CN102058488A - Low-pressure type propellant and application thereof - Google Patents
Low-pressure type propellant and application thereof Download PDFInfo
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- CN102058488A CN102058488A CN 201010542492 CN201010542492A CN102058488A CN 102058488 A CN102058488 A CN 102058488A CN 201010542492 CN201010542492 CN 201010542492 CN 201010542492 A CN201010542492 A CN 201010542492A CN 102058488 A CN102058488 A CN 102058488A
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Abstract
The invention discloses a low-pressure type propellant which is formed by separated acid source and gas source, wherein the acid source is one or more of citric acid, crylic acid, tartaric acid, fumaric acid, adipic acid and malic acid, and the gas source is one or more of sodium carbonate, sodium bicarbonate, potassium bicarbonate and calcium carbonate. The application of the low-pressure type propellant can be used for daily chemicals comprising mousse, hair spray, unhairing articles, mosquitoes-dispelling articles, aerosol-type sunscreen articles, hidroschesis spray, aerosol-type shaving foam and foot spray. The invention also discloses a low-pressure mousse comprising a low-pressure type propellant and a hair processing composition. The invention broadens the service range and reduces the energy consumption of the aerosol-type product, reduces air pollution and improves the efficiency of the aerosol-type product.
Description
Technical field
The present invention relates to a kind of propellant, particularly a kind of low-pressure type propellant and application thereof.
Background technology
Mousse is configured for typing, settles and arranges purpose, perhaps is used for other as cleaning, conditioning, nursing, painted purpose, and the purpose of their combination.Hands that mousse can be by user or the comb that is designed for this purpose are smeared in hair and are applied on the hair.The main aspect that mousse arouses attention is to be easy to use and can control the amount and the distribution of product.
In the art, mouse compositions usually and compressed propellant formulated together and be packaged in during withstand voltage high-pressure type packs, this packing is furnished with for example compressible allotter, nozzle or valve.The selection of known propellant type and amount can influence foamy feature.
For improving the propellant that good foam is inclined to use, flammable usually high as LPG and dimethyl ether, dangerous for user.And the withstand voltage packing that is used for containing compressed propellant is very expensive, needs special steps in process of production.This improves product cost.And withstand voltage packing can not be filled once more by consumer, and is difficult in and reuses in the industry or circulate, and considers not preferred this method from environmental angle.
Mentioned the trial of the mouse compositions that no compressed propellant is provided in this area.But do not have the product that compressed propellant can obtain the bad and poor stability of foam usually, the result obtains being difficult to control the product of consumption and distribution on the hair.
Based on the above, therefore need a kind of compressed propellant that do not comprise, the mouse compositions of the good foaming feature that is obtained by the mouse compositions that comprises compressed propellant still can be provided usually.
Summary of the invention
In order to solve above-mentioned the deficiencies in the prior art part, the object of the present invention is to provide a kind of low-pressure type propellant.
Purpose of the present invention is achieved through the following technical solutions:
A kind of low-pressure type propellant is made of acid source separated from one another, source of the gas, and wherein acid source is one or more in citric acid, acrylic acid, tartaric acid, fumaric acid, adipic acid, the malic acid; Source of the gas is one or more in sodium carbonate, sodium bicarbonate, potassium bicarbonate, the calcium carbonate.
Described low-pressure type propellant is in the middle application of household chemicals.
Described household chemicals comprises hair mousse, hair spray, depilation articles for use, mosquito repellant product, aerosol-type sunscreen, hidroschesis spray, aerosol shaving foam, foot spray.
A kind of low pressure mousse comprises low-pressure type propellant and Hiar treatment compositions.
Described Hiar treatment compositions comprises water and at least a water-soluble fixed polymer that maybe can be scattered in the water, and wherein the mass fraction of fixed polymer accounts for 0.1%～40% of compositions.
The fixed polymer mass fraction that described water soluble maybe can loose in water accounts for 0.1%～30% of compositions.
But described fixed polymer is the polymer with anionic group or anionizable group, the polymer with cation group or cationizable groups, amphion and/or amphiphilic polymers, non-ionic polymers,
But the polymer that wherein has anionic group or anionizable group is selected from the homopolymer of acrylic or methacrylic acid or their salt or copolymer, the copolymer of .beta.-methylacrylic acid, single unsaturated C4-C8 carboxylic acid or the copolymer of anhydride, the polyacrylamide with carboxylic acid ester groups, the polymer with sulfonic acid group, anion polyurethanes, anionic grafting siloxane polymer;
Polymer with cation group or cationizable groups is selected from cationic polymer and is selected from: the polymer, cationic polysaccharides, vinyl pyrrolidone, vinyl imidazole base polymer, the chitosan that contain the amide of amido functional group;
Amphion and/or amphiphilic polymers be selected from acid vinyl units and alkaline vinyl units copolymer, polyaminoamide, have the unitary polymer of amphion, polymer, (C1-C5) alkyl vinyl ether and the copolymer of maleic anhydride, amphoteric polyurethanes, amphoteric grafted silicone polymer derived from chitosan;
Non-ionic polymers is selected from the homopolymer of the homopolymer of poly-alkylated oxazoline quinoline, vinyl acetate or copolymer, acrylate or copolymer, copolymer, styrene homopolymers or copolymer, the polyamide of acrylonitrile, the vinylamide homopolymer that is different from the vinyl pyrrolidone homopolymer, vinyl lactam copolymer, non-ionic polyurethanes, non-ionic grafted silicone polymer.
Described Hiar treatment compositions also comprises one or more of following material in addition: the loose siloxanes of form of solvable, dispersion or differential, handle activating agent, wetting agent, ultraviolet screening agent, acid, alkali, plasticizer, solubilizer, antiseptic, vitamin, provitamin, coloring agent, pigment, surfactant, spice, slow releasing agent.
The present invention has widened the scope of application of aerosol products.With sun-proof mousse is example, and its content is typical emulsion, and its pluses and minuses and emulsion are close.Its major advantage is to carry with easy to use, but when using by the sea, sunshine high temperature, container inner pressure increases, and may cause danger.Equally, the mousse series products also was restricted in summer or torrid areas use.Patent of the present invention can address this problem preferably.
Reduce the energy consumption of aerosol-type product, reduce air pollution.Aerosol-type product energy consumption in system filling process is bigger, and the propellant liquefied petroleum gas also is a fuel, so energy consumption is big than other products in the whole process of production.Aerosol products discharges the organic compound steam to air in use in addition, and air is polluted.Adopt the present invention not only can effectively reduce the energy consumption of aerosol products, can also reduce the production process pollution on the environment.
Can improve the efficient of aerosol-type product.The withstand voltage packing that aerosol products is used for containing compressed propellant is very expensive, needs special steps in process of production.This improves product cost.And withstand voltage packing can not be filled once more by consumer, and is difficult in and reuses in the industry or circulate.Adopt the present invention can reduce the production cost of aerosol products, enhance productivity greatly.
The specific embodiment
Low pressure mousse embodiment one:
45 gram saturated solution of sodium bicarbonate and citric acids, 50 grams are pulverized in the A packing of packing into, and citric acid is by the container and the sodium bicarbonate isolation of liquid permeable, and propanoic acid acid esters solution is packed in the container B, and A has conduit to lead among the B.When using this product, shake body earlier, sodium bicarbonate solution contacts with citric acid, and the great amount of carbon dioxide gas of generation communicates with acrylate solution by conduit.When opening nozzle group valve, the ejection of carbon dioxide gas compressing product, and form the mousse shape.
Table 1
Aerosol embodiment
45 gram saturated solution of sodium bicarbonate and citric acids, 50 grams are pulverized in the A packing of packing into, and citric acid is by the container and the sodium bicarbonate isolation of liquid permeable, and aerosol substrate is packed in the container B, and A has conduit to lead among the B.When using this product, shake body earlier, sodium bicarbonate solution contacts with citric acid, and the great amount of carbon dioxide gas of generation communicates with substrate by conduit.When opening nozzle group valve, the ejection of carbon dioxide gas compressing product, and form spray form.
Table 2
The foregoing description is a preferred implementation of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (8)
1. low-pressure type propellant, it is characterized in that: it is made of acid source, source of the gas, and wherein acid source is one or more in citric acid, acrylic acid, tartaric acid, fumaric acid, adipic acid, the malic acid; Source of the gas is one or more in sodium carbonate, sodium bicarbonate, potassium bicarbonate, the calcium carbonate.
2. according to the application of the described low-pressure type propellant of claim 1 in household chemicals, medicine, coating, adhesive.
3. according to the application of the described low-pressure type propellant of claim 2 in household chemicals, medicine, coating, adhesive, it is characterized in that: household chemicals comprises hair mousse, hair spray, depilation articles for use, mosquito repellant product, aerosol-type sunscreen, hidroschesis spray, aerosol shaving foam, foot spray.
4. a low pressure mousse is characterized in that: comprise low-pressure type propellant and Hiar treatment compositions.
5. according to the described a kind of low pressure mousse of claim 4, it is characterized in that: described Hiar treatment compositions comprises water and at least a water-soluble fixed polymer that maybe can be scattered in the water, and wherein the mass fraction of fixed polymer accounts for 0.1%～40% of compositions.
6. according to the described a kind of low pressure mousse of claim 5, it is characterized in that: the water-soluble fixed polymer mass fraction that maybe can loose in water accounts for 0.1%～30% of compositions.
7. according to the described a kind of low pressure mousse of claim 5, it is characterized in that: but fixed polymer is selected from the polymer with anionic group or anionizable group, the polymer with cation group or cationizable groups, amphion and/or amphiphilic polymers, non-ionic polymers
But the polymer that wherein has anionic group or anionizable group is selected from the homopolymer of acrylic or methacrylic acid or their salt or copolymer, the copolymer of .beta.-methylacrylic acid, single unsaturated C4-C8 carboxylic acid or the copolymer of anhydride, the polyacrylamide with carboxylic acid ester groups, the polymer with sulfonic acid group, anion polyurethanes, anionic grafting siloxane polymer;
Polymer with cation group or cationizable groups is selected from cationic polymer and is selected from: the polymer, cationic polysaccharides, vinyl pyrrolidone, vinyl imidazole base polymer, the chitosan that contain the amide of amido functional group;
Amphion and/or amphiphilic polymers be selected from acid vinyl units and alkaline vinyl units copolymer, polyaminoamide, have the unitary polymer of amphion, polymer, (C1-C5) alkyl vinyl ether and the copolymer of maleic anhydride, amphoteric polyurethanes, amphoteric grafted silicone polymer derived from chitosan;
Non-ionic polymers is selected from the homopolymer of the homopolymer of poly-alkylated oxazoline quinoline, vinyl acetate or copolymer, acrylate or copolymer, copolymer, styrene homopolymers or copolymer, the polyamide of acrylonitrile, the vinylamide homopolymer that is different from the vinyl pyrrolidone homopolymer, vinyl lactam copolymer, non-ionic polyurethanes, non-ionic grafted silicone polymer.
8. according to the described a kind of low pressure mousse of claim 4, it is characterized in that: Hiar treatment compositions also comprises one or more of following material in addition: the loose siloxanes of form of solvable, dispersion or differential, handle activating agent, wetting agent, ultraviolet screening agent, acid, alkali, plasticizer, solubilizer, antiseptic, vitamin, provitamin, coloring agent, pigment, surfactant, spice, slow releasing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010542492 CN102058488A (en) | 2010-11-11 | 2010-11-11 | Low-pressure type propellant and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010542492 CN102058488A (en) | 2010-11-11 | 2010-11-11 | Low-pressure type propellant and application thereof |
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| CN102058488A true CN102058488A (en) | 2011-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010542492 Pending CN102058488A (en) | 2010-11-11 | 2010-11-11 | Low-pressure type propellant and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102600049A (en) * | 2012-03-22 | 2012-07-25 | 徐克之 | Medical unhairing spray and purpose of medical unhairing spray |
| CN104812376A (en) * | 2012-09-27 | 2015-07-29 | Msd消费保健品公司 | Foaming skincare formulations |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119935A (en) * | 1994-05-07 | 1996-04-10 | 孙爱斌 | Mousse products without pressure |
-
2010
- 2010-11-11 CN CN 201010542492 patent/CN102058488A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119935A (en) * | 1994-05-07 | 1996-04-10 | 孙爱斌 | Mousse products without pressure |
Non-Patent Citations (2)
| Title |
|---|
| 《中国化妆品》 19991231 汪伟 水摩丝-未来摩丝的发展趋势 36-37 1-8 , 第3期 2 * |
| 《日用化学品科学》 19961231 刘创 喷雾摩丝 21 1-8 , 第6期 2 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102600049A (en) * | 2012-03-22 | 2012-07-25 | 徐克之 | Medical unhairing spray and purpose of medical unhairing spray |
| CN104812376A (en) * | 2012-09-27 | 2015-07-29 | Msd消费保健品公司 | Foaming skincare formulations |
| EP2900218A4 (en) * | 2012-09-27 | 2016-04-06 | Bayer Consumer Care Holdings Llc | Foaming skincare formulations |
| US10179094B2 (en) | 2012-09-27 | 2019-01-15 | Bayer Healthcare Llc | Foaming skincare formulations |
| TWI679024B (en) * | 2012-09-27 | 2019-12-11 | 瑞士商拜耳保健消費品股份有限公司 | Foaming skincare formulations |
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Application publication date: 20110518 |