CN102199534A - Solar-assisted biogas fermentation device and method - Google Patents
Solar-assisted biogas fermentation device and method Download PDFInfo
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- CN102199534A CN102199534A CN201110084281XA CN201110084281A CN102199534A CN 102199534 A CN102199534 A CN 102199534A CN 201110084281X A CN201110084281X A CN 201110084281XA CN 201110084281 A CN201110084281 A CN 201110084281A CN 102199534 A CN102199534 A CN 102199534A
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
- C12M41/12—Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
- C12M41/12—Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
- C12M41/18—Heat exchange systems, e.g. heat jackets or outer envelopes
- C12M41/24—Heat exchange systems, e.g. heat jackets or outer envelopes inside the vessel
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M43/00—Combinations of bioreactors or fermenters with other apparatus
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Abstract
The invention discloses a solar-assisted biomass fermentation device and a solar-assisted biomass fermentation method. The solar-assisted biomass fermentation device comprises elements such as a temperature sensor, a water inlet pipe, a thermal collector circulating pump, a hot water storage tank, an electric heating ring, a switch, an evacuated tube solar thermal collector, an angle demodulator, a solar storage battery and the like, wherein the hot water storage tank is connected with the evacuated tube solar thermal collector; the electric heating ring is arranged inside the hot water storage tank and is connected with the solar storage battery through a first conducting wire and the switch; the evacuated tube solar thermal collector produces the energy and transmits the energy to the solar storage battery through a battery connection board; the angle demodulator is positioned at the lower end of the battery connection board; the thermal collector circulating pump is arranged on the water inlet pipe; one end of the water inlet pipe is connected with the hot water storage tank and the other end of the water inlet pipe is connected with a water outlet pipe through a spiral radiating pipe; and the thermal collector circulating pump is connected with the temperature sensor through a second conducting wire. By the device and the method, the fermentation of biogas in highland areas where the solar radiation is strong and the temperature difference between day and night is high can be realized, and the yield of the biogas is improved.
Description
Technical field
The present invention relates to the biomass energy technology field, relate in particular to a kind of solar assisted methane fermentation device and method.
Background technology
Biogas is a kind of wide material sources, reproducible biomass energy, has the characteristics pollution-free, that preparation technique is simple, with low cost, in China rural area good popularization, application prospect is arranged.In recent years, marsh gas fermentation pool is greatly developed, is built in the rural area, and biogas has become one of applied leading new forms of energy in rural area from now on.The geographic solar energy resources in Qinghai-Tibet Platean is abundant, but temperature is lower, and the Chi Wenke of common brick tile structure methane-generating pit is reduced to the subzero several years, cause that temperature is lower than optimum fermentation temp in the pond, or make fermented product freeze, and had a strong impact on biogas output, reduced the utilising efficiency of methane-generating pit.
Summary of the invention
Technical problem to be solved by this invention provides a kind of solar assisted methane fermentation device and method, and it can realize the biogas fermentation of the highlands that solar radiation is strong, day and night temperature is big, and increases biogas output.
The present invention solves above-mentioned technical problem by following technical proposals: a kind of solar assisted methane fermentation device, it is characterized in that, described solar assisted methane fermentation device comprises temperature sensor, water inlet pipe, the heat collector recycle pump, hot water storage tank, add thermoelectric circle, switch, vacuum tube solar heating element, angle demodulator, solar storage battery, rising pipe, spiral radiator, first lead, second lead, cell connector, hot water storage tank is connected with vacuum tube solar heating element, add thermoelectric circle and be located at the inside of hot water storage tank, add thermoelectric circle by first lead, switch is connected with solar storage battery, the vacuum tube solar heating element generate energy also is transferred to solar storage battery through cell connector, angle demodulator is positioned at the lower end of cell connector, the heat collector recycle pump is installed on the water inlet pipe, one end of water inlet pipe is connected with hot water storage tank, the other end of water inlet pipe is connected with rising pipe by spiral radiator, and the heat collector recycle pump is connected with temperature sensor through second lead.
Preferably, described solar assisted methane fermentation device also comprises first warning light, second warning light, programmable logic controller, baroceptor, material level sensor, and temperature sensor, first warning light, second warning light, baroceptor, material level sensor all are connected with programmable logic controller.
Preferably, described solar assisted methane fermentation device also comprises standby power supply, and standby power supply is connected with hot water storage tank, household electricity.
The present invention also provides a kind of solar assisted methane fermentation process, it is characterized in that, this method adopts above-mentioned solar assisted methane fermentation device, and this method may further comprise the steps:
Step 1: judge the situation of sun power, if when sun power is sufficient, the water storage in the hot water storage tank is heated the water storage of hot water storage tank by vacuum tube solar heating element according to solar water heater's operating principle; If when sun power lacks, the then closed switch that is connected with first lead makes solar storage battery provide electric weight to adding thermoelectric circle, adds thermoelectric circle energising the water storage of hot water storage tank is heated;
Step 2: when treating that the detected natural pond of temperature sensor liquid temp is less than or equal to the optimum fermentation temp of biogas, temperature sensor sends signal by second lead to the heat collector recycle pump, and the heat collector recycle pump begins operation;
Step 3: hot water enters methane-generating pit by water inlet pipe, by spiral radiator fermented product in the methane-generating pit is heated, if when the natural pond liquid temp in the methane-generating pit is higher than optimum fermentation temp, the heat collector recycle pump stops operation.
Preferably, when the electric weight of the solar storage battery in the described step 1 exhausts, standby power supply and household electricity are connected.
Preferably, when the heat collector recycle pump in the described step 3 stopped operation, if sun power is when sufficient, then vacuum tube solar heating element became electric energy to be stored in the solar storage battery thermal power transfer that absorbs.
Positive progressive effect of the present invention is:
(1) solar assisted methane fermentation device of the present invention and method save energy, not needing to ferment with other fuel heats, and can reduce the biogas fermentation cost, guarantees that leavening temperature is constant in the methane-generating pit.
(2) solar assisted methane fermentation device of the present invention and method methane-generating pit seriously the freezing in the winter time the time that can prevent northern China common brick tile structure, by vacuum tube solar heating element, spiral radiator etc., no matter winter Xia Junke accomplishes thermophilic fermentation, effectively increases biogas output.
(3) solar assisted methane fermentation device of the present invention and method have realized the automatic routine control to fermented product heating, charging of accumulators in the pond.
(4) solar assisted methane fermentation device of the present invention has standby power supply, solar storage battery etc., can make the influence that the present invention is not changed by outside air temperature and rainy weather to have improved the operation scope of application of the present invention in marsh gas fermentation processes.
(5) solar assisted methane fermentation device of the present invention and method can realize heating, the automatic control and the monitoring of biogas air pressure, fermented product storage capacity, need not manual work, time saving and energy saving.
(6) solar assisted methane fermentation device of the present invention is simple in structure, compact, can directly be reequiped utilization on existing common methane-generating pit, meets the modern rural novel energy source device of present China and promotes requirement.
Description of drawings
Fig. 1 is the structural representation of solar assisted methane fermentation device of the present invention.
Fig. 2 is that vacuum tube solar heating element of the present invention is with the inner water storage heating of hot water storage tank schematic diagram.
Schema when Fig. 3 is temperature sensor of the present invention and the work of heat collector recycle pump.
Embodiment
Provide preferred embodiment of the present invention below in conjunction with accompanying drawing, to describe technical scheme of the present invention in detail.
As depicted in figs. 1 and 2, solar assisted methane fermentation device of the present invention comprises the solar energy heating accumulating system, the natural pond liquid heating water storage recycle system, fermented product storage capacity and biogas pressure monitoring system, solar assisted methane fermentation device of the present invention specifically comprises temperature sensor 1, water inlet pipe 2, heat collector recycle pump 3, standby power supply 4, hot water storage tank 5, add thermoelectric circle 6, switch 7, vacuum tube solar heating element 8, angle demodulator 9, solar storage battery 10, rising pipe 11, spiral radiator 12, first lead 131, second lead 132, cell connector 14, first warning light 151, second warning light 152, programmable logic controller (Programmable Logic Controller, PLC) 16, baroceptor 17, material level sensor 18.Wherein, the solar energy heating accumulating system comprises hot water storage tank 5, add thermoelectric circle 6, switch 7 and vacuum tube solar heating element 8, angle demodulator 9, solar storage battery 10, first lead 131, cell connector 14, the natural pond liquid heating water storage recycle system comprises water inlet pipe 2, heat collector recycle pump 3, rising pipe 11 and spiral radiator 12, hot water storage tank 5 is connected with vacuum tube solar heating element 8, vacuum tube solar heating element 8 is made of a valve tube at least, add thermoelectric circle 6 and be located at the inside of hot water storage tank 5, add thermoelectric circle 6 by first lead 131, switch 7 is connected with solar storage battery 10.Vacuum tube solar heating element 8 generate energys also are transferred to solar storage battery 10 through cell connector 14.Angle demodulator 9 is positioned at the lower end of cell connector 14, can realize that vacuum tube solar heating element 8 carries out 30～90 ° adjusting.Heat collector recycle pump 3 is installed on the water inlet pipe 2.One end of water inlet pipe 2 is connected with hot water storage tank 5, and the other end of water inlet pipe 2 is connected with rising pipe 11 by spiral radiator 12.Heat collector recycle pump 3 is connected with temperature sensor 1, programmable logic controller 16 through second lead 132.Standby power supply 4 is connected with hot water storage tank 5, household electricity, when no electric weight or produce electric weight and be not enough to drive when adding thermoelectric circle 6, standby power supply 4 and household electricity are connected, and standby power supply 4 is given hot water storage tank 5 and added thermoelectric circle 6 provides electric energy, and methane-generating pit can work on like this.Fermented product storage capacity and biogas pressure monitoring system comprise temperature sensor 1, first warning light 151, second warning light 152, programmable logic controller 16, baroceptor 17, material level sensor 18; Wherein temperature sensor 1, first warning light 151, second warning light 152, baroceptor 17, material level sensor 18 all are connected with programmable logic controller 16, control respective element work with this; When material level sensor 18 sends signal, 152 flickers of second warning light, it specifically is the maximum capacity limit place that material level sensor 18 is installed in methane-generating pit fermented product capacity, when the fermented product amount in the methane-generating pit increases to material level sensor place, material level sensor 18 sends electronic signal, by the processing of 16 pairs of these electronic signals of programmable logic controller, 152 flickers of second warning light remind the user should in time discharge the interior fermented product raw material of methane-generating pit.Baroceptor 17 is installed in the methane-generating pit ingress, when baroceptor 17 sends signal, 151 flickers of first warning light, specifically be to set a standard pressure value (the standard pressure value is that methane-generating pit bears atmospheric pressure value to greatest extent) for baroceptor 17, when the biogas air pressure that produces in the methane-generating pit surpassed this standard pressure value, baroceptor 17 sent electronic signal; By the processing of 16 pairs of these electronic signals of programmable logic controller, 151 flickers of first warning light remind the user should in time handle, use a large amount of biogas that produced.Like this, realize the automatic control and the monitoring of heating, biogas air pressure, fermented product storage capacity by temperature sensor 1, first warning light 151, second warning light 152, programmable logic controller 16, baroceptor 17, material level sensor 18.
Temperature sensor 1 is mainly used in detection when natural pond liquid temp in the methane-generating pit during less than the optimum fermentation temp of biogas, sends signal by second lead 132 to heat collector recycle pump 3; Water inlet pipe 2 is mainly used in the hot water in the hot water storage tank 5 is inputed in spiral radiator 12 and the whole heating unit; Heat collector recycle pump 3 is mainly used in the internal hot-water of hot water storage tank 5 circulation power in addition, the circulating of assurance device internal hot-water; Standby power supply 4 is mainly used in when inner the no electric weight of heating unit or produces electric weight and is not enough to drive when adding thermoelectric circle operation, itself and household electricity connection can be satisfied the device job requirements; Hot water storage tank 5 is mainly used in the storage of the inner heating of device water; Add thermoelectric circle 6 and be mainly used in when meeting overcast and rainy or night, during the solar heating disabler, can be by adding thermoelectric circle energising operation, the hot water temperature in the assurance device during biogas fermentation can continue aerogenesis; Switch 7 is mainly used in the situation that is switched on or switched off that adds between thermoelectric circle and the store battery of controlling; Vacuum tube solar heating element 8 is mainly used in by solar heat, and the tap water that the temperature in the hot water storage tank is lower is heated to device needs temperature; Angle demodulator 9 is mainly used in by manual shift, and the angle of radiation maximum of the vacuum tube solar heating element and the sun guarantees best endothermic effect in the assurance device; Solar storage battery 10 is mainly used in when the valve tube solar energy collector and stops when hot water storage tank provides energy, the heat that absorbs this moment is converted into electric energy stores; Rising pipe 11 is mainly used in and exports the water at low temperature in the whole heating unit to hot water storage tank and heat; The main spirals by its different depths of spiral radiator 12 distribute, and the hot water heat that flows through by means of its inside is with the fermented product heating of methane-generating pit inside; First lead 131 is mainly used in the connection conduction that adds thermoelectric circle, switch and solar storage battery; Second lead 132 is mainly used in being connected of temperature sensor and heat collector recycle pump, makes things convenient for the temperature signal transmission; Cell connector 14 is mainly used in the energy that vacuum tube solar heating element is produced and is transferred to solar storage battery.First warning light 151 is mainly used in when baroceptor sends signal, and flicker reminds the user should in time handle, use a large amount of biogas that produced.Second warning light 152 is mainly used in when the material level sensor sends signal, and flicker reminds the user should in time discharge the interior fermented product raw material of methane-generating pit.Programmable logic controller 16 is mainly used in temperature sensor, baroceptor, level sensor, first warning light, second warning light is sent signal instruction and control.Baroceptor 17 is mainly used in and detects the limit of bearing whether the biogas air pressure that produces in the methane-generating pit surpasses this methane-generating pit setting.Material level sensor 18 is mainly used in detection biogas fermentation thing capacity and whether reaches methane-generating pit maximum capacity limit.
The present invention also provides a kind of solar assisted methane fermentation process, and it comprises the steps:
Step 1: judge the situation of sun power, handle according to different situations.If when sun power abundance (such as sunny weather, sunshine abundance), then the water storage in the hot water storage tank 5 is heated the water storage of hot water storage tank 5 by vacuum tube solar heating element 8 according to solar water heater's operating principle.If when sun power lacks (such as rainy weather, inadequate, night at sunshine), the water storage heating that then relies on 8 pairs of hot water storage tanks 5 of vacuum tube solar heating element can not the time, the closed switch 7 that is connected with first lead 131, solar storage battery 10 is in discharge condition, make 10 pairs of solar storage batteries add thermoelectric circle 6 electric weight is provided, add thermoelectric circle 6 energisings the water storage of hot water storage tank 5 is heated.When if the electric weight of solar storage battery 10 exhausts, standby power supply 4 and household electricity are connected.
Step 2: as shown in Figure 3, when treating that temperature sensor 1 detected natural pond liquid temp is less than or equal to the optimum fermentation temp of biogas (optimum fermentation temp is the setting working value of heat collector recycle pump 3), temperature sensor 1 sends signal by programmable logic controller 16 controls and by second lead 132 to heat collector recycle pump 3, the 3 beginning operations of heat collector recycle pump.
Step 3: as shown in Figure 3, hot water enters methane-generating pit by water inlet pipe 2, heats by fermented product in 12 pairs of methane-generating pits of spiral radiator, if when the natural pond liquid temp in the methane-generating pit is higher than optimum fermentation temp, heat collector recycle pump 3 stops operation.
When heat collector recycle pump 3 stopped operation, if sun power is when sufficient, then vacuum tube solar heating element 8 became electric energy to be stored in (being that solar storage battery 10 is in charging state) in the solar storage battery 10 thermal power transfer that absorbs.
Solar assisted methane fermentation device of the present invention is heated to water storage at sun power under 66～90 ℃ the situation, and under the effect of heat collector recycle pump, per hour fermentation materials heats up 2～3 ℃ in the fermentation vat.When being in 21 ℃ of left and right sides of external temperature in summer, this moment, the methane-generating pit temperature was about 14～16 ℃, carried out 13～16 hours operation by solar assisted methane fermentation device of the present invention, and just can reach the interior fermented product temperature of methane-generating pit is more than 48 ℃.To this device observation thermometry, found through experiments, find that in 25 days observation this device can be regulated automatically, the methane-generating pit leavening temperature is influenced by extraneous natural temperature hardly, and the variation equilibrium in the week in the methane-generating pit is between 2～3 ℃.Use this device and carry out 32 days test, test-results is as follows:
Different fermentations thing fermentation time limit and temperature are produced the relation table (1m of biogas speed
3The fermentation vat volume)
| The fermented product kind | Temperature/℃ | Concentration/% | Fate/d | Factor of created gase (ml/g) |
| Human excrement+stalk | 48 | 15 | 9.5 | 3960 |
| Chicken manure+stalk | 49 | 16 | 8.5 | 4010 |
| Pig manure+stalk | 47.5 | 15 | 7 | 3850 |
| Cow dung+stalk | 48 | 16 | 6 | 3600 |
Test-results shows: solar assisted methane fermentation device of the present invention can make various biogas fermentation things commonly used under steady temperature comparatively, the time of aerogenesis shortens 3～4 times greatly, more common methane tank gas production efficient has improved 3.5 times more than, can improve the utilization benefit of this device greatly.
Though more than described the specific embodiment of the present invention, it will be understood by those of skill in the art that these instrument are to illustrate, under the prerequisite that does not deviate from principle of the present invention and essence, can make numerous variations or modification to these embodiments.Therefore, protection scope of the present invention is limited by appended claims.
Claims (6)
1. solar assisted methane fermentation device, it is characterized in that, described solar assisted methane fermentation device comprises temperature sensor, water inlet pipe, the heat collector recycle pump, hot water storage tank, add thermoelectric circle, switch, vacuum tube solar heating element, angle demodulator, solar storage battery, rising pipe, spiral radiator, first lead, second lead, cell connector, hot water storage tank is connected with vacuum tube solar heating element, add thermoelectric circle and be located at the inside of hot water storage tank, add thermoelectric circle by first lead, switch is connected with solar storage battery, the vacuum tube solar heating element generate energy also is transferred to solar storage battery through cell connector, angle demodulator is positioned at the lower end of cell connector, the heat collector recycle pump is installed on the water inlet pipe, one end of water inlet pipe is connected with hot water storage tank, the other end of water inlet pipe is connected with rising pipe by spiral radiator, and the heat collector recycle pump is connected with temperature sensor through second lead.
2. solar assisted methane fermentation device as claimed in claim 1, it is characterized in that, described solar assisted methane fermentation device also comprises first warning light, second warning light, programmable logic controller, baroceptor, material level sensor, and temperature sensor, first warning light, second warning light, baroceptor, material level sensor all are connected with programmable logic controller.
3. solar assisted methane fermentation device as claimed in claim 2 is characterized in that described solar assisted methane fermentation device also comprises standby power supply, and standby power supply is connected with hot water storage tank, household electricity.
4. a solar assisted methane fermentation process is characterized in that, this method adopts as solar assisted methane fermentation device as described in the claim 3, and this method may further comprise the steps:
Step 1: judge the situation of sun power, if when sun power is sufficient, the water storage in the hot water storage tank is heated the water storage of hot water storage tank by vacuum tube solar heating element according to solar water heater's operating principle; If when sun power lacks, the then closed switch that is connected with first lead makes solar storage battery provide electric weight to adding thermoelectric circle, adds thermoelectric circle energising the water storage of hot water storage tank is heated;
Step 2: when treating that the detected natural pond of temperature sensor liquid temp is less than or equal to the optimum fermentation temp of biogas, temperature sensor sends signal by second lead to the heat collector recycle pump, and the heat collector recycle pump begins operation;
Step 3: hot water enters methane-generating pit by water inlet pipe, by spiral radiator fermented product in the methane-generating pit is heated, if when the natural pond liquid temp in the methane-generating pit is higher than optimum fermentation temp, the heat collector recycle pump stops operation.
5. solar assisted methane fermentation process as claimed in claim 4 is characterized in that, when the electric weight of the solar storage battery in the described step 1 exhausts, standby power supply and household electricity is connected.
6. solar assisted methane fermentation process as claimed in claim 4, it is characterized in that, when the heat collector recycle pump in the described step 3 stopped operation, if sun power is when sufficient, then vacuum tube solar heating element became electric energy to be stored in the solar storage battery thermal power transfer that absorbs.
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| CN107164226A (en) * | 2017-05-27 | 2017-09-15 | 梁树钦 | A kind of local adjustable fermentation tank of internal temperature |
| CN107267372A (en) * | 2017-08-17 | 2017-10-20 | 安徽益佳园环境工程有限公司 | A kind of solar biogas, aerogenesis, air storage integrated glass fiber reinforced plastic composite device |
| CN107840552A (en) * | 2017-12-20 | 2018-03-27 | 皖西学院 | It is a kind of to utilize solar energy and the rural domestic sewage treatment system of wind energy |
| CN108101302A (en) * | 2017-12-20 | 2018-06-01 | 皖西学院 | Utilize solar energy and the rural domestic sewage treatment system of wind energy |
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| CN107267372A (en) * | 2017-08-17 | 2017-10-20 | 安徽益佳园环境工程有限公司 | A kind of solar biogas, aerogenesis, air storage integrated glass fiber reinforced plastic composite device |
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| CN102199534B (en) | 2013-08-07 |
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