CN103450518A - Highly wear resistant rubber and preparation method thereof - Google Patents
Highly wear resistant rubber and preparation method thereof Download PDFInfo
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- CN103450518A CN103450518A CN2012101805085A CN201210180508A CN103450518A CN 103450518 A CN103450518 A CN 103450518A CN 2012101805085 A CN2012101805085 A CN 2012101805085A CN 201210180508 A CN201210180508 A CN 201210180508A CN 103450518 A CN103450518 A CN 103450518A
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Abstract
Highly wear resistant rubber comprises, by mass, 40-50 parts of natural rubber, 55-62 parts of butadiene rubber, 8-12 parts of styrene butadiene rubber, 28-32 parts of white carbon black, 5 parts of processing oil, 5 parts of a wear resistance agent, 5 parts of zinc oxide powder, 3 parts of an H550 activator, 2 parts of a PEG activator, 2 parts of an H600 tackifier, 2.5 parts of an H606 antioxidant, 0.5 parts of stearic acid, 2.5 parts of an HA2 accelerant, 0.15 parts of a TS/80 accelerant, and 2.5 parts of S80 sulfur. The highly wear resistant rubber comprises a plurality of high-molecular polymers and chemical engineering raw materials according to a certain ratio, and is prepared through banburying, roller and flat platform vulcanization and the like. The highly wear resistant rubber has the advantages of light weight, good elasticity, good flexibility and the like when the highly wear resistant rubber is used on sports soles.
Description
Technical field:
The present invention relates to a kind of rubber of footwear, refer to especially high wear-resistant rubber and manufacture method thereof that a kind of Sports shoe sole is used.
Background technology:
Along with improving constantly of people's living standard and sports level, light comfortable footwear become main flow, and the density of common shoemaking rubber is 1.2G/CM3, wears away as 110mm3, and sole is heavier, wear-resisting poor, and flexibility is not good enough.
Summary of the invention:
The object of the invention is to overcome above-mentioned shortcoming, a kind of high wear-resistant rubber and manufacture method thereof are provided, this rubber consists of by a certain percentage various high molecular polymers and some industrial chemicals, and through ten thousand horsepowers, the rubber sole of a kind of high abrasion that the operating processes such as roller and the sulfuration of concora crush platform make, this rubber sole is applied on Sports shoe sole, has lightweight; Good springiness; The advantages such as flexibility is good.
For reaching above-mentioned purpose, the present invention adopts following technical scheme:
High wear-resistant rubber, described rubber is comprised of the material of following mass parts: natural gum 40-50 part; Cis-butadiene cement 55-62 part; Butadiene-styrene rubber 8-12 part; White Carbon black 28-32 part; 5 parts of treated oils; 5 parts of anti-wear agents; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 2 parts of H600 tackifier, 2.5 parts of H606 antioxidants; 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur.
Concrete, described rubber is comprised of the material of following mass parts: 45 parts of natural gums; 60 parts of cis-butadiene cements; 10 parts of butadiene-styrene rubbers; 30 parts of White Carbon blacks; 5 parts of treated oils; 5 parts of on-slip agent; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 3 parts of H600 tackifier, 2.5 parts of H606 antioxidants; 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur.
The manufacture method of high wear-resistant rubber:
(1) get 45 parts of natural gums; 60 parts of cis-butadiene cements; 10 parts of butadiene-styrene rubbers; 45 parts of White Carbon blacks; 5 parts of treated oils; 5 parts of on-slip agent; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 2 parts of H600 tackifier, 2.5 parts of H606 antioxidants, be placed on a high temperature tempering tank, mixed internally mix;
(2) use ten thousand horsepowers of boards the sizing material after the mixing banburying, by section, the mode refining of playing the triangle bag is even;
(3) sizing material after refining goes out into the standard sheet material and deposits 24 hours, stablizes the physical property of sizing material;
(4) after treating that it's stationary phase has been past sizing material, use ten thousand horsepowers of boards, by section, after the mode of playing the triangle bag is even sheet material sizing material refining, add 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur, then, after repeatedly beating triangle bag and plain thin operation by 3 times, slice is cooling;
(5) cooling sizing material afterwards, the size of pressing mould, determine the material needed by cutting;
(6) in 12 hours, then, through 150 degree high temperature, the approximately mould of 300 seconds compacting, be produced into the Sports shoe sole that a pair of has skid-proof function to these rubber mass.
Adopt technique scheme, this rubber consists of by a certain percentage various high molecular polymers and some industrial chemicals, and through ten thousand horsepowers, the rubber sole of a kind of high abrasion that the operating processes such as roller and the sulfuration of concora crush platform make, this rubber sole is applied on Sports shoe sole, has lightweight; Good springiness; The advantages such as flexibility is good.The density of this rubber is less than 1.1G/CM3, and abrasion are less than 70mm3, and after implementing above-mentioned formula, the wear resistance of sole improves more than 36%, wears more comfortable safety.
The accompanying drawing explanation:
Nothing
Embodiment:
Below in conjunction with embodiment, the present invention is described in detail:
High wear-resistant rubber is characterized in that: described rubber is comprised of the material of following mass parts: natural gum 40-50 part; Cis-butadiene cement 55-62 part; Butadiene-styrene rubber 8-12 part; White Carbon black 28-32 part; 5 parts of treated oils; 5 parts of anti-wear agents; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 2 parts of H600 tackifier, 2.5 parts of H606 antioxidants; 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur.
Concrete, described rubber is comprised of the material of following mass parts: 45 parts of natural gums; 60 parts of cis-butadiene cements; 10 parts of butadiene-styrene rubbers; 30 parts of White Carbon blacks; 5 parts of treated oils; 5 parts of on-slip agent; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 3 parts of H600 tackifier, 2.5 parts of H606 antioxidants; 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur.
The manufacture method of high wear-resistant rubber:
(1) get 45 parts of natural gums; 60 parts of cis-butadiene cements; 10 parts of butadiene-styrene rubbers; 45 parts of White Carbon blacks; 5 parts of treated oils; 5 parts of on-slip agent; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 2 parts of H600 tackifier, 2.5 parts of H606 antioxidants, be placed on a high temperature tempering tank, mixed internally mix;
(2) use ten thousand horsepowers of boards the sizing material after the mixing banburying, by section, the mode refining of playing the triangle bag is even;
(3) sizing material after refining goes out into the standard sheet material and deposits 24 hours, stablizes the physical property of sizing material;
(4) after treating that it's stationary phase has been past sizing material, use ten thousand horsepowers of boards, by section, after the mode of playing the triangle bag is even sheet material sizing material refining, add 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur, then, after repeatedly beating triangle bag and plain thin operation by 3 times, slice is cooling;
(5) cooling sizing material afterwards, the size of pressing mould, determine the material needed by cutting;
(6) in 12 hours, then, through 150 degree high temperature, the approximately mould of 300 seconds compacting, be produced into the Sports shoe sole that a pair of has skid-proof function to these rubber mass.
This rubber consists of by a certain percentage various high molecular polymers and some industrial chemicals, and through ten thousand horsepowers, the rubber sole of a kind of high abrasion that the operating processes such as roller and the sulfuration of concora crush platform make, this rubber sole is applied on Sports shoe sole, has lightweight; Good springiness; The advantages such as flexibility is good, the density of this rubber is generally less than 1.150G/CM3, and abrasion are less than 70mm3, and after implementing above-mentioned formula, the wear resistance of sole improves more than 36%, wears more comfortable safety.
This rubber can be used for any position of sole, is applicable to running basketball, tennis, outdoor shoe, the categories such as playshoes; This type of Sports shoe sole is on coarse road surface, and it stops abrasion ability obviously to improve, wear more steady, allow Sport & Casual follow one's inclinations please.
Claims (3)
1. high wear-resistant rubber, it is characterized in that: described rubber is comprised of the material of following mass parts: natural gum 40-50 part; Cis-butadiene cement 55-62 part; Butadiene-styrene rubber 8-12 part; White Carbon black 28-32 part; 5 parts of treated oils; 5 parts of anti-wear agents; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 2 parts of H600 tackifier, 2.5 parts of H606 antioxidants; 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur.
2. high wear-resistant rubber as claimed in claim 1, it is characterized in that: described rubber is comprised of the material of following mass parts: 45 parts of natural gums; 60 parts of cis-butadiene cements; 10 parts of butadiene-styrene rubbers; 30 parts of White Carbon blacks; 5 parts of treated oils; 5 parts of on-slip agent; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 3 parts of H600 tackifier, 2.5 parts of H606 antioxidants; 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur.
3. the manufacture method of high wear-resistant rubber as claimed in claim 1 or 2:
(1) get 45 parts of natural gums; 60 parts of cis-butadiene cements; 10 parts of butadiene-styrene rubbers; 45 parts of White Carbon blacks; 5 parts of treated oils; 5 parts of on-slip agent; 5 parts of zinc whites; 3 parts of H550 promoting agents; 2 parts of PEG promoting agents; 2 parts of H600 tackifier, 2.5 parts of H606 antioxidants, be placed on a high temperature tempering tank, mixed internally mix;
(2) use ten thousand horsepowers of boards the sizing material after the mixing banburying, by section, the mode refining of playing the triangle bag is even;
(3) sizing material after refining goes out into the standard sheet material and deposits 24 hours, stablizes the physical property of sizing material;
(4) after treating that it's stationary phase has been past sizing material, use ten thousand horsepowers of boards, by section, after the mode of playing the triangle bag is even sheet material sizing material refining, add 0.5 part of stearic acid; 2.5 parts of HA2 promotor; 0.15 part of TS/80 promotor; 2.5 parts, S80 sulphur, then, after repeatedly beating triangle bag and plain thin operation by 3 times, slice is cooling;
(5) cooling sizing material afterwards, the size of pressing mould, determine the material needed by cutting;
(6) in 12 hours, then, through 150 degree high temperature, the approximately mould of 300 seconds compacting, be produced into the Sports shoe sole that a pair of has skid-proof function to these rubber mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012101805085A CN103450518A (en) | 2012-06-04 | 2012-06-04 | Highly wear resistant rubber and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012101805085A CN103450518A (en) | 2012-06-04 | 2012-06-04 | Highly wear resistant rubber and preparation method thereof |
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| CN2012101805085A Pending CN103450518A (en) | 2012-06-04 | 2012-06-04 | Highly wear resistant rubber and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103980560A (en) * | 2014-03-13 | 2014-08-13 | 中国化工橡胶桂林有限公司 | High-wear-resistant engineering tire tread rubber |
| CN104945692A (en) * | 2015-07-07 | 2015-09-30 | 三角轮胎股份有限公司 | Rubber combination with self-sealing function |
| CN105524322A (en) * | 2014-09-29 | 2016-04-27 | 青岛亨达股份有限公司 | Method for manufacturing antiskid shoe sole |
| CN105639825A (en) * | 2016-01-04 | 2016-06-08 | 中国人民解放军总后勤部军需装备研究所 | Boots special for military parade and manufacturing method thereof |
| CN110606999A (en) * | 2019-09-27 | 2019-12-24 | 际华三五三七有限责任公司 | Rubber for rubber shoe forming clamp and preparation method thereof |
| CN113121894A (en) * | 2021-04-21 | 2021-07-16 | 浙江中瑞橡胶高分子材料股份有限公司 | Wear-resistant anti-slip rubber |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6086669A (en) * | 1998-04-09 | 2000-07-11 | Ppg Industries Ohio, Inc. | Dispersible free flowing particulate silica composition |
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
-
2012
- 2012-06-04 CN CN2012101805085A patent/CN103450518A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6086669A (en) * | 1998-04-09 | 2000-07-11 | Ppg Industries Ohio, Inc. | Dispersible free flowing particulate silica composition |
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103980560A (en) * | 2014-03-13 | 2014-08-13 | 中国化工橡胶桂林有限公司 | High-wear-resistant engineering tire tread rubber |
| CN105524322A (en) * | 2014-09-29 | 2016-04-27 | 青岛亨达股份有限公司 | Method for manufacturing antiskid shoe sole |
| CN104945692A (en) * | 2015-07-07 | 2015-09-30 | 三角轮胎股份有限公司 | Rubber combination with self-sealing function |
| CN105639825A (en) * | 2016-01-04 | 2016-06-08 | 中国人民解放军总后勤部军需装备研究所 | Boots special for military parade and manufacturing method thereof |
| CN105639825B (en) * | 2016-01-04 | 2017-10-03 | 中国人民解放军总后勤部军需装备研究所 | One kind is reviewed troops special footwear and preparation method thereof |
| CN110606999A (en) * | 2019-09-27 | 2019-12-24 | 际华三五三七有限责任公司 | Rubber for rubber shoe forming clamp and preparation method thereof |
| CN113121894A (en) * | 2021-04-21 | 2021-07-16 | 浙江中瑞橡胶高分子材料股份有限公司 | Wear-resistant anti-slip rubber |
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Application publication date: 20131218 |