CN102153907A - Adhesion promoter for intaglio ink and preparation method thereof - Google Patents
Adhesion promoter for intaglio ink and preparation method thereof Download PDFInfo
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- CN102153907A CN102153907A CN201110058657XA CN201110058657A CN102153907A CN 102153907 A CN102153907 A CN 102153907A CN 201110058657X A CN201110058657X A CN 201110058657XA CN 201110058657 A CN201110058657 A CN 201110058657A CN 102153907 A CN102153907 A CN 102153907A
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Abstract
The invention discloses an adhesion promoter for intaglio ink and a preparation method thereof. The preparation method comprises the following steps: mixing a plant oleic acid with a solvent; adding an amino silane coupling agent; reacting; cooling; and regulating the viscosity of the product with the solvent so as to obtain the adhesion promoter for the intaglio ink. The adhesion promoter for the intaglio ink is prepared by chemical reaction of the silane coupling agent and the plant oleic acid, can be directly added in the intaglio ink without influencing the printability and storage property of the ink, contains no aromatic hydrocarbon solvents and belongs to an environment-friendly auxiliary for the ink; the binding fastness on various base materials, such as neutral paper, polyethylene terephthalate (PET) and the like, is greatly promoted; the volatility and the heavy metal content index of the adhesion promoter meet related technical requirements of environment-friendly products; the production process is simple, the reaction temperature is low, and the production process is easy to control; and the viscosity of the prepared adhesion promoter is moderate, and the property of the prepared adhesion promoter is stable.
Description
Technical field
The present invention relates to a kind of printing ink adhesion promoter.
Background technology
In printing industry, the engraving intaglio printing ink especially for high-end money printing need simultaneous adaptation osmosis type and non-osmosis type printed substrate, so gravure ink just seems especially important with the adhesion performance of different printed substrates.
Commercially available adhesion promoter is gone up by society at present, promote resin etc. or in plate engraving ink, improve the sticking power effect undesirable as titanate coupling agent, silane coupling agent, aldehyde ketone sticking power, the not environmental protection of adopting of solvent, and the application of these sticking power auxiliary agents also can influence the China ink and the stable storing performance of printing ink.
Summary of the invention
The object of the present invention is to provide a kind of plate engraving ink with adhesion promoter and preparation method thereof, to overcome the above-mentioned defective that prior art exists.
Order plate engraving ink of the present invention comprises the steps: with the preparation method of adhesion promoter
With vegetable oil acid and solvent, add amino silicane coupling agent down at 100-150 ℃, reacted 20～40 minutes, be cooled to 50～80 ℃, viscosity when adjusting 40 ℃ of products with solvent is 0.5～20paS, is described plate engraving ink adhesion promoter.
Preferably, adopt the mode that drips, add amino silicane coupling agent, the dropping time is 10～40 minutes.
The weight percent of each component is:
Amino silicane coupling agent 15-30%,
Vegetable oil acid 40-70%,
Solvent 10-30%.
Described amino silicane coupling agent is selected from the silane coupling agent that contains amino group, preferably N-(β-aminoethyl)-γ-An Bingjisanjiayangjiguiwan, N-(β-aminoethyl)-γ-An Bingjisanyiyangjiguiwan or γ one aminopropyl triethoxysilane;
Described vegetable oil acid is selected from linolic acid, eleostearic acid or soybean oleic acid;
Described solvent is selected from vegetable oil esters class or aliphatics alkanes;
Described vegetable oil esters class is selected from more than one in soybean oil methyl esters, methyl linoleate or the eleostearic acid methyl esters;
The aliphatics alkanes is selected from the carbon dodecane hydrocarbon of straight or branched, carbon tridecane hydrocarbon or the carbon tridecane hydrocarbon of side chain or the environmental protection aliphatics alkane that other can be used for printing ink of straight chain;
Adopt the plate engraving ink adhesion promoter of method for preparing, can be used for plate engraving ink, addition plate engraving ink weight 3% in;
Plate engraving ink of the present invention has following advantage with adhesion promoter: made by silane coupling agent and vegetable oil acid chemical reaction, can directly be added in the plate engraving ink, do not influence the printability and the storge quality of printing ink, to neutral paper, multiple base materials such as PET film promote bigger in conjunction with fastness ability, do not contain aromatic solvent, volatility and toxicity and heavy metal content index meet the correlation technique requirement of environmentfriendly products, belong to environment-friendly type printing ink used additives, production technique is simple, temperature of reaction is low, production process is easy to control, the adhesion promoter modest viscosity of preparation, stable performance.
Embodiment
Embodiment 1
With vegetable oil acid and solvent, drip down amino silicane coupling agents at 100 ℃, the dropping time is 25 minutes, react 40 minutes, is cooled to 70 ℃, the viscosity during with 40 ℃ of solvent adjustment products is 2paS, is described plate engraving ink adhesion promoter.
The weight percent of each component is:
Amino silicane coupling agent 30%,
Vegetable oil acid 40%,
Solvent 30%.
Amino silicane coupling agent is selected N-(β-aminoethyl)-γ-An Bingjisanjiayangjiguiwan for use, and adopting Japan XINYUE's trade mark is the product of KBM-603;
Vegetable oil acid is selected linolic acid for use;
Solvent is selected methyl linoleate for use;
This auxiliary agent is added in the engraving intaglio printing ink by 2% (weight), presses ASTM D3359-2002 method test attachment fastness, and the result is as follows:
To neutral paper substrate in conjunction with fastness ability: promote 0.5 grade than adding auxiliary agent printing ink.
The printability of this printing ink on printing press is with not add auxiliary agent printing ink suitable.
Storge quality: normal temperature storage was greater than 6 months.
The heavy metal content index of this printing ink and volatile matter index meet the standard-required of HJ/T371-2007.
Embodiment 2
With vegetable oil acid and solvent, drip amino silicane coupling agent down at 150 ℃, the dropping time is 30 minutes, reaction insulation 20 minutes, be cooled to 80 ℃, the viscosity when adjusting 40 ℃ of products with solvent is 15paS, is described plate engraving ink adhesion promoter.
The weight percent of each component is:
Amino silicane coupling agent 15%,
Vegetable oil acid 70%,
Solvent 15%.
It is the product of A-1100 that amino silicane coupling agent selects for use γ one aminopropyl triethoxysilane to adopt U.S.'s union carbide corporation trade mark;
Vegetable oil acid is selected eleostearic acid for use;
Solvent is the aliphatics alkanes, is selected from the isomery carbon dodecane hydrocarbon of Exxon Mobil Corporation;
This auxiliary agent is added in the engraving intaglio printing ink by 2% (weight), presses ASTM D3359-2002 method test attachment fastness, and the result is as follows:
To neutral paper substrate in conjunction with fastness ability: promote 1 grade than adding auxiliary agent printing ink.
The printability of this printing ink on printing press is with not add auxiliary agent printing ink suitable.
Storge quality: normal temperature storage was greater than 6 months.
The heavy metal content index of this printing ink and volatile matter index meet the standard-required of HJ/T371-2007.
Embodiment 3
With vegetable oil acid and solvent, drip amino silicane coupling agent down at 130 ℃, the dropping time is 15 minutes, reaction insulation 30 minutes, be cooled to 60 ℃, the viscosity when adjusting 40 ℃ of products with solvent is 10paS, is described plate engraving ink adhesion promoter.
The weight percent of each component is:
Amino silicane coupling agent 20%,
Vegetable oil acid 70%,
Solvent 10%.
It is the product of HD-108 that amino silicane coupling agent selects for use N-(β-aminoethyl)-γ-An Bingjisanyiyangjiguiwan to adopt Hangzhou company of the earth chemical industry company limited trade mark;
Vegetable oil acid is selected soybean oleic acid for use;
Solvent is selected the mixture of eleostearic acid methyl esters and methyl linoleate for use, and mass ratio is 1: 1.
This auxiliary agent is added in the engraving intaglio printing ink by 3% (weight), presses ASTM D3359-2002 method test attachment fastness, and the result is as follows:
To neutral paper substrate in conjunction with fastness ability: promote 1 grade than adding auxiliary agent printing ink.
The printability of this printing ink on printing press is with not add auxiliary agent printing ink suitable.
Storge quality: normal temperature storage was greater than 6 months.
The heavy metal content index of this printing ink and volatile matter index meet the standard-required of HJ/T371-2007.
Claims (8)
1. plate engraving ink is characterized in that with the preparation method of adhesion promoter, comprises the steps: vegetable oil acid and solvent, add amino silicane coupling agent, reaction, cooling, viscosity with solvent adjustment product promptly obtains described plate engraving ink adhesion promoter.
2. method according to claim 1 is characterized in that, adopts the mode that drips, and adds amino silicane coupling agent.
3. method according to claim 2 is characterized in that, the dropping time is 10～40 minutes.
4. method according to claim 1 is characterized in that, adds down amino silicane coupling agent at 100-150 ℃, react 20～40 minutes, is cooled to 50～80 ℃, and the viscosity during with 40 ℃ of solvent adjustment products is 0.5～20paS.
5. according to each described method of claim 1～4, it is characterized in that the weight percent of each component is: amino silicane coupling agent 15-30%, vegetable oil acid 40-70%, solvent 10-30%.
6. method according to claim 5 is characterized in that described amino silicane coupling agent is selected from the silane coupling agent that contains amino group, and described vegetable oil acid is selected from linolic acid, eleostearic acid or soybean oleic acid;
Described solvent is selected from vegetable oil esters class or aliphatics alkanes;
Described vegetable oil esters class is selected from one or more in soybean oil methyl esters, methyl linoleate or the eleostearic acid methyl esters;
The aliphatics alkanes is selected from the carbon tridecane hydrocarbon of carbon dodecane hydrocarbon, straight chain carbon tridecane hydrocarbon or side chain of straight or branched or the environmental protection aliphatics alkane that other can be used for printing ink.
7. method according to claim 6, it is characterized in that described amino silicane coupling agent is selected from N-(β-aminoethyl)-γ-An Bingjisanjiayangjiguiwan, N-(β-aminoethyl)-γ-An Bingjisanyiyangjiguiwan or γ one aminopropyl triethoxysilane.
8. according to the plate engraving ink adhesion promoter of each described method preparation of claim 1～7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110058657.XA CN102153907B (en) | 2011-03-11 | 2011-03-11 | Adhesion promoter for intaglio ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110058657.XA CN102153907B (en) | 2011-03-11 | 2011-03-11 | Adhesion promoter for intaglio ink and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102153907A true CN102153907A (en) | 2011-08-17 |
| CN102153907B CN102153907B (en) | 2013-07-17 |
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| CN201110058657.XA Active CN102153907B (en) | 2011-03-11 | 2011-03-11 | Adhesion promoter for intaglio ink and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002020679A1 (en) * | 2000-09-08 | 2002-03-14 | Sakata Inx Corp. | Ink composition for offset printing |
| JP2008184600A (en) * | 2007-01-31 | 2008-08-14 | Toyo Ink Mfg Co Ltd | Waterless planographic printing ink composition |
| CN101339850A (en) * | 2008-06-10 | 2009-01-07 | 舟山市新龙电子设备有限公司 | Capacitor aluminum housing coating paint and coating process |
| CN101717606A (en) * | 2009-12-02 | 2010-06-02 | 中钞特种防伪科技有限公司 | Adhesion force promoter composition, preparation method and application thereof |
-
2011
- 2011-03-11 CN CN201110058657.XA patent/CN102153907B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002020679A1 (en) * | 2000-09-08 | 2002-03-14 | Sakata Inx Corp. | Ink composition for offset printing |
| JP2008184600A (en) * | 2007-01-31 | 2008-08-14 | Toyo Ink Mfg Co Ltd | Waterless planographic printing ink composition |
| CN101339850A (en) * | 2008-06-10 | 2009-01-07 | 舟山市新龙电子设备有限公司 | Capacitor aluminum housing coating paint and coating process |
| CN101717606A (en) * | 2009-12-02 | 2010-06-02 | 中钞特种防伪科技有限公司 | Adhesion force promoter composition, preparation method and application thereof |
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| CN102153907B (en) | 2013-07-17 |
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Address after: 288 Xiuyan Road, Pudong New Area, Shanghai, 201315 Patentee after: CHINA BANKNOTE INK Co.,Ltd. Patentee after: China Banknote Printing and Minting Group Co.,Ltd. Address before: 288 Xiuyan Road, Pudong New Area, Shanghai, 201315 Patentee before: CHINA BANKNOTE INK Co.,Ltd. Patentee before: CHINA BANKNOTE PRINTING AND MINTING Corp. |