CN102208554B - Substrate for flexible luminous device and preparation method thereof - Google Patents
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Abstract
The invention discloses a substrate for a flexible luminous device. The substrate comprises a flexible substrate and a conductive layer, and the flexible substrate and the conductive layer are formed in one of the following two modes: (1) the flexible substrate is adhesive to be doubly cured, the conductive layer is a thin layer carbon nano tube, and inorganic luminous nano particles are filled into gaps of the thin layer carbon nano tube; and (2) the flexible substrate is inorganic luminous nano particle-doped adhesive to be doubly cured, the conductive layer is a thin layer carbon nano tube, and the inorganic luminous nano particle-doped adhesive to be doubly cured is filled into gaps of the thin layer carbon nano tube, wherein the adhesive to be doubly cured comprises an ultraviolet curing and thermal curing system, an ultraviolet curing and microwave curing system, an ultraviolet curing and anaerobic curing system and an ultraviolet curing and electron beam curing system.
Description
Technical field
The present invention relates to the organic optoelectronic technical field, be specifically related to a kind of flexible luminescent device substrate and preparation method thereof.
Background technology
Photoelectron technology is the very high industry of scientific and technological content that develops rapidly after microelectric technique.Along with the fast development of photoelectron technology, photoelectron products such as solar cell, optical image sensor, flat-panel screens, thin film transistor (TFT) are all full-fledged gradually, and they have improved people's life greatly.Simultaneously, opto-electronic information technology has also been created growing great market in the extensive use of social life every field.Developed country all the optoelectronic information industry as one of field of giving priority to, the competition of the field of opto-electronic information just launches at world wide.
Photoelectron technology is the very high industry of scientific and technological content that develops rapidly after microelectric technique.Along with the fast development of photoelectron technology, photoelectron products such as solar cell, optical image sensor, flat-panel screens, thin film transistor (TFT) are all full-fledged gradually, and they have improved people's life greatly.Simultaneously, opto-electronic information technology has also been created growing great market in the extensive use of social life every field.Developed country all the optoelectronic information industry as one of field of giving priority to, the competition of the field of opto-electronic information just launches at world wide.
Organic optoelectronic device mostly is that preparation is at rigid substrates (on glass or silicon chip), though they have good device performance, anti-vibration at present, shock proof ability a little less than, weight is heavier relatively, and it is very not convenient to carry, and is very restricted in the application of some occasion.People begin to attempt to be deposited on organic optoelectronic device on the flexible base, board rather than on the rigid substrates.
With flexible base, board replace the benefit of rigid substrates be product lighter, be difficult for broken, institute takes up space little and be more convenient for carrying.But, although these advantages are arranged, replace rigid substrates also to have many restrictions with flexible base, board, the preparation of flexible device still has many underlying issues to need to solve.For flexible substrate, because the profile pattern of flexible substrate is also far away from rigid substrate, to handle equipment and the technology difficulty of wanting special bigger and flexible substrate is carried out surface smoothing, improved substrate production cost; The water of flexible substrate, oxygen permeability be much larger than rigid substrate, causes opto-electronic device to be subjected to the influence of the water oxygen that sees through from substrate, reduced the performance of device.
For electrode layer, conventional electrode layer material In
2O
3: SnO
2(ITO) there is following shortcoming in the electrode as flexible base, board: the indium among (1) ITO has severe toxicity, and is harmful in preparation and application; (2) In among the ITO
2O
3Expensive, cost is higher; (3) ito thin film is vulnerable to the reduction of hydrogen plasma, and effect reduces, and this phenomenon also can take place under low temperature, low plasma density; (4) phenomenon that electrical conductivity descends can appear because of the bending of flexible substrate in the ito thin film on flexible substrate; (5) adopt thick ITO layer can reduce light transmittance, the light of 50-80% sponges at glass, ITO and organic layer, adopts thin ITO layer process difficulty bigger.Owing to having high mechanical strength and elasticity and good conductor characteristics, CNT receives publicity.2006, people such as Canadian R.Martel (Appl.Phys.lett., 2006,88,183104) pointed out that the increase of carbon nano-tube film thickness can reduce visible light transmissivity and the resistance of film.For carbon nano-tube film is obtained than high visible light transmissivity, just must reduce the thickness of carbon nano-tube film, increased side's resistance of carbon nano-tube film so again, make side's resistance of carbon nano-tube film obtain 10
3Ω/sq magnitude has reduced the carbon nano-tube film electrical conductivity.
Therefore, if can solve above-mentioned these problems, will make opto-electronic device obtain using more widely and development more fast.
Summary of the invention
Technical problem to be solved by this invention is how a kind of flexible luminescent device substrate and preparation method thereof is provided, this substrate has solved the problem of adhesion difference between thin layer carbon nano tube surface poor flatness, side's resistance height and CNT and the flexible substrate, has improved the electrical conductivity of thin layer CNT and substrate to the obstructing capacity of water oxygen.
Technical problem proposed by the invention is to solve like this: a kind of flexible luminescent device substrate is provided, comprise flexible substrate and conductive layer, it is characterized in that, described flexible substrate and conductive layer are made of following dual mode: 1. flexible substrate is the adhesive that needs dual cure, conductive layer is the thin layer CNT, is filled with the inorganic light-emitting nano particle in the space of described thin layer CNT; 2. flexible substrate is the adhesive that needs dual cure of doping inorganic light-emitting nano particle, conductive layer is the thin layer CNT, be filled with the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described thin layer CNT, the thickness of described carbon nanotube layer is less than or equal to 100nm, and the described adhesive of dual cure that needs comprises ultraviolet light polymerization-heat cured system, ultraviolet light polymerization-microwave curing system, ultraviolet light polymerization-anaerobic curing system and ultraviolet light polymerization-electronic beam curing system:
1. free radical type ultraviolet light polymerization-heat cured system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then be heating and curing, carry out ultraviolet light polymerization again; Perhaps be heating and curing earlier, then carry out ultraviolet light polymerization, be heating and curing again;
2. free radical type ultraviolet light polymerization-microwave curing system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then carry out microwave curing, carry out ultraviolet light polymerization again; Perhaps carry out microwave curing earlier, then carry out ultraviolet light polymerization, again heating or microwave curing;
3. free radical type ultraviolet light polymerization-anaerobic curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then be not subjected to illumination and be in adhesive segment under the anoxia condition carrying out the anaerobic curing reaction automatically, carry out ultraviolet light polymerization again;
4. free radical type ultraviolet light polymerization-electronic beam curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then carry out electronic beam curing under vacuum, carry out ultraviolet light polymerization again;
5. cation type ultraviolet photo-curing-heat cured system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then be heating and curing, carry out ultraviolet light polymerization again; Perhaps be heating and curing earlier, then carry out ultraviolet light polymerization, be heating and curing again;
6. cation type ultraviolet photo-curing-microwave curing system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then carry out microwave curing, carry out ultraviolet light polymerization again; Perhaps carry out microwave curing earlier, then carry out ultraviolet light polymerization, again heating or microwave curing;
7. cation type ultraviolet photo-curing-anaerobic curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then be not subjected to illumination and be in adhesive segment under the anoxia condition carrying out the anaerobic curing reaction automatically, carry out ultraviolet light polymerization again;
8. cation type ultraviolet photo-curing-electronic beam curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then carry out electronic beam curing under vacuum, carry out ultraviolet light polymerization again.
According to flexible luminescent device substrate provided by the present invention, it is characterized in that described inorganic light-emitting nanoparticle size is 1～50nm, 2. in the mode doping mass ratio of inorganic light-emitting nano particle be less than or equal to 40%.
According to flexible luminescent device substrate provided by the present invention, it is characterized in that, described inorganic light-emitting nano particle is to be luminous host with sulfide, oxide, fluoride, phosphate, vanadate, niobates, aluminate, molybdate etc., with the light-emitting particles of rare earth lanthanide as activator and co-activator.
According to flexible luminescent device substrate provided by the present invention, it is characterized in that described sulfide comprises zinc sulphide, lanthanum sulfide, calcium sulfide, cerium sulphide, praseodymium sulfide, neodymium sulfide, samaric sulfide and gadolinium sulfide; Described oxide comprises zinc oxide, yittrium oxide, titanium oxide, gadolinium oxide and luteium oxide; Described fluoride comprises yttrium fluoride, gadolinium fluoride, lanthanum fluoride and cerium fluoride; Described phosphate comprises lanthanum orthophosphate, Gadolinium monophosphate, strontium phosphate, yttrium phosphate and barium phosphate; Described vanadate comprises vanadic acid gadolinium, vanadic acid yttrium, vanadic acid lanthanum, cerium vanadate, vanadic acid calcium, lead vanadate and vanadic acid strontium; Described niobates comprises calcium niobate, niobic acid yttrium, niobic acid gadolinium and niobic acid lutetium; Described aluminate comprises yttrium aluminate, barium aluminate, aluminic acid gadolinium, calcium aluminate and strontium aluminate; Described molybdate comprises lanthanum molybdate, strontium molybdate and barium molybdate; Described rare earth lanthanide comprises europium, samarium, erbium, neodymium, terbium, dysprosium, samarium, cerium, ytterbium and praseodymium.
According to flexible luminescent device substrate provided by the present invention, it is characterized in that, described free radical thermal curing agents comprises: ethylenediamine, hexamethylene diamine, triethylene tetramine, the ethoxy diethylenetriamine, hydroxyl isopropyl diethylenetriamine, poly-ethanedioic acid adipamide, diformazan ammonia propylamine, 4-methyl-diaminopropane, dicyandiamide, two amido diphenyl sulfones, two amido diphenyl methanes, m-phenylene diamine (MPD), diethyl toluene diamine, N-(aminopropyl)-toluenediamine, dimethylethanolamine, dimethyl Bian amine, triethyl group benzyl ammonium chloride, benzyl-dimethylamine, the N-benzyl dimethylamine, 2,4,6,-three-(dimethylamino methyl)-phenol, the phenol formaldehyde (PF) hexamethylene diamine, N, the N-dimethyl benzylamine, the 2-ethyl imidazol(e), the 2-phenylimidazole, glyoxal ethyline, the 2-ethyl imidazol(e), 2-ethyl-4-methylimidazole, 1-(2-amino-ethyl)-glyoxal ethyline, maleic anhydride, the diphenyl ether tetracarboxylic dianhydride, phthalic anhydride, trimellitic anhydride, the tetrabromo-benzene dicarboxylic acid anhydride, gather acetic anhydride in the ninth of the ten Heavenly Stems, sebacic dihydrazide, AH, carbonic acid two hydrazides, oxalic acid two hydrazides, succinic acid hydrazide ii, adipic dihydrazide, the amino polyacrylamide of N-, the decanedioic acid hydrazides, the M-phthalic acid hydrazides, to the Para Hydroxy Benzoic Acid hydrazides, azelaic acid two hydrazides, isophthalic dihydrazide, the ferrocene tetrafluoroborate, TAC, toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate, hexamethylene diisocyanate, the trimethyl hexamethylene diisocyanate, dicyclohexyl methyl hydride diisocyanate, XDI, tetramethylxylylene diisocyanate, the methyl styrene isocyanates, the hexahydrotoluene vulcabond, triphenyl first-4,4 ', 4 '-triisocyanate, diaminodiphenyl-methane, the chlorophenyl of N--N-N-dimethyl urea, 3-phenyl-1, the 1-dimethyl urea, 3-rubigan-1, the 1-dimethyl urea, 4,4 '-the diamino-diphenyl bis-phenol, polyurethanes, Lauxite, epoxy-ethylenediamine carbamate, 2,4,6-three (dimethylamino methyl) phenol, 2, the 4-diaminotoluene, polyurethane, the methyl-etherified Lauxite, three (3-aminopropyl) amine, 2-amino-ethyl-two (3-aminopropyl) amine, 4,4 '-MDA, 4,4 '-the diamino-diphenyl bis-phenol, 4,4 '-DADPS, three (3-aminopropyl) amine, melmac, the benzoguanamine resin, hexamethylol melamine resin, the hexamethoxymethyl melamine resin, urea-melamine resin, the polyester melamine, the TCCA ester, aminotriazine resins, urethane acrylate, the 4-aminopyridine resin, the amino mylar of N-β-aminoethyl, the α-An Jibiding resin, aminodiphenylether resin, the phosphoramidic acid resin, the hydroxyethylamino mylar; Described microwave curing adhesive and hot setting adhesive use same material or different materials; Described anaerobic curing adhesive comprises: methacrylate tetraethylene-glycol ester, methacrylate multicondensed ethylene glycol ester, the triethylene Glycol double methyl methacrylate, the methacrylate glycol ester, hydroxyethyl methacrylate or hydroxypropyl acrylate, the methoxylated polyethylene glycol methacrylate, the phthalic acid Triethylene Glycol, Jia Jibingxisuanβ-Qiang Yizhi, the triethylene Glycol double methyl methacrylate, methacrylate sulfo-diethylene glycol (DEG) ester, phthalic acid two (diethylene glycol (DEG) acrylate), the ethoxylation bisphenol a dimethacrylate, dimethacrylate bisphenol-A ethylene glycol fat, second diester methacrylate, the triethylene-glycol dimethylacrylate, the condensed ethandiol double methyl methacrylate, glycol methacrylate, one diethyl acetal double methyl methacrylate, the epoxy resin methacrylate, methacrylate diglycol ester; Described electronic beam curing adhesive comprises: triphenol methylmethane tetraglycidel ether epoxy resin, the bicyclopentadiene bisphenol-type epoxy resin, the bisphenol A-type vinyl ester resin, epoxy vinyl ester resin, Epocryl, maleimide resin, 4,4 '-diphenyl methane dimaleimide, bisphenol-A-diphenyl ether BMI, bisphenol-A maleic acid vinylite, ethylene bromide base ester resin, the phenolic aldehyde epoxy vinyl ester resin, the methylolation bisphenol A type epoxy resin, the bisphenol-A acrylate, urethane acrylate, the bisphenol-A epoxy vinyl ester resin, bisphenol A benzoxazine-epoxy resin, bisphenol fluorene epoxy resin, the bisphenol-a epoxy acrylate resin, bisphenol A diglycidyl ether and bisphenol-A epoxy chloropropene acid esters resin.
According to flexible luminescent device substrate provided by the present invention, it is characterized in that, described light trigger comprises styrax and derivative benzoin methyl ether, benzoin ethyl ether, acetophenone derivative and benzoin isopropyl ether, cation light initiator comprises aromatic sulfonium salts, salt compounded of iodine and luxuriant molysite class, sensitising agent comprises benzophenone, thia anthraquinone and Michler's keton, and auxiliary agent comprises plasticizer and coupling agent.
According to flexible luminescent device substrate provided by the present invention, it is characterized in that described plasticizer comprises: dioctyl phthalate, dibutyl phthalate, three vinyl butyl ether base phosphates, polyvinyl butyral resin, tributyl 2-acetylcitrate, repefral, diethyl phthalate, adipic acid two (butoxy ethyoxyl) ethyl ester, isopropyl titanate, tetrabutyl titanate, citrate, the own ester of trimellitic acid (2-ethyl), the own ester of phthalic acid two (2-ethyl), the own ester of decanedioic acid two (2-ethyl), the diglycol dibenzoate, phthalic anhydride, dipropylene glycol dibenzoate and chlorosulfonated polyethylene; Described coupling agent comprises the methyl ethylene dichlorosilane, methyl hydrogen dichlorosilane, dimethyldichlorosilane, chlorodimethyl silane, vinyl trichlorosilane, γ-An Bingjisanjiayangjiguiwan, dimethyl silicone polymer, poly-hydrogen methylsiloxane, poly-methyl methoxy radical siloxane, γ-methacrylic acid third vinegar base trimethoxy silane, gamma-aminopropyl-triethoxy-silane, γ-glycidol ether propyl trimethoxy silicane, the aminopropyl silsesquioxane, γ-methacryloxypropyl trimethoxy silane, the chain alkyl trimethoxy silane, VTES, vinyltrimethoxy silane, γ-chloropropyl triethoxysilane, two-(the silica-based propyl group of γ-triethoxy), anilinomethyl triethoxysilane, N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyl methyl dimethoxysilane, γ-(2,3-epoxy, third oxygen) propyl trimethoxy silicane, γ-(methacryloxypropyl) oxypropyl trimethyl silane, γ-Qiu Jibingjisanjiayangjiguiwan and γ-sulfydryl propyl-triethoxysilicane.
A kind of flexible luminescent device is characterized in that with the preparation method of substrate, may further comprise the steps:
1. the rigid substrates (as glass or silicon chip) of surface roughness less than 1nm cleaned, clean the back and dry up with drying nitrogen;
2. take the mode of spin coating or spraying or self assembly or inkjet printing or serigraphy to prepare carbon nanotube layer at the rigid substrates of cleaning;
3. the adhesive layer that needs dual cure of spin coating or spraying doping inorganic light-emitting nano particle on carbon nanotube layer, or first spin coating or drip and to be coated with or to spray the solution that contains the inorganic light-emitting nano particle, spin coating or spraying need the adhesive layer of dual cure again, described dual cure by two independently cure stage finish, one of them stage is to react by ultraviolet light polymerization, another stage is dark reaction, the described adhesive of dual cure that needs comprises ultraviolet light polymerization-heat cured system, ultraviolet light polymerization-microwave curing system, ultraviolet light polymerization-anaerobic curing system and ultraviolet light polymerization-electronic beam curing system, when using ultraviolet light polymerization-heat cure or ultraviolet light polymerization-microwave curing system, the order that adopts is to be heating and curing earlier or microwave curing, carry out ultraviolet light polymerization then, be heating and curing again or microwave curing; Perhaps carry out ultraviolet light polymerization earlier, be heating and curing then or microwave curing, carry out ultraviolet light polymerization again;
4. the adhesive layer that needs dual cure after carbon nanotube layer and the curing or the adhesive that needs dual cure of doping inorganic light-emitting nano particle are peeled off the rigid substrates surface, form the compliant conductive substrate;
5. test the parameters of transmitance, electrical conductivity and the surface topography of compliant conductive substrate.
Beneficial effect of the present invention: conductive layer of the present invention adopts the thin layer CNT, be filled with the adhesive that needs dual cure of inorganic light-emitting nano particle or doping inorganic light-emitting nano particle in the space of thin layer CNT, there is the inorganic light-emitting nano particle in the conductive layer, make conductive layer luminous under the exciting light irradiation, not only strengthened the luminous intensity based on the luminescent device of this substrate, and simplified based on the structure of the luminescent device of this substrate and required material; Conductive layer of the present invention prepares at the little rigid substrates of roughness, be filled with the adhesive that needs dual cure of inorganic light-emitting nano particle or doping inorganic light-emitting nano particle in the conductive layer space, form the conductive layer of flexible base, board by the method peeled off, improved the flatness of conductive layer surface; The adhesive that employing needs dual cure is as effective the seeing through of block water oxygen of flexible substrate, and the adhesive of dual cure that needs of the present invention has the characteristics of high visible light transmissivity simultaneously, and the substrate visible light transmissivity is improved.
Description of drawings
Fig. 1 is the structural representation that the flexible luminescent device of embodiment of the invention 1-12 is used substrate;
Fig. 2 is the visible light transmissivity of the substrate in the embodiment of the invention 1.
Wherein, 1, flexible substrate, 2, conductive layer.
The specific embodiment
Be further described below in conjunction with accompanying drawing and the present invention of embodiment:
Technical scheme of the present invention provides a kind of flexible luminescent device substrate, and as shown in Figure 1, the structure of device comprises flexible substrate 1, conductive layer 2.
Need each composition of adhesive of dual cure to be described as follows among the present invention:
UV-curing technology is owing to adopted ultraviolet light as solidifying the energy, determined there is the limitation of self, mainly show: to using the base material shape certain restriction is arranged, low to band color system curing rate, deep layer and object shadow region are difficult to solidify, and solidify the back volume contraction and cause problems such as poor adhesive force and light trigger be residual more greatly.These deficiencies have influenced further developing and using of UV-curing technology, and solidify the range of application that volume contraction bigger shortcoming in back has also had a strong impact on ultraviolet photocureable material.Dual cure (dual-curing) technology is the combination of photocuring and other curing.
In the dual cure system, the crosslinked or polymerisation of system is to finish by two stages that independently have the differential responses principle, and one of them stage is by photocuring reaction, and another stage is undertaken by dark reaction.Wherein, photocuring can be the free radical ultraviolet light polymerization, also can be the cation ultraviolet light polymerization; Dark curing can be heat cure, electronic beam curing, anaerobic curing and microwave polymerization etc.So just can utilize photocuring to make the system fast shaping or reach surface drying, and utilize dark reaction to make dash area or bottom partly solidified fully.
The stage of photocuring and dark curing can be at free radical type and cationic ultra-violet curing adhesive, so have free radical type and cationic heat cure etc.
Be some typical system of lifting below, and some concrete operating parameters.
The free radical type ultraviolet curable agent comprises: the material of polyester-acrylate, epoxy-acrylate, carbamate-acrylate, polyethers-acrylate and following molecular structure;
The cation type ultraviolet photo-curing agent comprises: epoxy resin or modified epoxy.
Plasticizer comprises dioctyl phthalate, dibutyl phthalate, three vinyl butyl ether base phosphates, polyvinyl butyral resin, tributyl 2-acetylcitrate, repefral, diethyl phthalate, adipic acid two (butoxy ethyoxyl) ethyl ester, isopropyl titanate, tetrabutyl titanate, citrate, the own ester of trimellitic acid (2-ethyl), the own ester of phthalic acid two (2-ethyl), the own ester of decanedioic acid two (2-ethyl), the diglycol dibenzoate, phthalic anhydride, dipropylene glycol dibenzoate and chlorosulfonated polyethylene; Described coupling agent comprises the methyl ethylene dichlorosilane, methyl hydrogen dichlorosilane, dimethyldichlorosilane, chlorodimethyl silane, vinyl trichlorosilane, γ-An Bingjisanjiayangjiguiwan, dimethyl silicone polymer, poly-hydrogen methylsiloxane, poly-methyl methoxy radical siloxane, γ-methacrylic acid third vinegar base trimethoxy silane, gamma-aminopropyl-triethoxy-silane, γ-glycidol ether propyl trimethoxy silicane, the aminopropyl silsesquioxane, γ-methacryloxypropyl trimethoxy silane, the chain alkyl trimethoxy silane, VTES, vinyltrimethoxy silane, γ-chloropropyl triethoxysilane, two-(the silica-based propyl group of γ-triethoxy), anilinomethyl triethoxysilane, N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyl methyl dimethoxysilane, γ-(2,3-epoxy, third oxygen) propyl trimethoxy silicane, γ-(methacryloxypropyl) oxypropyl trimethyl silane, γ-Qiu Jibingjisanjiayangjiguiwan, γ-sulfydryl propyl-triethoxysilicane.
The free radical activity diluent is divided into exploitation first generation acrylic acid polyfunctional monomer, the second generation acrylic acid polyfunctional monomer of recent development and more excellent third generation acrylic monomers early.
The simple function reactive diluent has: styrene, N-vinyl pyrrolidone, Isooctyl acrylate monomer, hydroxy-ethyl acrylate and isobornyl acrylate, methacrylate phosphate and isobornyl methacrylate, latter two is the good toughness reinforcing monomer of plasticising.
The difunctionality reactive diluent has: triethylene glycol diacrylate, tripropylene glycol diacrylate, glycol diacrylate, polyethylene glycol diacrylate alcohol ester, neopentylglycol diacrylate and propoxyl group neopentylglycol diacrylate, the acrylate-functional monomer mainly contains 1,6-hexanediyl ester (HDDA), 1,4-butanediol diacrylate (BDDA), propylene glycol diacrylate (DPGDA), glycerine diacrylate (TPGDA), the trihydroxy methyl propane triacrylate (TMPTA) of trifunctional, pentaerythritol triacrylate (PETA), trihydroxy methyl propane triol triacrylate (TMPTMA), trimethylolpropane triacrylate, the propoxylation trihydroxy is through the methylpropane triacrylate, pentaerythrite three propylene alcohol esters, pentaerythritol propoxylate propylene alcohol ester, N, N-dihydroxy ethyl-3 amido methyl propionate, triethylene glycolbismethyl-acrylate, long-chain fat hydrocarbon glycidol ether acrylic acid, the resorcinol bisglycidyl ether, double pentaerythritol C5 methacrylate, tri (propylene glycol) diacrylate, phthalic acid diethanol diacrylate (PDDA).They have replaced active little first generation acrylic acid monofunctional monomer.But along with the develop rapidly of UV curing technology, they reveal the big shortcoming of the excitant of skin.
Second generation acrylic acid polyfunctional monomer mainly is to introduce ethyoxyl or propoxyl group in molecule, has overcome the big shortcoming of excitant, also should have higher activity and state of cure.As ethoxylation trihydroxy methyl propane triol triacrylate (TMP (EO) TMA), propoxylation trihydroxy methyl propane triol triacrylate (TMP (PO) TMA), propoxylation glycerine triacrylate (G (PO) TA).Third generation acrylic monomers is mainly the acrylate that contains methoxyl group, preferably resolves the contradiction of high curing rate and shrinkage factor, low state of cure.This class material has 1,6-hexylene glycol methoxyl group mono acrylic ester (HDOMEMA), ethoxylation neopentyl glycol methoxyl group mono acrylic ester (TMP (PO) MEDA).After introducing alkoxyl in the molecule, can reduce the viscosity of monomer, reduce the excitant of monomer simultaneously.
The introducing of alkoxyl is also improved a lot to the compatibility of diluent monomer, and VTES (A15I), gamma-methyl allyl acyloxypropyl trimethoxysilane (A174) can be used as monomer.
Cruel in various active epoxy diluent resins and various cyclic ethers, the ring, vinyl ether monomers etc. can be as the diluent of cation photocuring resin.Therein ethylene pyridyl ethers compound and oligomer curing rate are fast, modest viscosity, tasteless, nontoxic, can be used with epoxy resin.Vinyl ether monomers has: 1,2,3-propanetriol-diglycidyl-ether (EPON-812), triethylene glycol divinyl ether (DVE-3), 1,4-butanediol vinyl ethers (HBVE), cyclohexyl vinyl ether (CHVE), perfluoro methyl vinyl ether (PMVE), the perfluor n-propyl vinyl ether, IVE, hydroxy butyl vinyl ether, vinyl ethyl ether, ethyl vinyl ether, the ethyl vinyl ether propylene, ethylene glycol monoallyl ether, hydroxy butyl vinyl ether, butyl vinyl ether, CTFE (CTFE), triethylene glycol divinyl ether, methoxy ethylene, the vinyl n-butyl ether, dodecyl vinyl (DDVE), cyclohexyl vinyl ether, tribenzyl-benzene phenol polyethenoxy base ether, tetrafluoroethene-perfluoro propyl vinyl ether, tetrafluoroethene-perfluoro propyl vinyl ether, tert-Butyl vinyl ether:
The epoxide monomer has: 3,4-epoxy radicals hexahydrobenzoid acid-3 ', 4 '-epoxy radicals cyclohexyl methyl esters (ERL-4221), bisphenol A type epoxy resin (EP), epoxy acrylate, epoxy vinyl ester, acrylic acid epoxy ester, methacrylic acid epoxy-ester, water-soluble itaconic acid epoxy ester resin:
The effect of light trigger is after it absorbs the ultraviolet light energy, produces free radical through decomposing, thus the unsaturated bond polymerization in the initiator system, and crosslinking curing becomes an integral body.Radical photoinitiator commonly used has the cracking type and puies forward Hydrogen two big classes.
Crack type photoinitiator: crack type photoinitiator mainly contains benzoin ethers (styrax ethers), benzil ketals and acetophenone etc.Crack type photoinitiator is chapped after absorbing ultraviolet light, produces two free radicals, and free radical causes the unsaturated group polymerization.Benzoin ethers (styrax ethers) comprising: styrax (Benzoin), benzoin methyl ether, benzoin ethyl ether (Benzoin ethyl ether), benzoin isobutyl ether (Benzoin butyl ether), styrax lose (Benzoin oxime), benzoin isopropyl ether; Acylphosphine oxide comprises: 2; 4; 6 trimethylbenzene formyl diphenyl phosphine oxides (TPO) and (2; 4; 6-trimethylbenzene formyl) phenyl phosphine oxide (BAPO phenylbis (2; 4; 6-trimethyl benzoyl) phosphine oxide); two (2,4, the 6-trimethylbenzoyl) phosphine oxides (819) of phenyl; tetramethylpiperidone oxide (TMPO); triethyl phosphate (TEPO); they are more satisfactory light triggers; have very high light-initiated activity, the long wave near ultraviolet ray is had absorption, be applicable to the situation that whitewash and film are thicker; and have good stability, can variable color or fade.
Carry the Hydrogen initator: carry the Hydrogen initator and mainly contain benzophenone and thioxanthones etc.Wherein at 380-420nm, and absorbability and hydrogen-taking capacity are strong, have higher efficiency of initiation at the maximum absorption wavelength in black light district for thioxanthone photoinitiator.Carrying the Hydrogen initator must have hydrogen donor as collaborative composition, otherwise efficiency of initiation is too low, so that can not be put to use.Triplet state carbonyl free radical than more likely extracting hydrogen on the secondary carbon or on the methyl, is connected on hydrogen on the hetero atoms such as oxygen or nitrogen than the easier extraction of the hydrogen on the carbon atom from the tertiary carbon of hydrogen donor molecule.This class hydrogen donor has amine, hydramine (triethanolamine, methyl diethanolamine, triisopropanolamine etc.), mercaptan, N, the N-diethyl-and to the dimethylamino benzamide.
The benzophenone light initiation system, benzophenone need be with alcohol, ether or amine and with just making vinyl monomer carry out photopolymerization.Mainly comprise: benzophenone, the thia anthraquinone, Michler's keton, dimethoxy benzene acetophenone (DMPA), alpha-hydroxy-2,2 dimethyl acetophenones (1173), Alpha-hydroxy cyclohexyl-phenyl ketone (184), α-amine alkyl phenones, 2-methyl isophthalic acid (4-first coloured glaze base phenyl)-2-morpholinyl acetone (MMMP), 2,2 '-dibenzamidodiphenyl disulfide (DBMD), (4-dimethylamino phenyl)-(1-piperidyl)-ketone, isopropyl thioxanthone (ITX), (4-dimethylamino phenyl)-(4-morpholinyl)-ketone, 2-hydroxy-2-methyl-1-phenyl-1-phenyl-1-acetone, two phenoxy group benzophenone, hydroxy-2-methyl phenyl-propane-1-ketone.And mixed system, as eliminating oxygen in the glued membrane to the benzophenone of the inhibition of Raolical polymerizable and the initiator system that cooperates of uncle's ammonia; Michler's keton and benzophenone are used, and can obtain more cheap and effectively initiator system.
Cationic photoinitiator: aromatic sulfonium salts and salt compounded of iodine class initator have excellent high-temperature stability, and also have stability after epoxy resin cooperates, so be widely used in the cationic curing system.This type of initator comprises: xylyl iodine hexafluorophosphate (PI810); hydroxy phenyl salt compounded of iodine (HTIB); 4; the two detergent alkylate iodine hexafluoro antimonates of 4-; the xylyl salt compounded of iodine; diphenyl hexafluoroarsenate salt compounded of iodine; [4-(2-hydroxyl-3-butoxy-1-propoxyl group) phenyl] benzene iodo-hexafluoro antimonate; [4-(to the benzoyl thiophenyl) benzene] phenyl-iodide hexafluorophosphate; [4-(4-benzoyl phenoxy group) benzene] phenyl-iodide hexafluorophosphate; 4-(to the benzoyl thiophenyl) benzene] the phenyl-iodide hexafluorophosphate; 4; 4 '-dimethyl diphenyl salt compounded of iodine hexafluorophosphate (IHT-PI 820); 4; 4 '-the diacetylamino diphenyl iodine hexafluorophosphate; 37-dinitro dibenzo ring-type salt compounded of iodine and 3; 7 one dinitro dibenzo ring-type bromine salt; the tetrafluoro boric acid diaryl group iodized salt; 3; 3 '-the dinitro diphenyl salt compounded of iodine; 3; 3 '-dinitro diphenyl salt compounded of iodine and several 2; 2 '-two replace (iodine; bromine; chlorine)-5; 5 '-the dinitrophenyl salt compounded of iodine; iodate 2-[2-(3-indolizine) vinyl]-1-methylquinoline salt; iodate 4-(2-benzoxazole)-N-picoline salt; 3-nitrobenzophenone diphenyl sulphur hexafluorophosphate; triaryl phosphine glyoxalidine salt; triaryl phosphine 1; 1 '-dinaphthalene glyoxalidine ring salt; 3; 7-dinitro dibenzo bromine five rings salt; p-methyl benzenesulfonic acid triphenyl sulfosalt; bromination triphenyl sulfosalt; (4-thiophenyl-phenyl) diphenyl sulphur hexafluorophosphate; 4-(thiophenyl) triphenyl sulphur hexafluorophosphate; 3; 3 '-dinitro diphenyl iodine hexafluorophosphate; 3-nitrobenzophenone diphenyl sulphur hexafluorophosphate; the triphenyl sulfosalt; 4-chlorphenyl diphenyl sulphur hexafluorophosphate; 3-nitrobenzophenone diphenyl sulphur hexafluorophosphate; 4-acetamido phenyl diphenyl sulphur hexafluorophosphate; 3-benzoyl phenyl diphenyl sulphur hexafluorophosphate; triphenyl sulphur borofluoride; triphenyl sulphur hexafluorophosphate; triphenyl sulphur hexafluoro antimonate; 4-tolyl diphenyl sulphur hexafluorophosphate; the phosphorus hexafluoride triaryl sulfonium salts; the antimony hexafluoride triaryl sulfonium salts; [4-(to the benzoyl thiophenyl) benzene] phenyl-iodide hexafluorophosphate; 1-(4 '-bromo-2 '-luorobenzyl) pyridiniujm; [4-(to the benzoyl thiophenyl) benzene] phenyl-iodide hexafluorophosphate; 4-[4-(p-nitrophenyl formoxyl) thiophenyl] and benzene } the phenyl-iodide hexafluorophosphate; 4-[4-(to methyl benzoyl) thiophenyl] and benzene } the phenyl-iodide hexafluorophosphate; 4-[4-(to methyl benzoyl) phenoxy group] and benzene } the phenyl-iodide hexafluorophosphate; [4-(to the benzoyl phenoxy group) benzene] phenyl-iodide hexafluorophosphate; the two detergent alkylate iodine hexafluoro antimonates of 4,4-.
Luxuriant molysite class: luxuriant molysite class light initiation system is a kind of new cation light initiator that develops after two fragrant salt compounded of iodine and three aromatic sulfonium salts; mainly comprise: cyclopentadienyl group-iron-benzene salt; cyclopentadienyl group-iron-toluene salt; cyclopentadienyl group-iron-paraxylene salt; cyclopentadienyl group-iron-naphthalene salts; cyclopentadienyl group-iron-biphenyl salt; cyclopentadienyl group-iron-2; 4-dimethyl acetophenone salt; acetyl group-cyclopentadienyl group-iron-paraxylene salt; cyclopentadienyl group-iron-methyl phenyl ethers anisole salt; cyclopentadienyl group-iron-diphenyl ether salt; cyclopentadienyl group-iron-2; 4-diethoxybenzene salt; the ferrocene tetrafluoroborate; the luxuriant iron tetrafluoroborate of toluene; cyclopentadienyl group-iron-methyl phenyl ethers anisole salt; cyclopentadienyl group-iron-diphenyl ether salt; cyclopentadienyl group-iron-1; 4-diethoxybenzene salt; cyclopentadienyl group-iron-chlorobenzene salt; cyclopentadienyl group-iron-(1; the 4-diethoxybenzene) hexafluorophosphate; cyclopentadienyl group-iron-diphenyl ether hexafluorophosphate; 1; 10-phenanthrolene ferrous perchlorate salt; 1; 10-phenanthrolene ferrous sulfate cyclopentadienyl group-iron-methyl phenyl ethers anisole salt; cyclopentadienyl group-iron-diphenyl ether salt; [1; 1 '-two (diphenylphosphine) ferrocene] Nickel Chloride; vinyl ferrocene; N; N '-di-ferrocene methylene butanediamine quaternary ammonium salt; ferrocene formamide; ferrocene acyl propionic acid; ferrocenyl methyl ketone; ethyl dicyclopentadienyl iron; Butyrylferrocene; butyl ferrocene; N; N-dimethyl-amine methyl ferrocene; 1; 1 '-the dibenzoyl ferrocene; (3-carboxyl propionyl group) ferrocene; 1,1 '-the dibromo ferrocene; amino ferrocene.
Ultraviolet light polymerization-heat cured system: the mechanical performance of cured product is significantly improved after the discovery heat treatment, and along with the increase of epoxy component, hybrid systems has good adhesion property at grounds such as metals, this is because epoxide shrinks little cause when solidifying on the one hand, is owing to eliminated the internal stress that produces when radical photoinitiator solidifies during heat cure on the other hand.According to flexible luminescent device substrate provided by the present invention, it is characterized in that the thermal curing agents in the described heat cure mode comprises: epoxy resin, isocyanates, amino resins class and free radical thermal curing agents.
Epoxy resin comprises: aliphatic amine, aromatic amine, dicyandiamide class, imidazoles, organic acid anhydride class, organic hydrazides class, lewis acid amine and microcapsules class.
The aliphatic amine comprises: ethylenediamine, hexamethylene diamine, diethylenetriamine, triethylene tetramine, the ethoxy diethylenetriamine, hydroxyl isopropyl diethylenetriamine, poly-ethanedioic acid adipamide, diethanol amine, tetramethylethylenediamine, the glycyrrhizic acid diamines, N-(2-ethoxy) ethylenediamine, two (4-amido phenoxy group)-phenyl phosphorous oxide, two (3-aminocarbonyl phenyl) phenyl phosphorous oxide, the tetrapropyleneglycol diamines, N-hydroxyethyl-ethylenediamine, methyl ring pentanediamine, polyetheramine, pnenolic aldehyde amine hardener (T-31), AEEA, IPD, the Meng alkane diamines, diformazan ammonia propylamine, two (4-amino-3-methylcyclohexyl) methane, 4-methyl-diaminopropane, amine epoxy curing agent modified (593), fat amine epoxy hardener (3380, TG-03, LX-502, D230), fatty amine modification addition product (HB-206, HB-205, HB-2512, HB-9305, HB-9409).
The dicyandiamide class comprises: dicyandiamide, 3, the cyanoguanidine derivative of 5 disubstituted benzenes amine modifications (HT2833, HT 2844), dicyandiamide (MD 02, made by expoxy propane and dicyandiamide reaction), modification cyanoguanidine derivative (AEHD-610, AEHD-210) and the derivative that contains following molecular formula.
Aromatic amine comprises: two amido diphenyl sulfones (DDS), two amido diphenyl methanes (DDM), m-phenylene diamine (MPD) (m PDA), 8 naphthylenediamines, diethyl toluene diamine, o-phenylenediamine, p-phenylenediamine (PPD), pi-allyl fragrance diamines, N-(aminopropyl)-toluenediamine, IPD, dimethylethanolamine, dimethyl Bian amine, triethyl group benzyl ammonium chloride, benzyl-dimethylamine, the N-benzyl dimethylamine, 2,4,6,-three-(dimethylamino methyl)-phenol, the phenol formaldehyde (PF) hexamethylene diamine, N, N-dimethyl benzylamine (BDMA), the carboxyl phenyl succinimide of N-(p-CPMD).
Imidazoles comprises: the 1-methylimidazole, the 2-ethyl imidazol(e), the 2-phenylimidazole, glyoxal ethyline, 1-8-amino-ethyl-glyoxal ethyline (AMz), 2-undecyl imidazole adipic acid disalt, the 2-ethyl imidazol(e), 2-ethyl-4-methylimidazole (2E4Mz), 1-(2-amino-ethyl)-glyoxal ethyline, 1-cyano group-2-ethyl-4-methylimidazole, 2-heptadecyl imidazoles, 2-ethyl-4-methylimidazole-carboxyl, 3-dihydroxymethyl substituted ramification of imidazole, the chloride of 1,3-diphenyl-glyoxal ethyline, 1-decyl-2-ethyl imidazol(e), modified imidazole (JH-0511, JH-0512, JH-0521).
The organic acid anhydride class comprises: epoxidized polybutadiene/acid anhydrides, maleic anhydride, 70# acid anhydrides (synthetic by butadiene and maleic anhydride), 647# acid anhydrides (synthetic by dicyclopentadiene and maleic anhydride), 308 tung oil acid anhydrides are (by tung oil-modified maleic anhydride, methyl inner methylidyne tetrahydric phthalic anhydride (MNA) is synthetic), pyromellitic acid anhydride (PMTA) (pyromellitic acid anhydride mixes with maleic anhydride), methyl hexahydrophthalic anhydride (MeHHPA), the diphenyl ether tetracarboxylic dianhydride, phthalic anhydride (PA), hexahydrophthalic anhydride (HHPA), tetrahydrochysene phthalate anhydride (THPA), methyl tetrahydrochysene phthalate anhydride, epoxidized polybutadiene/acid anhydrides, trimellitic anhydride (TMA), the tetrabromo-benzene dicarboxylic acid anhydride, poly-acetic anhydride in the ninth of the ten Heavenly Stems (PAPA).
Organic hydrazides class comprises: sebacic dihydrazide (SDH), AH, carbonic acid two hydrazides, oxalic acid two hydrazides, succinic acid hydrazide ii, adipic dihydrazide, the amino polyacrylamide of N-, N (CH
2CH
2CO-NHNH
2)
3, (H
2NHNCOCH
2CH
2)
2NCH
2CH
2N (CHCHCONHNH
2)
2, butanedioic acid hydrazides, decanedioic acid hydrazides, M-phthalic acid hydrazides, to Para Hydroxy Benzoic Acid hydrazides (POBH), azelaic acid two hydrazides, isophthalic dihydrazide.
The lewis acid amine is by BF
3, AlCl
3, ZnCl
2, PF
5Form complex compound and form Deng lewis acid and primary amine or secondary amine, comprising: cyclopentadienyl group isopropylbenzene iron hexafluorophosphate (Irgacure 261), boron trifluoride, ferrocene tetrafluoroborate.
The microcapsules class comprises: cellulose, gelatin, polyvinyl alcohol, polyester, polysulfones.
Isocyanates comprises: TAC, toluene di-isocyanate(TDI) (TDI), '-diphenylmethane diisocyanate (MDI), poly methylene poly phenyl poly isocyanate (PAPI), hexamethylene diisocyanate (HDI), IPDI (IPDI), trimethyl hexamethylene diisocyanate (TMDI), dicyclohexyl methyl hydride diisocyanate (HMDI), XDI (XDI), tetramethylxylylene diisocyanate (TMXDI), methyl styrene isocyanates (TMI), hexahydrotoluene vulcabond (HTDI), acrylonitrile-butadiene rubber, Heptad isocyanate, triphenyl first-4,4 ', 4 '-triisocyanate, tri o cresyl thiophosphate (4-NCO phenyl ester), tetraisocyanate, Heptad isocyanate, biuret polyisocyanate, oxolane PPG-epoxy resin-isocyanates, trihydroxy PPOX polyalcohol-isocyanates.
Amino resins comprises: diaminodiphenyl-methane (DDM), the chlorophenyl of N--N-N-dimethyl urea, 3-phenyl-1, the 1-dimethyl urea, 3-rubigan-1, the 1-dimethyl urea, 4,4 '-the diamino-diphenyl bis-phenol, polyurethanes, Lauxite, epoxy-ethylenediamine carbamate, N, N, N ', N '-four propargyl-4,4 '-diaminourea-diphenyl-methane (TPDDM), 2,4,6-three (dimethylamino methyl) phenol, 2, the 4-diaminotoluene, 4,6-three (dimethylamino methyl) phenol, polyurethane, the methyl-etherified Lauxite, three (3-aminopropyl) amine, 2-amino-ethyl-two (3-aminopropyl) amine, N, N, N ', N '-four (3-aminopropyl) ethylenediamine, 1-[two (3-aminopropyl) amino]-the 2-propyl alcohol; N-(2-amino-ethyl)-N-(3-aminopropyl) amine, the 1-[(2-amino-ethyl)-(3-aminopropyl) amino]-1-ethanol, the 1-[(2-amino-ethyl)-(3-aminopropyl) amino]-the 2-propyl alcohol, the 3-dimethylaminopropylamine, 4,4 '-MDA (DDM), 4,4 '-the diamino-diphenyl bis-phenol, 4,4 '-DADPS (DDS), three (3-aminopropyl) amine, melmac, the benzoguanamine resin, hexamethylol melamine resin, the methyl-etherified melmac, methyl-etherified benzoguanamine resin, methyl-etherified urea melamine condensation copolymerization resin, hexamethoxymethyl melamine resin (TMMM), methyl alcohol modification trimethylol melamine, urea-melamine resin, the polyester melamine, 2-secondary butyl phenenyl-N-methylamino acid esters, the DCCA ester, the TCCA ester, aminotriazine resins, urethane acrylate, the 4-aminopyridine resin, the amino mylar of N-β-aminoethyl, the α-An Jibiding resin, aminodiphenylether resin, amino silicones, the phosphoramidic acid resin, the maleopimaric acid polyester amino resin, piperazine aminodithioformic acid type chelating resin, the hydroxyethylamino mylar.
The free radical thermal curing agents comprises: cumyl peroxide, the acrylic acid epoxy monoesters, benzoic acid uncle fourth fat, urethane acrylate, polyurethane diol, the polyester triol, two (hexafluorophosphoric acid esters), polymethyl methacrylate (PMMA), cinnamic acrylic ester, polybutadiene type crylic acid hydroxy ester, the polyester urethane acrylate, the acrylic acid epoxy monoesters, butadiene-methyl methacrylate-benzene diene copolymers, butadiene-methyl methacrylate, ethylene-acrylate, polyacrylate, chlorination polypropylene-acrylate, polymethyl methacrylate, polyethyl methacrylate, cyanoacrylate, 2-acrylic acid-1, the 2-propylene glycol monoester, methyl methacrylate, EMA, butyl methacrylate, hydroxyethyl methacrylate, isobutyl methacrylate, isobutyl methacrylate, EHMA, methacrylic acid 2 methylamino ethyl esters, methyl acrylate, ethyl acrylate, butyl acrylate, acrylic acid 2 hydroxy propyl esters, hydroxy-ethyl acrylate, Isooctyl acrylate monomer, vinylacetate-butyl acrylate, polymethyl methacrylate.
Ultraviolet light polymerization-microwave curing system: the microwave curing agent in the microwave curing mode is identical with thermal curing agents in the heat cure mode.Its technical characterstic is to use the mode of microwave curing that thermal curing agents is solidified.Microwave is because of " in the molecule " even mode of heating of uniqueness, make that resin solidification is even, speed is fast, be easy to control, save the energy, equipment investment is few, microwave replaces heat cure more and more to come into one's own in the research aspect thermosetting resin and the composite material solidification thereof in recent years.
Ultraviolet light polymerization-anaerobic curing system: the anaerobic curing agent in the anaerobic curing system comprises: methacrylate tetraethylene-glycol ester, methacrylate multicondensed ethylene glycol ester is (as the happy Thailand 290 of the U.S. and the happy Thailand of mixing with fumaric acid bisphenol-A unsaturated polyester (UP) 271, happy safe 277 etc.), the triethylene Glycol double methyl methacrylate, the methacrylate glycol ester, hydroxyethyl methacrylate or hydroxypropyl acrylate are (as homemade anchor 302, the triple bond 1030 of Japan), the bisphenol-A epoxy ester is (as homemade Y-150, GY-340 etc. are the mixtures of epoxy-ester and multicondensed ethylene glycol ester), the product of hydroxyethyl methacrylate alkyl phenol and polyalcohol is (as happy safe 372 of the U.S., homemade GY-168, anchor 352 and BN-601), polyurethane, the different hydrogen acid ether (hydrogen acid ester) of polyurethane, hydroxy propyl methacrylate, hydroxy propyl methacrylate-polyethers, hydroxy polybutadiene type polyurethane, polyurethane-acrylate, hydroxypropyl acrylate (HPA), glycol methacrylate, cumyl hydroperoxide, acrylic acid o-cresol formaldehyde epoxy-ester, the methoxylated polyethylene glycol methacrylate, the phthalic acid Triethylene Glycol, Jia Jibingxisuanβ-Qiang Yizhi, trimethylol-propane trimethacrylate, the triethylene Glycol double methyl methacrylate, the multicondensed ethylene glycol double methyl methacrylate, methacrylate sulfo-diethylene glycol (DEG) ester, phthalic acid two (diethylene glycol (DEG) acrylate), the ethoxylation bisphenol a dimethacrylate, dimethacrylate bisphenol-A ethylene glycol fat, second diester methacrylate, the condensed ethandiol double methyl methacrylate, glycol methacrylate, one diethyl acetal double methyl methacrylate, phthalic anhydride diglycol ethylene double methyl methacrylate, epoxy resin (methyl) acrylate, methacrylate diglycol ester, double methyl methacrylate triethylene glycol ester, propenoic methyl carbamate, the a-Methyl 2-cyanoacrylate, the a-cyanacrylate, GMA, polyethylene glycol dimethacrylate, the triethylene glycol dimethylacrylate, methacrylic acid bicyclic pentadiene one oxygen monoethyl ester, the methyl-prop dimethylaminoethyl acrylate.
Ultraviolet light polymerization-electronic beam curing system: the electronic beam curing agent in the electronic beam curing mode comprises: triphenol methylmethane tetraglycidel ether epoxy resin, the bicyclopentadiene bisphenol-type epoxy resin, bisphenol A-type vinyl ester resin (V-411), epoxy vinyl ester resin (V-901), Epocryl (BRT2000), maleimide resin, 4,4 '-diphenyl methane dimaleimide, bisphenol-A-diphenyl ether BMI, bisphenol-A maleic acid vinylite, vinyl ester resin, ethylene bromide base ester resin, fumaric acid mixed ethylene base ester resin, acrylic acid mixed ethylene base ester resin, carbamate mixed ethylene base ester resin, the rubber mix vinyl ester resin, the phenolic aldehyde epoxy vinyl ester resin, the hybrid epoxidized acrylate of isocyanates, toluene di-isocyanate(TDI) mixing acrylic acid-hydroxyl ethyl ester, the methylolation bisphenol-type epoxy resin, the bisphenol-A acrylate, urethane acrylate, the bisphenol-A epoxy vinyl ester resin, bisphenol-A benzoxazine-epoxy resin, bisphenol fluorene epoxy resin, the bisphenol-a epoxy acrylate resin, bisphenol A diglycidyl ether, bisphenol-A epoxy chloropropene acid esters resin.
DER383
DER383-TBBA
Below be specific embodiments of the invention:
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure, and conductive layer 2 adopts CNT, fills the inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 15 nanometers, and the thickness of described carbon nanotube layer is 70nm.
The preparation method is as follows:
1. the glass substrate of surface roughness less than 1nm cleaned, clean the back and dry up with drying nitrogen;
2. even carbon nanotube is dispersed in the solvent, takes the spin coating mode to prepare carbon nanotube layer at the substrate of cleaning, rotating speed is 4000 revolutions per seconds during spin coating, duration 60 seconds, and thickness is about 70 nanometers;
3. drip at carbon nanotube layer and be coated with the solution that contains the inorganic light-emitting nano particle, glass substrate was placed 30 minutes in 80 ℃ environment, remove solvent remaining in the carbon nanotube layer, need the adhesive of dual cure again in the carbon nanotube layer spraying, described adhesive raw materials comprises following component:
4. glass baseplate surface being carried out ultraviolet light polymerization handled 30 seconds;
5. glass baseplate surface is carried out heat cure and handle, temperature is 110 ℃;
6. reuse the UV-irradiation glass baseplate surface, carry out photocuring;
7. the adhesive layer of the dual cure after carbon nanotube layer and the curing is peeled off glass baseplate surface, form the compliant conductive substrate;
8. test the parameters of transmitance, electrical conductivity and the surface topography of compliant conductive substrate.
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure, conductive layer 2 adopts CNT, fill the inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 10 nanometers, the thickness of described carbon nanotube layer is 60nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 3
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure, conductive layer 2 adopts CNT, fill the inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 5 nanometers, the thickness of described carbon nanotube layer is 50nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 4
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure, conductive layer 2 adopts CNT, fill the inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 1 nanometer, the thickness of described carbon nanotube layer is 40nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 5
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure, conductive layer 2 adopts CNT, fill the inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 20 nanometers, the thickness of described carbon nanotube layer is 70nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 6
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure, conductive layer 2 adopts CNT, fill the inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 20 nanometers, the thickness of described carbon nanotube layer is 80nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 7
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure of doping inorganic light-emitting nano particle, the doping mass ratio of described inorganic light-emitting nano particle is 5%, conductive layer 2 adopts CNT, fill the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 25 nanometers, and the thickness of described CNT is 80nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 8
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure of doping inorganic light-emitting nano particle, the doping mass ratio of described inorganic light-emitting nano particle is 10%, conductive layer 2 adopts CNT, fill the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 15 nanometers, and the thickness of described CNT is 70nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 9
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure of doping inorganic light-emitting nano particle, the doping mass ratio of described inorganic light-emitting nano particle is 15%, conductive layer 2 adopts CNT, fill the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 10 nanometers, and the thickness of described CNT is 60nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 10
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure of doping inorganic light-emitting nano particle, the doping mass ratio of described inorganic light-emitting nano particle is 20%, conductive layer 2 adopts CNT, fill the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 10 nanometers, and the thickness of described CNT is 50nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 11
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure of doping inorganic light-emitting nano particle, the doping mass ratio of described inorganic light-emitting nano particle is 30%, conductive layer 2 adopts CNT, fill the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 30 nanometers, and the thickness of described CNT is 90nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Embodiment 12
Board structure as shown in Figure 1, flexible substrate 1 adopts the adhesive that needs dual cure of doping inorganic light-emitting nano particle, the doping mass ratio of described inorganic light-emitting nano particle is 40%, conductive layer 2 adopts CNT, fill the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described carbon nanotube layer, described inorganic light-emitting nanoparticle size is 50 nanometers, and the thickness of described CNT is 100nm, and described adhesive raw materials comprises following component:
The preparation method is similar to embodiment 1.
Claims (8)
1. flexible luminescent device substrate, comprise flexible substrate and conductive layer, it is characterized in that, described flexible substrate and conductive layer are made of following dual mode: a, flexible substrate are the adhesive that needs dual cure, conductive layer is the thin layer CNT, is filled with the inorganic light-emitting nano particle in the space of described thin layer CNT; B, flexible substrate are the adhesive that needs dual cure of doping inorganic light-emitting nano particle, conductive layer is the thin layer CNT, be filled with the adhesive that needs dual cure of doping inorganic light-emitting nano particle in the space of described thin layer CNT, the thickness of described carbon nanotube layer is less than or equal to 100nm; The described adhesive of dual cure that needs comprises ultraviolet light polymerization-heat cured system, ultraviolet light polymerization-microwave curing system, ultraviolet light polymerization-anaerobic curing system and ultraviolet light polymerization-electronic beam curing system:
1. free radical type ultraviolet light polymerization-heat cured system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then be heating and curing, carry out ultraviolet light polymerization again; Perhaps be heating and curing earlier, then carry out ultraviolet light polymerization, be heating and curing again;
2. free radical type ultraviolet light polymerization-microwave curing system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then carry out microwave curing, carry out ultraviolet light polymerization again; Perhaps carry out microwave curing earlier, then carry out ultraviolet light polymerization, again heating or microwave curing;
3. free radical type ultraviolet light polymerization-anaerobic curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then be not subjected to illumination and be in adhesive segment under the anoxia condition carrying out the anaerobic curing reaction automatically, carry out ultraviolet light polymerization again;
4. free radical type ultraviolet light polymerization-electronic beam curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then carry out electronic beam curing under vacuum, carry out ultraviolet light polymerization again;
5. cation type ultraviolet photo-curing-heat cured system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then be heating and curing, carry out ultraviolet light polymerization again; Perhaps be heating and curing earlier, then carry out ultraviolet light polymerization, be heating and curing again;
6. cation type ultraviolet photo-curing-microwave curing system, raw material comprises the component of following weight portion:
Solidification process is: carry out ultraviolet light polymerization earlier, then carry out microwave curing, carry out ultraviolet light polymerization again; Perhaps carry out microwave curing earlier, then carry out ultraviolet light polymerization, again heating or microwave curing;
7. cation type ultraviolet photo-curing-anaerobic curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then be not subjected to illumination and be in adhesive segment under the anoxia condition carrying out the anaerobic curing reaction automatically, carry out ultraviolet light polymerization again;
8. cation type ultraviolet photo-curing-electronic beam curing system, raw material comprises the component of following weight portion:
Solidification process is: at first carry out ultraviolet light polymerization, then carry out electronic beam curing under vacuum, carry out ultraviolet light polymerization again.
2. flexible luminescent device substrate according to claim 1 is characterized in that, described inorganic light-emitting nanoparticle size is 1～50nm, and the doping mass ratio of inorganic light-emitting nano particle is less than or equal to 40% in b kind mode.
3. flexible luminescent device substrate according to claim 1, it is characterized in that, described inorganic light-emitting nano particle is to be luminous host with sulfide, oxide, fluoride, phosphate, vanadate, niobates, aluminate or molybdate, with the light-emitting particles of rare earth lanthanide as activator and co-activator.
4. flexible luminescent device substrate according to claim 3 is characterized in that described sulfide comprises zinc sulphide, lanthanum sulfide, calcium sulfide, cerium sulphide, praseodymium sulfide, neodymium sulfide, samaric sulfide or gadolinium sulfide; Described oxide comprises zinc oxide, yittrium oxide, titanium oxide, gadolinium oxide or luteium oxide; Described fluoride comprises yttrium fluoride, gadolinium fluoride, lanthanum fluoride or cerium fluoride; Described phosphate comprises lanthanum orthophosphate, Gadolinium monophosphate, strontium phosphate, yttrium phosphate or barium phosphate; Described vanadate comprises vanadic acid gadolinium, vanadic acid yttrium, vanadic acid lanthanum, cerium vanadate, vanadic acid calcium, lead vanadate or vanadic acid strontium; Described niobates comprises calcium niobate, niobic acid yttrium, niobic acid gadolinium or niobic acid lutetium; Described aluminate comprises yttrium aluminate, barium aluminate, aluminic acid gadolinium, calcium aluminate or strontium aluminate; Described molybdate comprises lanthanum molybdate, strontium molybdate or barium molybdate; Described rare earth lanthanide comprises europium, samarium, erbium, neodymium, terbium, dysprosium, samarium, cerium, ytterbium or praseodymium.
5. flexible luminescent device substrate according to claim 1, it is characterized in that, described free radical thermal curing agents comprises: ethylenediamine, hexamethylene diamine, triethylene tetramine, the ethoxy diethylenetriamine, hydroxyl isopropyl diethylenetriamine, poly-ethanedioic acid adipamide, diformazan ammonia propylamine, 4-methyl-diaminopropane, dicyandiamide, two amido diphenyl sulfones, two amido diphenyl methanes, m-phenylene diamine (MPD), diethyl toluene diamine, N-(aminopropyl)-toluenediamine, dimethylethanolamine, dimethyl Bian amine, triethyl group benzyl ammonium chloride, benzyl-dimethylamine, the N-benzyl dimethylamine, 2,4,6,-three-(dimethylamino methyl)-phenol, the phenol formaldehyde (PF) hexamethylene diamine, N, the N-dimethyl benzylamine, the 2-ethyl imidazol(e), the 2-phenylimidazole, glyoxal ethyline, the 2-ethyl imidazol(e), 2-ethyl-4-methylimidazole, 1-(2-amino-ethyl)-glyoxal ethyline, maleic anhydride, the diphenyl ether tetracarboxylic dianhydride, phthalic anhydride, trimellitic anhydride, the tetrabromo-benzene dicarboxylic acid anhydride, gather acetic anhydride in the ninth of the ten Heavenly Stems, sebacic dihydrazide, AH, carbonic acid two hydrazides, oxalic acid two hydrazides, succinic acid hydrazide ii, adipic dihydrazide, the amino polyacrylamide of N-, the decanedioic acid hydrazides, the M-phthalic acid hydrazides, to the Para Hydroxy Benzoic Acid hydrazides, azelaic acid two hydrazides, isophthalic dihydrazide, the ferrocene tetrafluoroborate, TAC, toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate, hexamethylene diisocyanate, the trimethyl hexamethylene diisocyanate, dicyclohexyl methyl hydride diisocyanate, XDI, tetramethylxylylene diisocyanate, the methyl styrene isocyanates, the hexahydrotoluene vulcabond, triphenyl first-4,4 ', 4 '-triisocyanate, diaminodiphenyl-methane, the chlorophenyl of N--N-N-dimethyl urea, 3-phenyl-1, the 1-dimethyl urea, 3-rubigan-1, the 1-dimethyl urea, 4,4 '-the diamino-diphenyl bis-phenol, polyurethanes, Lauxite, epoxy-ethylenediamine carbamate, 2,4,6-three (dimethylamino methyl) phenol, 2, the 4-diaminotoluene, polyurethane, the methyl-etherified Lauxite, three (3-aminopropyl) amine, 2-amino-ethyl-two (3-aminopropyl) amine, 4,4 '-MDA, 4,4 '-the diamino-diphenyl bis-phenol, 4,4 '-DADPS, three (3-aminopropyl) amine, melmac, the benzoguanamine resin, hexamethylol melamine resin, the hexamethoxymethyl melamine resin, urea-melamine resin, the polyester melamine, the TCCA ester, aminotriazine resins, urethane acrylate, the 4-aminopyridine resin, the amino mylar of N-β-aminoethyl, the α-An Jibiding resin, aminodiphenylether resin, the phosphoramidic acid resin, the hydroxyethylamino mylar; Described microwave curing adhesive and hot setting adhesive use same material or different materials; Described anaerobic curing adhesive comprises: methacrylate tetraethylene-glycol ester, methacrylate multicondensed ethylene glycol ester, the triethylene Glycol double methyl methacrylate, the methacrylate glycol ester, hydroxyethyl methacrylate or hydroxypropyl acrylate, the methoxylated polyethylene glycol methacrylate, the phthalic acid Triethylene Glycol, Jia Jibingxisuanβ-Qiang Yizhi, the triethylene Glycol double methyl methacrylate, methacrylate sulfo-diethylene glycol (DEG) ester, phthalic acid two (diethylene glycol (DEG) acrylate), the ethoxylation bisphenol a dimethacrylate, dimethacrylate bisphenol-A ethylene glycol fat, second diester methacrylate, the triethylene-glycol dimethylacrylate, the condensed ethandiol double methyl methacrylate, glycol methacrylate, one diethyl acetal double methyl methacrylate, the epoxy resin methacrylate, methacrylate diglycol ester; Described electronic beam curing adhesive comprises: triphenol methylmethane tetraglycidel ether epoxy resin, the bicyclopentadiene bisphenol-type epoxy resin, the bisphenol A-type vinyl ester resin, epoxy vinyl ester resin, Epocryl, maleimide resin, 4,4 '-diphenyl methane dimaleimide, bisphenol-A-diphenyl ether BMI, bisphenol-A maleic acid vinylite, ethylene bromide base ester resin, the phenolic aldehyde epoxy vinyl ester resin, the methylolation bisphenol A type epoxy resin, the bisphenol-A acrylate, urethane acrylate, the bisphenol-A epoxy vinyl ester resin, bisphenol A benzoxazine-epoxy resin, bisphenol fluorene epoxy resin, the bisphenol-a epoxy acrylate resin, bisphenol A diglycidyl ether and bisphenol-A epoxy chloropropene acid esters resin.
6. flexible luminescent device substrate according to claim 1, it is characterized in that, described free radical type ultraviolet light polymerization-heat cured system, free radical type ultraviolet light polymerization-microwave curing system, free radical type ultraviolet light polymerization-anaerobic curing system, light trigger in free radical type ultraviolet light polymerization-electronic beam curing system comprises styrax and derivative benzoin methyl ether thereof, benzoin ethyl ether, acetophenone derivative and benzoin isopropyl ether, described cation type ultraviolet photo-curing-heat cured system, cation type ultraviolet photo-curing microwave curing system, cation type ultraviolet photo-curing-anaerobic curing system, cation light initiator in cation type ultraviolet photo-curing-electronic beam curing system comprises aromatic sulfonium salts, salt compounded of iodine or and the molysite class, sensitising agent comprises benzophenone, thia anthraquinone and Michler's keton, auxiliary agent comprise plasticizer and coupling agent.
7. flexible luminescent device substrate according to claim 6, it is characterized in that described plasticizer comprises: dioctyl phthalate, dibutyl phthalate, three vinyl butyl ether base phosphates, polyvinyl butyral resin, tributyl 2-acetylcitrate, repefral, diethyl phthalate, adipic acid two (butoxy ethyoxyl) ethyl ester, isopropyl titanate, tetrabutyl titanate, citrate, the own ester of trimellitic acid (2-ethyl), the own ester of phthalic acid two (2-ethyl), the own ester of decanedioic acid two (2-ethyl), the diglycol dibenzoate, phthalic anhydride, dipropylene glycol dibenzoate and chlorosulfonated polyethylene; Described coupling agent comprises the methyl ethylene dichlorosilane, methyl hydrogen dichlorosilane, dimethyldichlorosilane, chlorodimethyl silane, vinyl trichlorosilane, γ-An Bingjisanjiayangjiguiwan, dimethyl silicone polymer, poly-hydrogen methylsiloxane, poly-methyl methoxy radical siloxane, γ-methacrylic acid third vinegar base trimethoxy silane, gamma-aminopropyl-triethoxy-silane, γ-glycidol ether propyl trimethoxy silicane, the aminopropyl silsesquioxane, γ-methacryloxypropyl trimethoxy silane, the chain alkyl trimethoxy silane, VTES, vinyltrimethoxy silane, γ-chloropropyl triethoxysilane, two-(the silica-based propyl group of γ-triethoxy), anilinomethyl triethoxysilane, N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyl methyl dimethoxysilane, γ-(2,3-epoxy, third oxygen) propyl trimethoxy silicane, γ-(methacryloxypropyl) oxypropyl trimethyl silane, γ-Qiu Jibingjisanjiayangjiguiwan and γ-sulfydryl propyl-triethoxysilicane.
8. the preparation method of a flexible luminescent device usefulness substrate is characterized in that, may further comprise the steps:
1. the rigid substrates of surface roughness less than 1nm cleaned, clean the back and dry up with drying nitrogen;
2. take the mode of spin coating or spraying or self assembly or inkjet printing or serigraphy to prepare carbon nanotube layer at the rigid substrates of cleaning;
3. the adhesive layer that needs dual cure of spin coating or spraying doping inorganic light-emitting nano particle on carbon nanotube layer, or first spin coating or drip and to be coated with or to spray the solution that contains the inorganic light-emitting nano particle, spin coating or spraying need the adhesive layer of dual cure again, described dual cure by two independently cure stage finish, one of them stage is to react by ultraviolet light polymerization, another stage is dark reaction, the described adhesive of dual cure that needs comprises ultraviolet light polymerization-heat cured system, ultraviolet light polymerization-microwave curing system, ultraviolet light polymerization-anaerobic curing system and ultraviolet light polymerization-electronic beam curing system, when using ultraviolet light polymerization-heat cure or ultraviolet light polymerization-microwave curing system, the order that adopts is to be heating and curing earlier or microwave curing, carry out ultraviolet light polymerization then, be heating and curing again or microwave curing; Perhaps carry out ultraviolet light polymerization earlier, be heating and curing then or microwave curing, carry out ultraviolet light polymerization again;
4. the adhesive layer that needs dual cure after carbon nanotube layer and the curing or the adhesive that needs dual cure of doping inorganic light-emitting nano particle are peeled off the rigid substrates surface, form the compliant conductive substrate;
5. test transmitance, electrical conductivity, surface roughness, the surface filming uniformity of compliant conductive substrate, the tension parameters of conductive film.
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| CN103029355B (en) * | 2012-11-30 | 2015-05-13 | 电子科技大学 | Photoinduced bending flexible electro-conductive baseplate and preparation method thereof |
| EP3390542B1 (en) * | 2015-12-18 | 2021-10-06 | Essilor International | Liquid polymerizable composition comprising chain-growth and step-growth polymerization monomers and inorganic nanoparticles dispersed therein, and its use to manufacture an optical article |
| CN107868941B (en) * | 2016-09-27 | 2018-11-09 | 韩山师范学院 | The manufacturing method of down-conversion luminescent material |
| CN110713817B (en) * | 2018-07-12 | 2022-05-17 | 欧菲影像技术（广州）有限公司 | Adhesive and preparation method and application thereof |
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