CN102093746A - Preparation method of basella rubra berry natural plant dye liquor and application of basella rubra berry natural plant dye liquor - Google Patents
Preparation method of basella rubra berry natural plant dye liquor and application of basella rubra berry natural plant dye liquor Download PDFInfo
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- CN102093746A CN102093746A CN2010106055086A CN201010605508A CN102093746A CN 102093746 A CN102093746 A CN 102093746A CN 2010106055086 A CN2010106055086 A CN 2010106055086A CN 201010605508 A CN201010605508 A CN 201010605508A CN 102093746 A CN102093746 A CN 102093746A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0083—Solutions of dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The invention provides a preparation method of basella rubra berry natural plant dye liquor and application of the basella rubra berry natural plant dye liquor. The preparation method is as follows: grinding washed and dried basella rubra berry into basella rubra berry slurry; adding water in the basella rubra berry slurry to dip for 1-2 hours under the normal temperature airtight condition, wherein the weight ratio of basella rubra berry slurry to water is 1: (3-6), and number of times of dipping is 1-2 times; merging and filtering the dipping liquid obtained by dipping so as to obtain the basella rubra berry natural plant dye liquor. The application of the basella rubra berry natural plant dye liquor is as follows: fabric is dyed by using a non chrome process or a pre-mordant process, a metachrome process, an afterchrome process, and then the dyed fabric is taken out, washed with water and dried in the shade. In the invention, natural plant dye is extracted from waste basella rubra berry and the fabric is dyed by using the natural plant dye, thereby achieving waste utilization of basella rubra berry, increasing dye varieties of textiles and improving grade of textiles. The basella rubra berry natural plant dye liquor is especially suitable for dyeing of wool fabrics and silk fabrics. The preparation and dyeing processes are simple and have good economic benefits and social benefits.
Description
Technical field
The present invention relates to a kind of preparation method and application thereof of natural phant dye liquor, the preparation method and the application thereof of the certain herbaceous plants with big flowers berry natural phant dye liquor that particularly falls.
Background technology
At present, the employed dyestuff overwhelming majority is synthetic dyestuff on the textile dyeing and finishing, and its raw material, intermediate are derived from oil, is toxic substance greatly wherein, serious environment pollution not only in the production process of synthetic dyestuff brings directly and indirect injury also for the wearer or the producer.Along with the continuous enhancing of people's environmental protection, health perception, traditional natural dyestuff causes people's attention again, to pursue higher quality of the life.The consistency of natural dyestuff and environment is good, and is biodegradable, nontoxic even have certain nourishing function; In addition, natural dyestuff has rich natural resource, does not have the problem of resource exhaustion, and the tone nature has suitable vast market prospect.
The certain herbaceous plants with big flowers that falls, another name Herba basellae rubrae, kermes dish, kermes beans, rattan Cai, Zhong certain herbaceous plants with big flowers, purple angle leaf etc.The certain herbaceous plants with big flowers that falls is annual voluble herb, well developed root system, and it is dark and wide to distribute, and absorbing power is very strong.Stem is easily given birth to adventive root, feasible cottage propagation in the ground of humidity.The certain herbaceous plants with big flowers that falls is divided into blue or green stalk fall two kinds of the certain herbaceous plants with big flowers of certain herbaceous plants with big flowers and red stalk that fall, and is all and overgrows, and stem is smooth, and meat does not have hair, divides principal stresses strong, reaches several meters.The blue or green stalk green white of certain herbaceous plants with big flowers stem that falls, the red stalk certain herbaceous plants with big flowers stem red-purple that falls.Fruit is a berry, atropurpureus, oval, 5～10 millimeters of diameters.Pulp purple succulence.6-9 month Flower of Red Vinespinach phase, the fruit phase 7-10 month.The certain herbaceous plants with big flowers complete stool that falls can be used as medicine, and seed and blade are gone into Chinese medicine, and distinguish the flavor of sweet, little acid, cold cunning have the effect of heat radiation, diuresis, moist people's face, clearing heat and cooling blood.Generally, the purple black berry of the certain herbaceous plants with big flowers that falls is extractd, and does not obtain utilizing.And,, do not report to some extent as yet about certain herbaceous plants with big flowers berry natural dyestuff preparation method and the application thereof of falling yet.
Summary of the invention
The purpose of this invention is to provide the preparation method and the application thereof of a kind of aboundresources, the certain herbaceous plants with big flowers berry natural phant dye liquor that falls that Color is good, turn waste into wealth to realize the certain herbaceous plants with big flowers berry, increase the natural plant dye kind, enrich the dyestuff chromatogram, exploitation dyed textiles product innovation.
Be real above-mentioned purpose, the technical solution used in the present invention is:
The preparation method of the certain herbaceous plants with big flowers berry natural plant dye that falls of the present invention may further comprise the steps:
1) will fall the certain herbaceous plants with big flowers berry clean drain after, grind to form certain herbaceous plants with big flowers berry slurry;
2) add entry in the above-mentioned certain herbaceous plants with big flowers berry slurry that falls, the weight ratio of fall certain herbaceous plants with big flowers berry slurry and water is 1: 3～6, floods 1～2h under the normal temperature air tight condition, lixiviate 1～2 time;
3) immersion liquid with above-mentioned lixiviate merges, filters, and certain herbaceous plants with big flowers berry natural phant dye liquor must fall.
What above-mentioned filtration was adopted is 400～600 purpose filter screens, and filter screen is a kind of in nylon wire, the terylene net.
The application of the certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the present invention: adopt no mordant dyeing look or pre-mordant dyeing look, with mordant dyeing look, back mordant dyeing color method, after fabric is dyeed, take out fabric, the water flushing, dry in the shade.
Above-mentioned employing does not have the mordant dyeing look and fabric is carried out painted method is, with the bath raio ratio of the weight of dye liquor (fabric with) is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, regulate dye liquor pH value to 4.0～5.0, input is through the abundant wetting fabric of 45～55 ℃ of warm water, behind dyeing 60～90min under 60～70 ℃, take out fabric, water washes, dries in the shade.
The pre-mordant dyeing look of above-mentioned employing carries out painted method to fabric and is, gets the mordant of fabric weight 3～5%, the bath raio with 1: 45～55, under 60～70 ℃ to fabric mordant dyeing 30～60min after, take out the fabric flushing, extract; With bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, regulates dye liquor pH value to 4.0～5.0, and the fabric after the mordant dyeing is dropped in the dye liquor, at 60～70 ℃ of dyeing 60～90min down, takes out fabric, the water flushing, dries in the shade.
Above-mentioned employing is carried out painted method with the mordant dyeing look to fabric, with bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, the mordant that adds fabric weight 3～5%, re-adjustment dye liquor pH value to 4.0～5.0, input is through the abundant wetting fabric of 45～55 ℃ of warm water, behind dyeing 60～90min under 60～70 ℃, take out fabric, water washes, dries in the shade.
The mordant dyeing look carries out painted method to fabric and is after the above-mentioned employing, with bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, regulate dye liquor pH value to 4.0～5.0, drop into, in 60～70 ℃ of 25～40min that dye down through the abundant wetting fabric of 45～55 ℃ of warm water; The mordant that adds fabric weight 3～5% again in the above-mentioned dye liquor, 60～70 ℃ continuous down dye 30～60min after, take out fabric, the water flushing, dry in the shade.
Above-mentioned mordant is a kind of in Tai-Ace S 150, ferric sulfate, copper sulfate, sal epsom, zinc sulfate and the tin protochloride.
Above-mentioned fabrics is wool fabric or silk fabric.
The employed reagent of above-mentioned adjusting dye liquor pH value is acetic acid.
The present invention is owing to extract natural plant dye from depleted falls the certain herbaceous plants with big flowers berry, and fabric dyeed, the utilization of waste material of certain herbaceous plants with big flowers berry has realized falling, increased the dyeing kind of textiles, improve the class of textiles, be particularly suitable for the dyeing of wool fabric, silk fabric, fabric is worn safety, does not have any anaphylaxis, and is good with Environmental compatibility, biodegradable, and the certain herbaceous plants with big flowers that falls is wide at China's distributed pole, abundant raw material, and the preparation and the dyeing of dyestuff are simple, constant product quality has good economic benefit and social benefit.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention may further comprise the steps:
1) select the sophisticated certain herbaceous plants with big flowers berry that falls, clean drain after, grind to form certain herbaceous plants with big flowers berry slurry;
2) add entry in the above-mentioned certain herbaceous plants with big flowers berry slurry that falls, the weight ratio of fall certain herbaceous plants with big flowers berry slurry and water is 1: 6, floods 1.5h under the normal temperature air tight condition, lixiviate 1 time;
3) with the immersion liquid of above-mentioned lixiviate with 400 order nylon net filters, certain herbaceous plants with big flowers berry natural phant dye liquor must fall.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with no mordant dyeing color method silk fabric being dyeed is example:
With bath raio is to measure above-mentioned the fall certain herbaceous plants with big flowers berry natural phant dye liquor that make at 1: 45, drips Glacial acetic acid and regulate pH value to 4.0 in dye liquor, drops into through the abundant wetting silk fabric of 50 ℃ of warm water, behind dyeing 60min under 60 ℃, take out silk fabric, the water flushing is dried in the shade.
After measured, the silk fabric after the dyeing is red-purple, its L
*Value is 68.63, a
*Value is 8.05, b
*Value is 1.72, c
*Value is 8.23, and the h value is 12.03, and the K/S value is 0.5843.
Embodiment 2:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention may further comprise the steps:
1) select the sophisticated certain herbaceous plants with big flowers berry that falls, clean drain after, grind to form certain herbaceous plants with big flowers berry slurry;
2) add entry in the above-mentioned certain herbaceous plants with big flowers berry slurry that falls, the weight ratio of fall certain herbaceous plants with big flowers berry slurry and water is 1: 6, floods 2h under the normal temperature air tight condition, lixiviate 2 times;
3) immersion liquid with above-mentioned lixiviate merges, and with 600 order terylene net filtrations, certain herbaceous plants with big flowers berry natural phant dye liquor must fall.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with no mordant dyeing color method wool fabric being dyeed is example:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls that makes at 1: 50, drips Glacial acetic acid at dye liquor and regulates pH value to 5.0, drops into through the abundant wetting wool fabric of 45 ℃ of warm water, at 70 ℃ down behind the dyeing 90min, takes out wool fabric, and water washes, and dries in the shade.
After measured, the wool fabric after the dyeing is red-purple, its L
*Value is 45.20, a
*Value is 25.08, b
*Value is-9.50, c
*Value is 26.81, and the h value is 339.25, and the K/S value is 4.1891.
Embodiment 3:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention may further comprise the steps:
1) select the sophisticated certain herbaceous plants with big flowers berry that falls, clean drain after, grind to form certain herbaceous plants with big flowers berry slurry;
2) add entry in the above-mentioned certain herbaceous plants with big flowers berry slurry that falls, the weight ratio of fall certain herbaceous plants with big flowers berry slurry and water is 1: 3, floods 1h under the normal temperature air tight condition, lixiviate 2 times;
3) immersion liquid with above-mentioned lixiviate merges, and with 500 order nylon net filters, certain herbaceous plants with big flowers berry natural phant dye liquor must fall.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with pre-mordant dyeing color method silk fabric being dyeed is example:
The Tai-Ace S 150 of getting silk fabric weight 3% is as mordant, and adding water, to be mixed with bath raio be 1: 45 mordanting bath, drops into through the abundant wetting silk fabric of 52 ℃ of warm water, behind 60 ℃ of following mordant dyeing 30min, takes out silk fabric, the water flushing, extracts.With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 55, drips Glacial acetic acid at dye liquor and regulates pH value to 4.0, and the silk fabric after the mordant dyeing is dropped in the dye liquor, at 60 ℃ down behind the dyeing 60min, takes out silk fabric, and water washes, and dries in the shade.
After measured, the silk fabric after the dyeing is red-purple, its L
*Value is 67.80, a
*Value is 8.06, b
*Value is 0.61, c
*Value is 8.08, and the h value is 4.33, and the K/S value is 0.6247.
Embodiment 4:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with pre-mordant dyeing color method wool fabric being dyeed is example:
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with pre-mordant dyeing color method wool fabric being dyeed is example:
The copper sulfate of fetching and delivering wool fabric weight 4% is as mordant, and adding water, to be mixed with bath raio be 1: 50 mordanting bath, drops into wool fabric, behind 60 ℃ of following mordant dyeing 60min, takes out wool fabric, the water flushing, extracts.With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 50, drips Glacial acetic acid at dye liquor and regulates pH value to 5.0, and the wool fabric after the mordant dyeing is dropped in the dye liquor, at 60 ℃ down behind the dyeing 60min, takes out wool fabric, and water washes, and dries in the shade.
After measured, the wool fabric after the dyeing is grass green, its L
*Value is 63.78, a
*Value is-1.68, b
*Value is 18.03, c
*Value is 18.11, and the h value is 95.33, and the K/S value is 3.2919.
Embodiment 5:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 3.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with pre-mordant dyeing color method silk fabric being dyeed is example:
The sal epsom of getting silk fabric weight 5% is as mediator, and adding water, to be mixed with bath raio be 1: 55 mordanting bath, drops into through the abundant wetting silk fabric of 48 ℃ of warm water, behind 70 ℃ of following mordant dyeing 60min, takes out silk fabric, the water flushing, extracts.With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 50, drips Glacial acetic acid at dye liquor and regulates pH value to 4.0, and the silk fabric after the mordant dyeing is dropped in the dye liquor, at 60 ℃ down behind the dyeing 90min, takes out silk fabric, and water washes, and dries in the shade.
After measured, the silk fabric after the dyeing is red-purple, its L
*Value is 68.16, a
*Value is 8.52, b
*Value is 0.52, c
*Value is 8.54, and the h value is 3.49, and the K/S value is 0.6142.
Embodiment 6:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 3.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, with pre-mordant dyeing color method silk fabric being dyeed is example:
Get the tin protochloride of silk fabric weight 5% and make mordant, adding water, to be mixed with bath raio be 1: 50 mordanting bath, drops into silk fabric, behind 60 ℃ of following mordant dyeing 30min, takes out silk fabric, the water flushing, extracts.With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 50, drips Glacial acetic acid at dye liquor and regulates pH value to 4.0, and the silk fabric after the mordant dyeing is dropped in the dye liquor, at 60 ℃ down behind the dyeing 90min, takes out silk fabric, and water washes, and dries in the shade.
After measured, the silk fabric after the dyeing is orange, its L
*Value is 71.76, a
*Value is 6.49, b
*Value is 3.38, c
*Value is 7.32, and the h value is 27.50, and the K/S value is 0.4380.
Embodiment 7:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is an example with the mordant dyeing color method wool fabric is dyeed:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 45, the tin protochloride that in dye liquor, adds wool fabric weight 3% as mordant, in dye liquor, drip Glacial acetic acid again and regulate pH value to 5.0, input is through the abundant wetting wool fabric of 50 ℃ of warm water, behind dyeing 60min under 60 ℃, take out wool fabric, the water flushing is dried in the shade.
After measured, the wool fabric after the dyeing is orange, its L
*Value is 46.91, a
*Value is 27.94, b
*Value is 3.26, c
*Value is 28.13, and the h value is 6.66, and the K/S value is 3.5628.
Embodiment 8:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is an example with the mordant dyeing color method silk fabric is dyeed:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 50, the ferric sulfate that in dye liquor, adds silk fabric weight 4% as mordant, in dye liquor, drip Glacial acetic acid again and regulate pH value to 4.0, input is through the abundant wetting silk fabric of 50 ℃ of warm water, behind dyeing 60min under 70 ℃, take out silk fabric, the water flushing is dried in the shade.
After measured, the silk fabric after the dyeing is light brown, its L
*Value is 68.87, a
*Value is 2.05, b
*Value is 8.07, c
*Value is 8.33, and the h value is 75.76, and the K/S value is 1.1434.
Embodiment 9:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is an example with the mordant dyeing color method wool fabric is dyeed:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 55, the Tai-Ace S 150 that in dye liquor, adds wool fabric weight 5% as mordant, in dye liquor, drip Glacial acetic acid again and regulate pH value to 5.0, input is through the abundant wetting wool fabric of 50 ℃ of warm water, behind dyeing 90min under 60 ℃, take out wool fabric, the water flushing is dried in the shade.
After measured, the wool fabric after the dyeing is red-purple, its L
*Value is 49.71, a
*Value is 23.25, b
*Value is-8.50, c
*Value is 24.76, and the h value is 339.91, and the K/S value is 2.9983.
Embodiment 10:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, later mordant dyeing color method dyes to wool fabric and is example:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 45, in dye liquor, drip Glacial acetic acid and regulate pH value to 5.0, input is through the abundant wetting wool fabric of 50 ℃ of warm water, behind dyeing 30min under 60 ℃, the copper sulfate that in dye liquor, adds wool fabric weight 3% again as mordant, 60 ℃ down continuous dye 30min after, take out wool fabric, the water flushing is dried in the shade.
After measured, the wool fabric after the dyeing is grass green, its L
*Value is 61.50, a
*Value is 0.45, b
*Value is 19.33, c
*Value is 19.33, and the h value is 88.65, and the K/S value is 3.4536.
Embodiment 11:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, later mordant dyeing color method dyes to silk fabric and is example:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 55, in dye liquor, drip Glacial acetic acid and regulate pH value to 4.0, input is through the abundant wetting fabric of 50 ℃ of warm water, behind dyeing 30min under 60 ℃, the tin protochloride that adds silk fabric weight 4% as mordant, 60 ℃ continuous down dye 30min after, take out silk fabric, the water flushing is dried in the shade.
After measured, the silk fabric after the dyeing is orange, its L
*Value is 68.97, a
*Value is 14.27, b
*Value is 3.94, c
*Value is 14.81, and the h value is 15.44, and the K/S value is 0.6275.
Embodiment 12:
The preparation method of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention is with embodiment 2.
The application of the described certain herbaceous plants with big flowers berry natural phant dye liquor that falls of the embodiment of the invention, later mordant dyeing color method dyes to wool fabric and is example:
With bath raio is to measure the above-mentioned certain herbaceous plants with big flowers berry natural phant dye liquor that falls at 1: 50, in dye liquor, drip Glacial acetic acid and regulate pH value to 5.0, input is through the abundant wetting wool fabric of 50 ℃ of warm water, behind dyeing 30min under 70 ℃, the sal epsom that adds wool fabric weight 5% as mordant, 70 ℃ down continuous dye 60min after, take out the fabric of seeing off, the water flushing, dry in the shade.
After measured, the wool fabric after the dyeing is red-purple, its L
*Value is 49.37, a
*Value is 23.51, b
*Value is-7.90, c
*Value is 24.80, and the h value is 341.43, and the K/S value is 3.0777.
Claims (10)
1. the fall preparation method of certain herbaceous plants with big flowers berry natural plant dye is characterized in that: may further comprise the steps:
1) will fall the certain herbaceous plants with big flowers berry clean drain after, grind to form certain herbaceous plants with big flowers berry slurry;
2) add entry in the above-mentioned certain herbaceous plants with big flowers berry slurry that falls, the weight ratio of fall certain herbaceous plants with big flowers berry slurry and water is 1: 3～6, floods 1～2h under the normal temperature air tight condition, lixiviate 1～2 time;
3) immersion liquid with above-mentioned lixiviate merges, filters, and makes certain herbaceous plants with big flowers berry natural phant dye liquor.
2. the preparation method of the certain herbaceous plants with big flowers berry natural plant dye that falls according to claim 1 is characterized in that: what above-mentioned filtration was adopted is 400～600 purpose filter screens, and filter screen is a kind of in nylon wire, the terylene net.
3. the application of the certain herbaceous plants with big flowers berry natural plant dye that falls that preparation method according to claim 1 obtains, it is characterized in that: adopt no mordant dyeing look or pre-mordant dyeing look, with mordant dyeing look, back mordant dyeing color method, after fabric dyeed, take out fabric, the water flushing, dry in the shade.
4. the application of the certain herbaceous plants with big flowers berry natural plant dye that falls according to claim 3, it is characterized in that: above-mentioned employing does not have the mordant dyeing look and fabric is carried out painted method is, with bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, regulate dye liquor pH value to 4.0～5.0, input is through the abundant wetting fabric of 45～55 ℃ of warm water, behind dyeing 60～90min under 60～70 ℃, take out fabric, water washes, dries in the shade.
5. the application of the certain herbaceous plants with big flowers berry natural plant dye that falls according to claim 3, it is characterized in that: the pre-mordant dyeing look of above-mentioned employing carries out painted method to fabric and is, get the mordant of fabric weight 3～5%, bath raio with 1: 45～55, under 60～70 ℃ to fabric mordant dyeing 30～60min after, the flushing of taking-up fabric is extracted; With bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, regulates dye liquor pH value to 4.0～5.0, and the fabric after the mordant dyeing is dropped in the dye liquor, at 60～70 ℃ of dyeing 60～90min down, takes out fabric, the water flushing, dries in the shade.
6. the application of the certain herbaceous plants with big flowers berry natural plant dye that falls according to claim 3, it is characterized in that: above-mentioned employing is carried out painted method with the mordant dyeing look to fabric and is, with bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, the mordant that adds fabric weight 3～5%, drop into through the abundant wetting fabric of 45～55 ℃ of warm water, behind dyeing 60～90min under 60～70 ℃ re-adjustment dye liquor pH value to 4.0～5.0, take out fabric, water washes, dries in the shade.
7. the application of the certain herbaceous plants with big flowers berry natural plant dye that falls according to claim 3, it is characterized in that: the mordant dyeing look carries out painted method to fabric and is after the above-mentioned employing, with bath raio is 1: 45～55 to measure certain herbaceous plants with big flowers berry natural phant dye liquor, regulate dye liquor pH value to 4.0～5.0, input is through the abundant wetting fabric of 45～55 ℃ of warm water, in 60～70 ℃ of 25～40min that dye down; The mordant that adds fabric weight 3～5% again in the above-mentioned dye liquor, 60～70 ℃ continuous down dye 30～60min after, take out fabric, the water flushing, dry in the shade.
8. according to the application of the described certain herbaceous plants with big flowers berry natural plant dye that falls of one of claim 3 to 7, it is characterized in that: above-mentioned fabrics is wool fabric or silk fabric.
9. according to the application of the described certain herbaceous plants with big flowers berry natural plant dye that falls of one of claim 5 to 7, it is characterized in that: above-mentioned mordant is a kind of in Tai-Ace S 150, ferric sulfate, copper sulfate, sal epsom, zinc sulfate and the tin protochloride.
10. according to the application of the described certain herbaceous plants with big flowers berry natural plant dye that falls of one of claim 4 to 7, it is characterized in that: the employed reagent of above-mentioned adjusting dye liquor pH value is acetic acid.
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| CN106835759A (en) * | 2017-01-21 | 2017-06-13 | 达利(中国)有限公司 | The preparation method and applications of natural dye Freehandhand-drawing real silk fabric |
| CN106906674A (en) * | 2017-03-14 | 2017-06-30 | 无锡城市职业技术学院 | A kind of method that natural botanical extraction liquid dyes mohair yarn fiber |
| CN107829313A (en) * | 2017-11-16 | 2018-03-23 | 河南工程学院 | A kind of natural dye extraction and dyeing one one step processing method of bath |
| CN109355933A (en) * | 2018-10-17 | 2019-02-19 | 江苏华东纺织产品检测有限公司 | Mordant dyeing color method after a kind of vegetable colour of superfine wool |
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| CN109355933A (en) * | 2018-10-17 | 2019-02-19 | 江苏华东纺织产品检测有限公司 | Mordant dyeing color method after a kind of vegetable colour of superfine wool |
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Application publication date: 20110615 |