CN102161786A - High-mutual viscosity lustered yellowing-resistance bleached sole rubber and preparation method thereof - Google Patents
High-mutual viscosity lustered yellowing-resistance bleached sole rubber and preparation method thereof Download PDFInfo
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Abstract
The invention relates to high-mutual viscosity lustered yellowing-resistance bleached sole rubber and a preparation method thereof. The high-mutual viscosity lustered yellowing-resistance bleached sole rubber comprises 60 to 70 weight parts of No.1 standard rubber, 10 to 20 weight parts of 2000R solution polymerized butadiene-styrene rubber, 15 to 25 weight parts of cis-1,4-butadiene rubber, 1 to 3 weight parts of sulfur, 2.2 to 2.6 weight parts of promoter, 5 to 6 weight parts of stearic acid, 2 to 3 weight parts of nano zinc oxide, 4 to 5 weight parts of polyethylene glycol No.4000, 1 to 2 weight parts of anti-aging agent, 1.7 to 2.1 weight parts of ultramarine, 45 to 55 weight parts of titanium white, 40 to 50 weight parts of white carbon black, 20 to 30 weight parts of nano calcium carbonate, 0.4 to 0.6 weight part of 1-percent pigment permanent violet and 7 to 9 weight parts of white engine oil. In the invention, the formula and preparation method of the product are improved, and sole rubber, which has high rubber viscosity and luster and is yellowing-resistance and as white as snow, is obtained by screening.
Description
Technical field
The present invention relates to a kind of rubber and preparation method thereof, especially a kind of bleaching look sole rubber and preparation method thereof.
Background technology
Sole rubber is according to the purposes needs, various mix proportion scheme is arranged, vulcanized rubber is wherein a kind of, present vulcanized rubber has that the snow-white degree of color is low, glossiness is low, be sub-smooth type, work in-process sizing material viscosity is low, removing from mould decorative pattern model keeping character is poor, easily cause compressive strain, the product appearance profile is unintelligible; And reach 3～5 grades with the anti-xanthochromia under the sun lamp B method, and the anti-xanthochromia of sun lamp B method is lower than 3 grades of persons and must uses high price such as anti-xanthochromia promotor, ultraviolet absorbers functional materials; The sticking mutually difference of film surface viscosity is easily fallen sheet, and the mutual viscous force of unvulcanized rubber is not more than 1.5KN/m; Under the condition of 110 ℃ of X40min heat of compression air (pressure 0.38Mpa), the vulcanized rubber physicals is: tensile strength 6～9Mpa, tensile yield 300～400%, Akron wear volume 1.5～2.0cm3/1.61km.Above performance all causes vulcanized rubber when using as sole rubber, has a lot of deficiencies, is difficult to satisfy the use needs.
Summary of the invention
The objective of the invention is: the anti-xanthochromia bleaching of a kind of high mutual viscosity gloss type look sole rubber and preparation method thereof is provided, and every excellent performance can satisfy and use needs, to overcome the deficiencies in the prior art.
The present invention is achieved in that the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, it is characterized in that: calculate by weight, it comprises 60～70 parts of 1# standard glue, 25～45 parts of synthetical glues, 1.8～2.5 parts of sulphur, 2.2～2.6 parts of promotor, 7～9 vulcanization levellers, 4～5 parts of Macrogol 4000s, 1～2 part of anti-aging agent, 1.7～2.1 portions of ultramarines, 45～55 parts of titanium dioxides, 40～50 parts of white carbon blacks, 20～30 parts of nano-calcium carbonates, 0.4～0.6 part of mass percent is permanent violet rubber master batch and 7～9 parts of white machine oil of 1%.
Preferred scheme is, calculates by weight, and it comprises 65 parts of 1# standard glue, 15 parts of 2000R solution polymerized butylbenzene glue, 20 parts of cis-butadiene cements, 2 parts of sulphur, 2.6 part Microcrystalline Wax, 2.4 parts of promotor, 5.6 parts of stearic acid, 2.5 part nano zine oxide, 4.3 parts of Macrogol 4000 #, 1.7 parts of anti-aging agent, 1.9 part ultramarine, 50 parts of titanium dioxides, 45 parts of white carbon blacks, 25 parts of nano-calcium carbonates, 0.50 part of mass percent are 1% permanent violet rubber master batch, 8 parts of white machine oil and 2.5 parts of RX-80 xylene resins.
Synthetical glue is made up of 10～20 parts of solution polymerized butylbenzene glue and 15～25 parts of cis-butadiene cements.
Vulcanization leveller is made up of 5～6 parts of three grades of stearic acid and 2～3 parts of nano zine oxides.
Per 2.4 parts of promotor are made up of 0.5 part of captax and 1.9 parts of altaxs.
Mass percent is that 1% permanent violet rubber master batch is that 1 part of permanent violet and 100 parts of 1# standard glue mix.
Anti-aging agent is anti-aging agent KY-405L.
Also comprise 2.4～2.8 parts of Microcrystalline Waxes and 2～3 parts of RX-80 xylene resins.
The preparation method of the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, plasticate earlier, with 1# standard glue in Banbury mixer, press the refining 1～3min after, add anti-aging agent, mention floating weight behind pressure refining 2～4min and make the sizing material upset, continue to press and to mention floating weight behind refining 3～5min and make the sizing material upset, continue to press discharge behind refining 1～3min; Behind the Banbury mixer discharge, 25min with interior the material of discharging is dropped into 0 roll spacing from opening rubber mixing machine in, on draw logical 2～3 roads, then the roll spacing of mill is transferred to 4～6mm from 0, with sizing material bag roll row bubble, with sizing material reel metering, obtain plasticity number and be 0.40～0.45 broken-(down)rubber after finishing; With sizing material deposit carry out again more than 4 hours mixing, broken-(down)rubber and solution polymerized butylbenzene glue and cis-butadiene cement are put into Banbury mixer close refining 1min, add titanium dioxide then, middle material and white carbon black, press refining 2～4 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber and sweep go back to banburying chamber, continue to press refining 1～3 minute, mention the powder material that floating weight of banbury mixer will overflow banburying chamber once more and sweep go back to banburying chamber, and add nano-calcium carbonate and white machine oil successively, press refining to mention the powder material that floating weight of banbury mixer will overflow banburying chamber after 2 minutes then and sweep go back to banburying chamber, press refining 2 minutes again, obtain rubber unvulcanizate; Rubber unvulcanizate is added mill, is to wrap roller under 4～5mm condition in roll spacing, to operate on reel 1/2nd modes, about operate on and turn refining 7～8 minutes, per three of scribing cooling back is spilt one deck Paris white and is taken up, and film proportionally adds sulphur in use, promptly obtains finished product.
Material is Microcrystalline Wax, promotor, stearic acid, nano zine oxide, Macrogol 4000, ultramarine, permanent violet rubber master batch and RX-80 xylene resin in described.
Standard glue is to come fractionated by unified in the world physics and chemistry usefulness, index, these physicochemical properties comprise seven of foreign matter content, plasticity initial value, plasticity retention(percentage), nitrogen content, volatile content, ash oontent and color and luster indexes etc., wherein with taking as the leading factor property of foreign matter content index, more than impurity, be divided into totally five ranks such as 5L, 5,10,20 and 50 etc. less.
The stearic acid industrial goods are white in color or little yellow particle or piece, are the mixture of 45% stearic acid and 55% Palmiticacid, and contain a small amount of oleic acid, slightly fatty smell.Industrial goods branch one-level (be once called as three pressures, through three times squeezing), secondary (being once called as two pressures) and three grades (being once called as a pressure) through single pressing or without squeezing through twice pressing.Be based on stearic acid and contain the mixing acid of Palmiticacid etc.The firsts and seconds stearic acid is that to have gloss or contain be the white waxy solid of crystal grain.Three grades of stearic acid are faint yellow waxy solids.
The chemical name of anti-aging agent KY-405L is 4, two (α, the α-Er Jiajibianji) pentanoic of 4'-.
Ultramarine is the most ancient and the most bright-coloured blue pigments, and toxicological harmless, environmental protection belong to the mineral dye category.It is used to carry white, can eliminate the sodium yellow in whitewash or other white pigment, and is water insoluble, alkaline-resisting, high temperature resistant, extremely stable to Exposure to Sunlight and erosion by wind and rain in atmosphere, but not acidproof, meets acid and decomposes variable color.
It is 2003 solution polymerized butylbenzene glue that solution polymerized butylbenzene glue is selected model for use, and its production firm is that Japanese Asahi Chemical Industry produces.
The model of titanium dioxide is selected R930 for use.
RX-80 xylene resin, RX-80 resin are the polymkeric substance by xylene formaldehyde resin, natural resin and polyvalent alcohol synthetic intermediate molecular weight in the presence of catalyzer.With various synthetic rubber and natural rubber good consistency is arranged, can play softening, tackify and strengthening action to rubber, and can improve the complete processing of rubber, improve elastomeric usage ratio.Product is light brown or brown solid, and no volatile matter below 180 ℃ is overflowed, and is a kind of nontoxic, tasteless thermoplastic resin.Because of it contains aromatic ring, ester bond and ehter bond so with various rubber consistency is preferably arranged all, have than obvious effects the perviousness of rubber, softening tackifying, plasticity, and its not contaminative and non-transport property have in addition become the good auxiliary agent of rubber and plastic industry.Softening, tackify when product has been widely used in tire, footwear industry compounding rubber at present; The plasticising of rubber item; The binding agent of sneakers, leather shoes also can be used as the additive (improve the rheological of oil product, improve the lubricant effect of oil product) of oil product.
Synthetic and the application of RX-80 resin is a main raw material with dimethylbenzene, formaldehyde, rosin, the main processes of synthetic rubber tenderizer, aspects factors such as raw materials cost, conversion unit condition and product quality indicator have been taken all factors into consideration, determine that at last with formaldehyde, dimethylbenzene be the synthetic xylene formaldehyde resin of basic material, further react the operational path of synthetic RX-80 resin again, and the RX-80 resin has been discussed as Rubber Softener some application at rubber industry with rosin.
The present invention makes them play active effect to product performance by the mutual combination between the batching, and is specific as follows:
1, sizing material viscosity satisfies the product processing requirement: 45 parts of white carbon blacks, 8 parts in white machine oil, 2.5 parts of RX-80 xylene resins are guaranteed sizing material viscosity.
Table 1
Learn according to table 1 test-results, select 2.5 parts of 45 parts of white carbon blacks, 8 parts in white machine oil and RX-80 xylene resins for use, make the sizing material property endured good and shrink little, film size stability height, the mutual viscosity height, Forming Quality is good.
2, sizing material gloss test
Table 2
Annotate: 45 parts of this prescription white carbon blacks, 8 parts in white machine oil, 2.5 parts of RX-80 xylene resins.
Learn according to table 2 test-results, use " 2.6 parts of Microcrystalline Waxes, 5.6 parts of stearic acid (three grades), 25 parts of nano-calcium carbonates ", cooperate original position to generate high sole glossiness.
3, non-yellowing test:
Table 3
Annotate: test conditions in the table: 2.0 parts in sulphur, 2.8 parts, 15 parts solution polymerized butylbenzene glue of zinc oxide, cis-butadiene cement 25,45 parts of white carbon blacks, 4.30 parts of Macrogol 4000s.
According to knowing of the experimental result of table 3, under " 2.0 parts in white carbon black 45 parts (4.30 parts of Macrogol 4000s), sulphur " condition, 0.5 part, 15 parts solution polymerized butylbenzene glue 2000R of captax cooperate with 1# standard glue and cis-butadiene cement, use 2.8 parts of nano zine oxides, the sizing material anti-yellowing property is best, reaches 2 grades of levels of sun lamp B method.
4, bleaching color testing
Table 4
Test-results according to table 4 draws: 0.50 part of 1% permanent violet rubber master batch, 50 parts of titanium dioxides (anatase titanium dioxide), 1.90 parts in white ultramarine obtain bleaching the coloring agent material.
It comprises 65 parts of 1# standard glue, 15 parts of 2000R solution polymerized butylbenzene glue, 20 parts of cis-butadiene cements, 2 parts of sulphur, 2.6 parts of Microcrystalline Waxes, 2.4 parts of promotor, 5.6 part stearic acid, 2.5 parts of nano zine oxides, 4.3 parts of Macrogol 4000 #, 1.7 part anti-aging agent, 1.9 portions of ultramarines, 50 parts of titanium dioxides, 45 parts of white carbon blacks, 25 parts of nano-calcium carbonates, 0.50 part of 1% permanent violet rubber master batch, 8 parts of white machine oil and 2.5 parts of RX-80 xylene resins.
Owing to adopted technique scheme, compared with prior art, the present invention improves the prescription and the preparation method of product, by screening obtained that sizing material viscosity is good, glossiness is high, anti-xanthochromia and the snow-white sole rubber of color.Aborning, its work in-process sizing material property endured height, removing from mould decorative pattern model keeping character are strong, and product appearance is well-pressed; And footwear are not more than 2 grades with this color glue component through the anti-xanthochromia of sun lamp B method, replace using high price functional materials such as anti-xanthochromia promotor, ultraviolet absorbers, and yellowing resistance is good; The film surface viscosity glues to fall sheet mutually, and the unvulcanized rubber bounding force is greater than 1.5KN/m, and sizing material viscosity is good; The physicals of the vulcanized rubber that rubber overshoes obtain under 110 ℃ of X40min heat of compression air (pressure 0.38Mpa) condition is: tensile strength greater than 12.3Mpa, tensile yield greater than 600%, the Akron wear volume is less than 0.9 cm3/1.61km.Method of the present invention is simple, and is with low cost, and result of use is good.
Embodiment
Embodiments of the invention 1: the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, calculate by weight, it comprises 65 parts of 1# standard glue, 15 parts of 2000R solution polymerized butylbenzene glue, 20 parts of cis-butadiene cements, 2 parts of sulphur, 2.6 part Microcrystalline Wax, 0.5 part of captax, 1.9 parts of altaxs, 5.6 part three grades of stearic acid, 2.5 parts of nano zine oxides; 4.3 part Macrogol 4000,1.7 parts of anti-aging agent KY-405L, 1.9 portions of ultramarines, 50 parts of titanium dioxides (R930), 45 parts of white carbon blacks, 25 parts of nano-calcium carbonates, 0.50 part of 1% permanent violet rubber master batch, 8.6 parts of white machine oil of 5# and 2.5 parts of RX-80 xylene resins.
The preparation method of the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, it is characterized in that: plasticate earlier, with 1# standard glue in Banbury mixer, press the refining 2min after, add anti-aging agent, mention floating weight behind the pressure refining 3min and make the sizing material upset, continue to press and to mention floating weight behind the refining 4min and make the sizing material upset, continue to press discharge behind the refining 2min; Behind the Banbury mixer discharge, 25min with interior the material of discharging is dropped into 0 roll spacing from opening rubber mixing machine in, on draw logical 3 roads, then the roll spacing of mill is transferred to 5mm from 0, with sizing material bag roll row bubble, with sizing material reel metering, obtain plasticity number and be 0.42 broken-(down)rubber after finishing; Sizing material deposited carried out mixing again in 8 hours, broken-(down)rubber and solution polymerized butylbenzene glue and cis-butadiene cement are put into Banbury mixer close refining 1min, add titanium dioxide, Microcrystalline Wax, promotor, stearic acid, nano zine oxide, Macrogol 4000, ultramarine, permanent violet rubber master batch and RX-80 xylene resin then.And white carbon black, press refining 3 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber and sweep go back to banburying chamber, continue to press refining 2 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber once more and sweep go back to banburying chamber, and add nano-calcium carbonate and white machine oil successively, press refining to mention the powder material that floating weight of banbury mixer will overflow banburying chamber after 2 minutes then and sweep go back to banburying chamber, press refining 2 minutes again, obtain rubber unvulcanizate; Rubber unvulcanizate is added mill, is to wrap roller under the 4.5mm condition in roll spacing, to operate on reel 1/2nd modes, about operate on and turn refining 7.5 minutes, per three of scribing cooling back is spilt one deck Paris white and is taken up, and film proportionally adds sulphur in use, promptly obtains finished product.
Embodiments of the invention 2: the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, calculate by weight, it comprises 60 parts of 1# standard glue, 20 parts of 2000R solution polymerized butylbenzene glue, 15 parts of cis-butadiene cements, 1 part of sulphur, 2.4 part Microcrystalline Wax, 0.4 part of captax, 2.0 parts of altaxs, 5 parts of three grades of stearic acid, 2 parts of nano zine oxides; 4 parts of Macrogol 4000 #, 12 parts of anti-aging agent KY-405L, 1.7 portions of ultramarines, 55 parts of titanium dioxides (R930), 40 parts of white carbon blacks, 30 parts of nano-calcium carbonates, 0.1 part of 1% permanent violet rubber master batch, 8 parts of white machine oil of 5# and 2 parts of RX-80 xylene resins.
The preparation method of the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, it is characterized in that: plasticate earlier, with 1# standard glue in Banbury mixer, press the refining 1min after, add anti-aging agent, mention floating weight behind the pressure refining 2min and make the sizing material upset, continue to press and to mention floating weight behind the refining 3min and make the sizing material upset, continue to press discharge behind the refining 1min; Behind the Banbury mixer discharge, 25min with interior the material of discharging is dropped into 0 roll spacing from opening rubber mixing machine in, on draw logical 2 roads, then the roll spacing of mill is transferred to 4mm from 0, with sizing material bag roll row bubble, with sizing material reel metering, obtain plasticity number and be 0.40 broken-(down)rubber after finishing; Sizing material deposited carried out mixing again in 4 hours, broken-(down)rubber and solution polymerized butylbenzene glue and cis-butadiene cement are put into Banbury mixer close refining 1min, add titanium dioxide, Microcrystalline Wax, promotor, stearic acid, nano zine oxide, Macrogol 4000, ultramarine, permanent violet rubber master batch and RX-80 xylene resin then.And white carbon black, press refining 2 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber and sweep go back to banburying chamber, continue to press refining 1 minute, mention the powder material that floating weight of banbury mixer will overflow banburying chamber once more and sweep go back to banburying chamber, and add nano-calcium carbonate and white machine oil successively, press refining to mention the powder material that floating weight of banbury mixer will overflow banburying chamber after 2 minutes then and sweep go back to banburying chamber, press refining 2 minutes again, obtain rubber unvulcanizate; Rubber unvulcanizate is added mill, is to wrap roller under the 4mm condition in roll spacing, to operate on reel 1/2nd modes, about operate on and turn refining 7 minutes, per three of scribing cooling back is spilt one deck Paris white and is taken up, and film proportionally adds sulphur in use, promptly obtains finished product.
Embodiments of the invention 3: the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, it is characterized in that: calculate by weight, it comprises 70 parts of 1# standard glue, 10 parts of 2000R solution polymerized butylbenzene glue, 25 parts of cis-butadiene cements, 3 parts of sulphur, 2.8 part Microcrystalline Wax, 0.6 part of captax, 1.8 parts of altaxs, 6 parts of three grades of stearic acid, 3 parts of nano zine oxides; 5 parts of Macrogol 4000 #, 2 parts of anti-aging agent KY-405L, 2.1 portions of ultramarines, 45 parts of titanium dioxides (R930), 50 parts of white carbon blacks, 20 parts of nano-calcium carbonates, 0.15 part of 1% permanent violet rubber master batch, 9 parts of white machine oil of 5# and 2～3 parts of RX-80 xylene resins.
The preparation method of the anti-xanthochromia bleaching of high mutual viscosity gloss type look sole rubber, it is characterized in that: plasticate earlier, with 1# standard glue in Banbury mixer, press the refining 3min after, add anti-aging agent, mention floating weight behind the pressure refining 4min and make the sizing material upset, continue to press and to mention floating weight behind the refining 5min and make the sizing material upset, continue to press discharge behind the refining 3min; Behind the Banbury mixer discharge, 25min with interior the material of discharging is dropped into 0 roll spacing from opening rubber mixing machine in, on draw logical 3 roads, then the roll spacing of mill is transferred to 6mm from 0, with sizing material bag roll row bubble, with sizing material reel metering, obtain plasticity number and be 0.45 broken-(down)rubber after finishing; Sizing material deposited carried out mixing again in 12 hours, mixing program is: broken-(down)rubber and solution polymerized butylbenzene glue and cis-butadiene cement are put into Banbury mixer close refining 1min, add titanium dioxide, Microcrystalline Wax, promotor, stearic acid, nano zine oxide, Macrogol 4000, ultramarine, permanent violet rubber master batch and RX-80 xylene resin then.And white carbon black, press refining 4 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber and sweep go back to banburying chamber, continue to press refining 3 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber once more and sweep go back to banburying chamber, and add nano-calcium carbonate and white machine oil successively, press refining to mention the powder material that floating weight of banbury mixer will overflow banburying chamber after 2 minutes then and sweep go back to banburying chamber, press refining 2 minutes again, obtain rubber unvulcanizate; Rubber unvulcanizate is added mill, is to wrap roller under the 5mm condition in roll spacing, to operate on reel 1/2nd modes, about operate on and turn refining 8 minutes, per three of scribing cooling back is spilt one deck Paris white and is taken up, and film proportionally adds sulphur in use, promptly obtains finished product.
Claims (10)
1. the one kind high anti-xanthochromia of mutual viscosity gloss type is bleached look sole rubber, it is characterized in that: calculate by weight, it comprises 60～70 parts of 1# standard glue, 25～45 parts of synthetical glues, 1.8～2.5 parts of sulphur, 2.2～2.6 parts of promotor, 7～9 vulcanization levellers, 4～5 parts of Macrogol 4000s, 1～2 part of anti-aging agent, 1.7～2.1 portions of ultramarines, 45～55 parts of titanium dioxides, 40～50 parts of white carbon blacks, 20～30 parts of nano-calcium carbonates, 0.4～0.6 part of mass percent is permanent violet rubber master batch and 7～9 parts of white machine oil of 1%.
2. the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 1 look sole rubber, it is characterized in that: calculate by weight, it comprises 65 parts of 1# standard glue, 15 parts of 2000R solution polymerized butylbenzene glue, 20 parts of cis-butadiene cements, 2 parts of sulphur, 2.6 part Microcrystalline Wax, 2.4 part promotor, 5.6 parts of stearic acid, 2.5 parts of nano zine oxides, 4.3 part Macrogol 4000 #, 1.7 part anti-aging agent, 1.9 portions of ultramarines, 50 parts of titanium dioxides, 45 parts of white carbon blacks, 25 parts of nano-calcium carbonates, 0.50 part of mass percent are 1% permanent violet rubber master batch, 8 parts of white machine oil and 2.5 parts of RX-80 xylene resins.
3. the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 1 and 2 look sole rubber, it is characterized in that: synthetical glue is made up of 10～20 parts of solution polymerized butylbenzene glue and 15～25 parts of cis-butadiene cements.
4. the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 1 and 2 look sole rubber, it is characterized in that: vulcanization leveller is made up of 5～6 parts of three grades of stearic acid and 2～3 parts of nano zine oxides.
5. the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 1 and 2 look sole rubber, it is characterized in that: per 2.4 parts of promotor are made up of 0.5 part of captax and 1.9 parts of altaxs.
6. the anti-xanthochromia of high mutual viscosity gloss type according to claim 1 and 2 bleaching look sole rubber is characterized in that: mass percent is that 1% permanent violet rubber master batch is that 1 part of permanent violet and 100 parts of 1# standard glue mix.
7. the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 1 and 2 look sole rubber, it is characterized in that: anti-aging agent is anti-aging agent KY-405L.
8. the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 1 and 2 look sole rubber is characterized in that: also comprise 2.4～2.8 parts of Microcrystalline Waxes and 2～3 parts of RX-80 xylene resins.
9. the preparation method of the anti-xanthochromia bleaching of one kind high mutual viscosity gloss type look sole rubber,
It is characterized in that: plasticate earlier, 1# standard glue pressed refining 1～3min in Banbury mixer after, add anti-aging agent, press and mention floating weight behind refining 2～4min and make the sizing material upset, continue to press and to mention floating weight behind refining 3～5min and make the sizing material upset, continue to press discharge behind refining 1～3min; Behind the Banbury mixer discharge, 25min with interior the material of discharging is dropped into 0 roll spacing from opening rubber mixing machine in, on draw logical 2～3 roads, then the roll spacing of mill is transferred to 4～6mm from 0, with sizing material bag roll row bubble, with sizing material reel metering, obtain plasticity number and be 0.40～0.45 broken-(down)rubber after finishing; With sizing material deposit carry out again more than 4 hours mixing, broken-(down)rubber and solution polymerized butylbenzene glue and cis-butadiene cement are put into Banbury mixer close refining 1min, add titanium dioxide then, middle material and white carbon black, press refining 2～4 minutes, mention the powder material that floating weight of banbury mixer will overflow banburying chamber and sweep go back to banburying chamber, continue to press refining 1～3 minute, mention the powder material that floating weight of banbury mixer will overflow banburying chamber once more and sweep go back to banburying chamber, and add nano-calcium carbonate and white machine oil successively, press refining to mention the powder material that floating weight of banbury mixer will overflow banburying chamber after 2 minutes then and sweep go back to banburying chamber, press refining 2 minutes again, obtain rubber unvulcanizate; Rubber unvulcanizate is added mill, is to wrap roller under 4～5mm condition in roll spacing, to operate on reel 1/2nd modes, about operate on and turn refining 7～8 minutes, per three of scribing cooling back is spilt one deck Paris white and is taken up, and film proportionally adds sulphur in use, promptly obtains finished product.
10. the preparation method of the anti-xanthochromia bleaching of high mutual viscosity gloss type according to claim 9 look sole rubber, it is characterized in that: material is Microcrystalline Wax, promotor, stearic acid, nano zine oxide, Macrogol 4000, ultramarine, permanent violet rubber master batch and RX-80 xylene resin in described.
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| CN102898695A (en) * | 2012-09-29 | 2013-01-30 | 广东智达行新材料有限公司 | Super yellowing-resistant rubber for soles and preparation method for super yellowing-resistant rubber |
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| CN105131367A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Inter-steam vulcanization rolling type internal bonding type pink odorless sole rubber and preparation method and application thereof |
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| CN105153487A (en) * | 2015-10-09 | 2015-12-16 | 际华三五三七制鞋有限责任公司 | Intermittent steam vulcanization die-pressed orange shoe sole rubber as well as preparation method and application thereof |
| CN105639825A (en) * | 2016-01-04 | 2016-06-08 | 中国人民解放军总后勤部军需装备研究所 | Boots special for military parade and manufacturing method thereof |
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| CN109836630A (en) * | 2019-01-21 | 2019-06-04 | 茂泰(福建)鞋材有限公司 | A kind of high-weatherability white rubber sole and preparation method thereof |
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| CN110606999A (en) * | 2019-09-27 | 2019-12-24 | 际华三五三七有限责任公司 | Rubber for rubber shoe forming clamp and preparation method thereof |
| CN111333922A (en) * | 2019-09-27 | 2020-06-26 | 际华三五三七有限责任公司 | Rubber cement for double-blade scraping of middle base cloth of rubber shoes as well as preparation method and application of rubber cement |
| CN111349277A (en) * | 2020-04-30 | 2020-06-30 | 黄成余 | Low-hardness high-wear-resistance anti-slip sole material for shoes and preparation method thereof |
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| CN102417621A (en) * | 2011-11-25 | 2012-04-18 | 芜湖风雪橡胶有限公司 | Wear resistant undersole rubber material for shoes |
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| CN102898695A (en) * | 2012-09-29 | 2013-01-30 | 广东智达行新材料有限公司 | Super yellowing-resistant rubber for soles and preparation method for super yellowing-resistant rubber |
| CN104788879A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Electric-shock-resistant rubber sole and preparation method thereof |
| CN105131367A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Inter-steam vulcanization rolling type internal bonding type pink odorless sole rubber and preparation method and application thereof |
| CN105131361A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Inter-steam vulcanization rolling type peak green external binding method rubber sole glue and preparation method and application thereof |
| CN105153487A (en) * | 2015-10-09 | 2015-12-16 | 际华三五三七制鞋有限责任公司 | Intermittent steam vulcanization die-pressed orange shoe sole rubber as well as preparation method and application thereof |
| CN105639825A (en) * | 2016-01-04 | 2016-06-08 | 中国人民解放军总后勤部军需装备研究所 | Boots special for military parade and manufacturing method thereof |
| CN105639825B (en) * | 2016-01-04 | 2017-10-03 | 中国人民解放军总后勤部军需装备研究所 | One kind is reviewed troops special footwear and preparation method thereof |
| CN106235512A (en) * | 2016-08-19 | 2016-12-21 | 嘉兴宜泰鞋业有限公司 | A kind of ultralight color inhibition sole of composite and preparation method thereof |
| CN109836630A (en) * | 2019-01-21 | 2019-06-04 | 茂泰(福建)鞋材有限公司 | A kind of high-weatherability white rubber sole and preparation method thereof |
| CN109836630B (en) * | 2019-01-21 | 2021-02-26 | 茂泰(福建)鞋材有限公司 | High-weather-resistance white rubber sole and preparation method thereof |
| CN110028712A (en) * | 2019-04-22 | 2019-07-19 | 昆山多威体育用品有限公司 | A kind of rubber ground and its preparation method and application of wear-resisting on-slip rebound |
| CN110606999A (en) * | 2019-09-27 | 2019-12-24 | 际华三五三七有限责任公司 | Rubber for rubber shoe forming clamp and preparation method thereof |
| CN111333922A (en) * | 2019-09-27 | 2020-06-26 | 际华三五三七有限责任公司 | Rubber cement for double-blade scraping of middle base cloth of rubber shoes as well as preparation method and application of rubber cement |
| CN111349277A (en) * | 2020-04-30 | 2020-06-30 | 黄成余 | Low-hardness high-wear-resistance anti-slip sole material for shoes and preparation method thereof |
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