CN102051237B - Preparation formula of high-cleanliness gasoline - Google Patents

Preparation formula of high-cleanliness gasoline Download PDF

Info

Publication number
CN102051237B
CN102051237B CN2009103094391A CN200910309439A CN102051237B CN 102051237 B CN102051237 B CN 102051237B CN 2009103094391 A CN2009103094391 A CN 2009103094391A CN 200910309439 A CN200910309439 A CN 200910309439A CN 102051237 B CN102051237 B CN 102051237B
Authority
CN
China
Prior art keywords
gasoline
parts
cleanliness
fuel
methyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2009103094391A
Other languages
Chinese (zh)
Other versions
CN102051237A (en
Inventor
车春玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG TAIDE NEW ENERGY CO Ltd
Original Assignee
Jinan Development Zone Xinghuo Technology Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinan Development Zone Xinghuo Technology Research Institute filed Critical Jinan Development Zone Xinghuo Technology Research Institute
Priority to CN2009103094391A priority Critical patent/CN102051237B/en
Publication of CN102051237A publication Critical patent/CN102051237A/en
Application granted granted Critical
Publication of CN102051237B publication Critical patent/CN102051237B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention relates to vehicle fuel, in particular to high-cleanliness gasoline fuel which can be used for vehicles by replacing national standard gasoline. The components of the high-cleanliness gasoline fuel comprise methanol, gasoline, naphtha, rare-earth mixed naphthenate and a C5 fraction. Each index of the high-cleanliness gasoline fuel conforms to a national unleaded gasoline standard, the discharge amounts of carbon monoxide and hydrocarbon are both lower than those of carbon monoxide and hydrocarbon of the national standard gasoline, and the high-cleanliness gasoline fuel can be used as vehicle fuel oil by completely replacing the traditional national standard gasoline.

Description

A kind of preparation formula of high-cleanliness gasoline
Technical field
The present invention relates to a kind of vehicle fuel oil field, particularly a kind ofly can substitute the fuel of GB gasoline for the high-clean gasoline of vehicle.
Background technology
The conventional gasoline processing technology is to utilize the different boiling fractionation in addition of heterogeneity in crude oil, fractionate out different products, such as Sweet natural gas, gasoline, diesel oil, heavy oil and pitch etc., or the explained hereafter such as in addition catalysis, cracking, reformation require higher oil fuel, as aviation kerosene etc.But producing the processed oil of different boiling, different ratios, traditional technology often can not a large amount of demand of satisfying the market also greatly expend crude oil, increase the cost of cost oil, therefore, develop the gasoline dope technology according to this market requirement, directly join in processed oil, generate the label gasoline of daily need, thereby reduce the usage quantity of crude oil.
In addition, along with the raising of people's environmental protection consciousness, the vehicle emission pollution problem more and more comes into one's own.Europe, the United States, Japan and China have proposed national new gasoline standard in succession, and it has all proposed strict regulation and restriction to sulphur content, benzene content, aromaticity content, olefin(e) centent and oxygen level.Because motor vehicle emission is one of topsoil main source, it is always in rising trend that the contamination level of vehicular emission accounts for the topsoil ratio, along with China's automobile production amount and recoverable amount constantly increase, Abgasgesetz is increasingly strict, and society is to improving fuel oil quality, using the cry of clean fuel more and more high.
In order further to reduce the tail gas pollution that brings due to incomplete combustion, people, the important directions of oxygen containing clean fuel as fuel research from now on, mainly concentrate on and use alcohols and ethers to add component as gasoline gradually.The industrial chemicals that is easy to get greatly because of the methyl alcohol amount of being, so, methyl alcohol becomes main research direction as the exploitation of automobile fuel, but experimental results demonstrate: methyl alcohol can not directly replace gasoline to be used for motor car engine fuel, this is because the lower boiling impact of methyl alcohol directly has influence on startup and the acceleration of automobile.Therefore, in the research of high-clean gasoline, often use methyl alcohol and gasoline miscible, and add associated additives.
Chinese patent 200410054960.2 discloses a kind of blended gasoline that contains methyl alcohol, and its component comprises: petroleum naphtha, xylol, toluene, methyl alcohol, Virahol, C9+ petroleum hydrocarbon, iso-pentane, methyl tertiary butyl ether or and tertbutyl ether.The shortcoming of this blended gasoline is, the content of the petroleum naphtha take oil as raw material is higher, like this reducing oil consumption, to reduce effect aspect the dependence of oil be not clearly, in addition, selected methyl tertiary butyl ether in component, because making it very easily pass soil, itself characteristic enters underground water, just have strong peculiar smell and contain a small amount of methyl tertiary butyl ether in tap water, will produce stimulation nose and throat if human body sucks a small amount of methyl tertiary butyl ether, cause headache, nauseating and dizzy.So select methyl tertiary butyl ether very undesirable as the environment protecting of blend component.
In addition, because methanol gasoline usually exists and do not dissolve each other, demixing phenomenon when configuring, the part evaporation causes vapour lock to make running of an engine intermittency occur in use, be short of power, and methyl alcohol mixes and do not dissolve each other with other gasoline, the phenomenons such as layering, be difficult to produce on a large scale and promote.
Purpose of the present invention is exactly for above shortcoming, provides a kind of methanol usage large, and production cost is low, and is not stratified, stable performance, and octane value is high, without vapour lock, and can mix the high-clean gasoline that uses with other conventional gasoline arbitrary proportions.
Summary of the invention
The invention provides that a kind of environment protecting is good, cost is lower, stable performance, need not to use the preparation method of clean gasoline and this clean gasoline of methyl tertiary butyl ether.
A kind of preparation formula of high-cleanliness gasoline, it is prepared from by following component by weight:
Methyl alcohol 10-20 part;
Gasoline 20-50 part;
Petroleum naphtha 30-50 part;
Naphthenate 20-30 part of mishmetal;
C5 fraction 20-35 part;
Mixed benzene 5-10 part.
Methyl alcohol, gasoline, petroleum naphtha, naphthenate, C5 fraction, mixed each component of benzene, by said ratio, are fully mixed in airtight Mixer pot, through check, make.
Wherein, methanol purity is more than 95%; Gasoline is regular gasoline, can be 93#, 95# or 97#; Petroleum naphtha has the characteristics such as cut is light, alkane, naphthene content is high, roadholding good, heavy metal content is low, sulphur content is low, toxicity is less.The naphthenate of mishmetal refers to the mixing of arbitrary proportion of the naphthenate of the lanthanide series metals such as lanthanum naphthenate, cerium naphthenate; The purity of mixed benzene is 99.5%http: //www.chemworld.com.cn/price_trade.jsp? kid=1205043.
The octane enhancing additive that the present invention adopts adopts the naphthenate of mishmetal, than simple use 2-3 point of the more than enough raising of a kind of energy wherein, successful.Adopt in addition C5 fraction, the mixed synergistic pattern of benzene in component, meet boiling range, the index of correlation requirements such as density, also significantly reduce than toxic and harmful in the tail gas of same index product discharging.
Beneficial effect of the present invention is: effectively improved the octane value of methyl alcohol, gasoline and petroleum naphtha blending ingredients by adding the octane enhancing additives such as naphthenate, made it to reach the GB requirement.The production operation operational path is simple and easy to do, and cost is low, and is easy to use, sufficient combustion, and automobile oil-way is carbon deposit not, and noxious gas emission is few; Dynamic performance, with suitable with the label regular gasoline, can be mixed and use with any ratio with regular gasoline, ethanol petrol, need not automobile is done any change; Not water funk, easy cold-starting.
Embodiment
Following embodiment is to further illustrating of inventing, but the present invention is not limited with embodiment.
Embodiment 1
A kind of preparation formula of high-cleanliness gasoline, it is prepared from by following component by weight:
15 parts of methyl alcohol, 20 parts, gasoline, 30 parts of petroleum naphthas, 20 parts of the naphthenates of mishmetal, 40 parts of C5 fractions, 5 parts of mixed benzene.
Each component, by said ratio, is fully mixed in airtight Mixer pot, through check, make.
The performance index of gained high-clean gasoline are as follows:
Test item The prior art index Index of the present invention
Research octane number (RON) 93 95
Sulphur content (μ g/g) 35 9
Copper corrosion (50 ℃, 4h), level 1a 1a
Mechanical impurity (%) Nothing Nothing
Existent gum (mg/100ml) 4.07 2.95
Lead content (g/L) 0.005 0.001
Manganese content (g/L) 0.017 0.016
Iron level (g/L) 0.01 0.005
Quantity discharged
Particulate matter PM/g.km -1 0.05 0.035
HC+NO/g.km -1 0.5 0.2
CO/g.km -1 1.8 1.2
Embodiment 2
A kind of preparation formula of high-cleanliness gasoline, it is prepared from by following component by weight:
10 parts of methyl alcohol, 30 parts, gasoline, 35 parts of petroleum naphthas, 25 parts of the naphthenates of mishmetal, 30 parts of C5 fractions, 8 parts of mixed benzene.
Each component, by said ratio, is fully mixed in airtight Mixer pot, through check, make.
Figure G200910309439120091109D000031
Figure G200910309439120091109D000041
Embodiment 3
A kind of preparation formula of high-cleanliness gasoline, it is prepared from by following component by weight:
20 parts of methyl alcohol, 50 parts, gasoline, 35 parts of petroleum naphthas, 25 parts of the naphthenates of mishmetal, 30 parts of C5 fractions, 8 parts of mixed benzene.
Each component, by said ratio, is fully mixed in airtight Mixer pot, through check, make.
Test item The prior art index Index of the present invention
Research octane number (RON) 93 95
Sulphur content (μ g/g) 35 9
Copper corrosion (50 ℃, 4h), level 1a 1a
Mechanical impurity (%) Nothing Nothing
Existent gum (mg/100ml) 4.07 2.96
Lead content (g/L) 0.005 0.002
Manganese content (g/L) 0.017 0.015
Iron level (g/L) 0.01 0.005
Quantity discharged
Particulate matter PM/g.km -1 0.05 0.032
HC+NO/g.km -1 0.5 0.19
CO/g.km -1 1.8 1.18
Embodiment 4
10 parts of methyl alcohol, 30 parts, gasoline, 35 parts of petroleum naphthas, 20 parts of the naphthenates of mishmetal, 35 parts of C5 fractions, 10 parts of mixed benzene.
Each component, by said ratio, is fully mixed in airtight Mixer pot, through check, make.
Figure G200910309439120091109D000042
Figure G200910309439120091109D000051

Claims (1)

1. preparation formula of high-cleanliness gasoline, it is characterized in that: it consists of following component by weight:
20 parts of methyl alcohol;
50 parts, gasoline;
35 parts of petroleum naphthas;
25 parts of the naphthenates of mishmetal;
30 parts of C5 fractions;
8 parts of mixed benzene.
CN2009103094391A 2009-11-09 2009-11-09 Preparation formula of high-cleanliness gasoline Active CN102051237B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009103094391A CN102051237B (en) 2009-11-09 2009-11-09 Preparation formula of high-cleanliness gasoline

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009103094391A CN102051237B (en) 2009-11-09 2009-11-09 Preparation formula of high-cleanliness gasoline

Publications (2)

Publication Number Publication Date
CN102051237A CN102051237A (en) 2011-05-11
CN102051237B true CN102051237B (en) 2013-11-13

Family

ID=43956042

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009103094391A Active CN102051237B (en) 2009-11-09 2009-11-09 Preparation formula of high-cleanliness gasoline

Country Status (1)

Country Link
CN (1) CN102051237B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865294B (en) * 2018-07-10 2020-09-25 谢爱丽 Corrosion-resistant and water-resistant methanol gasoline
CN108795513B (en) * 2018-07-10 2020-09-25 谢爱丽 Corrosion-resistant expansion-inhibiting water-resistant methanol gasoline

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300912A (en) * 1980-10-07 1981-11-17 Union Carbide Corporation Synthetic fuel containing methanol and butanol
CN1368540A (en) * 2001-02-01 2002-09-11 呼世滨 Anti-explosion additive of gasoline and gasoline prepared from it
CN1401743A (en) * 2001-08-28 2003-03-12 济南开发区星火科学技术研究院 Ethanol and mixed alcohol gasoline
CN1727451A (en) * 2004-07-26 2006-02-01 俞昌镐 Alcohol gasoline

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300912A (en) * 1980-10-07 1981-11-17 Union Carbide Corporation Synthetic fuel containing methanol and butanol
CN1368540A (en) * 2001-02-01 2002-09-11 呼世滨 Anti-explosion additive of gasoline and gasoline prepared from it
CN1401743A (en) * 2001-08-28 2003-03-12 济南开发区星火科学技术研究院 Ethanol and mixed alcohol gasoline
CN1727451A (en) * 2004-07-26 2006-02-01 俞昌镐 Alcohol gasoline

Also Published As

Publication number Publication date
CN102051237A (en) 2011-05-11

Similar Documents

Publication Publication Date Title
CN100580064C (en) Methanol gasoline for vehicle
JP2009504827A (en) Fuel composition
CN101085937A (en) Environmental protection energy-saving type vehicular lead-free gasoline
CN100487088C (en) Clean gasoline and prepartion method
CN103666595A (en) Clean gasoline for replacing ethanol and methanol gasoline and preparation method of clean gasoline
WO2011035219A3 (en) Mesitylene as an octane enhancer for automotive gasoline, additive for jet fuel, and method of enhancing motor fuel octane and lowering jet fuel carbon emissions
CN101144041A (en) Gasoline anti-knock agent mixture for vehicle
CN102051237B (en) Preparation formula of high-cleanliness gasoline
CN107629824A (en) A kind of vehicle lead-free synthetic fuel
CN102492496A (en) Additive of pure methanol fuel
CN101580747A (en) Fuel composition capable of meeting motor vehicle pollutant emission limit
CN101597525A (en) Improve the alcohol-ether fuel composition of fuel economy
CN103695052A (en) Vehicle methanol gasoline cosolvent
CN101195769B (en) Low carbon mixture alcohol gasoline
CN102408926A (en) No.93 ethanol gasoline blending component oil for vehicle and blending method thereof
CN101824341A (en) High-clean gasoline additive
CN101538489A (en) Automotive mixed alcohol clean fuel
CN103980960B (en) Environmental protection composite gasoline
CN102304397A (en) Low-proportion methanol gasoline additive
CN102492499A (en) Additive of M30 methanol gasoline
CN104109564B (en) A kind of high pure blended gasoline and preparation method thereof
CN1730626A (en) Environment protectional antiknock additive for high-effective and clean gasoline for vehicle, and method for manufacturing same
CN1245486C (en) Synthetic gasoline
CN108676591A (en) A kind of gasoline additive
CN102322376A (en) The mixed method of Vehicular alcohol Fuel Petroleum and device

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20160224

Address after: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100

Patentee after: SHANDONG TAIDE NEW ENERGY Co.,Ltd.

Address before: 250100 Shandong city of Ji'nan province high tech Zone (Licheng District) Xinluo Avenue No. 786 Room 201

Patentee before: JINAN DEVELOPMENT ZONE XINGHUO SCIENCE AND TECHNOLOGY Research Institute

PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20191017

Granted publication date: 20131113

PD01 Discharge of preservation of patent
PD01 Discharge of preservation of patent

Date of cancellation: 20221017

Granted publication date: 20131113

PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20230207

Granted publication date: 20131113