CN102190914A - Formula of thermal-spraying colorants for toughened glass - Google Patents

Formula of thermal-spraying colorants for toughened glass Download PDF

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Publication number
CN102190914A
CN102190914A CN2011100550648A CN201110055064A CN102190914A CN 102190914 A CN102190914 A CN 102190914A CN 2011100550648 A CN2011100550648 A CN 2011100550648A CN 201110055064 A CN201110055064 A CN 201110055064A CN 102190914 A CN102190914 A CN 102190914A
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China
Prior art keywords
dissolved
hcl
solvent
sncl
dissolving
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CN2011100550648A
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Chinese (zh)
Inventor
程忠付
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DUYUN DEVELOPMENT ZONE FUTIAN CHEMICAL Co Ltd
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DUYUN DEVELOPMENT ZONE FUTIAN CHEMICAL Co Ltd
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Priority to CN2011100550648A priority Critical patent/CN102190914A/en
Publication of CN102190914A publication Critical patent/CN102190914A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a formula of thermal-spraying colorants for toughened glass. A light green colorant is formed by dissolving CrO3 in HCl or purified water; a golden yellow colorant is formed by dissolving AgNo3 in the water; a sky blue colorant is formed by dissolving CrCl2 in the HCl; a dusty blue colorant is formed by dissolving SnCl4.5H2O and SnCl2.2H2O in the HCl or ethanol; a grey purple colorant is formed by dissolving SnCl4.5H2O and SnCl2.2H2O in the HCl or the ethanol; a brownish yellow colorant is formed by dissolving FeCl3.6H2O in the HCl or the ethanol; a smoky grey colorant is formed by dissolving Co(CH3COO)2.4H2O in the water; an orange colorant is formed by dissolving SnCl4.5H2O and FeCl3.6H2O in the HCl or the ethanol and adding SnCl4 and FeCl3 in sequence to prevent precipitation; a pale orange colorant is formed by dissolving CuCl in the HCl; and a light pink colorant is formed by dissolving SnCl4.5H2O and CrO3 in the HCl and adding SnCl4 and CrO3 in sequence. Different colors are formed on a glass surface, which is colorful.

Description

Toughened glass thermospray color dyes agent prescription
Technical field
The present invention relates to the thermospray tinting material, distinct colors relates in particular to toughened glass thermospray color dyes agent prescription with the painted technology of different metal inorganic salt solution sprayings.
Background technology
The thermospray of glass is that one or more metal salt solutions are sprayed to the heating glass surface, glass arrives the colour attaching area of spray booth through the high-temperature zone from the tempering body of heater, under the certain temperature condition, be sprayed onto the coating substance of glass surface, it is oxide film that the heat of dependence glass itself makes the coating substance pyrolysis, thereby form the plated film coating, thermospray is painted to be compared with the conventional color process of glass, it is simple to have equipment, work simplification, cost is low, advantages such as the transposing color is convenient, also can spray continuously, be suitable for using on the glass automatic forming line, utilize heat spraying method to use different spray colouration agent can produce the glassy product of different colours, make glass surface have the conduction reflection, performances such as heat absorption and absorption ultraviolet ray, therefore be widely used in building, lighting, aspect such as daily utensil and art glass is for new field has been opened up in the manufacturing of coloured glass.
Summary of the invention
The purpose of this invention is to provide and produce toughened glass thermospray color dyes agent prescription, produce the toughened glass of various different colours, make toughened glass produce the prescription of different colours through thermospray:
The contained quantity of metal-salt solute is by gram in every 100ml solvent, and the component of solute, solvent and quantity are prepared by following color:
1, light green: CrO 340-60g is a solute, is dissolved in the solvent of HCl or pure water;
2, golden yellow: AgNo 350-70g is dissolved in the pure water with the bottled AgNo of brown glass 3, matching while using solution;
3, sky blue: CrCl 250-75g is dissolved in the HCl solvent;
4, dusty blue: SnCl 4.5H 2O80-100g adds SnCl 2.2H 2O5-15g is dissolved in HCl or the alcohol solvent;
5, gray purple: SnCl 45H 2O70-90g adds SnCl 22H 2O13-33g is dissolved in HCl or the alcohol solvent;
6, pale brown look: FeCl 36H 2O40-60g is dissolved in HCl or the alcohol solvent;
7, smoky gray: Co (CH 3COO) 24H 2O5-20g is dissolved in the distilled water, and water temperature is 60-80 ℃ of dissolving;
8, orange: SnCl 45H 2O20-40g adds FeCl 36H 2O20-40g is dissolved in HCl or the alcohol solvent, should add SnCl earlier 4Add FeCl again 3In case precipitation;
9, greenish orange yellow: CuCl5-15g is dissolved in the HCl solvent;
10, light pink: SnCl 45H 2O80-105g adds CrO 32-9g is dissolved in the HCl solvent, adds SnCl earlier 4After add CrO 3
Adopt the thermospray solution of above-mentioned metal-salt solute and solvent preparation, can produce above-mentioned different colours more than 10 kinds at glass surface, make the toughened glass product of different purposes form colorful, dazzlingly beautiful, prismy glass articles for use, enrich people's life, satisfy pursuit and the hobby of people different color.
Embodiment
Toughened glass thermospray color dyes agent prescription of the present invention, details are as follows again for embodiment:
The contained quantity of metal-salt solute is produced following shades of colour by gram as the thermospray solution of toughened glass in every 100ml solvent:
1, light green: CrO 350g is dissolved in the HCl solvent, or CrO 350g is dissolved in the solvent of pure water;
2, golden yellow: AgNO 360g is dissolved in the pure water AgNo 3With the bottled matching while using solution of brown glass;
3, sky blue: CrCl 265g is dissolved in the HCl solvent;
4, dusty blue: SnCl 4.5H 2Og92g+SnCl 2.2H 2O9.5g is dissolved in HCl or the alcohol solvent;
5, gray purple: SnCl 45H 2O80g+SnCl 22H 2O23.8g is dissolved in HCl or the alcohol solvent;
6, pale brown look: FeCl 36H 2O50g is dissolved in HCl or the alcohol solvent;
7, smoky gray: Co (CH 3COO) 24H 2O13g is dissolved in the distilled water, and water is heated 60-80 ℃ of promotion dissolving;
8, orange: SnCl 45H 2O30g+FeCl 36H 2O30g is dissolved in HCl or the alcohol solvent, should add SnCl earlier 4Add FeCl again 3In case precipitation;
9, greenish orange yellow: CuCl12g is dissolved in the HCl solvent;
10, light pink: SnCl 45H 2O96g+CrO34g is dissolved in the HCl solvent, adds SnCl earlier 4After add CrO 3

Claims (2)

1. toughened glass thermospray color dyes agent prescription is characterized in that: the contained quantity of metal-salt solute is by gram in every 100ml solvent, and following color is produced in the component of solute, solvent and quantity preparation:
1), light green: CrO 340-60g is a solute, is dissolved in the solvent of HCl or pure water;
2), golden yellow: AgNO 350-70g is dissolved in the pure water, with the bottled AgNO of brown glass 3, matching while using solution;
3), sky blue: CrCl 250-75g is dissolved in the HCl solvent;
4), dusty blue: SnCl 4.5H 2O80-100g adds SnCl 2.2H 2O5-15g is dissolved in HCl or the alcohol solvent;
5), gray purple: SnCl 45H 2O70-90g adds SnCl 22H 2O13-33g is dissolved in HCl or the alcohol solvent;
6), pale brown look: FeCl 36H 2O40-60g is dissolved in HCl or the alcohol solvent;
7), smoky gray: Co (CH 3COO) 24H 2O5-20g is dissolved in the distilled water, and water temperature is dissolved at 60-80;
8), orange: SnCl 45H 2O20-40g adds FeCl 36H 2O20-40g is dissolved in HCl or the alcohol solvent, should add SnCl earlier 4Add FeCl again 3In case precipitation;
9), greenish orange yellow: CuCl5-15g is dissolved in the HCl solvent;
10), light pink: SnCl 45H 2O80-105g adds CrO 32-9g is dissolved in the HCl solvent, adds SnCl earlier 4After add CrO 3
2. toughened glass thermospray color dyes agent prescription according to claim 1 is characterized in that: the contained quantity of metal-salt solute is by gram in every 100ml solvent, and solvent is produced following color by the component and the quantity preparation of ml solute, solvent:
1), light green: CrO 350g is dissolved in the HCl solvent, or CrO 350g is dissolved in the solvent of pure water;
2), golden yellow: AgNO 360g is dissolved in the pure water AgNO 3With the bottled matching while using solution of brown glass;
3), sky blue: CrCl 265g is dissolved in the HCl solvent;
4), dusty blue: SnCl 4.5H 2Og92g+SnCl 2.2H 2O9.5g is dissolved in HCl or the alcohol solvent;
5), gray purple: SnCl 45H 2O80g+SnCl 22H 2O23.8g is dissolved in HCl or the alcohol solvent;
6), pale brown look: FeCl 36H 2O50g is dissolved in HCl or the alcohol solvent;
7), smoky gray: Co (CH 3COO) 24H 2O13g is dissolved in the distilled water, and water is heated 60-80 ℃ of promotion dissolving;
8), orange: SnCl 45H 2O30g+FeCl 36H 2O30g is dissolved in HCl or the alcohol solvent, should add SnCl earlier 4Add FeCl again 3In case precipitation;
9), greenish orange yellow: CuCl12g is dissolved in the HCl solvent;
10), light pink: SnCl 45H 2O96g+CrO 34g is dissolved in the HCl solvent, adds SnCl earlier 4After add CrO 3
CN2011100550648A 2011-03-09 2011-03-09 Formula of thermal-spraying colorants for toughened glass Pending CN102190914A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011100550648A CN102190914A (en) 2011-03-09 2011-03-09 Formula of thermal-spraying colorants for toughened glass

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Application Number Priority Date Filing Date Title
CN2011100550648A CN102190914A (en) 2011-03-09 2011-03-09 Formula of thermal-spraying colorants for toughened glass

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CN102190914A true CN102190914A (en) 2011-09-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106795034A (en) * 2014-09-30 2017-05-31 波米欧利罗克股份有限公司 The method of hot preparation coloured glass fragment of brick

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640834A (en) * 2004-01-17 2005-07-20 德州振华装饰玻璃有限公司 Colour glass brown colouring pigment and its preparing process
CN1640835A (en) * 2004-01-17 2005-07-20 德州振华装饰玻璃有限公司 Colour glass blue colouring pigment and its preparing process
CN1640833A (en) * 2004-01-17 2005-07-20 德州振华装饰玻璃有限公司 Colour glass green colouring pigment and its preparing process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640834A (en) * 2004-01-17 2005-07-20 德州振华装饰玻璃有限公司 Colour glass brown colouring pigment and its preparing process
CN1640835A (en) * 2004-01-17 2005-07-20 德州振华装饰玻璃有限公司 Colour glass blue colouring pigment and its preparing process
CN1640833A (en) * 2004-01-17 2005-07-20 德州振华装饰玻璃有限公司 Colour glass green colouring pigment and its preparing process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王承遇等: "《玻璃表面装饰(第2版)》", 31 January 2011, article "色釉的着色剂和色素", pages: 211-219 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106795034A (en) * 2014-09-30 2017-05-31 波米欧利罗克股份有限公司 The method of hot preparation coloured glass fragment of brick
CN106795034B (en) * 2014-09-30 2020-06-16 波米欧利罗克股份有限公司 Method for thermally producing colored glass blocks

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Application publication date: 20110921