CN102050615A - Dolomite magnesia cement pantile and manufacturing method thereof - Google Patents

Dolomite magnesia cement pantile and manufacturing method thereof Download PDF

Info

Publication number
CN102050615A
CN102050615A CN2010105418186A CN201010541818A CN102050615A CN 102050615 A CN102050615 A CN 102050615A CN 2010105418186 A CN2010105418186 A CN 2010105418186A CN 201010541818 A CN201010541818 A CN 201010541818A CN 102050615 A CN102050615 A CN 102050615A
Authority
CN
China
Prior art keywords
magnesium
magnesium chloride
dolomite
pantile
cement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2010105418186A
Other languages
Chinese (zh)
Other versions
CN102050615B (en
Inventor
肖学英
李发福
张全有
常成功
王继东
张志宏
董生发
王惠娟
马艳芳
王明英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinghai Zhongke Yanhu Technology Innovation Co ltd
Qinghai Institute of Salt Lakes Research of CAS
Original Assignee
Qinghai Zhongke Yanhu Technology Innovation Co ltd
Qinghai Institute of Salt Lakes Research of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinghai Zhongke Yanhu Technology Innovation Co ltd, Qinghai Institute of Salt Lakes Research of CAS filed Critical Qinghai Zhongke Yanhu Technology Innovation Co ltd
Priority to CN201010541818A priority Critical patent/CN102050615B/en
Publication of CN102050615A publication Critical patent/CN102050615A/en
Application granted granted Critical
Publication of CN102050615B publication Critical patent/CN102050615B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention relates to a dolomite magnesia cement pantile and a manufacturing method thereof, which belongs to the field of chemical and building materials. The dolomite magnesia cement pantile comprises caustic dolomite powder, magnesium chloride, a light filler, an inert filler, water and a thermal insulating material, the mass ratio of which is 1.00:0.12 to 0.40:0.10 to 0.60:0.05 to 0.30:0.44 to 1.20:0.05 to 0.30, and a supporting material is properly added. The manufacturing method comprises the following steps of slurry mixing, shaping, curing and maintaining. The produced dolomite magnesia cement pantile for buildings has the advantages of fire protection, thermal insulation, high strength, good water resistance, anticorrosion, shock prevention, easiness in construction, environmental protection, energy conservation, simple production process, low energy consumption and the like, is an updated product for replacing various color steel light partition wall boards, silicate cement partition wall boards and other boards, belongs to an environment-friendly building material and can be widely applied to the building industry.

Description

A kind of rhombspar magnesium-cement corrugated tile and manufacture method thereof
One, technical field
The present invention is a kind of rhombspar magnesium-cement corrugated tile and manufacture method thereof, belongs to the chemical building material field
Two, background technology
The pantile of domestic production at present has asbestos tile, Glass Steel Tile, color steel watt, cement tile etc.Asbestos tile is restricted use owing to contain carcinogens; Glass Steel Tile has the aged defective, easily processing of color steel watt, easily installs, uses wider, but have shortcomings such as not heat insulation, not sound insulation, easy oxidation corrosion; Cement tile is used also wider, but its unit weight is big, is difficult for shortcomings such as installation.The magnesite pantile is with good performance such as fire prevention, high-strength light, anticorrosion, anti-aging, easily characteristics such as construction are widely-used at building materials field, at present, main raw material light burnt powder (magnesia) place of production that produces pantile mainly concentrates on China Liaoning, limited by the resource region, it is higher to produce magnesite PLASTIC LAMINATED decorative sheet raw materials cost, is difficult for promoting.
Three, summary of the invention
The present invention is that (it is that lime carbonate and magnesiumcarbonate double salt are the ore of main component, and molecular formula is CaMg (CO with dolomite mineral 3) 2) the caustic dolomite powder and the magnesium chloride that obtain after roasting be main raw material, by mixing slurry, forming and hardening, operations such as maintenance are made the rhombspar magnesium-cement corrugated tile, the technical scheme that the present invention intends taking is: a kind of rhombspar magnesium-cement corrugated tile and manufacture method thereof, it is characterized in that the rhombspar magnesium-cement corrugated tile is by the caustic dolomite powder, magnesium chloride, light filler, inert filler, water and lagging material are formed, its mass ratio is 1.00: 0.12~0.40: 0.10~0.60: 0.05~0.30: 0.44~1.20: 0.05~0.30, the middle an amount of supporting material that adds, supporting material is middle alkali glass silk cloth and non-woven fabrics, light filler is sawdust or straw (shell) or agricultural crop straw powder or its mixture etc., inert filler is flyash or slag powders or talcum powder or its mixture etc., lagging material is pearlstone or expanded vermiculite or organic polymer or its mixture etc., its manufacture method is for mixing slurry → forming and hardening → maintenance, the processing requirement of mixing slurry is formation magnesium chloride solution that magnesium chloride is dissolved in the water in proportion, magnesium chloride solution and caustic dolomite powder, light filler, inert material, the pro rata mixture of lagging material carries out mix, form caustic dolomite magnesium cement slurry, the processing requirement of forming and hardening is that above-mentioned caustic dolomite magnesium cement slurry is injected system watt machine or particular manufacturing craft, an amount of supporting material is put in the shop, solidify the demoulding after 18~24 hours under 10~40 ℃ of conditions, the processing requirement of maintenance is at 10~40 ℃ after the demoulding, relative air humidity less than indoor maintenance under 80% condition greater than 28 days.Magnesium chloride can substitute with the hydrate of magnesium chloride among the present invention.The present invention realizes like this, at first the hydrate water with magnesium chloride or magnesium chloride is mixed with solution, become uniform slurry with the mixture mix of caustic dolomite powder, light filler, inert material and lagging material then, slurry injects system watt machine or particular manufacturing craft forming and hardening, maintenance after the demoulding, maintenance are finished and are product.The present invention proposes to adopt activity caustic dolomite powder manufacturing preferably rhombspar magnesium-cement corrugated tile, the dolomite mineral resource is then widely distributed, almost national each province all has, reserves are abundanter, make full use of the rhombspar resource, locally draw materials, will reduce the cost of producing this product, expand the application of magnesium cement material, have great importance for development various places economy and China save timber in a large number.The pantile that adopts manufacture method of the present invention to produce, have fire prevention, insulation, intensity height, water-tolerant, anticorrosion, shockproof, easy construction, strong, the long service life of weathering resistance, production technique is simple, energy consumption is low, characteristics such as environmental protection and energy saving, be the renewal product that substitutes various asbestos tiles, Glass Steel Tile, color steel watt, cement tile etc. watt, belong to green structural material, can be widely used in construction industry.
 
Four, embodiment
Embodiment 1: a kind of rhombspar magnesium-cement corrugated tile and manufacture method thereof, get caustic dolomite powder 10kg, magnesium chloride 1.2kg, sawdust 1kg, flyash 0.5kg, pearlstone 0.5kg, water 4.4kg, magnesium chloride and water are mixed with solution, and solution and unclassified stores stir in spices device, make slurry, inject laminator making sheet after making slurry, two layers of glass fiber meshs are put in the shop simultaneously, and non-woven fabrics is put in shop, the back side, move into the pantile mould after the making sheet (in 1800 * 720 * 5mm), under 10 ℃ of conditions, forming and hardening demoulding after 18 hours, at 10 ℃, relative air humidity is less than being true qualities rhombspar magnesium-cement corrugated tile after the indoor maintenance to 28 under 80% condition day after the demoulding.
Finished product its key technical indexes after measured is as follows:
Walk crosswise fracture resistence force: the vertical fracture resistence force of 4800N/m: 330N/m
Anti-impact force: do not chap, the flawless opacity: an immersion back watt quilt cover does not have the spot of spreading and sinking in, water droplet
Frost resistance: no aliquation phenomenon weathering age changes level after 25 freeze thawing: no change
Water-intake rate: 11% horizontal firing S:0 is S:0 then vertically
Embodiment 2: a kind of rhombspar magnesium-cement corrugated tile and manufacture method thereof, get caustic dolomite powder 10kg, magnesium chloride 4kg, agricultural crop straw powder 6kg, talcum powder 3kg, expanded vermiculite 3kg, water 12kg is mixed with solution with magnesium chloride and water, solution and unclassified stores stir in spices device, make slurry, make and inject laminator making sheet behind the slurry, two layers of glass fiber meshs are put in the shop simultaneously, non-woven fabrics is put in shop, the back side, immigration pantile mould after the making sheet (in 1800 * 720 * 5mm), under 40 ℃ of conditions, forming and hardening demoulding after 24 hours, after the demoulding at 40 ℃, relative air humidity, is treated to be colored pantile finished product after the pigment completely solidified with polyester pigment spraying pantile front less than after the indoor maintenance to 28 under 80% condition day.
Finished product its key technical indexes after measured is as follows:
Walk crosswise fracture resistence force: the vertical fracture resistence force of 4900N/m: 340N/m
Anti-impact force: do not chap, the flawless opacity: an immersion back watt quilt cover does not have the spot of spreading and sinking in, water droplet
Frost resistance: no aliquation phenomenon weathering age changes level after 25 freeze thawing: no change
Water-intake rate: 12% horizontal firing S:0 is S:0 then vertically
Weathering age aberration level: 0.67
Embodiment 3: a kind of rhombspar magnesium-cement corrugated tile and manufacture method thereof, get caustic dolomite powder 10kg, magnesium chloride 2kg, straw (shell) 3kg, slag 3kg, polystyrene 2kg, water 8kg is mixed with solution with magnesium chloride and water, solution and unclassified stores stir in spices device, make slurry, make and inject laminator making sheet behind the slurry, two layers of glass fiber meshs are put in the shop simultaneously, non-woven fabrics is put in shop, the back side, immigration pantile mould after the making sheet (in 1800 * 720 * 5mm), under 28 ℃ of conditions, forming and hardening demoulding after 20 hours, after the demoulding at 28 ℃, relative air humidity, is treated to be colored pantile finished product after the pigment completely solidified with polyester pigment spraying pantile front less than after the indoor maintenance to 28 under 80% condition day.
Finished product its key technical indexes after measured is as follows:
Walk crosswise fracture resistence force: the vertical fracture resistence force of 4750N/m: 330N/m
Anti-impact force: do not chap, the flawless opacity: an immersion back watt quilt cover does not have the spot of spreading and sinking in, water droplet
Frost resistance: no aliquation phenomenon weathering age changes level after 25 freeze thawing: no change
Water-intake rate: 11% horizontal firing S:0 is S:0 then vertically
Weathering age aberration level: 0.66.

Claims (1)

1. rhombspar magnesium-cement corrugated tile and manufacture method thereof, it is characterized in that the rhombspar magnesium-cement corrugated tile is by the caustic dolomite powder, magnesium chloride, light filler, inert filler, water and lagging material are formed, its mass ratio is 1.00: 0.12~0.40: 0.10~0.60: 0.05~0.30: 0.44~1.20: 0.05~0.30, the middle an amount of supporting material that adds, supporting material is middle alkali glass silk cloth and non-woven fabrics, light filler is sawdust or straw (shell) or agricultural crop straw powder or its mixture etc., inert filler is flyash or slag powders or talcum powder or its mixture etc., lagging material is pearlstone or expanded vermiculite or organic polymer or its mixture etc., its manufacture method is for mixing slurry → forming and hardening → maintenance, the processing requirement of mixing slurry is formation magnesium chloride solution that magnesium chloride is dissolved in the water in proportion, magnesium chloride solution and caustic dolomite powder, light filler, inert material, the pro rata mixture of lagging material carries out mix, form caustic dolomite magnesium cement slurry, the processing requirement of forming and hardening is that above-mentioned caustic dolomite magnesium cement slurry is injected system watt machine or particular manufacturing craft, an amount of supporting material is put in the shop, solidify the demoulding after 18~24 hours under 10~40 ℃ of conditions, the processing requirement of maintenance is at 10~40 ℃ after the demoulding, relative air humidity less than indoor maintenance under 80% condition greater than 28 days.
CN201010541818A 2010-11-03 2010-11-03 Dolomite magnesia cement corrugated tile and manufacturing method thereof Active CN102050615B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201010541818A CN102050615B (en) 2010-11-03 2010-11-03 Dolomite magnesia cement corrugated tile and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201010541818A CN102050615B (en) 2010-11-03 2010-11-03 Dolomite magnesia cement corrugated tile and manufacturing method thereof

Publications (2)

Publication Number Publication Date
CN102050615A true CN102050615A (en) 2011-05-11
CN102050615B CN102050615B (en) 2012-09-12

Family

ID=43955474

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201010541818A Active CN102050615B (en) 2010-11-03 2010-11-03 Dolomite magnesia cement corrugated tile and manufacturing method thereof

Country Status (1)

Country Link
CN (1) CN102050615B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102951895A (en) * 2012-12-10 2013-03-06 常熟建工建设集团有限公司苏州分公司 Novel ecological composite tile for building
CN103922678A (en) * 2014-03-20 2014-07-16 北京市飞翔建筑艺术雕刻有限责任公司 Roof tiles and manufacture method thereof
CN104230258A (en) * 2014-08-25 2014-12-24 沈礼群 Straw heat-insulating colored tile and preparation method thereof
CN106007645A (en) * 2016-05-18 2016-10-12 青海文旅投资有限公司 Magnesia composite material for roofs and preparation process of magnesium composite
CN106348693A (en) * 2016-08-29 2017-01-25 玉林兴业闽福钰耀建材厂 Insulation bending asbestos tile and preparing method thereof
CN106365565A (en) * 2016-08-29 2017-02-01 玉林兴业闽福钰耀建材厂 Asbestos tile and preparation method thereof
CN106396568A (en) * 2016-08-29 2017-02-15 玉林兴业闽福钰耀建材厂 Fireproof and waterproof high-strength asbestos tile and production method thereof
CN108996954A (en) * 2018-09-25 2018-12-14 新乡市鑫寓彩瓦科技有限公司 A kind of durability cement encaustic tile and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0355507A1 (en) * 1988-08-17 1990-02-28 Siemens Aktiengesellschaft Process for solidifying liquid waste concentrates
CN1098394A (en) * 1994-07-01 1995-02-08 薛耀民 A kind of magnesite binding material and uses thereof
RU2136623C1 (en) * 1996-02-29 1999-09-10 Ивановская государственная химико-технологическая академия Magnesian binder
KR20030036382A (en) * 2003-03-21 2003-05-09 안성호 Cement terazo composite materials using the magnesia
CN101070238A (en) * 2007-06-18 2007-11-14 刘丰 Bolivian magnesium external wall board and floor board thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0355507A1 (en) * 1988-08-17 1990-02-28 Siemens Aktiengesellschaft Process for solidifying liquid waste concentrates
CN1098394A (en) * 1994-07-01 1995-02-08 薛耀民 A kind of magnesite binding material and uses thereof
RU2136623C1 (en) * 1996-02-29 1999-09-10 Ивановская государственная химико-технологическая академия Magnesian binder
KR20030036382A (en) * 2003-03-21 2003-05-09 안성호 Cement terazo composite materials using the magnesia
CN101070238A (en) * 2007-06-18 2007-11-14 刘丰 Bolivian magnesium external wall board and floor board thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102951895A (en) * 2012-12-10 2013-03-06 常熟建工建设集团有限公司苏州分公司 Novel ecological composite tile for building
CN103922678A (en) * 2014-03-20 2014-07-16 北京市飞翔建筑艺术雕刻有限责任公司 Roof tiles and manufacture method thereof
CN103922678B (en) * 2014-03-20 2015-08-26 北京市飞翔建筑艺术雕刻有限责任公司 Roofing tile and manufacture method thereof
CN104230258A (en) * 2014-08-25 2014-12-24 沈礼群 Straw heat-insulating colored tile and preparation method thereof
CN106007645A (en) * 2016-05-18 2016-10-12 青海文旅投资有限公司 Magnesia composite material for roofs and preparation process of magnesium composite
CN106348693A (en) * 2016-08-29 2017-01-25 玉林兴业闽福钰耀建材厂 Insulation bending asbestos tile and preparing method thereof
CN106365565A (en) * 2016-08-29 2017-02-01 玉林兴业闽福钰耀建材厂 Asbestos tile and preparation method thereof
CN106396568A (en) * 2016-08-29 2017-02-15 玉林兴业闽福钰耀建材厂 Fireproof and waterproof high-strength asbestos tile and production method thereof
CN108996954A (en) * 2018-09-25 2018-12-14 新乡市鑫寓彩瓦科技有限公司 A kind of durability cement encaustic tile and preparation method thereof

Also Published As

Publication number Publication date
CN102050615B (en) 2012-09-12

Similar Documents

Publication Publication Date Title
CN102050615B (en) Dolomite magnesia cement corrugated tile and manufacturing method thereof
CN102060501B (en) Dolomite magnesium cement inner and outer wall fireproof decoration board and preparation method thereof
CN102040365A (en) Light dolomite magnesium cement partition plate and manufacturing method thereof
CN105967535B (en) Ground polymers foam concrete, foam concrete sandwich composite thermo-insulating wall board and preparation
CN102875073B (en) Aerated brick
CN102417331B (en) Thermal insulation sheet material and preparation method thereof
CN103626458B (en) A kind of preparation method of light gypsum base anti-fire door core board
CN101514089B (en) Self-insulation external wallboard for buildings
CN104631688A (en) Microcrystalline foamed wall block produced by use of tailings and manufacturing method of microcrystalline foamed wall block
CN107840612B (en) High-strength light inorganic energy-saving heat-insulating building material and preparation method thereof
CN101492943B (en) Self-insulating decorative building block and method for producing the same
CN102786317B (en) Recycled foam material using granite powder as raw material
CN102924001A (en) Novel expanded perlite insulation board and preparation method thereof
CN101725210A (en) Light foaming sandwich heat and moisture preserving building block
CN102643064B (en) Energy-saving fireproof insulation board and manufacturing method thereof
CN102173677A (en) Inflaming retarding building heat insulation material and production method thereof
CN105350706A (en) Glass fiber grid cloth enhanced inorganic organic composite lightweight baffle wall
CN103833324A (en) Composite fireproof insulation board
CN102400530A (en) Low-carbon fireproof thermal insulation decoration integrated board and preparation method thereof
CN102408210B (en) Heat insulation decoration plate and preparation method thereof
CN105601220A (en) Multifunctional improved decoration material and preparation method thereof
CN101891446B (en) Preparation method of novel energy-saving inorganic thermal insulation plate
CN105239681A (en) Inorganic fireproof thermal insulation plate and preparation method thereof
CN105350707A (en) Mineral fiber reinforced green energy-saving environmentally-friendly novel wall and preparation method
CN102503252B (en) Light building exterior wall fireproof and heat insulating material prepared by slag rock wool

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant