CN102057235A - Multi-refrigerant cooling system with provisions for adjustment of refrigerant composition - Google Patents

Multi-refrigerant cooling system with provisions for adjustment of refrigerant composition Download PDF

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Publication number
CN102057235A
CN102057235A CN2009801213784A CN200980121378A CN102057235A CN 102057235 A CN102057235 A CN 102057235A CN 2009801213784 A CN2009801213784 A CN 2009801213784A CN 200980121378 A CN200980121378 A CN 200980121378A CN 102057235 A CN102057235 A CN 102057235A
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CN
China
Prior art keywords
cold
refrigerant
flow point
cooling circuit
producing medium
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CN2009801213784A
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Chinese (zh)
Inventor
W·G·黑斯
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General Electric Technology GmbH
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Alstom Technology AG
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Publication of CN102057235A publication Critical patent/CN102057235A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/006Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B1/00Compression machines, plants or systems with non-reversible cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B45/00Arrangements for charging or discharging refrigerant
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0027Oxides of carbon, e.g. CO2
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • F25J1/0055Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0212Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a single flow MCR cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244Operation; Control and regulation; Instrumentation
    • F25J1/0245Different modes, i.e. 'runs', of operation; Process control
    • F25J1/0249Controlling refrigerant inventory, i.e. composition or quantity
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2345/00Details for charging or discharging refrigerants; Service stations therefor
    • F25B2345/004Details for charging or discharging refrigerants; Service stations therefor with several tanks to collect or charge a cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/20Processes or apparatus using other separation and/or other processing means using solidification of components
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/70Flue or combustion exhaust gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/80Separating impurities from carbon dioxide, e.g. H2O or water-soluble contaminants
    • F25J2220/82Separating low boiling, i.e. more volatile components, e.g. He, H2, CO, Air gases, CH4

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)
  • Cooling Or The Like Of Electrical Apparatus (AREA)

Abstract

A multi-refrigerant cooling system comprising a cooling circuit (100) for circulation of a refrigerant mixture. The cooling circuit comprises, i.a., one or more separator(s) (102, 103) configured to separate and withdraw a respective refrigerant fraction of the refrigerant mixture. Each separator is connected to a respective holding tank (201, 202). Each holding tank is further connected to the cooling circuit via a supply conduit (207), the supply conduit being configured to supply one or more refrigerant fraction(s) to the cooling circuit. Method for adjusting the composition of a refrigerant mixture of a multi-refrigerant cooling system. The method allows adjustment of the composition of the refrigerant mixture during operation of the multi-refrigerant cooling system.

Description

Many refrigerant cools system of the adjusting of cold-producing medium composition is provided
The cross reference of related application
The application requires the U.S. Provisional Patent Application No.61/058 of submission on June 5th, 2008,947 rights and interests, and this application is combined in herein by reference and integrally.
Invention field
The present invention relates to many refrigerant cools system (multi-refrigerant cooling system), and the method for composition (composition) that is used to regulate the refrigerant mixture of many refrigerant cools system.
Background
Many refrigerant cools system is former to be to be known that and to utilize the refrigerant mixture of two or more cold-producing mediums with different condensation temperatures to operate.Therefore, the mixture of cold-producing medium circulates in the cooling circuit of many refrigerant cools system.Many refrigerant systems are particularly useful for requiring in the commercial Application of low-down temperature.It is by making CO that a typical case uses 2Ice freezing (frost) and come from exhaust, to catch carbon dioxide (CO 2).
Many refrigerant cools system has disclosed in for example file US 7,073,348 and US 2006/0277942.Disclosed system operates according to the cooling principle that is called integrated cascade (integrated cascade).
In order to change the composition of refrigerant mixture, close many refrigerant cools system, empty its refrigerant mixture, and filling has the refrigerant mixture that expectation is formed again.
General introduction
Target of the present invention comprises: the possibility of reusing cold-producing medium when the composition that is provided at the refrigerant mixture of carrying out many refrigerant cools system is regulated; Provide the amount of the cold-producing medium that will during the composition of the refrigerant mixture of regulating many refrigerant cools system, be wasted to keep minimum possibility; And the possibility that is provided at the composition adjusting of the operating period execution refrigerant mixture that keeps many refrigerant cools system.
Regulate in conjunction with the composition of refrigerant mixture and to avoid or reduce that cold-producing medium from many refrigerant cools system is emitted on economic aspect and be important aspect the environment.In addition, allowing the composition at the operating period of many refrigerant cools system adjusting refrigerant mixture is important in operating aspect and at economic aspect.
In first aspect, realize above-mentioned target and other target by a kind of many refrigerant cools system, after the following description of research, these targets will become apparent those skilled in the art, this many refrigerant cools system comprises the cooling circuit of the circulation of the refrigerant mixture that is used to comprise two or more cold-producing mediums, and cooling circuit comprises: the compressor with entrance and exit; Be configured to separate and extract one or more separators of the corresponding cold-producing medium flow point of (withdraw) refrigerant mixture; And client computer (client), the outlet of compressor is connected on the client computer by (a plurality of) separator, wherein, each separator is connected on the corresponding storage tank by corresponding extraction pipeline, each storage tank is arranged to receive the corresponding cold-producing medium flow point (fraction) from its corresponding separator, wherein, each storage tank also is connected on the cooling circuit by supply line, and supply line is configured to supply one or more cold-producing medium flow points to cooling circuit.
Therefore, many refrigerant cools system of the adjusting of a kind of permission carries out its refrigerant mixture under advantage composition is provided.Particularly, can handle adjusting by the composition that changes the cold-producing medium admixture in operating period of cooling system about the environment temperature of the client computer temperature requirement that changes and/or variation.
As used herein, term " client computer " refer to along cooling circuit, treat article (item) by many refrigerant cools system cools.Except described herein, the detailed placement of cooling circuit or its operation principle are inessential for the purpose of the present invention.
The position that system can be included between (a plurality of) separator and the client computer is connected to other storage tank on the cooling circuit by other extraction pipeline, other storage tank is arranged to receive the cold-producing medium flow point from cooling circuit, wherein, other storage tank also is connected on the cooling circuit by supply line.Therefore, when regulating the composition of refrigerant mixture, can utilize the cold-producing medium flow point that after separator separates one or more other cold-producing medium flow points and extracts (a plurality of) storage tank subsequently, remains in the cooling circuit.
Supply line can be connected on the cooling circuit in the position between the inlet of client computer and compressor.The cold-producing medium flow point is typically remaining in its storage tank under the pressure of its corresponding separator or under lower slightly pressure.Because (a plurality of) separator typically belongs to the high-pressure side of cooling circuit, the position between the inlet of client computer and compressor advantageously, promptly on the low-pressure side of cooling circuit, this cold-producing medium flow point is fed to cooling circuit from its storage tank by supply line.Therefore, feasible is under the situation that does not have pump or other pressure regulating device or under the situation that still less needs pump or other pressure regulating device, and this cold-producing medium flow point is fed to cooling circuit.Therefore, system can be provided with (a plurality of) storage tank, this storage tank remains under the pressure between such pressure (that is, supply line is connected at this pressure) in such pressure in the cooling circuit (that is, corresponding cold-producing medium flow point is separated under this pressure) and the cooling circuit.
Each extracts pipeline and also can be connected on the enlarged portion (flare).If extracting flow point is undesirable on purity, then can from cooling circuit, remove this flow point, but not storage or/reuse this flow point.Therefore, can discard the cold-producing medium flow point of isolating and extracting of refrigerant mixture.This can pass to exit skirt by the cold-producing medium flow point that will isolate and extract and realize easily.
As an example, client computer can be the freezing container of carbon dioxide (carbon dioxide frosting vessel), and promptly wherein gaseous carbon dioxide is captured as the container of dry ice (carbon dioxide ice) at the low temperature place.Therefore, the present invention relates in addition and uses many refrigerant cools system to come the freezing container of cooled carbon dioxide as described above.
System can be configured to be controlled by control system.The control device that has the control signalling foundation structure (control signalling infrastructure) that is associated is careful amount in (keep track of) each storage tank by for example pressure sensor, and control device also can be careful the percentage of the various cold-producing mediums in the system by the multicomponent detector.Control device also according to refrigerant mixture required adjusting determine opening speed and opening the time (length) of different control valves.
In second aspect, the method for the composition by a kind of refrigerant mixture that is used to regulate many refrigerant cools system realizes some target of the present invention, said method comprising the steps of:
A) one or more flow points of extraction refrigerant mixture from many refrigerant cools system, described flow point has different cold-producing mediums and forms;
B) cold-producing medium stream is fed to many refrigerant cools system;
Make the composition of refrigerant mixture of many refrigerant cools system be adjusted to new composition, described new composition is different with the composition of cold-producing medium stream; And
C) at step a) and b) during, the refrigerant mixture of many refrigerant cools system is remained in the amount that allows the operation of many refrigerant cools system;
Thereby allow to regulate the composition of refrigerant mixture in the operating period of many refrigerant cools system.
At economic aspect and importantly avoiding aspect the environment or reducing discharging from the cold-producing medium of many refrigerant cools system in conjunction with the adjusting of the composition of refrigerant mixture.Therefore, can be stored in (multiple) flow point that extracts in the step a) one or more separately, all preferred.Store the flow point that extracts individually and help other processing, for example the flow point that extracts is reclaimed or recycles.Can discard (for example diffusing away (flare off)) not any flow point of storage.Typically can discard but not store the flow point that extracts, if this flow point undesirable words on purity.
In order not only to avoid or reduce the discharging of cold-producing medium, but also realize the end (closing) of expectation of the operation of many refrigerant cools process, the cold-producing medium stream of supplying in step b) can comprise one or more in (multiple) flow point of storage, preferably is made up of in (multiple) flow point of storage one or more.Therefore, (multiple) flow point that extracts from many refrigerant cools system can turn back to many refrigerant cools system, but so that amount and/or ratio that the composition of the refrigerant mixture of many refrigerant cools system changes.Be not from many refrigerant cools system, extract but typically be fed to many refrigerant cools system aptly in pure mode or with the part that the additional cold-producing medium (Make-up refrigerant) of the mixture supply of the composition set can be used as the cold-producing medium stream of step b) basically.
Typically, the operation of many refrigerant cools system comprises inherently and its refrigerant mixture is separated into fully (at large) different flow point corresponding to the corresponding cold-producing medium of refrigerant mixture.Therefore, valuably, the quantity of the flow point that extracts in step a) can be equal to or less than, preferably equal the quantity of the cold-producing medium in the refrigerant mixture of many refrigerant cools system.
Once in a while, can be useless is any flow point that extracts of storage refrigerant mixture, can be discarded in (multiple) flow point that extracts in the step a).As mentioned above, can diffuse away such (multiple) flow point.Can be one the reasonable quantity of the flow point that in step a), extracts in this case.But, but not from many refrigerant cools system, to extract typically basically in pure mode or with the part that the additional cold-producing medium of the mixture supply of the composition set can be used as the cold-producing medium stream of step b) to be fed to many refrigerant cools system.
The storage (a plurality of) flow point can remain on separately be in many refrigerant cools system such position (promptly, corresponding flow point is extracted in such position in step a)) pressure of the refrigerant mixture located and being under the pressure between the pressure of the refrigerant mixture of such position (that is, step b) is carried out in such position) of many refrigerant cools locating.Alternatively or additionally, such position of each comfortable many refrigerant cools system of (multiple) flow point that extracts in step a) is extracted, that is, in this position refrigerant mixture than at execution in step b) time the position of many refrigerant cools system be under the higher pressure.As the favourable outcome of as this paper suggestion, considering the pressure aspect, can be under the situation that does not have pump or other pressure regulating device, perhaps under the situation that still less needs pump or other pressure regulating device, can carry out the storage of the extraction of (multiple) flow point of refrigerant mixture, such (multiple) flow point and/or the supply of cold-producing medium stream.
As an example, but the freezing container of many refrigerant cools system cooled carbon dioxide, and promptly wherein gaseous carbon dioxide is captured as the container of dry ice at the low temperature place.
Description of drawings
Fig. 1 is the schematic diagram of many refrigerant cools system according to an embodiment of the invention.
Fig. 2 is the schematic diagram of another many refrigerant cools system according to an embodiment of the invention.
The specific embodiment
Described many refrigerant cools system in Fig. 1, it comprises the cooling circuit 100 of the circulation that is used for refrigerant mixture and is used to regulate the assembly 200 of the composition of refrigerant mixture.
Cooling circuit 100 comprises compressor 101, cold-producing medium separator 102 and 103 and client computer 104, and this client computer 104 is treated by many refrigerant cools system cools.The outlet of compressor 101 is connected on the client computer 104 by separator 102 and 103.Cooling circuit 100 also comprises the expansion mechanism 105,106 and 107 of the different flow points that are used for refrigerant mixture, and heat exchanger (condenser/evaporator) 108 and 109, their whole layouts become according to the cooling principle that is called integrated cascade to carry out the operation of cooling circuit.Shown in cooling circuit be designed for the refrigerant mixture of three components.Be stressed that the detailed placement of cooling circuit or its operation principle are not crucial for the purpose of the present invention.
The assembly 200 that is used for regulating the composition of refrigerant mixture comprises each the storage tank 201,202 and 203 that just is used for replenishing at the cold-producing medium of the refrigerant mixture of cooling circuit 100 circulations.Storage tank by corresponding valve 204,205 and 206 and supply line 207 be connected on the cooling circuit 100.(promptly on the low-pressure side at cooling circuit) is connected on the cooling circuit 100 supply line 207 in the position between the inlet of client computer 104 and compressor 101.Enlarged portion 208 is connected on the cooling circuit 100 by valve 209.
In Fig. 1, do not show the control device that has the control signalling foundation structure that is associated, this control device is careful amount in each storage tank 201,202 and 203 by pressure sensor, and the percentage of being careful the various cold-producing mediums in the refrigerant mixture of cooling circuit 100 by the multicomponent detector, and control valve 204,205,206 and 209.
For the composition of the refrigerant mixture of regulating cooling circuit 100, the cooling circuit part of refrigerant mixture that is cleared, and be filled with one or more cold-producing mediums of appropriate amount again, so that influence the composition of mixture.Therefore, valve 209 is temporarily opened, and is discharged to enlarged portion 208 to allow a part of refrigerant mixture of system from cooling circuit 100.One or more in the valve 204,205 and 206 temporarily open, to allow being fed to cooling circuit 100 from (multiple) cold-producing medium of storage tank 201,202 and/or 203 by supply line 207.The control device (not shown) determines the speed of opening of valve according to the adjusting of being carried out and opens the time, and the signal of correspondence outputed to one or more in valve 204,205,206 and 209 as may needing.
Described another many refrigerant cools system in Fig. 2, it comprises the cooling circuit 100 of the circulation that is used for refrigerant mixture and is used to regulate the assembly 200 of the composition of refrigerant mixture.
Cooling circuit 100 among Fig. 2 is similar to the cooling circuit 100 of Fig. 1.But, emphasize that once more the detailed placement of cooling circuit or its operation principle are not crucial for the present invention.
The assembly 200 that is used to regulate the composition of refrigerant mixture comprises storage tank 201 and 202, storage tank 201 and 202 separately by corresponding extraction pipeline 210 and 211 and corresponding valve 212 and 213 be connected on corresponding separator 102 or 103.The position of other storage tank 203 between separator 103 and client computer 104 is connected on the cooling circuit 100 by extracting pipeline 214 and valve 215.Therefore, each storage tank 201,202 and 203 is arranged to receive the corresponding cold-producing medium flow point from cooling circuit 100.Storage tank by corresponding valve 204,205 and 206 and supply line 207 be connected on the cooling circuit 100.(promptly on the low-pressure side at cooling circuit) is connected on the cooling circuit 100 supply line 207 in the position between the inlet of client computer 104 and compressor 101.Enlarged portion 208 is connected to by corresponding valve 216,217 and 218 and extracts on the pipeline 210,211 and 214.
Do not show the control device that has the control signalling foundation structure that is associated among Fig. 2, this control device is careful amount in each storage tank 201,202 and 203 by pressure sensor, and the percentage of being careful the various cold-producing mediums in the refrigerant mixture of cooling circuit 100 by the multicomponent detector, and the percentage of the various cold-producing mediums in the cold-producing medium flow point in each storage tank 201,202 and 203, and control valve 204,205,206,212,213,215,216,217 and 218.Control device can comprise for example all-purpose computer, dedicated computing device, perhaps receives the input signal show these systematic parameters, uses the instruction of storage to handle input signal and provide output signal so that come other programmable controller of operating system in mode as herein described to various control valves.
For the composition of the refrigerant mixture of regulating cooling circuit 100, the cooling circuit part of refrigerant mixture that is cleared, and be filled with one or more cold-producing medium flow points of appropriate amount again, so that influence the composition of mixture.Therefore, one or more in the valve 212,213 and 215 temporarily open, lead to corresponding storage tank 201,202 or 203 with a part that allows corresponding cold-producing medium flow point, perhaps one or more in the valve 216,217 and 218 temporarily open, and are discharged to enlarged portion 208 with a part that allows corresponding cold-producing medium flow point from cooling circuit 100.One or more in the valve 204,205 and 206 temporarily open, to allow being fed to cooling circuit 100 from (multiple) cold-producing medium flow point of storage tank 201,202 and/or 203 by supply line 207.The control device (not shown) is determined the speed of opening and the unlimited time of valve according to the adjusting of being carried out, and the signal of correspondence is outputed to one or more in valve 204,205,206,212,213,215,216,217 and 218 as may needing.
Alternatively, many refrigerant cools of Fig. 2 system can be described below.
Many refrigerant cools system (MRC) comprises the cooling circuit 100 of the circulation of the refrigerant mixture that is used to comprise two or more cold-producing medium flow points.MRC operates by two or more cold-producing mediums that blending in a process has different condensation temperatures.Cooling circuit 100 comprises compressor 101, client computer 104, the one or more separators 102,103 in loop 100 between compressor 101 and client computer 104.Each separator 102,103 are configured to can also pass through guide coupling 210 except separating, 211 extract specific cold-producing medium flow point from the bottom of each separator of refrigerant mixture, in the bottom of each separator, (a plurality of) guide coupling 210,211 are connected on the specific memory jar 201,202 that accommodates a kind of specific cold-producing medium.(a plurality of) storage tank 201,202 is arranged to receive the specific flow point from its corresponding separator 102,103.In the guide coupling 210,211 each all is equipped with two groups of control valves 212,216; 213,217, wherein, one group of 212,213 stream that regulate to feed in the storage tank, and the stream of exit skirt 208 is led in one group of 216,217 adjusting.Each storage tank 201,202 further and individually connects by pipe, and wherein, each described pipe is attached on the cooling circuit by common collector 207.Each pipe all is equipped with control valve 204,205, and control valve 204,205 is configured to regulate the one or more supplies of arriving one or more specific cold-producing medium flow points of cooling circuit 100 from (a plurality of) storage tank 201,202.The cold-producing medium that has minimum condensation temperature does not have the separator of itself, and exists with pure state after last separator 103, and this cold-producing medium is connected on its storage tank 203 by pipe joint element 214.This pipe joint element 214 is equipped with one group of control valve 215,218, and wherein, control valve 215 is regulated the stream that feeds in the storage tanks 203, and another control valve 218 then adjusting leads to the stream of exit skirt 208.Storage tank 203 also is separately connected on the cooling circuit by common collector 207 by pipe.This pipe also is equipped with control valve 206, and this control valve 206 is configured to regulate from storage tank 203 to cooling circuit the supply of 100 specific cold-producing medium flow point.
In order to reduce the amount of the specific cold-producing medium in the MRC system, control corresponding valve 212,213,215 open, and leave MRC with the cold-producing medium that allows expectation, and enter its corresponding storage tank 201,202,203, perhaps by opening control valve 216, one or more enlarged portion that are discharged in 217,218.In order to improve the amount of the specific cold-producing medium in the MRC system, control corresponding valve 204,205,206 is opened, and leaves its corresponding storage tank 201,202,203 to allow corresponding cold-producing medium, and preferably enters process stream on low-pressure side.Can not need pumping to realize that these cold-producing mediums transmit by only using pressure reduction.
Though, it will be understood by those skilled in the art that and in spirit of the present invention, to make other modification to thinking that at present preferred embodiment is described.Be described in more than the embodiment and be not intended on the scope to limit or restrictive.Should be appreciated that to the invention is not restricted to the foregoing description, but opposite, should in the complete meaning of claim and scope, explain the present invention.

Claims (14)

1. refrigerant cools system more than a kind comprises the cooling circuit (100) of the circulation of the refrigerant mixture that is used to comprise two or more cold-producing mediums, and described cooling circuit comprises: the compressor (101) with entrance and exit; Be configured to separate and extract one or more separators (102,103) of the corresponding cold-producing medium flow point of described refrigerant mixture; And client computer (104), the outlet of described compressor (101) is by described (a plurality of) separator (102,103) be connected on the described client computer (104), wherein, each separator (102,103) by the corresponding pipeline (210 that extracts, 211) be connected to corresponding storage tank (201,202) on, each storage tank (201,202) be arranged to receive from its corresponding separator (102,103) corresponding cold-producing medium flow point, wherein, each storage tank (201,202) also be connected on the described cooling circuit (100) by supply line (207), described supply line (207) is configured to one or more cold-producing medium flow points are fed to described cooling circuit (100).
2. system according to claim 1, it is characterized in that, described system is included in described (a plurality of) separator (102,103) and the position between the described client computer (104) be connected to other storage tank (203) on the described cooling circuit (100) by other extraction pipeline (214), described other storage tank (203) is arranged to receive the cold-producing medium flow point from described cooling circuit (100), wherein, described other storage tank (203) also is connected on the described cooling circuit (100) by described supply line (207).
3. system according to claim 1 and 2 is characterized in that, the position of described supply line (207) between the inlet of described client computer (104) and described compressor (101) is connected on the described cooling circuit (100).
4. according to each described system in the claim 1 to 3, it is characterized in that each extracts pipeline (210,211,214) and is also connected on the enlarged portion (208).
5. according to each described system in the claim 1 to 4, it is characterized in that described client computer is the freezing container of carbon dioxide.
6. the method for the composition of a refrigerant mixture that is used to regulate many refrigerant cools system said method comprising the steps of:
A) extract one or more flow points of described refrigerant mixture from described many refrigerant cools system, described flow point has different cold-producing mediums and forms;
B) cold-producing medium stream is fed to described many refrigerant cools system;
Make the composition of refrigerant mixture of described many refrigerant cools system be adjusted to new composition, described new composition is different with the composition of described cold-producing medium stream; And
C) at step a) and b) during, the refrigerant mixture of described many refrigerant cools system is remained in the amount of the operation that allows described many refrigerant cools system;
Thereby allow to regulate the composition of described refrigerant mixture in the operating period of described many refrigerant cools system.
7. method according to claim 6 is characterized in that, one or more in (multiple) flow point that extracts in step a), is preferably all stored separately.
8. method according to claim 7 is characterized in that, the described cold-producing medium stream of supplying in step b) comprises one or more in (multiple) flow point of described storage, preferably is made up of in (multiple) flow point of described storage one or more.
9. according to claim 7 or 8 described methods, it is characterized in that the quantity of the flow point that extracts is equal to or less than, preferably equals the quantity of the cold-producing medium in the refrigerant mixture of described many refrigerant cools system in step a).
10. method according to claim 6 is characterized in that, discards (multiple) flow point that extracts in step a).
11. method according to claim 10 is characterized in that, the quantity of the flow point that extracts in step a) is one.
12. according to each described method in the claim 7 to 9, it is characterized in that the pressure and the execution in step b of the described refrigerant mixture of the position of the described many refrigerant cools system when (multiple) flow point of described storage keeps being extracting in the step a) corresponding flow point separately) time the pressure of described refrigerant mixture of position of described many refrigerant cools between pressure under.
13. according to each described method in the claim 6 to 12, it is characterized in that, such position of the described many refrigerant cools of each leisure of (multiple) flow point that extracts in step a) system is extracted, that is, at refrigerant mixture described in this position than at execution in step b) time the position of described many refrigerant cools system be under the higher pressure.
14., it is characterized in that the freezing container of described many refrigerant cools system cools carbon dioxide according to each described method in the claim 6 to 13.
CN2009801213784A 2008-06-05 2009-06-03 Multi-refrigerant cooling system with provisions for adjustment of refrigerant composition Pending CN102057235A (en)

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US12/474567 2009-05-29
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US20090301108A1 (en) 2009-12-10

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Application publication date: 20110511