CN102146192A - Thermoplastic elastomer capable of performing oil injection processing easily for environmentally friendly toy - Google Patents
Thermoplastic elastomer capable of performing oil injection processing easily for environmentally friendly toy Download PDFInfo
- Publication number
- CN102146192A CN102146192A CN 201010611913 CN201010611913A CN102146192A CN 102146192 A CN102146192 A CN 102146192A CN 201010611913 CN201010611913 CN 201010611913 CN 201010611913 A CN201010611913 A CN 201010611913A CN 102146192 A CN102146192 A CN 102146192A
- Authority
- CN
- China
- Prior art keywords
- weight percent
- accounts
- account
- thermoplastic elastomer
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to thermoplastic elastomer capable of performing oil injection processing easily for the environmentally friendly toy. The thermoplastic elastomer comprises the following components by weight percent: 30%-50% of styrene elastomer, 5%-25% of inorganic nanometer filler, 0.3%-1% of methyl styrene, 3%-5% of 1,2-polybutadiene polymer, 10%-25% of mineral filling oil, 10%-25% of transparent anti-impact butadiene-styrene resin and 10%-25% of anti-impact polystyrene. Therefore, the thermoplastic elastomer has the advantages of no toxicity, safety and durability, and is environmental-friendly.
Description
Technical field
The present invention relates to a kind of thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing that is used for.
Background technology
Existing thermoplastic elastomer is generally made by PVC, and PVC is a kind of polymeric material of vinyl in fact, and its material is a kind of amorphism material.The PVC material often adds stablizer, lubricant, secondary process agent, colorant, impact modifier and other additive in actual use.Have noninflammability, high strength, good geometrical stability.PVC has very strong resistibility to oxygenant, reductive agent and strong acid.Yet it can be corroded by dense oxidizing acid such as the vitriol oil, concentrated nitric acid, and the also inapplicable occasion that contacts with aromatic hydrocarbon, chlorinated hydrocarbon.Its objectionable impurities of the elastomerics that PVC makes is too high, and the low temperature hardening becomes fragile, and adds and cause oil spout " burning glue " phenomenon man-hour easily, and the paint flake problem can occur.
Summary of the invention
The technical problem to be solved in the present invention provides the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing that is used for of a kind of asepsis environment-protecting, safety durable.The present invention is achieved through the following technical solutions:
A kind of thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing that is used for of the present invention, comprise styrenic elastomer, inorganic nano-filler, vinyl toluene, 1,2 polybutadiene polymers, mineral-filled oil, butylbenzene transparent impact-resistant resin, High Impact Polystyrene (HIPS); Wherein, it is that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 10%-25% for 10%-25%, High Impact Polystyrene (HIPS) for 10%-25%, butylbenzene transparent impact-resistant resin for 3%-5%, mineral-filled oil for 0.3%-1%, 1,2 polybutadiene polymers for 5%-25%, vinyl toluene for 30%-50%, inorganic nano-filler that styrenic elastomer accounts for weight percent.
As improvement, wherein, styrenic elastomer accounts for that weight percent is 50%, inorganic nano-filler accounts for that weight percent is 6%, vinyl toluene accounts for that weight percent is that 0.5%, 1,2 polybutadiene polymers accounts for that weight percent is 5.5%, mineral-filled oil accounts for that weight percent is 13%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 12%, to account for weight percent be 13% to High Impact Polystyrene (HIPS).
As improvement, wherein, styrenic elastomer accounts for that weight percent is 40%, inorganic nano-filler accounts for that weight percent is 15%, vinyl toluene accounts for that weight percent is that 0.5%, 1,2 polybutadiene polymers accounts for that weight percent is 4.5%, mineral-filled oil accounts for that weight percent is 15%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 13%, to account for weight percent be 12% to High Impact Polystyrene (HIPS).
As improvement, wherein, styrenic elastomer accounts for that weight percent is 30%, inorganic nano-filler accounts for that weight percent is 20%, vinyl toluene accounts for that weight percent is that 1%, 1,2 polybutadiene polymers accounts for that weight percent is 5%, mineral-filled oil accounts for that weight percent is 16%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 15%, to account for weight percent be 13% to High Impact Polystyrene (HIPS).
As improvement, described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
As improvement, described inorganic nano-filler is a kind of in the above talcum powder of number 5000 orders, barium sulfate, lime carbonate, the mica powder.
A kind of thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing that is used for of the present invention, owing to comprise styrenic elastomer, inorganic nano-filler, vinyl toluene, 1,2 polybutadiene polymers, mineral-filled oil, butylbenzene transparent impact-resistant resin, High Impact Polystyrene (HIPS), can replace PVC, therefore, it has the benefit of asepsis environment-protecting, safety durable.
Embodiment
A kind of thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing that is used for of the present invention, comprise styrenic elastomer, inorganic nano-filler, vinyl toluene, 1,2 polybutadiene polymers, mineral-filled oil, butylbenzene transparent impact-resistant resin, High Impact Polystyrene (HIPS); Wherein, it is that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 10%-25% for 10%-25%, High Impact Polystyrene (HIPS) for 10%-25%, butylbenzene transparent impact-resistant resin for 3%-5%, mineral-filled oil for 0.3%-1%, 1,2 polybutadiene polymers for 5%-25%, vinyl toluene for 30%-50%, inorganic nano-filler that styrenic elastomer accounts for weight percent.Therefore, it has the benefit of asepsis environment-protecting, safety durable.
Embodiment one: wherein, styrenic elastomer accounts for that weight percent is 50%, inorganic nano-filler accounts for that weight percent is 6%, vinyl toluene accounts for that weight percent is that 0.5%, 1,2 polybutadiene polymers accounts for that weight percent is 5.5%, mineral-filled oil accounts for that weight percent is 13%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 12%, to account for weight percent be 13% to High Impact Polystyrene (HIPS).
Embodiment two: wherein, styrenic elastomer accounts for that weight percent is 40%, inorganic nano-filler accounts for that weight percent is 15%, vinyl toluene accounts for that weight percent is that 0.5%, 1,2 polybutadiene polymers accounts for that weight percent is 4.5%, mineral-filled oil accounts for that weight percent is 15%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 13%, to account for weight percent be 12% to High Impact Polystyrene (HIPS).
Embodiment three: wherein, styrenic elastomer accounts for that weight percent is 30%, inorganic nano-filler accounts for that weight percent is 20%, vinyl toluene accounts for that weight percent is that 1%, 1,2 polybutadiene polymers accounts for that weight percent is 5%, mineral-filled oil accounts for that weight percent is 16%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 15%, to account for weight percent be 13% to High Impact Polystyrene (HIPS).
In the foregoing description, described inorganic nano-filler is a kind of in the above talcum powder of number 5000 orders, barium sulfate, lime carbonate, the mica powder; Described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
A kind of thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing that is used for of the present invention, owing to comprise styrenic elastomer, inorganic nano-filler, vinyl toluene, 1,2 polybutadiene polymers, mineral-filled oil, butylbenzene transparent impact-resistant resin, High Impact Polystyrene (HIPS); Wherein, it is that to account for weight percent be that to account for weight percent be 0.3%-1%, 1 for 5%-25%, vinyl toluene for 30%-50%, inorganic nano-filler that styrenic elastomer accounts for weight percent, 2 polybutadiene polymers account for weight percent be 3%-5%, mineral-filled oil account for weight percent be 10%-25%, butylbenzene transparent impact-resistant resin account for weight percent be 10%-25%, High Impact Polystyrene (HIPS) to account for weight percent be 10%-25%, can replace PVC.Therefore, it has its benefit with asepsis environment-protecting, safety durable.
Claims (6)
1. one kind is used for the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing, comprise styrenic elastomer, inorganic nano-filler, vinyl toluene, 1,2 polybutadiene polymers, mineral-filled oil, butylbenzene transparent impact-resistant resin, High Impact Polystyrene (HIPS); Wherein, it is that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 10%-25% for 10%-25%, High Impact Polystyrene (HIPS) for 10%-25%, butylbenzene transparent impact-resistant resin for 3%-5%, mineral-filled oil for 0.3%-1%, 1,2 polybutadiene polymers for 5%-25%, vinyl toluene for 30%-50%, inorganic nano-filler that styrenic elastomer accounts for weight percent.
2. according to claim 1ly be used for the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing, it is characterized in that: wherein, styrenic elastomer accounts for that weight percent is 50%, inorganic nano-filler accounts for that weight percent is 6%, vinyl toluene accounts for that weight percent is that 0.5%, 1,2 polybutadiene polymers accounts for that weight percent is 5.5%, mineral-filled oil accounts for that weight percent is 13%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 12%, to account for weight percent be 13% to High Impact Polystyrene (HIPS).
3. according to claim 1ly be used for the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing, it is characterized in that: wherein, styrenic elastomer accounts for that weight percent is 40%, inorganic nano-filler accounts for that weight percent is 15%, vinyl toluene accounts for that weight percent is that 0.5%, 1,2 polybutadiene polymers accounts for that weight percent is 4.5%, mineral-filled oil accounts for that weight percent is 15%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 13%, to account for weight percent be 12% to High Impact Polystyrene (HIPS).
4. according to claim 1ly be used for the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing, it is characterized in that: wherein, styrenic elastomer accounts for that weight percent is 30%, inorganic nano-filler accounts for that weight percent is 20%, vinyl toluene accounts for that weight percent is that 1%, 1,2 polybutadiene polymers accounts for that weight percent is 5%, mineral-filled oil accounts for that weight percent is 16%, butylbenzene transparent impact-resistant resin accounts for that weight percent is 15%, to account for weight percent be 13% to High Impact Polystyrene (HIPS).
5. according to claim 1ly be used for the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing, it is characterized in that: described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
6. according to claim 1ly be used for the thermoplastic elastomer that tool on the environmental protection toy is easy to oil spout processing, it is characterized in that: described inorganic nano-filler is a kind of in the above talcum powder of number 5000 orders, barium sulfate, lime carbonate, the mica powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106119139A CN102146192B (en) | 2010-12-29 | 2010-12-29 | Thermoplastic elastomer capable of performing oil injection processing easily for environmentally friendly toy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106119139A CN102146192B (en) | 2010-12-29 | 2010-12-29 | Thermoplastic elastomer capable of performing oil injection processing easily for environmentally friendly toy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102146192A true CN102146192A (en) | 2011-08-10 |
| CN102146192B CN102146192B (en) | 2012-07-25 |
Family
ID=44420677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106119139A Expired - Fee Related CN102146192B (en) | 2010-12-29 | 2010-12-29 | Thermoplastic elastomer capable of performing oil injection processing easily for environmentally friendly toy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102146192B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530627A (en) * | 2015-01-28 | 2015-04-22 | 李康 | High-melt-strength thermoplastic elastomer and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130630A (en) * | 2006-08-22 | 2008-02-27 | 东丽纤维研究所（中国）有限公司 | Polyamide composition for high impact thick wall product |
| WO2009031686A1 (en) * | 2007-09-07 | 2009-03-12 | Bridgestone Corporation | Rubber composition and tire using the rubber composition |
-
2010
- 2010-12-29 CN CN2010106119139A patent/CN102146192B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130630A (en) * | 2006-08-22 | 2008-02-27 | 东丽纤维研究所（中国）有限公司 | Polyamide composition for high impact thick wall product |
| WO2009031686A1 (en) * | 2007-09-07 | 2009-03-12 | Bridgestone Corporation | Rubber composition and tire using the rubber composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530627A (en) * | 2015-01-28 | 2015-04-22 | 李康 | High-melt-strength thermoplastic elastomer and preparation method thereof |
| CN104530627B (en) * | 2015-01-28 | 2017-03-29 | 北京中嘉卫华科技发展有限公司 | A kind of high melt strength thermoplastic elastomer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102146192B (en) | 2012-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103589109B (en) | Formula of reinforced melaminoformaldehyde resin | |
| BR112012024516A2 (en) | method for producing modified conjugated diene rubber, modified conjugated diene rubber, rubber composition, and tires | |
| WO2010077091A2 (en) | High-strength polyphenylene sulfide/polyethylene terephthalate blended resin composition and a production method therefor | |
| CN104194077A (en) | Anti-abrasion and flame-retardant modified natural rubber | |
| CA2862782A1 (en) | Toughness modifier for curable resin, and curable resin composition | |
| CN102140240A (en) | Thermoplastic elastomer for injection adhering with acrylonitrile-butadiene and styrene terpolymer | |
| CN102146192B (en) | Thermoplastic elastomer capable of performing oil injection processing easily for environmentally friendly toy | |
| CN104262755A (en) | HDPE (High-Density Polyethylene) plastic and preparation method thereof | |
| CN104987646A (en) | Thermoplastic styrenic elastomer composition with high elongation and low stretching permanent deformation | |
| CN105199371A (en) | High-transparency TPU thin film for light guide plate material and preparation method of high-transparency TPU thin film | |
| WO2013043363A3 (en) | Epoxy-functional resin compositions | |
| CN103483945A (en) | Environment-friendly wear-resistant paint | |
| MX342023B (en) | High solids coating and process for coating. | |
| CN103146265A (en) | Anticorrosive paint compound with high shock resistance | |
| CN103571191A (en) | Formula of modified polyphenylene sulfide resin | |
| CN103497384A (en) | Anti-aging rubber composition containing unsaturated carboxylic acid metal salt vulcanizing agent | |
| CN104530634B (en) | Environment-friendly type regenerates ABS flame-proof modified compositions and preparation method and application at high proportion | |
| CN103540153A (en) | Flexible high-molecular plastic | |
| CN102993497A (en) | Seal puddle | |
| WO2018092593A1 (en) | Thermally conductive elastomer composition and thermally conductive molded article | |
| CN103740088A (en) | Formula for modifying polyether-ether-ketone plastics | |
| CN103709597A (en) | Formula of modified urea-formaldehyde resin | |
| CN103214710A (en) | Environmental-friendly flame retardation plastic pallet | |
| WO2018097496A3 (en) | Compound | |
| CN102140241A (en) | Transparent thermoplastic elastomer to be bonded with acrylonitrile-brtadiene-styrene terpolymer by shooting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120725 Termination date: 20151229 |