CN102050686A - Micro smoke ignition agent for fireworks - Google Patents
Micro smoke ignition agent for fireworks Download PDFInfo
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- CN102050686A CN102050686A CN2009100446948A CN200910044694A CN102050686A CN 102050686 A CN102050686 A CN 102050686A CN 2009100446948 A CN2009100446948 A CN 2009100446948A CN 200910044694 A CN200910044694 A CN 200910044694A CN 102050686 A CN102050686 A CN 102050686A
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Abstract
The invention discloses a micro smoke ignition agent for fireworks, which consists of potassium perchlorate, carbon powder, nitro-cotton and/or nitroguanidine, a high-energy reducing agent and a detonation agent. The invention has the advantages that: an oxidant adopts a high-oxygen content and high-stability substance, so that the using amount can be controlled and smoke can be reduced; combustibles can release a large amount of heat during combustion, so that a high-temperature substance is generated; therefore, the using amount can be controlled and the smoke can be reduced; and main combustibles adopt high-oxygen content substances, so that the using amount of smoke oxidants can be reduced to the greatest extent. Therefore, only micro smoke is generated during combustion of the ignition agent. Due to the detection result of light transmittance, compared with that of the conventional same-class corresponding products, the produced smoke is reduced by 70 percent. Meanwhile, the configuration of the whole medicament system guarantees ignition performance and stability of the ignition agent, and the safety performance meets the requirement of the national standard.
Description
Technical field
The present invention relates to a kind of pyrotechnic composition composition, particularly a kind of fireworks are with little smoke point powder composition.
Background technology
Fireworks have a drug effect fruit part with what ignition powder was used for firework bright bead, powder column and generation handle, wandering star and other moulding, himself are launched medicine or blasting powders is lighted afterfire, remove to light the higher effect medicament of point of ignition again.In the prior art, fireworks all are with the different black powder of various proportionings with ignition powder or black powder adds potassium perchlorate and aluminium-magnesium alloy powder is made.The amount of smoke that its burning produces is very big.Have a strong impact on the igniting fireworks effect, cause environmental pollution.
Summary of the invention
In order to overcome above-mentioned drawback, technical problem to be solved by this invention is, has only little cigarette after a kind of setting off is provided, and can keep the ignition characteristic of its original priming charge and little smoke point gunpowder of stability.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is, a kind of fireworks are made up of potassium perchlorate, powdered carbon, nitro-cotton and/or nitroguanidine, high energy reductive agent, the medicament that detonates with little smoke point powder composition:
Described high energy reductive agent adopted the high hot combustiblematerials powder of 100-500 mesh standard sieve, was any one or any multiple arbitrary proportion mixture in zirconium, titanium, aluminium, aluminum magnesium alloy, titanium hydride, zircoium hydride, the calcium silicide powder; The described medicament that detonates adopts any one in lead azoimide, the nickel hydrazine nitrate.
Described each component mixes, in order to avoid medicine is because of the layering of density difference.Whole medicine has all been starched drying with starch solution and has been ground, so that increase ignition characteristic.
As a kind of preferred, described fireworks with the ratio of weight and number of little smoke point powder composition are: nitro-cotton and/or nitroguanidine 30-90 part, potassium perchlorate 5-15 part, powdered carbon 5-10 part, high energy reductive agent 3-15 part, the medicament 1-5 part of detonating.
Described potassium perchlorate is as oxygenant, and is because of its oxygen level height, though it can produce smog in combustion processes, because amount is few, little to the cigarette amount influence of whole little cigarette medicament.
Described nitro-cotton and nitroguanidine can materials for smokelessly containing, and can be used singly or in combination as the burning main body, can make medicament little cigarette that burns; It is the single, double original washing powder of main component that the present firework industry of nitro-cotton adopts nitro-cotton mostly, is made through operations such as fragmentation, interpolation tranquilizers by military retired single-base powder or double-base powder, and it is cheap, is suitable for low-cost firework medicament.
Described high energy reductive agent all can be emitted big calorimetric when burning, thereby produces high temperature, so that light high burning-point medicine.Their consumptions are all very little, so can not produce a lot of smog.Described powdered carbon, especially waste of flax powdered carbon, point of ignition is low, is convenient to be lighted.Both are used in combination and can effectively improve the medicine ignition characteristic.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1: the preparation process of described little smoke point powder composition is as follows:
1, high energy reductive agent-aluminium-magnesium alloy powder is crossed 200 mesh standard sieves;
2, by ratio of weight and the number of copies, get 78 parts of single, double original washing powders, 10 parts of potassium perchlorates, 5 parts of waste of flax powdered carbons, 5 parts of aluminium-magnesium alloy powders, 2 parts of lead azoimide, described medicine adopt the method for repeatedly sieving fast to mix, again with starch solution starch, dry, grind.Promptly finish the preparation of described little smoke point powder composition.Each constituent materials of the present invention all can be buied in firework raw material market or Chemical market according to described title.
Embodiment 2: difference from Example 1 is that the component of described little smoke point powder composition and ratio of weight and number are: 27 parts of single, double original washing powders, 40 parts of nitroguanidines, 15 parts of potassium perchlorates, 10 parts of pine powdered carbons, 10 parts of titanium hydrides, 3 parts of nickel hydrazine nitrates.
Embodiment 3: difference from Example 1 is that the component of described little smoke point powder composition and ratio of weight and number are: 35 parts of single, double original washing powders, 5 parts of potassium perchlorates, 7 parts of China fir powdered carbons, 3 parts of metallic aluminium powders, 1 part of nickel hydrazine nitrate.
Embodiment 4: difference from Example 1 is that the component of described little smoke point powder composition and ratio of weight and number are: 30 parts of nitroguanidines, 8 parts of potassium perchlorates, 6 parts of waste of flax powdered carbons, 7 parts of calcium silicides, 3 parts of lead azoimide.
Embodiment 5: difference from Example 1 is that the component of described little smoke point powder composition and ratio of weight and number are: 45 parts of single, double original washing powders, 12 parts of potassium perchlorates, 8 parts of waste of flax powdered carbons, 9 parts of metallic titanium powder, 5 parts of lead azoimide.
Embodiment 6: difference from Example 1 is that the component of described little smoke point powder composition and ratio of weight and number are: 57 parts of single, double original washing powders, 30 parts of nitroguanidines, 6 parts of potassium perchlorates, 9 parts of pine powdered carbons, 6 parts of metal zirconium powders, 1 part of nickel hydrazine nitrate.
Through actual detected, little smoke point powder composition described in the various embodiments described above, its impact sensitivity are between 40-43%, and friction sensitivity is about 42%, and rate of moisture absorption≤1.3%, 75 a ℃ stability test result is " stabilizing ".Regulation according to the standard of GB10631-2004 " fireworks and crackers safety and quality ": impact sensitivity≤50%, there is not decomposing phenomenon under friction sensitivity≤60%, 75 ℃ ± 2 ℃, the 48h condition, rate of moisture absorption≤2.0% is considered as meeting national standard.(1. the friction sensitivity testing method is carried out according to 5.5 regulation among the SN 0545-1996; 2. the impact sensitivity testing method is carried out according to 5.4 regulation among the SN 0545-1996; 3. water absorbability is carried out according to the method for QB/T1914.5.)
The beneficial effect of technical solution of the present invention is that oxidant adopts the material of oxygen content height and good stability, reduces smog thereby can control consumption; Combustible adopts when burning can emit big calorimetric, produces the material of high temperature, reduces smog thereby can control consumption, and main combustible adopts high oxygen carrier, thereby reduces the consumption that the cigarette oxidant is arranged as far as possible. So, only have minute mist during ignition powder burning of the present invention, according to the light transmittance testing result, compare with existing equal corresponding product, the amount of smoke of its generation has reduced 70%. Simultaneously, the configuration of whole drug system has guaranteed ignition performance and the stability of ignition charge, and security performance complies with the national standard requirements.
Claims (5)
1. fireworks is characterized in that with little smoke point powder composition, and described little smoke point powder composition is made up of potassium perchlorate, powdered carbon, nitro-cotton and/or nitroguanidine, high energy reductive agent, the medicament that detonates:
Described high energy reductive agent adopted the high hot combustiblematerials powder of 100-500 mesh standard sieve, was any one or any multiple arbitrary proportion mixture in zirconium, titanium, aluminium, aluminum magnesium alloy, titanium hydride, zircoium hydride, the calcium silicide powder;
The described medicament that detonates adopts any one in lead azoimide, the nickel hydrazine nitrate.
2. a kind of fireworks as claimed in claim 1 is characterized in that with little smoke point powder composition the ratio of weight and number of described little smoke point powder composition is: potassium perchlorate 5-15 part, powdered carbon 5-10 part, nitro-cotton and/or nitroguanidine 30-90 part, high energy reductive agent 3-15 part, the medicament 1-5 part of detonating.
3. a kind of fireworks as claimed in claim 1 is characterized in that with little smoke point powder composition each component of described little smoke point powder composition adopts the method for repeatedly sieving fast to mix, and whole medicine has all been starched drying with starch solution and ground.
As claim 1,2,3 each described a kind of fireworks with little smoke point powder composition, it is characterized in that described nitro-cotton adopts single, double original washing powder.
As claim 1,2,3 each described a kind of fireworks with little smoke point powder composition, it is characterized in that described powdered carbon adopts the waste of flax powdered carbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910044694A CN102050686B (en) | 2009-10-30 | 2009-10-30 | Micro smoke ignition agent for fireworks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910044694A CN102050686B (en) | 2009-10-30 | 2009-10-30 | Micro smoke ignition agent for fireworks |
Publications (2)
| Publication Number | Publication Date |
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| CN102050686A true CN102050686A (en) | 2011-05-11 |
| CN102050686B CN102050686B (en) | 2012-10-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910044694A Expired - Fee Related CN102050686B (en) | 2009-10-30 | 2009-10-30 | Micro smoke ignition agent for fireworks |
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| CN (1) | CN102050686B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584506A (en) * | 2012-01-16 | 2012-07-18 | 南京理工大学 | Modular smokeless firework emission ammunition with multi-hierarchy hole structure and preparation method for modular smokeless firework emission ammunition |
| CN102924193A (en) * | 2012-10-15 | 2013-02-13 | 周健 | Smokeless propellant powder with safe, environmental-friendly and porous structure for fireworks |
| CN104860787A (en) * | 2015-04-08 | 2015-08-26 | 江西省万载县金峰花炮有限公司 | Safe and environment-friendly slight-smoke colored spraying fireworks |
| CN104944423A (en) * | 2015-06-10 | 2015-09-30 | 北京理工大学 | High-energy-point gunpowder and preparation method |
| CN104944422A (en) * | 2015-06-10 | 2015-09-30 | 北京理工大学 | Ignition powder and preparation method |
| CN108546221A (en) * | 2018-05-15 | 2018-09-18 | 罗永年 | A kind of fireworks and firecrackers organic polymer type oxidant and preparation method thereof |
| CN108578945A (en) * | 2018-03-20 | 2018-09-28 | 宋建芳 | A kind of aerosol fire-extinguishing patch |
| CN108911933A (en) * | 2018-08-30 | 2018-11-30 | 浏阳象形精品烟花出口制造有限公司 | A kind of colloid gunpowder of high nitrogen type solvent flashing |
| CN109206290A (en) * | 2018-11-08 | 2019-01-15 | 东信烟花集团有限公司 | Without sulphur without chlorine pyrotechnics drug composition |
| CN110950723A (en) * | 2019-12-10 | 2020-04-03 | 江西吉润花炮新材料科技有限公司 | Flame bright type smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof |
| CN113698263A (en) * | 2021-02-09 | 2021-11-26 | 北京理工大学 | Preparation method of low-cost combustion improver for safe and environment-friendly fireworks |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253278A (en) * | 1998-11-05 | 2000-05-17 | 杨宗强 | High-safety colour-light firecracker and its production technology |
| US6599379B2 (en) * | 2001-04-12 | 2003-07-29 | Dmd Systems, Llc | Low-smoke nitroguanidine and nitrocellulose based pyrotechnic compositions |
-
2009
- 2009-10-30 CN CN200910044694A patent/CN102050686B/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584506B (en) * | 2012-01-16 | 2014-03-19 | 南京理工大学 | Modular smokeless firework emission ammunition with multi-hierarchy hole structure and preparation method for modular smokeless firework emission ammunition |
| CN102584506A (en) * | 2012-01-16 | 2012-07-18 | 南京理工大学 | Modular smokeless firework emission ammunition with multi-hierarchy hole structure and preparation method for modular smokeless firework emission ammunition |
| CN102924193A (en) * | 2012-10-15 | 2013-02-13 | 周健 | Smokeless propellant powder with safe, environmental-friendly and porous structure for fireworks |
| CN102924193B (en) * | 2012-10-15 | 2014-12-17 | 周健 | Smokeless propellant powder with safe, environmental-friendly and porous structure for fireworks |
| CN104860787A (en) * | 2015-04-08 | 2015-08-26 | 江西省万载县金峰花炮有限公司 | Safe and environment-friendly slight-smoke colored spraying fireworks |
| CN104944423A (en) * | 2015-06-10 | 2015-09-30 | 北京理工大学 | High-energy-point gunpowder and preparation method |
| CN104944422A (en) * | 2015-06-10 | 2015-09-30 | 北京理工大学 | Ignition powder and preparation method |
| CN104944423B (en) * | 2015-06-10 | 2018-03-02 | 北京理工大学 | A kind of high-energy igniter charge and preparation method |
| CN108578945B (en) * | 2018-03-20 | 2021-04-09 | 广州市友安消防科技有限公司 | Aerosol extinguishing patch |
| CN108578945A (en) * | 2018-03-20 | 2018-09-28 | 宋建芳 | A kind of aerosol fire-extinguishing patch |
| CN108546221A (en) * | 2018-05-15 | 2018-09-18 | 罗永年 | A kind of fireworks and firecrackers organic polymer type oxidant and preparation method thereof |
| CN108546221B (en) * | 2018-05-15 | 2020-08-18 | 罗永年 | Organic polymerization type oxidant for fireworks and crackers and preparation method thereof |
| CN108911933A (en) * | 2018-08-30 | 2018-11-30 | 浏阳象形精品烟花出口制造有限公司 | A kind of colloid gunpowder of high nitrogen type solvent flashing |
| CN109206290A (en) * | 2018-11-08 | 2019-01-15 | 东信烟花集团有限公司 | Without sulphur without chlorine pyrotechnics drug composition |
| CN110950723A (en) * | 2019-12-10 | 2020-04-03 | 江西吉润花炮新材料科技有限公司 | Flame bright type smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof |
| CN113698263A (en) * | 2021-02-09 | 2021-11-26 | 北京理工大学 | Preparation method of low-cost combustion improver for safe and environment-friendly fireworks |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102050686B (en) | 2012-10-10 |
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