201231069 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種整髮劑用喷霧化妝品。更詳細而言， 本發明係關於一種為凝膠狀之組合物且以霧狀喷出而使用 之整髮劑用喷霧化妝品。又，本發明係關於一種使用上述 整髮劑用喷霧化妝品之整髮劑。 【先前技術】 作為可對毛髮廣範圍且均勻地塗佈，並且抑制塗佈後之 自毛髮之滴落，進而亦提高使用感之化妝品’先前有將凝 膠狀之組合物填充於泵容器等化妝品用喷霧容器中，喷出 為霧狀之形態之噴霧化妝品（例如參照專利文獻丨〜3)。 上述形態之噴霧化妝品可提高使用感。然而，若為賦予 充分之整髮力而將通用之形成皮膜之聚合物等定型劑調配 於上述喷霧化妝品中’則於在毛髮上形成皮膜這一特性上 存在一旦進行整㈣無法再整髮之㈣。X，亦存在由長 期使用所致之噴出口之堵塞等問題。 ι 使用特定之油性成分而賦予上述喷霧化妝品 &髮效果。例如揭示有含有低結晶性纖維素、蠛類等聚氧 …土力成物及水’且為黏度為特定值以上之凝勝狀，於 ::時噴出為鉍密之霧狀而使用的凝膠狀毛髮化妝品(例 如參照專利文獻4)。 .、，、、而，即便依據上述嘗試， 達到獲得充分之整髮力之水準 化妝中，存在產生源自蠟類 與通常之整髮劑相比，仍未 。進而，於上述凝膠狀毛髮 等油性成分之黏腻感而使用 160552.doc 201231069 感惡化等問題'。 [先前技術文獻] [專利文獻] [專利文獻1]日本專利特開2005-53809號公報 [專利文獻2]曰本專利特開2007-204422號公報 [專利文獻3]曰本專利特開2009_191045號公報 [專利文獻4]日本專利特開2009-191046號公報 【發明内容】 [發明所欲解決之問題] 本發明係鑒於上述先前技術而完成者，其課題在於提供 一種整髮劑用喷霧化妝品，其係凝膠狀之組合物且以霧狀 喷出而使用，可廣範圍且均句地塗佈於毛髮上而不會滴 落，進而可無黏腻感地進行整髮，發揮整髮力與再整髮性 均優異之效果。又，本發明之課題在於提供―種使用上述 整髮劑用噴霧化妝品之整髮劑。 [解決問題之技術手段] 根據本發明之較廣之態樣，可提供一種整髮劑用喷霧仆 妝品，其係藉由泵式分注器或指扣式分注器（trigge ――以霧狀喷出而使用者，且為含有石夕酸針及疏冰 化石夕酸酐中之至4、】接 ^ _ 種、豕皂石族黏土礦物、及乙醇之淘 膠狀組合物。 :本發明之整髮劑用喷霧化妝品之某特定態樣中， 石族黏土礦物為鋰蒙脫石及皂石中之至少1種。 於本發明之整髮劑用喷霧化妝品之其他特定態樣中 160552.doc 201231069 述凝膠狀組合物100重量％中 量％ ο 上述乙醇之含量為20〜60質 於本發明之整髮劑用喷霧化妝品之另κ態樣中，上 述凝膠狀組合物含有多元醇。 、於本發明之整髮劑用喷霧化妝品之其他特定態樣中，上 述凝膠狀組合物含有覆膜形成劑。 一本發明之整髮劑包含含有泵式分注器或指扣式分注器之 容器、及填充於該容器内之上述整髮劑用噴霧化妝品。 [發明之效果] 本發明之整髮劑用喷霧化妝品係含有石夕酸野及疏水化矽 酸酐中之至少1種、蒙皂石族黏土礦物、&乙醇之凝膠狀 組合物，因此於藉由泵式分注器或指扣式分注器以霧狀喷 出而使用時，可廣範圍且均勻地塗佈於毛髮上而無滴落。 進而，本發明之整髮劑用喷霧化妝品可無黏腻感地進行整 髮’充分地發揮優異之整髮力’並且發揮再整髮性亦優異 之效果。 【實施方式】 本發明之整髮劑用喷霧化妝品係藉由泵式分注器或指扣 式分注器以霧狀喷出而使用。本發明之整髮劑用喷霧化妝 品係用作整髮齊:之喷霧化妝品。本發明之整髮劑用喷霧化 妝im可作為内容物填充於包含果式分注器或指扣式分注器 之容器内而較佳地使用。本發明之整髮劑用喷霧化妝品係 含有矽酸酐及疏水化矽酸酐中之至少1種（(A)成分）、蒙皂 石族黏土礦物（(B)成分）、及乙醇（(C)成分）之凝膠狀組合 160552.doc 201231069 物。本發明之整髮劑用嗔霧化妝品為凝膠狀。再者本發 月中之所a胃霧狀包含喷霧狀。本發明之整髮劑用喷霧化妝 品亦為整髮劑用霧狀化妝品。 又，於本發明之整髮劑用喷霧化妝品中，儘管調配有粉 體成分，但凝膠狀組合物之保存穩定性仍優異。本發明之 整髮劑用喷霧化妝品係含有矽酸酐及疏水化矽酸酐中之至 ;1種、蒙皂石族黏土礦物、及乙醇之凝膠狀組合物，因 此亦發揮即便長期使用亦可抑制喷出口之堵塞，持續維持 霧狀之喷出形態之效果。於本發明之整髮劑用喷霧化妝品 中，即便上述凝膠狀組合物含有下述覆膜形成劑，亦可抑 制因長期使用引起之喷出口之堵塞，持續維持霧狀之喷出 形態。 首先，對作為整髮劑用喷霧化妝品之凝膠狀組合物加以 說明》 作為上述（A)成分之石夕酸野及疏水化石夕酸酐中之至少丄種 係作為用以獲得可無黏腻感地進行整髮，具有優異之整髮 力’亦可進行再整髮之喷霧化妝品之成分而調配於上述凝 膠狀組合物中之粉體。 疏水化矽酸酐係矽酸酐之表面經疏水化處理之粉體。疏 水化處理中可使用各種處理劑。矽酸酐係並非疏水化石夕酸 酐之矽酸酐。矽酸酐係未經疏水化處理之矽酸酐。 作為疏水化處理中所使用之具體之處理劑，例如可列 舉：甲基三氣矽烷、二曱基二氣矽烷、三曱基氣矽烧、六 甲基二石夕氮烧、甲基三烧氧基石夕院、二曱基二貌氧基石夕 160552.doc 201231069 院-曱基烷氧基矽烷、乙基三氣矽烷、丙基三氣矽烷、 己基三氣矽烷、長鏈烷基三氣矽烷、乙基三烷氧基矽烷、 丙基二烷氧基矽烷、己基三烷氧基矽烷、長鏈烷基三烷氧 基矽烷、甲基丙烯醯基矽烷、氟烷基矽烷、全氟烷基矽烷 等有機矽烷基化合物；二甲基聚矽氧烷（聚矽氧油）、甲基 苯基聚碎氧院、甲基氫聚碎氧院、胺基改性聚⑦氧等聚石夕 氧化合物等。疏水化處理之方法並無特別限定，可採用公 知之方法。作為疏水化處理之方法，例如可例示：液相 法、氣相法、高壓釜法（autoclave method)等。 作為具體之疏水化矽酸酐，例如可例示：二曱基矽烷氧 基化矽酸酐、二甲基矽烷氧基化矽酸酐、辛基矽烷氧基化 矽酸酐、經聚矽氧油處理之矽酸酐、甲基丙烯醯基矽烷氧 基化矽酸酐等。 上述（A)成分可單獨使用1種，亦可適當組合2種以上而 使用。作為上述（A)成分，可僅使用矽酸酐，亦可僅使用 疏水化矽酸酐，還可使用矽酸酐與疏水化矽酸酐兩者。上 述（A)成分較佳為石夕酸酐，亦較佳為疏水化石夕酸酐。矽酸 酐可僅使用1種，亦可併用2種以上。疏水化石夕酸酐可僅使 用1種’亦可併用2種以上。就使噴霧化妝品充分地發揮整 髮力之觀點以及使更良好之再整髮亦成為可能之觀點而 言，上述矽酸酐及疏水化矽酸酐之下述吸油量（mL/丨〇〇 g) 較佳為下述下限以上，較佳為下述上限以下。 作為更具體之吸油量，矽酸酐及疏水化矽酸酐之每100 g之吸油量較佳為100 mL/100 g以上、更佳為150 mL/100 g 160552.doc 201231069 以上、進而較佳為200 mL/100 g以上，較佳為looo mL/i〇〇 g以下、更佳為800 mL/100 g以下、進而較佳為700 mL/100 g以下。石夕酸if及疏水化石夕酸針之每100 g之吸油量較佳為 100〜1000 mL/100 g之範圍内、更佳為150〜800 mL/100 g之 範圍内、進而較佳為200〜700 mL/100 g之範圍内。再者， 吸油量係依據JIS K5101中所記載之方法而測定之值。 再者，作為矽酸酐及疏水化矽酸酐，亦可直接使用市售 品。具體而言，作為矽酸酐之市售品，例如可例示： AEROSIL 50、90G、130、150、ί〇〇、300、380、200V、 OX50(商品名’均由 Nippon Aerosil 公司製造）；Sunsphere H-31、H-51、H-121、H-201、H-32、H-52、H-122、H- 33、Η-53(商品名，均由AGC Si-Tech公司製造）等。 作為二甲基石夕烧氧基化石夕酸酐之市售品，例如可例示： AEROSIL R972、R974、R9200(商品名，均由 Nippon Aerosil公司製造）等。 作為三甲基矽烷氧基化矽酸酐之市售品，例如可例示： AEROSIL RX200 ' R8200、RX300、R812S(商品名，均由201231069 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a spray cosmetic for hair styling. More specifically, the present invention relates to a spray cosmetic for hair styling which is a gel-like composition and which is sprayed in a mist form. Further, the present invention relates to a hair styling agent for a spray cosmetic using the above hair styling agent. [Prior Art] As a cosmetic which can coat a wide range of hair and uniformly, and suppress dripping from the hair after application, and further improve the feeling of use, a gel-like composition is previously filled in a pump container or the like. In a spray container for cosmetics, a spray cosmetic in a form of a mist is sprayed (for example, see Patent Document 丨3). The spray cosmetic of the above form can improve the feeling of use. However, if a styling agent such as a general-purpose film-forming polymer is blended in the above-mentioned spray cosmetic for imparting sufficient hair styling power, there is a problem that the film is formed on the hair once it is completely (four) cannot be re-formed. (4). X, there are also problems such as clogging of the discharge port caused by long-term use. ι The above-mentioned spray cosmetic & hair effect is imparted using a specific oily component. For example, it is disclosed that it contains a polycrystalline silicon such as a low crystalline cellulose, a hydrazine, or the like, and a water condensate having a viscosity of a specific value or more, and is condensed in a dense mist. A gel-like hair cosmetic (for example, refer to Patent Document 4). . . . , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Further, the problem of the deterioration of the oily component such as the gel-like hair is used. [Prior Art Document] [Patent Document 1] Japanese Patent Laid-Open Publication No. 2005-53809 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2007-204422 [Patent Document 3] Japanese Patent Laid-Open No. 2009-191045 [Problem to be Solved by the Invention] The present invention has been made in view of the above prior art, and an object of the invention is to provide a spray cosmetic for hair styling agents. It is a gel-like composition and is sprayed and used in a mist form, and can be applied to the hair in a wide range and uniformly, without dripping, and can be used for hair styling without stickiness. Both the force and the re-hairing are excellent. Further, an object of the present invention is to provide a hair styling agent which uses the above-mentioned spray cosmetic for hair styling agents. [Technical means for solving the problem] According to a broader aspect of the present invention, a spray servant for hair styling can be provided by a pump dispenser or a finger-type dispenser (trigge - It is sprayed in a mist and is used by the user, and is a toluene-like composition containing the aspartic acid needle and the ice-cold fossilic anhydride to 4, the _ species, the saponite clay mineral, and the ethanol. In a specific aspect of the spray cosmetic for hair styling of the present invention, the shale clay mineral is at least one of hectorite and saponite. Other specific states of the spray cosmetic for the hair styling agent of the present invention 160552.doc 201231069 The gel composition is 100% by weight of the medium amount ο The content of the above ethanol is 20 to 60. In the other κ aspect of the spray cosmetic of the hair dressing agent of the present invention, the above gelatinous form The composition contains a polyol. In other specific aspects of the spray cosmetic of the hair dressing of the present invention, the gel composition comprises a film forming agent. A hair dressing of the present invention comprises a pump dispensing. a container of a button or a dispenser, and the above-mentioned hair styling agent filled in the container Spraying Cosmetics. [Effects of the Invention] The spray cosmetic for hair styling of the present invention contains at least one of sulphuric acid and hydrophobic phthalic anhydride, a smectite clay mineral, and a gelled combination of ethanol Therefore, when it is used in a mist spray by a pump dispenser or a finger-type dispenser, it can be applied to the hair in a wide range and uniformly without dripping. Further, the hair of the present invention In the spray cosmetic, the hair styling agent can exhibit the effect of improving the hair styling ability and the hair styling property of the hair styling agent. It is used by spraying in a mist by a pump dispenser or a finger-type dispenser. The spray cosmetic for hair styling of the present invention is used as a hair spray cosmetic product. The hair styling agent of the present invention The spray makeup im can be preferably used as a content in a container containing a fruit dispenser or a button-type dispenser. The spray cosmetic of the hair conditioner of the present invention contains phthalic anhydride and is hydrophobized. At least one of phthalic anhydride ((A) component), smectite clay mineral a gel-like combination of (B) component) and ethanol ((C) component) 160552.doc 201231069. The hair styling agent of the present invention is gelatinized by a mist-foaming cosmetic. In the form of a spray, the sprayed cosmetic for hair styling of the present invention is also a cosmetic for hair styling. Further, in the spray cosmetic for hair styling of the present invention, although a powder component is formulated, The gel composition is excellent in storage stability. The spray cosmetic for hair styling of the present invention contains phthalic anhydride and hydrophobizic anhydride; one type, smectite clay mineral, and gel of ethanol In the spray cosmetic of the hair styling agent of the present invention, the gel composition is contained in the spray cosmetic of the present invention. The following film forming agent can also suppress the clogging of the discharge port due to long-term use and maintain the spray form of the mist. First, a gel-like composition for a spray cosmetic as a hair styling agent will be described as a non-sticky type of at least an anthraquinone of the above-mentioned (A) component It is a powder which is prepared by dispersing the whole hair and having an excellent hair styling ability, and can also be formulated into a gel composition in which the component of the spray cosmetic is re-formulated. Hydrophobized phthalic anhydride is a hydrophobized powder on the surface of phthalic anhydride. Various treatment agents can be used in the hydrophobization treatment. The phthalic anhydride is not a phthalic anhydride of hydrophobized fossilic anhydride. The phthalic anhydride is an anhydride which is not hydrophobized. Specific examples of the treatment agent used in the hydrophobization treatment include methyl trioxane, dimercapto dioxane, trimethyl sulfonium, hexamethyl diazepine, and methyl tricarbide. Oxygen stone Xiyuan, Diterpenoid dimorphic oxygen oxylithium 160552.doc 201231069 Institute - mercapto alkoxy decane, ethyl trioxane, propyl trioxane, hexyl trioxane, long chain alkyl trioxane , ethyl trialkoxy decane, propyl dialkoxy decane, hexyl trialkoxy decane, long chain alkyl trialkoxy decane, methacryl decyl decane, fluoroalkyl decane, perfluoroalkyl Organic sulfonyl compounds such as decane; dimethyl polyoxyalkylene (polyoxyxane), methyl phenyl polyoxynitride, methyl hydrogen polyoxychloride, amine modified poly 7 oxygen, etc. Compounds, etc. The method of the hydrophobization treatment is not particularly limited, and a known method can be employed. The method of the hydrophobization treatment may, for example, be a liquid phase method, a gas phase method, an autoclave method or the like. Specific examples of the hydrophobized phthalic anhydride include, for example, dimercaptodecyloxylated phthalic anhydride, dimethyl decyloxy phthalic anhydride, octyl decyloxy phthalic anhydride, and phthalic anhydride treated with polyoxy sulfonate. Methyl propylene decyl decyloxy phthalic anhydride or the like. The above component (A) may be used singly or in combination of two or more. As the component (A), only phthalic anhydride may be used, or only hydrophobized phthalic anhydride may be used, and both phthalic anhydride and hydrophobizic anhydride may be used. The above component (A) is preferably a rock anhydride, and is preferably a hydrophobic fossil anhydride. The phthalic anhydride may be used alone or in combination of two or more. The hydrophobized fossil anhydride may be used alone or in combination of two or more. The following oil absorption (mL/丨〇〇g) of the above-mentioned phthalic anhydride and hydrophobized phthalic anhydride is more effective in terms of making the spray cosmetic fully exerting the hair styling power and making it possible to make better re-hairing. It is preferably at least the lower limit described above, and preferably not more than the lower limit described below. As a more specific oil absorption amount, the oil absorption per 100 g of the phthalic anhydride and the hydrophobic phthalic anhydride is preferably 100 mL/100 g or more, more preferably 150 mL/100 g 160552.doc 201231069 or more, and further preferably 200. The mL/100 g or more is preferably less than the looo mL/i〇〇g, more preferably 800 mL/100 g or less, and further preferably 700 mL/100 g or less. The oil absorption per 100 g of the aspartic acid and the hydrophobic fossil acid acid needle is preferably in the range of 100 to 1000 mL/100 g, more preferably in the range of 150 to 800 mL/100 g, and further preferably 200. ~700 mL/100 g range. Further, the oil absorption amount is a value measured in accordance with the method described in JIS K5101. Further, as the phthalic anhydride and the hydrophobic phthalic anhydride, a commercially available product can be used as it is. Specifically, as a commercial product of phthalic anhydride, for example, AEROSIL 50, 90G, 130, 150, 〇〇, 300, 380, 200V, OX50 (trade names 'all manufactured by Nippon Aerosil Co., Ltd.); Sunsphere H can be exemplified; -31, H-51, H-121, H-201, H-32, H-52, H-122, H-33, Η-53 (trade names, all manufactured by AGC Si-Tech Co., Ltd.), and the like. For example, AEROSIL R972, R974, and R9200 (trade names, all manufactured by Nippon Aerosil Co., Ltd.) and the like can be exemplified as a commercially available product of dimethyl sulphate. As a commercial item of trimethyl decyloxy phthalic anhydride, for example, AEROSIL RX200 'R8200, RX300, R812S (trade names, by
Nippon Aerosil公司製造）等。 作為辛基矽烷氧基化矽酸酐之市售品，例如可例示 AEROSIL R805(商品名，Nippon Aerosil公司製造）等。 作為經聚矽氧油處理之石夕酸酐之市售品，例如可例示： AEROSIL R202、RY200、RY2〇〇S、RY3〇〇(商品名，岣由Nippon Aerosil company) and so on. As a commercial product of octyl decyloxy phthalic anhydride, for example, AEROSIL R805 (trade name, manufactured by Nippon Aerosil Co., Ltd.) or the like can be exemplified. As a commercial item of the polyoxyphthalic acid-treated oxalic anhydride, for example, AEROSIL R202, RY200, RY2〇〇S, RY3〇〇 (trade name, 岣 by 可)
Nippon Aerosil公司製造）等。 作為甲基丙烯醯基矽烧氧基化矽酸酐之市售品，例如可 160552.doc 201231069 例示AEROSIL R711 (商品名，Nippon Aerosil公司製造） 等。 石夕酸肝及疏水化石夕酸肝之整體之含量（(A)成分之含量）只 要可充分賦予所需之效果則無特別限定。通常，就可更加 無黏膩感地進行整髮，使喷霧化妝品充分地發揮整髮力之 觀點而5 ’上述凝膠狀組合物100質量％中，碎酸軒及疏 水化矽酸酐之整體之含量（(A)成分之含量）較佳為0.2質量％ 以上，更佳為0.5質量〇/〇以上。又，就使得使用感良好之觀 點而言，上述凝膠狀組合物1〇〇質量％中，矽酸酐及疏水 化矽酸酐之整體之含量（(A)成分之含量）較佳為1〇質量％以 下’更佳為5質量％以下。就該等觀點而f，上述凝膠狀 組合物100質量％中，矽酸酐及疏水化矽酸酐之整體之含 量（(A)成分之含量）較佳為〇2〜1〇ff%，更佳為〇5〜5質量 %。 蒙皂石族之層狀石夕酸鹽礦物。作為蒙矣石族黏土礦物，具 體而言，例如Μ示：蒙脫石、貝得石㈣eime)、綠脫 石（nontronite)，，皂石、鐘蒙 象脫石、矽鎂石、鋅蒙脫石 (sauconite)等。蒙皂石族 崤物可為天然物、源自天然 物之純化物及合成品中之任一 者，並無特別限定。又，於 本發明中，作為蒙皂 型陽雜早只而、 、黏土礦物，亦可使用經四級銨鹽 1陽離子界面活性劑處理 .L , 磯改性蒙皂石族黏土礦物。 作為上述四級銨鹽型陽雜 A-甲甚… 面活性劑’可列舉：氯化院 基二甲基鉍、氯化二烷基二 τ基叙、氣化苯二甲烴銨等。 J60552.doc 201231069 蒙皂石族㉟土礦#中含有上述有機改性蒙皂石族黏土礦 物。蒙皂石族黏土礦物可單獨使用丨種，亦可適當組合2種 以上而使用。就使保存穩定性良好之觀點而言，蒙皂石族 黏土礦物較佳為鋰蒙脫石及皂石中之至少【種。蒙皂石族 黏土礦物較佳為鋰蒙脫石，亦較佳為皂石。 再者，作為蒙皂石族黏土礦物，亦可直接使用市售品。 具體而δ，作為皂石之市售品，例如可例示μ (商品名’ KUNIMINE INDUSTRIES公司製造）；作為鐘蒙 脫石之市售品，例如可例示Lap〇nite XLG(商品名， LAPORTE公司製造）等。 蒙皂石族黏土礦物之含量只要可充分賦予所需之效果則 無特別限定。通常，就使保存穩定性良好之觀點而言上 述凝膠狀組合物100質量％中，蒙皂石族黏土礦物之含量 較佳為G.5質# %以上，更佳為1 f量％以上。又，就防止 堵塞之觀點而言，上述凝膠狀組合物1〇〇質量％中蒙皂 石族黏土礦物之含量較佳為1Qf量％以下，更佳為5質量％ 以下。就該等觀點而言，上述凝膠狀組合物ι〇〇質量％ 中，蒙皂石族黏土礦物之含量較佳為〇5〜1〇質量％， 為1〜5質量。/0。 ^佳 作為上述（C)成分之乙醇並無特別㈣，可使用能夠用 作化妝品原料之乙醇。乙醇之含量只要可充分賦予戶斤需之 效果則無特別限定。通常’就提高保存穩定性之觀點 言，上述凝膠狀組合物1〇〇質量％中，乙醇之含量而 2。質量%以上’更佳為25量%以上…就良好地維^ I60552.doc -10- 201231069 膠狀之觀點而言，上述凝膠狀組合物100質量％中，乙醇 之含量較佳為60質量❶/。以下，更佳為50質量％以下。就該 等觀點而言，上述凝膠狀組合物1 〇〇質量％中，乙醇之含 量較佳為20〜60質量。/〇’更佳為25〜50質量％。 於本發明中，就更良好地維持霧狀之噴出狀態並且防止 喷霧後之毛髮上之滴落之觀點而言，蒙皂石族黏土礦物 ((B)成分）與乙醇（(C)成分）之含量較佳為以質量含有比（(b) 成分之含量：（C)成分之含量）計為1:4〜1:4〇之範圍内，更 佳為1:7〜1:3 0之範圍内。 就進-步提高保存穩定性之觀點而言，上述凝膠狀组合 物較佳為含有多元醇（(D)成分）。藉由使上述凝膠狀組合： 含有多元醇，可進一步提高凝膠狀組合物之保存穩定性。 進而，可進-步提高抑料出口之堵塞，㈣料霧狀之 噴出形態之效果。 作為上述⑼成分之多⑽，例如可列舉：二醇類、甘 油類、糖醇等。作為多元醇，更具體而言，可例示：乙二 醇乙-冑-乙-醇、聚乙二醇、丙二醇、二丙二 :、聚丙二醇、異戊二醇、丨，3-丁二醇、U-丁二醇、12_ 戊一”己二醇、u_辛二醇ή 甘油、雙甘油、聚甘油等甘油類. 寺一醇類， 糖醇、甘露醇、山梨糖醇、赤;二糖酵、海藻糖、麥芽 醇、半乳糖醇、葡萄糖醇阿拉伯糖醇、核糖 單獨使用1種，亦可適當組合種^醇等° “醇可 m u上而使用。 就除提高保存敎性以外，亦可防止堵塞，持續維持霧 I60552.doc 201231069 狀之喷出形態之觀點而言，多 丙二醇、二丙二醇、13丁1:佳為選自聚乙二醇、 至少1種，其中爭社* 雙甘油之群中之 其中更佳為1，3-丁二醇及甘油中之至 述多元醇較佳種。上 一开权佳為1，3-丁二醇，亦較佳為甘油。 多元醇之含量只要可充分賦予 定。通當，兮组古ν 累之效果則無特別限 就k尚保存穩定性之觀點而+ 合物1。。質量❶/。中，多元醇之人晋二：’上述凝膠狀組 … 較佳為0.5質量％以上， 更佳為1質量％以上》又，就使 士 , 便用感良好之觀點而 吕’上述凝膠狀組合物i 〇〇質量〇/中 .1Λ@^0 貝®/οτ多π㉟之含量較佳Nippon Aerosil company) and so on. As a commercial product of methacrylonitrile oxime alkoxylated phthalic anhydride, for example, AEROSIL R711 (trade name, manufactured by Nippon Aerosil Co., Ltd.) or the like can be exemplified by 160552.doc 201231069. The content of the whole of the liver and the hydrophobized fossil liver (the content of the component (A)) is not particularly limited as long as the desired effect can be sufficiently imparted. In general, it is possible to carry out hair styling more without stickiness, and to make the spray cosmetic fully exert the hair styling power, and 5' of the above gel composition, 100% by mass of the gelatinous composition, and the whole of the hydrophobic acid anhydride The content (the content of the component (A)) is preferably 0.2% by mass or more, more preferably 0.5% by mass or more. In addition, in the gel composition of 1% by mass, the content of the entire phthalic anhydride and the hydrophobized phthalic anhydride (the content of the component (A)) is preferably 1 〇 by mass. % or less 'more preferably 5% by mass or less. In view of the above, in the 100% by mass of the gel composition, the content of the entire phthalic anhydride and the hydrophobized phthalic anhydride (the content of the component (A)) is preferably 〇2 to 1 〇 ff%, more preferably It is 5 to 5 mass%. A layered sulphate mineral of the smectite family. As a smectite clay mineral, specifically, for example, montmorillonite, beide stone (four) eime), nontronite, saponite, bell stone, sillimanite, zinc montmorillonite Stone (sauconite) and so on. The smectite family of the scorpion is not particularly limited as long as it is a natural product, a purified product derived from a natural product, and a synthetic product. Further, in the present invention, as the smectite type, the clay mineral may be treated with a quaternary ammonium salt 1 cation surfactant, and the sulphur-modified clay mineral of the smectite type. The above-mentioned quaternary ammonium salt type cation-containing A-methyl-... surfactant may be exemplified by chlorination of dimethyl hydrazine, chlorinated dialkyl bis thiol, and vaporized benzalkonium chloride. J60552.doc 201231069 The smectite family 35 earth mine # contains the above organic modified smectite clay mineral. The smectite clay minerals may be used singly or in combination of two or more. The smectite clay mineral is preferably at least one of hectorite and saponite from the viewpoint of good storage stability. The smectite clay mineral is preferably hectorite, and is preferably saponite. Further, as the smectite clay mineral, a commercially available product can also be used as it is. Specifically, as a commercially available product of saponite, for example, μ (trade name 'KUNIMINE INDUSTRIES CO., LTD.) can be exemplified, and as a commercial product of kiln stone, for example, Lap〇nite XLG (trade name, manufactured by LAPORTE Co., Ltd.) can be exemplified. )Wait. The content of the smectite clay mineral is not particularly limited as long as it can sufficiently impart the desired effect. In general, the content of the smectite-type clay mineral is preferably G.5 mass% or more, more preferably 1% by volume or more, in terms of 100% by mass of the gel composition. . In addition, the content of the smectite clay mineral in the gel composition of 1% by mass is preferably 1% by weight or less, more preferably 5% by mass or less. In view of the above, the content of the smectite clay mineral is preferably 〇5 to 1% by mass, and is 1 to 5 mass. /0. Preferably, the ethanol as the component (C) is not particularly (iv), and ethanol which can be used as a raw material for cosmetics can be used. The content of the ethanol is not particularly limited as long as it can sufficiently impart the effect required by the household. In general, in terms of improving storage stability, the gel composition is 1% by mass, and the content of ethanol is 2. The mass % or more is more preferably 25 % by mass or more. In terms of the gel form, the content of the ethanol is preferably 60% by mass in the above gel composition of 100% by mass. ❶/. Hereinafter, it is more preferably 50% by mass or less. In view of the above, the content of ethanol in the gel composition of 1% by mass is preferably 20 to 60% by mass. /〇' is more preferably 25 to 50% by mass. In the present invention, the smectite clay mineral ((B) component) and ethanol ((C) component) are more excellent in maintaining the spray state of the mist and preventing dripping on the hair after spraying. The content of the component is preferably in the range of 1:4 to 1:4, more preferably 1:7 to 1:3, in terms of the mass content ratio (the content of the component (b): the content of the component (C)). Within the scope. The gel composition preferably contains a polyol ((D) component) from the viewpoint of further improving storage stability. By combining the gels described above and containing a polyol, the storage stability of the gel composition can be further improved. Further, it is possible to further increase the clogging of the reject outlet, and (4) the effect of the spray-like form of the mist. The poly (10) component (10) may, for example, be a glycol, a glycerin or a sugar alcohol. As the polyol, more specifically, ethylene glycol ethyl hydrazine-ethyl alcohol, polyethylene glycol, propylene glycol, dipropylene di:, polypropylene glycol, isoprene glycol, hydrazine, 3-butanediol can be exemplified. , U-butanediol, 12_penta-hexanediol, u-octanediol glycerol, diglycerin, polyglycerol and other glycerol. Temple-alcohol, sugar alcohol, mannitol, sorbitol, red; Glycol, trehalose, maltitol, galactitol, glucosamine arabitol, and ribose may be used singly or in combination with an alcohol or the like. In addition to improving the preservation of sputum, it can also prevent clogging and maintain the fog. From the viewpoint of the spray pattern, polypropylene glycol, dipropylene glycol, and 13 butyl 1: preferably selected from polyethylene glycol, at least One of them is preferably one of 1,3-butanediol and glycerin as the preferred polyol in the group of diglycerides. The first one is preferably 1,3-butanediol, and is preferably glycerin. The content of the polyol can be sufficiently determined. The effect of the group 古 ν 无 无 无 无 无 无 无 无 无 无 + + + + + + + + + + + + + . Quality ❶ /. In the case of the polyol, the second group of the above-mentioned gel-like group is preferably 0.5% by mass or more, more preferably 1% by mass or more, and the above is a gelatinous appearance. Composition i 〇〇 mass 〇 / medium. 1 Λ @ ^ 0 ® / / / / / τ τ π π
為10質量％以下，更佳為sI 更佳為5質量％以下。就該等觀點而言， 於上述凝膠狀組合物100質量％中，多元醇之含量較佳為 〇.5〜10質量％，更佳為1〜5質量％。 就賦予喷霧化妝品整髮保持力之觀點而言，上述凝膠狀 組合物較佳為含有覆膜形成劑（⑻成分）。由於上述凝膠狀 組合物含有矽酸酐及疏水化矽酸酐、蒙皂石黏土礦物、及 乙醇，故而即便上述凝膠狀組合物含有覆膜形成劑，亦可 抑制喷出口之堵塞，並且獲得優異之整髮保持力。 上述覆膜形成劑只要可賦予優異之整髮保持力則無特別 限定。作為上述覆膜形成劑，例如可列舉：陰離子性覆膜 形成劑、陽離子性覆膜形成劑、兩性覆臈形成劑、非離子 性覆膜形成劑等。 作為具體之上述陰離子性覆膜形成劑，可例示：（曱基） 丙烯酸烷基酯共聚物、（甲基）丙烯酸/(甲基）丙烯酸烷基酯 共聚物、丙烯酸系樹脂烷醇胺、甲基乙烯基醚/順丁烯二 160552.doc 12 201231069 酸酯共聚物、乙酸乙烯酯/丁烯酸共聚物、乙酸乙烯酯/丁 烯酸/新癸酸乙烯酯共聚物、乙酸乙烯酯/丁烯酸/丙酸乙烯 酯共聚物、乙酸乙烯酯/順丁烯二酸單丁酯/丙烯酸異冰片 酯共聚物、丙烯酸/丙烯酸烷基酯/烷基丙烯醯胺共聚物、 聚乙烯基吡咯烷酮/丙烯酸酯/(甲基）丙烯酸共聚物、（笨乙 烯/丙烯酸烷基酯）共聚物、（苯乙烯/丙烯酸醯胺）共聚物、 胺基甲酸酯-丙烯酸系共聚物、聚苯乙烯績酸鈉等。再 者，於本說明書中，所謂「（曱基）丙烯醢基」，係表示「丙 烯醯基」及「甲基丙烯醯基」兩者。 作為具體之上述陽離子性覆膜形成劑，可例示：乙烯基 吡咯烷酮· Ν,Ν-二甲基胺基乙基甲基丙烯酸共聚物二乙基 硫酸鹽、氣化0-[2-羥基-3-(三曱基銨基）丙基]羥基乙基纖 維素、三氣化乙烯基咪唑鏽/乙烯基吡咯烷酮共聚物、羥 基乙基纖維素/二曱基二烯丙基氣化銨、聚乙烯基吡咯烷 酮/丙烯酸烷基胺基酯/乙烯基己内醯胺共聚物、氣化曱基 乙烯基咪唑鏽.乙烯基吡咯烷酮共聚物、（乙烯基吡咯烷 酮/二曱基胺基丙基甲基丙烯醯胺/月桂基二曱基胺基丙基 曱基丙烯醯胺）共聚物等》 作為具體之上述兩性覆膜形成劑，可例示：N-甲基丙烯 酿氧基乙基-N，N-二曱基録- (χ-Ν-甲基叛基甜菜驗·甲基丙 烯酸烷基酯共聚物、N，N-二甲基-N-(2-甲基丙烯醯氧基乙 基）胺=N-氧化物•甲基丙稀酸院基酯共聚物、丙烯酸經基 丙酯/甲基丙烯酸丁基胺基乙酯/丙烯酸辛基醢胺共聚物、 甲基丙烯酸二烷基胺基乙酯/曱基丙烯酸烷基酯共聚物之 160552.doc 13 201231069 一氣乙酸兩性化物、（異丁嫦/二乙基胺基丙基順丁稀二酿 亞胺/順丁烯二酸）共聚物等。 作為具體之上述非離子性覆膜形成劑，可例示：聚乙烯 基°比咯烧酮、乙烯基吡咯院酮/乙酸乙婦酯共聚物、乙烯 基吡咯烷酮/曱基丙烯醯胺/乙烯基咪唑共聚物、乙烯基曱 醚•順丁烯二酸乙酯共聚物、聚乙烯醇、聚乙烯基己内醯 胺等。 上述覆膜形成劑可單獨使用1種，亦可適當組合2種以上 而使用。就不易產生喷出口之堵塞，使喷霧化妝品發揮更 優異之整髮保持力之觀點而言，上述覆膜形成劑較佳為選 自陰離子性覆膜形成劑、非離子性覆膜形成劑及兩性覆膜 形成劑中之至少1種。其中，上述覆膜形成劑更佳為選自 丙烯酸系樹脂烷醇胺、乙烯基吡咯烷酮/甲基丙烯醯胺/乙 稀基味。坐共聚物、乙烯基吡咯烷酮/乙酸乙烯酯共聚物及 N，N-二甲基-N-(2-曱基丙烯醢氧基乙基）胺=N_氧化物•曱 基丙烯酸烷基酯共聚物中之至少1種。 上述覆膜形成劑之含量只要可充分賦予所需之效果則無 特別限定。通常，就賦予喷霧化妝品更良好之整髮保持力 之觀點而言’上述凝膠狀組合物1〇〇質量％中，上述覆膜 形成劑之含量較佳為〇.〇5質量％以上，更佳為〇丨質量％以 上。又，就防止堵塞之觀點而言，上述凝膠狀組合物1〇〇 質量％中，上述覆膜形成劑之含量較佳為1〇質量％以下， 更佳為5質量％以下。就該等觀點而|，上述凝膠狀組合 物議質量％中’上述覆膜形成劑之含量較佳為G.05〜1〇質 160552.doc 201231069 量％ ’更佳為0_ 1〜5質量％。 於上述凝膠狀組合物中，只要於無損本發明之效果之範 圍内，則除上述成分之以外亦可調配通常化粧品中所使用 之成77。例如可於上述凝膠狀組合物中根據目的而適當調 配磷酸及其鹽類、檸檬酸及其鹽類、乳酸及其鹽類、氫氧 化鈉、三乙醇胺等pH值調整劑；防腐劑、紫外線吸收劑、 保濕劑、著色劑、香料等。 上述凝膠狀組合物之製造方法並無特別限定，可藉由公 知之方法而製造。作為上述凝膠狀組合物之製造方法，例 如可例不添加上述成分，使用分散混合器、槳式混合器等 公知之混合裝置進行混合之方法等。但是，本發明並不僅 限定於上述製造方法。 又，上述凝膠狀組合物之稠度只要可使喷霧化妝品以霧 狀噴出則無特別限定。上述凝膠狀組合物之稠度較佳為5 gf以上、更佳為10 gf以上，較佳為1〇〇 #以下、更佳為 gf以下。上述凝膠狀組合物之稠度較佳為5〜1〇〇 gf之範圍 内，更佳為10-70 gf之範圍内。其理由在於，於上述稠度 未達5 gf之情形時’存在保存穩定性較差之傾向。又，於 上述稠度大於100 gf之情形時，不僅存在易產生噴出口之 堵塞之傾向，而且亦存在無法持續維持霧狀之喷出形態之 傾向。 再者’上述稠度可使用流變計（CR_5〇〇DX，SUN SCIENTIFIC公司製造）’於測定條件：25°c、適配器 (adapter): φ17 mm平型、衝程（stroke)2〇 mm之條件下測 160552.doc 201231069 心 本發明之整髮劑用喷霧化妝品係藉由栗式分注器或指扣 式分注器以霧狀喷出而使用。於使用本發明之整髮劑用喷 霧化妝品時，使用系式分注器或指扣式分注器使上述凝膠 狀組合物以霧狀喷出。 本發明之整髮劑包含含有泵式分注器或指扣式分注器之 容器、及填充於該容器内之本發明之整髮劑用喷霧化妝 =本發明之整髮劑中’本發明之整髮劑用喷霧化妝品 係填充於上述容器内之内容物。 藉由泵式分注器或指扣式分注器之一 霧的上述喷霧化妝„之哈屮*D 噴出步驟所喷 果之孴I! 要為可充分發揮所需之效 則無特別限定。就對毛髮廣範圍且均句地 佈:無滴落，且更絲腻感地進行整髮之觀點而言 :之喷出步驟所喷霧之上述嗔霧化妝品之喷出量二 =所1^下、更佳為G.5 mL/1次以下。藉由-次之t出步 •欠之r 2上述喷霧化妝品之喷出量較佳為0.05〜w — -人之範圍内，更佳為τ 又1圭為0.15〜〇·5 mL/1次之範圍内。 又’所使用之泵式分4 , 能之分…作為泵式二=“式分注器係具有嘴霧功 限定，可使用通常廣泛及指扣式分注器，並無特別 J使用通常廣泛通用之分 尚未廣泛制之新賴之亦可使用通常 而言，作為泵式分二器:指扣式分注器。具體 Y-150(按壓，次排出約〇15 ::野工業所公司製造之It is 10% by mass or less, more preferably sI is more preferably 5% by mass or less. In view of the above, the content of the polyhydric alcohol is preferably from 5% to 10% by mass, more preferably from 1 to 5% by mass, based on 100% by mass of the above gel composition. The gel composition preferably contains a film forming agent (component (8)) from the viewpoint of imparting hair styling retention to the spray cosmetic. Since the gel composition contains phthalic anhydride, hydrophobized phthalic anhydride, smectite clay mineral, and ethanol, even if the gel composition contains a film forming agent, clogging of the discharge port can be suppressed and excellent The hair is maintained. The film forming agent is not particularly limited as long as it can impart excellent hair styling retention. Examples of the film forming agent include an anionic film forming agent, a cationic film forming agent, an amphoteric coating forming agent, and a nonionic film forming agent. Specific examples of the anionic coating film forming agent include a (fluorenyl) alkyl acrylate copolymer, a (meth)acrylic acid/alkyl (meth) acrylate copolymer, an acrylic resin alkanolamine, and a Vinyl ether / maleate 160552.doc 12 201231069 acid ester copolymer, vinyl acetate / butenoic acid copolymer, vinyl acetate / butenoic acid / vinyl neodecanoate copolymer, vinyl acetate / butyl Acrylic acid/vinyl propionate copolymer, vinyl acetate/monobutyl maleate/isobornyl acrylate copolymer, acrylic acid/alkyl acrylate/alkyl acrylamide copolymer, polyvinylpyrrolidone/ Acrylate/(meth)acrylic acid copolymer, (stupid ethylene/alkyl acrylate) copolymer, (styrene/melamine acrylate) copolymer, urethane-acrylic copolymer, polystyrene Sodium and so on. In the present specification, the term "(fluorenyl) acrylonitrile" means both "propylene" and "methacryl". Specific examples of the above cationic film-forming agent include vinyl pyrrolidone oxime, fluorene-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, and gasification 0-[2-hydroxy-3. -(tridecylammonium)propyl]hydroxyethylcellulose, tri-vaporized vinylimidazole rust/vinylpyrrolidone copolymer, hydroxyethylcellulose/dimercaptopropylammonium vaporate, polyethylene Pyrrolidone/alkylamino acrylate/vinyl caprolactam copolymer, gasified mercapto vinyl imidazole rust. vinyl pyrrolidone copolymer, (vinyl pyrrolidone / dimercaptopropyl propyl methacrylate Amine/lauryl dimercaptopropyl propyl decyl acrylamide copolymer, etc. As a specific amphoteric film forming agent, N-methyl propylene ethoxyethyl-N, N-di曱基录- (χ-Ν-methyl-rebel beet test·alkyl methacrylate copolymer, N,N-dimethyl-N-(2-methylpropenyloxyethyl)amine=N -Oxide/Methyl acrylate acid ester copolymer, propyl acrylate / butyl methacrylate / octyl decyl amide copolymer , dialkylaminoethyl methacrylate / alkyl methacrylate copolymer 160552.doc 13 201231069 monogas acetic acid amphoteric, (isobutyl hydrazine / diethylamino propyl cis-butyl diimine /maleic acid) copolymer, etc. Specific examples of the above nonionic film forming agent include polyvinylpyrrolidone, vinylpyrrolidone/ethyl acetate copolymer, and vinyl Pyrrolidone / mercapto acrylamide / vinyl imidazole copolymer, vinyl oxime ether / ethyl maleate copolymer, polyvinyl alcohol, polyvinyl caprolactam, etc. The above film forming agent can be used alone One type may be used in combination of two or more kinds. The clogging of the discharge port is less likely to occur, and the coating film forming agent is preferably selected from the group consisting of anionic properties. At least one of a film forming agent, a nonionic film forming agent, and an amphoteric film forming agent. The film forming agent is more preferably selected from the group consisting of acrylic resin alkanolamines, vinylpyrrolidone/methacrylic acid. Indoleamine/ethylene-based flavor , vinylpyrrolidone/vinyl acetate copolymer and N,N-dimethyl-N-(2-mercaptopropenyloxyethyl)amine=N_oxide•alkyl methacrylate copolymer The content of the above-mentioned film forming agent is not particularly limited as long as the desired effect can be sufficiently imparted. In general, the above gel composition is provided from the viewpoint of imparting a better hair styling retention to the spray cosmetic. In the case of 1% by mass, the content of the film forming agent is preferably 5% by mass or more, more preferably 〇丨 by mass or more. Further, in view of preventing clogging, the above gel composition In the case of 1% by mass, the content of the film forming agent is preferably 1% by mass or less, more preferably 5% by mass or less. From the viewpoints of the above, the gel composition is considered to have the above-mentioned The content of the film forming agent is preferably G.05 〜1 〇 160 160552.doc 201231069 重量 % 'more preferably 0 _ 1 〜 5 mass %. In the above gel composition, as long as the effect of the present invention is not impaired, the film 77 used in the usual cosmetics may be blended in addition to the above components. For example, a pH adjusting agent such as phosphoric acid and a salt thereof, citric acid and a salt thereof, lactic acid and a salt thereof, sodium hydroxide or triethanolamine can be appropriately blended in the above gel composition according to the purpose; preservative, ultraviolet light Absorbents, moisturizers, colorants, perfumes, and the like. The method for producing the gel composition is not particularly limited, and it can be produced by a known method. As a method of producing the gel composition, for example, a method in which the above components are not added, and a known mixing device such as a dispersing mixer or a paddle mixer is used for mixing can be used. However, the present invention is not limited to the above manufacturing method. Further, the consistency of the gel composition is not particularly limited as long as the spray cosmetic can be sprayed in a mist form. The consistency of the gel composition is preferably 5 gf or more, more preferably 10 gf or more, and is preferably 1 〇〇 # or less, more preferably gf or less. The consistency of the above gel composition is preferably in the range of 5 to 1 〇〇 gf, more preferably in the range of 10 to 70 gf. The reason for this is that there is a tendency for poor storage stability when the above-mentioned consistency is less than 5 gf. Further, in the case where the consistency is more than 100 gf, there is a tendency that clogging of the discharge port is liable to occur, and there is a tendency that the spray form of the mist cannot be continuously maintained. Furthermore, 'the above consistency can be measured using a rheometer (CR_5〇〇DX, manufactured by SUN SCIENTIFIC)' under the conditions of 25 ° C, adapter: φ 17 mm flat, stroke 2 〇 mm. Measured 160552.doc 201231069 The spray cosmetic of the hair styling agent of the present invention is used by spraying in a mist form by a chest type dispenser or a button type dispenser. In the case of using the spray cosmetic for the hair dressing agent of the present invention, the gel composition is sprayed in a mist form using a system dispenser or a finger-type dispenser. The hair styling agent of the present invention comprises a container containing a pump dispenser or a finger-type dispenser, and a hair spray preparation of the hair styling agent of the present invention filled in the container; in the hair styling agent of the present invention The hair styling agent of the invention is filled with the contents of the container in a spray cosmetic. The above-mentioned spray makeup by one of the pump dispenser or the finger-type dispenser is not limited to the effect of the spray. From the point of view of the wide range of hair and the uniform distribution of the hair: no dripping, and more delicate feeling: the spray amount of the above-mentioned mist sprayed by the spray step is two = 1 ^下, more preferably G.5 mL / 1 time or less. By - second t step = owed r 2 The above spray cosmetic spray volume is preferably 0.05~w - in the range of people, more Jia is τ and 1 Gui is in the range of 0.15~〇·5 mL/1 time. Also 'the pump type used is 4, the energy can be divided as...The pump type 2=“The type of dispenser is limited by the nozzle mist It can be used in a wide range of general-purpose and button-type dispensers. It is not used in general. It is not widely used. It is not widely used. It can also be used as a pump-type splitter: a button-type dispenser. . Specific Y-150 (press, discharge approximately 〇15 :: manufactured by Nono Industrial Co., Ltd.
)、二谷閥門（MITANI 160552.doc -16- 201231069 VALVE)公司製造之Z_155(按壓！次排出約〇15 mL);作為 指扣式分注器’可例示：吉野工業所公司製造2M3_M。 次排出約0.5 mL)、三谷閥門（MITANI VALVE)公司製造之 Z-305、T-3 05(l 次排出約 〇.3 mL)等。 以下，基於實施例進一步詳細地說明本發明。本發明並 不僅限定於該等實施例。再者，調配量只要無特別記載， 則表示「質量％」。又，下述表3所示之_、㈣及※8) 之成分之調配量係換算為純分之量。 (試樣之製備1) 依據表1〜3所示之組成，製備實施例丨〜12及比較例丨〜6之 各凝膠狀組合物（整髮劑用喷霧化妝品）。使用所獲得之凝 膠狀組合物，針對下述各試驗例之評價項目進行評價◊將 結果示於表1〜3 再者，評價均係於23t、濕度6〇%之恆 溫恆濕之固定條件下實施。 (s式驗例1 :保存穩定性之評價） 將所製備之各凝膠狀組合物填充於容積6〇 mL2透明玻 璃今器中，於往復式恆溫槽（於5〜4〇〇c之範圍内變動（循環） 之恆溫槽）内保管1個月。依據下述評價基準對丨個月後之 透明玻璃容H中的凝膠狀組合物之「保存穩定性」進行目 視評價。 <保存穩定性之評價基準> 。：自剛製造後至保管後完全未確認到變化 △:於保管後確認到稍有分離等變化 X:於保管後確認到明顯之分離 160552.doc -17- 201231069 (試驗例2 :第1喷出形態之評價） 僅對實施例1〜6及比較例1〜6中所製備之凝膠狀組合物 價第1喷出形態β ° 將所製備之各凝膠狀組合物填充於包含泵式分注 器ΟΜ50,吉野工業所公司製造，喷出量為〇 i5 mL/^^ 壓）之容積50 „^之容器内，保管於4〇t之恆溫槽中，每: 重複下述操作，進行喷出（喷霧）形態之確認試驗。 自恆溫槽中取出試樣，立即進行1〇次喷出（喷霧）。噴出 (喷霧）後，將各試樣放回恆溫槽中，每天早晨、中午、 晚實施3次相同之試驗。重複實施該操作直至容器内之= 膠狀Μ合物完全消失為止或直至因堵塞等而變得無法噴出 (喷霧）為止。依據下述基準對喷出形態進行評價。 <第1喷出形態之評價基準> 〇 :於觀察期間内，喷出（喷霧）狀態上未見異常， 霧狀之形‘態 持 △:於觀察期間内，喷出（喷霧）狀態稍有變弱，但 霧狀之形態 無法塗佈，或無法以霧狀之形態喷出（喷霧），或者 於觀察期間内變得完全無法噴出 一 (§式驗例3 :塗佈性之評價） 。將所製備之各凝膠狀組合物填充於包含系式分注 器（Y-l5〇 ’吉野工業所公司製造，喷出量為〇 次按 壓）之容器中。繼而’讓20名官能評價員使用假髮（授課模 型mannequin) : YUKARI JApAN公司製造），藉由 160552.doc 201231069 喷霧將噴霧化妝品塗佈於毛髮上。依據下述評價基準對 「塗佈性」進行官能評價。 <塗佈性之評價基準> 〇 : 20名中16名以上回答可廣範圍且均勻地塗佈而無滴落 △ : 20名中1〇〜15名回答可廣範圍且均勻地塗佈而無滴落 X : 20名中9名以下回答可廣範圍且均勻地塗佈而無滴落 (試驗例4 :整髮時之評價） 試驗例3之評價後，讓相同之2〇名官能評價員以對毛髮 進行揉握之方式實施整髮，依據下述評價基準對整髮時之 「黏腻感」及「整髮力」進行官能評價。 再者，於「整髮力」之評價中，以對毛髮進行揉搓之方 式使其倒豎’將保持該倒豎形狀之情形判斷為整髮力較 高。 <黏腻感之評價基準> 〇 : 20名中16名以上回答無黏膩感 Δ : 20名中10〜15名回答無黏膩感 X : 20名中9名以下回答無黏腻感 <整髮力之評價基準> 〇 : 20名中16名以上回答整髮力較高 Δ : 20名中10〜15名回答整髮力較高 X : 20名中9名以下回答整髮力較高 (試驗例5 :再整髮時之評價）Z_155 manufactured by the company MITANI 160552.doc -16- 201231069 VALVE (pressing! The discharge is about 15 mL); as a button-type dispenser, it can be exemplified by 2M3_M manufactured by Yoshino Industrial Co., Ltd. About 0.5 mL of the discharge, Z-305 and T-3 05 manufactured by MITANI VALVE (1 time discharge about 〇.3 mL). Hereinafter, the present invention will be described in further detail based on examples. The invention is not limited to the embodiments. In addition, the amount of blending means "% by mass" unless otherwise specified. Further, the blending amounts of the components of _, (4), and *8) shown in Table 3 below are converted into pure fractions. (Preparation of Sample 1) Each of the gel compositions (spray cosmetics for hair dressings) of Examples 丨 to 12 and Comparative Examples 丨 to 6 was prepared in accordance with the compositions shown in Tables 1 to 3. The obtained gel-like composition was evaluated for the evaluation items of the following test examples, and the results are shown in Tables 1 to 3. Further, the evaluation was carried out under the conditions of constant temperature and humidity of 23 t and humidity of 6〇%. Implemented below. (s test example 1: evaluation of storage stability) Each of the prepared gel-like compositions was filled in a volume of 6 〇 mL 2 transparent glass, in a reciprocating thermostat (in the range of 5 to 4 〇〇c) The internal temperature change (cycle) is kept for 1 month. The "storage stability" of the gel composition in the clear glass volume H after one month was visually evaluated based on the following evaluation criteria. <Evaluation criteria for storage stability>. : No change was observed from the time of manufacture until storage. △: A slight separation was observed after storage. X: A clear separation was confirmed after storage. 160552.doc -17- 201231069 (Test Example 2: First discharge) Evaluation of morphology) Only the gel-like compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 6 were priced at the first discharge form β °, and each of the prepared gel-like compositions was filled in a pump-containing dispensing solution. ΟΜ50, manufactured by Yoshino Industrial Co., Ltd., with a discharge volume of 〇i5 mL/^^), in a 50 „^ container, stored in a 4 〇t thermostat, each: repeat the following operation to squirt (Spray) form confirmation test. Take out the sample from the constant temperature bath and immediately spray (spray) one time. After spraying (spraying), return each sample to the constant temperature bath every morning, noon. The same test was carried out three times in the evening. This operation was repeated until the gelatinous compound in the container completely disappeared or until it could not be ejected (sprayed) due to clogging or the like. Evaluation was performed. <Evaluation criteria of the first discharge form> 〇: Observed In the middle, there was no abnormality in the state of spray (spray), and the shape of the mist was Δ: during the observation period, the state of the spray (spray) was slightly weakened, but the form of the mist could not be coated. Or it may not be sprayed (sprayed) in the form of a mist, or it may become completely incapable of being ejected during the observation period (§ Example 3: Evaluation of coatability). Each gel composition prepared is filled. In the container containing the system-type dispenser (Y-l5〇 'Yoshino Industrial Co., Ltd., the amount of discharge is 〇), and then 'Let 20 evaluators use wigs (teaching model mannequin): YUKARI JApAN Manufactured, the sprayed cosmetic was applied to the hair by spraying with a spray of 160552.doc 201231069. The "coating property" was evaluated for the function according to the following evaluation criteria. <Evaluation Criteria for Applicability> 〇: 16 or more of the 20 respondents can be widely applied and uniformly coated without dripping Δ: 1 to 15 in 20 people can be widely and uniformly coated No dripping X: 9 out of 20 people can be widely and uniformly coated without dripping (Test Example 4: Evaluation at the time of hair styling) After the evaluation of Test Example 3, the same 2 官能 官能The evaluator performed hair styling by licking the hair, and evaluated the "stickiness" and "hair styling" at the time of hair styling according to the following evaluation criteria. Further, in the evaluation of the "finishing force", it is judged that the hair styling force is high in the case where the hair is rubbed in the manner of squatting the hair. <Evaluation criteria for sticky feeling> 〇: 16 out of 20 responded with no sticky feeling Δ: 10 out of 20 answered no sticky feeling X: 9 out of 20 answered no sticky feeling <Evaluation criteria for hair growth strength> 〇: 16 out of 20 responded to higher hair Δ: 20 out of 20 answered higher hair styling power X: 9 out of 20 responded to hair styling High force (test case 5: evaluation during re-issue)
自試驗例4之評價起1小日^ ^ A 〜1』日寻後，讓相同之20名官能評價員 160552.doc -19- 201231069 再次以對毛髮進行揉搓之方式實施整髮，依據卞述評價基 準對「再整髮性」進行官能評價。 <再整髮之評價基準> 〇 : 20名中16名以上回答可如願重新整髮 △ : 20名中1〇〜15名回答可如願重新整髮 X : 20名中9名以下回答可如願重新整髮 (試驗例6 :第2喷出形態之評價） 將所製備之各凝膠狀組合物在填充於包含泵式分注器 (Y15〇，吉野工業所公司製造，喷出量為0.15 mL/1次按 壓）之谷積50 mL的容器内之狀態下保管於40°C之恆溫槽 中每隔4天重複下述操作，進行喷出（喷霧）形態之確認試 驗。 自惶溫槽中取^ ψ q 4装 & 成樣’立即進行10次喷出（喷霧）。喷 (喷霧）後’將各試樣放回恒溫槽中，重複上述操作直至 内之凝膠狀組合物完全消失為止或直至因堵塞等而變 你诚喷出（噴霧）為止’進行喷出（喷霧）形態之確認試驗 依據下述基準對其噴出形態進行評價。 <第2噴出形態之評價基準> ο:於觀察期間内，喑 霧狀之形態、 0 t出（噴霧）狀態上未見異常，維 △:於觀察期間内 霧狀之形態 喷出（噴霧）狀態稍有變弱，但維持 x:無法塗佈， 於觀察期間内變得 或無法以霧狀之形態喷出（噴霧）， 元全無法噴出 或者 160552.doc •20- 201231069 (試驗例7 :整髮保持力之評價） 僅對實施例1〜12中所製備之凝膠狀組合物評價整髮保持 力。 將所製備之各凝膠狀組合物填充於包含泵式分注器（γ_ 15〇’吉野工業所公司製造，噴出量為〇15 mL/i次按壓）之 容積50 mLUII内。繼而’讓2G名官能評價員使用假髮 (授課模型：爾趟MPAN公司製造），藉由喷霧將喷霧 化妝品塗佈於毛髮上後，以對毛髮進行揉搓之方式實施整 髮。依據下述評價基準對「整髮保持力」進行官能評價。 再者，「錢㈣力」之評價係㈣毛髮進行揉握之方 式使其倒豎’將H、時後亦保持該倒暨形狀之 整髮保持力較高。 斯為 <整髮保持力之評價基準> 〇 : 20名中16名以上回答整髮保持力較高 △ : 20名中1〇〜15名回答整髮保持力較高 X : 20名中9名以下回答整髮保持力較高 將結果示於下述表1〜3。再者，實施们〜12中 喷霧化妝品之稠度（於上述測定條杜 寸 160552.doc •21 · 201231069 [表l] 實施例 1 2 3 4 5 6 矽酸酐※1 0.5 - - - - 1 矽酸酐※2 - 4 2 - - 1 三曱基矽烷氧基化矽酸酐※3 - 1 - 2.5 5 1 鋰蒙脫石※4 2 - 1.5 - 5 2 皂石※5 - '1.8 - 1 - 2 乙醇 25 50 35 25 40 35 1,3-丁二酵 - 1 - - 1.5 2.5 甘油 5 - 3 5 1.5 2.5 檸樣酸 0.05 - 0.05 - 0.1 0.1 純化水 剩餘部分 剩餘部分 剩餘部分 剩餘部分 剩餘部分 剩餘部分 合計 100 100 100 100 100 100 保存穩定性 〇 0 0 〇 〇 0 第1喷出形態 〇 〇 0 〇 〇 〇 第2喷出形態 〇 〇 〇 〇 〇 〇 塗佈性 〇 〇 〇 0 〇 0 黏腻感 〇 〇 〇 〇 〇 〇 整髮力 〇 〇 〇 〇 〇 〇 再整髮性 〇 〇 〇 〇 〇 〇 整髮保持力 〇 〇 0 〇 〇 0 22- 160552.doc 201231069 [表2] 比較例 1 2 3 4 5 6 矽酸酐※] - - - - 1 矽酸酐※2 - - 2 - - 1 三曱基矽烷氧基化矽酸酐※3 蜂 - 2.5 5 1 滑石 0.5 - - - - - 高嶺土 - 5 - - - - 鋰蒙脫石※4 2 - - - 2 皂石※5 - 1.8 - - - 2 羧乙烯聚合物 - - 0.5 - - - 丙烯酸•甲基丙烯酸烷基酯 - - - 2 - - 三乙醇胺 - - 0.5 0.5 - - 三仙膠 - - - 2 - 乙醇 25 50 35 25 40 - 1,3-丁二醇 - 1 - - 1.5 2.5 甘油 5 - 3 5 1.5 2.5 檸檬酸 0.05 - - - 0.1 純化水 剩餘部分 剩餘部分 剩餘部分 剩餘部分 剩餘部分 剩餘部分 合計 100 100 100 100 100 100 保存穩定性 〇 〇 〇 0 0 X 第1喷出形態 0 0 X X X 〇 第2喷出形態 0 〇 X X X 0 塗佈性 〇 〇 X X X Δ 黏腻感 Δ 〇 〇 Δ X X 整髮力 X X 0 〇 〇 〇 再整髮性 X X 〇 〇 0 0 -23· I60552.doc 201231069 [表3] 實施例 7 8 9 10 11 12 矽酸酐※1 0.5 - - - - 1 矽酸酐※2 - 4 2 - - 1 三甲基矽烷氧基化矽酸酐※3 - 1 - 2.5 5 1 鋰蒙脫石※4 2 - 1.5 - 5 2 皂石※5 - 1.8 - 1 - 2 乙醇 25 50 35 25 40 35 1，3-丁二醇 - 1 - - 1.5 2.5 甘油 5 - 3 5 1.5 2.5 丙烯酸系樹脂烷醇胺※6 5 - 1 - • 0.05 乙烯基吡咯烷酮/甲基丙烯醯胺/乙烯基 咪唑共聚物※7 - - - 0.5 0.2 0.1 Ν,Ν-二曱基-N-(2-甲基丙烯醯氡基乙基) 胺=N-氧化物•曱基丙烯酸烷基酯共聚 物※8 - 0.5 • 2 - - 檸檬酸 0.05 - 0.05 - 0.1 0.1 純化水 剩餘部 剩餘部 剩餘部 剩餘部 剩餘部 剩餘部 分 分 分 分 分 分 合計 100 100 100 100 100 100 保存穩定性 0 0 〇 〇 0 〇 第2噴出形態 〇 〇 〇 〇 〇 〇 塗佈性 〇 〇 〇 〇 0 〇 黏腺感 〇 〇 〇 〇 〇 〇 整髮力 〇 〇 〇 〇 0 0 再整髮性 0 〇 〇 〇 〇 〇 整髮保持力 〇 〇 〇 〇 0 〇 再者，於表1、表2及表3中，※1)〜※8)係表示以下成 分0 •24· 160552.doc 201231069 ※ 1) Sunsphere H-33(AGC Si-Tech公司製造） ※ 2) AEROSIL 300(Nippon Aerosil公司製造） ※ 3) AEROSIL R8200(Nippon Aerosil公司製造） ※ 4) Laponite XLG(LAPORTE公司製造） ※ 5) Sumecton SA(KUNIMINE INDUSTRIES公司製造） ※6) PLASCIZE L-6330(互應化學公司製造） ※7) Luviset Clear(BASF(巴斯夫）公司製造） ※8) Diaformer Z-711(三菱化學公司製造） 根據表1、表2及表3所示之結果，可知各實施例之凝膠 狀組合物（整髮劑用喷霧化妝品）發揮保存穩定性優異之效 果’因此可於凝膠狀組合物中穩定地調配粉體。又，亦可 知各實施例之整髮劑用喷霧化妝品即便長期使用亦無喷出 口之堵塞，持續維持霧狀之噴出形態。進而可知，各實施 例之整髮劑用喷霧化妝品可廣範圍且均勻地塗佈而無滴 落可無黏腻感地進行整髮，可充分發揮優異之整髮力， 且發揮再整髮性亦優異之效果。 可去相對於此，於將矽酸酐及疏水化矽酸酐替換為其 他柘體之比較例丨〜2中’本發明特有之整髮特性完全無法 ，得。又’可知於將㈣野及疏水切酸酐替換為通用於 製成通常之凝勝狀組合物之增黏劑的比較例 以霧狀噴出，因此枭 ‘，，、古 ，，、法句勻地塗佈’從而無法獲得優異之 堂髮力或再整性 進而，於未調配乙醇之比較例6中， 保存穩定性較差。 τ 進而 根據表3所示之結果 可知於含有覆膜形成劑之 160552.doc -25- 201231069 各實施例之凝膠狀纽合物（整髮劑用喷霧化妝品）中，即便 長期使用亦無喷出口之堵塞，持續維持霧狀之喷出形態。 又，亦知可保持實施有整髮之毛 整髮保持力。 毛髮之形狀，而發揮優異之 再者，於表1、3中，實施例⑷之整髮保持力之評價結 果均為「。」。但是，讓評價整㈣持力之相同之2g名官能 評價員利用上述整髮保持力之評價方法對實施例m實施 例7、實施例2與實施例8、實施例3與實施例9、實施例_ 實施例！〇、f施例5與實施仙、及實施例6與實施例。之 各凝膠狀組合物之整髮保持力進行評價而直接對比，結果 名中16名以上回答實施例7之整髮保持力較實施例丨優 異，回答實施例8之整髮保持力較實施例2優異，回答實施 例9之整髮保持力較實施例3優異，回答實施例1〇之整髮保 持力較實施例4優異，回答實施例u之整髮保持力較實施 例5優異，回答實施例12之整髮保持力較實施例6優異。 160552.doc 26-After the evaluation of the test example 4, 1 day ^ ^ A ~ 1』 After the day of the search, let the same 20 functional evaluators 160552.doc -19- 201231069 again perform the hair styling in the way of hair, according to the description The evaluation criteria were evaluated for "reproducibility". <Evaluation criteria for re-transformation> 〇: 16 or more of the 20 respondents can re-issue as usual. △: 20 out of 1 to 15 respondents can re-issue X: 20 out of 9 Re-shaping (Test Example 6: Evaluation of the second discharge form) Each of the prepared gel-like compositions was filled in a pump-containing dispenser (Y15〇, manufactured by Yoshino Industrial Co., Ltd., and the discharge amount was The following operation was repeated every 4 days in a thermostat bath of 40 ° C in a state of 50 mL of a container having a volume of 50 mL in a volume of 0.15 mL/1 press, and a discharge (spray) form confirmation test was performed. Take ψ q 4 from the 惶 惶 q 4 & sample ' immediately 10 sprays (spray). After spraying (spraying), put each sample back into the constant temperature bath, repeat the above operation until the gelatinous composition inside completely disappears, or until it is ejected (sprayed) due to clogging, etc. (Spray) Form Confirmation Test The discharge form was evaluated based on the following criteria. <Evaluation criteria of the second discharge form> ο: In the observation period, no abnormality was observed in the form of mist and the state of 0 t (spray), and the dimension Δ was sprayed in the form of mist during the observation period ( The state of the spray is slightly weaker, but it is maintained at x: it cannot be applied, and it may not be sprayed (sprayed) in the form of a mist during the observation period, and it is impossible to eject it or 160552.doc •20-201231069 (Test Example) 7: Evaluation of hair styling retention) Only the gel-like compositions prepared in Examples 1 to 12 were evaluated for hair styling retention. Each of the prepared gel-like compositions was filled in a volume of 50 mL UII containing a pump dispenser (manufactured by Yoshino Industrial Co., Ltd., with a discharge amount of mL15 mL/i). Then, the 2G-named evaluator was used to apply the wig (teaching model: manufactured by 趟 趟 MPAN Co., Ltd.), and the sprayed cosmetic was applied to the hair by spraying, and then the hair was smashed. The "main hair retention" was evaluated for the sensory according to the following evaluation criteria. In addition, the evaluation of "money (four) force" is based on (4) the way in which the hair is gripped, so that it is inverted, and the maintenance of the hair is maintained at a high level.斯为<Evaluation criteria for hair growth retention> 〇: 16 out of 20 responded to higher hair retention △: 20 out of 1 to 15 responded to higher hair retention X: 20 The results of the above nine responses to higher hair retention are shown in Tables 1 to 3 below. Furthermore, the consistency of the sprayed cosmetics of the above-mentioned 12 was carried out (in the above-mentioned measurement strip Du tong 160552.doc • 21 · 201231069 [Table 1] Example 1 2 3 4 5 6 phthalic anhydride*1 0.5 - - - - 1 矽Anhydride ※2 - 4 2 - - 1 Tridecyl alkoxylated phthalic anhydride ※3 - 1 - 2.5 5 1 Hectorite*4 2 - 1.5 - 5 2 Soapstone*5 - '1.8 - 1 - 2 Ethanol 25 50 35 25 40 35 1,3-butyrate - 1 - - 1.5 2.5 Glycerin 5 - 3 5 1.5 2.5 Lime acid 0.05 - 0.05 - 0.1 0.1 The remaining part of the remaining part of the remaining part of the purified water 100 100 100 100 100 100 Storage stability 〇0 0 〇〇0 1st discharge form 〇〇0 〇〇〇2nd discharge form〇〇〇〇〇〇Coating property〇〇〇0 〇0 Stickiness 〇 〇〇〇〇〇 发 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇〇 22 22 0 22-160552.doc 201231069 [Table 2] Comparative Example 1 2 3 4 5 6 phthalic anhydride ※] - - - - 1 phthalic anhydride ※2 - - 2 - - 1 tridecyl decyloxy phthalic anhydride ※3 Bee - 2.5 5 1 Stone 0.5 - - - - - Kaolin - 5 - - - - Hectorite ※4 2 - - - 2 Soapstone ※5 - 1.8 - - - 2 Carboxyrene polymer - - 0.5 - - - Acrylic • Methacrylic acid Alkyl ester - - 2 - - triethanolamine - - 0.5 0.5 - - Sanxianjiao - - - 2 - Ethanol 25 50 35 25 40 - 1,3-butanediol - 1 - - 1.5 2.5 Glycerin 5 - 3 5 1.5 2.5 Citric acid 0.05 - - - 0.1 Purified water remaining part remaining part remaining part remaining part remaining part total 100 100 100 100 100 100 Storage stability 〇〇〇0 0 X 1st ejection form 0 0 XXX 〇 2nd Spraying form 0 〇 XXX 0 Coating 〇〇 XXX Δ Stickiness Δ 〇〇 Δ XX Hair XX 0 〇〇〇 Re-hair XX 〇〇 0 0 -23· I60552.doc 201231069 [Table 3] Example 7 8 9 10 11 12 phthalic anhydride*1 0.5 - - - - 1 phthalic anhydride ※2 - 4 2 - - 1 trimethyl decyloxy phthalic anhydride ※3 - 1 - 2.5 5 1 hectorite ※ 4 2 - 1.5 - 5 2 Saponite ※5 - 1.8 - 1 - 2 Ethanol 25 50 35 25 40 35 1,3-Butanediol - 1 - - 1.5 2.5 Glycerin 5 - 3 5 1.5 2.5 Acrylic Resin alkanolamine *6 5 - 1 - • 0.05 vinylpyrrolidone / methacrylamide / vinyl imidazole copolymer *7 - - - 0.5 0.2 0.1 Ν, Ν-dimercapto-N-(2-methyl Propylene decylethyl)amine=N-oxide•alkyl methacrylate copolymer ※8 - 0.5 • 2 - - citric acid 0.05 - 0.05 - 0.1 0.1 Remaining part of the remaining part of the remaining part of purified water The remaining parts are divided into points and totals 100 100 100 100 100 100 Storage stability 0 0 〇〇0 〇 2nd ejection form 〇〇〇〇〇〇 coating property 〇〇〇〇 0 〇 sticky gland 〇〇〇〇〇 〇 发 发 0 0 0 re-sharpening 0 〇〇〇〇〇 hair styling retention 〇 0 〇 again, in Table 1, Table 2 and Table 3, *1) ~ ※ 8 ) indicates the following components: 0 • 24· 160552.doc 201231069 ※ 1) Sunsphere H-33 (manufactured by AGC Si-Tech) ※ 2) AEROSIL 300 (manufactured by Nippon Aerosil Co., Ltd.) * 3) AEROSIL R8200 (manufactured by Nippon Aerosil Co., Ltd.) ※ 4) Laponite XLG (manufactured by LAPORTE) ※ 5) Sumecton SA (KUNIMINE INDUSTRIES *6) PLASCIZE L-6330 (manufactured by Mutual Chemical Co., Ltd.) *7) Luviset Clear (manufactured by BASF) *8) Diaformer Z-711 (manufactured by Mitsubishi Chemical Corporation) According to Tables 1 and 2 As a result of the results shown in Table 3, it is understood that the gel composition (the spray cosmetic for hair styling) of each of the examples exhibits an effect of excellent storage stability. Therefore, the powder can be stably formulated in the gel composition. Further, it is also known that the spray cosmetic for hair dressings of the respective examples does not have a clogging of the discharge port even if it is used for a long period of time, and the spray form of the mist is continuously maintained. Further, it is understood that the spray cosmetic for hair styling of each of the examples can be applied in a wide range and uniformly, and can be hair-free without dripping, and can fully exert excellent hair styling power and perform hair styling. The effect is also excellent. In contrast, in the comparative example 丨~2 in which phthalic anhydride and hydrophobized phthalic anhydride were replaced with other steroids, the unique hair styling characteristic of the present invention was completely impossible. Further, it can be seen that a comparative example in which (4) wild and hydrophobic dianhydride are replaced with a tackifier which is generally used for forming a conventional condensed composition is sprayed in a mist, so that 枭',,,,,,,, The coating was not able to obtain excellent strength or re-formability, and in Comparative Example 6 in which ethanol was not formulated, the storage stability was poor. τ Further, according to the results shown in Table 3, it is known that the gel-like conjugate (spray cosmetic for hair styling) of each of the examples containing the film-forming agent of 160552.doc -25-201231069 is not used for a long period of time. The clogging of the discharge port continues to maintain the spray pattern of the mist. Moreover, it is also known that the hair styling ability can be maintained. Further, in Tables 1 and 3, the evaluation results of the hair styling retention power of Example (4) were all ".". However, the evaluation method of the above-mentioned hair styling retention is performed by the same evaluation method of the above-mentioned hair styling ability by the same evaluation method of Example 4, Example 2, Example 8, Example 3, and Example 9. Example _ Example!施, f Example 5 and implementation, and Example 6 and Examples. The hair styling retention of each of the gel-like compositions was evaluated and directly compared. In the results, 16 or more of the respondents answered that the hair styling retention power of Example 7 was superior to that of the Example ,, and the hair styling retention power of Example 8 was compared with that of the implementation. In the second example, the hair styling retention power of the ninth embodiment was superior to that of the third embodiment, and the hair styling retention power of the ninth embodiment was superior to that of the fourth embodiment, and the hair styling retention power of the ninth embodiment was superior to that of the fifth embodiment. The hair styling retention power of Example 12 was superior to that of Example 6. 160552.doc 26-