CN102242009B - Metal rolling oil and preparation method thereof - Google Patents
Metal rolling oil and preparation method thereof Download PDFInfo
- Publication number
- CN102242009B CN102242009B CN 201010172489 CN201010172489A CN102242009B CN 102242009 B CN102242009 B CN 102242009B CN 201010172489 CN201010172489 CN 201010172489 CN 201010172489 A CN201010172489 A CN 201010172489A CN 102242009 B CN102242009 B CN 102242009B
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- CN
- China
- Prior art keywords
- rolling oil
- metal rolling
- oil
- rolling
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010731 rolling oil Substances 0.000 title claims abstract description 27
- 239000002184 metal Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 10
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012964 benzotriazole Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 7
- -1 Phosphoric acid trimethylbenzene phenolic ester Chemical class 0.000 claims description 7
- 239000002199 base oil Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 abstract description 13
- 239000002994 raw material Substances 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 5
- 238000005461 lubrication Methods 0.000 abstract description 4
- 238000000137 annealing Methods 0.000 abstract description 3
- 238000005097 cold rolling Methods 0.000 abstract description 3
- 231100000241 scar Toxicity 0.000 abstract description 3
- 239000003921 oil Substances 0.000 abstract description 2
- 208000032544 Cicatrix Diseases 0.000 abstract 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 abstract 1
- 230000003749 cleanliness Effects 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000037387 scars Effects 0.000 abstract 1
- 238000012545 processing Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000005069 Extreme pressure additive Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses metal rolling oil and a preparation method thereof. Under a special temperature condition, the metal rolling oil is prepared by mixing and stirring the following raw materials by weight percent according to a certain sequence: 84-94.9% of basic oil, 0.1-1% of benzotriazole, 3.0-11% of dioctyl adipate, 0.5-1.5% of antioxidant 246, 1-1.5% of isomerous tetradecanol and 0.5-2% of o-tolyl phosphate. The metal rolling oil is prepared by using quality raw materials and an advanced formula as well as a simple method, thereby meeting good lubricity, cooling property and annealing cleanliness in the machining process; and the machined product has good radiance and no rolling scars. Compared with the products in the same industry, the metal rolling oil disclosed by the invention has good cost performance, is suitable for technological lubrication of a large and medium cold rolling unit, and especially for plastic rolling machines and cold rolling units.
Description
Technical field
The present invention relates to a kind of metal rolling oil and preparation method thereof, specifically relate to a kind of high saponification value metal rolling oil and preparation method thereof.
Background technology
Rolling technology needs a kind of water-soluble rolling emulsion, plays the Cooling and Lubricator effect, because the main component of rolling emulsion is water, has good cooling performance, and a small amount of oil ingredient can play good lubrication again.Present rolling technology all requires at a high speed and high yield, and is therefore also more and more higher for the requirement of rolling emulsion.ROLLING OIL is the mother liquor for the configuration rolling emulsion, is generally to be configured to rolling emulsion after ROLLING OIL is mixed by certain proportioning with water during use.
At present, the lack of lubrication of known ROLLING OIL to workpiece easily causes workpiece to run over and injure, and rolling workpiece luminance brightness does not reach most of clients' requirement, and rolling efficiency is low, and the frequent replacing of ROLLING OIL causes tooling cost to increase.
Summary of the invention
In order to overcome defects, the invention provides a kind of metal rolling oil and preparation method thereof, metal rolling oil of the present invention is a kind of high saponification value metal rolling oil, can process the workpiece of the materials such as steel, carbon steel, have good oilness, cooling and annealing cleanness, product luminance brightness after processing is good, without rolling scar.
The present invention for the technical scheme that solves its technical problem and adopt is:
A kind of metal rolling oil, in total weight percent, each component proportion is as follows:
Base oil: 84～94.9%;
Benzotriazole: 0.1～1%;
Octyl adipate: 3.0～11%;
Oxidation inhibitor 246:0.5～1.5%;
Isomery tetradecyl alcohol: 1～1.5%;
Phosphoric acid trimethylbenzene phenolic ester: 0.5～2%.
Wherein, base oil and Octyl adipate lubricate; Benzotriazole plays antioxygen, anti-variable color effect; The isomery tetradecyl alcohol plays stabilization, can be effectively anticorrosion, anti-metamorphic, antibacterium; Phosphoric acid trimethylbenzene phenolic ester is anti-combustion and extreme-pressure additive, can protect the workpiece in the course of processing and safe operating environment can be provided.
A kind of preparation method of metal rolling oil, carry out in the steps below:
1., add base oil, benzotriazole and Octyl adipate in container, heat and stir;
2., stopped heating, add oxidation inhibitor 246 and isomery tetradecyl alcohol, and stir;
3., add phosphoric acid trimethylbenzene phenolic ester, and stir, make described metal rolling oil.
Step 1. in, heating and temperature control is at 60～70 ℃, churning time is 25～35min.
Step 2. in, churning time is 5～15min.
Step 3. in, the whole step 3. temperature of process is controlled at 45～55 ℃, churning time is 1～10min.
The invention has the beneficial effects as follows: metal rolling oil of the present invention prepares by simple method, and the raw material and the proportioning thereof that adopt all carried out the optimization consideration, in order to be effective, can make minimization of cost, has improved the competitiveness of product in market; Base oil in raw material of the present invention and Octyl adipate can satisfy needed lubricity in the course of processing; extreme-pressure additive phosphoric acid trimethylbenzene phenolic ester in raw material can be protected the workpiece in the course of processing, and the benzotriazole in raw material, oxidation inhibitor 246 and isomery tetradecyl alcohol can make metal rolling oil of the present invention in use keep stable performance.To sum up, metal rolling oil of the present invention adopts raw material and the advanced formula of high-quality, and made by simple method, not only can satisfy oilness good in the course of processing, cooling and annealing cleanness, product luminance brightness after processing is good, without rolling scar, and metal rolling oil of the present invention and product of the same trade to compare cost performance good, be applicable to the technological lubrication of big-and-middle-sized cold rolling unit, being specially adapted to can north milling train and tandem mills.
Embodiment
The formula of various embodiments of the present invention sees the following form 1:
Table 1 (unit: weight percent %)
According to above-mentioned formula, preparation method of the present invention is as follows:
A kind of preparation method of metal rolling oil, carry out in the steps below:
1., add base oil, benzotriazole and Octyl adipate in container, heat and stir, heating and temperature control is at 60～70 ℃, churning time is 25～35min;
2., stopped heating, add oxidation inhibitor 246 and isomery tetradecyl alcohol, and stir, churning time is 5～15min;
3., add phosphoric acid trimethylbenzene phenolic ester, and stir, the whole step 3. temperature of process is controlled at 45～55 ℃, churning time is 1～10min, makes described metal rolling oil.
Claims (2)
1. a metal rolling oil, is characterized in that, in total weight percent, each component proportion is as follows:
Base oil: 84～94.9%;
Benzotriazole: 0.1～1%;
Octyl adipate: 3.0～11%;
Oxidation inhibitor 246:0.5～1.5%;
Isomery tetradecyl alcohol: 1～1.5%;
Phosphoric acid trimethylbenzene phenolic ester: 0.5～2%.
2. the preparation method of a metal rolling oil as claimed in claim 1, is characterized in that, carries out in the steps below:
1., add base oil, benzotriazole and Octyl adipate in container, heat and stir;
2., stopped heating, add oxidation inhibitor 246 and isomery tetradecyl alcohol, and stir;
3., add phosphoric acid trimethylbenzene phenolic ester, and stir, make described metal rolling oil;
Step 1. in, heating and temperature control is at 60～70 ℃, churning time is 25～35min;
Step 2. in, churning time is 5～15min;
Step 3. in, the whole step 3. temperature of process is controlled at 45～55 ℃, churning time is 1～10min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010172489 CN102242009B (en) | 2010-05-12 | 2010-05-12 | Metal rolling oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010172489 CN102242009B (en) | 2010-05-12 | 2010-05-12 | Metal rolling oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102242009A CN102242009A (en) | 2011-11-16 |
| CN102242009B true CN102242009B (en) | 2013-06-05 |
Family
ID=44960260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010172489 Expired - Fee Related CN102242009B (en) | 2010-05-12 | 2010-05-12 | Metal rolling oil and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN102242009B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590843A (en) * | 2016-11-30 | 2017-04-26 | 广州科卢斯流体科技有限公司 | Precision stainless steel band cold-rolling rolling oil |
| CN111440656B (en) * | 2020-05-08 | 2022-08-19 | 昆山道普润滑科技有限公司 | Chlorine-free long rust-proof carbon steel pipe rolling oil |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054172B1 (en) * | 1980-12-12 | 1985-06-05 | Sms Schloemann-Siemag Aktiengesellschaft | Method of and arrangement for rolling stress-free strip |
| CN101560433A (en) * | 2009-05-11 | 2009-10-21 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
| CN102660357A (en) * | 2012-04-26 | 2012-09-12 | 北京科技大学 | Calendaring copper foil rolled oil and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53127352A (en) * | 1977-04-14 | 1978-11-07 | Kyodo Yushi | Hot rolling lubricant for steel material |
| JPH08143881A (en) * | 1994-11-24 | 1996-06-04 | Nippon Steel Corp | Lubricant composition for hot rolling of steel material |
-
2010
- 2010-05-12 CN CN 201010172489 patent/CN102242009B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054172B1 (en) * | 1980-12-12 | 1985-06-05 | Sms Schloemann-Siemag Aktiengesellschaft | Method of and arrangement for rolling stress-free strip |
| CN101560433A (en) * | 2009-05-11 | 2009-10-21 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
| CN102660357A (en) * | 2012-04-26 | 2012-09-12 | 北京科技大学 | Calendaring copper foil rolled oil and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN102242009A (en) | 2011-11-16 |
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Address after: Qiandeng Town Kunshan city Suzhou Shipu new house Road No. 266 of 215300 cities in Jiangsu Province Patentee after: BUHMWOO CHEMICAL (KUNSHAN) CO.,LTD. Address before: 215343 Jiangsu province Kunshan City Qiandeng Town Shipu Street No. 988 Lane Road land Patentee before: KUNSHAN XINYU CHEMICAL Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130605 |