CN102268334B - Natural plant cleanser essence - Google Patents
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Abstract
The invention discloses a natural plant cleanser essence and a preparation method thereof. The natural plant cleanser essence is prepared by the following steps of: extracting, filtering and removing harmful substances such as tannic acid and the like by taking natural tea seeds as raw materials; preparing a concentrated solution; and preparing the cleanser essence by supplementing other plant extracts. The cleanser essence comprises the following components in percentage by weight: 60-85 percent of Be' tea saponin concentrated solution of 20-30 degrees, 5-15 percent of plant extracts and the balance of solvent. The cleanser essence is different from the conventional commonly used chemical cleanser essence in which a synthetic petrochemical raw material is mainly used in that the saponin in the natural tea seed is used as a main surfactant; then the main surfactant is supplemented by other plant extracts to prepare the pure natural plant cleanser essence; and thus, the active matter content is more than or equal to 20-30 percent, the raw material source is extremely rich and belongs to a renewable resource, the cleanser essence has the characteristics of strong detergency, easiness in biodegradation, environmental friendliness, safety in use and the like, and industrial production can be realized.
Description
Technical field
The present invention relates to filed of daily-use chemical industry, specifically is a kind of natural phant liquid detergent and preparation method thereof.
Background technology
The detergents and cosmetic washing composition is becoming the daily necessities that current social people be unable to do without step by step, no matter be in public places, the deluxe hotel, still in each family, popular refreshment stand, we can see the trace of soapless soap.On the news media of every day such as broadcasting, TV, the newpapers and periodicals also in the advertisement of doing soapless soap in large quantities.In the use of these packaged well-rounded soapless soaps, people are unawares as relying on it as taking drugs.When using soapless soap, chemical pollution is just endangering human beings'health through various channels with can not extricate oneself.So problem that some scientists is familiar with soapless soap with the spirit proposition that the mankind are responsible for again.The annual tableware cleaning essence of using of China reaches 600,000 tons, the just undemonstrative corrosion of these petrochemical materialss we, the authoritative group of Japan---japanese consumers alliance raises a cry of warning through the investigation in more than 20 years, experiment and according to the accident reporting to the human consumer: " soapless soap could not have been used again! " soapless soap is actually the byproduct with the exploitation of oil rubbish, because it is water-soluble, fall so its essence is out in the cold always; Because its cost is low, scourability is good, thus once discovery, be accepted very soon, and with the cover-up of color, smell and taste it is wired up and to enter among the daily life.The wash removability of soapless soap is mainly from tensio-active agent, because having, tensio-active agent can reduce capillary effect, can penetrate into Lian Shui all can't ooze in people's the fiber gap, the dirt of ensconcing in the fiber gap is extruded, meanwhile soapless soap then squeezes among these spaces, even water also is difficult to clean them; Equally, tensio-active agent also can infiltrate human body, stick in washing composition on the skin nearly 0.5% and infiltrate blood, on the skin if having wound then seepage force improve more than 10 times.The soapless soap toxin that enters in the human body can make calcium ion concn decline in the blood, acidification of blood, make the people tired easily, these toxin also make the functions of expelling toxin of liver reduce, the former toxin alluvial that should excrete is taken care of the pence in vivo, make people's immunity degradation, cancer is brought out in the liver cell lesion aggravation easily.Soapless soap is invaded behind the human body after other chemical substance is combined, and toxicity can increase several times, especially has the very strong cancer characteristic of bringing out.According to relevant report, stomach cancer cell is cultivated in artificial experiment, injection soapless soap base substance LAS can accelerate the deterioration of cancer cells.The blood dissolubility of LAS is also very strong, causes the variation of oxyphorase easily, causes anemia.Spreading unchecked of chemical products is the increasing maximum root of human cancer.Because soapless soap is human the closest the most direct daily necessities, people use widely that soapless soap hair washing is sent out, the chopsticks of washing the dishes, wash clothes, have a bath in, chemical toxicant just infiltrates from thousands upon thousands pores, human body is just in day and night drug abuse, chemical pollution is infiltrated from mouth, infiltrate from skin, accumulate over a long period the assembly of hiding.Because therefore the harm of this pollution can not clearly, tend to out in the cold at short notice.But micropollution continues to enter in the body, takes care of the pence and can cause serious consequence, causes the various pathologies of human body.Human lives's urbanization is inevasible, and city life also is inevitable to the dependence of sanitising agent.So, improve washing composition, use not harmful to human, do not destroy living environment, non-toxic and non-pollution washing composition just becomes the task of top priority.In the cry of shout environmental protection in the whole world, helping planet Earth, many countries place hope in the ocean on, the extracting natural washing composition is universe's hope too impatient to wait from inexhaustible, nexhaustible seawater, and near the resident the Dead Sea, more than the 3000 years preceding Middle East just understands with seawater and is castrated; At World War I eve, the washing composition that Germany just refines from seawater in research; Also can buy medical sea water detergent the eighties in the pharmaceutical chemists of Japan, this washing composition is near non-toxic and non-pollution standard.Hair washing is sent out in China also Ceng Youyong Ovum Gallus domesticus album, record with the soaked way such as wash clothes of Chinese honey locust, this illustrates that also the exploitation washing composition is the future broadness in natural resource, after people progressively are familiar with the harm of having understood soapless soap, and the paces of the accelerate development that is bound to natural detergent resource.Patent No. publication number CN 1375547A disclose a kind of with soya bean be liquid detergent that raw material is made be a kind of be the liquid detergent that raw material is made with soya bean, but raw material and grain are competed, so the applicant seeks a kind of natural phant liquid detergent that can the substituted chemistry washing composition in plant.
Oil tea is the distinctive woody edible oil materials seeds of China, is big superior resources of forestry development, the cultivation in more than 2000 year is arranged and utilize historical.At present, China's oil tea area has 4,500 ten thousand mu approximately, about 1,000,000 tons of tea seed annual production, produce about 260,000 tons of tea oil per year, and the annual output of the residuum after the oil expression tea dregs of rice can reach 68.39 ten thousand tons, and this valuable resource can only be used for because there is not modern production technology to change into productivity making fertilizer and killing fish etc.Tea-seed oil is one of the distinctive woody oily section of China crop, contain the tea saponin of having an appointment about 10%-15% in the tea oil, tea saponin is a kind of non-ionic type natural surface active agent of excellent property, not only there is the surface of good activity also to have outstanding biological activity, have stronger foaming, emulsification, dispersion, wetting action, and be subjected to the influence of water hardness hardly, so select this natural surface active agent substituted chemistry of tea saponin liquid detergent in the residuum tea dregs of rice of the applicant's exploration after oil expression.
Summary of the invention
Purpose of the present invention just provides a kind of natural phant liquid detergent, is used for the substituted chemistry washing composition.Another object of the present invention provides the preparation method of this natural phant liquid detergent.
The present invention's technical scheme of taking of dealing with problems is: a kind of natural phant liquid detergent, and it comprises following composition: 20-30 ° of B é tea saponin concentrated solution 60-85%, plant milk extract 5-15%, and surplus is solvent, and described ratio is weight percentage;
Described plant milk extract is wherein one or more extract of garden euphorbia herb, Japanese Honeysuckle, radix bupleuri, Herba Andrographis, ginger;
Described solvent is water or ethanol.
This natural phant liquid detergent can also comprise following composition: 20-30 ° of B é tea saponin concentrated solution 60-85%, garden euphorbia herb extract 5-15%, Rhizoma Zingiberis Recens extract 5-15%, and surplus is water, and described ratio is weight percentage.
The preparation method of described natural phant liquid detergent may further comprise the steps:
1. the preparation of tea saponin concentrated solution: be that raw material extracts wherein surface active ingredient with solvent with the tea seed kernel, through organic membrane filter, ultra-filtration membrane purifying, macroporous adsorbent resin is removed tannic acid, pigment objectionable impurities, and what vacuum concentration obtained having tea seed original flavor then contains the amber concentrated stoste of saponin;
Described extraction solvent can be edible ethanol, n-propyl alcohol, propyl carbinol, pure water is a kind of or several.
Described macroporous adsorbent resin is weak anion resin;
Described vacuum concentration is made and concentrated stoste is 20-30 ° of B é concentrated solution;
2. choosing raw material by the degree of above-mentioned prescription mixes.
Main component tea saponin concentrated solution among the present invention extracts from tea seed, and main component is tea saponin, is main tensio-active agent.China oil tea produces 68.39 ten thousand tons of the tea dregs of rice, utilize the surfactivity of its uniqueness can produce 200,000 tons of natural phant liquid detergents, owing to be that the residuum tea seed that squeezes behind the tea oil with the rural area is raw material production, belong to the agricultural-product comprehensive utilization, can not bring secondary pollution to environment and the mankind, can also drive farmer richness.
Oil tea saponin uses human body safety, biology department of Hunan Normal University, the Hu Shaohai of Hunan Prov. Labour Health Occupation Disease Dispensary etc. have reported and the oil tea saponin dry powder (its content＞85%) that extracts with Ethanol Method the SD rat has been carried out subchronic toxicity testing research from cake of camellia oleifera seeds.In report, laboratory animal male and female half and half, press the contrast of 100mg/kg, 200mg/g, 400mg/kg oil tea saponin group and distilled water totally 4 groups etc. hold and irritate stomach, 6d weekly, last 3 months, experimental result shows: oil tea saponin is little to the rat growthing development influence, and internal organs such as liver, renal function and the heart, liver, spleen, lung, kidney are not had obvious damage yet.The SD rat has been carried out per os, tested through skin acute toxicity and cumulative toxicity, and its per os LD 50 is 4466.8mg/kg, the 95% credible 2951mg/g～6824mg/kg that is limited to; Through skin LD50＞1000mg/kg, belong to low toxicity material.Oil tea saponin cumulative coefficient (k) is 5.3, and the only slight cumulative effect of tool of this material is described.
Various extracts in the present invention all are to adopt the traditional Chinese medicine extraction method to extract effective ingredients in plant, do not contain harmful toxic ingredient, and wherein garden euphorbia herb belongs to the Euphorbiaceae Euphorbia, have clearing heat and detoxicating, effect such as dampness removing is antipruritic, eczema, dermatitis, skin pruritus are controlled in external application; Japanese Honeysuckle property is sweet, and is cold, gas fragrance, and clearing away heat with drugs sweet in flavor and cold in nature and not injuring one's stomach, fragrance reaches thoroughly and can be eliminating evil, can dispelling wind-heat, also kind removing summer-heat blood poison; Radix bupleuri nature and flavor hardship is slightly cold, and evacuation is brought down a fever, and rises the easypro liver of sun; The Herba Andrographis bitter, cold in nature, clearing heat and detoxicating, cool blood, detumescence, eliminating dampness; Ginger nature and flavor suffering, tepor, relieving the exterior syndrome by diaphoresis, warming middle-JIAO to arrest vomiting, warm lung cough-relieving, solving toxin of fish and crab, antidote poison.Japanese Honeysuckle, radix bupleuri, Herba Andrographis, ginger all can go the sterilization of distinguishing the flavor of.Wherein any one or a few all can compatibility with above-mentioned plant milk extract.Choose said components and tea saponin concentrated liquid prescription, all are pure natural plant extract, toxic side effect is little, and raw material sources are very abundant and belong to renewable resources, have strong detergency, readily biodegradable, environmentally friendly, use characteristics such as safety, can realize suitability for industrialized production.
Adopt the tea saponin concentrated solution of method preparation of the present invention to remove objectionable impuritiess such as tannic acid, pigment, be the amber thickness transparent liquid of tea seed original flavor De Han Suds glucoside, active matter content 〉=28-36, oil removal rate 〉=90%, be aided with garden euphorbia herb, Japanese Honeysuckle, radix bupleuri, Herba Andrographis, Rhizoma Zingiberis Recens extract and prepare the natural phant liquid detergent, reaching country fully about the standard of manual dishwashing with washing composition, below is to detect index.According to GB9985-2000 " manual dishwashing washing composition " state compulsion standard detection:
Embodiment
Describe the present invention in detail with embodiment below.
The prescription of natural phant liquid detergent: 20-30 ° of B é tea saponin concentrated solution 60-85%, plant milk extract 5-15%, surplus is solvent.(described ratio is weight percentage)
Fill a prescription 60 kilograms of 1:30 ° of B é tea saponin concentrated solutions, 10 kilograms of garden euphorbia herb extracts, 30 kilograms of 75% ethanol.
Fill a prescription 60 kilograms of 2:30 ° of B é tea saponin concentrated solutions, 10 kilograms of Rhizoma Zingiberis Recens extracts, 30 kilograms of 75% ethanol.
Fill a prescription 85 kilograms of 3:20 ° of B é tea saponin concentrated solutions, 5 kilograms of Radix Bupleuri extracts, 10 kilograms of 75% ethanol.
Fill a prescription 85 kilograms of 4:20 ° of B é tea saponin concentrated solutions, 10 kilograms of Flos Lonicerae extracts, 5 kilograms of 75% ethanol.
Fill a prescription 70 kilograms of 5:28 ° of B é tea saponin concentrated solutions, 15 kilograms of Herba Andrographis extracts, 15 kilograms of 75% ethanol.
Fill a prescription 65 kilograms of 6:28 ° of B é tea saponin concentrated solutions, 10 kilograms of garden euphorbia herb extracts, 5 kilograms of Rhizoma Zingiberis Recens extracts, 15 kilograms of 75% ethanol.
Fill a prescription 75 kilograms of 7:28 ° of B é tea saponin concentrated solutions, 5 kilograms of garden euphorbia herb extracts, 2.5 kilograms of Rhizoma Zingiberis Recens extracts, 2.5 kilograms of Radix Bupleuri extracts, 2.5 kilograms of Flos Lonicerae extracts, 2.5 kilograms of Herba Andrographis extracts, 10 kilograms of 75% ethanol.
Fill a prescription 70 kilograms of 8:28 ° of B é tea saponin concentrated solutions, 5 kilograms of garden euphorbia herb extracting solutions, 5 kilograms of Rhizoma Zingiberis Recens extracts, 2.5 kilograms of Radix Bupleuri extracts, 2.5 kilograms of Flos Lonicerae extracts, 15 kilograms of 75% ethanol.
Fill a prescription 75 kilograms of 9:28 ° of B é tea saponin concentrated solutions, 7.5 kilograms of garden euphorbia herb extracting solutions, 5 kilograms of Rhizoma Zingiberis Recens extracts, 2.5 kilograms of Flos Lonicerae extracts, 10 kilograms in water.
The preparation method of natural phant liquid detergent may further comprise the steps:
1, the preparation of tea saponin concentrated solution: extract wherein surface active ingredient for the raw material water with the tea seed kernel, through organic membrane filter, ultra-filtration membrane purifying, the weakly-basic anion macroporous adsorbent resin is removed objectionable impuritiess such as tannic acid, pigment, and what vacuum concentration made that 20-30 ° of B é have a tea seed original flavor then contains the amber concentrated solution of saponin.
2, the preparation of garden euphorbia herb, Japanese Honeysuckle, radix bupleuri, Herba Andrographis, Rhizoma Zingiberis Recens extract.
The said extracted thing also can prepare: extracting method extracts garden euphorbia herb, Japanese Honeysuckle, radix bupleuri, Herba Andrographis, ginger water respectively routinely, finally makes powder.
3, choose raw material by the degree of above-mentioned prescription and mix, stir, sterilization, can.
Embodiment 1
Get 28 ° of B é and contain 85 kilograms of the concentrated stostes of saponin tea seed, 10 kilograms of garden euphorbia herb extracts, be transferred to 100 kilograms with 75% ethanol, mix the sterilization of pasteurize machine through the reaction stirring tank.Quality index is amber concentrated thickness stoste, active matter content 〉=30% of tea seed original flavor, detects saponin content with HPLC, through the can warehouse-in that is up to the standards.
Embodiment 2
Get 28 ° of B é and contain 70 kilograms of the concentrated stostes of saponin tea seed, 10 kilograms of garden euphorbia herb extracts, 5 kilograms of Rhizoma Zingiberis Recens extracts are transferred to 100 kilograms with 75% ethanol, mix the sterilization of pasteurize machine through the reaction stirring tank.Quality index is the amber concentrated thickness stoste of tea seed original flavor, and active matter content 〉=28% detects saponin content with HPLC, through the can warehouse-in that is up to the standards.
Can in formula range, produce on demand, not describe one by one herein.
Claims (5)
1. natural phant liquid detergent, it consists of: 20-30 ° of B é tea saponin concentrated solution 60-85%, plant milk extract 5-15%, surplus is solvent, described ratio is weight percentage;
Described plant milk extract is made up of garden euphorbia herb extract, Rhizoma Zingiberis Recens extract;
Described solvent is water or ethanol.
2. natural phant liquid detergent, it consists of: 20-30 ° of B é tea saponin concentrated solution 60-85%, plant milk extract 5-15%, surplus is solvent, described ratio is weight percentage;
Described plant milk extract is made up of garden euphorbia herb extract, Rhizoma Zingiberis Recens extract, Flos Lonicerae extract;
Described solvent is water or ethanol.
3. natural phant liquid detergent, it consists of: 20-30 ° of B é tea saponin concentrated solution 60-85%, plant milk extract 5-15%, surplus is solvent, described ratio is weight percentage;
Described plant milk extract is made up of garden euphorbia herb extract, Rhizoma Zingiberis Recens extract, Radix Bupleuri extract, Flos Lonicerae extract;
Described solvent is water or ethanol.
4. natural phant liquid detergent, it consists of: 20-30 ° of B é tea saponin concentrated solution 60-85%, plant milk extract 5-15%, surplus is solvent, described ratio is weight percentage;
Described plant milk extract is made up of garden euphorbia herb extract, Rhizoma Zingiberis Recens extract, Flos Lonicerae extract, Radix Bupleuri extract, Herba Andrographis extract;
Described solvent is water or ethanol.
5. the preparation method of a natural phant liquid detergent may further comprise the steps:
1. the preparation of tea saponin concentrated solution: be that raw material extracts wherein surface active ingredient with solvent with the tea seed kernel, through organic membrane filter, ultra-filtration membrane purifying, macroporous adsorbent resin is removed tannic acid, pigment objectionable impurities, and what vacuum concentration obtained having tea seed original flavor then contains the amber concentrated stoste of saponin;
Described extraction solvent can be edible ethanol, n-propyl alcohol, propyl carbinol, pure water is a kind of or several;
Described macroporous adsorbent resin is weak anion resin;
Described vacuum concentration is made 20-30 ° of B é concentrated solution;
2. choosing raw material by the degree in aforesaid right requirement 1 or 2 mixes.
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| CN 201110187043 CN102268334B (en) | 2011-07-01 | 2011-07-01 | Natural plant cleanser essence |
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| CN 201110187043 CN102268334B (en) | 2011-07-01 | 2011-07-01 | Natural plant cleanser essence |
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| CN102268334B true CN102268334B (en) | 2013-09-25 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103266025B (en) * | 2013-05-28 | 2014-07-16 | 上海艳紫化工科技有限公司 | Ginger detergent |
| CN103351957B (en) * | 2013-06-28 | 2015-06-17 | 山东科技大学 | Ginger detergent processed at ultrahigh pressure and preparation method thereof |
| CN103343064A (en) * | 2013-07-22 | 2013-10-09 | 孙佳丽 | Fading resistant strong-detergency laundry detergent |
| CN103756808B (en) * | 2014-01-19 | 2016-09-07 | 福州喜自然生物科技有限公司 | A kind of natural washing liquid of preservative free and preparation method thereof |
| CN104974868A (en) * | 2014-04-13 | 2015-10-14 | 海南大学 | Pollution-free vegetable and fruit pesticide residue removal agent |
| CN104212647A (en) * | 2014-09-11 | 2014-12-17 | 陈育烨 | Preparation method of pure natural tea seed detergent |
| CN104263541A (en) * | 2014-09-19 | 2015-01-07 | 吴伟銮 | Tea pulp powder detergent and preparation method thereof |
| CN104277929A (en) * | 2014-09-26 | 2015-01-14 | 青岛康和食品有限公司 | Easy-to-blister liquid detergent |
| CN104479889A (en) * | 2014-11-15 | 2015-04-01 | 陈育烨 | Preparation method of tea seed cleanser |
| CN107365636A (en) * | 2016-05-11 | 2017-11-21 | 张永强 | A kind of production method of liquid detergent |
| CN106590951A (en) * | 2016-10-19 | 2017-04-26 | 湖南古洞春茶业有限公司 | Big-leaf tea extract detergent and preparation method thereof |
| CN109749876A (en) * | 2017-11-01 | 2019-05-14 | 鼎汉泰捷科技（武汉）有限公司 | A kind of Novel detergent formula and preparation method |
| CN107955728B (en) * | 2017-12-13 | 2020-04-14 | 安徽大学 | Edible detergent containing natural plant saponin component and preparation method thereof |
| CN108517260A (en) * | 2018-03-28 | 2018-09-11 | 贵州大学 | A kind of environmental protection liquid detergent |
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Denomination of invention: Natural plant cleanser essence Effective date of registration: 20191220 Granted publication date: 20130925 Pledgee: Agricultural Development Bank of China Chenxi County sub branch Pledgor: Hunan Hanqing Biological Co., Ltd. Registration number: Y2019980001187 |