CN102228178A - Granular substance containing calcium, iron, zinc and selenium - Google Patents
Granular substance containing calcium, iron, zinc and selenium Download PDFInfo
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- CN102228178A CN102228178A CN2011101644318A CN201110164431A CN102228178A CN 102228178 A CN102228178 A CN 102228178A CN 2011101644318 A CN2011101644318 A CN 2011101644318A CN 201110164431 A CN201110164431 A CN 201110164431A CN 102228178 A CN102228178 A CN 102228178A
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- zinc
- calcium
- selenium
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- 239000011669 selenium Substances 0.000 title claims abstract description 27
- 229910052711 selenium Inorganic materials 0.000 title claims abstract description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract description 19
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title abstract description 17
- 239000011575 calcium Substances 0.000 title abstract description 17
- 229910052791 calcium Inorganic materials 0.000 title abstract description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract description 16
- 229910052742 iron Inorganic materials 0.000 title abstract description 10
- 239000011701 zinc Substances 0.000 title abstract description 10
- 229910052725 zinc Inorganic materials 0.000 title abstract description 10
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title abstract description 9
- 239000000126 substance Substances 0.000 title abstract description 9
- 229940091258 selenium supplement Drugs 0.000 claims abstract description 27
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 22
- 244000248349 Citrus limon Species 0.000 claims abstract description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 19
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims abstract description 14
- 235000011086 calcium lactate Nutrition 0.000 claims abstract description 14
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 12
- 229930006000 Sucrose Natural products 0.000 claims abstract description 12
- 235000013925 ferrous lactate Nutrition 0.000 claims abstract description 12
- 235000011478 zinc gluconate Nutrition 0.000 claims abstract description 12
- 239000004375 Dextrin Substances 0.000 claims abstract description 11
- 229920001353 Dextrin Polymers 0.000 claims abstract description 11
- 235000010358 acesulfame potassium Nutrition 0.000 claims abstract description 11
- 235000019425 dextrin Nutrition 0.000 claims abstract description 11
- 229920003081 Povidone K 30 Polymers 0.000 claims abstract description 10
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000011781 sodium selenite Substances 0.000 claims abstract description 10
- 229960001471 sodium selenite Drugs 0.000 claims abstract description 10
- 235000015921 sodium selenite Nutrition 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 22
- 239000005720 sucrose Substances 0.000 claims description 11
- 235000015165 citric acid Nutrition 0.000 claims description 10
- 239000000284 extract Substances 0.000 claims description 10
- 238000012056 up-stream process Methods 0.000 claims description 9
- 229960005069 calcium Drugs 0.000 abstract description 16
- 239000000047 product Substances 0.000 abstract description 15
- 239000001527 calcium lactate Substances 0.000 abstract description 7
- 229960002401 calcium lactate Drugs 0.000 abstract description 7
- 235000019640 taste Nutrition 0.000 abstract description 7
- 229960003284 iron Drugs 0.000 abstract description 6
- DKKCQDROTDCQOR-UHFFFAOYSA-L Ferrous lactate Chemical compound [Fe+2].CC(O)C([O-])=O.CC(O)C([O-])=O DKKCQDROTDCQOR-UHFFFAOYSA-L 0.000 abstract description 5
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 abstract description 5
- 239000004225 ferrous lactate Substances 0.000 abstract description 5
- 229940037907 ferrous lactate Drugs 0.000 abstract description 5
- 239000011670 zinc gluconate Substances 0.000 abstract description 5
- 229960000306 zinc gluconate Drugs 0.000 abstract description 5
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 abstract description 4
- 206010070840 Gastrointestinal tract irritation Diseases 0.000 abstract description 4
- 239000000619 acesulfame-K Substances 0.000 abstract description 4
- 229960004793 sucrose Drugs 0.000 abstract description 2
- 239000013589 supplement Substances 0.000 abstract 2
- 239000002552 dosage form Substances 0.000 abstract 1
- 210000004211 gastric acid Anatomy 0.000 abstract 1
- 239000002366 mineral element Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 9
- 235000010755 mineral Nutrition 0.000 description 9
- 239000011707 mineral Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229960004998 acesulfame potassium Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 210000004051 gastric juice Anatomy 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000020985 whole grains Nutrition 0.000 description 2
- 206010000087 Abdominal pain upper Diseases 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- VNYMQKINNCZIQN-UHFFFAOYSA-M [O-][Se](O)=O.[Na+].[SeH2] Chemical compound [O-][Se](O)=O.[Na+].[SeH2] VNYMQKINNCZIQN-UHFFFAOYSA-M 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- CPEPWXXWVALFCE-UHFFFAOYSA-J dicalcium 2-hydroxypropanoate Chemical compound [Ca+2].[Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O CPEPWXXWVALFCE-UHFFFAOYSA-J 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 230000003862 health status Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229940029985 mineral supplement Drugs 0.000 description 1
- 235000020786 mineral supplement Nutrition 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- -1 stir and block Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229940091251 zinc supplement Drugs 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The invention discloses a granular substance containing calcium, iron, zinc and selenium. The granular substance is prepared from 2520 to 3080 parts by weight of calcium lactate, 54 to 66 parts by weight of zinc gluconate, 36 to 44 parts by weight of ferrous lactate, 0.0405 to 0.0495 parts by weight of sodium selenite, 1494 to 1826 parts by weight of cane sugar, 186.7 to 228.2 parts by weight of dextrin, 90 to 110 parts by weight of citric acid, 81 to 99 parts by weight of Acesulfame-K, 22.5 to 27.5 parts by weight of povidone K30, 13.5 to 16.5 parts by weight of lemon essence and 2.25 to 2.75 parts by weight of lemon yellow. The granular substance as a supplement supplying calcium, iron, zinc and selenium adopts calcium lactate, organic zinc and organic selenium as raw materials, does not react with gastric acid and does not produce a gastrointestinal irritation, thus is suitable for all people. The granular substance has a good taste and a convenient dosage form. Compared with other similar products, the granular substance containing calcium, iron, zinc and selenium has a greatly improved taking rate and a complete completion rate in a mineral element supplement cycle for an adult.
Description
Technical field the present invention relates to a kind of health products, is a kind of replenishing the calcium and micro-health products specifically.
Background technology calcium is the macroelement of needed by human, and iron, zinc, selenium are the mineral matter elements that human body needs.Human body is different because of the difference at age to the demand of calcium, iron, zinc, selenium.
The adult lacks mineral matter elements such as calcium, iron, zinc, selenium can influence normal physiological function, causes being in for a long time sub-health state, and severe patient can cause multiple physiological illness.Through investigation, the cycle (being generally 3 months) at replenishing mineral matter element, only have 61% adult can adhere to taking finishing, only have 41% adult in an additional cycle fully on request daily dose take.All the other all do not finish an additional cycle because of a variety of causes.Be directed to adult physiology, psychological characteristics, the taste that mineral matter element is replenished goods improves with the mode of taking, and can easier additional crowd accept, and improves the rate of taking greatly.
Most health products react and just can become the particle calcium that is easy to absorb with the replenishers of calcium carbonate as calcium, it and hydrochloric acid in gastric juice, and groups of people have enteron aisle to stimulate, particularly children have the part children taking product of replenishing the calcium calciferous, upset,gastro-intestinal, stomach-ache causes can not continue to take.
We have carried out a large amount of technical recipe research in this field, adjust the optimum prescription of ferro-calcium-zinc-selenium particle, with the most acceptant taste, the instructions of taking that no enteron aisle stimulates and the most acceptant granule of adult is taken after mixing it with water is led over the goods of commercially available other additional calcium, iron, zinc, selenium minerals prime element.
Summary of the invention the object of the present invention is to provide a kind of ferro-calcium-zinc-selenium particle, its features good taste, no gastrointestinal irritation, can improve the acceptance level of the fastidious adult of adult and part to the mineral matter element supplementing preparation, make most of crowd that need replenish mineral matter element easily finish additional process, make the fastidious adult of part be easier to accept calcium and replenish goods.
Granule of the present invention is made by the raw material of following parts by weight:
2520～3080 parts of calcium lactates, 54～66 parts of zinc gluconates, 36～44 parts of ferrous lactates, 0.0405～0.0495 part of sodium selenite, 1494～1826 parts of sucrose, 186.7～228.2 parts in dextrin, 90～110 parts of citric acids, 81～99 parts of acesulfame potassiums, 3022.5～27.5 parts of 30 POVIDONE K 30 BP/USPs, 13.5～16.5 parts of lemon extracts, lemon yellow 2.25～2.75 parts.
The preferred version of above-mentioned prescription is:
2750 parts of calcium lactates, 59 parts of zinc gluconates, 39 parts of ferrous lactates, 0.046 part of sodium selenite, 1650 parts of sucrose, 206 parts in dextrin, 101 parts of citric acids, 89 parts of acesulfame potassiums, 3024.5 parts of 30 POVIDONE K 30 BP/USPs, 15.5 parts of lemon extracts, lemon yellow 2.55 parts.
The effect such as the table 1. of above-mentioned each component
The effect of table 1 batching
| Sequence number | Title | Effect |
| 1 | Calcium lactate | Calcium complement agent |
| 2 | Zinc gluconate | Zinc supplements |
| 3 | Ferrous lactate | Supplements-iron |
| 4 | Sodium selenite | Selenium supplement |
| 5 | Sucrose | Filler, flavor enhancement |
| 6 | Dextrin | Filler, disintegrant |
| 7 | Citric acid | Flavor enhancement |
| 8 | Acesulfame potassium | Flavor enhancement |
| 9 | 30 POVIDONE K 30 BP/USP 30 | Adhesive |
| 10 | Lemon extract | Flavor enhancement |
| 11 | Lemon yellow | Toner |
Advantage of the present invention:
1, calcium complement agent of the present invention adopts calcium lactate, organic calcium does not react with hydrochloric acid in gastric juice, calcium carbonate and hydrochloric acid in gastric juice reaction just can become particle calcium, have enteron aisle to stimulate, calcium lactate of the present invention does not almost have GI irritation, other component zinc gluconate, it is organic zinc, ferrous lactate is organic iron, does not have GI irritation, is fit to everyone.
2, take at the adult more than 18 years old, the success rate of finishing the additional cycle of an additional mineral matter element significantly improves.
Select 300 health adults more than 18 years old,, divide three groups respectively in enterprises and institutions, colleges and universities, every group 100 people, 30.1 years old mean age of three groups, 30.2 years old, 30.3 years old, three groups of men and women are 1: 1 than, age, health status do not have difference between group, have comparativity.Required to take product of the present invention, ferro-calcium-zinc-selenium particle (green strong garden, Beijing bio tech ltd product), ferro-calcium-zinc-selenium particle (Wuhan hundred reason kings medicine Co., Ltds) respectively each 3 months.The results are shown in Table 2.
Table 2 product of the present invention and commercially available other products are taken the rate contrast table
Through the contrast experiment, product of the present invention and commercially available calcium complement agent are taken contrast, and the result shows, ferro-calcium-zinc-selenium particle of the present invention to the additional mineral matter element of being grown up take rate in the cycle, completion rate has significantly than other two kinds of products fully increases.
3, compare with commercially available other similar products and have following aspect advantage:
(1) special taste:
This product taste is unique " citrus scented ", is the more acceptant tastes of most adults.
(2) take mode:
Formulation in the mineral supplement of difference and other brand, the granule that formula for a product of the present invention is designed to more easily take only needs get final product with mixing in water for oral taking, more easily takes.
(3) smell:
The essence that this prescription adds has slight volatilization, and opening bag promptly has delicate fragrance, and the effect that promotes appetite, improves mood is arranged.
(4) outward appearance:
It is soft faint yellow that the ferro-calcium-zinc-selenium uniform particles that this prescription is made, gently crisp, particle show, and is the tone of releiving, and look most of crowds easily accept and like.
The specific embodiment:
Embodiment 1:
With the following prescription preparation ferro-calcium-zinc-selenium particle that feeds intake:
2600 parts of calcium lactates, 55 parts of zinc gluconates, 37 parts of ferrous lactates, 0.042 part of sodium selenite, 1550 parts of sucrose, 190 parts in dextrin, 93 parts of citric acids, 83 parts of acesulfame potassiums, 3023 parts of 30 POVIDONE K 30 BP/USPs, 14 parts of lemon extracts, lemon yellow 2.35 parts.
After above prescription fed intake, the ferro-calcium-zinc-selenium particle reached every specification requirement of defined in " multidimensional that board ferro-calcium-zinc-selenium granular mass standard ".
Embodiment 2:
With the following prescription preparation ferro-calcium-zinc-selenium particle that feeds intake:
2750 parts of calcium lactates, 59 parts of zinc gluconates, 39 parts of ferrous lactates, 0.046 part of sodium selenite, 1650 parts of sucrose, 206 parts in dextrin, 101 parts of citric acids, 89 parts of acesulfame potassiums, 3024.5 parts of 30 POVIDONE K 30 BP/USPs, 15.5 parts of lemon extracts, lemon yellow 2.55 parts.
After above prescription fed intake, the ferro-calcium-zinc-selenium particle reached every specification requirement of defined in " multidimensional that board ferro-calcium-zinc-selenium granular mass standard ".
Embodiment 3:
With the following prescription preparation ferro-calcium-zinc-selenium particle that feeds intake:
3020 parts of calcium lactates, 63 parts of zinc gluconates, 42 parts of ferrous lactates, 0.0480 part of sodium selenite, 1800 parts of sucrose, 225 parts in dextrin, 108 parts of citric acids, 96 parts of acesulfame potassiums, 3026 parts of 30 POVIDONE K 30 BP/USPs, 15.5 parts of lemon extracts, lemon yellow 2.6 parts.
After above prescription fed intake, the ferro-calcium-zinc-selenium particle reached every specification requirement of defined in " multidimensional that board ferro-calcium-zinc-selenium granular mass standard ".
Above-mentioned raw materials, auxiliary material manufacturer
| Sequence number | The name of an article | The place of production |
| 1 | Calcium lactate | Jia Kang source, Beijing development in science and technology Co., Ltd |
| 2 | Zinc gluconate | Zhangshu City is preced with a food additives Co., Ltd |
| 3 | Ferrous lactate | Jia Kang source, Beijing development in science and technology Co., Ltd |
| 4 | Sodium selenite | Henan Province can chemical industry Co., Ltd |
| 5 | Sucrose | Inner Mongol Leng Shan sugar industry Co., Ltd |
| 6 | Dextrin | Qingdao Hai Daer starch Co., Ltd |
| 7 | Citric acid | Nanchang bright auspicious chemical industry Co., Ltd |
| 8 | Acesulfame potassium | Tianning Flavor ﹠ Fragrance (Jiangsu) Co., Ltd. |
| 9 | 30 POVIDONE K 30 BP/USP 30 | YingKou AODA Pharmaceutical CO.,LTD |
| 10 | Lemon extract | They peaceful limited public affairs of spices (Jiangsu) |
| 11 | Lemon yellow | Xi'an rich inferior chemical industry Co., Ltd |
Specific embodiment is as follows:
1, preprocessing raw material and auxiliary material
Get corresponding supplementary material from storehouse, check the lot number and the inspection report of each supplementary material, qualified supplementary material can put into production, and the defective supplementary material of all microorganism checkings never allows to put into production.
Sucrose is pulverized, and sieves; Calcium lactate sieves.
The preparation of look liquid: sodium selenite, lemon yellow dissolving in proportion stir.
2, granulate
Take by weighing calcium lactate, ferrous lactate, zinc gluconate, sucrose, dextrin, acesulfame potassium, citric acid by formula rate, place granulator.Do and mix to mixing;
Add look liquid wet mixing evenly in proportion in above-mentioned material after, add adhesive, stir and block, softwood is made in chopping; Softwood delivered to wave under the granulator, granulate.The particle that makes is dry, whole grain to the drying machine.Particle behind the whole grain is packed in the mixer, add lemon extract in proportion and carry out always mixing, mix to particle and auxiliary material.
3, pack
Confirm that the bag chartered plane is intact, after the cleaning, particle is added material bin, adjust bag and heavily heavily pack for the regulation bag, every bag of specification is 5 grams, and inner packaging material is a composite membrane.
4, check
Be responsible for product is tested by quality management department, enter the external packing flow process after qualified.
5, packing, warehouse-in
Packing is labelled, cases, is put in storage.
Claims (2)
1. ferro-calcium-zinc-selenium particle, it is characterized in that: it is made by the raw material of following parts by weight:
2520～3080 parts of calcium lactates, 54～66 parts of zinc gluconates, 36～44 parts of ferrous lactates, 0.0405～0.0495 part of sodium selenite, 1494～1826 parts of sucrose, 186.7～228.2 parts in dextrin, 90～110 parts of citric acids, 81～99 parts of acesulfame potassiums, 3022.5～27.5 parts of 30 POVIDONE K 30 BP/USPs, 13.5～16.5 parts of lemon extracts, lemon yellow 2.25～2.75 parts.
2. according to the described ferro-calcium-zinc-selenium particle of claim 1, it is characterized in that: it is made by the raw material of following parts by weight:
2750 parts of calcium lactates, 59 parts of zinc gluconates, 39 parts of ferrous lactates, 0.046 part of sodium selenite, 1650 parts of sucrose, 206 parts in dextrin, 101 parts of citric acids, 89 parts of acesulfame potassiums, 3024.5 parts of 30 POVIDONE K 30 BP/USPs, 15.5 parts of lemon extracts, lemon yellow 2.55 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110164431 CN102228178B (en) | 2011-06-18 | 2011-06-18 | Granular substance containing calcium, iron, zinc and selenium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110164431 CN102228178B (en) | 2011-06-18 | 2011-06-18 | Granular substance containing calcium, iron, zinc and selenium |
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| Publication Number | Publication Date |
|---|---|
| CN102228178A true CN102228178A (en) | 2011-11-02 |
| CN102228178B CN102228178B (en) | 2013-04-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110164431 Active CN102228178B (en) | 2011-06-18 | 2011-06-18 | Granular substance containing calcium, iron, zinc and selenium |
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| Country | Link |
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| CN102613470A (en) * | 2012-03-29 | 2012-08-01 | 常熟市珍门麦芽糖厂 | Dish juice with effects of calcium supplement and health protection |
| CN103417489A (en) * | 2012-05-16 | 2013-12-04 | 黄华 | Calcium gluconate zinc gluconate particulate agent preparation method |
| CN108185508A (en) * | 2018-01-08 | 2018-06-22 | 中国烟草总公司广东省公司 | A kind of tobacco rich in selenium is brewed containing product |
| CN108185507A (en) * | 2018-01-04 | 2018-06-22 | 中国烟草总公司广东省公司 | A kind of tobacco chewable tablets rich in selenium |
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| CN102613470A (en) * | 2012-03-29 | 2012-08-01 | 常熟市珍门麦芽糖厂 | Dish juice with effects of calcium supplement and health protection |
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| CN108185507A (en) * | 2018-01-04 | 2018-06-22 | 中国烟草总公司广东省公司 | A kind of tobacco chewable tablets rich in selenium |
| CN108185507B (en) * | 2018-01-04 | 2020-12-08 | 中国烟草总公司广东省公司 | Selenium-rich tobacco chewable tablet |
| CN108185508A (en) * | 2018-01-08 | 2018-06-22 | 中国烟草总公司广东省公司 | A kind of tobacco rich in selenium is brewed containing product |
| CN108185508B (en) * | 2018-01-08 | 2020-11-20 | 中国烟草总公司广东省公司 | Selenium-rich tobacco brewing product |
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| CN102228178B (en) | 2013-04-17 |
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