Summary of the invention
The present invention is directed to deficiency, propose a kind of eye protection and apply some make up, the nutritional labeling collocation rationally improves the eye bad phenomenon.
In order to realize the foregoing invention purpose, the invention provides following technical scheme: a kind of eye protection applies some make up, and is made up of following components in weight percentage:
The C phase:
D phase: Radix Hamamelidis Mollis extracting solution 3%~10%
Triethanolamine 0.3%~1%.
Compared with prior art, eye protection of the present invention does not have oil ingredient in applying some make up and filling a prescription, and is rich in sea water pearls and skims the cream off milk, and goes the eye pouch convergence plain, crease-resistant Moisture factor, and hyaluronic acid or the like adopts advanced biotechnology formulated.Accurately grasp the anti-maximum temperature requirement of each active component, avoid high temperature active influence.The high polymer dissolving is abundant, in order to avoid influence product appearance and effect.Formulation stability is good, and performance is good.Have the following advantages: be easy to skin and absorb, eye skin zero is born, and refines the complete combination of top component and basic components, and pure natural does not add essence, pigment, is the skin decompression, back to nature.
The eye protection that the present invention adopts a plurality of combination of compositions to form applies some make up, and wherein Margarita has the arresting convulsion of calming the nerves, and the heat clearing away YIN nourishing makes eye bright, and aspects such as slow down aging, freckle removing and whitening, supplement calcium all have unique effect.Modern study shows the main component of Margarita: calcium carbonate, Organic substance, water, and inorganic microelement.Be rich in peptide matters in the liquid of Margarita after hydrolysis, its composition of peptide matters is less than 50 amino acid whose low molecular weight proteins, is undertaking important regulatory function in vivo, therefore is called as biologically active peptide (also being Functional Polypeptides).The nutritive value Functional Polypeptides of Functional Polypeptides is in assimilation effect the best of intestinal, and the human body internal protein in fact major part be that form with polypeptide absorbs.After deliberation, Functional Polypeptides has its unique effect aspect beauty treatment, thereby as the situation of osseocolla polypeptide collagen synthetic low effect improvement skin that has clear improvement that ageing-related; Collagen polypeptide is rich in the hydrophilic Moisture factor, can conserve moisture of skin, makes skin have good affinity and elasticity.
To imidazolidinyl urea is antiseptic in a kind of cosmetics, is mainly used in the breeding that suppresses microorganism.Action principle is a slow release formaldehyde, to removing from office blue formula positive bacteria, the blue formula negative bacterium of leather, comprises that pseudomonas has fungistatic effect, and yeast, mycete are suppressed selectively.But this side chain low-molecular-weight ester can improve the coating of product and a kind of slick aftereffect sensation is arranged, and can significantly reduce product because of adding thick and heavy greasy feeling and the viscosity that UV absorbent and pigment cause.
Hyaluronic acid has special water retention, it is the best material of finding at present of occurring in nature moisture retention, (Natural moisturizing factor, NMF) for example: 2% pure hyaluronic acid aqueous solution can keep 98% moisture securely to be called as ideal nature moisturizing factor.Hyaluronic acid is a kind of multi-functional substrate, and hyaluronic acid (hyaluronic acid) HA is distributed widely in the partes corporis humani position.Wherein skin also contains a large amount of hyaluronic acids.Ripe and the ageing process of human skin also changes along with hyaluronic content and metabolism, it can improve the skin-nourishing metabolism, making that skin is tender, smooth, wrinkle removing, increase elasticity, prevent aging, is again the good transdermal absorption enhancer when preserving moisture.Be used with other nutritional labelings, can play the better effect that promotes alimentation.
The main component of reed fragrant plant glue (Lubrajel) is the polymethyl acid glyceride, is a kind of water-soluble not dry lubricant, and performance of keeping humidity is excellent, is widely used in particularly eye-care cosmetics of gel cosmetic products.Improve the skin sense and the lubricity of product.Good water solubility is transparent moisturizing substrate.Have dual moisture-keeping efficacy, be easy to during massage and skin absorbs, microcirculation improvement promotes cellular metabolism, adjusts the skin pH value, effectively lipid regulating secretion, pore refining.Because of the polymethyl acid glyceride forms unique cagelike structure, make reed fragrant plant glue have the strong point of water-soluble skin isostearyl glyceryl pentaerythrityl ether and glossy skin isostearyl glyceryl pentaerythrityl ether concurrently, have the lock outlet capacity, be a kind of wettability equilibrium agent.
Go that main component includes 20 sour octadecanol esters, 20 acid-16-methyl-15,16-alkene Heptadecyl alcohol ester, Palmic acid, cupreol, oleanolic acid and daucosterol in the eye pouch convergence element.
Main one-tenth includes tannin, kaempferol, Quercetin in the Sargassum extract.
Main one-tenth includes close glycoprotein, polysaccharide, vitamin in the Radix Hamamelidis Mollis extracting solution.
Each component in the effect of being played during eye protection of the present invention applies some make up respectively shown in following table 1,2,3 and 4:
Table 1 is the A effect of each component mutually
Material name |
Effect |
Hydrolyzed pearl |
Preserve moisture, whiten, crease-resistant |
Disodiumedetate |
Chelating agent |
Water |
Solvent |
Hyaluronic acid |
Wetting agent |
To imidazolidinyl urea |
Antiseptic |
Table 2 is the B effect of each component mutually
Material name |
Effect |
Glycerol |
Wetting agent |
Reed fragrant plant glue |
Wetting agent |
Sargassum extract |
Preserve moisture, crease-resistant |
Water |
Solvent |
Table 3 is the C effect of each component mutually
Material name |
Effect |
Carbomer |
Thickening |
Go the eye pouch convergence plain |
Remove eye pouch |
Elastin laminin |
Repair thin tail stricture of vagina |
Collagen protein |
Crease-resistant |
Lecithin |
Crease-resistant |
Water |
Solvent |
Table 4 is the D effect of each component mutually
Material name |
Effect |
The Radix Hamamelidis Mollis extracting solution |
Crease-resistant, releive |
Triethanolamine |
Thickening, pH regulator |
The preparation method that the present invention also provides above-mentioned eye protection to apply some make up may further comprise the steps:
1., by weight ratio with hydrolyzed pearl, disodiumedetate, to imidazolidinyl urea and water mixing, be heated with stirring to 45 ℃~65 ℃ dissolvings; Filter cleaner is cooled to 35 ℃~45 ℃ and adds hyaluronic acid, stirs, and makes the A phase;
2., by weight ratio with glycerol, reed fragrant plant glue, Sargassum extract and water mixing, be heated with stirring to 45 ℃~65 ℃ dissolvings, filter cleaner, the B phase;
3., by weight ratio will remove eye pouch convergence element, elastin laminin, collagen protein, lecithin and water mixing, be heated with stirring to 45 ℃~65 ℃ dissolvings; Filter cleaner is cooled to 35 ℃~45 ℃ and adds carbomer, and stirring and dissolving is even, gets the C phase;
4., with step 1. with the A that 2. prepares respectively mutually with B mutually, add the C phase that 3. step prepares, stir, leave standstill;
5., with the Radix Hamamelidis Mollis extracting solution of D in mutually add step 4. in the homomixture, stir, leave standstill froth breaking; Add the triethanol ammonium of D in mutually again, stir.
Preferably, step is the extracting method of middle Margarita hydrolysate 1., may further comprise the steps:
(1), get Margarita freshwater mussel internal organs, break into meat slurry; Meat slurry is 1~2 part by weight, adds 2~4 parts of volume ratios and be 1~2: 2~4 CHCl in the meat slurry
3: CH
3The OH mix reagent stirred 0.5~2 hour; Add 1~2 part of CHCl again
3, stirred 1~2 hour, add 1~2 part of distilled water, stirred 1~2 hour; Sucking filtration gets filtrate, and standing demix is collected CHCl
3Layer; CHCl
3Layer is under 30 ℃~40 ℃, and evacuation is removed CHCl
3With CH
3OH gets the internal organs extract;
(2), the middle sucking filtration gained filtering residue of step () adds the water layer in the standing demix, the isopyknic concentrated hydrochloric acid of adding behind the mixing, stirring; Treat to add alkali adjusting pH value to 6.5~7.5, standing demix after the concentrated hydrochloric acid volatilization; Add the papain of supernatant cumulative volume 0.8%~1.2%, stir, 58 ℃~65 ℃ following hydrolysis 15~30 hours; Sucking filtration is collected filtrate, with the internal organs extract mixing of step (), gets the Margarita hydrolysate.
Preferably, the nitrogen content of described hydrolyzed pearl 〉=2.4%.
Preferably, the step 2. preparation method of middle Sargassum extract is with the Sargassum pulping, adds 60%~75% ethanol extraction, filters and collects filtrate, concentrates.
The present invention adopts pure natural Margarita freshwater mussel to carry out biological enzymolysis to react and extract the Margarita hydrolysate, extract the effective ingredient in the pure natural Margarita freshwater mussel in two steps: the internal organs extract that step () is extracted is a docosahexenoic acid, step (two) obtains the docosahexenoic acid mixing of hydrolysate and step () by enzymolysis, promptly gets the Margarita hydrolysate; Component difference stirring and evenly mixing that each phase comprised then applies some make up eye protection, again in certain sequence with each phase mix homogeneously, each material can be dissolved more fully, shorten the production time, whole process operation is easy, can dissolve in the required separately temperature of each component, effective ingredient is discharged reach capacity, help production operation, production process is better smooth and easy.
The specific embodiment
Describe the present invention below in conjunction with specific embodiment, the description of this part only is exemplary and explanatory, should any restriction not arranged to protection scope of the present invention.
Need to prove that the manufacturer of the employed material of following embodiment is as shown in the table respectively:
Embodiment 1
The preparation method that eye protection applies some make up may further comprise the steps:
1, gets Margarita freshwater mussel internal organs, break into the meat slurry; The meat slurry is 1 part by weight, and 4 parts of volume ratios of adding are 1: 4 CHCl in the meat slurry
3: CH
3The OH mix reagent stirred 0.5 hour; Add 2 parts of CHCl again
3, stirred 1 hour, add 2 parts of distilled water, stirred 1 hour; Sucking filtration gets filtrate, and standing demix is collected CHCl
3Layer; CHCl
3Layer is under 40 ℃, and evacuation is removed CHCl
3With CH
3OH gets the internal organs extract;
2, the water layer in the sucking filtration gained filtering residue adding standing demix in the step 1 adds isopyknic concentrated hydrochloric acid behind the mixing, stirs; Treat to add alkali adjusting pH value to 6.5, standing demix after the concentrated hydrochloric acid volatilization; Add the papain of supernatant cumulative volume 1.2%, stir, 58 ℃ of following hydrolysis 30 hours; Sucking filtration is collected filtrate, with the internal organs extract mixing of step 1, gets hydrolyzed pearl;
3, get step 2 hydrolyzed pearl, disodiumedetate, to imidazolidinyl urea and water mixing, be heated with stirring to 65 ℃; Filter cleaner is cooled to 35 ℃ and adds hyaluronic acid, stirs, and makes the A phase; Wherein Margarita hydrolysate, disodiumedetate, imidazolidinyl urea and water are respectively 2%, 0.5%, 0.1%, 0.5%, 10% at the shared weight content of output aggregate;
4, with glycerol, reed fragrant plant glue, Sargassum extract and water mixing, be heated with stirring to 45 ℃, filter cleaner gets the B phase; Wherein glycerol, reed fragrant plant glue, Sargassum extract and water are respectively 10%, 2%, 5%, 10% at the shared weight content of output aggregate;
5, will remove eye pouch convergence element, elastin laminin, collagen protein, lecithin and water mixing, be heated with stirring to 65 ℃; Filter cleaner is cooled to 35 ℃ and adds carbomer, stirs, and gets the C phase; Wherein carbomer, go eye pouch convergence element, elastin laminin, collagen protein, lecithin and water to be respectively 1%, 0.2%, 0.5%, 0.2%, 0.5%, 40% at the shared weight content of output aggregate;
6, the A that step 3 and 4 is prepared respectively mutually with B mutually, add the C phase of step 5 preparation, stir, leave standstill;
7, with in the homomixture in the Radix Hamamelidis Mollis extracting solution adding step 6, stir, leave standstill froth breaking; Add the triacetic acid ammonium again, stir, promptly get eye protection and apply some make up; Wherein Radix Hamamelidis Mollis extracting solution and triacetic acid ammonium are respectively 10% and 0.3% at the shared weight content of output aggregate.
Embodiment 2
The preparation method that eye protection applies some make up may further comprise the steps:
1, gets Margarita freshwater mussel internal organs, break into the meat slurry; The meat slurry is 2 parts by weight, and 2 parts of volume ratios of adding are 1: 1 CHCl in the meat slurry
3: CH
3The OH mix reagent stirred 2 hours; Add 1 part of CHCl again
3, stirred 2 hours, add 1 part of distilled water, stirred 2 hours; Sucking filtration gets filtrate, and standing demix is collected CHCl
3Layer; CHCl
3Layer is under 30 ℃, and evacuation is removed CHCl
3With CH
3OH gets the internal organs extract;
2, the water layer in the sucking filtration gained filtering residue adding standing demix in the step 1 adds isopyknic concentrated hydrochloric acid behind the mixing, stirs; Treat to add alkali adjusting pH value to 7.5, standing demix after the concentrated hydrochloric acid volatilization; Add the papain of supernatant cumulative volume 0.8%, stir, 65 ℃ of following hydrolysis 15 hours; Sucking filtration is collected filtrate, with the internal organs extract mixing of step 1, gets hydrolyzed pearl;
3, get step 2 hydrolyzed pearl, disodiumedetate, to imidazolidinyl urea and water mixing, be heated with stirring to 45 ℃; Filter cleaner is cooled to 45 ℃ and adds hyaluronic acid, stirs, and makes the A phase; Wherein Margarita hydrolysate, disodiumedetate, imidazolidinyl urea and water are respectively 5%, 0.1%, 0.5%, 0.2%, 20% at the shared weight content of output aggregate;
4, with glycerol, reed fragrant plant glue, Sargassum extract and water mixing, be heated with stirring to 65 ℃, filter cleaner gets the B phase; Wherein glycerol, reed fragrant plant glue, Sargassum extract and water are respectively 3%, 8%, 2%, 20% at the shared weight content of output aggregate;
5, will remove eye pouch convergence element, elastin laminin, collagen protein, lecithin and water mixing, be heated with stirring to 45 ℃; Filter cleaner is cooled to 35 ℃ and adds carbomer, stirs, and gets the C phase; Wherein carbomer, go eye pouch convergence element, elastin laminin, collagen protein, lecithin and water to be respectively 0.2%, 1%, 0.2%, 0.5%, 0.2%, 50% at the shared weight content of output aggregate;
6, the A that step 3 and 4 is prepared respectively mutually with B mutually, add the C phase of step 5 preparation, stir, leave standstill;
7, with in the homomixture in the Radix Hamamelidis Mollis extracting solution adding step 6, stir, leave standstill froth breaking; Add the triacetic acid ammonium again, stir, promptly get eye protection and apply some make up; Wherein Radix Hamamelidis Mollis extracting solution and triacetic acid ammonium are respectively 3% and 1% at the shared weight content of output aggregate.
Embodiment 3
The preparation method that eye protection applies some make up may further comprise the steps:
1, gets Margarita freshwater mussel internal organs, break into the meat slurry; The meat slurry is 1.5 parts by weight, and 3 parts of volume ratios of adding are 1.5: 2.5 CHCl in the meat slurry
3: CH
3The OH mix reagent stirred 1 hour; Add 1.5 parts of CHCl again
3, stirred 1.2 hours, add 1.6 parts of distilled water, stirred 1.5 hours; Sucking filtration gets filtrate, and standing demix is collected CHCl
3Layer; CHCl
3Layer is under 35 ℃, and evacuation is removed CHCl
3With CH
3OH gets the internal organs extract;
2, the water layer in the sucking filtration gained filtering residue adding standing demix in the step 1 adds isopyknic concentrated hydrochloric acid behind the mixing, stirs; Treat to add alkali adjusting pH value to 7, standing demix after the concentrated hydrochloric acid volatilization; Add the papain of supernatant cumulative volume 1.0%, stir, 62 ℃ of following hydrolysis 20 hours; Sucking filtration is collected filtrate, with the internal organs extract mixing of step 1, gets hydrolyzed pearl;
3, get step 2 hydrolyzed pearl, disodiumedetate, to imidazolidinyl urea and water mixing, be heated with stirring to 53 ℃; Filter cleaner is cooled to 38 ℃ and adds hyaluronic acid, stirs, and makes the A phase; Wherein Margarita hydrolysate, disodiumedetate, imidazolidinyl urea and water are respectively 4%, 0.2%, 0.3%, 0.4%, 13% at the shared weight content of output aggregate;
4, with glycerol, reed fragrant plant glue, Sargassum extract and water mixing, be heated with stirring to 56 ℃, filter cleaner gets the B phase; Wherein glycerol, reed fragrant plant glue, Sargassum extract and water are respectively 6%, 4%, 3%, 17% at the shared weight content of output aggregate;
5, will remove eye pouch convergence element, elastin laminin, collagen protein, lecithin and water mixing, be heated with stirring to 50 ℃; Filter cleaner is cooled to 42 ℃ and adds carbomer, stirs, and gets the C phase; Wherein carbomer, go eye pouch convergence element, elastin laminin, collagen protein, lecithin and water to be respectively 0.6%, 0.4%, 0.3%, 0.4%, 0.3%, 43% at the shared weight content of output aggregate;
6, the A that step 3 and 4 is prepared respectively mutually with B mutually, add the C phase of step 5 preparation, stir, leave standstill;
7, with in the homomixture in the Radix Hamamelidis Mollis extracting solution adding step 6, stir, leave standstill froth breaking; Add the triacetic acid ammonium again, stir, promptly get eye protection and apply some make up; Wherein Radix Hamamelidis Mollis extracting solution and triacetic acid ammonium are respectively 8% and 0.6% at the shared weight content of output aggregate.
Embodiment 4
The preparation method that eye protection applies some make up may further comprise the steps:
1, gets Margarita freshwater mussel internal organs, break into the meat slurry; The meat slurry is 1.8 parts by weight, and 3.5 parts of volume ratios of adding are 2: 3 CHCl in the meat slurry
3: CH
3The OH mix reagent stirred 1.5 hours; Add 1.6 parts of CHCl again
3, stirred 1.2 hours, add 1.7 parts of distilled water, stirred 1.5 hours; Sucking filtration gets filtrate, and standing demix is collected CHCl
3Layer; CHCl
3Layer is under 34 ℃, and evacuation is removed CHCl
3With CH
3OH gets the internal organs extract;
2, the water layer in the sucking filtration gained filtering residue adding standing demix in the step 1 adds isopyknic concentrated hydrochloric acid behind the mixing, stirs; Treat to add alkali adjusting pH value to 7.5, standing demix after the concentrated hydrochloric acid volatilization; Add the papain of supernatant cumulative volume 1.1%, stir, 60 ℃ of following hydrolysis 22 hours; Sucking filtration is collected filtrate, with the internal organs extract mixing of step 1, gets hydrolyzed pearl;
3, get step 2 hydrolyzed pearl, disodiumedetate, to imidazolidinyl urea and water mixing, be heated with stirring to 55 ℃; Filter cleaner is cooled to 41 ℃ and adds hyaluronic acid, stirs, and makes the A phase; Wherein Margarita hydrolysate, disodiumedetate, imidazolidinyl urea and water are respectively 4%, 0.2%, 0.4%, 0.3%, 14% at the shared weight content of output aggregate;
4, with glycerol, reed fragrant plant glue, Sargassum extract and water mixing, be heated with stirring to 56 ℃, filter cleaner gets the B phase; Wherein glycerol, reed fragrant plant glue, Sargassum extract and water are respectively 5%, 6%, 3%, 14% at the shared weight content of output aggregate;
5, will remove eye pouch convergence element, elastin laminin, collagen protein, lecithin and water mixing, be heated with stirring to 53 ℃; Filter cleaner is cooled to 37 ℃ and adds carbomer, stirs, and gets the C phase; Wherein carbomer, go eye pouch convergence element, elastin laminin, collagen protein, lecithin and water to be respectively 0.7%, 0.5%, 0.3%, 0.3%, 0.4%, 48% at the shared weight content of output aggregate;
6, the A that step 3 and 4 is prepared respectively mutually with B mutually, add the C phase of step 5 preparation, stir, leave standstill;
7, with in the homomixture in the Radix Hamamelidis Mollis extracting solution adding step 6, stir, leave standstill froth breaking; Add the triacetic acid ammonium again, stir, promptly get eye protection and apply some make up; Wherein Radix Hamamelidis Mollis extracting solution and triacetic acid ammonium are respectively 6% and 0.5% at the shared weight content of output aggregate.
Adopt the prepared product of the foregoing description, select 20~50 years old Ms of different skin matter to use, compare operating position such as following each table with the result of use of commercially available eye cream product.
Using method: after clean, dip in nameless abdomen and to get an amount of product, press palpebra inferior and canthus skin gently for several times, softly be massaged into absorption then from inside to outside.
Test example 1, be 20~30 ℃ in the weather mass dryness fraction, relative humidity is 60~90%, and 80 Mries dry skin are divided into two groups: one group is used embodiment 1 product; Another group is divided equally five kinds of commercially available eye creams of use; Through 2 months effects relatively, the results are shown in following table 1.
Table 1, dry skin
Test example 2, be 20~30 ℃ in the weather mass dryness fraction, relative humidity is 60~90%, and 80 Mries neutral skin are divided into two groups: one group is used embodiment 2 products; Another group is divided equally five kinds of commercially available eye creams of use; Through 2 months effects relatively, the results are shown in following table 2.
Table 2 neutral skin
Test example 3, be 20~30 ℃ in the weather mass dryness fraction, relative humidity is 60~90%, and 80 Mries mixed skin are divided into two groups: one group is used embodiment 3 products; Another group is divided equally five kinds of commercially available eye creams of use; Through 2 months effects relatively, the results are shown in following table 3.
Table 3, mixed skin
Test example 4, be 20~30 ℃ in the weather mass dryness fraction, relative humidity is 60~90%, and 80 Mries oily skin are divided into two groups: one group is used embodiment 4 products; Another group is divided equally five kinds of commercially available eye creams of use; Through 2 months effects relatively, the results are shown in following table 4.
Table 4, oily skin
To sum up four forms are described, and product of the present invention obviously is better than commercially available brand eye cream to the eye problem effective percentage of all kinds of skin matter, reach 91.3% at effective percentage aspect moist the preserving moisture; Reach 80% at effective percentage aspect the desalination microgroove, reach 71.3% at effective percentage aspect the black eye of dispelling; Reach 70% at effective percentage aspect the eye pouch of dispelling; Reach 96.3% at effective percentage aspect the fat granule of dispelling.
Therefore illustrate that product of the present invention has following effect:
1, effectively prevents and improve eye microgroove, crows-feet; Prevent that the eye skin is lax sagging; Effectively alleviate black eye, eye pouch etc.
2, effectively replenish skin loss collagen, keep collagen fiber and elastic fibers vigor, alleviate the eye skin ageing.
3, can prevent fibrous tissue sclerosis and aging for skin replenishes and the pinning adequate water, make skin around the eyes jade-like stone profit, full, dynamic.
4, the fatigue of effectively releiving is shone eye life.
It below only is preferred implementation of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.