CN102162174A - Silver/carbon deodorizing antibacterial non-woven fabric and preparation method thereof - Google Patents

Silver/carbon deodorizing antibacterial non-woven fabric and preparation method thereof Download PDF

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Publication number
CN102162174A
CN102162174A CN 201110089590 CN201110089590A CN102162174A CN 102162174 A CN102162174 A CN 102162174A CN 201110089590 CN201110089590 CN 201110089590 CN 201110089590 A CN201110089590 A CN 201110089590A CN 102162174 A CN102162174 A CN 102162174A
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China
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silver
fiber
nano
nonwoven fabric
antibacterial
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Granted
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CN 201110089590
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Chinese (zh)
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CN102162174B (en
Inventor
周立新
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Suzhou Emy Medical Supplies Co., Ltd.
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Changshu Lixin Nonwovens Fabricet Co Ltd
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Priority to CN2011100895906A priority Critical patent/CN102162174B/en
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Abstract

The invention discloses a silver/carbon deodorizing antibacterial non-woven fabric and a preparation method thereof, belonging to the technical field of non-woven fabrics. The silver/carbon deodorizing antibacterial non-woven fabric is prepared by mixing an active carbon fiber and a nano silver antibacterial fiber. The method comprises the following steps: soaking a viscose fiber in a nano silver solution; dehydrating and drying the soaked viscose fiber; controlling the drying temperature, the drying time and the moisture content of the dried viscose fiber to obtain the nano silver antibacterial fiber; opening the active carbon fiber and the nano silver antibacterial fiber by an opening machine; introducing the opened 80-90 parts by weight of active carbon fiber and the opened 10-20 parts by weight of nano silver antibacterial fiber into a cotton mixing machine and uniformly mixing to obtain the silver/carbon deodorizing antibacterial fiber mixture; carding the silver/carbon deodorizing antibacterial fiber mixture by a carding machine, and spreading the mixture into a cotton net by a lapping machine; and needling the cotton net by a needling machine or a spunlaced machine to obtain the silver/carbon deodorizing antibacterial nonwoven fabric. The silver/carbon deodorizing antibacterial non-woven fabric has a good effect in suppressing and killing the bred bacteria, mould and the like, and is environment-friendly.

Description

Silver charcoal deodorizing antibiotic nonwoven fabric and preparation method thereof
Technical field
The invention belongs to the bondedfibre fabric technical field, be specifically related to a kind of silver-colored charcoal deodorizing antibiotic nonwoven fabric, and relate to the preparation method of this silver charcoal deodorizing antibiotic nonwoven fabric.
Background technology
Known antibacterial nonwoven cloth made is to add through the deodorizing antibiotic agent solution to soak and the iatric fiber of oven dry in as polyester fiber, polypropylene fibre and/or the natural fabric of main material such as cotton fiber, iatric fiber both can be aforesaid polyester fiber, polypropylene fibre and/or cotton fiber, also can be other similar fiber such as acid fiber by polylactic or the like.With iatric fiber and other fiber mixed with fibers (industry claims mixed cotton) of one or more in the fiber as described above, and after opener shredding, carding machine combing, the lapping of lapping machine,, obtain the deodorizing antibiotic nonwoven fabric again through needing machine acupuncture or through spun-laced machine water thorn.This deodorizing antibiotic nonwoven fabric exists the deodorizing antibiotic effect to be difficult to lasting shortcoming, and for example, along with the increase of wash number, the deodorizing antibiotic effect fails gradually.And the expansion because the persistence of deodorizing antibiotic effect is short of to purposes constitutes restriction, for example is difficult to expand to get into bed dress product, medical and hygiene article, feminine hygiene articles, disposable sanitary articles and filtering material or the like.
Antibiotic nonwoven material or claim that nonwoven fabric is at document particularly existing report, for example CN1346905A(process for preparing Ag-carried antibacterial composite non-woven fabric in the Chinese patent literature), the antibiotic superfine fibre nonwoven cloth production method of CN101302682A(embedded with nano silvery) and CN1227292A(anti-bacterial water prick nonwoven cloth and production method thereof) or the like.The typical Nanometer Antibacterial Non-woven Cloth Filter And Preparation Method that provides as the antibacterial nonwoven cloth made of silver fiber and the CN1253615C of CN100535220C recommendation, the former is the silver-colored fiber that the surface of the 0.5-2% of interpolation total weight of fiber in nonwoven fabric is coated with silvering, silver-colored fiber is mixed as other raw material of one of raw material and nonwoven fabric, finally make antibacterial nonwoven cloth made of silver fiber; The latter is to be that polypropylene fibre of 91-88 part and the silver of 1-9 part are that antiseptic nano powder is made by parts by weight, specifically is to be that the antiseptic nano powder mixing obtains base-material with polypropylene fibre particle and silver, and base-material obtains antibacterial nonwoven cloth made through melting and spraying.
The resulting nonwoven material of aforementioned CN100535220C and CN1253615C has the strong point of antibiotic and sterilizing, but, therefore do not have the effect of toxic and harmful in deodorizing, purification, filtration and the absorbed air etc. because main composition still is polyester fiber, polypropylene fibre and/or a natural fabric as the nonwoven fabric raw material.
Along with improving constantly of health of people consciousness, the environment-friendly and green of the bedroom that is not limited to exemplify previously being adorned articles for use, medical and hygiene article, maternity and child hygiene articles for use, disposable daily necessities and even automobile interior articles for use such as roof of the vehicle and carpet or the like requires harsh day by day, therefore expect that present widely used nonwoven fabric except the strong point that possesses antibiotic and sterilizing, also has environment protectings such as aforesaid deodorizing, purification, filtration and absorption.
The applicant has carried out long-term and good try for this reason, and technical scheme described below produces under this background.
Summary of the invention
Task of the present invention is to provide a kind of not only to be had excellent antibiotic and sterilizing effect but also has both the silver-colored charcoal deodorizing antibiotic nonwoven fabric that desirable deodorizing, purification, filtration and absorption property are arranged.
Another task of the present invention is to provide a kind of preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric, this method technological requirement is harsh and can rely on conventional producing technology of non-woven fabrics and equipment to be achieved, and can ensure comprehensive embodiment of the antibiotic and sterilizing effect of nonwoven fabric.
Task of the present invention is finished like this, a kind of silver-colored charcoal deodorizing antibiotic nonwoven fabric, and it is to be mixed and made into by active carbon fibre peacekeeping nano Ag antibacterial fiber.
In a specific embodiment of the present invention, described activated carbon fiber shared parts by weight in nonwoven fabric are 80-90 part, and the parts by weight that described nano Ag antibacterial fiber accounts in nonwoven fabric are 10-20 part.
Another task of the present invention is finished like this, a kind of preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric, and this method may further comprise the steps:
A) preparation nano Ag antibacterial fiber is inserted viscose in the Nano silver solution earlier and is soaked into, and then dewater and dry, and the moisture content of control bake out temperature, control drying time and the control viscose after drying, obtain nano Ag antibacterial fiber;
B) shredding, with activated carbon fiber by the opener shredding, and with nano Ag antibacterial fiber equally by the opener shredding, obtain the nano Ag antibacterial fiber of the active carbon fibre peacekeeping shredding of shredding;
C) mixed cotton is introduced the cotton blender machine mixing with 80-90 part activated carbon fiber of shredding and 10-20 part nano Ag antibacterial fiber of shredding by weight, obtains silver-colored charcoal deodorizing and antibacterial fiber compound;
D) combing and lapping, elder generation by the carding machine combing, becomes web by lapping machine laying with silver-colored charcoal deodorizing and antibacterial fiber compound again;
E) thorn closes, and web is closed by needing machine or spun-laced machine thorn, obtains silver-colored charcoal deodorizing antibiotic nonwoven fabric.
The concentration of the Nano silver solution in another specific embodiment of the present invention, steps A) is 500-1000ppm.
The particle diameter of the Nano Silver in another specific embodiment of the present invention, steps A) is 5-20nm.
The time of the infiltration in another specific embodiment of the present invention, steps A) is 10-30min.
Also have in the specific embodiment of the present invention, steps A) the control bake out temperature described in is that bake out temperature is controlled to be 130-160 ℃, described control drying time is that the time is controlled to be 10-30min, and the moisture content after the described control oven dry is that moisture content is controlled to be 8-14%.
The fiber number of the viscose more of the present invention and in specific embodiment, steps A) is 1.5-1.8dtex, and the length of viscose is 35-40 ㎜.
Technical scheme provided by the invention is owing to adopted mixing of activated carbon fiber and nano Ag antibacterial fiber, therefore resulting nonwoven fabric not only has good inhibition and bactericidal action to the bacterium that grows, mould etc., and play by activated carbon fiber and to embody feature of environmental protection green such as the effect of the toxic and harmful of formaldehyde, benzene etc. in remarkable deodorizing, purification, transition and the absorbed air, make the purposes of the silver-colored charcoal deodorizing antibiotic nonwoven fabric that obtains be able to abundant expansion.
Description of drawings
The process chart of Fig. 1 silver-colored charcoal deodorizing antibiotic nonwoven fabric for the present invention prepares.
The specific embodiment
Embodiment 1:
Ask for an interview Fig. 1.
A) preparation nano Ag antibacterial fiber, be that the viscose of 40 ㎜ is inserted and soaked into 10min in the Nano silver solution that mass percent concentration is 1000ppm for 1.5dtex and length earlier with the fiber number (also claiming fineness) of high whiteness, then dewater and dry, the temperature of oven dry is controlled to be 160 ℃, drying time is controlled to be 10min, moisture content after the oven dry is controlled to be 9%, obtain nano Ag antibacterial fiber, wherein: aforesaid concentration is that the Nano silver solution of 1000ppm is to be that the high concentration dispersion liquid dilution of the nanometer-level silver particle of 50000ppm obtains by silver particles particle diameter 5-20nm and concentration;
B) shredding, the activated carbon fiber that will be obtained by commercially available channel is through the habitual opener shredding of on-woven production industry, and will be by steps A) nano Ag antibacterial fiber that obtains is equally by the opener shredding, obtains the nano Ag antibacterial fiber of the active carbon fibre peacekeeping shredding of shredding;
C) mixed cotton, will be by step B) in the shredding that obtains 80 parts of activated carbon fiber with equally by step B) 20 parts of nano Ag antibacterial fibers of the shredding that obtains introduce in the habitual cotton blender machine of on-woven production industry (also claiming to mix fine machine or fiber mixer) fully mixing in the lump, obtain silver-colored charcoal deodorizing and antibacterial fiber compound;
D) combing and lapping, earlier will be by step C) the silver-colored charcoal deodorizing and antibacterial fiber compound that obtains is for the carding machine combing, become web by lapping machine laying again, preferably, the grammes per square metre of individual layer web is 10-20g/ ㎡, and the grammes per square metre behind the laying is preferably 50-400g/ ㎡, in the present embodiment, the grammes per square metre of individual layer web is 20g/ ㎡, and the laying number of plies is 20 layers;
E) thorn closes, will be by step D) web that obtains introduces needing machine acupuncture, acupuncture comprises pre-needling, goes up thorn, stings, goes up thorn and this five roads acupuncture of thorn down down, makes entanglement mutually between the fiber, goes out needing machine and obtain the silver-colored charcoal deodorizing antibiotic nonwoven fabric that grammes per square metre is 400g/ ㎡ after the hot-rolling mill hot pressure.
The silver-colored charcoal deodorizing antibiotic nonwoven fabric that present embodiment obtains, the functions such as deodorizing, purification, filtration and absorption of active carbon had both been utilized, the bactericidal function of the Nano Silver of Li Yonging again, in with harmful substance (peculiar smell, impurity) Molecular Adsorption, the bacterium that grows thus and mould etc. are carried out good restraining and sterilization.Behind the equalization point of balanced deodorizing and sterilization, draw best allocation ratio, to reach deodorizing and antibiotic double effects.
The silver-colored charcoal deodorizing antibiotic nonwoven fabric that present embodiment obtains can be widely used in the production of house ornamentation, automobile, health, filtration purification industry and other products, as have the wallpaper and a carpet of deodorizing sterilizing effect, can remove the car carpeting and the ceiling cloth of automobile peculiar smell, the base material of products such as the urine pad for baby of air purifier filtering material, antibacterial mask, deodorizing antibiotic, sanltary towel, shoe-pad and slippers, prospect is boundless.
Embodiment 2:
With steps A) in the fiber number (being fineness) of high whiteness viscose change 1.8dtex into, the length of viscose changes 35 ㎜ into, the mass percent concentration of Nano silver solution changes 500ppm into, change infiltrating time into 30min, bake out temperature changes 130 ℃ into, drying time changes 30min, and the moisture content after the oven dry is that the moisture content of nano Ag antibacterial fiber changes 14% into; With step C) in the parts by weight of activated carbon fiber change 90 parts into, change the parts by weight of nano Ag antibacterial fiber into 10 parts; With step D) in the grammes per square metre of individual layer web change 10g/ ㎡ into, the web laying number of plies changes 5 layers into; Step e) use spun-laced machine water thorn instead, obtaining grammes per square metre is the silver-colored charcoal deodorizing antibiotic nonwoven fabric of 50g/ ㎡, and all the other are all with the description to embodiment 1.
Embodiment 3:
With steps A) in the fiber number of high whiteness viscose change 1.65dtex into, the mass percent concentration that the length of viscose changes 38 ㎜ Nano silver solutions into changes 750ppm into, infiltrating time changes 20min into, bake out temperature changes 145 ℃ into, drying time changes 20min, and the moisture content of the fiber after the oven dry changes 12% into; With step C) in the parts by weight of activated carbon fiber change 85 parts into, change the parts by weight of nano Ag antibacterial fiber into 15 parts; With step D) in the grammes per square metre of individual layer web change 15g/ ㎡ into, the web laying number of plies changes 15 layers into; Through step e) grammes per square metre of the silver-colored charcoal deodorizing antibiotic nonwoven fabric that obtains after closing of thorn is 225g/ ㎡, all the other are all with the description to embodiment 1.
Embodiment 4:
With steps A) in the mass percent concentration of Nano silver solution change 850ppm into, infiltrating time changes 15min into; With step C) in the parts by weight of activated carbon fiber change 82.5 parts into, change the parts by weight of nano Ag antibacterial fiber into 17.5 parts; With step D) in the grammes per square metre of individual layer web change 12g/ ㎡ into, the web laying number of plies changes 10 layers into; The grammes per square metre of the silver-colored charcoal deodorizing antibiotic nonwoven fabric that step e) obtains is 120g/ ㎡, and all the other are all with the description to embodiment 1.
Embodiment 5:
Only with step D) in the grammes per square metre of individual layer web change 18g/ ㎡ into, the web laying number of plies changes 20 layers into; The grammes per square metre of the silver-colored charcoal deodorizing antibiotic nonwoven fabric that step e) obtains is 360g/ ㎡, and all the other are all with the description to embodiment 1.

Claims (8)

1. a silver-colored charcoal deodorizing antibiotic nonwoven fabric is characterized in that it is to be mixed and made into by active carbon fibre peacekeeping nano Ag antibacterial fiber.
2. silver-colored charcoal deodorizing antibiotic nonwoven fabric according to claim 1 it is characterized in that described activated carbon fiber shared parts by weight in nonwoven fabric are 80-90 part, and the parts by weight that described nano Ag antibacterial fiber accounts for is 10-20 part in nonwoven fabric.
3. the preparation method of a silver-colored charcoal deodorizing antibiotic nonwoven fabric as claimed in claim 1 is characterized in that this method may further comprise the steps:
A) preparation nano Ag antibacterial fiber is inserted viscose in the Nano silver solution earlier and is soaked into, and then dewater and dry, and the moisture content of control bake out temperature, control drying time and the control viscose after drying, obtain nano Ag antibacterial fiber;
B) shredding, with activated carbon fiber by the opener shredding, and with nano Ag antibacterial fiber equally by the opener shredding, obtain the nano Ag antibacterial fiber of the active carbon fibre peacekeeping shredding of shredding;
C) mixed cotton is introduced the cotton blender machine mixing with 80-90 part activated carbon fiber of shredding and 10-20 part nano Ag antibacterial fiber of shredding by weight, obtains silver-colored charcoal deodorizing and antibacterial fiber compound;
D) combing and lapping, elder generation by the carding machine combing, becomes web by lapping machine laying with silver-colored charcoal deodorizing and antibacterial fiber compound again;
E) thorn closes, and web is closed by needing machine or spun-laced machine thorn, obtains silver-colored charcoal deodorizing antibiotic nonwoven fabric.
4. the preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric according to claim 3 is characterized in that steps A) described in the concentration of Nano silver solution be 500-1000ppm.
5. the preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric according to claim 3 is characterized in that steps A) described in the particle diameter of Nano Silver be 5-20nm.
6. the preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric according to claim 3 is characterized in that steps A) described in time of infiltration be 10-30min.
7. the preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric according to claim 3, it is characterized in that steps A) described in the control bake out temperature be that bake out temperature is controlled to be 130-160 ℃, described control drying time is that the time is controlled to be 10-30min, and the moisture content after the described control oven dry is that moisture content is controlled to be 8-14%.
8. the preparation method of silver-colored charcoal deodorizing antibiotic nonwoven fabric according to claim 3 is characterized in that steps A) described in the fiber number of viscose be 1.5-1.8dtex, the length of viscose is 35-40 ㎜.
CN2011100895906A 2011-04-11 2011-04-11 Silver/carbon deodorizing antibacterial non-woven fabric and preparation method thereof Expired - Fee Related CN102162174B (en)

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Cited By (21)

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CN103054247A (en) * 2011-10-18 2013-04-24 苏艺强 Prepared method of baby pants
CN103445328A (en) * 2013-07-29 2013-12-18 天津开发区金衫包装制品有限公司 Pure-cotton-gauze based sterile dustproof mask and producing method thereof
CN103485072A (en) * 2013-10-14 2014-01-01 江苏顺远纺织科技有限公司 Novel blending deodorant antibacterial non-woven fabrics
CN104179033A (en) * 2014-08-01 2014-12-03 陕西科技大学 Production method of functional synthetic leather for mobile phone case
CN104494219A (en) * 2014-12-15 2015-04-08 常熟市一心无纺制品有限公司 Antibacterial non-woven fabric
CN105862250A (en) * 2016-05-16 2016-08-17 上海申欧企业发展有限公司 Active carbon composite cloth and preparation process and application thereof
CN105951272A (en) * 2016-07-19 2016-09-21 安徽贵谷电子商务有限公司 Processing process for antimicrobial down jacket fabric
CN106012294A (en) * 2016-06-30 2016-10-12 梧州市光华纺织制品有限责任公司 Manufacturing method of vehicle wiping towel
CN106012310A (en) * 2016-06-30 2016-10-12 梧州市光华纺织制品有限责任公司 Vehicle wiping towel
CN106012528A (en) * 2016-06-28 2016-10-12 江苏德邦卫生用品有限公司 Preparation method of antibacterial and deodorizing hot air nonwoven fabric
CN106042539A (en) * 2016-07-26 2016-10-26 常熟市立新无纺布织造有限公司 SMS composite nonwoven fabric
CN107364195A (en) * 2017-07-28 2017-11-21 界首市双鑫纺织有限公司 A kind of preparation method of antibacterial repairing type medical non-woven fabrics
CN107460637A (en) * 2017-08-02 2017-12-12 六安尚荣无纺布制品有限公司 A kind of processing technology of Medical composite non-woven fabrics
CN107938170A (en) * 2017-12-25 2018-04-20 上海瑞洋思生活用品有限公司 A kind of activated carbon spun laced fabric inhaled color and inhale taste antibacterial
CN108193377A (en) * 2017-12-29 2018-06-22 浙江弘扬无纺新材料有限公司 A kind of fabric containing active carbon nanoparticles, production method and its application
CN108914381A (en) * 2018-07-16 2018-11-30 刘福芳 A kind of nonwoven production processing technology
CN110236251A (en) * 2019-05-07 2019-09-17 浙江迪亚服饰有限公司 A kind of processing technology of antimicrobial form feather dress fabric
CN110393978A (en) * 2018-04-25 2019-11-01 马鞍山同杰良生物材料有限公司 A kind of antibacterial ordor removing non-woven filter material and its application
CN110422477A (en) * 2019-07-24 2019-11-08 浙江格新包装科技有限公司 A kind of preparation process of nonwoven fabrics package bag
CN110629404A (en) * 2019-09-20 2019-12-31 红豆集团(无锡)纺织品有限公司 Taxus chinensis environment-friendly antibacterial anti-mite flocculus and preparation method thereof
CN110791881A (en) * 2019-12-03 2020-02-14 福建恒安集团有限公司 Preparation method of odor-removing disposable hygienic product

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CN103054247A (en) * 2011-10-18 2013-04-24 苏艺强 Prepared method of baby pants
CN103445328A (en) * 2013-07-29 2013-12-18 天津开发区金衫包装制品有限公司 Pure-cotton-gauze based sterile dustproof mask and producing method thereof
CN103445328B (en) * 2013-07-29 2016-03-30 天津开发区金衫包装制品有限公司 Based on antimicrobial dust-proof mouth mask and the processing method thereof of cotton gauze
CN103485072A (en) * 2013-10-14 2014-01-01 江苏顺远纺织科技有限公司 Novel blending deodorant antibacterial non-woven fabrics
CN104179033A (en) * 2014-08-01 2014-12-03 陕西科技大学 Production method of functional synthetic leather for mobile phone case
CN104179033B (en) * 2014-08-01 2016-07-20 陕西科技大学 A kind of cell-phone cover production method of functional synthetic leather
CN104494219A (en) * 2014-12-15 2015-04-08 常熟市一心无纺制品有限公司 Antibacterial non-woven fabric
CN105862250A (en) * 2016-05-16 2016-08-17 上海申欧企业发展有限公司 Active carbon composite cloth and preparation process and application thereof
CN106012528A (en) * 2016-06-28 2016-10-12 江苏德邦卫生用品有限公司 Preparation method of antibacterial and deodorizing hot air nonwoven fabric
CN106012294A (en) * 2016-06-30 2016-10-12 梧州市光华纺织制品有限责任公司 Manufacturing method of vehicle wiping towel
CN106012310A (en) * 2016-06-30 2016-10-12 梧州市光华纺织制品有限责任公司 Vehicle wiping towel
CN105951272A (en) * 2016-07-19 2016-09-21 安徽贵谷电子商务有限公司 Processing process for antimicrobial down jacket fabric
CN106042539A (en) * 2016-07-26 2016-10-26 常熟市立新无纺布织造有限公司 SMS composite nonwoven fabric
CN107364195A (en) * 2017-07-28 2017-11-21 界首市双鑫纺织有限公司 A kind of preparation method of antibacterial repairing type medical non-woven fabrics
CN107364195B (en) * 2017-07-28 2019-02-15 界首市双鑫纺织有限公司 A kind of preparation method of antibacterial repairing type medical non-woven fabrics
CN107460637A (en) * 2017-08-02 2017-12-12 六安尚荣无纺布制品有限公司 A kind of processing technology of Medical composite non-woven fabrics
CN107938170A (en) * 2017-12-25 2018-04-20 上海瑞洋思生活用品有限公司 A kind of activated carbon spun laced fabric inhaled color and inhale taste antibacterial
CN108193377A (en) * 2017-12-29 2018-06-22 浙江弘扬无纺新材料有限公司 A kind of fabric containing active carbon nanoparticles, production method and its application
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CN108914381A (en) * 2018-07-16 2018-11-30 刘福芳 A kind of nonwoven production processing technology
CN110236251A (en) * 2019-05-07 2019-09-17 浙江迪亚服饰有限公司 A kind of processing technology of antimicrobial form feather dress fabric
CN110422477A (en) * 2019-07-24 2019-11-08 浙江格新包装科技有限公司 A kind of preparation process of nonwoven fabrics package bag
CN110629404A (en) * 2019-09-20 2019-12-31 红豆集团(无锡)纺织品有限公司 Taxus chinensis environment-friendly antibacterial anti-mite flocculus and preparation method thereof
CN110791881A (en) * 2019-12-03 2020-02-14 福建恒安集团有限公司 Preparation method of odor-removing disposable hygienic product

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