecting it to subsequent heat treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22174790A JPH04108185A (en) | 1990-08-22 | 1990-08-22 | Washing-resistant anti-bacterial treatment of textile structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22174790A JPH04108185A (en) | 1990-08-22 | 1990-08-22 | Washing-resistant anti-bacterial treatment of textile structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04108185A true JPH04108185A (en) | 1992-04-09 |
Family
ID=16771589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22174790A Pending JPH04108185A (en) | 1990-08-22 | 1990-08-22 | Washing-resistant anti-bacterial treatment of textile structure |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04108185A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0849161A (en) * | 1994-08-02 | 1996-02-20 | N S Bureen:Kk | Processing system and method for clothing |
| WO1999007932A1 (en) * | 1997-08-07 | 1999-02-18 | Fukusen Kogyo Co., Ltd. | Process for the fungistatic and/or antibacterial finishing of sewings and equipment therefor |
| US8071694B2 (en) | 2008-02-20 | 2011-12-06 | Sabic Innovative Plastics Ip B.V. | Thermoplastic polycarbonate/polyester blend compositions with improved mechanical properties |
| CN102277746A (en) * | 2011-07-28 | 2011-12-14 | 杭州贝斯特化纤有限公司 | Antimicrobial emulsion used for textile fibers and application method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5249397A (en) * | 1975-10-14 | 1977-04-20 | Toyo Boseki | Treatment of synthetic fiber for wadding |
| JPS5288700A (en) * | 1976-01-19 | 1977-07-25 | Mitsubishi Rayon Co | Production of synthetic fiber with good durability and soft smoothness |
| JPS59163485A (en) * | 1983-03-08 | 1984-09-14 | 株式会社クラレ | Production of fatique resistance enhanced tufted carpet |
| JPH0192483A (en) * | 1987-09-30 | 1989-04-11 | Unitika Ltd | Durable water repelling and shrinkproof processing of wool fabric |
-
1990
- 1990-08-22 JP JP22174790A patent/JPH04108185A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5249397A (en) * | 1975-10-14 | 1977-04-20 | Toyo Boseki | Treatment of synthetic fiber for wadding |
| JPS5288700A (en) * | 1976-01-19 | 1977-07-25 | Mitsubishi Rayon Co | Production of synthetic fiber with good durability and soft smoothness |
| JPS59163485A (en) * | 1983-03-08 | 1984-09-14 | 株式会社クラレ | Production of fatique resistance enhanced tufted carpet |
| JPH0192483A (en) * | 1987-09-30 | 1989-04-11 | Unitika Ltd | Durable water repelling and shrinkproof processing of wool fabric |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0849161A (en) * | 1994-08-02 | 1996-02-20 | N S Bureen:Kk | Processing system and method for clothing |
| WO1999007932A1 (en) * | 1997-08-07 | 1999-02-18 | Fukusen Kogyo Co., Ltd. | Process for the fungistatic and/or antibacterial finishing of sewings and equipment therefor |
| US6440363B1 (en) | 1997-08-07 | 2002-08-27 | Fukusen Kogyo Co., Ltd. | Process for the fungistatic and/or antibacterial finishing of sewings and equipment therefor |
| US8071694B2 (en) | 2008-02-20 | 2011-12-06 | Sabic Innovative Plastics Ip B.V. | Thermoplastic polycarbonate/polyester blend compositions with improved mechanical properties |
| CN102277746A (en) * | 2011-07-28 | 2011-12-14 | 杭州贝斯特化纤有限公司 | Antimicrobial emulsion used for textile fibers and application method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7713891B1 (en) | Flame resistant fabrics and process for making | |
| US8012890B1 (en) | Flame resistant fabrics having a high synthetic content and process for making | |
| KR20130008015A (en) | Deodorant fiber structure | |
| AU605958B2 (en) | Method of altering the surface of a solid synthetic polymer | |
| JPS61296178A (en) | Flame-proof processing of cellulosic fiber material | |
| JPH04108185A (en) | Washing-resistant anti-bacterial treatment of textile structure | |
| DE60027951T2 (en) | Cellulose fibers containing fabric | |
| JP2002088649A (en) | Cellulosic fiber-containing fiber structure | |
| JPH04108179A (en) | Washing-resistant antifungal processing for fibrous structure | |
| US3041199A (en) | Wrinkle resistant cellulose fabric and method of production | |
| Shaw et al. | The Finishing of Wool Fabrics | |
| US2709638A (en) | Process for imparting wool-like finish to cellulose-acid-nitrogen complex fabrics and product thereof | |
| JPH07292572A (en) | Moth-proofing antibacterial textile structure having washing durability | |
| JP4264767B2 (en) | Cellulosic fiber-containing fiber structure for form-stable processing and method for producing form-stable cellulosic fiber-containing fiber structure | |
| JPH0827675A (en) | Method for improving strike through of polynosic fabric | |
| JP2000096442A (en) | Finishing of cellulosic textile fabric | |
| JPS6364545B2 (en) | ||
| JPH06228884A (en) | Washing-resistant antibacterial processing method for textile structure | |
| JP2621580B2 (en) | Antibacterial and deodorant colored polyester fiber structure and method for producing the same | |
| JPH10325075A (en) | Antimicrobial fiber material and its production | |
| JP3580110B2 (en) | Polyester fiber structure and method for producing the same | |
| JPH04174765A (en) | Production of deodorizing fabric | |
| JP3593539B2 (en) | Processing method for cellulose fiber products | |
| JP2001316973A (en) | Cellulosic fiber-including fiber structural article | |
| JPH08337973A (en) | Resin finishing of cellulose-based textile structural product |