CN102174293B - Golden spraying liquid and production method for preparing golden glass ceramic from same - Google Patents
Golden spraying liquid and production method for preparing golden glass ceramic from same Download PDFInfo
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- CN102174293B CN102174293B CN 201110026085 CN201110026085A CN102174293B CN 102174293 B CN102174293 B CN 102174293B CN 201110026085 CN201110026085 CN 201110026085 CN 201110026085 A CN201110026085 A CN 201110026085A CN 102174293 B CN102174293 B CN 102174293B
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- 238000005507 spraying Methods 0.000 title claims abstract description 29
- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000007788 liquid Substances 0.000 title abstract 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims description 16
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 238000002425 crystallisation Methods 0.000 claims description 9
- 230000008025 crystallization Effects 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 238000011282 treatment Methods 0.000 claims description 7
- SJUCACGNNJFHLB-UHFFFAOYSA-N O=C1N[ClH](=O)NC2=C1NC(=O)N2 Chemical compound O=C1N[ClH](=O)NC2=C1NC(=O)N2 SJUCACGNNJFHLB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 238000005485 electric heating Methods 0.000 claims description 3
- 239000006210 lotion Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 abstract description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 239000000047 product Substances 0.000 description 47
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- 229910021532 Calcite Inorganic materials 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 241000237502 Ostreidae Species 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000006132 parent glass Substances 0.000 description 1
- -1 produces refraction Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
The invention discloses golden spraying liquid and a production method for preparing golden glass ceramic from the same. The golden spraying liquid is characterized by being prepared from the following components in percentage by weight: 0.1 to 0.3 percent of tetrachloroauric acid, 5.5 to 7.5 percent of copper nitrate, 1.5 to 2.5 percent of bismuth nitrate, 1.5 to 2.5 percent of titanium tetrachloride, 13 to 17 percent of rosin resin, 18 to 24 percent of 200# solvent oil and 50 to 57 percent of turpentine. The golden glass ceramic prepared from the golden spraying liquid has a bright and stable color, the production process is environment-friendly, special electroplating equipment is not required to be added, and cost is saved.
Description
Technical field
The present invention relates to the glass-ceramic field, specifically a kind of golden spray coating liquor and make the production method of aurene pottery with it.
Background technology
Glass-ceramic has another name called for " opaque glass ", " devitrified glass ", is smelted into parent glass take quartz as main raw, processes through overmolding and crystallization, makes device shape and uses functional similarity in the product (as cup, dish, bowl etc.) of pottery.
Conventional glass-ceramic is all oyster white or edematus, because product color is dull, be difficult to satisfy the modern consumption crowd and product used the double requirements of function and outward appearance art, in the glass-ceramic production industry, the employing plating mode has been arranged, plate one deck the colorful one coating to product, but the product that this plating mode is produced, the texture that can not reflect glass-ceramic, and can bring serious pollution in manufacturing processed, not welcome by the human consumer.How to make simultaneously product material production colour-change in the formed product process, and this color is will never fade, makes glass and ceramic product possess multicolour, be the research of technique difficult problem in the glass-ceramic industry always.
Summary of the invention
The objective of the invention is to solve the colour-change of glass-ceramic production material, a kind of golden spray coating liquor is provided and makes the production method of aurene pottery with it.
Golden spray coating liquor of the present invention, it is characterized in that, made by following compositions in weight percentage: tetra chlorauric acid 0.1～0.3%, cupric nitrate 5.5～7.5%, Bismuth trinitrate 1.5～2.5%, titanium tetrachloride 1.5～2.5%, Gum Rosin 13～17%, 200# solvent oil 18～24%, turps 50～57%.
The production method of described golden spray coating liquor is characterized in that, first Gum Rosin is heated to 140～160 ℃, and constant temperature kept 4～6 hours, made its melting, then added successively cupric nitrate, Bismuth trinitrate, titanium tetrachloride, after the question response thing becomes the brownish black lotion, constant temperature keeps slowly adding tetra chlorauric acid after 1～3 hour, stirs homogenizing 1～3 hour, be cooled to 80～120 ℃, add successively 200# solvent oil, turps, constant temperature stirred 1～3 hour, made golden spray coating liquor.
Golden spray coating liquor of the present invention need to adopt the glass-ceramic of special material to be used in conjunction with, in composition and the proportioning of this this glass-ceramic of simple declaration.
The glass-ceramic that is exclusively used in the golden spray coating liquor of the present invention contains following composition: SiO by weight percentage
262～68%, Al
2O
32～4%, B
2O
311～15%, Na
2O 6.5～8.5%, K
2O0.4～1%, CaO 3～5%, and BaO 0.05～0.3%, and ZnO 0.5～2%, Fe
2O
30.01～0.05%, F
23～6%, P
2O
50.1～1%, CeO
20.1～0.5%.
Above-mentioned glass-ceramic, preferably made by following compositions in weight percentage: quartz sand 40～60%, aluminum oxide 1～3%, calcite 5～8%, Sodium Silicofluoride 4～7%, BORAX PENTAHYDRATE-99.9 MIN 14～21%, boric acid 4～7%, zinc oxide 0.5～2%, saltpetre 0.5～2%, primary ammonium phosphate 0.5～2%, cerium oxide 0.1～1%, useless opaque glass 5～15%.
The production method of aurene pottery of the present invention is characterized in that, comprises following production stage:
(1), the glass-ceramic raw material is carried out melting under 1400～1550 ℃, form glass metal standby;
(2), adopt steel mould, will inject the die cavity of mould through the glass metal of melting, when glass metal was cooled to 550～650 ℃, the preliminary coagulation forming of glass metal took out product with fixture;
(3), the depanning product is placed on rotation platform, adopt spray gun, golden spray coating liquor is evenly sprayed product surface; Because product temperature this moment is 550～650 ℃, when spray coating liquor touches product, absorbed and mummification by product surface at once, make product surface become silvery white;
(4), will put into electric heating Temperature Treatment stove through the product of spraying and carry out crystallization and process, treatment temp is 550～650 ℃, the time is 20～40 minutes; The process that crystallization is processed is to make metal object in sprayed coating be penetrated into plane of crystal in the product material, and with the plane of crystal mortise;
(5), the product after crystallization is processed takes out, and naturally is cooled to normal temperature, product progressively presents gold, makes aurene ceramic product of the present invention.Because firmly ooze with metal object on the glass crystal surface in product, product is smooth through cooling rear surface, and light sees through the microcrystal in the product material, produces refraction, product appearance is produced golden, forms the aurene ceramic product.
With the aurene pottery that golden spray coating liquor of the present invention is made, bright in colour stable, the pollution that produces in process of production is little, need not to increase special electroplating device, provides cost savings.
Description of drawings
Fig. 1 is the product picture that the embodiment of the present invention is produced.
Embodiment
The present invention will be described in detail to reach by the following examples Comparative Examples.
Embodiment:
(1) prepare by weight percentage following golden spray coating liquor raw material: tetra chlorauric acid 0.2%, cupric nitrate 6.8%, Bismuth trinitrate 2.0%, titanium tetrachloride 2.0%, Gum Rosin 15%, 200# solvent oil 21%, turps 53%;
(2) first Gum Rosin is heated to 150 ℃, and constant temperature kept 5 hours, made its melting, then added successively cupric nitrate, Bismuth trinitrate, titanium tetrachloride, after the question response thing becomes the brownish black lotion, constant temperature keeps slowly adding tetra chlorauric acid after 2 hours, stirs homogenizing 2 hours, be cooled to 100 ℃, add successively 200# solvent oil, turps, constant temperature stirred 2 hours, made at last golden spray coating liquor standby;
(3) prepare by weight percentage following glass-ceramic raw material: quartz sand 50%, aluminum oxide 1.63%, calcite 6.7%, Sodium Silicofluoride 5.91%, BORAX PENTAHYDRATE-99.9 MIN 17.8%, boric acid 6.09%, zinc oxide 0.88%, saltpetre 0.84%, primary ammonium phosphate 0.81%, cerium oxide 0.34%, useless opaque glass 9.0%;
(4) the glass-ceramic raw material is carried out melting under 1500 ℃, form glass metal;
(5) adopt steel mould, will inject through the glass metal of melting the die cavity of mould, when 600 ℃ of glass metal coolings, take out product with fixture;
After testing, the product of making this moment contains following composition: SiO by weight percentage
265.01%, Al
2O
33.10%, B
2O
313.40%, Na
2O 7.45%, K
2O 0.60%, and CaO 4.10%, and BaO 0.18%, and ZnO 1.0%, Fe
2O
30.01%, F
24.40%, P
2O
50.50%, CeO
20.25%;
(6) the depanning product is placed on rotation platform, adopts spray gun, golden spray coating liquor is evenly sprayed product surface;
(7) will put into electric heating Temperature Treatment stove through the product of spraying and carry out the crystallization processing, treatment temp is 600 ℃, and the time is 30 minutes;
(8) product after the crystallization processing is taken out, and naturally be cooled to normal temperature, product progressively presents gold, makes the present invention's aurene ceramic product shown in Figure 1.It is golden that the product of making is, smooth surface.
Comparative Examples 1: different from embodiment is, in step (5), just takes out spraying after product is cooled to 200 ℃, and spray coating liquor can't infiltrate through in the product material, the product shows white of making.
Comparative Examples 2: different from embodiment is, in step (5), just takes out spraying after product is cooled to 800 ℃, and product self is softening, and in spray coating liquor, the part material is decomposed, and modification appears in the product of making, and is white in color.
Comparative Examples 3: different from embodiment is, in step (7), the crystallization treatment temp is 300 ℃, and the product gold effect of making is not obvious, and product is in the week after making, and has 50% product automatic embrittlement to occur.
Comparative Examples 4: different from embodiment is, in step (1), cupric nitrate is reduced to 2.8%, and the product appearance of making presents faint yellow.
Comparative Examples 5: different from embodiment is, in step (1), cupric nitrate is increased to 10%, and the product appearance of making presents bronze-colored.
Comparative Examples 6: different from embodiment is, in step (3), calcite is reduced to 2%, and the product of making is released brilliant weak effect, can't produce sufficient refraction of light, has affected the effect of product gold.
Claims (3)
1. golden spray coating liquor, it is characterized in that, made by following compositions in weight percentage: tetra chlorauric acid 0.1～0.3%, cupric nitrate 5.5～7.5%, Bismuth trinitrate 1.5～2.5%, titanium tetrachloride 1.5～2.5%, Gum Rosin 13～17%, 200# solvent oil 18～24%, turps 50～57%.
2. the production method of the described golden spray coating liquor of claim 1, is characterized in that, first Gum Rosin is heated to 140～160 ℃, and constant temperature kept 4～6 hours, made its melting, then added successively cupric nitrate, Bismuth trinitrate, titanium tetrachloride, after the question response thing becomes the brownish black lotion, constant temperature keeps slowly adding tetra chlorauric acid after 1～3 hour, stirs homogenizing 1～3 hour, be cooled to 80～120 ℃, add successively 200# solvent oil, turps, constant temperature stirred 1～3 hour, made golden spray coating liquor.
3. the production method of aurene pottery, is characterized in that, comprises following production stage:
(1), the glass-ceramic raw material is carried out melting under 1400～1550 ℃, form glass metal standby;
(2), adopt steel mould, will inject the die cavity of mould through the glass metal of melting, when glass metal is cooled to 550～650 ℃, take out product with fixture;
(3), the depanning product is placed on rotation platform, adopt spray gun, the described golden spray coating liquor of claim 1 is evenly sprayed product surface;
(4), will put into electric heating Temperature Treatment stove through the product of spraying and carry out crystallization and process, treatment temp is 550～650 ℃, the time is 20～40 minutes;
(5), the product after crystallization is processed takes out, and naturally is cooled to normal temperature, product progressively presents gold, makes product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110026085 CN102174293B (en) | 2011-01-22 | 2011-01-22 | Golden spraying liquid and production method for preparing golden glass ceramic from same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110026085 CN102174293B (en) | 2011-01-22 | 2011-01-22 | Golden spraying liquid and production method for preparing golden glass ceramic from same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102174293A CN102174293A (en) | 2011-09-07 |
| CN102174293B true CN102174293B (en) | 2013-06-05 |
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ID=44517559
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110026085 Expired - Fee Related CN102174293B (en) | 2011-01-22 | 2011-01-22 | Golden spraying liquid and production method for preparing golden glass ceramic from same |
Country Status (1)
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|---|---|
| CN (1) | CN102174293B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104944784B (en) * | 2015-06-14 | 2017-06-27 | 广东三元玉瓷文化发展股份有限公司 | A kind of preparation method of the smooth domestic glass ceramics spoon in surface |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1239254C (en) * | 2003-01-22 | 2006-02-01 | 河南大学 | Spray coating fluid for fabricating photocatalysed antibafcterial ceramics |
| CN100488918C (en) * | 2006-04-28 | 2009-05-20 | 冯建光 | Method for preparing imitating gold water |
| CN101407915B (en) * | 2008-11-24 | 2010-11-10 | 夏光甫 | Environment-friendly type metal rust-removing anti-rust spraying solution |
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2011
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| Publication number | Publication date |
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| CN102174293A (en) | 2011-09-07 |
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