CN102070846B - Formula of rubber floorboard covering used for rail vehicle - Google Patents

Formula of rubber floorboard covering used for rail vehicle Download PDF

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Publication number
CN102070846B
CN102070846B CN2011100321102A CN201110032110A CN102070846B CN 102070846 B CN102070846 B CN 102070846B CN 2011100321102 A CN2011100321102 A CN 2011100321102A CN 201110032110 A CN201110032110 A CN 201110032110A CN 102070846 B CN102070846 B CN 102070846B
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China
Prior art keywords
percent
flame retardant
agent
rubber
rail vehicle
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CN2011100321102A
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Chinese (zh)
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CN102070846A (en
Inventor
蒋建华
金建国
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Jingsu Changda Eco-technologies Co., Ltd.
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CHANGZHOU CHANGDA RAIL EQUIPMENT CO LTD
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Abstract

The invention discloses a combination of a rubber floorboard covering used for a rail vehicle. The formula comprises the following components in percentage by weight: 22 to 35 percent of synthetic rubber ethylene-propylene-diene monomer (EPDM), 0.6 to 1.5 percent of inorganic activating agent zinc oxide, 0.2 to 0.4 percent of stearic acid, 0.3 to 0.8 percent of ozone-resistant anti-aging agent, 0.4 to 2.0 percent of thermal oxidation-resistant anti-aging agent, 0.5 to 2.5 percent of flame retardant microencapsulated red phosphorus, 5 to 7 percent of flame retardant decabromdiphenylethane, 8 to 15percent of flame retardant smoke suppressor magnesium hydroxide, 1.8 to 3.0 percent of special polyolefin environmentally-friendly flame retardant, 10 to 27 percent of inorganic flame retardant aluminum hydroxide, 2 to 6 percent of additive type flame retardant diantimony trioxide, 2 to 6 percent of additive smoke-suppressing flame retardant zinc borate, 3 to 8 percent of reinforcing agent white carbon black, 6 to 10 percent of filling agent superfine talcpowder, 1 to 5 percent of filler and colorant titanium dioxide, 0.3 to 1.5 percent of internal dispersant, 0.8 to 1.5 percent of rubber surface activating agent, 0.1 to 0.5 percent of protection microcrystalline wax, 0.2 to 0.6 percent of antioxidant, 0.2 to 0.6 percent of anti-yellowing promoting agent, 0.3 to 1.0 percent of vulcanization accelerator, 0.5 to 1.5 percent of efficient vulcanization accelerator, and 0.2 to 0.8 percent of insoluble sulfur.

Description

The obducent compsn of used for rail vehicle rubber floor covering
Technical field
The present invention relates to rubber floor covering coverture field, the special prescription that relates to a kind of low cigarette that is used for rail vehicle, Halogen, fire-retardant, environment-friendly rubber floor covering.
Background technology
The rubber floor covering coverture has excellent characteristics such as snappiness, anti-skidding, anti-electrostatic, anti-air aging, UV resistant, anti-ozone ageing, wear-resistant, weak acid resistant weak base because of it; It is applied on the rail vehicle widely, and said rail vehicle comprises railway high speed passenger vehicle (EMUs), light rail (containing the rail electric car), railcar etc.In obducent requirement to rubber floor covering; High-speed railway passenger and light rail railcar satisfy method mark NF F31-812 " rail vehicles rubber floor covering coverture " standard code requirement, wherein: on material property, must resist the various infringements that in use possibly run into; When using washing composition to clean outside, compartment or floor, the effect that the cleaning product of being selected for use produces it; The friction that passenger's dealing caused and the abrasion that cause; The cigarette end calcination does not cause fire, does not stay any vestige through cleaning; Ageing-resistant, long service life; This standard is pointed out simultaneously: during like accidental disasters such as presence of fire; The rubber floor covering coverture must be able to reach fire-retardant, not spread, hangs down the cigarette-brand standard because of the gas of fire or the generation of other factors; Be to guarantee to see clearly passway for escaping after fire takes place; The obducent prescription of rubber floor covering is originally as the Halogen prescription simultaneously; Promptly do not contain halogen family element or halogen derivative in the prescription, so just can guarantee can not volatilize poisonous deathlike atmosphere after the fusion of rubber floor covering coverture in presence of fire or under high-temperature condition.But the rubber floor covering coverture of present domestic used for rail vehicle is external imported product, and annual China reaches 1,000,000,000 yuans in the obducent import volume of the rubber floor covering of EMUs, and the light rail subway reaches 500,000,000 yuans.
Summary of the invention
To domestic vacancy that should technology, the present invention provides the prescription of a kind of coincidence method mark NF F31-812 " rail vehicles rubber floor covering coverture " low cigarette that standard code requires, Halogen, fire-retardant, environment-friendly rubber floor covering.
For realizing above-mentioned purpose, the present invention adopts following technical scheme to realize:
The obducent compsn of used for rail vehicle rubber floor covering, the percentage meter comprises following component by weight:
Figure GDA0000145942530000021
Figure GDA0000145942530000031
The preferred obducent compsn of used for rail vehicle rubber floor covering, the percentage meter comprises following component by weight:
Figure GDA0000145942530000032
The polyolefine special environment protection fire retardant HT-101 that the present invention adopts has replaced Antimony Trioxide: 99.5Min commonly used in the present prescription; Strengthened flame retardant effect; The anti-xanthochromia accelerant A G201 that adopts has simultaneously replaced vulcanizing agent commonly used in the present prescription; The defective that improved the anti-xanthochromia of rubber floor covering coverture, is prone to revert has prolonged rubber floor covering obducent work-ing life; Do not contain halogen family element and halogenide in the prescription of the present invention simultaneously; Under environmentfriendly products, its chance fire or high-temperature condition; Gas after the fusion can not damage health within 30 minutes; Do not have the sootiness sequela, for the escape personnel provides the guarantee of surviving, this index is through U.S.'s Occupational safety and the life and health of health research institute (NIOSH) and the check of time shutter.In addition; Be that multiple fire retardant is composite in the prescription of the present invention, in the time of can being implemented in 850 ℃ nature, do not decompose compared with techniques such as the no fire-retardant agent prescription in compared to prior art, single fire retardant prescription; Effect fire-retardant, that do not spread, hang down cigarette of the present invention is more outstanding; Burning can not produce black smoke, thick fog behind this product, and the flue gas that discharges does not have peculiar smell, HCl, HBr, HF, HCN, CO, CO 2, SO 2All conformance with standard requirements, the present invention Public Transportation Corporation laboratory test through French PATP Paris of filling a prescription has reached method mark NF F31-812 " rail vehicles rubber floor covering coverture " standard code requirement.Chemical chain is stable in its physics of component of being selected for use in the prescription of the present invention, chemistry, the combustion reactions, therefore has good antiwear property and resistance of aging.
Embodiment
Through specific embodiment, the present invention is done detailed elaboration below:
Embodiment 1
The obducent compsn of used for rail vehicle rubber floor covering, the percentage meter comprises following component by weight:
Figure GDA0000145942530000051
Embodiment 2
The obducent compsn of used for rail vehicle rubber floor covering, the percentage meter comprises following component by weight:
Figure GDA0000145942530000061
Embodiment 3
The obducent compsn of used for rail vehicle rubber floor covering, the percentage meter comprises following component by weight:
Figure GDA0000145942530000062
Figure GDA0000145942530000071
The Public Transportation Corporation laboratory test through French PATP Paris, gained index parameter such as following table:
Figure GDA0000145942530000081

Claims (2)

1. the obducent compsn of used for rail vehicle rubber floor covering is characterized in that, the percentage meter comprises following component by weight:
2. the obducent compsn of used for rail vehicle rubber floor covering is characterized in that, the percentage meter comprises following component by weight:
Figure FDA0000145942520000021
CN2011100321102A 2011-01-29 2011-01-29 Formula of rubber floorboard covering used for rail vehicle Expired - Fee Related CN102070846B (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN2011100321102A CN102070846B (en) 2011-01-29 2011-01-29 Formula of rubber floorboard covering used for rail vehicle

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106987028A (en) * 2017-04-25 2017-07-28 江苏昌达环保科技有限公司 A kind of composition, fireproof rubber floor and preparation method for improving rubber oxygen index (OI)

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CN104610668A (en) * 2015-02-09 2015-05-13 安徽中鼎密封件股份有限公司 No-coloring low-peculiar-smell flame-retardant ethylene-propylene rubber material and preparation method thereof
CN105061908A (en) * 2015-07-28 2015-11-18 苏州市相城区明达复合材料厂 Special rubber flame-retardant floor for passenger car
CN106280021B (en) * 2016-08-09 2018-09-14 中国铁道科学研究院金属及化学研究所 Rubber floor covering cloth and the application of a kind of rubber floor covering cloth composition and its preparation
CN106084502A (en) * 2016-08-23 2016-11-09 西安航天华阳机电装备有限公司 EPDM series environment-friendly type rubber floor covering sizing material and preparation method thereof
CN106589626A (en) * 2016-12-21 2017-04-26 上海精橡胶科技有限公司 Environmental protection like flame-retardant elastomer material for electric appliance
CN107556566A (en) * 2017-10-16 2018-01-09 北京海月星科技有限公司 A kind of damping glue band and its preparation method and application
CN108587168A (en) * 2018-03-28 2018-09-28 天长市蓝天复合材料有限公司 A kind of anti slip glass steel grating and preparation method
CN109135071A (en) * 2018-07-03 2019-01-04 佛山国科科丽宝橡胶制品有限公司 A kind of rubber floor covering material and the preparation method and application thereof adding core-shell structure fire retardant
CN109535576A (en) * 2018-12-28 2019-03-29 扬州华通橡塑有限公司 A kind of ethylene propylene diene rubber environmental protection flame retardant sizing material and preparation method thereof
CN110003575A (en) * 2019-02-22 2019-07-12 安徽立信橡胶科技有限公司 A kind of ethylene propylene diene rubber of halogen-free flameproof

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EP0230564A1 (en) * 1985-12-02 1987-08-05 Bando Chemical Industries, Ltd. Rubber Flooring
CN1168393A (en) * 1996-05-27 1997-12-24 来安县亨通橡塑制品有限公司 Fireproof rubber floor and its production process
CN1327004A (en) * 2001-07-02 2001-12-19 汪正红 Colour elastic anti-slip rubber floor tile and its preparing method
CN1827675A (en) * 2005-03-01 2006-09-06 恒昌(昆山)精密模具有限公司 High-strength wearable floor rubber and process for preparing same
CN101230159A (en) * 2007-12-30 2008-07-30 郝玉寿 Environment-friendly type flame-retardant rubber floor and production method thereof
CN101260205A (en) * 2008-04-21 2008-09-10 兰斯登(福建)科技建材有限公司 Rubber floor capable of releasing negative oxygen ion and manufacturing method thereof
CN101356227A (en) * 2005-09-21 2009-01-28 卡尔弗罗伊登柏格两合公司 Rubber compound
JP2009184184A (en) * 2008-02-05 2009-08-20 Bando Chem Ind Ltd Sheet-like rubber floor material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0230564A1 (en) * 1985-12-02 1987-08-05 Bando Chemical Industries, Ltd. Rubber Flooring
CN1168393A (en) * 1996-05-27 1997-12-24 来安县亨通橡塑制品有限公司 Fireproof rubber floor and its production process
CN1327004A (en) * 2001-07-02 2001-12-19 汪正红 Colour elastic anti-slip rubber floor tile and its preparing method
CN1827675A (en) * 2005-03-01 2006-09-06 恒昌(昆山)精密模具有限公司 High-strength wearable floor rubber and process for preparing same
CN101356227A (en) * 2005-09-21 2009-01-28 卡尔弗罗伊登柏格两合公司 Rubber compound
CN101230159A (en) * 2007-12-30 2008-07-30 郝玉寿 Environment-friendly type flame-retardant rubber floor and production method thereof
JP2009184184A (en) * 2008-02-05 2009-08-20 Bando Chem Ind Ltd Sheet-like rubber floor material
CN101260205A (en) * 2008-04-21 2008-09-10 兰斯登(福建)科技建材有限公司 Rubber floor capable of releasing negative oxygen ion and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106987028A (en) * 2017-04-25 2017-07-28 江苏昌达环保科技有限公司 A kind of composition, fireproof rubber floor and preparation method for improving rubber oxygen index (OI)

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Owner name: JIANGSU CHANGDA ECO-TECHNOLOGIES CO., LTD.

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Address after: Double high road Cooperstown District of Nanjing city in Jiangsu province Gaochun 211000 No. 86-14

Patentee after: Jingsu Changda Eco-technologies Co., Ltd.

Address before: 213033 Jiangsu city of Changzhou province river town New District Huagang Road No. 9

Patentee before: Changzhou Changda Rail Equipment Co.,Ltd.

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