A kind of high-clean gasoline modulation prescription
Technical field
The present invention relates to a kind of vehicle fuel oil field, particularly a kind ofly can substitute the buy car in installments fuel of high-clean gasoline of a use of GB gasoline.
Background technology
The conventional gasoline processing technology is to utilize the different boiling fractionation in addition of heterogeneity in the crude oil, fractionate out different products, such as Sweet natural gas, gasoline, diesel oil, heavy oil and pitch etc., or explained hereafter such as in addition catalysis, cracking, reformation require higher oil fuel, as aviation kerosene etc.But traditional technology is produced the processed oil of different boiling, different ratios and often can not be satisfied a large amount of demand in market and expend crude oil greatly, increase the cost of cost oil, therefore, develop the gasoline dope technology according to this market requirement, directly join in the processed oil, generate the label gasoline of daily need, thereby reduce the usage quantity of crude oil.
In addition, along with the raising of people's environmental protection consciousness, the vehicle emission pollution problem more and more comes into one's own.Europe, the United States, Japan and China have proposed national new gasoline standard in succession, and it has all proposed strict regulation and restriction to sulphur content, benzene content, aromaticity content, olefin(e) centent and oxygen level.Because motor vehicle emission is one of topsoil main source, it is in rising trend always that the contamination level of vehicular emission accounts for the topsoil ratio, along with China's automobile production amount and recoverable amount constantly increase, Abgasgesetz is strict day by day, and society is to improving fuel oil quality, using the cry of clean fuel more and more high.
In order further to reduce the tail gas pollution that brings owing to incomplete combustion, people mainly concentrate on and use alcohols and ethers to add component as gasoline gradually the important directions of oxygen containing clean fuel as fuel research from now on.The industrial chemicals that is easy to get greatly because of the methyl alcohol amount of being, so, methyl alcohol becomes main research direction as the development and use of automobile fuel, but experimental results demonstrate: methyl alcohol directly gasoline replacing is used for motor car engine fuel, this is because the lower boiling influence of methyl alcohol directly has influence on the startup and the acceleration of automobile.Therefore, in the research of high-clean gasoline, often use methyl alcohol and gasoline miscible, and add associated additives.
Chinese patent 200410054960.2 discloses a kind of blended gasoline that contains methyl alcohol, and its component comprises: petroleum naphtha, xylol, toluene, methyl alcohol, Virahol, C9+ petroleum hydrocarbon, iso-pentane, methyl tertiary butyl ether or and tertbutyl ether.The shortcoming of this blended gasoline is, the content of petroleum naphtha that with the oil is raw material is higher, not clearly reducing oil consumption, reducing like this to effect aspect the dependence of oil, in addition, selected methyl tertiary butyl ether in the component, because the characteristic of itself makes it very easily pass soil and enters underground water, just have the intensive peculiar smell and contain a small amount of methyl tertiary butyl ether in the tap water, will produce stimulation nose and throat if human body sucks a spot of methyl tertiary butyl ether, cause headache, nauseating and dizzy.So select for use methyl tertiary butyl ether very undesirable as the environment protecting of blend component.
In addition, because usually existing, methanol gasoline do not dissolve each other demixing phenomenon when configuration, the part evaporation causes vapour lock to make running of an engine intermittency occur in use, be short of power, and methyl alcohol does not dissolve each other with other gasoline mixing, phenomenons such as layering are difficult to produce on a large scale and promote.
Purpose of the present invention is exactly at above shortcoming, provides a kind of methanol usage big, and production cost is low, and is not stratified, stable performance, and the octane value height, no vapour lock, and can mix the high-clean gasoline that uses with other conventional gasoline arbitrary proportions.
Summary of the invention
The invention provides that a kind of environment protecting is good, cost is lower, stable performance, need not to use the preparation method of clean gasoline and this clean gasoline of methyl tertiary butyl ether.
A kind of high-clean gasoline modulation prescription, it is prepared from by following component by weight:
Methyl alcohol 10-20 part;
Gasoline 20-50 part;
Petroleum naphtha 30-50 part;
Naphthenate 20-30 part of mishmetal;
C5 fraction 20-35 part;
Mix benzene 5-10 part.
By said ratio, thorough mixing is even in airtight Mixer pot, makes through check with methyl alcohol, gasoline, petroleum naphtha, naphthenate, C5 fraction, mixed each component of benzene.
Wherein, methanol purity is more than 95%; Gasoline is regular gasoline, can be 93#, 95# or 97#; Petroleum naphtha has characteristics such as cut is light, alkane, naphthene content height, roadholding is good, heavy metal content is low, sulphur content is low, toxicity is less.The naphthenate of mishmetal is meant the mixing of arbitrary proportion of the naphthenate of lanthanide series metals such as lanthanum naphthenate, cerium naphthenate; The purity of mixing benzene is 99.5%http: //www.chemworld.com.cn/price_trade.jsp? kid=1205043.
The octane enhancing additive that the present invention adopts adopts the naphthenate of mishmetal, and than 2-3 point of the more than enough raising of wherein a kind of energy of simple use, effect is obvious.Adopt C5 fraction in addition in the component, mix the synergistic pattern of benzene, satisfy boiling range, index of correlation requirements such as density also significantly reduce than toxic and harmful in the same index product discharge tail gas.
Beneficial effect of the present invention is: by adding the octane value that octane enhancing additives such as naphthenate have effectively improved methyl alcohol, gasoline and petroleum naphtha blending ingredients, make it to reach the GB requirement.The production operation operational path is simple and easy to do, and cost is low, and is easy to use, sufficient combustion, and the automobile oil circuit is carbon deposit not, and noxious gas emission is few; Dynamic performance can be used with any mixed with regular gasoline, ethanol petrol with suitable with the label regular gasoline, need not automobile is done any change; Not water funk, easy cold-starting.
Embodiment
Following embodiment is to further specifying of inventing, but the present invention is not exceeded with embodiment.
Embodiment 1
A kind of high-clean gasoline modulation prescription, it is prepared from by following component by weight:
15 parts of methyl alcohol, 20 parts in gasoline, 30 parts of petroleum naphthas, 20 parts of the naphthenates of mishmetal, 40 parts of C5 fractions mix 5 parts of benzene.
By said ratio, thorough mixing is even in airtight Mixer pot with each component, makes through check.
The performance index of gained high-clean gasoline are as follows:
Test item |
The prior art index |
Index of the present invention |
Research octane number (RON) |
93 |
95 |
Sulphur content (μ g/g) |
35 |
9 |
Copper corrosion (50 ℃, 4h), level |
1a |
1a |
Mechanical impurity (%) |
Do not have |
Do not have |
Existent gum (mg/100ml) |
4.07 |
2.95 |
Lead content (g/L) |
0.005 |
0.001 |
Manganese content (g/L) |
0.017 |
0.016 |
Iron level (g/L) |
0.01 |
0.005 |
Quantity discharged |
|
|
Particulate matter PM/g.km
-1 |
0.05 |
0.035 |
HC+NO/g.km
-1 |
0.5 |
0.2 |
CO/g.km
-1 |
1.8 |
1.2 |
Embodiment 2
A kind of high-clean gasoline modulation prescription, it is prepared from by following component by weight:
10 parts of methyl alcohol, 30 parts in gasoline, 35 parts of petroleum naphthas, 25 parts of the naphthenates of mishmetal, 30 parts of C5 fractions mix 8 parts of benzene.
By said ratio, thorough mixing is even in airtight Mixer pot with each component, makes through check.
Embodiment 3
A kind of high-clean gasoline modulation prescription, it is prepared from by following component by weight:
20 parts of methyl alcohol, 50 parts in gasoline, 35 parts of petroleum naphthas, 25 parts of the naphthenates of mishmetal, 30 parts of C5 fractions mix 8 parts of benzene.
By said ratio, thorough mixing is even in airtight Mixer pot with each component, makes through check.
Test item |
The prior art index |
Index of the present invention |
Research octane number (RON) |
93 |
95 |
Sulphur content (μ g/g) |
35 |
9 |
Copper corrosion (50 ℃, 4h), level |
1a |
1a |
Mechanical impurity (%) |
Do not have |
Do not have |
Existent gum (mg/100ml) |
4.07 |
2.96 |
Lead content (g/L) |
0.005 |
0.002 |
Manganese content (g/L) |
0.017 |
0.015 |
Iron level (g/L) |
0.01 |
0.005 |
Quantity discharged |
|
|
Particulate matter PM/g.km
-1 |
0.05 |
0.032 |
HC+NO/g.km
-1 |
0.5 |
0.19 |
CO/g.km
-1 |
1.8 |
1.18 |
Embodiment 4
10 parts of methyl alcohol, 30 parts in gasoline, 35 parts of petroleum naphthas, 20 parts of the naphthenates of mishmetal, 35 parts of C5 fractions mix 10 parts of benzene.
By said ratio, thorough mixing is even in airtight Mixer pot with each component, makes through check.