CN102100234A - Sterilization composition containing pyraclostrobin and carbamates - Google Patents
Sterilization composition containing pyraclostrobin and carbamates Download PDFInfo
- Publication number
- CN102100234A CN102100234A CN2011100709226A CN201110070922A CN102100234A CN 102100234 A CN102100234 A CN 102100234A CN 2011100709226 A CN2011100709226 A CN 2011100709226A CN 201110070922 A CN201110070922 A CN 201110070922A CN 102100234 A CN102100234 A CN 102100234A
- Authority
- CN
- China
- Prior art keywords
- pyraclostrobin
- propamocarb
- bactericidal composition
- benzene metsulfovax
- mould prestige
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005869 Pyraclostrobin Substances 0.000 title claims abstract description 115
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 title claims abstract description 115
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 150000004657 carbamic acid derivatives Chemical class 0.000 title claims abstract description 5
- 230000001954 sterilising effect Effects 0.000 title abstract 3
- 238000004659 sterilization and disinfection Methods 0.000 title abstract 3
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000005821 Propamocarb Substances 0.000 claims abstract description 48
- 150000003839 salts Chemical class 0.000 claims abstract description 22
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 19
- 241000221785 Erysiphales Species 0.000 claims abstract description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 132
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 claims description 44
- 230000000844 anti-bacterial effect Effects 0.000 claims description 30
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 16
- 201000010099 disease Diseases 0.000 claims description 15
- 206010039509 Scab Diseases 0.000 claims description 3
- 241000219122 Cucurbita Species 0.000 claims 1
- 235000009852 Cucurbita pepo Nutrition 0.000 claims 1
- 235000012055 fruits and vegetables Nutrition 0.000 claims 1
- 239000004562 water dispersible granule Substances 0.000 abstract description 20
- 239000000375 suspending agent Substances 0.000 abstract description 17
- LNJNFVJKDJYTEU-UHFFFAOYSA-N diethofencarb Chemical compound CCOC1=CC=C(NC(=O)OC(C)C)C=C1OCC LNJNFVJKDJYTEU-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005759 Diethofencarb Substances 0.000 abstract description 2
- 241000395107 Cladosporium cucumerinum Species 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000000546 pharmaceutical excipient Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 23
- -1 second Chemical compound 0.000 description 21
- 239000000843 powder Substances 0.000 description 17
- 238000009736 wetting Methods 0.000 description 14
- 240000008067 Cucumis sativus Species 0.000 description 13
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 239000002131 composite material Substances 0.000 description 11
- 229920005646 polycarboxylate Polymers 0.000 description 10
- 230000003449 preventive effect Effects 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 9
- 229920002472 Starch Polymers 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 239000008107 starch Substances 0.000 description 9
- 235000019698 starch Nutrition 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000575 pesticide Substances 0.000 description 8
- 230000001018 virulence Effects 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000005995 Aluminium silicate Substances 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- 239000003899 bactericide agent Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
- 235000002566 Capsicum Nutrition 0.000 description 5
- 240000008574 Capsicum frutescens Species 0.000 description 5
- 229920001732 Lignosulfonate Polymers 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000004996 alkyl benzenes Chemical class 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000001390 capsicum minimum Substances 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 210000000481 breast Anatomy 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 238000009313 farming Methods 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 239000005800 Kresoxim-methyl Substances 0.000 description 3
- 206010067482 No adverse event Diseases 0.000 description 3
- 240000003377 Shepherdia canadensis Species 0.000 description 3
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 3
- 235000021003 saturated fats Nutrition 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 230000009885 systemic effect Effects 0.000 description 3
- 231100000820 toxicity test Toxicity 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 241000233654 Oomycetes Species 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 230000002438 mitochondrial effect Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 230000000241 respiratory effect Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- KBRSJPHSCOAFDR-UHFFFAOYSA-N 3-chloro-6-methyl-5,5-dioxo-11h-benzo[c][2,1]benzothiazepin-11-ol Chemical compound O=S1(=O)N(C)C2=CC=CC=C2C(O)C2=CC=C(Cl)C=C21 KBRSJPHSCOAFDR-UHFFFAOYSA-N 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 241000726221 Gemma Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- MKIMSXGUTQTKJU-UHFFFAOYSA-N Propamocarb hydrochloride Chemical compound [Cl-].CCCOC(=O)NCCC[NH+](C)C MKIMSXGUTQTKJU-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- USRKFGIXLGKMKU-ABAIWWIYSA-N benthiavalicarb-isopropyl Chemical compound C1=C(F)C=C2SC([C@@H](C)NC(=O)[C@H](C(C)C)NC(=O)OC(C)C)=NC2=C1 USRKFGIXLGKMKU-ABAIWWIYSA-N 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- 230000003612 virological effect Effects 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a sterilization composition containing pyraclostrobin and carbamates, which comprises effective active components of pyraclostrobin (A) and one (B) selected from diethofencarb, propamocarb or salts thereof, or isopropyl, wherein the weight ratio of A to B is 60:1-1:60. Assistants and excipients are added into the effective active components so that the effective active components are prepared into water dispersible granules, a suspending agent and the like. The sterilization composition is mainly used for controlling downy mildew, pestilence, gray mold, powdery mildew, anthracnose, leaf spot, cladosporium cucumerinum and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the preparation and the application of the bactericidal composition of a kind of pyraclostrobin-containing and carbamates.
Technical background
Pyraclostrobin (pyraclostrobin), molecular formula: C
20H
23N
3O
2, chemical name: methyl (N)-[[[1-(4-chlorobenzene) pyrazoles-3 base)-oxygen]-the O-methoxyl group]-the N-methoxymethyl carbamate.
Pyraclostrobin is the bactericide of BASF AG's latest model methoxy acrylic.Pure product are that white is to the tasteless crystalline solid of oldlace.The mechanism of action is the mitochondrial respiratory inhibitor.Make mitochondria can not produce and provide cell eubolism institute energy requirement, finally cause cell death.It can control most of diseases such as Ascomycetes, Basidiomycetes, deuteromycetes, Oomycete.Growth to spore germination and leaf intramatrical mycelium has very strong inhibitory action, has protection and therapeutic activity.Have permeability and local systemic activity, the lasting period is long, resistance of rainwater washing against.Be widely used in preventing and treating the disease on wheat, paddy rice, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco and ornamental plants, lawn and other field crops.This compound not only toxicity is low, to non-target organism safety, and also all friendly safely to user and environment, classified as " the candidate's medicament that reduces risk " by U.S. EPA.In addition, pyraclostrobin can be to making the positive physiological regulatory action of deposits yields, and the generation of its energy ethene suppressing can help crop to have longer time deposit bio-energy to guarantee maturity like this; Can significantly improve the activity of the restore nitrification enzyme of crop, mean the use that can reduce nitrogenous fertilizer in the soil, thereby further reduce phreatic influence; When crop was subjected to viral attack, it can quicken to resist the formation of albumen--and identical with crop self salicylic acid synthetic to the synthesis of degeneration-resistant albumen.Pyraclostrobin is the efficient mitochondrial respiratory inhibitor after improving on the kresoxim-methyl basis, is to have replaced o-methyl-phenyl-in the kresoxim-methyl molecular structure with N-rubigan pyrazolyl, and the another methoxy acrylic wide-spectrum bactericide of exploitation.Its activity is higher, is present 3 times with series bactericidal agent.And the report that kresoxim-methyl just takes place relevant for the wheat powdery mildew resistance after 1 year in practical application, to 2000 the resistance spore (2%-99%) in the north of Germany, the existing a large amount of reports in the north and Britain of France.Descend to the preventive effect of powdery mildew is existing at present at home.
The mould prestige of second (diethofencarb), molecular formula are C
14H
21NO
4, chemical name: 3,4-diethoxy phenylcarbamic acid isopropyl ester.
The mould prestige of second is a systemic fungicide, suppresses the formation of botrytis cinerea gemma spindle, is used to prevent and treat the bacterial strain of anti-Bentazons such as grape, citrus, the double powdery mildew of controlling.
Propamocarb (propamocarb), molecular formula are C
9H
21N
2O
2Cl, chemical name: 3-(dimethylamino) propyl carbamic acid propyl ester; Described propamocarb (propamocarb hydrochloride), chemical name: propyl group-3-(dimethylamino) propyl carbamic acid hydrochloride.
Propamocarb or propamocarb have local systemic action, also can be used as impregnation process and seed protectant.
Benzene metsulfovax (benthiavalicarb-isopropyl) molecular formula: C
18H
24FN
3O
3S, chemical name: [(S)-1-[(R)-1-(6-fluoro benzothiazole-2-yl) ethylamino formoxyl]-the 2-methyl-propyl] carbamic acid isopropyl ester.
The benzene metsulfovax is a kind of new type bactericide, belongs to the cell wall synthetic inhibitor.Oomycete germ to various crop all has good active, can control late blight, downy mildew of garpe, downy mildew of cucurbits, the parasitic downy mildew of potato and tomato effectively with lower dosage (25～75g a.i./hm2).The benzene metsulfovax has the toxicity and the feature of environmental protection preferably, to many vegetables and fruit nonhazardous.Have excellent prevention, treatment, osmotically active, and good lasting effect and resistance of rainwater washing against are arranged.
No matter be the mould prestige of pyraclostrobin, second, Propamocarb or its salt, benzene metsulfovax or other efficient germicides, long-term use separately, disease is developed immunity to drugs, cause the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, be unfavorable for environment sustainable development.And a kind ofly do not have the novel pesticide of cross resistance to prevent and treat pathogen if want newly developed, and then need screen 10,000～1.5 ten thousand compounds, expensive 1～1.5 hundred million dollar, the construction cycle is 6～10 years.And that the active ingredient of the different mechanisms of action is carried out is composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.
Pyraclostrobin is different with the mechanism of action of the mould prestige of second, Propamocarb or its salt, benzene metsulfovax, and mutually composite have good synergistic effect within the specific limits.And composite about pyraclostrobin and the mould prestige of second, Propamocarb or its salt, benzene metsulfovax do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of generation or delaying drug resistance speed that can prevent disease drug resistance, the bactericidal composition that use cost is low, preventive effect is good.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition of pyraclostrobin-containing, wherein the mould prestige of pyraclostrobin and second, Propamocarb or its salt or benzene metsulfovax weight ratio are 60: 1～1: 60.
The bactericidal composition of described pyraclostrobin-containing, wherein the weight ratio of the mould prestige of pyraclostrobin and second, Propamocarb or its salt or benzene metsulfovax be preferably 10: 1～1: 30.
The bactericidal composition of described pyraclostrobin-containing, wherein the weight ratio of pyraclostrobin and the mould prestige of second is more preferably 5: 1～1: 30, is preferably 1: 1～1: 10.
The bactericidal composition of described pyraclostrobin-containing, wherein the weight ratio of pyraclostrobin and Propamocarb or its salt is more preferably 5: 1～1: 30, is preferably 1: 5～1: 30.
The bactericidal composition of described pyraclostrobin-containing, wherein the weight ratio of pyraclostrobin and benzene metsulfovax is more preferably 10: 1～1: 10, is preferably 5: 1～1: 5.
The bactericidal composition of described pyraclostrobin-containing connection, wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The bactericidal composition of described pyraclostrobin-containing is according to method known in those skilled in the art, adds corresponding additive and filler, make agricultural and go up any formulation that allows, more preferably as: wetting powder, water dispersible granules or suspending agent.
Described auxiliary agent has dispersant, wetting agent, disintegrant, binding agent, defoamer, antifreeze, thickener.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described binding agent is selected from: one or more in diatomite, starch, PVA, carboxymethyl (ethyl) cellulose.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10 one 20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 1600
#In (phenethyl phenol polyoxy ethyl polypropylene-base ether), the ethylene oxide-propylene oxide block copolymer one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in prevents and treats powdery mildew, anthracnose, downy mildew, eqpidemic disease, scab, ring spot, spot defoliation etc.
Beneficial effect of the present invention: (1) present composition effective active composition pyraclostrobin and the mould prestige of second, Propamocarb or its salt or benzene metsulfovax belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition shows good synergistic effect in given scope, and preventive effect is apparently higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to downy mildew, eqpidemic disease, gray mold, powdery mildew, anthracnose, leaf spot, the scab of vegetables and fruit tree.
Embodiment
To further instruction of the present invention, but the present invention is not limited thereto below in conjunction with embodiment.Percentage in following examples all is weight percentage.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Implementation of an application example one: pyraclostrobin and Propamocarb or its salt (or benzene metsulfovax) are composite to the cucumber downy mildew Toxicity Determination
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament cucumber downy mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively pyraclostrobin and the mould prestige of second, Propamocarb or its salt or benzene metsulfovax shared ratio in combination
A is a pyraclostrobin
B is the mould prestige of second, Propamocarb or its salt or benzene metsulfovax
Result of the test is as shown in the table:
Table 1 pyraclostrobin, the mould prestige of second and composite toxicity test analysis of results table thereof to cucumber downy mildew
As shown in Table 1, pyraclostrobin, the mould prestige of second are to the EC of cucumber downy mildew
50Be respectively 0.48mg/L and 12.68mg/L.The virulence of pyraclostrobin is higher than the virulence of the mould prestige of second.The mould prestige of pyraclostrobin and second was mixed in the scope at 60: 1～1: 60 and all shows obvious synergistic effect.Wherein, both mixed synergies in 10: 1～1: 30 scope are comparatively desirable, and mixed synergies is particularly outstanding in 1: 1～1: 10 scope.
Table 2 pyraclostrobin, Propamocarb or its salt and composite toxicity test analysis of results table thereof to cucumber downy mildew
As shown in Table 2, the EC of pyraclostrobin, Propamocarb or its salt pair cucumber downy mildew
50Be respectively 0.48mg/L and 25.12mg/L.The virulence of pyraclostrobin is higher than the virulence of Propamocarb or its salt.Pyraclostrobin and Propamocarb or its salt were mixed in the scope at 60: 1～1: 60 and all show obvious synergistic effect.Wherein, both mixed synergies in 10: 1～1: 30 scope are comparatively desirable, and mixed synergies is particularly outstanding in 1: 1～1: 30 scope.
Table 3 pyraclostrobin, benzene metsulfovax and composite toxicity test analysis of results table thereof to cucumber downy mildew
As shown in Table 3, pyraclostrobin, benzene metsulfovax are to the EC of cucumber downy mildew
50Be respectively 0.84mg/L and 43.32mg/L.The virulence of pyraclostrobin is higher than the virulence of benzene metsulfovax.Pyraclostrobin and benzene metsulfovax were mixed in the scope at 60: 1～1: 60 and all show obvious synergistic effect.Wherein, both mixed synergies in 30: 1～1: 30 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Implementation of an application example two the implementation of Formulation Example
(1) pyraclostrobin Propamocarb or its salt:
Embodiment 1 80% pyraclostrobin Propamocarb water dispersible granules
Pyraclostrobin 10%, Propamocarb 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 5%, kaolin 5%, mixed 80% pyraclostrobin Propamocarb water dispersible granules.
Embodiment 2 70% pyraclostrobin propamocarb water dispersible granules
Pyraclostrobin 10%, propamocarb 60%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 10%, the mixed 70% pyraclostrobin propamocarb water dispersible granules that gets.
Embodiment 3 62% pyraclostrobin Propamocarb water dispersible granules
Pyraclostrobin 2%, Propamocarb 60%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 8%, bentonite 22%, mixed 62% pyraclostrobin Propamocarb water dispersible granules.
Embodiment 4 40% pyraclostrobin Propamocarb suspending agents
Pyraclostrobin 10%, Propamocarb 30%, alkyl benzene sulfonate calcium salt 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, phenyl phenol polyoxy ethyl ether 2%, deionized water adds to 100%, the mixed 40% pyraclostrobin Propamocarb suspending agent that gets.
Embodiment 5 30% pyraclostrobin propamocarb suspending agents
Pyraclostrobin 15%, propamocarb 15%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, the mixed 30% pyraclostrobin propamocarb suspending agent that gets.
Embodiment 6 28% pyraclostrobin Propamocarb suspending agents
Pyraclostrobin 4%, Propamocarb 24%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 28% pyraclostrobin Propamocarb suspending agent that gets.
(2) pyraclostrobin benzene metsulfovax
Embodiment 7 80% pyraclostrobin benzene metsulfovax water dispersible granules
Pyraclostrobin 20%, benzene metsulfovax 60%, alkylphenol-polyethenoxy are phonetic 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, starch 10%, mixed 80% pyraclostrobin benzene metsulfovax water dispersible granules.
Embodiment 8 60% pyraclostrobin benzene metsulfovax water dispersible granules
Pyraclostrobin 55%, benzene metsulfovax 5%, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 20%, the mixed 60% pyraclostrobin benzene metsulfovax water dispersible granules that gets.
Embodiment 9 48% pyraclostrobin benzene metsulfovax water dispersible granules
Pyraclostrobin 8%, benzene metsulfovax 40%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, starch 15%, diatomite 22%, mixed 48% pyraclostrobin benzene metsulfovax water dispersible granules.
Embodiment 10 40% pyraclostrobin benzene metsulfovax suspending agents
Pyraclostrobin 20%, benzene metsulfovax 20%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, the mixed 40% pyraclostrobin benzene metsulfovax suspending agent that gets.
Embodiment 11 36% pyraclostrobin benzene metsulfovax suspending agents
Pyraclostrobin 30%, benzene metsulfovax 6%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 36% pyraclostrobin benzene metsulfovax suspending agent that gets.
Embodiment 12 15% pyraclostrobin benzene metsulfovax suspending agents
Pyraclostrobin 10%, benzene metsulfovax 5%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 15% pyraclostrobin benzene metsulfovax suspending agent that gets.
(3) the mould prestige of pyraclostrobin second:
The mould prestige water dispersible granules of embodiment 13 85% pyraclostrobin second
Pyraclostrobin 10%, the mould prestige 75% of second, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, bentonite 5%, the mixed mould prestige water dispersible granules of 85% pyraclostrobin second that gets.
The mould prestige water dispersible granules of embodiment 14 75% pyraclostrobin second
Pyraclostrobin 15%, the mould prestige 60% of second, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, bentonite 12%, mixed the mould prestige water dispersible granules of 75% pyraclostrobin second.
The mould prestige water dispersible granules of embodiment 15 62% pyraclostrobin second
Pyraclostrobin 2%, the mould prestige 60% of second, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 8%, diatomite 22%, mixed the mould prestige water dispersible granules of 62% pyraclostrobin second.
The mould prestige wetting powder of embodiment 16 80% pyraclostrobin second
Pyraclostrobin 20%, the mould prestige 60% of second, alkylphenol-polyethenoxy are phonetic 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, kaolin 10%, mixed the mould prestige wetting powder of 80% pyraclostrobin second.
The mould prestige wetting powder of embodiment 17 55% pyraclostrobin second
Pyraclostrobin 5%, the mould prestige 50% of second, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, kaolin 35%, the mixed mould prestige wetting powder of 55% pyraclostrobin second that gets.
The mould prestige wetting powder of embodiment 18 45% pyraclostrobin second
Pyraclostrobin 40%, the mould prestige 5% of second, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, precipitated calcium carbonate 47%, mixed the mould prestige wetting powder of 45% pyraclostrobin second.
Embodiment uses the bactericidal composition control capsicum epidemic disease test of pesticide effectiveness of three pyraclostrobin-containings
This experimental establishment is in the Qianshan County, Gansu Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., the contrast medicament mould prestige wetting powder of 50% second (commercial), 72% Propamocarb aqua (commercial), 20% benzene metsulfovax wetting powder (commercial), 10% pyraclostrobin suspending agent (commercial).
The investigation capsicum epidemic disease state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated the capsicum epidemic disease disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
The bactericidal composition control capsicum epidemic disease test of pesticide effectiveness of table 4 pyraclostrobin-containing
As can be seen from Table 4, can effectively prevent and treat capsicum epidemic disease after the mould prestige of pyraclostrobin and second, Propamocarb or its salt or benzene metsulfovax are composite, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication, the target crop is had no adverse effects.
Implementation of an application example four: the bactericidal composition control cucumber anthracnose test of pesticide effectiveness of pyraclostrobin-containing
This experimental establishment is at the Xian City, Shanxi Province Changan District, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., the contrast medicament mould prestige wetting powder of 50% second (commercial), 72% propamocarb aqua (commercial), 20% benzene metsulfovax wetting powder (commercial), 10% pyraclostrobin suspending agent (commercial).
Investigation cucumber anthracnose state of an illness radix before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
The bactericidal composition control cucumber anthracnose test of pesticide effectiveness of table 5 pyraclostrobin-containing
As can be seen from Table 5, can effectively prevent and treat cucumber anthracnose after the mould prestige of pyraclostrobin and second, Propamocarb or its salt or benzene metsulfovax are composite takes place, control efficiency all is better than contrasting medicament, in this test scope of medication, the target crop is had no adverse effects, and powdery mildew of cucumber had good preventive effect, preventive effect reaches more than 90%.
Implementation of an application example five: the bactericidal composition of pyraclostrobin-containing is prevented and treated the downy mildew of garpe test of pesticide effectiveness
This experimental establishment is at Hu County, Shaanxi Province Lv Jiacun, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., the contrast medicament mould prestige wetting powder of 50% second (commercial), 72% Propamocarb aqua (commercial), 20% benzene metsulfovax wetting powder (commercial), 10% pyraclostrobin suspending agent (commercial).
Investigation downy mildew of garpe state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
The bactericidal composition of table 6 pyraclostrobin-containing is prevented and treated the downy mildew of garpe test of pesticide effectiveness
As can be seen from Table 6, can effectively prevent and treat downy mildew of garpe after pyraclostrobin and Propamocarb or its salt are composite and take place, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Claims (8)
1. the bactericidal composition of pyraclostrobin-containing and carbamates is characterized in that bactericidal composition effective active composition (A) pyraclostrobin and a kind of weight ratio in (B) the mould prestige of second, Propamocarb or its salt or the benzene metsulfovax are 60: 1～1: 60.
2. bactericidal composition according to claim 1 is characterized in that: wherein (A) pyraclostrobin is 10: 1～1: 30 with a kind of weight ratio in (B) the mould prestige of second, Propamocarb or its salt or the benzene metsulfovax.
3. bactericidal composition according to claim 2 is characterized in that: wherein (A) pyraclostrobin is 1: 1～1: 10 with (B) weight ratio of the mould prestige of second.
4. bactericidal composition according to claim 2 is characterized in that: wherein (A) pyraclostrobin is 1: 5～1: 30 with the weight ratio of (B) Propamocarb or its salt.
5. bactericidal composition according to claim 2 is characterized in that: wherein (A) pyraclostrobin is 5: 1～1: 5 with (B) weight ratio of benzene metsulfovax.
6. bactericidal composition according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
7. bactericidal composition according to claim 6 is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
8. bactericidal composition according to claim 1 is used to prevent and treat downy mildew, eqpidemic disease, gray mold, powdery mildew, anthracnose, leaf spot, the scab of gourd, fruit and vegetable.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103053560A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Benthiavalicarb isopropyl and kresoxim-methyl sterilization composition |
| CN103371163A (en) * | 2012-04-11 | 2013-10-30 | 中国农业科学院蔬菜花卉研究所 | Bactericide composition for control of corynespora cassiicola of crops |
| CN103719122A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing composite of pyraclostrobin and carbamates bactericide |
| CN105284844A (en) * | 2015-11-17 | 2016-02-03 | 山东棉花研究中心 | Pesticide composition containing pyraflufen-ethyl and pyraclostrobin |
| CN109619109A (en) * | 2019-01-21 | 2019-04-16 | 深圳诺普信农化股份有限公司 | A kind of pyraclostrobin compounds aqueous suspension agent and preparation method thereof with figured silk fabrics bacterium amine |
| CN109673655A (en) * | 2019-01-10 | 2019-04-26 | 陕西标正作物科学有限公司 | The bactericidal composition of the amine of bacterium containing figured silk fabrics and its application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6436979B1 (en) * | 1998-05-04 | 2002-08-20 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN1915019A (en) * | 2005-08-17 | 2007-02-21 | 浙江化工科技集团有限公司 | Composition of bactericide |
| CN101203136A (en) * | 2005-06-20 | 2008-06-18 | 巴斯福股份公司 | Crystalline modifications to pyraclostrobin |
| CN101822263A (en) * | 2010-01-27 | 2010-09-08 | 深圳诺普信农化股份有限公司 | Sterilization compound containing ZJ0712 |
| WO2012076634A1 (en) * | 2010-12-08 | 2012-06-14 | Basf Se | Fungicidal mixtures comprising pyraclostrobin |
-
2011
- 2011-03-23 CN CN201110070922.6A patent/CN102100234B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6436979B1 (en) * | 1998-05-04 | 2002-08-20 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN101203136A (en) * | 2005-06-20 | 2008-06-18 | 巴斯福股份公司 | Crystalline modifications to pyraclostrobin |
| CN1915019A (en) * | 2005-08-17 | 2007-02-21 | 浙江化工科技集团有限公司 | Composition of bactericide |
| CN101822263A (en) * | 2010-01-27 | 2010-09-08 | 深圳诺普信农化股份有限公司 | Sterilization compound containing ZJ0712 |
| WO2012076634A1 (en) * | 2010-12-08 | 2012-06-14 | Basf Se | Fungicidal mixtures comprising pyraclostrobin |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103371163A (en) * | 2012-04-11 | 2013-10-30 | 中国农业科学院蔬菜花卉研究所 | Bactericide composition for control of corynespora cassiicola of crops |
| CN103371163B (en) * | 2012-04-11 | 2015-04-01 | 中国农业科学院蔬菜花卉研究所 | Bactericide composition for control of corynespora cassiicola of crops |
| CN103053560A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Benthiavalicarb isopropyl and kresoxim-methyl sterilization composition |
| CN103053560B (en) * | 2012-12-29 | 2015-01-28 | 广东中迅农科股份有限公司 | Benthiavalicarb isopropyl and kresoxim-methyl sterilization composition |
| CN103719122A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing composite of pyraclostrobin and carbamates bactericide |
| CN105284844A (en) * | 2015-11-17 | 2016-02-03 | 山东棉花研究中心 | Pesticide composition containing pyraflufen-ethyl and pyraclostrobin |
| CN109673655A (en) * | 2019-01-10 | 2019-04-26 | 陕西标正作物科学有限公司 | The bactericidal composition of the amine of bacterium containing figured silk fabrics and its application |
| CN109619109A (en) * | 2019-01-21 | 2019-04-16 | 深圳诺普信农化股份有限公司 | A kind of pyraclostrobin compounds aqueous suspension agent and preparation method thereof with figured silk fabrics bacterium amine |
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