CN102102299A - Material for multifunctional shoe pad and preparation method thereof - Google Patents
Material for multifunctional shoe pad and preparation method thereof Download PDFInfo
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- CN102102299A CN102102299A CN200910201439XA CN200910201439A CN102102299A CN 102102299 A CN102102299 A CN 102102299A CN 200910201439X A CN200910201439X A CN 200910201439XA CN 200910201439 A CN200910201439 A CN 200910201439A CN 102102299 A CN102102299 A CN 102102299A
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Abstract
The invention relates to a material for a multifunctional shoe pad, which contains three layers of materials, wherein common fabrics are arranged on the bottom layer; antibiosis non-woven fabrics are arranged on the upper layer; and the middle layer contains high water-absorption resin particles covered by the inorganic nanometer silver antibacterial agent on the surface and hard micro beads covered by the hot melt adhesive on the surface. A preparation method comprises the following steps: (1) coating materials: on a support plate, covering the antibiosis non-woven fabrics, spreading the hard micro beads and high water-absorption resin particles, and covering the common fabrics; (2) heating: heating the compound three-layered materials; (3) hot-pressing: hotly pressing the heated compound three-layered materials so as to form the material for multifunctional shoe; and (4) collecting the finished products. Before the step (1) is performed, the steps of covering the surface of the hard micro bead with hot melt adhesive and covering the surface of the high water-absorption resin with the antibacterial agent are performed. The material for multifunctional shoe has the advantages that the prepared materials have high moisture-absorption property and functions of antibiosis, deodorization and massaging sole of the foot, the functions are lasting, the effects of antibiosis and deodorization are obvious, and the materials are easily produced and have bright application prospect.
Description
[technical field]
The present invention relates to a kind of shoe-pad with multiple function with material and preparation method thereof, specifically, is a kind of shoe-pad with high moisture absorption, antibiotic, deodorization, foot massages function with material and preparation method thereof.
[background technology]
Pin is smelly, is a kind of commonplace phenomenon, especially among physical labourer and active student group.Produce the smelly pin sweat that mainly has its source in of pin, vexed can not get in shoes of more pin sweat distributed, will be deposited in the shoe-pad, make the shoe-pad humidity, give birth to various bacteriums now, just produce stink at leisure, this not only makes people's pin produce " moisture " easily, very itches and feels bad, and also can have a strong impact on the air in house after taking off one's shoes, the place of especially air-conditioned relative closure makes the people very worried.
Be foot smell prevention, market has suffered and various functional innersoles occurred, and wherein, most shoe-pads all are to have flooded some chemicalses, originally are the effects with antibacterial deodourizing, in case but chemicals volatilization or flush away effect just obviously go down.The functional innersole that also has has added inorganic antiseptics such as some Nano Silvers or nanometer copper, and they can suppress bacterium under dry situation, still, in case after shoe-pad is made soaked with sweat by pin, not only can not suppress bacterium, also can promote the breeding of bacterium.Hygroscopic materials such as bamboo charcoal have also appearred adding in shoe-pad at present, but because its hygroscopic capacity is limited, so, also be difficult to the generation that prevents that effectively pin is smelly.
[summary of the invention]
The objective of the invention is to overcome the deficiencies in the prior art, provide a kind of shoe-pad with multiple function with material and preparation method thereof, the shoe-pad that the material that obtains with this preparation method is made has the multiple efficacies of high moisture absorption, antibiotic, deodorization and foot massages.
For achieving the above object, the technical scheme taked of the present invention is:
A kind of shoe-pad material with multiple function comprises bottom, intermediate layer and upper strata trilaminate material, and bottom is a common fabric, is mainly polyester-cotton fabric, also can use other fabric; The upper strata is an antibacterial nonwoven cloth made, be mainly the polyacrylonitrile nonwoven fabric (also claiming the AB anti-bacteria cloth on the market) that contains nanometer copper on the polyacrylonitrile molecule, it is characterized by, high hydroscopic resin particle and hard microballon are contained in the intermediate layer, be coated with the inorganic nano silver antibacterial agent on the surface of high hydroscopic resin particle, be coated with hot melt adhesive on the surface of hard microballon.
Described hard microballon or glass microballoon or plastics microballon or metal microbead, or their mixture, the particle diameter of microballon are 1～5mm.
The described inorganic nano silver antibacterial agent that coats at the high hydroscopic resin particle surface mainly is zeolite silver Nano Silver inorganic antiseptic or zeolite silver Nano Silver, zinc inorganic antiseptic or the agent of basic zirconium phosphate silver nano antibacterial, by weight, the amount of the inorganic nano silver antibacterial agent that contains of high hydroscopic resin particle is 1～4 percent.
Described hot melt adhesive is an ethylene-vinyl acetate copolymer matter EVA hot melt adhesive, or the chlorinated polypropylene hot melt adhesive, or low molecule nylon powder hot melt adhesive, or polyurethane hot melt, or the polyvinyl butyral resin hot melt adhesive.
Described shoe-pad material contains high hydroscopic resin 50～500 grams, hard microballon 1000-6000 grain in every square meter of material.
A kind of shoe-pad preparation methods with multiple function is characterized in that, comprises following production stage:
(1) cloth
On the supporting plate of equipment, carry out cloth,
1. at first, unreel cloth by the antibacterial nonwoven cloth made reel, antibacterial nonwoven cloth made reel and finished product are collected reel and are kept synchronizing speed,
2. secondly, dispense tube by the hard microballon and dispense the hard microballon on antibacterial nonwoven cloth made, the hard microballon dispenses tube and keeps synchronizing speed with the antibacterial nonwoven cloth made reel,
3. the 3rd, dispense tube by high hydroscopic resin and on antibacterial nonwoven cloth made, dispense high hydroscopic resin, high hydroscopic resin dispenses tube and keeps synchronizing speed with the antibacterial nonwoven cloth made reel,
4. the 4th, unreel cloth by the common fabric reel, common fabric is covered on the antibacterial nonwoven cloth made that has dispensed hard microballon and high hydroscopic resin, and by guide roller that common fabric and antibacterial nonwoven cloth made is compound, common fabric reel and antibacterial nonwoven cloth made reel keep synchronizing speed;
(2) heating
Heated by the heating plate of equipment hard microballon and the high hydroscopic resin to antibacterial nonwoven cloth made and common fabric parcel, heating and temperature control is at 110～150 ℃;
(3) hot pressing
By the hot pressing roller of equipment after to heating antibacterial nonwoven cloth made and common fabric to carry out hot pressing compound, hard microballon and high hydroscopic resin are coated wherein, form shoe-pad material with multiple function;
(4) finished product is collected
Collecting reel by finished product collects the shoe-pad with multiple function that hot pressing forms with material is concentrated.
Before carrying out (1) step 2., carry out the step of hard microballon coating hot melt adhesive earlier: the hard microballon is placed in the baking oven heat, insulation is 15～20 minutes in the time of 110 ℃, after the taking-up, take advantage of heat to be poured into and be equipped with in the homogenizer of hot melt adhesive powder, stirred 3～10 minutes, and made the hard bead surface coat one deck hot melt adhesive.
Before carrying out (1) step 3., carry out the step of high hydroscopic resin surface coating antiseptic earlier: high hydroscopic resin is placed homogenizer, the Nano Silver inorganic antiseptic that takes by weighing high hydroscopic resin weight percentage 1～4% is again poured in the homogenizer, stirred 5～10 minutes, when the homogenizer indicated temperature is 107～150 ℃ (fusing point on used resin is decided), stop to stir, coat and finish.
Described hot melt adhesive is an ethylene-vinyl acetate copolymer matter EVA hot melt adhesive, or the chlorinated polypropylene hot melt adhesive, or low molecule nylon powder hot melt adhesive, or polyurethane hot melt, or the polyvinyl butyral resin hot melt adhesive.
Described Nano Silver inorganic antiseptic is zeolite silver Nano Silver inorganic antiseptic or zeolite silver Nano Silver, zinc inorganic antiseptic or the agent of lithium phosphate silver nano antibacterial.
Good effect of the present invention is:
(1) antibacterial nonwoven cloth made directly contacts with people's sole, helps antibacterial;
(2) water absorption rate of high hydroscopic resin is more than 400 times of own wt, so can absorb pin sweat in a large number, keeps the drying of shoe-pad, and the antiseptic that resin surface has can suppress the shoe-pad breed bacteria behind the absorbing sweat;
(3) the hard bead surface contains hot melt adhesive and had both played adhesive effect, can protect high hydroscopic resin not trampled down again, can also play the effect of massage sole.
(4) shoe-pad that adopts material of the present invention to make has the multiple efficacies of high moisture absorption, antibiotic, deodorization and foot massages, and keep the time of effect long, the antibacterial deodourizing effect is obvious, produces easily, can greatly improve people's quality of life, have application promise in clinical practice.
[description of drawings]
Accompanying drawing has the technological process of production schematic diagram of the shoe-pad of multiple function with material preparation method for the present invention is a kind of;
Label among the figure is respectively:
1, antibacterial nonwoven cloth made reel, 2, the hard microballon dispenses tube, 3, high hydroscopic resin dispenses tube,
4, common fabric reel, 5, guide roller, 6, heating plate,
7, hot pressing roller, 8, finished product collects reel, 9, supporting plate.
[specific embodiment]
Explain a kind of specific embodiment with shoe-pad of multiple function with preparation methods of the present invention below in conjunction with accompanying drawing, enforcement of the present invention is not limited to following embodiment.
Embodiment 1
(1) the high hydroscopic resin surface coats antiseptic
Take by weighing 10 kilograms of high hydroscopic resins, pour in the homogenizer, taking by weighing Nano Silver inorganic antiseptic 200 grams again pours in the homogenizer, under 1600 rev/mins rotating speed, stirred 5～10 minutes, when homogenizer indicated temperature during at 107～150 ℃ (fusing point on used resin is decided), stop to stir, coat and finish;
(2) the hard microballon coats hot melt adhesive
Take by weighing 10 kilograms of glass microballoons, in baking oven, heat earlier, insulation is 15～20 minutes in the time of 110 ℃, after the taking-up, take advantage of heat to be poured into and be equipped with in the homogenizer of 1000 gram EVA hot melt adhesive powder, under 1000 rev/mins rotating speed, stirred 5～10 minutes, because the surface temperature of glass microballoon is the melting temperature of EVA hot melt adhesive powder, so the glass microballoon surface can be dissolved and be coated on to the EVA hot melt adhesive just.
Below progressively carry out by preparation method's of the present invention step.
(1) the high hydroscopic resin surface coats antiseptic
Take by weighing 10 kilograms of high hydroscopic resins, be poured in the homogenizer, take by weighing Nano Silver inorganic antiseptic 300g again, pour in the homogenizer, all the other processes are with embodiment 1 (1);
(2) the hard microballon coats hot melt adhesive
Take by weighing 10 kilograms of plastics microballons, heat in baking oven earlier, insulation is 5～10 minutes in the time of 100 ℃, after the taking-up, takes advantage of heat to be poured into and is equipped with in the homogenizer of 800g chlorinated polypropylene hot melt adhesive, and all the other processes are with embodiment 1 (2).
Below progressively carry out by preparation method's of the present invention step.
Embodiment 3
(1) the high hydroscopic resin surface coats antiseptic
Take by weighing 10 kilograms of high hydroscopic resins, pour in the homogenizer, take by weighing Nano Silver zinc inorganic antiseptic 400g again, pour in the high speed spice machine, all the other processes are with embodiment 1 (1);
(2) the hard microballon coats hot melt adhesive
Take by weighing 10 kilograms of metal microbeads, heat in baking oven earlier, insulation is 20 minutes in the time of 180 ℃, after the taking-up, takes advantage of heat to be poured into and is equipped with in the spice machine of 600g polyvinyl butyral resin hot melt adhesive, and all the other processes are with embodiment 1 (2).
Below progressively carry out by preparation method's of the present invention step.
Get embodiment 1 or 2 or 3 hard microballon and the high hydroscopic resins that coat after handling, press the present invention's technological process of production figure concrete operations shown in the drawings:
Carried out the cloth of antibacterial nonwoven cloth made earlier by antibacterial nonwoven cloth made reel 1, antibacterial nonwoven cloth made is delivered to the hard microballon through supporting plate 9 dispense tube 2 times, the hard microballon dispenses tube 2 and dispenses in the hard microballon on the antibacterial nonwoven cloth made equably by the mesh on the lower roller; Again antibacterial nonwoven cloth made is delivered to high hydroscopic resin through supporting plate 9 and dispense tube 3 times, high hydroscopic resin dispenses tube 3 mesh that pass through high hydroscopic resin is dispensed on the antibacterial nonwoven cloth made; Common fabric reel 4 is compound through guide roller 5 and antibacterial nonwoven cloth made with common fabric, after compound, the antibacterial nonwoven cloth made and the common fabric that are enclosed with hard microballon and high hydroscopic resin by 6 pairs on hot pressing roller carry out hot pressing, formation has the shoe-pad material of multiple function, collects reel 8 with the finished product rolling by finished product at last.
The common fabric that adopts in implementation process is mainly and washs, COTTON FABRIC, also can adopt other fabric;
Described antibacterial nonwoven cloth made is mainly the polyacrylonitrile nonwoven fabric that contains nanometer copper on the polyacrylonitrile molecule, i.e. alleged AB anti-bacteria cloth on the market;
Described hard microballon can adopt glass microballoon or plastics microballon or metal microbead or their mixture, and the particle diameter of microballon is 1～5mm; Consider the factor of cost, adopt glass microballoon both economical;
Described high hydroscopic resin is the high hydroscopic resin that is used for sanitary napkin or baby diaper, but the many water more than 400 times of absorptance self;
The described inorganic nano silver antibacterial agent that is coated on the high hydroscopic resin particle surface, be mainly zeolite silver Nano Silver inorganic antiseptic or zeolite silver Nano Silver, zinc inorganic antiseptic or the agent of basic zirconium phosphate silver nano antibacterial, by weight, the amount of the inorganic nano silver antibacterial agent that contains of high hydroscopic resin particle is 1～4 percent.
Described hot melt adhesive can adopt ethylene-vinyl acetate copolymer matter EVA hot melt adhesive, also can adopt chlorinated polypropylene hot melt adhesive or low molecule nylon powder hot melt adhesive or polyurethane hot melt or polyvinyl butyral resin hot melt adhesive, consider the factor of cost, adopt a little EVA hot melt adhesive of low price more suitable.
In preparation process, the hard microballon of employing dispenses tube 2, and the mesh of its cylindrical shell should be than big several of the particle diameter of used hard microballon; Equally, high hydroscopic resin dispense tube 3 mesh also should be than big several of the particle diameter of high hydroscopic resin, to make things convenient for dispensing of hard microballon and high hydroscopic resin.
The amount of dispensing of hard microballon and high hydroscopic resin is to be controlled by mesh spacing size and transmission speed forward, both amounts of dispensing on antibacterial nonwoven cloth made are difficult to strict control, as long as it is interior just passable to be controlled at certain scope, because these do not influence enforcement of the present invention.
Claims (10)
1. the shoe-pad material with multiple function comprises bottom, intermediate layer and upper strata trilaminate material, and bottom is a common fabric, is mainly polyester-cotton fabric, also can use other fabric; The upper strata is an antibacterial nonwoven cloth made, be mainly the polyacrylonitrile nonwoven fabric that contains nanometer copper on the polyacrylonitrile molecule, it is characterized in that, high hydroscopic resin particle and hard microballon are contained in the intermediate layer, be coated with the inorganic nano silver antibacterial agent on the surface of high hydroscopic resin particle, be coated with hot melt adhesive on the surface of hard microballon.
2. a kind of shoe-pad material with multiple function according to claim 1 is characterized in that described hard microballon or glass microballoon or plastics microballon or metal microbead, or their mixture, the particle diameter of microballon are 1～5mm.
3. a kind of shoe-pad material according to claim 1 with multiple function, it is characterized in that, the described inorganic nano silver antibacterial agent that coats at the high hydroscopic resin particle surface mainly is zeolite silver Nano Silver inorganic antiseptic or zeolite silver Nano Silver, zinc inorganic antiseptic or the agent of basic zirconium phosphate silver nano antibacterial, by weight, the amount of the inorganic nano silver antibacterial agent that contains of high hydroscopic resin particle is 1～4 percent.
4. a kind of shoe-pad material according to claim 1 with multiple function, it is characterized in that, described hot melt adhesive is a then EVA hot melt adhesive of ethylene-vinyl acetate copolymer, or chlorinated polypropylene hot melt adhesive, or low molecule nylon powder hot melt adhesive, or polyurethane hot melt, or polyvinyl butyral resin hot melt adhesive.
5. a kind of shoe-pad material with multiple function according to claim 1 is characterized in that, described shoe-pad material contains high hydroscopic resin 50～500 grams, hard microballon 1000-6000 grain in every square meter of material.
6. the shoe-pad preparation methods with multiple function as claimed in claim 1 is characterized in that, comprises following production stage:
(1) cloth
On the supporting plate of equipment, carry out cloth,
1. at first, unreel cloth by the antibacterial nonwoven cloth made reel, antibacterial nonwoven cloth made reel and finished product are collected reel and are kept synchronizing speed,
2. secondly, dispense tube by the hard microballon and dispense the hard microballon on antibacterial nonwoven cloth made, the hard microballon dispenses tube and keeps synchronizing speed with the antibacterial nonwoven cloth made reel,
3. the 3rd, dispense tube by high hydroscopic resin and on antibacterial nonwoven cloth made, dispense high hydroscopic resin, high hydroscopic resin dispenses tube and keeps synchronizing speed with the antibacterial nonwoven cloth made reel,
4. the 4th, unreel cloth by the common fabric reel, common fabric is covered on the antibacterial nonwoven cloth made that has dispensed hard microballon and high hydroscopic resin, and by guide roller that common fabric and antibacterial nonwoven cloth made is compound, common fabric reel and antibacterial nonwoven cloth made reel keep synchronizing speed;
(2) heating
Heated by the heating plate of equipment hard microballon and the high hydroscopic resin to antibacterial nonwoven cloth made and common fabric parcel, heating and temperature control is at 110～150 ℃;
(3) hot pressing
By the hot pressing roller of equipment after to heating antibacterial nonwoven cloth made and common fabric to carry out hot pressing compound, hard microballon and high hydroscopic resin are coated wherein, form shoe-pad material with multiple function;
(4) finished product is collected
Collecting reel by finished product collects the shoe-pad with multiple function that hot pressing forms with material is concentrated.
7. a kind of shoe-pad material according to claim 6 with multiple function, it is characterized in that, before carrying out (1) step 2., carry out the step of hard microballon coating hot melt adhesive earlier: the hard microballon is placed in the baking oven heat, insulation is 15～20 minutes in the time of 110 ℃, after the taking-up, takes advantage of heat to be poured into and is equipped with in the homogenizer of EVA hot melt adhesive powder, stirred 3～10 minutes, and made the hard bead surface coat one deck hot melt adhesive.
8. a kind of shoe-pad material according to claim 6 with multiple function, it is characterized in that, before carrying out (1) step 3., carry out the step of high hydroscopic resin surface coating antiseptic earlier: high hydroscopic resin is placed homogenizer, the Nano Silver inorganic antiseptic that takes by weighing high hydroscopic resin weight percentage 1～4% is again poured in the homogenizer, stirs 5～10 minutes, when the homogenizer indicated temperature is 110～150 ℃, stop to stir, coat and finish.
9. a kind of shoe-pad material according to claim 7 with multiple function, it is characterized in that, described hot melt adhesive is an ethylene-vinyl acetate copolymer matter EVA hot melt adhesive, or chlorinated polypropylene hot melt adhesive, or low molecule nylon powder hot melt adhesive, or polyurethane hot melt, or polyvinyl butyral resin hot melt adhesive.
10. a kind of shoe-pad material according to claim 8 with multiple function, it is characterized in that described Nano Silver inorganic antiseptic is zeolite silver Nano Silver inorganic antiseptic or zeolite silver Nano Silver, zinc inorganic antiseptic or the agent of basic zirconium phosphate silver nano antibacterial.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910201439XA CN102102299A (en) | 2009-12-18 | 2009-12-18 | Material for multifunctional shoe pad and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910201439XA CN102102299A (en) | 2009-12-18 | 2009-12-18 | Material for multifunctional shoe pad and preparation method thereof |
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| CN102102299A true CN102102299A (en) | 2011-06-22 |
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| CN200910201439XA Pending CN102102299A (en) | 2009-12-18 | 2009-12-18 | Material for multifunctional shoe pad and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102975377A (en) * | 2012-11-27 | 2013-03-20 | 常州悦诚新材料有限公司 | Production method of thermoplastic plastic profiles reinforced by continuous fiberglass fabrics |
| CN103355853A (en) * | 2013-07-22 | 2013-10-23 | 向祖树 | Method for resisting bacteria and deodorizing in shoe |
| CN104522936A (en) * | 2014-12-10 | 2015-04-22 | 青岛亨达股份有限公司 | Making method of insole capable of preventing deformation of foot arch |
| CN104553174A (en) * | 2015-01-06 | 2015-04-29 | 山东俊富无纺布有限公司 | Composite nonwoven material and preparation method thereof |
| CN107385906A (en) * | 2016-05-17 | 2017-11-24 | 金猴集团威海鞋业有限公司 | A kind of novel plant composite shoe material |
| CN107558185A (en) * | 2017-08-30 | 2018-01-09 | 江苏龙商环保科技有限公司 | The preparation method and preparation facilities of a kind of composite textile materials |
| CN112641167A (en) * | 2020-09-25 | 2021-04-13 | 郎溪润祥橡胶新材料有限公司 | Mining rubber shoe capable of preventing coal cinder and water accumulation |
| CN113305972A (en) * | 2021-06-16 | 2021-08-27 | 东莞市亿家卫浴科技有限公司 | Preparation process of environment-friendly soft-seat toilet lid |
| RU221218U1 (en) * | 2023-07-27 | 2023-10-25 | Вячеслав Петрович Тимофеев | ORTHOPEDIC INSOLE |
-
2009
- 2009-12-18 CN CN200910201439XA patent/CN102102299A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102975377A (en) * | 2012-11-27 | 2013-03-20 | 常州悦诚新材料有限公司 | Production method of thermoplastic plastic profiles reinforced by continuous fiberglass fabrics |
| CN102975377B (en) * | 2012-11-27 | 2015-07-29 | 江苏泰瑞斯特新材料科技有限公司 | The production method of continuous glass-fiber cloth reinforced thermoplastics section bar |
| CN103355853A (en) * | 2013-07-22 | 2013-10-23 | 向祖树 | Method for resisting bacteria and deodorizing in shoe |
| CN104522936A (en) * | 2014-12-10 | 2015-04-22 | 青岛亨达股份有限公司 | Making method of insole capable of preventing deformation of foot arch |
| CN104553174A (en) * | 2015-01-06 | 2015-04-29 | 山东俊富无纺布有限公司 | Composite nonwoven material and preparation method thereof |
| CN107385906A (en) * | 2016-05-17 | 2017-11-24 | 金猴集团威海鞋业有限公司 | A kind of novel plant composite shoe material |
| CN107558185A (en) * | 2017-08-30 | 2018-01-09 | 江苏龙商环保科技有限公司 | The preparation method and preparation facilities of a kind of composite textile materials |
| CN112641167A (en) * | 2020-09-25 | 2021-04-13 | 郎溪润祥橡胶新材料有限公司 | Mining rubber shoe capable of preventing coal cinder and water accumulation |
| CN113305972A (en) * | 2021-06-16 | 2021-08-27 | 东莞市亿家卫浴科技有限公司 | Preparation process of environment-friendly soft-seat toilet lid |
| RU221218U1 (en) * | 2023-07-27 | 2023-10-25 | Вячеслав Петрович Тимофеев | ORTHOPEDIC INSOLE |
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Application publication date: 20110622 |