CN105639825B - One kind is reviewed troops special footwear and preparation method thereof - Google Patents
One kind is reviewed troops special footwear and preparation method thereof Download PDFInfo
- Publication number
- CN105639825B CN105639825B CN201610004278.5A CN201610004278A CN105639825B CN 105639825 B CN105639825 B CN 105639825B CN 201610004278 A CN201610004278 A CN 201610004278A CN 105639825 B CN105639825 B CN 105639825B
- Authority
- CN
- China
- Prior art keywords
- footwear
- parts
- shoe
- mdi
- troops
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B3/00—Footwear characterised by the shape or the use
- A43B3/02—Boots covering the lower leg
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/10—Footwear characterised by the material made of rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/42—Filling materials located between the insole and outer sole; Stiffening materials
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B21/00—Heels; Top-pieces or top-lifts
- A43B21/02—Heels; Top-pieces or top-lifts characterised by the material
- A43B21/06—Heels; Top-pieces or top-lifts characterised by the material rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Reviewed troops special footwear and preparation method thereof the invention discloses one kind.The present invention review troops special footwear sole include polyurethane material prepare footwear midsole, elastomeric material 1 prepare the big bottom of footwear and elastomeric material 2 prepare heel；It is attached between the upper of a shoe of the footwear and the big bottom of the footwear by injecting the footwear midsole of the polyurethane material formation；The sole is provided with texture.Sole matter of the present invention is hard, light, wear-resisting, and the intensity of heel is high；As footwear of reviewing troops, the sound that stride walking is contacted with ground is loud and clear, comfortable and easy to wear.Footwear outsourcing is with inboard design rubber and plastic wear plate；Heel of a shoe structure design is asymmetric, improves performance comfortable and easy to wear.Shoestring uses polymorphic structure, and substantially, the shoestring storage band set on flap is easy to shoestring exposed portion to deposit to Shoestring tying effect, in case footwear is attractive in appearance.
Description
Technical field
Reviewed troops special footwear and preparation method thereof the present invention relates to one kind.
Background technology
It is activity that country and one of army have Special Significance to review troops.Mainly completed refering to personnel queue advance training and
Displaying, is different from general training, queue is advanced, and training physical consumption is big, and training strength is high, and footwear comfortableness, durability etc. are needed
Ask higher, it is necessary to carry out special footwear research of reviewing troops, meet the particular/special requirement that queue is advanced to footwear.
Queue training of advancing is included in step and stride.The conventional footwork that soldier advances in step, the essential of exercise is, left foot to
Front steps about 75cm, is landed according to the order of first heel hind paw, while centre of body weight moves forward, method is acted right crus of diaphragm like this,
Gait of march 116~122 step per minute.Stride is mainly used in march-past, and the essential of exercise is that left foot kicks out of about 75 lis to front
Rice, leg is exceptionally straight, and tiptoe is pushed, and sole is parallel to the ground, from the ground about 25cm, appropriate firmly full sole is landed, while body
The body weight heart is moved forward, and method is acted right crus of diaphragm like this, gait of march 110~116 step per minute.More conventional training, to army waiting for inspection's queue
Traveling neat and consistent, the officers and men's action norm that is reviewed requirement tighter, standard is higher.The officers and men that are reviewed add up the daily training time
10 hours, training strength is high, and the physical efficiency to officers and men is a kind of test, for footwear, is also in terms of comfortableness, durability
A kind of test close to the limit.
Conventional footwear is different from, reviews troops and uses footwear, especially square team footwear has particularity and specificity on foot, specifically
Show as：One is influenceed by high pressure training, and footwear of reviewing troops should possess preferable durability.By queue traveling action feature and height
Strength training is influenceed, and footwear of reviewing troops easily is damaged, and concrete condition shows as vamp and broken hole occurs, and sole anti-skid design is smoothed,
Main portions are bosom and sole in toe-cap inboard, boot upper heel.More conventional footwear, footwear of reviewing troops footwear material should possess preferably
Anti-wear performance and resistance to performance of colliding with.Two be that leg of a boot design meets foot motion, improves comfort property.The design of footwear of the reviewing troops leg of a boot should
Softness, taut pin pressing action when facilitating stride, meanwhile, wrapped after upper of a shoe with needing particular design, it is to avoid because of heel during taut underfooting pressure
Material stacking wrinkles and causes mill pin problem.Three are during queue is advanced, and footwear of reviewing troops sole lands megaphonia, clear and melodious.Refer to
Square team emphasizes spring heel position during quick march, megaphonia when the full facies palmaris of sole lands when stride is advanced, clear and melodious, with routine
Sole possesses silencing function and contradicted when making caliga traveling, it is necessary to for this particular/special requirement design specialized footwear sole construction and flower
Line.Four be that square team spring heel can provide human body powerful support on foot.Require that spring heel is hard refering to square team, when walking in step
Human body powerful support can be provided, it is to avoid body rises and falls with the crimp of heel material, and then influence uniform queue effect
Really.By investigation, make caliga special functional demands for army waiting for inspection, it is necessary to carry out special footwear research of reviewing troops.
The content of the invention
Reviewed troops boots special and preparation method thereof it is an object of the invention to provide one kind.Sole matter of the present invention is hard, light, resistance to
Mill, the intensity of heel is high；As footwear of reviewing troops, the sound that stride walking is contacted with ground is loud and clear, comfortable and easy to wear.
Reviewed troops special footwear the invention provides one kind, the sole of the footwear is included in footwear prepared by polyurethane material
Heel prepared by the big bottom of footwear and elastomeric material 2 prepared by bottom, elastomeric material 1；
By injecting the footwear that the polyurethane material is formed between the upper of a shoe of the footwear and the big bottom of the footwear
Midsole is attached；
The sole is provided with texture.
In above-mentioned footwear, the thickness of the texture of the sole is 4.8~5.2mm；
The polyurethane material is made up of the component of following portions by weight：
1 60~70 parts of polyethers；
2 10~20 parts of polyethers；
10~15 parts of chain extender；
0.5~1.0 part of surfactant；
1.0~3.0 parts of dispersant；
1.0~2.0 parts of amine catalyst；
0.1~0.5 part of water；
135~145 parts of MDI modifiers；
The elastomeric material 1 is made up of the component of following portions by weight：
1~3 part of solution polymerized butylbenzene；
20~30 parts of cis-butadiene cement；
Mark 8~15 parts of glue SVR-3L；
10~15 parts of carbon black；
1.0~3.0 parts of zinc oxide；
0.3~0.5 part of stearic acid；
1.0~1.5 parts of activating agent；
0.5~1.0 part of accelerator；
0.5~0.8 part of sulphur；
The elastomeric material 2 is made up of the component of following portions by weight：
3.0~8.0 parts of high-phenylethylene；
20~30 parts of the cis-butadiene cement；
5~10 parts of the mark glue SVR-3L；
10~20 parts of the carbon black；
1.0~3.0 parts of the zinc oxide；
Described stearic acid 0.3-0.5 parts；
1.0~2.0 parts of the activating agent；
0.5~1.0 part of the accelerator；
0.5~1.0 part of the sulphur.
In above-mentioned footwear, the polyethers 1 is at least one of TED-28, KE-510 and DP-4000E；
The polyethers 2 is at least one of ZST-21, KE-3704 and DP-6000；
The chain extender is at least one of ethylene glycol, propane diols, butanediol, trimethylolpropane and glycerine；
The surfactant is for silicone surfactant and/or without silicone surfactant；Live on the silicone surface
Property agent be Mai Tu company produce L1500, L1540 and/or L1505, it is described without silicone surfactant be gas companies life
The LK221 and/or LK043 of production；
The dispersant is n- dodecyl mereaptan, dodecyl sodium sulfonate is received and/or polyethylene glycol；
The amine catalyst is A33, A333L, triethanolamine and/or glycerine；
The MDI modifiers are polyether-modified MDI；
The molecular weight of the solution polymerized butylbenzene is 135~180 (135,158,180)；
The molecular weight of the cis-butadiene cement is 30,000~120,000 (3-5 ten thousand, 7-8 ten thousand, 10-12 ten thousand)；
The activating agent is polyethylene glycol；
The accelerator is at least one of the parallel thiazole of diphenyl disulfide, benzoyl peroxide and Sulfur.
In the present invention, the TED-28, the KE-510 and the DP-4000E are trade name, and Tianjin is available commercially from respectively
Petrochemical industry, can Leah chemistry and Plant of Tianjin Petrochemical Company；
The ZST-21, the KE-3704 and the DP-6000 are trade name, be available commercially from respectively Plant of Tianjin Petrochemical Company, can profit
Sub- chemistry and Plant of Tianjin Petrochemical Company；
The A33, the A333L are trade name, are available commercially from air chemical industry.
In above-mentioned footwear, the polyether-modified MDI is prepared in accordance with the following steps：By MDI and TED-28, KE3704 and two
Mixed with propylene glycol, is warming up to 65~85 DEG C of 2~5h of reaction, then adds the liquefied MDI, continue to react, produce described
Polyether-modified MDI.
In above-mentioned footwear, the heel is shaped as irregular shape, the heel exceed the outsourcing of the sole with；
Flap sewing shoestring storage bag in place's suitable for reading of the footwear；
The shoestring is abnormity, and the shoestring of the footwear uses open front lace-tied type；
The vamp material of the footwear is combined using skin cloth；
The resistance to rubber and plastic piece that collides with of the footwear followed by inboard sewing.
Present invention also offers the preparation method of above-mentioned special footwear of reviewing troops, comprise the following steps：(1) claim is used
Polyurethane material any one of 2-5 prepares the footwear midsole, the elastomeric material 1 and prepares the big bottom of the footwear and described
Elastomeric material 2 prepares the heel, the sole is provided with texture；
(2) by injecting the footwear that the polyurethane material is formed between the upper of a shoe of the footwear and the big bottom of the footwear
Boots midsole is attached, and produces the special footwear of reviewing troops.
In above-mentioned method, comprise the following steps：1) by the footwear outer bottom prepared with the polyurethane material and institute
State the described followed by fluffing, washing, brush coating of the preparation of elastomeric material 2；Upper of a shoe fluffs；
2) at the upper of a shoe flank position, the viscous viscous polyurethane foam of the heart, the heel region that hooks fills out core；
3) by step 2) upper of a shoe drying after processing, then the upper of a shoe is covered last carving by footwear outer bottom heating；
4) the footwear outer bottom is first added in a mold, and the poly- ammonia is injected between the footwear outer bottom and the upper of a shoe
The raw material reaction of ester material obtains the footwear midsole, then depanning；
5) by step 4) the dress last carving sizing of obtained footwear, then with shoe-pad, that is, obtain the special footwear of reviewing troops.
In above-mentioned method, step 1) in, the temperature of the washing is 60~70 DEG C, concretely 60 DEG C, the washing
Time can be 2~7min, concretely 2min；
The temperature of the brush coating can be 30~35 DEG C, and the time of the brush coating can be 2~3min；
The depth of the upper of a shoe fluffing is no more than the 1/4 of the upper of a shoe thickness；
Step 3) in, the temperature of the drying and the heating can be 75~80 DEG C, concretely 80 DEG C；
The time of the drying and the heating can be 1~2min；
Step 5) in, the temperature of the dress last carving sizing is -5~15 DEG C, and the time of the dress last carving sizing is 5~10min；
Also include the footwear repairing mouth of a river glue and/or appearance modification in step 5, the appearance modification is specially that vamp is thrown
Polishing is bright.
Invention further provides the polyurethane material of the footwear midsole for the special footwear of reviewing troops, the polyurethane
Material is made up of the component of following portions by weight：
1 60~70 parts of polyethers；
2 10~20 parts of polyethers；
10~15 parts of chain extender；
0.5~1.0 part of surfactant；
1.0~3.0 parts of dispersant；
1.0~2.0 parts of amine catalyst；
0.1~0.5 part of water；
135~145 parts of MDI modifiers.
In above-mentioned polyurethane material, the polyethers 1 is at least one of TED-28, KE-510 and DP-4000E；
The polyethers 2 is at least one of ZST-21, KE-3704 and DP-6000；
The chain extender is at least one of ethylene glycol, propane diols, 1.4 butanediols, trimethylolpropane and glycerine；
The surfactant is for silicone surfactant and/or without silicone surfactant；Live on the silicone surface
Property agent be Mai Tu company produce L1500, L1540 and/or L1505, it is described without silicone surfactant be gas companies life
The LK221 and/or LK043 of production；
The dispersant is n- dodecyl mereaptan, dodecyl sodium sulfonate is received and/or polyethylene glycol；
The amine catalyst is A33, A333L, triethanolamine and/or glycerine；
The MDI modifiers are polyether-modified MDI；The polyether-modified MDI is prepared in accordance with the following steps：By MDI with
TED-28, KE3704 and DPG mixing, are warming up to 65~85 DEG C of 2~5h of reaction, then add the liquefied MDI,
Continue to react, produce the polyether-modified MDI；
The molecular weight of the solution polymerized butylbenzene is 135~180 (135,158,180)；
The molecular weight of the cis-butadiene cement is 30,000~120,000 (3-5 ten thousand, 7-8 ten thousand, 10-12 ten thousand)；
The activating agent is polyethylene glycol；
Changed accelerator is at least one of the parallel thiazole of diphenyl disulfide, benzoyl peroxide and Sulfur.
The present invention has advantages below：
Sole matter of the present invention is hard, light, wear-resisting, and the intensity of heel is high；As footwear of reviewing troops, stride walking is contacted with ground
Sound it is loud and clear, it is comfortable and easy to wear.Footwear outsourcing is with inboard design rubber and plastic wear plate；Heel of a shoe structure design is asymmetric, is improved
Performance comfortable and easy to wear.Shoestring uses polymorphic structure, and substantially, the shoestring storage band set on flap is easy to shoestring to Shoestring tying effect
Exposed portion is deposited, in case footwear is attractive in appearance.
Brief description of the drawings
Fig. 1 is the sole of special footwear of the invention of reviewing troops, and wherein Fig. 1 (a) is the side view of sole, and Fig. 1 (b) is sole
Front elevation.
Fig. 2 is the outer cup and inner cup figure of special footwear of the invention of reviewing troops, and wherein Fig. 2 (a) is outer cup figure, and Fig. 2 (b) is inner cup
Figure.
Fig. 3 is the special-shaped of special footwear of the invention of reviewing troops followed by schemes.
Embodiment
Experimental method used in following embodiments is conventional method unless otherwise specified.
Material, reagent used etc., unless otherwise specified, are commercially obtained in following embodiments.
The preparation of embodiment 1, footwear midsole
First, polyurethane material is by the A of following portions by weight, and B component is made：
(1) component A formula and processing technology：
1. formula：A:68.333 parts of polyethers 1 (Plant of Tianjin Petrochemical Company TED-28)；
B:15.889 parts of polyethers 2 (can Leah chemistry KE3704)；
C:14.111 parts of chain extender (1.4 butanediol)；
D. 0.5 part of surfactant (air chemical industry LK221)；
E. 2.5 parts of dispersant (n- dodecyl mereaptan)；
F. 1.333 parts of amine catalyst (air chemical industry A33)；
G. 0.333 part of water；
2. production technology：By above raw material, put into sequence in reactor, be warming up to 65 degree, constant temperature 2 hours takes
Sample detects the acid number of product, and hydroxyl value in acceptability limit, cools to 40 degree, sealed stand-by.
It is attached：Product index：Acid number：≤ 0.3, hydroxyl value：190±10.
(2) polyether-modified MDI：
1. formula：
A1Pure MDI:65 parts
B1.TED-28:20 parts
C1.KE3704:5 parts
D1DPG:5 parts
E1Liquefied mdi:5 parts
2. production technology：
2.1 according to above-mentioned formula table, first by A1In material input reactor, stirring is opened.
B is added under 2.2 stirrings1、C1、D1Material, is warming up to 70 DEG C, constant temperature 3 hours.
2.3 cool to 60 degree, enter E1Material, is stirred 45 minutes in 55-60 DEG C.
NCO is surveyed in 2.4 samplings, in acceptability limit, cools to 40 DEG C, stops stirring, and inflated with nitrogen sealing preserve is stand-by.
Polyether-modified MDI product indexs：NCO:18.5 ± 0.3%, outward appearance：Clear.
(3) by the good component A of above-mentioned production and polyether-modified MDI components material, according to mass ratio 100：135 mixing, at a high speed
Stir in rear mold and react, you can obtain footwear midsole.
4th, as shown in table 1, the performance of footwear midsole of the present invention refers to the performance indications of footwear midsole of the present invention as shown in Table 1
Mark test value and exceed set quota in the prior art, therefore with performances such as well wear-resisting, folding, light weights.
The performance indications of the footwear midsole of table 1
| Inspection project | Measurement unit | Standard set quota | Test value |
| Hardness | Shore A | 80±3 | 81 |
| Proportion | g/cm3 | 0.65±0.05 | 0.61 |
| Tensile strength | MPa | ≥5.0 | 6.8 |
| Elongation | % | ≥350 | 420 |
| Trousers shape tearing strength | kN/m | ≥5.0 | 5.8 |
| Resilience | % | ≥30 | 36 |
| Compression deformation rate | % | ≤20 | 7.6 |
| Folding quality | It is secondary | At -15 DEG C, it is not broken for 100,000 times | Do not split |
The preparation of embodiment 2, footwear outer bottom
The formula of elastomeric material 1：
A. solution polymerized butylbenzene:10 parts；
B. cis-butadiene cement:28 parts；
C. glue SVR-3L marks in Vietnam:5 parts；
D. carbon black:20 parts；
E. zinc oxide:2.25 part；
F stearic acid:0.42 part；
G. polyethylene glycol:1.4 part；
H. accelerator:(the thio bisbenzothiazoles of 2.2-):0.65 part；
I. sulphur:0.8 part；
The preparation of footwear outer bottom：By the recipe ingredient of above-mentioned elastomeric material 1, according to it is above-mentioned prepare elastomeric material 1 the step of
It is added in mould and reacts, you can obtains footwear outer bottom.
As shown in table 2, the elongation of footwear outer bottom of the present invention is the performance indications of footwear outer bottom of the present invention as shown in Table 2
373% has more 73% than minimum value in standard value index 300%, illustrates that the present invention has good elasticity；While others
Energy index shows that anti-wear performance of the present invention and folding quality are good.
The performance indications of the footwear outer bottom of table 2
| Inspection project | Measurement unit | Standard set quota | Test value |
| Hardness | Shao A | 75±3 | 73 |
| Proportion | g/cm3 | 1.15±0.03 | 1.58 |
| Tensile strength | MPa | ≥13.5 | 16.7 |
| Elongation | % | ≥300 | 373 |
| Trousers shape tearing strength | kN/m | ≥15.0 | 22.5 |
| DIN is wear-resisting | ≤60 | 47 | |
| National standard polishing scratch | Mm | ≤4.0 | 3.2 |
| Akron polishing scratch | cm3 | ≤0.1 | 0.04 |
| Folding quality | It is secondary | At 25 DEG C, it is not broken for 100,000 times | Do not split |
The preparation of embodiment 3, the heel of footwear
1. the formula of elastomeric material 2：
A. high-phenylethylene:5 parts；
B. cis-butadiene cement:25 parts；
C.SVR-3L marks glue:10 parts；
D. carbon black:17 parts；
E. zinc oxide:2.0 part；
F. stearic acid:0.4 part；
G. polyethylene glycol:1.5 part；
H. accelerator (the thio bisbenzothiazoles of 2.2-)：0.6 part；
I. 0.8 part of sulphur；
2. rubber outsole production technology：
2.1. weigh
All raw materials in addition to added promoter are weighed by the formula of design；
2.2 banburying
Accurate high-phenylethylene, cis-butadiene cement and SVR-3L mark collagen material mixing will be weighed, starts banbury banburying, makes material
It is well mixed, the carbon black of 2/3 amount is added, continues banburying, rubber and carbon black mixing, lumps again, when temperature reaches 100 DEG C,
All remaining raw materials (E-I) and remaining carbon black are added, until when temperature continues to rise to 100 DEG C, the mixing of all raw materials
Body lumps again；
2.3 mills plus sulphur
The good sizing material of banburying is subjected to mill, discharged with sheet material；The sheet material for coming out mill by proportioning is put in
Stood at drying, begin to use mill to carry out plus sulphur (added promoter), first beaten sheet material in mill for the first time
With second of triangle bag, then third time triangle bag is beaten, spacer gel is left above roll spacing, while added promoter is added in into accumulation
On glue, then carry out smashing glue, mix, mill play, which is changed to, beats triangle bag and clot method, after being well mixed, discharging；
2.4 survey curing curve
The small pieces material of clip one, becomes instrument with sulphur and surveys curing curve, record time of scorch and sulfurizing time, and adjust to conjunction
Lattice scope.
2.5. get the raw materials ready：
The material of test passes takes slice respectively by sole type body difference, and shaping, die are cut out the modes such as bar and got the raw materials ready
2.6. followed by super abrasive block oil pressure shaping
The cure time of hydraulic press is adjusted according to record time of scorch and sulfurizing time, the first material is cut into super
It is wear-resisting block-shaped, oil pressure in hydraulic press is put in after pound weight and is molded, super abrasive block is produced；Deburring processing is carried out, is treated and General Purpose Rubber
Big bottom post forming.Super abrasive block storage during pay special attention to it is dust-proof, it is anti-pollution.
2.7. big bottom shaping
Damping wear-resistant block is put into the big bed die tool of correspondence model, with big bottom common raw material after auto-vulcanization in 24 hours
Primary oil pressure is molded.
2.8. post processing：
The good sole of production carries out deburring, beats thick, and edging, spray painting etc. are carried out according to type body difference and client's specific requirement.
The preparation of the heel of footwear：By the recipe ingredient of above-mentioned elastomeric material 2, according to the above-mentioned step for preparing elastomeric material 2
Rapid be added in mould is reacted, you can obtain the heel of footwear.
The performance indications of the heel of footwear of the present invention as shown in table 3, survey as shown in Table 3 by the hardness of the heel of footwear of the present invention
Examination value is 91, illustrates that the hardness of the heel of footwear of the present invention is strong；Test value 91 wear-resisting DIN, explanation lower than standard set quota
Wearability of the present invention is good.
The performance indications of the heel of the footwear of table 3
| Inspection project | Measurement unit | Standard set quota | Test value |
| Hardness | Shao A | 90±3 | 91 |
| Proportion | g/cm3 | 1.2±0.03 | 1.207 |
| Tensile strength | MPa | ≥13.5 | 16.1 |
| Elongation | % | ≥200 | 232 |
| Pants type tearing strength | kN/m | ≥10.0 | 11.1 |
| DIN is wear-resisting | ≤100 | 91 | |
| National standard polishing scratch | mm | ≤4.0 | 2.9 |
| Akron polishing scratch | cm3 | ≤0.1 | 0.073 |
The preparation of embodiment 4, special footwear of reviewing troops
Abnormity followed by design, as shown in Figure 3：Pushed for the ease of sole, reduce because sole push cause followed by heap help into
And there is the phenomenon of mill pin heel, counter is asymmetric design and sewing.Abnormity followed by structure are wrapped after including with+heel
Sponge+small master is with+heel.This inner high outer low design matches with foot followed by skeletal muscle distribution, improves dress
Comfortableness.
The resistance to piece that collides with of rubber and plastic：
Queue traveling training requirement, every sufficient front tip part bit interleaving, which is touched in heel, cherishes leg after position keeps one's balance
Thus kick out of, therefore, heel of a shoe is inboard easily damaged, and the resistance to rubber and plastic piece that collides with is sewed at the position, and intensity is worn in raising.The rubber and plastic
Piece material TPU modifications are made and hardness is 90A.
The preparation method for special footwear of reviewing troops, comprises the following steps：1) heel prepared by footwear outer bottom and elastomeric material 2 rises
Hair, wash 2min at 60 DEG C, twice of 30~35 DEG C of 2~3min of brush coating activate 2~3min at 60 DEG C；Upper of a shoe fluffs, by son
Mouth edge is fluffed, and sand wound side pin is not answered, and the 1/4 of leather thickness is not to be exceeded in fluffing depth；
2) at upper of a shoe flank position, the viscous viscous polyurethane foam of the heart, heel region that hooks fills out core, is adhesively fixed using PUR, should
It is viscous just, cement；
3) by step 2) processing after upper of a shoe drying, at 80 DEG C dry 1~2min, footwear outer bottom heat 80 DEG C, 1~
2min, then covers last carving by upper of a shoe, set just, set it is flat；
4) rubber outsole is first added in a mold, and polyurethane material is injected between the big bottom of footwear and upper of a shoe and is obtained in footwear
Bottom, rim of the mouth and abutment wall decorative pattern are clear, do not come unglued, and foaming is abundant, and foamed glue is firmly combined with outer layer rubber, not starved, is then gone out
Mould；
5) by step 4) the dress last carving sizing of obtained footwear, dress last carving in place, do not answer wrong number, and cryogenic temperature is -5 DEG C, time
10min；Mouth of a river glue is repaiied, mouth of a river glue should be cut to be repaiied together only, should not injure sole；Appearance modification, vamp throwing polishing is bright, then with footwear
Pad, that is, obtain the present invention and review troops special footwear, as shown in Figure 2.
Claims (10)
- The special footwear 1. one kind is reviewed troops, it is characterised in that：The sole of the footwear includes footwear midsole, rubber prepared by polyurethane material Heel prepared by the big bottom of footwear and elastomeric material 2 prepared by glue material 1；By injecting the footwear midsole that the polyurethane material is formed between the upper of a shoe of the footwear and the big bottom of the footwear It is attached；The sole is provided with texture；The polyurethane material is made up of the component of following portions by weight：1 60~70 parts of polyethers；2 10~20 parts of polyethers；10~15 parts of chain extender；0.5~1.0 part of surfactant；1.0~3.0 parts of dispersant；1.0~2.0 parts of amine catalyst；0.1~0.5 part of water；135~145 parts of MDI modifiers；The polyethers 1 is at least one of TED-28, KE-510 and DP-4000E；The polyethers 2 is at least one of ZST-21, KE-3704 and DP-6000；The elastomeric material 1 is made up of the component of following portions by weight：1~3 part of solution polymerized butylbenzene；20~30 parts of cis-butadiene cement；Mark 8~15 parts of glue SVR-3L；10~15 parts of carbon black；1.0~3.0 parts of zinc oxide；0.3~0.5 part of stearic acid；1.0~1.5 parts of activating agent；0.5~1.0 part of accelerator；0.5~0.8 part of sulphur；The elastomeric material 2 is made up of the component of following portions by weight：3.0~8.0 parts of high-phenylethylene；20~30 parts of the cis-butadiene cement；5~10 parts of the mark glue SVR-3L；10~20 parts of the carbon black；1.0~3.0 parts of the zinc oxide；Described stearic acid 0.3-0.5 parts；1.0~2.0 parts of the activating agent；0.5~1.0 part of the accelerator；0.5~1.0 part of the sulphur.
- 2. special footwear according to claim 1 of reviewing troops, it is characterised in that：The thickness of the texture of the sole be 4.8~ 5.2mm。
- 3. special footwear according to claim 2 of reviewing troops, it is characterised in that：The chain extender is ethylene glycol, propane diols, fourth At least one of glycol, trimethylolpropane and glycerine；The surfactant is for silicone surfactant and/or without silicone surfactant；The silicone surfactant L1500, L1540 and/or the L1505 produced for Mai Tu company, described is what gas companies were produced without silicone surfactant LK221 and/or LK043；The dispersant is n- dodecyl mereaptan, dodecyl sodium sulfonate is received and/or polyethylene glycol；The amine catalyst is A33, A333L, triethanolamine and/or glycerine；The MDI modifiers are polyether-modified MDI；The molecular weight of the solution polymerized butylbenzene is 135~180；The molecular weight of the cis-butadiene cement is 30,000~120,000；The activating agent is polyethylene glycol；The accelerator is at least one of the parallel thiazole of diphenyl disulfide, benzoyl peroxide and Sulfur.
- 4. special footwear according to claim 3 of reviewing troops, it is characterised in that：The polyether-modified MDI is in accordance with the following steps Prepare：MDI is mixed with TED-28, KE3704 and DPG, 65~85 DEG C of 2~5h of reaction is warming up to, then adds liquid The MDI changed, continues to react, produces the polyether-modified MDI.
- 5. special footwear according to claim 1 or 2 of reviewing troops, it is characterised in that：The heel is shaped as irregular shape Shape, the heel exceed the sole outsourcing with；Flap sewing shoestring storage bag in place's suitable for reading of the footwear；The shoestring is abnormity, and the shoestring of the footwear uses open front lace-tied type；The vamp material of the footwear is combined using skin cloth；The resistance to rubber and plastic piece that collides with of the footwear followed by inboard sewing.
- 6. the preparation method for special footwear of being reviewed troops any one of claim 1-5, comprises the following steps：(1) right is used It is required that polyurethane material any one of 2-5 prepare the footwear midsole, the elastomeric material 1 prepare the big bottom of the footwear and The elastomeric material 2 prepares the heel, the sole is provided with texture；(2) by injecting in the footwear of the polyurethane material formation between the upper of a shoe of the footwear and the big bottom of the footwear Bottom is attached, and produces the special footwear of reviewing troops.
- 7. preparation method according to claim 6, comprises the following steps：1) described in being prepared with the polyurethane material The described followed by fluffing of footwear outer bottom and the preparation of the elastomeric material 2, washing, brush coating；Upper of a shoe fluffs；2) at the upper of a shoe flank position, the viscous viscous polyurethane foam of the heart, the heel region that hooks fills out core；3) by step 2) upper of a shoe drying after processing, then the upper of a shoe is covered last carving by footwear outer bottom heating；4) the footwear outer bottom is first added in a mold, and the polyurethane material is injected between the footwear outer bottom and the upper of a shoe The raw material reaction of material obtains the footwear midsole, then depanning；5) by step 4) the dress last carving sizing of obtained footwear, then with shoe-pad, that is, obtain the special footwear of reviewing troops.
- 8. preparation method according to claim 7, it is characterised in that：Step 1) in, the temperature of the washing is 60~70 DEG C, the time of the washing is 5~7min；The temperature of the brush coating is 30~35 DEG C, and the time of the brush coating is 2~3min；The depth of the upper of a shoe fluffing is no more than the 1/4 of the upper of a shoe thickness；Step 3) in, the temperature of the drying and the heating is 75~80 DEG C；The time of the drying and the heating is 1~2min；Step 5) in, the temperature of the dress last carving sizing is -5~15 DEG C, and the time of the dress last carving sizing is 5~10min；Also include the footwear repairing mouth of a river glue and/or appearance modification in step 5, the appearance modification is specially that vamp throws polishing Amount.
- 9. a kind of polyurethane material of footwear midsole for special footwear of being reviewed troops any one of claim 1-5, it is special Levy and be：The polyurethane material is made up of the component of following portions by weight：1 60~70 parts of polyethers；2 10~20 parts of polyethers；10~15 parts of chain extender；0.5~1.0 part of surfactant；1.0~3.0 parts of dispersant；1.0~2.0 parts of amine catalyst；0.1~0.5 part of water；135~145 parts of MDI modifiers；The polyethers 1 is at least one of TED-28, KE-510 and DP-4000E；The polyethers 2 is at least one of ZST-21, KE-3704 and DP-6000.
- 10. polyurethane material according to claim 9, it is characterised in that：The chain extender is ethylene glycol, propane diols, 1.4 At least one of butanediol, trimethylolpropane and glycerine；The surfactant is for silicone surfactant and/or without silicone surfactant；The silicone surfactant L1500, L1540 and/or the L1505 produced for Mai Tu company, described is what gas companies were produced without silicone surfactant LK221 and/or LK043；The dispersant is n- dodecyl mereaptan, dodecyl sodium sulfonate is received and/or polyethylene glycol；The amine catalyst is A33, A333L, triethanolamine and/or glycerine；The MDI modifiers are polyether-modified MDI；The polyether-modified MDI is prepared in accordance with the following steps：By MDI and TED-28, KE3704 and DPG mixing, are warming up to 65~85 DEG C of 2~5h of reaction, then add the liquefied MDI, continue anti- Should, produce the polyether-modified MDI；The molecular weight of the solution polymerized butylbenzene is 135~180；The molecular weight of the cis-butadiene cement is 30,000~120,000；The activating agent is polyethylene glycol；Changed accelerator is at least one of the parallel thiazole of diphenyl disulfide, benzoyl peroxide and Sulfur.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610004278.5A CN105639825B (en) | 2016-01-04 | 2016-01-04 | One kind is reviewed troops special footwear and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610004278.5A CN105639825B (en) | 2016-01-04 | 2016-01-04 | One kind is reviewed troops special footwear and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105639825A CN105639825A (en) | 2016-06-08 |
| CN105639825B true CN105639825B (en) | 2017-10-03 |
Family
ID=56491480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610004278.5A Active CN105639825B (en) | 2016-01-04 | 2016-01-04 | One kind is reviewed troops special footwear and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105639825B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109363290A (en) * | 2018-12-14 | 2019-02-22 | 瑞安市大虎鞋业有限公司 | Light solid ankle guard makees caliga |
| CN118406298A (en) * | 2024-07-03 | 2024-07-30 | 洛阳百捷运动用品有限公司 | Rubber hunting boot material and injection molding process |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117414A (en) * | 2007-06-26 | 2008-02-06 | 孙振华 | Abrasion-proof resin rubber cushion |
| CN101160336A (en) * | 2005-04-21 | 2008-04-09 | 旭硝子株式会社 | Low resilience flexible polyurethane foam and process for its production |
| CN101948575A (en) * | 2010-10-21 | 2011-01-19 | 际华三五三七制鞋有限责任公司 | Formula and preparation method of rolled in-situ generated high-brightness sole rubber |
| CN102161786A (en) * | 2011-06-01 | 2011-08-24 | 际华三五三七制鞋有限责任公司 | High-mutual viscosity lustered yellowing-resistance bleached sole rubber and preparation method thereof |
| CN102276887A (en) * | 2011-07-21 | 2011-12-14 | 际华三五三七制鞋有限责任公司 | Anti-slip folding-resistant wear-resistant sole rubber and preparation method thereof |
| CN102532621A (en) * | 2010-12-24 | 2012-07-04 | 福建省莆田市华丰鞋业有限公司 | Light modified rubber foaming undersole material prescription and processing technology |
| CN103159999A (en) * | 2013-04-03 | 2013-06-19 | 叶建华 | Wear-resistant sole material and preparation method thereof |
| CN103450518A (en) * | 2012-06-04 | 2013-12-18 | 特步(中国)有限公司 | Highly wear resistant rubber and preparation method thereof |
| CN103965523A (en) * | 2014-05-20 | 2014-08-06 | 南京东亚橡塑制品有限公司 | Dual-density sole and preparation method thereof |
-
2016
- 2016-01-04 CN CN201610004278.5A patent/CN105639825B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101160336A (en) * | 2005-04-21 | 2008-04-09 | 旭硝子株式会社 | Low resilience flexible polyurethane foam and process for its production |
| CN101117414A (en) * | 2007-06-26 | 2008-02-06 | 孙振华 | Abrasion-proof resin rubber cushion |
| CN101948575A (en) * | 2010-10-21 | 2011-01-19 | 际华三五三七制鞋有限责任公司 | Formula and preparation method of rolled in-situ generated high-brightness sole rubber |
| CN102532621A (en) * | 2010-12-24 | 2012-07-04 | 福建省莆田市华丰鞋业有限公司 | Light modified rubber foaming undersole material prescription and processing technology |
| CN102161786A (en) * | 2011-06-01 | 2011-08-24 | 际华三五三七制鞋有限责任公司 | High-mutual viscosity lustered yellowing-resistance bleached sole rubber and preparation method thereof |
| CN102276887A (en) * | 2011-07-21 | 2011-12-14 | 际华三五三七制鞋有限责任公司 | Anti-slip folding-resistant wear-resistant sole rubber and preparation method thereof |
| CN103450518A (en) * | 2012-06-04 | 2013-12-18 | 特步(中国)有限公司 | Highly wear resistant rubber and preparation method thereof |
| CN103159999A (en) * | 2013-04-03 | 2013-06-19 | 叶建华 | Wear-resistant sole material and preparation method thereof |
| CN103965523A (en) * | 2014-05-20 | 2014-08-06 | 南京东亚橡塑制品有限公司 | Dual-density sole and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105639825A (en) | 2016-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US12082640B2 (en) | Textiles and articles and processes for making the same | |
| US9428817B2 (en) | Footwear and other products incorporating cultured leather | |
| CN105520259B (en) | A kind of Protective Boots and preparation method thereof | |
| CN106108236A (en) | A kind of Multipurpose outdoor sport shoes | |
| CN105639825B (en) | One kind is reviewed troops special footwear and preparation method thereof | |
| CN105820307A (en) | Combat boot with light double-component sole and preparation method of combat boot | |
| CN109349746A (en) | A kind of production method of waterproof footwear | |
| CN103214700B (en) | Double-hardness and double-physical-property rubber sole and preparation technology thereof | |
| CN201440974U (en) | Footwear product with abrasion appearance | |
| CN209547132U (en) | A kind of polyurethane sponge insole and midsole product | |
| Jhanji | Mushroom and corn fibre—the green alternatives to unsustainable raw materials | |
| CN1262076A (en) | Oil-resistant baypren boots and its making technology | |
| Dooley | A manual of shoemaking and leather and rubber products | |
| CN110452424A (en) | A kind of preparation method of rubber overshoes | |
| CN106995520A (en) | A kind of preparation method of insoles special for sport shoes | |
| CN107793952A (en) | Rubber overshoes super fiber leather heat cure adhesive and preparation method thereof and application method | |
| Barker | Rubber Industry of the United States, 1839-1939... | |
| CN110074511A (en) | One kind having anti abrasive footwear product and its manufacturing method | |
| CN204132540U (en) | A kind ofly place the high and environmental protection of comfort level, there are good elasticity and the footwear of wearability | |
| CN220571638U (en) | Long section of thick bamboo rubber overshoes that waterproof performance is good | |
| CN217407929U (en) | Deodorant durable comfortable leather shoes | |
| Plucknett | Introduction to the theory and practice of boot and shoe manufacture | |
| KR102172574B1 (en) | A method of manufacturing functional lightweight shoes and therewith associated shoes | |
| CN202060079U (en) | Portable antiskid shoe cover | |
| US1995179A (en) | Artificial leather |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |